Bibliographies thématiques / Functional Porous Nanocomposite

Littérature scientifique sur le sujet « Functional Porous Nanocomposite »

Auteur : Grafiati
Publié le 7 septembre 2023

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Articles de revues sur le sujet "Functional Porous Nanocomposite"

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Al-Arjan, Wafa Shamsan, Muhammad Umar Aslam Khan, Samina Nazir, Saiful Izwan Abd Razak et Mohammed Rafiq Abdul Kadir. « Development of Arabinoxylan-Reinforced Apple Pectin/Graphene Oxide/Nano-Hydroxyapatite Based Nanocomposite Scaffolds with Controlled Release of Drug for Bone Tissue Engineering : In-Vitro Evaluation of Biocompatibility and Cytotoxicity against MC3T3-E1 ». Coatings 10, no 11 (20 novembre 2020) : 1120. http://dx.doi.org/10.3390/coatings10111120.

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Fabrication of reinforced scaffolds to repair and regenerate defected bone is still a major challenge. Bone tissue engineering is an advanced medical strategy to restore or regenerate damaged bone. The excellent biocompatibility and osteogenesis behavior of porous scaffolds play a critical role in bone regeneration. In current studies, we synthesized polymeric nanocomposite material through free-radical polymerization to fabricate porous nanocomposite scaffolds by freeze drying. Functional group, surface morphology, porosity, pore size, and mechanical strength were examined through Fourier Transform Infrared Spectroscopy (FTIR), Single-Electron Microscopy (SEM), Brunauer-Emmet-Teller (BET), and Universal Testing Machine (UTM), respectively. These nanocomposites exhibit enhanced compressive strength (from 4.1 to 16.90 MPa), Young’s modulus (from 13.27 to 29.65 MPa) with well appropriate porosity and pore size (from 63.72 ± 1.9 to 45.75 ± 6.7 µm), and a foam-like morphology. The increasing amount of graphene oxide (GO) regulates the porosity and mechanical behavior of the nanocomposite scaffolds. The loading and sustained release of silver-sulfadiazine was observed to be 90.6% after 260 min. The in-vitro analysis was performed using mouse pre-osteoblast (MC3T3-E1) cell lines. The developed nanocomposite scaffolds exhibited excellent biocompatibility. Based on the results, we propose these novel nanocomposites can serve as potential future biomaterials to repair defected bone with the load-bearing application, and in bone tissue engineering.
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Gerawork, Mekdes. « Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite ». Water Science and Technology 83, no 11 (29 avril 2021) : 2753–61. http://dx.doi.org/10.2166/wst.2021.165.

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Abstract Heterogeneous photocatalysis using nanocomposites is of great research interest in the treatment of industrial wastewater. The impregnated photocatalyst was produced by liquid state reaction of ZnO/CuO nanocomposite with extracted eggshells. The structure, functional group, metal composition, bandgap, and photocatalytic activity of the nanocomposites were characterized by using X-ray diffraction, Fourier-transform infrared spectroscopy, atomic absorption spectrometry, and UV–Vis spectroscopy, respectively, in the absence and presence of eggshells. Photocatalytic degradation activities of the nanocomposites under UV light irradiation have been tested for a real sewage sample taken from Debre Berhan Textile Industry. From the results, the optimized degradation efficiency of the dye was 97.95% with 0.4 g dose of the photocatalyst, 120 min irradiation time, 120 °C temperature, and pH of 6.7. The results revealed that eggshell impregnated nanocomposite had better catalytic activity than the naked nanocomposite. This is due to the highly porous structure of eggshell biomasses and their sorption characteristics. In conclusion, when nanocomposites are supported by eggshell biomasses, they are excellent photocatalysts and can minimize the contamination of organic dyes from textile effluents.
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Kundana, N., M. Venkatapathy, V. Neeraja, Chandra Sekhar Espenti, Venkata Ramana Jeedi et V. Madhusudhana Reddy. « Effect of Zr-Nanofiller on Structural and Thermal Properties of PVDF-co-HFP Porous Polymer Electrolyte Membranes Doped with Mg2+ Ions ». Asian Journal of Chemistry 35, no 1 (27 décembre 2022) : 99–108. http://dx.doi.org/10.14233/ajchem.2023.26893.

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New poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP)/ZrO2-based nanocomposite porous polymer membranes were prepared with doping of magnesium ions using THF as solvent. These membranes were prepared using the solvent casting technique. The optimal nanofiller (0, 2, 4, 6, 8 and 10% Zr nanopowder) was incorporated into the PVDF-co-HFP/MgTf3/ZrO2 and the incorporation of the nanofiller results in an increase in the porosity of the prepared membranes. The structural, morphological and thermal properties of the nanocomposite porous polymer membranes were also investigated. The structural investigation and the identification of functional groups were accomplished using FTIR technique. X-ray diffraction (XRD) analysis was performed to ascertain the phase of polymer membranes and the phase change that happens upon interaction with nanofiller and Mg2+ ions. Assessment of the nanocomposite porous polymer membrane's morphology and porous structure was performed using a scanning electron microscope (SEM). DSC analysis was used to evaluate the thermal behaviour of the nanocomposite porous membranes. The electrical and dielectric studies confirmed the structural reformation of the polymer electrolyte materials. It was found that 8% nanofiller is the best conducting composition for maximum ionic conductivity, dielectric constant and Mg2+ ion mobility. The incorporation of ZrO2 nanofiller predominantly increases the number of free ions and mobility of the charge carriers in the composite polymer electrolyte systems.
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Madhu, Rajesh, Vediyappan Veeramani, Shen-Ming Chen, Pitchaimani Veerakumar, Shang-Bin Liu et Nobuyoshi Miyamoto. « Functional porous carbon–ZnO nanocomposites for high-performance biosensors and energy storage applications ». Physical Chemistry Chemical Physics 18, no 24 (2016) : 16466–75. http://dx.doi.org/10.1039/c6cp01285j.

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Motin, Georgy Yu, et Aleksandr N. Kokatev. « Nanoporous alumina membranes as the basis for functional nanocomposite materials ». Transactions of the Kоla Science Centre of RAS. Series : Engineering Sciences 13, no 1/2022 (27 décembre 2022) : 173–79. http://dx.doi.org/10.37614/2949-1215.2022.13.1.030.

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In the present study, we report about results of obtaining nanocomposite materials based on various types of nanoporous alumina membranes (NAM). The NAM were fabricated by two ways: (I) — using the technique of thinning the barrier layer of porous anodic alumina; (2) — by two-layer galvanostatic electrochemical anodization of aluminium samples. Using atomic force microscopy, it was found that a method of thermal decomposition of K2MnO4 leads to the formation of nanoparticles γ-MnO2 with size ~ 20 nm on the surface and in the pores of NAM, and the use of the method of photochemical synthesis of Ag nanoparticles with a size of ~ 30 nm.
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Lin, Tao, Wenlong Liu, Bin Yan, Jing Li, Yi Lin, Yinghui Zhao, Zheng Shi et Sheng Chen. « Self-Assembled Polyaniline/Ti3C2Tx Nanocomposites for High-Performance Electrochromic Films ». Nanomaterials 11, no 11 (4 novembre 2021) : 2956. http://dx.doi.org/10.3390/nano11112956.

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Electrochromic materials and devices are attracting intense attention because of their low energy consumption and open-circuit memory effect. Considering the difficult processing characteristics of electrochromic conductive polymers, we developed a facile and scalable strategy to prepare solution processable polyaniline (PANI)-based nanocomposites by introducing two-dimensional titanium carbon nanosheets (MXene) through a self-assembly approach. The PANI/MXene nanocomposite can be fabricated into porous films via spray-coating process, which show an obvious synergetic effect of both materials, leading to superior electrochromic properties. The optical contrast of the optimized PANI/MXene film reached as high as 55% at =700 nm, and its response times were 1.3 s for coloration and 2.0 s for bleaching, respectively. In addition, the composite film also showed excellent cycle stability (after 500 cycles, the ΔT retention was above 87%). The improved electrochromic properties are owed to the high conductivity of MXene and the formation of the porous composite film structure, which promote the electronic/ionic transfer and migration efficiency. This research suggests that the self-assembly method and the conductive polymer/MXene nanocomposites have a potential application in the fields of electronic functional films and devices.
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Leontiev, Alexey P., Olga Yu Volkova, Irina A. Kolmychek, Anastasia V. Venets, Alexander R. Pomozov, Vasily S. Stolyarov, Tatiana V. Murzina et Kirill S. Napolskii. « Tuning the Optical Properties of Hyperbolic Metamaterials by Controlling the Volume Fraction of Metallic Nanorods ». Nanomaterials 9, no 5 (14 mai 2019) : 739. http://dx.doi.org/10.3390/nano9050739.

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Porous films of anodic aluminum oxide are widely used as templates for the electrochemical preparation of functional nanocomposites containing ordered arrays of anisotropic nanostructures. In these structures, the volume fraction of the inclusion phase, which strongly determines the functional properties of the nanocomposite, is equal to the porosity of the initial template. For the range of systems, the most pronounced effects and the best functional properties are expected when the volume fraction of metal is less than 10%, whereas the porosity of anodic aluminum oxide typically exceeds this value. In the present work, the possibility of the application of anodic aluminum oxide for obtaining hyperbolic metamaterials in the form of nanocomposites with the metal volume fraction smaller than the template porosity is demonstrated for the first time. A decrease in the fraction of the pores accessible for electrodeposition is achieved by controlled blocking of the portion of pores during anodization when the template is formed. The effectiveness of the proposed approach has been shown in the example of obtaining nanocomposites containing Au nanorods arrays. The possibility for the control over the position of the resonance absorption band corresponding to the excitation of collective longitudinal oscillations of the electron gas in the nanorods in a wide range of wavelengths by controlled decreasing of the metal volume fraction, is shown.
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Tsou, Chi-Hui, Rui Zeng, Chih-Yuan Tsou, Jui-Chin Chen, Ya-Li Sun, Zheng-Lu Ma, Manuel Reyes De Guzman, Lian-Jie Tu, Xin-Yuan Tian et Chin-San Wu. « Mechanical, Hydrophobic, and Barrier Properties of Nanocomposites of Modified Polypropylene Reinforced with Low-Content Attapulgite ». Polymers 14, no 17 (5 septembre 2022) : 3696. http://dx.doi.org/10.3390/polym14173696.

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Attapulgite (ATT) has never been used as a barrier additive in polypropylene (PP). As a filler, ATT should be added in high content to PP. However, that would result in increased costs. Moreover, the compatibility between ATT and the PP matrix is poor due to the lack of functional groups in PP. In this study, carboxylic groups were introduced to PP to form a modified polypropylene (MPP). ATT was purified, and a low content of it was added to MPP to prepare MPP/ATT nanocomposites. The analysis from FTIR indicated that ATT could react with MPP. According to the results of oxygen and water permeability tests, the barrier performance of the nanocomposite was optimal when the ATT content was 0.4%. This great improvement in barrier performance might be ascribed to the following three reasons: (1) The existence of ATT extended the penetration path of O2 or H2O molecules; (2) O2 or H2O molecules may be adsorbed and stored in the porous structure of ATT; (3) Most importantly, –COOH of MPP reacted with –OH on the surface of ATT, thereby the inner structure of the nanocomposite was denser, and it was less permeable to molecules. Therefore, nanocomposites prepared by adding ATT to MPP have excellent properties and low cost. They can be used as food packaging materials and for other related applications.
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Dzyazko, Yuliya, Ludmila Ponomarova, Yurii Volfkovich, Valentina Tsirina, Valentin Sosenkin, Nadiya Nikolska et Volodimir Belyakov. « Influence of Zirconium Hydrophosphate Nanoparticles on Porous Structure and Sorption Capacity of the Composites Based on Ion Exchange Resin ». Chemistry & ; Chemical Technology 10, no 3 (15 septembre 2016) : 329–35. http://dx.doi.org/10.23939/chcht10.03.329.

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Evolution of swelling of gel-like strongly acidic resin and organic-inorganic composites based on this ion-exchanger was investigated. Non-aggregated nanoparticles of zirconium hydrophosphate were found to provide size invariability of the polymer pores, which contain functional groups (up to 20 nm), the nanoparticle aggregates squeeze these pores (down to 3 nm). Owing to this, the nanocomposite shows higher break-through capacity during removal of Ni2+ from water, than the sample modified only with aggregates.
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Sun, Dongshu, Minjia Meng, Yao Lu, Bo Hu, Yongsheng Yan et Chunxiang Li. « Porous nanocomposite membranes based on functional GO with selective function for lithium adsorption ». New Journal of Chemistry 42, no 6 (2018) : 4432–42. http://dx.doi.org/10.1039/c7nj04733a.

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Thèses sur le sujet "Functional Porous Nanocomposite"

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Chubenko, E. B., A. L. Dolgiy, S. V. Redko, A. I. Sherstnyov, K. I. Yanushkevich, S. L. Prischepa et V. P. Bondarenko. « Functional Nanocomposites Formation by Electrochemical Deposition of Metals and Semiconductors into Porous Silicon ». Thesis, Sumy State University, 2015. http://essuir.sumdu.edu.ua/handle/123456789/42558.

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The paper concerns the study of formation of nanocomposites by electrochemical deposition of metals and semiconductors into the porous silicon. Ni and ZnO were used as experimental materials for deposition. The influence of deposition process parameters and structure of initial porous silicon substrates on morphology and composition of formed metal or semiconductor nanostructures are studied. Obtained nanocomposites demonstrated high filling factor and uniformity. Porous silicon/Ni nanocomposites showed strong magnetic anisotropy. Porous silicon/ZnO nanocomposites after thermal annealing had intensive photoluminescence in the visible range. Applications of obtained nanocomposites in the magnetic and optoelectronic devices discussed as well.
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Chapitres de livres sur le sujet "Functional Porous Nanocomposite"

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Asghar, Hamza, Sara Baig, Mahnoor Naeem, Shamim Aslam, Aneeqa Bashir, Saadia Mumtaz, Muhammad Ikram et al. « Graphene Based Functional Hybrids : Design and Technological Applications ». Dans Graphene - Recent Advances, Future Perspective and Applied Applications [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.108791.

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Because of the versatile chemical, physical, and electrical properties, graphene as well as its nanocomposites are regarded as the backbone of engineering and scientific innovation. Different physical and chemical methods are used to create sustainable carbon materials. Furthermore, fabrication methods are employed in order to produce the composites, which are of constituents with desirable properties. Because of their biocompatibility, graphene nanomaterials have enormous potential for improving biology and drug delivery. The proposed chapter provides a variety of fabrication methods for sustainable graphene composites and highlights various applications of graphene. Furthermore, graphene nanocomposites are promising multifunctional materials with improved tensile strength and elastic modulus. Despite some challenges and the fact that carbon nanotube/polymer composites are sometimes better in some specific performance, graphene nanocomposites may have a wide range of potential applications due to their outstanding properties and the low cost of graphene. Because these graphene composites have a controllable porous structure, a large surface area, high conductivity, high temperature stability, excellent anti-corrosion properties, and composite compatibility, they can be used in energy storage as electrocatalysts, electro-conductive additives, intercalation hosts, and an ideal substrate for active materials. Meanwhile, the chapter summaries the graphene nanocomposites requirements for technological innovation and scientific applied research.
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Actes de conférences sur le sujet "Functional Porous Nanocomposite"

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CHAUDHARI, AMIT, SAGAR DOSHI, MADISON WEISS, DAE HAN SUNG et ERIK THOSTESON. « CARBON NANOCOMPOSITE COATED TEXTILE-BASED SENSOR : SENSING MECHANISM AND DURABILITY ». Dans Thirty-sixth Technical Conference. Destech Publications, Inc., 2021. http://dx.doi.org/10.12783/asc36/35854.

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Carbon nanotube (CNT) composite films are deposited onto stretchable knit fabrics using electrophoretic deposition (EPD) and dip-coating techniques, which are industrially scalable processes for producing future wearable sensors. The deposited CNTs create an electrically conductive nanocomposite film on the surface of the fibers. These nanocomposite coated fabrics exhibit piezoresistive properties; under mechanical deformation/stretching, a large change in the electrical resistance is observed. Polyethyleneimine (PEI) functionalized carbon nanotubes deposited using EPD create a uniform, extremely thin porous coating on the fiber. Initial results show ultrahigh sensitivity of the carbon nanotube coated fabric when tested on elbow/knee to detect range of motion. The sensitivity of these sensors is exceptionally high when compared to a typical carbon nanotube-based polymer nanocomposite. The nanocomposite coating does not affect fabric's breathability or flexibility, making the sensor comfortable to wear. Because of these unique properties, tremendous potential exists for their use in functional/smart garments. Changes in electrical resistance for these fabrics are influenced by a combination of electron tunneling between the carbon nanotubes and the microstructure of the fabric. To investigate and characterize the unique sensing mechanism, the nanotube coated knit fabric's electromechanical response is studied at different length scales, from individual yarns to fabric levels. For applications in wearable sensors, the durability of the nanotube coating on the fabric is critical for repeatable and reliable sensing response. Durability testing of the sensing fabric for washing loads was conducted to study the nanotube coating's robustness. CNT coating's adhesion quality is evaluated based on the weight loss in the specimen and loss in electrical conductivity in each wash cycle. This research addresses the potential of these sensors for functional/smart garments by examining the underlying mechanism of the sensor response and the durability of the carbon nanotube coating.
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Behdinan, Kamran, et Rasool Moradi-Dastjerdi. « Electro-Mechanical Behavior of Smart Sandwich Plates With Porous Core and Graphene-Reinforced Nanocomposite Layers ». Dans ASME 2019 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/imece2019-10796.

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Abstract The use of piezoelectric sensor and/or actuator layers in engineering structures provides smart sandwich structures with adaptive responses. Moreover, due to the brittle behavior of piezoceramic materials, inserting nanocomposite and porous layers between piezoelectric layers offers more flexible and lighter structures along with maintaining the advantages of nanocomposite materials. Therefore, in this paper, we have proposed smart sandwich plates consisting of a porous polymeric core and two graphene-reinforced composite (GRC) layers integrated with two piezoceramic layers. The distributions of porosities and randomly oriented graphene particles are assumed to be functionally graded (FG) along the thickness of core and nanocomposite layers, respectively. For the static behavior of the proposed sandwich plates, the coupled electro-mechanical governing equation has been extracted by minimizing potential energy equation with respect to displacement and electrical potential. The governing equation has been discretized by adopting a higher order shear deformation theory (HSDT) of plates and a developed mesh-free method. Using the developed solution framework, the effects of porosity and graphene characteristics, electromechanical loads, and layer thicknesses on the deflection behavior of the proposed FG piezoelectric porous nanocomposite sandwich plates (FG-PPNSPs) have been studied.
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SUKATI, MUSA, ANIRBAN MONDAL, MRINAL C. SAHA, YINGTAO LIU, STEVEN PATTERSON et THOMAS ROBISON. « Additive Manufacturing of Controlled Porous Elastomeric Nanocomposites for Enhanced Sensing Function ». Dans American Society for Composites 2020. Lancaster, PA : DEStech Publications, Inc., 2020. http://dx.doi.org/10.12783/asc35/34851.

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Gou, J., H. C. Gu et G. Song. « Carbon Nanopaper Sheets for Damping Applications : Processing and Characterization ». Dans ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-41914.

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Carbon nanotubes and carbon nanofibers have been used as nanofillers for high performance damping composite materials in recent years. The large specific area (1000 m2/g) and aspect ratio (>1000) of carbon nanotubes and nanofibers promote significant interfacial friction between carbon nanotubes/nanofibers and the polymer matrix. The high stiffness and strength of carbon nanotubes and nanofibers enlarge the differences in the strains of individual constituents of the composites, which causes much higher energy dissipation in the polymer matrix. However, adding small amount of carbon nanotubes and nanofibers will significant increase the viscosity of polymer resin, which makes the dispersion and resin flow through the porous fiber mats extremely difficult. In addition, the fiber mats will filter carbon nanotubes and nanofibers during liquid molding process such as Resin Transfer Molding (RTM) and Vacuum-Assisted Resin Transfer Molding (VARTM). A unique concept of manufacturing nanocomposites with carbon nanotube/nanofiber based nanopaper sheets for structural damping applications has recently been explored. This approach involves making carbon nanopaper sheet by the filtration of well-dispersed carbon nanotubes and carbon nanofibers under controlled processing conditions. Subsequently, carbon nanopaper sheets are integrated into composite laminates using Vacuum Assisted Resin Transfer Molding (VARTM) process. In this study, several nanocomposite plates were fabricated with carbon nanopaper sheet as surface layer. For the comparative study, the regular composite plates without carbon nanopaper sheet were also fabricated. To identify the damping characteristics of each specimen, the Frequency Response Function (FRF) was estimated by a pair of piezoceramic patches: one as an actuator to excite the specimen and the other as a sensor to detect the induced vibrations. From the FRF, the damping ratio of the specimen at each modal frequency of interests was calculated. The experimental results clearly show a significant improvement of damping properties of nanocomposites plates. This research demonstrates structural damping enhancement via carbon nanopaper sheets and provided basic understanding of the damping characteristics for the optimal design and fabrication of high performance damping composites, which have the potential to be used as structural components for many applications.
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Katti, Kalpana S., Dinesh R. Katti et Avinash H. Ambre. « Unnatural Amino Acids Modified Clays for Design of Scaffolds for Bone Tissue Engineering ». Dans ASME 2010 First Global Congress on NanoEngineering for Medicine and Biology. ASMEDC, 2010. http://dx.doi.org/10.1115/nemb2010-13242.

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Here, we incorporate the results of our new “altered phase theory” (Sikdar et al. 2008a) into design of new polymer clay nanocomposites (PCNs) for bone biomaterials applications. Montmorillonite (MMT) clay was modified using unnatural amino acids as potentially new biocompatible modifiers. The longer carbon chain structures of the unnatural amino acids are expected to enhance non bonded interactions with clay as well as maintaining the usefulness of functional groups of natural amino acids. The specific choice of amino acids is based on both the antibacterial activity reported in literature and also our previous studies on role of chain length, functional groups etc of modifiers in influencing mechanical behavior in PCNs. Biocompatibility studies using cell culture experiments as well as mechanical behavior is evaluated for the PCNs. FTIR spectroscopy is used to compare changes to molecular structure. The increase in d001 spacing of modified clay compared to pure clay obtained from XRD experiments confirms successful intercalation of modifier. The osteoblast cells were found to grow and proliferate over the substrates. The major contribution of this work is the design of novel amino acid biopolymer-clay nanocomposites for biomaterials applications. Porous scaffold structures were also designed and fabricated.
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