Bibliographies thématiques / Decomposition of metal trifluoroacetates

Littérature scientifique sur le sujet « Decomposition of metal trifluoroacetates »

Auteur : Grafiati
Publié le 18 mai 2024

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Articles de revues sur le sujet "Decomposition of metal trifluoroacetates"

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R�ssel, C. « Preparation of LiF, CaF2 and YF3 by thermal decomposition of the metal trifluoroacetates ». Journal of Materials Science Letters 11, no 3 (1992) : 152–54. http://dx.doi.org/10.1007/bf00724675.

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Rüssel, Christian. « A pyrolytic route to fluoride glasses. I. Preparation and thermal decomposition of metal trifluoroacetates ». Journal of Non-Crystalline Solids 152, no 2-3 (février 1993) : 161–66. http://dx.doi.org/10.1016/0022-3093(93)90246-t.

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CHEN, S., Z. HAN, Q. LIU, S. S. WANG, Z. Y. SUN, K. SHI et H. P. YI. « EPITAXIAL GROWTH OF SrTiO3 THIN FILMS BY SOL-GEL SYNTHESIS ON LaAlO3 AND Ni SUBSTRATES ». International Journal of Modern Physics B 19, no 01n03 (30 janvier 2005) : 379–81. http://dx.doi.org/10.1142/s0217979205028608.

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A solution process was used to grow SrTiO 3 ( STO ) buffer layers on LaAlO 3 ( LAO ) and biaxially textured Ni substrates by spin coating technique. The epitaxial STO film obtained has strong cube texture and uniform microstructure. A metal organic decomposition process using trifluoroacetate precursors was applied to deposit YBa 2 Cu 3 O 7-δ ( YBCO ) thin films on these buffer layers. The YBCO / STO / LAO was biaxially textured and the T Conset and Δ T C is 90.1K and 2.7K, respectively.
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Berberich, F., H. Graafsma, B. Rousseau, A. Canizares, R. Ramy Ratiarison, N. Raimboux, P. Simon et al. « Combined synchrotron x-ray diffraction and micro-Raman for following in situ the growth of solution-deposited YBa2Cu3O7 thin films ». Journal of Materials Research 20, no 12 (1 décembre 2005) : 3270–73. http://dx.doi.org/10.1557/jmr.2005.0421.

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A unique combination of in situ synchrotron x-ray diffraction and in situ micro-Raman spectroscopy was used to study the growth process of YBa2Cu3O6+x films obtained by metal organic decomposition using trifluoroacetate precursor on LaAlO3 substrates. The techniques give complementary information: x-ray diffraction gives insight into the structural growth, whereas micro-Raman spectroscopy gives information of the chemical composition with additional information on the texture. To perform both experiments in situ, a special high-temperature process chamber was designed.
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Llordés, A., K. Zalamova, S. Ricart, A. Palau, A. Pomar, T. Puig, A. Hardy, M. K. Van Bael et X. Obradors. « Evolution of Metal-Trifluoroacetate Precursors in the Thermal Decomposition toward High-Performance YBa2Cu3O7Superconducting Films ». Chemistry of Materials 22, no 5 (9 mars 2010) : 1686–94. http://dx.doi.org/10.1021/cm903080k.

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Tissot, P., H. Lartigue et B. Perrenot. « Thermal decomposition of trifluoroacetates ». Thermochimica Acta 106 (septembre 1986) : 377–78. http://dx.doi.org/10.1016/0040-6031(86)85150-4.

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Logvinenko, V., T. Chingina, N. Sokolova et P. Semyannikov. « Thermal decomposition processes of lanthanide trifluoroacetates trihydrates ». Journal of Thermal Analysis and Calorimetry 74, no 2 (2003) : 401–5. http://dx.doi.org/10.1023/b:jtan.0000005174.86599.cc.

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Bogdanov, Viktor P., Veronika A. Dmitrieva, Vitaliy A. Ioutsi, Nikita M. Belov et Alexey A. Goryunkov. « Alkali metal trifluoroacetates for the nucleophilic trifluoromethylation of fullerenes ». Journal of Fluorine Chemistry 226 (octobre 2019) : 109344. http://dx.doi.org/10.1016/j.jfluchem.2019.109344.

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Glazunova, T. Yu, A. I. Boltalin et P. P. Fedorov. « Synthesis of calcium, strontium, and barium fluorides by thermal decomposition of trifluoroacetates ». Russian Journal of Inorganic Chemistry 51, no 7 (juillet 2006) : 983–87. http://dx.doi.org/10.1134/s0036023606070011.

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Tokareva, A. O., D. S. Tereschenko, A. I. Boltalin et S. I. Troyanov. « Crystal structure and synthesis of new trinuclear 3d-metal trifluoroacetates ». Acta Crystallographica Section A Foundations of Crystallography 61, a1 (23 août 2005) : c332—c333. http://dx.doi.org/10.1107/s0108767305085843.

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Thèses sur le sujet "Decomposition of metal trifluoroacetates"

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Stillman, T. J. « A crystallographic investigation into the structure of the metal - trifluoroacetates ». Thesis, Lancaster University, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383545.

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Sykes, Martin Lewis. « Metal carbonyl decomposition and carbon decomposition in the A.G.R ». Thesis, University of Newcastle Upon Tyne, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315635.

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Coetzee, Anita. « Thermal decomposition of mixed metal oxalates ». Thesis, Rhodes University, 1993. http://hdl.handle.net/10962/d1005053.

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The mixed metal oxalates, FeCu(ox)₂.3H₂0, CoCu(ox)₂.3H₂0, and NiCu(ox)₂.3.5H₂0, [ox = C₂0₄] have been prepared by coprecipitation from solution. The thermal behaviour of these compounds in nitrogen and in oxygen has been examined using thermogravimetry (TG), thermomagnetometry (TM), differential scanning calorimetry (DSC) and evolved gas analysis (EGA), and results are compared with results obtained for Cuox and Mox.yH₂0. The thermal behaviour of the mixed oxalates, MCU(OX)₂.xH₂0, differed from that of the individual metal oxalates, Cuox, Coox.2H₂0, Niox.2H₂0 and Feox.2H₂0. All three mixed oxalates on heating in N₂, first dehydrate and then decompose in at least two overlapping endothermic stages. Both CO and CO₂ were evolved in proportions which varied with the surrounding atmosphere, and from compound to compound, and with extent of reaction of a given compound. The mixed oxalates, MCU(OX)₂.xH₂0, do not show the exothermic behaviour characteristic of Cuox, and reasons for this are discussed. Thermochemical calculations were done and the enthalpies of formation of the hydrates and dehydrated oxalates were determined. It was found that the enthalpy of mixing was very small or within experimental error. X-ray powder diffraction patterns for the individual and mixed oxalates were compared. The pattern for Cuox differs from the patterns obtained for the other oxalates, confirming suggestions that Cuox has a structure different to most other transition metal oxalates. The kinetics of dehydration and decomposition of the mixed oxalates were investigated, using isothermal and programmed temperature TG and DSC experiments. The yield and composition of evolved gases during isothermal decomposition were measured and compared with the enthalpy changes. X-ray photoelectron spectroscopy studies provided some information on the electron environment of the metal atoms in the various oxalates.
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Waechtler, Thomas, Yingzhong Shen, Alexander Jakob, Ramona Ecke, Stefan E. Schulz, Lars Wittenbecher, Hans-Josef Sterzel et al. « Evaluation of Phosphite and Phosphane Stabilized Copper(I) Trifluoroacetates as Precursors for the Metal-Organic Chemical Vapor Deposition of Copper ». Universitätsbibliothek Chemnitz, 2006. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200600315.

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Copper has become the material of choice for metallization of high-performance ultra-large scale integrated circuits. As the feature size is continuously decreasing, metal-organic chemical vapor deposition (MOCVD) appears promising for depositing the Cu seed layer required for electroplating, as well as for filling entire interconnect structures. In this work, four novel organophosphane and organophosphite Cu(I) trifluoroacetates were studied as precursors for Cu MOCVD. Details are reported on CVD results obtained with Tris(tri-n-butylphosphane)copper(I)trifluoroacetate, (nBu3P)3CuO2CCF3. Solutions of this precursor with acetonitrile and isopropanol were used for deposition experiments on 100 mm Si wafers sputter-coated with Cu, Cu/TiN, and Al(2 % Si)/W. Experiments were carried out in a cold-wall reactor at a pressure of 0.7 mbar, using a liquid delivery approach for precursor dosage. On Cu seed layers, continuous films were obtained at low deposition rates (0.5 to 1 nm/min). At temperatures above 320°C, hole formation in the Cu films was observed. Deposition on TiN led to the formation of single copper particles and etching of the TiN, whereas isolating aluminum oxyfluoride was formed after deposition on Al(Si)/W. It is concluded that the formation of CF3 radicals during decarboxylation has a negative effect on the deposition results. Furthermore, the precursor chemistry needs to be improved for a higher volatility of the complex.
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Bocelli, Ludovica. « Catalytic decomposition of formic acid using supported metal nanoparticles ». Master's thesis, Alma Mater Studiorum - Università di Bologna, 2016. http://amslaurea.unibo.it/11929/.

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Upgrade of hydrogen to valuable fuel is a central topic in modern research due to its high availability and low price. For the difficulties in hydrogen storage, different pathways are still under investigation. A promising way is in the liquid-phase chemical hydrogen storage materials, because they can lead to greener transformation processes with the on line development of hydrogen for fuel cells. The aim of my work was the optimization of catalysts for the decomposition of formic acid made by sol immobilisation method (a typical colloidal method). Formic acid was selected because of the following features: it is a versatile renewable reagent for green synthesis studies. The first aim of my research was the synthesis and optimisation of Pd nanoparticles by sol-immobilisation to achieve better catalytic performances and investigate the effect of particle size, oxidation state, role of stabiliser and nature of the support. Palladium was chosen because it is a well-known active metal for the catalytic decomposition of formic acid. Noble metal nanoparticles of palladium were immobilized on carbon charcoal and on titania. In the second part the catalytic performance of the “homemade” catalyst Pd/C to a commercial Pd/C and the effect of different monometallic and bimetallic systems (AuxPdy) in the catalytic formic acid decomposition was investigated. The training period for the production of this work was carried out at the University of Cardiff (Group of Dr. N. Dimitratos).
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Makepeace, Joshua William. « Light metal amides for hydrogen storage and ammonia decomposition ». Thesis, University of Oxford, 2014. https://ora.ox.ac.uk/objects/uuid:baf23b20-eab8-4baa-98a8-e0084bd85e39.

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Hydrogen has long been touted as an alternative fuel which could form the basis of a sustainable energy system: the hydrogen economy. This thesis advances the application of light metal amide materials in the realisation of this transformative potential. One of the most vexing technical challenges to the widespread adoption of hydrogen in transportation applications is its low volumetric energy density, which makes the storage of a sufficient amount of hydrogen in a vehicle very difficult. In their conventional application, light metal amides (M(NH2)x),where M is a Group I or II metal) have been promoted as a means of storing large quantities hydrogen in the solid state, significantly increasing this energy density. This thesis highlights the impressive characteristics of amide-based materials, primarily the facile nature of the reversibility of the hydrogen storage reaction, as a model for the development and optimisation of solid-state hydrogen stores. The study of the relationship between the crystal structures of the relevant materials and their hydrogen storage properties through in situ X-ray and neutron powder diffraction measurements is reported for the lithium amide - lithium hydride (Li-N-H) hydrogen store. These investigations provide strong evidence for ionic mobility as the basis of reversible hydrogen storage in the Li-N-H system. The hydrogen storage and release reactions are seen to progress through a continuum of non-stoichiometric states, a transformation which is facilitated by its topotactic nature. The structural and energetic properties of these non-stoichiometric phases are reported, showing that they are intrinsically disordered and thermodynamically unstable relative to their parent structures. The study of the behaviour of the Li-N-H system is extended to many tens of hydrogenation-dehydrogenation cycles to examine practical performance, confirming the mechanism of capacity loss through the formation of parasitic lithium hydride, and showing that the addition of nitrogen improves the cycling lifetime of the system. An unexplored aspect of light metal amide chemistry is also presented, where the hydrogen storage and release reactions of sodium amide are performed simultaneously. Together, these reactions effect the chemical decomposition of ammonia. Ammonia is a high energy density liquid hydrogen carrier which has been largely overlooked, partly due to the difficulty extracting its stored hydrogen. This work demonstrates a new method of ammonia decomposition which gives comparable performance to the expensive rare-metal catalysts which are currently used for the productions of high-purity hydrogen. A survey of the ammonia decomposition efficiency of a number of light metal amides and imides is presented, showing that it is not only amides which decompose into their constituent elements (such as sodium amide) which are active in ammonia decomposition, but also imide-forming amides. Indeed, imides and imide-forming amides are shown to be advantageous from the perspective of containing the catalyst material. Neutron diffraction and isotope exchange measurements provide some initial insights into the mechanism of reaction, identifying clear avenues for development of these systems, and inviting further discussion of the potential of ammonia as a sustainable energy vector.
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Saunders, Andrew J. « Metal sulphur complexes and systematic investigation of their thermal decomposition ». Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432568.

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Tesfai, Teweldemedhim M. « Adsorption and decomposition of organophosphorus compounds on alumina supported metal oxides ». DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1998. http://digitalcommons.auctr.edu/dissertations/1540.

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Diffuse reflectance infrared spectroscopy techniques have been employed to investigate the interaction and decomposition of DMMP alumina supported iron oxide catalysts differing in iron oxide loading. At room temperature, the low loading iron oxide catalysts have shown no significant activity toward the decomposition ofDMMP, and they behave similarly to alumina. For the low loading iron oxide catalysts, all the methyl stretching vibrations were observed and their relative intensities did not change as a function of exposure to DMMP. On the other hand, DMMP adsorbs dissociatively on the high loading iron oxides, 8.5 wt%10 iron and above. It appears that the P-CH3 bond dissociates upon adsorption of DMMP on the high loading supported iron oxide catalysts at room temperature. DMMP on alumina supported copper catalyst, 4.04 wt"10 Cu, has been observed to adsorb on the metal oxide through the P=O bond to a Lewis acid site. On the surface, adsorbed DMMP has been observed to decompose with loss of both the methoxy methyl groups and the phosphorus-bound methyl groups between 100 and 200'C. All the methyl groups are decomposed above 300 'c and only phosphate complexes are observed on the surface.
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Stell, Jonathan Kendrew. « An E.S.R. study of the decomposition of peroxides by metal ions ». Thesis, University of York, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.276493.

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Zhang, Yanping. « Nitric oxide decomposition over metal ion-modified Cu-ZSM-5 catalysts ». Thesis, Massachusetts Institute of Technology, 1995. http://hdl.handle.net/1721.1/11260.

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Livres sur le sujet "Decomposition of metal trifluoroacetates"

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G, McDonald, et United States. National Aeronautics and Space Administration., dir. Metallic and metalloceramic coating by thermal decomposition. [Washington, DC?] : National Aeronautics and Space Administration, 1985.

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Hendricks, Robert C. Metallic and metalloceramic coating by thermal decomposition. [Washington, DC?] : National Aeronautics and Space Administration, 1985.

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Kuo, M. J. The decomposition of a series of metal oxalates. Salford : University of Salford, 1994.

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M, Di͡agileva L., et T͡Syganova E. I, dir. Termicheskoe razlozhenie organicheskikh proizvodnykh perekhodnykh metallov. Moskva : Nauka, 1993.

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L, Paciorek Kazimiera J., et United States. National Aeronautics and Space Administration., dir. Effect of metal alloys, degradation inhibitors, temperatures on thermal oxidative stability of CF₃O(CF₂O)[sub x](CF₂CF₂O)[sub y]CF₃ fluids. [Washington, DC : National Aeronautics and Space Administration, 1997.

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Gabis, Igor E., et Ilia A. Chernov. Kinetics of Binary Metal Hydride Decomposition. Nova Science Publishers, Incorporated, 2017.

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Lagerman, Robert K. Metal ion induced decomposition of N-Aryl-O-pivaloylhydroxylamines in aqueous solution. 1989.

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Sanguanruang, Oravan. [Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition. 1988.

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Sanguanruang, Oravan. [Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition. 1988.

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Hu, Xuhui. The syntax and semantics of English resultatives. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198808466.003.0003.

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This chapter argues that the English resultative construction denotes a single event involving two predicates. Therefore, only a single EP is involved in the syntactic derivation. The special thematic relationship is due to constraints imposed by the Integration Conditions proposed in Chapter 2. Dispensing with the CAUSE head of the event decomposition approach, this chapter explains the possible lack of causative meaning in English resultatives. A secondary predicate in a resultative can get a dynamic BECOME meaning (such as flat in John hammered the metal flat) because the secondary predicate shares the dynamic [iDiv] feature provided by V. Since both the activity denoted by the matrix V and the dynamic change of state take place in the same temporal scope of EP, the interpretation of a potential (and cancellable) culmination point is derived.
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Chapitres de livres sur le sujet "Decomposition of metal trifluoroacetates"

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Grushin, Vladimir V., David L. Thorn, William J. Marshall et Viacheslav A. Petrov. « New Applications of Electrophilic Aromatic C—H Activation with Metal Trifluoroacetates ». Dans ACS Symposium Series, 393–406. Washington, DC : American Chemical Society, 2004. http://dx.doi.org/10.1021/bk-2004-0885.ch024.

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Kreisle, D., K. Leiter, O. Echt et T. D. Märk. « Decomposition Channels for Multiply Charged Ammonia Clusters ». Dans Metal Clusters, 219–22. Berlin, Heidelberg : Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-642-71571-6_30.

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Cavell, Kingsley J., et Adrien T. Normand. « N-Heterocyclic Carbene Complexes : Decomposition Pathways ». Dans Catalysis by Metal Complexes, 299–314. Dordrecht : Springer Netherlands, 2010. http://dx.doi.org/10.1007/978-90-481-2866-2_13.

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Begemann, W., S. Dreihöfer, K. H. Meiwes-Broer et H. O. Lutz. « Sputtered Metal Cluster Ions : Unimolecular Decomposition and Collision Induced Fragmentation ». Dans Metal Clusters, 83–88. Berlin, Heidelberg : Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-642-71571-6_13.

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Hildenbrand, D. L., K. H. Lau et R. D. Brittain. « Mechanistic Aspects of Metal Sulfate Decomposition Processes ». Dans Materials Chemistry at High Temperatures, 427–40. Totowa, NJ : Humana Press, 1990. http://dx.doi.org/10.1007/978-1-4612-0481-7_32.

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Küppers, J. « Molecular Bonding and Decomposition at Metal Surfaces ». Dans Lectures on Surface Science, 203–14. Berlin, Heidelberg : Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71723-9_34.

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Zope, Indraneel Suhas. « Decomposition Behavior of Metal-Ion Exchanged Clays ». Dans Fire Retardancy Behavior of Polymer/Clay Nanocomposites, 61–82. Singapore : Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-10-8327-3_4.

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Pinzón, M., A. Sánchez-Sánchez, P. Sánchez, A. R. de la Osa et A. Romero. « Perovskites as Catalyst Precursor for Hydrogen Production from Ammonia Decomposition ». Dans Metal-Halide Perovskite Semiconductors, 221–38. Cham : Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-26892-2_11.

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Dem’janenko, V. N., E. V. Murav’ev, Yu M. Gorislavets, I. V. Kazachkov, A. F. Kolesnichenko, N. V. Lysak et V. O. Vodjanjuk. « Controlled Decomposition of Liquid Metal Jets and Films in Technological and Power Devices ». Dans Liquid Metal Magnetohydrodynamics, 293–98. Dordrecht : Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0999-1_36.

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Alexeeva, O. K. « Hydrogen Production from Thermocatalytic Hydrogen Sulfide Decomposition ». Dans Hydrogen Materials Science and Chemistry of Metal Hydrides, 49–60. Dordrecht : Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0558-6_6.

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Actes de conférences sur le sujet "Decomposition of metal trifluoroacetates"

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SNIEGOŇ, Michal, Markéta TKADLEČKOVÁ, Josef WALEK, Jiří CUPEK, Tomasz MERDER et Lucie CHUDOBOVÁ. « DETERMINATION OF AUSTENITE DECOMPOSITION TEMPERATURES USING THERMODYNAMIC SW FACTSAGE ». Dans METAL 2022. TANGER Ltd., 2022. http://dx.doi.org/10.37904/metal.2022.4450.

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Wang, Cheng-Hua, et David A. Bourne. « Concurrent Decomposition for Sheet-Metal Products ». Dans ASME 1997 Design Engineering Technical Conferences. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/detc97/dfm-4328.

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Abstract During the product development stage, designers often face the task of partitioning a product into functioning parts. Unfortunately, most decomposition decisions are made based on product functionality while the product manufacturability is usually ignored. As a result, the resulting parts can be too expensive to manufacture or sometimes impossible to make. In this paper, we present a systematic approach to help designers decompose sheet-metal products. This approach is primarily driven by product manufacturability. It takes into account the manufacturability of sheet metal cutting, bending and assembly processes, while trying to minimize the number of parts. To overcome the combinatorial nature of the decomposition problem, a develop-first-decompose-later strategy is used. The decomposition goes back and forth between the design and decomposition modules to achieve sub-optimal results. The decomposition results are sent to the corresponding process planners and a complete production plan is produced. A prototype system has been developed to demonstrate the proposed approach. Several decomposition examples are also presented.
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Lian, H. L., Q. Shen, Y. J. Fan, L. M. Wu et Z. X. Sun. « Thermal Decomposition Mechanism of Metal Xanthate to Metal Sulfide Nanoparticles in Ammonia Solution ». Dans The International Workshop on Materials, Chemistry and Engineering. SCITEPRESS - Science and Technology Publications, 2018. http://dx.doi.org/10.5220/0007437402680275.

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Fang, Shao-Yun, Yi-Shu Tai et Yao-Wen Chang. « Layout decomposition for Spacer-is-Metal (SIM) self-aligned double patterning ». Dans 2015 20th Asia and South Pacific Design Automation Conference (ASP-DAC). IEEE, 2015. http://dx.doi.org/10.1109/aspdac.2015.7059085.

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Oommen, Charlie, A. Apitha, B. Raghunandan et Ang Ghee. « Sonicated Metal Oxide-Ammonium Perchlorate Mixtures with Modified Thermal Decomposition Characterisitcs ». Dans 39th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit. Reston, Virigina : American Institute of Aeronautics and Astronautics, 2003. http://dx.doi.org/10.2514/6.2003-4631.

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Son, L. N., T. Tachiki et T. Uchida. « Electrical properties of VOx bolometer thin films prepared by metal-organic decomposition ». Dans 2010 35th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz 2010). IEEE, 2010. http://dx.doi.org/10.1109/icimw.2010.5612822.

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Squire, D. W., C. S. Dulcey et M. C. Lin. « Multiphoton ionization mass spectrometric studies of methyl metal decomposition on heated substrates ». Dans OSA Annual Meeting. Washington, D.C. : Optica Publishing Group, 1985. http://dx.doi.org/10.1364/oam.1985.thm9.

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Multiphoton ionization mass spectrometry (MPI/MS) is used as a probe for methyl radical in the pyrolysis of methyl metals (trimethylaluminum, TMA; trimethylgallium, TMG), important molecules in chemical vapor deposition of semiconductors. In TMA pyrolysis, methyl radical is produced with an activation energy of 13 kcal/mole despite an aluminum–carbon bond strength of ~60 kcal/mole. No ethane or methane formation can be seen from any substrate. The proposed mechanism for the pyrolysis is that formation of a bond between aluminum and the electron donating surface catalyzes the cleavage of the aluminum–carbon bond, hence methyl production. On a nonconducting surface (unable to bond to aluminum), the deposition (pyrolysis) proceeds by uncatalyzed thermal cleavage until sufficient metal is deposited to permit the rapid (low activation energy) rate. The methane and ethane seen in commercial deposition reactors are then the products of secondary gas phase reactions and not surface products. The pyrolysis of TMG shows similar results. Implications for chemical vapor deposition are discussed.
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Saito, Hina, Yoshito Ashizawa et Katsuji Nakagawa. « Garnet Films Fabricated by Metal Organic Decomposition Method on Glass Substrates and GD3GA5O12Substrates ». Dans 2016 International Conference of Asian Union of Magnetics Societies (ICAUMS). IEEE, 2016. http://dx.doi.org/10.1109/icaums.2016.8480020.

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Tong, Li, Ying Zeng, Shanglian Bao, Bin Yan et Linyuan Wang. « Multi-scale decomposition model-based segmentation algorithm for CT image with metal artifacts ». Dans 2013 IEEE International Conference on Medical Imaging Physics and Engineering (ICMIPE). IEEE, 2013. http://dx.doi.org/10.1109/icmipe.2013.6864507.

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Kunz, R. R., et T. M. Mayer. « Electron beam induced surface nucleation and low temperature thermal decomposition of metal carbonyls ». Dans AIP Conference Proceedings Vol. 167. AIP, 1988. http://dx.doi.org/10.1063/1.37155.

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Rapports d'organisations sur le sujet "Decomposition of metal trifluoroacetates"

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WALTERS, R. A General Initial Decomposition Reaction for Complex Metal Hydrides. Office of Scientific and Technical Information (OSTI), novembre 2004. http://dx.doi.org/10.2172/836748.

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S.E. Ziemniak. Metal Oxide Decomposition In Hydrothermal Alkaline Sodium Phosphate Solutions. Office of Scientific and Technical Information (OSTI), septembre 2003. http://dx.doi.org/10.2172/822273.

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Peterson, R. A. Results of Experimental Investigation into Noble Metal Catalyzed Decomposition of Sodium Tetraphenylborate. Office of Scientific and Technical Information (OSTI), octobre 2000. http://dx.doi.org/10.2172/765050.

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Morris, John R. Adsorption and Decomposition of CWA Simulants on Single Crystal and Nanostructured Metal Oxides. Fort Belvoir, VA : Defense Technical Information Center, janvier 2009. http://dx.doi.org/10.21236/ada517975.

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Weinberg, W. H. (The activation and decomposition of alkanes on group VIII transition metal surfaces : Dynamics, kinetics and spectroscopy). Office of Scientific and Technical Information (OSTI), janvier 1990. http://dx.doi.org/10.2172/5730531.

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Weinberg, W. H. [The activation and decomposition of alkanes on group VIII transition metal surfaces : Dynamics, kinetics and spectroscopy]. Progress report. Office of Scientific and Technical Information (OSTI), décembre 1990. http://dx.doi.org/10.2172/10128607.

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