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Littérature scientifique sur le sujet « Diazirina »

Auteur : Grafiati

Publié le 9 mars 2023

Mis à jour le 10 mars 2023

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Articles de revues sur le sujet "Diazirina"

Beiroth, Femke, Tomas Koudelka, Thorsten Overath, Stefan D. Knight, Andreas Tholey et Thisbe K. Lindhorst. « Diazirine-functionalized mannosides for photoaffinity labeling : trouble with FimH ». Beilstein Journal of Organic Chemistry 14 (24 juillet 2018) : 1890–900. http://dx.doi.org/10.3762/bjoc.14.163.

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Photoaffinity labeling is frequently employed for the investigation of ligand–receptor interactions in solution. We have employed an interdisciplinary methodology to achieve facile photolabeling of the lectin FimH, which is a bacterial protein, crucial for adhesion, colonization and infection. Following our earlier work, we have here designed and synthesized diazirine-functionalized mannosides as high-affinity FimH ligands and performed an extensive study on photo-crosslinking of the best ligand (mannoside 3) with a series of model peptides and FimH. Notably, we have employed high-performance mass spectrometry to be able to detect radiation results with the highest possible accuracy. We are concluding from this study that photolabeling of FimH with sugar diazirines has only very limited success and cannot be regarded a facile approach for covalent modification of FimH.

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Baldwin, J. E., J. B. Coates, J. B. Halpern, M. G. Moloney et A. J. Pratt. « Photoaffinity labelling of isopenicillin N synthetase by laser-flash photolysis ». Biochemical Journal 261, n^o 1 (1 juillet 1989) : 197–204. http://dx.doi.org/10.1042/bj2610197.

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Isopenicillin N synthetase (IPNS) from Acremonium chrysogenum was photolabelled by laser-flash photolysis in the presence of a diazirinyl-containing substrate, 2-[3-(3-trifluoromethyl-3H-diazirin-3-yl)-phenoxy]acetyl-S- methyloxycarbonylsulphenyl-L-cysteinyl-D-valine (DCV). Labelling of IPNS by DCV is partially inhibited in the presence of an excess of L-alpha-aminoadipoyl-L-cysteinyl-D-valine (ACV), the natural substrate. In the absence of light, DCV is converted into the corresponding penicillin with comparable Km but significantly depressed Vmax relative to ACV. Selective incorporation of [14C]DCV into IPNS has been demonstrated by fluorography of IPNS analysed by SDS/polyacrylamide-gel electrophoresis. Scintillation counting of labelled IPNS purified on an ion-exchange f.p.l.c. column confirms this result. This methodology may be applicable for studies aimed at investigating the binding of substrates to IPNS.

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Cheng, Xiaju, Rui Sun, Huawei Xia, Jianan Ding, Ling Yin, Zhifang Chai, Haibin Shi et Mingyuan Gao. « Light-triggered crosslinking of gold nanoparticles for remarkably improved radiation therapy and computed tomography imaging of tumors ». Nanomedicine 14, n^o 22 (novembre 2019) : 2941–55. http://dx.doi.org/10.2217/nnm-2019-0015.

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Aim: We aimed to characterize the tumor-targeting and radiosensitization properties of the photo-responsive gold nanoparticles (AuNPs) decorated photolabile diazirine group and folic acid for improved radiotherapy and computed tomography imaging of tumors. Methods: Folic acid and photolabile diazirine group were covalently conjugated on the surface of AuNPs to afford the desired photo-responsive dAuNP-FA (AuNPs capped with poly(ethylene) glycol ligands bearing photolabile diazirine group and folic acid). The probes were intravenously injected into tumor-bearing mice followed by photocrosslinking upon 405 nm laser irradiation for radiotherapy and computed tomography imaging of tumors in vivo. Results: Light-triggered crosslinking of AuNPs in vivo remarkably enhanced the accumulation and retention of AuNPs within tumors. Conclusion: We have successfully developed a novel photo-responsive Au particle-based tumor theranostic probe showing remarkably improved tumor targeting ability and radiosensitization effect.

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Ghiassian, Sara, Mark C. Biesinger et Mark S. Workentin. « Synthesis of small water-soluble diazirine-functionalized gold nanoparticles and their photochemical modification ». Canadian Journal of Chemistry 93, n^o 1 (janvier 2015) : 98–105. http://dx.doi.org/10.1139/cjc-2014-0287.

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Dual water and organic solvent soluble 3-aryl-3-(trifluormethyl) diazirine-functionalized gold nanoparticles (AuNPs) were prepared through a place exchange reaction from triethylene glycol monomethyl ether (EG3-Me) capped AuNPs. These nanoparticles were fully characterized using 1H and 19F nuclear magnetic resonance (NMR) spectroscopy, transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). TGA along with 1H NMR data allowed the determination of 15% incorporation of diazirine (Diaz) ligands onto mixed monolayer AuNPs, while TEM images showed an average diameter of 2.3 ± 0.5 nm. This information led to the estimated molecular formula of Au400 (S-EG4-Diaz)40 (S-EG3-Me)230 for these AuNPs. It is noteworthy that high-resolution XPS was a powerful tool for quantitative analysis. Irradiation of the diazirine capped AuNPs resulted in nitrogen extrusion and the formation of a highly reactive carbene with evidence of a portion of the reaction proceeding via the diazo intermediate and thus requiring a second photon for activation. The carbene species generated was utilized to tether the attached AuNPs via insertion into C=C or O–H functionality inherent on various substrates. Here, we demonstrated that photolysis of the diazirine modified AuNPs in the presence of a variety of model carbene scavengers led to clean and efficient insertion products while maintaining their solubility in polar solvents.

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Puzzarini, Cristina, et Alberto Gambi. « A theoretical study of diazirine (H2CN2), diazirinyl radical (HCN2) and their related cations (H2CN2+,HCN2+) : molecular structure, energetics and ionization potential ». Chemical Physics 306, n^o 1-3 (novembre 2004) : 131–41. http://dx.doi.org/10.1016/j.chemphys.2004.07.024.

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Walko, Martin, Eric Hewitt, Sheena E. Radford et Andrew J. Wilson. « Design and synthesis of cysteine-specific labels for photo-crosslinking studies ». RSC Advances 9, n^o 14 (2019) : 7610–14. http://dx.doi.org/10.1039/c8ra10436k.

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Verma, Udai P., Klaus Möller, Jürgen Vogt, Manfred Winnewisser et Jørn Johs Christiansen. « Microwave and millimetre wave spectra of diazirine-d2 : Rotational and hyperfine structure analysis and molecular structure ». Canadian Journal of Physics 63, n^o 9 (1 septembre 1985) : 1173–83. http://dx.doi.org/10.1139/p85-191.

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The rotational spectrum of diazirine-d2, [Formula: see text], has been recorded in the ranges 8–40 and 100–400 GHz. The hyperfine structure of the measured rotational lines has been analyzed. The analysis required the treatment of two pairs of equivalent nuclei, which is discussed in detail. The deduced deuterium nuclear-quadrupole coupling constants are[Formula: see text]The quadrupole coupling constants of the nitrogen nuclei[Formula: see text]are taken from the parent species, and the spin-rotation coupling constants are[Formula: see text]The rotational and centrifugal distortion constants have been obtained for the ground vibrational state from the analysis of the unperturbed line positions. The complete rs structure of diazirine has been determined using the rotational constants of all available isotopomers of diazirine. The internuclear distances are rs(C—N) = 148.13(24) pm, rs(C—H) = 108.03(29) pm, and rs(N—N) = 122.80(25) pm, and the bond angles are [Formula: see text] and [Formula: see text], with the HCH plane perpendicular to the NCN plane.

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Russell, AJ, AP Scott et L. Radom. « Ab initio Predictions of the Gas-Phase Acidities of Diazirine and Diazomethane ». Australian Journal of Chemistry 48, n^o 2 (1995) : 401. http://dx.doi.org/10.1071/ch9950401.

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Absolute gas-phase acidities of diazirine, diazomethane, dimethylamine, ethylamine and methylamine have been obtained with ab initio molecular orbital calculations at the G2 and G2(MP2) levels of theory. Values at the G2 and G2(MP2) levels are all within 1 kJ mol-1 of one another. The calculated gas-phase acidities for diazomethane, dimethylamine, ethylamine and methylamine (and other reference molecules considered) are all within 3 kJ mol-1 of experiment. For diazirine the calculated result, although consistent with experiment, would suggest an acidity towards the lower end of the range of possible experimental values.

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Dubinsky, Luba, Bastiaan P. Krom et Michael M. Meijler. « Diazirine based photoaffinity labeling ». Bioorganic & ; Medicinal Chemistry 20, n^o 2 (janvier 2012) : 554–70. http://dx.doi.org/10.1016/j.bmc.2011.06.066.

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Fan, Chen-Yo, Yi-Ren Hou, Avijit K. Adak, Juanilita T. Waniwan, Mira Anne C. dela Rosa, Penk Yeir Low, Takashi Angata, Kuo-Chu Hwang, Yu-Ju Chen et Chun-Cheng Lin. « Boronate affinity-based photoactivatable magnetic nanoparticles for the oriented and irreversible conjugation of Fc-fused lectins and antibodies ». Chemical Science 10, n^o 37 (2019) : 8600–8609. http://dx.doi.org/10.1039/c9sc01613a.

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Thèses sur le sujet "Diazirina"

DE, BELLIS VITO. « Multifunctionalized molecular systems for elastomers functionalization and as innovative crosslinkers in rubber compounds ». Doctoral thesis, Università degli Studi di Milano-Bicocca, 2022. http://hdl.handle.net/10281/368240.

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Lo scopo di questo progetto di dottorato riguarda la sintesi di una nuova classe di molecole reticolanti per polimeri utilizzati nel mondo degli pneumatici. In particolare, queste molecole devono essere stabili a temperatura ambiente ma in grado reagire termicamente con la matrice polimerica a temperature maggiori di 100 °C, formando legami covalenti irreversibili. Questi funzionalizzanti devono essere anche semplici da sintetizzare, integrabili in un processo industriale, versatili, economici, relativamente poco tossici e in grado di interagire con il polimero senza però influenzarne significativamente le proprietà. In questo contesto è stato realizzato un sistema in grado di generare due specie reattive in due range di temperature diverse: la prima funzionalità genera un carbene, la seconda una specie 1,3-dipolare di tipo nitrilimminico. Entrambe le specie sono in grado di fornire cicloaddotti con sistemi olefinici. Dopo un’attenta ricerca bibliografica al fine di individuare i sistemi più adatti, sono stati sintetizzati sia composti noti in letteratura sia nuovi, cercando di modulare la temperatura di attivazione di queste strutture. Tutti i sistemi sintetizzati sono stati caratterizzati mediante analisi NMR e IR. La caratterizzazione è stata completata dall’analisi termogravimetrica (TGA), con la quale si è rilevata la temperatura di attivazione delle funzionalità presenti; nonchè la temperatura alla quale dovrebbe avvenire la reazione di cicloaddizione. Infine, sui sistemi più interessanti selezionati, sono state eseguite delle prove di reattività su sistemi polimerici modello e facilmente processabili su scala di laboratorio, al fine di dimostrare l’effettiva funzionalizzazione per via termica. Le molecole che presentavano caratteristiche tecnologiche più interessanti sono state preparate in quantità nell’ordine dei grammi necessari a condurre prove in mescola tramite un mini-mescolatore “Brabander”. Queste mescole sono state poi analizzate tramite RPA (Rubber Process Analyzer) per osservare eventuali effetti positivi dei polimeri funzionalizzati. Il sistema a due temperature di attivazione differenti è stato impiegato per studiare possibili effetti sulla morfologia delle fasi all’interno di blend polimerici: si sfrutta la diversa reattività delle componenti carbenica e nitrilimminica cercando di migliorare l’interazione dei due polimeri nonché le proprietà fisiche del materiale risultante. Tutti le mescole sono state caratterizzate anche tramite swelling, trazioni Dumbbell, DSC, DMA, frequency sweep e densità.
The aim of this PhD project concerns the synthesis of a new class of cross-linking molecules for polymers used in the world of tires. In particular, these molecules must be stable at room temperature but capable of reacting thermally with the polymer matrix at temperatures greater than 100 ° C, forming irreversible covalent bonds. These functionalizers must also be simple to synthesize, integrable in an industrial process, versatile, economical, relatively low toxic and able to interact with the polymer without significantly affecting its properties. In this context, a system that is able to generate two reactive species in two different temperature ranges was created: the first functionality generates a carbene, the second a 1,3-dipolar species of the nitrilimino type. Both species are capable of providing cycloadducts with olefinic systems. After careful bibliographic research in order to identify the most suitable systems, both known and new compounds were synthesized, trying to modulate the activation temperature of these structures. All synthesized systems were characterized by NMR and IR analyzes. The characterization was completed by thermogravimetric analysis (TGA), with which the activation temperature of the functions present was detected; as well as the temperature at which the cycloaddition reaction should take place. Finally, on the most interesting selected systems, reactivity tests were performed on model polymeric systems that could be easily processed on a laboratory scale, in order to demonstrate the actual functionalization by thermal means. The molecules that presented the most interesting technological characteristics were prepared in quantities in the order of grams necessary to conduct compound tests using a "Brabander" mixer. These compounds were then analyzed by RPA (Rubber Process Analyzer) to observe any positive effects of the functionalized polymers. The system with two different activation temperatures was used to study possible effects on the morphology of the phases within polymeric blends: the different reactivity of the carbene and nitrilimine components is exploited, trying to improve the interaction of the two polymers as well as the physical properties of the resulting material. All compounds were also characterized by swelling, Dumbbell traction, DSC, DMA, frequency sweep and density.

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Orlov, Alexander G. « Synthesis of Diazirine-Functionalized Organic Semiconductor Materials ». Bowling Green State University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1354718561.

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Macro, Jason Brindley. « Substituted diazirines as polyfunctional photoactive substrates ». Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.670217.

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Fagour, William. « Synthesis of Polymeric Materials From Novel Monomers Featuring Diazirine Units ». Thesis, University of Reading, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.485366.

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In the past fifty years there have been increased concerns about the impact of pollutants not only on humans, but also on the environment. Significant progress has been made in several key research areas, such as catalysis, the design of safer chemicals and en~ironmentally begnin solvents. However, the constant demand for new materials exhibiting improved physico-chemical properties and commercial advantages within a green chemistry approach renders the development of new t'. . polymer chemistries a very challenging prospect. As a consequence, nitrogen based photochemical reagents raised a lot of interest and attention, since these photoactive substrates may respond to the criteria and principles imposed by 'Green. Chemistry'. Indeed, three membered diazirine rings can generate a very reactive carbene species by the extrusion of a nitrogen molecule upon activation either via ultrasonic, thermal, or photochemical means, and can combine with a broad range of functional groups to create new covalent bonds. Hence, as part of a programme undertaken at the University of Reading, new AB, AB2 and A2+B3 monomers have been targeted and identified. The homo/co polymerisations of 3,5 diallyloxy phenyl-3-methyldiazirine or 1,4-di(methyl diazirine) benzene associated with 1,3,5-tri(hydroxyl) benzene have been realized. In order to benefit from the advantages displayed by diazirines with regard to their chemical stability, preparation and potential applications, the monomers reported here all feature photoactive diazirine rings in conjunction with secondary functionalities such as alkenes or free hydroxyls. It was envisaged that these new diazirine monomer systems would lead to the development of new materials of diverse topologies that may be polymerised photoactively or thermally in situ upon the substrate surface and the preliminary studies in this area are reported in this thesis.

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Wartmann, Thomas [Verfasser]. « Synthese und Reaktivität photolabiler Indol- und Tryptophanderivate mit Diazirin-Teilstruktur / Thomas Wartmann ». München : Verlag Dr. Hut, 2014. http://d-nb.info/1051549752/34.

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Morgan, Scott Christopher. « Experimental and theoretical considerations of carbenes, diazirines, and nitrenes / ». The Ohio State University, 1992. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487779120907133.

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Al-Omari, Mohammad Hasan. « Synthesis of Alkynes from Bi-3H-diazirin-3-yls : Trapping of Strained Cycloalkynes ». Doctoral thesis, Universitätsbibliothek Chemnitz, 2004. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200400059.

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Abstract Al-Omari, Mohammad Synthesis of Alkynes from Bi-3H-diazirin-3-yls: Trapping of Strained Cycloalkynes Chemnitz Technical University, Fakulty of Science Dissertation 2003, 76 pages. In this study, we have succeeded in synthesis of alkynes by a new method using bidiazirines as precursors. Different bidiazirinyl systems, such as acyclic, cyclic, and bicyclic systems, were investigated to show if they could serve as appropriate precursors for cycloalkynes. It has been shown that alkynes of no strain (e.g. 2-butyne) as well as extremely strained cycloalkynes (e.g. norbornyne) could be generated utilizing this method. This new method represents a simple, clean, and very efficient route to alkynes. That the strained cycloalkynes had actually been generated was shown by different trapping experiments. In these experiments, the thermal or photoextrusion of nitrogen atoms of the bidiaziridine moieties will certainly leads to the formation of a C,C triple bond, most probably through carbene intermediate. In terms of their reactions with the trapping dienes reagents, the generated cycloalkynes should be considered as normal, yet strained alkynes. In turn, bidiazirines were easily synthesized by oxidative dehydrogenation of their corresponding bidiaziridines. Bidiaziridines, which were the key step in the whole process, were successfully synthesized from bisdiimine precursors. It has been shown, that bisdiimines were the only suitable starting materials for the synthesis of bidiaziridines. Neither the diketones, nor the iminoketone derivatives proved to serve as appropriate starting materials. keywords: 1,2-diketon, 1,2-diimines, bidiaziridin, bidiazirin, strained cycloalkynes, Norbornyne, trapping agents, cycloaddition
Bibliographische Beschreibung und Referat Al-Omari, Mohammad Synthesis of Alkynes from Bi-3H-diazirin-3-yls: Trapping of Strained Cycloalkynes Technische Universität Chemnitz, Fakultät für Naturwissenschaften Dissertation 2003, 76 Seiten. In der vorliegenden Arbeit wird eine neue Methode zur Synthese von Alkinen beschrieben. Ausgehend von acyclischen, mono- und bicyclischen 1,2-difunktionalisierten Vorläufern wurden Bidiazirine synthetisiert und deren Eignung als Precursoren für Alkine untersucht. Dabei musste festgestellt werden, dass sich weder von 1,2-Diketonen noch von Iminoketonen die als Zwischenprodukte benötigten Bidiaziridine direkt darstellen ließen. Der einzige erfolgreiche Syntheseweg führte über die 1,2-Diimine zu Diastereomeren-Gemischen der gewünschten Bidiaziridine. Die Oxidation der Bidiaziridine lieferte die Bidiazirine, welche als Vorstufen für die Synthese von Alkinen dienten. So konnten auf diesem Wege sowohl spannungsfreie lineare Alkine wie 2-Butin als auch extrem gespannte Cycloalkine wie Cyclohexin oder Norbornin synthetisiert werden. Der spektroskopische Nachweis der Alkine erfolgte dabei direkt bzw. über verschiedene Abfangprodukte. Stichworte: 1,2-Diketon, 1,2-Diimine, Bidiaziridin, Bidiazirin, gespannte Cycloalkine, Norbornin, Abfangreagentien, Cycloaddition

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Pastore, Heloise de Oliveira 1962. « Reatividade de diazirinas e diaziridinas com compostos de paladio (II) em solventes proticos e aproticos ». [s.n.], 1987. http://repositorio.unicamp.br/jspui/handle/REPOSIP/249088.

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Orientador : Pedro Faria dos Santos Filho
Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Quimica
Made available in DSpace on 2018-07-15T00:22:42Z (GMT). No. of bitstreams: 1 Pastore_HeloisedeOliveira_M.pdf: 4360939 bytes, checksum: 4b2a06a447bd997ebe69a323312947f0 (MD5) Previous issue date: 1987
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Zhang, Yunlong. « Ultrafast Time Resolved and Computational Studies of Diazo and Diazirine Excited States, and of Carbenes ». The Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1267479070.

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Blencowe, Anton. « The development of polymerisation and surface modification techniques using diazirines as carbene precursors ». Thesis, University of Reading, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433454.

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Livres sur le sujet "Diazirina"

H, Liu Michael T., dir. Chemistry of diazirines. Boca Raton, Fla : CRC Press, 1987.

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H, Liu Michael T., dir. Chemistry of diazirines. Boca Raton, Fla : CRC Press, 1987.

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Chapitres de livres sur le sujet "Diazirina"

Frey, H. M. « The Photolysis of the Diazirines ». Dans Advances in Photochemistry, 225–56. Hoboken, NJ, USA : John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470133347.ch8.

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Heine, Harold W. « Diaziridines, 3H-Diazirines, Diaziridinones, and Diaziridinimines ». Dans Chemistry of Heterocyclic Compounds : A Series Of Monographs, 547–628. Hoboken, NJ, USA : John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470187197.ch4.

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Murai, Yuta, Lei Wang et Makoto Hashimoto. « Synthesis of Diazirinyl Photophore and Optically Pure Diazirinylphenylalanines for Photoaffinity Labeling ». Dans Photoaffinity Labeling for Structural Probing Within Protein, 111–28. Tokyo : Springer Japan, 2017. http://dx.doi.org/10.1007/978-4-431-56569-7_6.

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Rochefort, A., P. H. McBreen et D. R. Salahub. « Molecular Adsorption of Diazirine on Palladium (110) Cluster Models Using the LCGTO-MCP-LSD Method ». Dans Metal-Ligand Interactions, 437–51. Dordrecht : Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0155-1_15.

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Krueger, A. « Diazirine Rearrangement ». Dans Polyynes, Arynes, Enynes, and Alkynes, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-043-00454.

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« d) 3H-Diazirine ». Dans Organische Stickstoffverbindungen III, sous la direction de Dieter Klamann. Stuttgart : Georg Thieme Verlag, 1992. http://dx.doi.org/10.1055/b-0035-116121.

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DeRosa, Thomas F. « Aziridines/Diazirines ». Dans Advances in Synthetic Organic Chemistry and Methods Reported in US Patents, 170–77. Elsevier, 2006. http://dx.doi.org/10.1016/b978-008044474-1/50017-7.

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Hashimoto, Makoto. « Diaziridines and Diazirines ». Dans Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2019. http://dx.doi.org/10.1016/b978-0-12-409547-2.14763-8.

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McAllister, G. D., A. Perry et R. J. K. Taylor. « Diaziridines and Diazirines ». Dans Comprehensive Heterocyclic Chemistry III, 539–57. Elsevier, 2008. http://dx.doi.org/10.1016/b978-008044992-0.00111-5.

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Kostyanovsky, Remir G., Ramiah Murugan et Murugan Sutharchanadevi. « Diaziridines and Diazirines ». Dans Comprehensive Heterocyclic Chemistry II, 347–64. Elsevier, 1996. http://dx.doi.org/10.1016/b978-008096518-5.00011-3.

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Actes de conférences sur le sujet "Diazirina"

Chee, Gaik-Lean, Jack Yalowich et Brian B. Hasinoff. « Abstract 3508 : A diazirine-based photoaffinity etoposide probe for labeling topoisomerase II ». Dans Proceedings : AACR 101st Annual Meeting 2010‐‐ Apr 17‐21, 2010 ; Washington, DC. American Association for Cancer Research, 2010. http://dx.doi.org/10.1158/1538-7445.am10-3508.

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Sohrabi, B. « The theoretical study of the various substitutions effect in the conversion of 3- cyclopropylmethoxy-3-chloro diazirine to various products ». Dans The 13th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland : MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00241.

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Sohrabi, B. « The investigation of transition state in the conversion of 3-cyclopropylmethoxy-3- chloro diazirine to various products by ab initio method ». Dans The 13th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland : MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00238.

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