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Littérature scientifique sur le sujet « Chain Shuttling Polymerization »

Auteur : Grafiati

Publié le 9 mars 2023

Mis à jour le 31 juillet 2025

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Articles de revues sur le sujet "Chain Shuttling Polymerization"

Martins, Roberto, Letícia Quinello, Giuliana Souza, and Maria Marques. "Polymerization of Ethylene with Catalyst Mixture in the Presence of Chain Shuttling Agent." Chemistry & Chemical Technology 6, no. 2 (2012): 153–62. http://dx.doi.org/10.23939/chcht06.02.153.

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Zintl, Manuela, and Bernhard Rieger. "Novel Olefin Block Copolymers through Chain-Shuttling Polymerization." Angewandte Chemie International Edition 46, no. 3 (2007): 333–35. http://dx.doi.org/10.1002/anie.200602889.

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Kuhlman, Roger L., and Timothy T. Wenzel. "Investigations of Chain Shuttling Olefin Polymerization Using Deuterium Labeling." Macromolecules 41, no. 12 (2008): 4090–94. http://dx.doi.org/10.1021/ma8004313.

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Arriola, D. J. "Catalytic Production of Olefin Block Copolymers via Chain Shuttling Polymerization." Science 312, no. 5774 (2006): 714–19. http://dx.doi.org/10.1126/science.1125268.

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Mohammadi, Yousef, Mohammad Saeb, Alexander Penlidis, et al. "Intelligent Machine Learning: Tailor-Making Macromolecules." Polymers 11, no. 4 (2019): 579. http://dx.doi.org/10.3390/polym11040579.

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Nowadays, polymer reaction engineers seek robust and effective tools to synthesize complex macromolecules with well-defined and desirable microstructural and architectural characteristics. Over the past few decades, several promising approaches, such as controlled living (co)polymerization systems and chain-shuttling reactions have been proposed and widely applied to synthesize rather complex macromolecules with controlled monomer sequences. Despite the unique potential of the newly developed techniques, tailor-making the microstructure of macromolecules by suggesting the most appropriate poly

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Xu, Qinwen, Rong Gao, and Dongbing Liu. "Studies on chain shuttling polymerization reaction of nonbridged half-titanocene and bis(phenoxy-imine) Zr binary catalyst system." Royal Society Open Science 6, no. 4 (2019): 182007. http://dx.doi.org/10.1098/rsos.182007.

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In this contribution, olefin block copolymers were produced via chain shuttling polymerization (CSP), using a new combination of catalysts and a chain shuttling agent (CSA) diethylzinc (ZnEt 2 ). The binary catalyst system included nonbridged half-titanocene catalyst, Cp*TiCl 2 (O-2,6- i Pr 2 C 6 H 3 ) (Cat A ) and bis(phenoxy-imine) zirconium, { η 2 -1-[C(H)=NC 6 H 11 ]-2-O-3- t Bu-C 6 H 3 } 2 ZrCl 2 (Cat B ), as well as co-catalyst methylaluminoxane (MAO). In contrast to dual-catalyst system in the absence of CSA, the blocky structure was obtained in the presence of CSA and rationalized from

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Urciuoli, Gaia, Antonio Vittoria, Giovanni Talarico, et al. "In-Depth Analysis of the Nonuniform Chain Microstructure of Multiblock Copolymers from Chain-Shuttling Polymerization." Macromolecules 54, no. 23 (2021): 10891–902. http://dx.doi.org/10.1021/acs.macromol.1c01824.

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Zhu, Lei, Haojie Yu, Li Wang, Yusheng Xing, and Bilal Ul Amin. "Advances in the Synthesis of Polyolefin Elastomers with “Chain-walking” Catalysts and Electron Spin Resonance Research of Related Catalytic Systems." Current Organic Chemistry 25, no. 8 (2021): 935–49. http://dx.doi.org/10.2174/1385272825666210126100641.

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In recent years, polyolefin elastomers play an increasingly important role in industry. The late transition metal complex catalysts, especially α-diimine Ni(II) and α-diimine Pd(II) complex catalysts, are popular “chain-walking” catalysts. They can prepare polyolefin with various structures, ranging from linear configuration to highly branched configuration. Combining the “chain-walking” characteristic with different polymerization strategies, polyolefins with good elasticity can be obtained. Among them, olefin copolymer is a common way to produce polyolefin elastomers. For instance, strictly

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Zhao, Jieming, Zhou Tian, Xixiang Zhang, Zhaoyang Duan, and Jingyi Lu. "Kinetics Parameter Identification of Chain Shuttling Polymerization Based on Physics-Informed Neural Networks." IFAC-PapersOnLine 58, no. 14 (2024): 184–91. http://dx.doi.org/10.1016/j.ifacol.2024.08.334.

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Xiao, Anguo, Shibiao Zhou, and Qingquan Liu. "A Novel Branched–Hyperbranched Block Polyolefin Produced via Chain Shuttling Polymerization from Ethylene Alone." Polymer-Plastics Technology and Engineering 53, no. 17 (2014): 1832–37. http://dx.doi.org/10.1080/03602559.2014.935409.

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Plus de sources

Thèses sur le sujet "Chain Shuttling Polymerization"

SIDARI, DIEGO. "Cyclolefin copolymers via chain shuttling." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2015. http://hdl.handle.net/10281/77608.

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L’introduzione di co- e ter-monomeri nella catena di polietilene, ottenuta con catalizzatori Ziegler-Natta permette di modularne le proprietà fisiche e chimiche come la temperatura di transizione vetrosa (Tg) e di incrementare le proprietà meccaniche e termiche del materiale. In particolare, i copolimeri etilene-norbornene (E-N) ottenuti per sintesi metallocenica hanno alta resistenza termica, elevata resistenza all’azione di solventi, elevate proprietà barriera ai gas e alta trasparenza ottica (I. Tritto, L. Boggioni, D.R. Ferro, Coordination Chemistry Reviews, 250, 212-241, (2006)). Copolim

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