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Articles de revues sur le sujet « Active mater »

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Auteur : Grafiati
Publié le 18 mai 2024

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1

Ma, He, Yu Wang, Lu Rong, Fangrui Tan, Yulan Fu, Guang Wang, Dayong Wang et al. « Correction : A flexible, multifunctional, active terahertz modulator with an ultra-low triggering threshold ». Journal of Materials Chemistry C 8, no 30 (2020) : 10474. http://dx.doi.org/10.1039/d0tc90146f.

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Scaffaro, R., M. Morreale, G. Lo Re et F. P. La Mantia. « Degradation of Mater-Bi®/wood flour biocomposites in active sewage sludge ». Polymer Degradation and Stability 94, no 8 (août 2009) : 1220–29. http://dx.doi.org/10.1016/j.polymdegradstab.2009.04.028.

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Liu, Hanle, Shunhan Jia, Limin Wu, Lei He, Xiaofu Sun et Buxing Han. « Active hydrogen-controlled CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub> ; electroreduction:From mechanism understanding to catalyst design ». Innovation Materials 2, no 1 (2024) : 100058. http://dx.doi.org/10.59717/j.xinn-mater.2024.100058.

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<p>The development of renewable-energy-powered electrocatalysis meets the need for the sustainable society. With water as the proton source, it enables efficient production of chemicals and fuels from renewable resources like CO<sub>2</sub>, N<sub>2</sub>, and NO<sub>x</sub> under ambient conditions. Hydrogen generated via water dissociation is a crucial participant in transforming reactants into desired products, but it also serves as a direct source of undesired reactions when in excess. In this review, we first present an overview of the functional mechanisms of active hydrogen in the electroreduction of CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub>. We then introduce a range of methods to enhance our understanding of these mechanisms. Furthermore, a detailed discussion of design strategies aimed at regulating active hydrogen in the reduction of CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub> is provided. Finally, an outlook on the critical challenges remaining in this research area and promising opportunities for future research is considered.</p>
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Jian, Yukun, Stephan Handschuh-Wang, Jiawei Zhang, Wei Lu, Xuechang Zhou et Tao Chen. « Correction : Biomimetic anti-freezing polymeric hydrogels : keeping soft-wet materials active in cold environments ». Materials Horizons 7, no 12 (2020) : 3339. http://dx.doi.org/10.1039/d0mh90071k.

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Jethwa, Rajesh B., Angelina Castro-Trujillo, Julia Valentin, Lakshman V. Kilari, Fernando Solorio-Soto, Stefan Stadlbauer et Stefan A. Freunberger. « Organic Bulk Liquid Redox Active Materials for Redox Flow Batteries ». ECS Meeting Abstracts MA2023-02, no 4 (22 décembre 2023) : 534. http://dx.doi.org/10.1149/ma2023-024534mtgabs.

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Redox flow batteries (RFBs) are one potential solution to grid-level electrical energy storage (EES) benefiting from a decoupled power and capacity scaling.1–3 High durability, long-calendar life, high efficiency EES with a low cost and fast response time is needed1,4 for the transition from fossil fuels to renewable sources.3 However, the low energy density3,5,6 and high capital costs5,6 of current systems preclude wide-scale deployment of this technology. In recent years, several new RFB chemistries have been explored to address these concerns.1,2,7 However, a high solubility for a high volumetric energy density remains a troublesome target.1 It is, therefore, no surprise that one growing trend in this regard is the design of redox active liquids (RALs).8–13 RALs provide a means of dramatically increasing the volumetric energy density of RFBs through either miscibility with typical supporting electrolytes, or by acting as both solvent and electrolyte themselves.9,12 In this work, we investigate a series of RALs that offer a similar theoretical energy density to conventional intercalation materials. A combination of computational and experimental techniques was employed herein for both molecular design and explanation of the physio-chemical phenomena. The candidate compounds were initially screened via electrochemical techniques to identify their electrochemical reversibility and stability. Exploration of the bulk properties was then carried out before system-level characterisation was undertaken. In tandem, the electrochemical and chemical stability of the samples was also investigated through the typical routes (NMR, EPR, UV-Vis). These systems show much promise for organic, tuneable electrical energy storage. Cao, J., Tian, J., Xu, J. & Wang, Y. Organic Flow Batteries: Recent Progress and Perspectives. Energy and Fuels 34, 13384–13411 (2020). Ding, Y., Zhang, C., Zhang, L., Zhou, Y. & Yu, G. Molecular engineering of organic electroactive materials for redox flow batteries. Chem. Soc. Rev. 47, 69–103 (2018). Alotto, P., Guarnieri, M. & Moro, F. Redox flow batteries for the storage of renewable energy: A review. Renew. Sustain. Energy Rev. 29, 325–335 (2014). Weber, A. Z. et al. Redox flow batteries: A review. J. Appl. Electrochem. 41, 1137–1164 (2011). Potash, R. A., McKone, J. R., Conte, S. & Abruña, H. D. On the Benefits of a Symmetric Redox Flow Battery. J. Electrochem. Soc. 163, A338–A344 (2016). Wang, W. et al. Recent progress in redox flow battery research and development. Adv. Funct. Mater. 23, 970–986 (2013). Li, Z., Jiang, T., Ali, M., Wu, C. & Chen, W. Recent Progress in Organic Species for Redox Flow Batteries. Energy Storage Mater. 50, 105–138 (2022). Shimizu, A. et al. Liquid Quinones for Solvent-Free Redox Flow Batteries. Adv. Mater. 29, 1606592 (2017). Robertson, L., Udin, M. A., Shlrob, I. A., Moore, J. S. & Zhang, L. Liquid Redoxmers for Nonaqueous Redox Flow Batteries. ChemSusChem e202300043 (2023) doi:10.1002/cssc.202300043. Chen, N., Chen, D., Wu, J., Lai, Y. & Chen, D. Polyethylene glycol modified tetrathiafulvalene for high energy density non-aqueous catholyte of hybrid redox flow batteries. Chem. Eng. J. 462, 141996 (2023). Smith, L. O. & Crittenden, D. L. Acid‐Base Chemistry Provides a Simple and Cost‐Effective Route to New Redox‐Active Ionic Liquids. Chem. – An Asian J. 18, e202201296 (2023). Zhao, Y. et al. TEMPO allegro: liquid catholyte redoxmers for nonaqueous redox flow batteries. J. Mater. Chem. A 9, 16769–16775 (2021). Huang, J. et al. Liquid Catholyte Molecules for Nonaqueous Redox Flow Batteries. Adv. Energy Mater. 5, 1401782 (2015).
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Kawashima, Hirotsugu, Kohsuke Kawabata et Hiromasa Goto. « Correction : Intramolecular charge transfer (ICT) of a chiroptically active conjugated polymer showing green colour ». Journal of Materials Chemistry C 3, no 5 (2015) : 1142. http://dx.doi.org/10.1039/c5tc90019k.

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Shen, Xingchen, Yi Xia, Guiwen Wang, Fei Zhou, Vidvuds Ozolins, Xu Lu, Guoyu Wang et Xiaoyuan Zhou. « Correction : High thermoelectric performance in complex phosphides enabled by stereochemically active lone pair electrons ». Journal of Materials Chemistry A 7, no 3 (2019) : 1356. http://dx.doi.org/10.1039/c8ta90286k.

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Gensel, Julia, Tina Borke, Nicolas Pazos Pérez, Andreas Fery, Daria V. Andreeva, Eva Betthausen, Axel H. E. Müller, Helmuth Möhwald et Ekaterina V. Skorb. « Active Surfaces : Cavitation Engineered 3D Sponge Networks and Their Application in Active Surface Construction (Adv. Mater. 7/2012) ». Advanced Materials 24, no 7 (7 février 2012) : 984. http://dx.doi.org/10.1002/adma.201290030.

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Schubert, Jasmin S., Leila Kalantari, Andreas Lechner, Ariane Giesriegl, Sreejith P. Nandan, Pablo Ayala, Shun Kashiwaya et al. « Correction : Elucidating the formation and active state of Cu co-catalysts for photocatalytic hydrogen evolution ». Journal of Materials Chemistry A 9, no 41 (2021) : 23731. http://dx.doi.org/10.1039/d1ta90213j.

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Wu, Jung-Tsu, Hsiang-Ting Lin et Guey-Sheng Liou. « Correction : Synthesis and optical properties of redox-active triphenylamine-based derivatives with methoxy protecting groups ». Journal of Materials Chemistry C 7, no 14 (2019) : 4267. http://dx.doi.org/10.1039/c9tc90046b.

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Giacalone, Francesco, Vincenzo Campisciano, Carla Calabrese, Valeria La Parola, Leonarda F. Liotta, Carmela Aprile et Michelangelo Gruttadauria. « Correction : Supported C60-IL-PdNPs as extremely active nanocatalysts for C–C cross-coupling reactions ». Journal of Materials Chemistry A 5, no 15 (2017) : 7210. http://dx.doi.org/10.1039/c7ta90071f.

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Beech, Jason P., Kevin Keim, Bao Dang Ho, Carlotta Guiducci et Jonas O. Tegenfeldt. « Microfluidics : Active Posts in Deterministic Lateral Displacement Devices (Adv. Mater. Technol. 9/2019) ». Advanced Materials Technologies 4, no 9 (septembre 2019) : 1970048. http://dx.doi.org/10.1002/admt.201970048.

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Lee, Jong Hwa, Kang Min Kim, Woongsik Jang, Sunyong Ahn, Young Yun Kim, O. Ok Park et Dong Hwan Wang. « Correction : Vacuum-process-based dry transfer of active layer with solvent additive for efficient organic photovoltaic devices ». Journal of Materials Chemistry C 5, no 6 (2017) : 1552. http://dx.doi.org/10.1039/c7tc90017a.

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Correction for ‘Vacuum-process-based dry transfer of active layer with solvent additive for efficient organic photovoltaic devices’ by Jong Hwa Lee et al., J. Mater. Chem. C, 2017, DOI: 10.1039/c6tc04743b.
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Guo, Biao, Weilong Zhou, Mengchun Wu, Junjie Lv, Chengzhuo Yu, Fenghong Li et Zhonghan Hu. « Correction : Improving the efficiency of polymer solar cells via a treatment of methanol : water on the active layers ». Journal of Materials Chemistry A 4, no 32 (2016) : 12667. http://dx.doi.org/10.1039/c6ta90124g.

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Han, Seung Ju, Sun-Mi Hwang, Hae-Gu Park, Chundong Zhang, Ki-Won Jun et Seok Ki Kim. « Correction : Identification of active sites for CO2 hydrogenation in Fe catalysts by first-principles microkinetic modelling ». Journal of Materials Chemistry A 8, no 35 (2020) : 18385. http://dx.doi.org/10.1039/d0ta90197k.

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Correction for ‘Identification of active sites for CO2 hydrogenation in Fe catalysts by first-principles microkinetic modelling’ by Seung Ju Han et al., J. Mater. Chem. A, 2020, 8, 13014–13023, DOI: 10.1039/D0TA01634A.
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Thakur, Pallavi, Jamsad Mannuthodikayil, Golap Kalita, Kalyaneswar Mandal et Tharangattu N. Narayanan. « Correction : In situ surface modification of bulk or nano materials by cytochrome-c for active hydrogen evolution catalysis ». Materials Chemistry Frontiers 5, no 5 (2021) : 2470. http://dx.doi.org/10.1039/d1qm90017j.

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Correction for ‘In situ surface modification of bulk or nano materials by cytochrome-c for active hydrogen evolution catalysis’ by Pallavi Thakur et al., Mater. Chem. Front., 2021, 5, 1295–1300, DOI: 10.1039/D0QM00627K.
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Sun, Yifei, Jianhui Li, Yimin Zeng, Babak Shalchi Amirkhiz, Mengni Wang, Yashar Behnamian et Jingli Luo. « Correction : A-site deficient perovskite : the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes ». Journal of Materials Chemistry A 5, no 2 (2017) : 852–53. http://dx.doi.org/10.1039/c6ta90256a.

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Correction for ‘A-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes’ by Yifei Sun et al., J. Mater. Chem. A, 2015, 3, 11048–11056.
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Pratap Singh, Piyush, Vikash Kumar, Eshan Tiwari et Vinay K. Chauhan. « Hybrid synchronisation of vallis chaotic systems using nonlinear active control ». International Journal of Engineering & ; Technology 7, no 2.21 (20 avril 2018) : 50. http://dx.doi.org/10.14419/ijet.v7i2.21.11834.

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In this paper, hybrid synchronisation of Vallis chaotic systems using a nonlinear control technique is proposed. Vallis system represents the principal quantitative features of the El-Nino Southern Oscillation (ENSO) phenomenon. A nonlinear active control technique is used for hybrid synchronisation. Control laws are designed by using the sum of the relevant variables of the both mater and slave systems. Required Lyapunov stability condition is devised using Lyapunov stability theory. Numerical simulation results reflect the successful achievement of the proposed objectives. MATLAB is used for simulation.
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Ni, Xing-Xing, Jian-Hua Li et Lu-Ping Yu. « Correction : A novel PVDF hybrid membrane with excellent active–passive integrated antifouling and antibacterial properties based on a PDA guiding effect ». Materials Advances 3, no 6 (2022) : 2945. http://dx.doi.org/10.1039/d2ma90025d.

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Correction for ‘A novel PVDF hybrid membrane with excellent active–passive integrated antifouling and antibacterial properties based on a PDA guiding effect’ by Xing-Xing Ni et al., Mater. Adv., 2021, 2, 3300–3314, DOI: 10.1039/D1MA00058F.
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Lee, Hye Soo, Ju Hyeon Kim, Joon-Seok Lee, Jae Young Sim, Jung Yoon Seo, You-Kwan Oh, Seung-Man Yang et Shin-Hyun Kim. « Photonic Crystals : Magnetoresponsive Discoidal Photonic Crystals Toward Active Color Pigments (Adv. Mater. 33/2014) ». Advanced Materials 26, no 33 (septembre 2014) : 5734. http://dx.doi.org/10.1002/adma.201470224.

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Bai, Feng, Binsong Li, Kaifu Bian, Raid Haddad, Huimeng Wu, Zhongwu Wang et Hongyou Fan. « Nanocrystals : Pressure-Tuned Structure and Property of Optically Active Nanocrystals (Adv. Mater. 10/2016) ». Advanced Materials 28, no 10 (mars 2016) : 1988. http://dx.doi.org/10.1002/adma.201670067.

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Huang, Tao, Vyacheslav R. Misko, Sophie Gobeil, Xu Wang, Franco Nori, Julian Schütt, Jürgen Fassbender, Gianaurelio Cuniberti, Denys Makarov et Larysa Baraban. « Janus Particles : Inverse Solidification Induced by Active Janus Particles (Adv. Funct. Mater. 39/2020) ». Advanced Functional Materials 30, no 39 (septembre 2020) : 2070260. http://dx.doi.org/10.1002/adfm.202070260.

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Lin, Yu-Che, Chung-Hao Chen, Nian-Zu She, Chien-Yao Juan, Bin Chang, Meng-Hua Li, Hao-Cheng Wang et al. « Correction : Twisted-graphene-like perylene diimide with dangling functional chromophores as tunable small-molecule acceptors in binary-blend active layers of organic photovoltaics ». Journal of Materials Chemistry A 9, no 42 (2021) : 24071–72. http://dx.doi.org/10.1039/d1ta90215f.

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Correction for ‘Twisted-graphene-like perylene diimide with dangling functional chromophores as tunable small-molecule acceptors in binary-blend active layers of organic photovoltaics’ by Yu-Che Lin et al., J. Mater. Chem. A, 2021, 9, 20510–20517, DOI: 10.1039/d1ta05697b.
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Kim, Jeongwon, Yejin Yang, Arim Seong, Hyuk-Jun Noh, Changmin Kim, Sangwook Joo, Ara Cho et al. « Correction : Identifying the electrocatalytic active sites of a Ru-based catalyst with high Faraday efficiency in CO2-saturated media for an aqueous Zn–CO2 system ». Journal of Materials Chemistry A 8, no 30 (2020) : 15187. http://dx.doi.org/10.1039/d0ta90146f.

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Correction for ‘Identifying the electrocatalytic active sites of a Ru-based catalyst with high Faraday efficiency in CO2-saturated media for an aqueous Zn–CO2 system’ by Jeongwon Kim et al., J. Mater. Chem. A, 2020, DOI: 10.1039/d0ta03050c.
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Castro Trujillo, Angelina, Rajesh Bharat Jethwa, Stefan Stadlbauer, Julia Valentin et Stefan A. Freunberger. « Redox Active Organic Liquids for Energy Storage ». ECS Meeting Abstracts MA2023-02, no 65 (22 décembre 2023) : 3050. http://dx.doi.org/10.1149/ma2023-02653050mtgabs.

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The necessity to move to renewable energy sources has increased over the last few years. However, to ensure a good transition and effective energy supply, efficient, cheap, and green technologies are required as grid-level storage.1 Redox-Active Organic Materials (ROMs) are a fast-growing research topic in different electrochemical storage devices. Their advantageous characteristics of being formed from highly abundant elements, having a high electrochemical tunability, ease of handling and device processing, and high versatility for a variety of energy storage applications make ROMs attractive.1–3 Redox-Active Liquids (RALs) are themselves a new trend within the category of ROMs because the physical properties of organic liquids are advantageous for some storage devices.4–6 Those advantages include no requirement for materials processing after synthesis, high miscibility and/or high solubility with battery electrolytes, the ability to be used as a solvent themselves without any additional additives,4,5 and the avoidance of surface-related changes e.g., dendrites.7 RALs have been studied as mediators or active materials in the context of different applications such as supercapacitors,6,8 conventional,4,5,9 and hybrid-flow batteries.10,11 In this work, we present the synthesis and physio-chemical characterization of different RALs that can be used in such energy storage devices. The characterization results supported by computational analyses were used to investigate the correlation between the chemical structure and the electrochemical properties of the compounds. The obtained information was then further used to inform the design of further compounds with enhanced electrochemical properties. (1) Schon, T. B.; McAllister, B. T.; Li, P. F.; Seferos, D. S. The Rise of Organic Electrode Materials for Energy Storage. Chem Soc Rev 2016, 45 (22), 6345–6404. https://doi.org/10.1039/c6cs00173d. (2) Kwon, G.; Ko, Y.; Kim, Y.; Kim, K.; Kang, K. Versatile Redox-Active Organic Materials for Rechargeable Energy Storage. Acc Chem Res 2021, 54 (23), 4423–4433. https://doi.org/10.1021/acs.accounts.1c00590. (3) Lee, S.; Hong, J.; Kang, K. Redox-Active Organic Compounds for Future Sustainable Energy Storage System. Advanced Energy Materials. Wiley-VCH Verlag August 1, 2020. https://doi.org/10.1002/aenm.202001445. (4) Zhao, Y.; Zhang, J.; Agarwal, G.; Yu, Z.; Corman, R. E.; Wang, Y.; Robertson, L. A.; Shi, Z.; Doan, H. A.; Ewoldt, R. H.; Shkrob, I. A.; Assary, R. S.; Cheng, L.; Srinivasan, V.; Babinec, S. J.; Zhang, L. TEMPO Allegro: Liquid Catholyte Redoxmers for Nonaqueous Redox Flow Batteries. J Mater Chem A Mater 2021, 9 (31), 16769–16775. https://doi.org/10.1039/d1ta04297a. (5) Robertson, L.; Udin, M. A.; Shlrob, I. A.; Moore, J. S.; Zhang, L. Liquid Redoxmers for Nonaqueous Redox Flow Batteries. ChemSusChem 2023, e202300043. https://doi.org/10.1002/CSSC.202300043. (6) Fontaine, O. A Deeper Understanding of the Electron Transfer Is the Key to the Success of Biredox Ionic Liquids. Energy Storage Mater 2019, 21, 240–245. https://doi.org/10.1016/J.ENSM.2019.06.023. (7) Bao, J.; Li, C.; Zhang, F.; Wang, P.; Zhang, X.; He, P.; Zhou, H. A Liquid Anode of Lithium Biphenyl for Highly Safe Lithium-Air Battery with Hybrid Electrolyte. Batter Supercaps 2020, 3 (8), 708–712. https://doi.org/10.1002/BATT.202000092. (8) Mourad, E.; Coustan, L.; Lannelongue, P.; Zigah, D.; Mehdi, A.; Vioux, A.; Freunberger, S. A.; Favier, F.; Fontaine, O. Biredox Ionic Liquids with Solid-like Redox Density in the Liquid State for High-Energy Supercapacitors. Nature Materials 2016 16:4 2016, 16 (4), 446–453. https://doi.org/10.1038/nmat4808. (9) Chen, H.; Niu, Z.; Zhao, Y. Redox-Active Binary Eutectics: Preparation and Their Electrochemical Properties. Electrochem commun 2021, 126. https://doi.org/10.1016/j.elecom.2021.107028. (10) Shimizu, A.; Takenaka, K.; Handa, N.; Nokami, T.; Itoh, T.; Yoshida, J.-I.; Shimizu, A.; Takenaka, K.; Yoshida, J.; Handa, N.; Nokami, T.; Itoh, T. Liquid Quinones for Solvent-Free Redox Flow Batteries. Advanced Materials 2017, 29 (41), 1606592. https://doi.org/10.1002/ADMA.201606592. (11) Chen, N.; Chen, D.; Wu, J.; Lai, Y.; Chen, D. Polyethylene Glycol Modified Tetrathiafulvalene for High Energy Density Non-Aqueous Catholyte of Hybrid Redox Flow Batteries. Chemical Engineering Journal 2023, 462. https://doi.org/10.1016/j.cej.2023.141996.
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Popovic-Neuber, Jelena. « (Invited) Cation Conducting Binders : From Liquid to Solid-State Batteries ». ECS Meeting Abstracts MA2023-02, no 6 (22 décembre 2023) : 917. http://dx.doi.org/10.1149/ma2023-026917mtgabs.

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Binders play an important role in providing connection between active electrode materials with the conductive agent, thus enabling electronic/ionic pathways and good mechanical properties of battery electrodes.1 In the first part of my talk, I will discuss the case of binders for high volume expansion electrodes (e.g. Si), where cycle life is strongly reduced by cracking of active particles and solid electrolyte interphases (SEIs), the process which in turn consumes the electrolyte continuously. Here, development of multi-functional polymeric binders with ionic conductivity (and potentially self-healing functionalities) substituting the standard polyvinylidene fluoride (PVDF) has been of utmost importance.2,3 Consecutively, I will touch upon binder development from the process energy point of view, and discuss ionically conductive solvent-free binders, of relevance for future solid-state batteries containing highly reactive sulfide-based electrolytes.4 Finally, possibility of employment of fully inorganic polyphosphates and polysilicates binders will be investigated.5 F. Zou, A. Manthiram, Adv. Funct. Mater. 10, 45, 2002508 (2020) J. Liu, Q. Zhang, T. Zhang, J.-T. Li, L. Huang, S.-G. Sun, Adv. Funct. Mater. 25, 23, 3599 (2015) H. Liu, Q. Wu, X. Guan, M. Liu, F. Wang, R. Li, J. Xu, ACS Appl. Energy Mater. 5, 4, 4934 (2022) S.-B. Hong, Y.-J. Lee, U.-H. Kim, C. Bak, Y. M. Lee, W. Cho, H. J. Hah, Y.-K. Sun, D.-W. Kim, ACS Energy Lett., 7, 3, 1092 (2022) S. Trivedi, V. Pamidi, M. Fichtner, M. A. Reddy, Green Chem., 24, 5620 (2022)
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León-Bravo, Gema, Irene Cantarero-Carmona et Javier Caballero-Villarraso. « Prevalence of Active Primitive Reflexes and Craniosacral Blocks in Apparently Healthy Children and Relationships with Neurodevelopment Disturbances ». Children 10, no 6 (4 juin 2023) : 1014. http://dx.doi.org/10.3390/children10061014.

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Background: In healthy children, the frequency of the anomalous persistence of primitive reflexes (PRs) and craniosacral blocks (CBs) is unknown, as well as their impact on neurodevelopment, behaviour disorders and related consequences. We aim to know the prevalence of anomalous PRs and CBs in apparently healthy children and their relationships with behavior and neurodevelopment anomalies. Methods: Participants (n = 120) were evaluated via a physical examination to detect PRs and CBs and an ad hoc parent survey to collect perinatal events, and children’s behavioral assessments were conducted by teachers using the Battelle score. Results: PRs were present in 89.5%. Moro (70.8%), cervical asymmetric (78.3%) and cervical symmetric PRs (67.5%) were the most frequently observed PRs. CBs were found in 83.2%, and the most frequent CBs were dura mater (77.5%) and sphenoid bone (70%) blocks. Moro, cervical asymmetric and cervical symmetric active primitive reflexes were significantly associated with cranial blocks of dura mater, parietal zones and sphenoid bone sway. Gestational disorders or perinatal complications were associated with a higher frequency of PRs and CBs. The presence of PRs and CBs was associated with abnormal Battelle scores and neurobehavioral problems. Conclusion: The presence of PRs and CBs in children without diagnosed diseases is frequent and related to disturbances in childhood neurodevelopment.
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Ko, Hyojin, Jumi Lee, Yongjun Kim, Byeongno Lee, Chan-Hee Jung, Jae-Hak Choi, Oh-Sun Kwon et Kwanwoo Shin. « Microfluidic Chips : Active Digital Microfluidic Paper Chips with Inkjet-Printed Patterned Electrodes (Adv. Mater. 15/2014) ». Advanced Materials 26, no 15 (avril 2014) : 2286. http://dx.doi.org/10.1002/adma.201470096.

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Pingree, Liam S. C., Obadiah G. Reid et David S. Ginger. « Scanning Probe Microscopy : Electrical Scanning Probe Microscopy on Active Organic Electronic Devices (Adv. Mater. 1/2009) ». Advanced Materials 21, no 1 (5 janvier 2009) : NA. http://dx.doi.org/10.1002/adma.200890111.

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Stec, Helena M., et Ross A. Hatton. « Organic Photovoltaics : Plasmon-Active Nano-Aperture Window Electrodes for Organic Photovoltaics (Adv. Energy Mater. 2/2013) ». Advanced Energy Materials 3, no 2 (février 2013) : 137. http://dx.doi.org/10.1002/aenm.201370006.

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Oh, Yeon-Su, Gwan Yeong Jung, Jeong-Hoon Kim, Jung-Hwan Kim, Su Hwan Kim, Sang Kyu Kwak et Sang-Young Lee. « Separator Membranes : Janus-Faced, Dual-Conductive/Chemically Active Battery Separator Membranes (Adv. Funct. Mater. 39/2016) ». Advanced Functional Materials 26, no 39 (octobre 2016) : 7195. http://dx.doi.org/10.1002/adfm.201670258.

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Mentovich, Elad D., Bogdan Belgorodsky, Itsik Kalifa et Shachar Richter. « Quantum Dot Transistors : 1-Nanometer-Sized Active-Channel Molecular Quantum-Dot Transistor (Adv. Mater. 19/2010) ». Advanced Materials 22, no 19 (18 mai 2010) : n/a. http://dx.doi.org/10.1002/adma.201090067.

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Cuesta, Virginia, Maida Vartanian, Pilar de la Cruz, Ganesh D. Sharma et Fernando Langa. « Molecular Engineering of Low-Bandgap Porphyrins for Highly Efficient Organic Solarcells ». ECS Meeting Abstracts MA2022-01, no 14 (7 juillet 2022) : 981. http://dx.doi.org/10.1149/ma2022-0114981mtgabs.

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Organic solar cells (OSCs) based on solution-processed bulk heterojunction (BHJ) active layers have emerged as promising solutions for the conversion of solar energy into electrical energy in building and indoor applications due to their unique advantages, such as being lightweight and semitrans-parent and the possibility of being processed by low-cost roll-to-roll methods. The BHJ active layer employed for OSCs consists of a blend of an electron-donating material and an electron-accepting material creating internal donor-acceptor heterojunctions, and their optical and electrochemical properties are very important for the realization of a high-power conversion efficiency (PCE). The optical and electrochemical properties of porphyrins can be adjusted by molecular design and functionalization on the b or meso positions of the porphyrin ring as well as by introduction of different central metal ions. Although the pioneering use of porphyrins in OSCs was disappointing, as reported efficiencies were very low;the situation has changed over the last five years as Zn-porphyrins with ABAB structures linked to acceptor units, having relatively long-lived singlet excited states, have been successfully used as donors or acceptors, resulting in increased efficiencies. Here, I´ll present our recent work in design, synthesis, and application of porphyrin-based small molecules for highly efficient OSCs with VOC>1V and PCE>15%. References V. Cuesta, M. Vartanian, P. de la Cruz, R. Singhal, G. D. Sharma and F. Langa, J. Mater. Chem. A,2017, 5, 1057. S. Arrechea, A. Aljarilla, P. de la Cruz, M. K. Singh, G. D. Sharma, F. Langa. J. Mater. Chem. C, 2017, 5, 4742. M. Vartanian, R. Singhal, P. de la Cruz, S. Biswas, G. D. Sharma and F. Langa, ACS Appl. Energy Mater. 2018, 1, 1304. M. Vartanian, P. de la Cruz, F. Langa, S. Biswas, G. D. Sharma. Nanoscale, 2018, 10, 12100. M. Vartanian, R. Singhal, P. de la Cruz, G. D. Sharma, F. Langa, Chem. Commun, 2018, 54, 14144. V. Cuesta, R. Singhal, P. de la Cruz, G. D. Sharma, F. Langa, ACS Appl. Mater. Interfaces, 2019, 11, 7216 . Cuesta, R. Singhal, P. de la Cruz, G. D. Sharma, F. Langa, ChemSusChem 2021, 14, 3439. H. Dahiya, V. Cuesta, P. de la Cruz, F. Langa, G. D. Sharma ACS Appl. Energy Mater. 2021, 4, 4498.
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Loewe, Benjamin, et Tyler N. Shendruk. « Passive Janus particles are self-propelled in active nematics ». New Journal of Physics 24, no 1 (1 janvier 2022) : 012001. http://dx.doi.org/10.1088/1367-2630/ac3b70.

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Abstract While active systems possess notable potential to form the foundation of new classes of autonomous materials (Zhang et al 2021 Nat. Rev. Mater. 6 437), designing systems that can extract functional work from active surroundings has proven challenging. In this work, we extend these efforts to the realm of designed active liquid crystal/colloidal composites. We propose suspending colloidal particles with Janus anchoring conditions in an active nematic medium. These passive Janus particles become effectively self-propelled once immersed into an active nematic bath. The self-propulsion of passive Janus particles arises from the effective +1/2 topological charge their surface enforces on the surrounding active fluid. We analytically study their dynamics and the orientational dependence on the position of a companion −1/2 defect. We predict that at sufficiently small activity, the colloid and companion defect remain bound to each other, with the defect strongly orienting the colloid to propel either parallel or perpendicular to the nematic. At sufficiently high activity, we predict an unbinding of the colloid/defect pair. This work demonstrates how suspending engineered colloids in active liquid crystals may present a path to extracting activity to drive functionality.
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Vetrone, Fiorenzo, Rafik Naccache, Venkataramanan Mahalingam, Christopher G. Morgan et John A. Capobianco. « Upconverting Nanoparticles : The Active-Core/Active-Shell Approach : A Strategy to Enhance the Upconversion Luminescence in Lanthanide-Doped Nanoparticles (Adv. Funct. Mater. 18/2009) ». Advanced Functional Materials 19, no 18 (23 septembre 2009) : NA. http://dx.doi.org/10.1002/adfm.200990081.

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Goto, Hiromasa. « Conducting Polymers : An Optically Active Polythiophene Exhibiting Electrochemically Driven Light-Interference Modulation (Adv. Funct. Mater. 9/2009) ». Advanced Functional Materials 19, no 9 (8 mai 2009) : NA. http://dx.doi.org/10.1002/adfm.200990035.

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Wang, Jia, Christian Larsen, Thomas Wågberg et Ludvig Edman. « Organic Field-Effect Transistors : Direct UV Patterning of Electronically Active Fullerene Films (Adv. Funct. Mater. 19/2011) ». Advanced Functional Materials 21, no 19 (26 septembre 2011) : 3598. http://dx.doi.org/10.1002/adfm.201190081.

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Cho, Kyung Gook, Hee Soo Kim, Seong Su Jang, Hyuna Kyung, Min Seok Kang, Keun Hyung Lee et Won Cheol Yoo. « Ionogels : Optimizing Electrochemically Active Surfaces of Carbonaceous Electrodes for Ionogel Based Supercapacitors (Adv. Funct. Mater. 30/2020) ». Advanced Functional Materials 30, no 30 (juillet 2020) : 2070199. http://dx.doi.org/10.1002/adfm.202070199.

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Bülbül, Gonca, Akhtar Hayat et Silvana Andreescu. « Biomolecular Recognition : ssDNA-Functionalized Nanoceria : A Redox-Active Aptaswitch for Biomolecular Recognition (Adv. Healthcare Mater. 7/2016) ». Advanced Healthcare Materials 5, no 7 (avril 2016) : 864. http://dx.doi.org/10.1002/adhm.201670036.

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Jia, Zhe, Tao Yang, Ligang Sun, Yilu Zhao, Wanpeng Li, Junhua Luan, Fucong Lyu et al. « Water Splitting : A Novel Multinary Intermetallic as an Active Electrocatalyst for Hydrogen Evolution (Adv. Mater. 21/2020) ». Advanced Materials 32, no 21 (mai 2020) : 2070166. http://dx.doi.org/10.1002/adma.202070166.

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Matsumi, Noriyoshi. « (Invited) Design of Specific Polymer Binders for Stabilization of Si Based Anode in Lib ». ECS Meeting Abstracts MA2023-02, no 6 (22 décembre 2023) : 897. http://dx.doi.org/10.1149/ma2023-026897mtgabs.

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In recent years, intense efforts have been focused on stabilization of silicon-based anode in Li ion secondary batteries due to their remarkably high theoretical capacity. At the same time, strategy has not yet been established on how to stabilize the silicon based anode sufficiently during long cycles so that it will be feasible for practical use. In this talk, several different approaches on stabilization of silicon-based anode will be introduced both in terms of polymer binders design and active materials design. Our group synthesized several self-healing polymer binder and polymer coating material which are efficient for the use in silicon-based anode. Poly(borosiloxane) (PBS)1 was prepared by dehydrocoupling polymerization between mesitylborane and diphenylsilanediol in the presence of transition metal catalyst. PBS was found to show self-healing property at 45oC when coated onto Si electrode. When PBS coated Si electrode was employed for anodic half cell (Si/EC:DEC (1/1=v/v)/Li), it showed much improved durability when compared with PVDF coated Si based cell or bare Si based cell. We also reported a design of BIAN (bis-imino-acenaphthene) based conjugated polymer (P-BIAN) /Poly(acrylic acid) (PAA) composite binder for Si based anode2,3. Due to combination of n-type imine-based conjugated polymer (H-bonding acceptor) and PAA (H-bonding donor), synergistic effect in stabilization of Si/C composite anode was observed due to both of desirable electronic structure of P-BIAN and H-bonding based self-healing properties. In this system, anodic half cell delivered specific discharging capacity of above 2000 mAhg-1 for 600 cycles. As alternative approaches, we are also working on preparation of specific Si based anodic active materials which showed extremely high durability. b-SiC/N-doped carbon4 was found to show excellent durability even in the presence of conventional binder materials due to restricted volumetric changes of b-SiC during lithiation/delithiation. We also report coating of mechanically highly robust silicon oxycarbide on micro silicon5, which was also found to be quite effective. References 1) Patnaik, S. G.; Jayakumar, T. P.; Sawamura, Y. Matsumi, N. ACS Appl. Ener. Mater. 2021, 4, 2241. 2) Gupta, A.; Badam, R.; Matsumi, N. ACS Appl. Ener. Mater. 2022, 5, 7977. 3) Gupta, A.; Badam, R.; Nag, A.; Kaneko, T.; Matsumi, N. ACS Appl. Ener. Mater. 2021, 4, 2231 4) Nandan, R.; Takamori, N.; Higashimine, K.; Badam, R.; Matsumi, N. J. Mater. Chem. A. 2022, 10, 5230. 5) Nandan, R.; Takamori, N.; Higashimine, K.; Badam, R.; Matsumi, N. J. Mater. Chem. A. 2022, 10, 15960.
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Menezes, Prashanth W., Jan Niklas Hausmann et Matthias Driess. « Intermetallic Water Splitting (Pre)Catalysts ». ECS Meeting Abstracts MA2022-02, no 48 (9 octobre 2022) : 1808. http://dx.doi.org/10.1149/ma2022-02481808mtgabs.

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The continuous increase in the population and industrial development has led to an increase in global energy demand. Most of the current primary energy consumption is obtained from the burning of fossil fuels that releases an enormous amount of greenhouse gases. Notably, hydrogen (H2) is a clean and eco-friendly fuel and has already shown its ability to be a promising substitute for fossil energy. One of the cleanest ways to produce H2 is by splitting of water by electrolysis.1 Recently, numerous inexpensive and robust catalysts based on transition metals (oxides, chalcogenides, pnictides, carbides, or alloys, etc.) have been developed for water splitting with reasonable activity.2 Despite the massive development of electrocatalysts for water splitting, huge challenges still exist for their use in practical application. Our current goals are to uncover new classes of suitable unconventional catalysts based on non-noble metals that can offer better overall catalytic efficiency for practical applications; to study their structural transformation, active sites, surface, and bulk structures; and to investigate the influence of precatalysts on the properties of the final catalyst. In this context, intermetallic compounds have numerous advantages owing to their intriguing structural, chemical and physical properties, especially being catalytically active and electrically conductive at the same time and thus, making them an ideal class of materials for electrocatalytic applications.3 Using different approaches, we synthesized various classes of intermetallic materials (e.g., stannides, gallides, germanides, indates, silicides, etc.) with interesting structural and electronic features.4-5 Most of these materials exhibited remarkable electrocatalytic activity for water splitting, yielding considerably low overpotentials with enhanced long-term durability for both O2 and H2 generation in alkaline media. The active catalyst structure during each half-reaction (H2 and O2) and the correlation of the structure with the activity of the catalysts were revealed by a profound understanding of the system using in-situ and ex-situ techniques. This talk will provide a brief summary of the ongoing water splitting research as well as delve into selected examples of our recent work to pave the way to a concept-guided design system beyond water electrolysis (e.g., paired electrolysis). References [1] H Yang, M Driess, P. W. Menezes, Adv. Energy Mater. 2021, 11, 2102074. [2] Z Chen, H Yang, Z Kang, M Driess, P. W. Menezes, Adv. Mater. 2022, 2108432. [3] C. Walter, P. W. Menezes, M. Driess, Chem. Sci. 2021, 12, 8603. [4] N. Hausmann, R. Beltrán-Suito, S. Mebs, V. Hlukhyy, T. F. Fässler, H. Dau, M. Driess, P. W. Menezes, Adv. Mater. 2021, 33, 2008823. [5] B. Chakraborty, R. Beltrán-Suito, S. Garai, J. N. Hausmann, M. Driess, P. W. Menezes, Adv. Energy Mater. 2020, 10, 2001377.
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Villegas, Carolina, Sara Martínez, Alejandra Torres, Adrián Rojas, Rocío Araya, Abel Guarda et María José Galotto. « Processing, Characterization and Disintegration Properties of Biopolymers Based on Mater-Bi® and Ellagic Acid/Chitosan Coating ». Polymers 15, no 6 (21 mars 2023) : 1548. http://dx.doi.org/10.3390/polym15061548.

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Among the most promising synthetic biopolymers to replace conventional plastics in numerous applications is MaterBi® (MB), a commercial biodegradable polymer based on modified starch and synthetic polymers. Actually, MB has important commercial applications as it shows interesting mechanical properties, thermal stability, processability and biodegradability. On the other hand, research has also focused on the incorporation of natural, efficient and low-cost active compounds into various materials with the aim of incorporating antimicrobial and/or antioxidant capacities into matrix polymers to extend the shelf life of foods. Among these is ellagic acid (EA), a polyphenolic compound abundant in some fruits, nuts and seeds, but also in agroforestry and industrial residues, which seems to be a promising biomolecule with interesting biological activities, including antioxidant activity, antibacterial activity and UV-barrier properties. The objective of this research is to develop a film based on commercial biopolymer Mater-Bi® (MB) EF51L, incorporating active coating from chitosan with a natural active compound (EA) at two concentrations (2.5 and 5 wt.%). The formulations obtained complete characterization and were carried out in order to evaluate whether the incorporation of the coating significantly affects thermal, mechanical, structural, water-vapor barrier and disintegration properties. From the results, FTIR analysis yielded identification, through characteristic peaks, that the type of MB used is constituted by three polymers, namely PLA, TPS and PBAT. With respect to the mechanical properties, the values of tensile modulus and tensile strength of the MB-CHI film were between 15 and 23% lower than the values obtained for the MB film. The addition of 2.5 wt.% EA to the CHI layer did not generate changes in the mechanical properties of the system, whereas a 5 wt.% increase in ellagic acid improved the mechanical properties of the CHI film through the addition of natural phenolic compounds at high concentrations. Finally, the disintegration process was mainly affected by the PBAT biopolymer, causing the material to not disintegrate within the times indicated by ISO 20200.
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Gunarto, Muji, et Dian Cahyawati. « Analysis of Alumni Loyalty in Private Universities Using the SEM-PLS Model Approach ». Jurnal Organisasi dan Manajemen 18, no 1 (14 juin 2022) : 46–59. http://dx.doi.org/10.33830/jom.v18i1.1311.2022.

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One of the main objectives of research in marketing both in the goods and services industry is customer loyalty. Research on college marketing also focuses on alumni loyalty. The purpose of this study was to analyze the effect of co-creation and experience value on student loyalty in private universities. The survey was conducted on 278 alumni from 5 (five) private universities in Palembang who were randomly selected. Data was collected by distributing the google form through the alumni unit at each university and alumni groups. Data analysis was carried out by using the structural equation model partial least square approach (SEM-PLS) with the SmartPLS3 application program. The results showed that co-creation had a positive and significant effect on the value of experience and alumni loyalty. Students who gain experience value during their lectures are those who have the opportunity to interact and play an active role on campus. High interaction shows a strong level of co-creation for students and shows a better experience value, thus impacting alumni loyalty. Alumni intend to recommend their alma mater to others and care more about their alma mater. Alumni should be given space to be able to build their campus through strong alumni ties. Alumni who have concern for the alma mater are those who have a lot of experience during their studies
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Cao, Hongzhi, Bin Fang, Jiejie Liu, Yu Shen, Jie Shen, Pan Xiang, Qin Zhou et al. « Photodynamic Therapy : Photodynamic Therapy Directed by Three‐Photon Active Rigid Plane Organic Photosensitizer (Adv. Healthcare Mater. 7/2021) ». Advanced Healthcare Materials 10, no 7 (avril 2021) : 2170028. http://dx.doi.org/10.1002/adhm.202170028.

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Alt, Karen, Francesco Carraro, Edwina Jap, Mercedes Linares‐Moreau, Raffaele Riccò, Marcello Righetto, Marco Bogar et al. « Self‐Assembly of Oriented Antibody‐Decorated Metal–Organic Framework Nanocrystals for Active‐Targeting Applications (Adv. Mater. 21/2022) ». Advanced Materials 34, no 21 (mai 2022) : 2270159. http://dx.doi.org/10.1002/adma.202270159.

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Kim, Minki, Min Young Ha, Woo‐Bin Jung, Jeesoo Yoon, Euichul Shin, Il‐doo Kim, Won Bo Lee, YongJoo Kim et Hee‐tae Jung. « Searching for an Optimal Multi‐Metallic Alloy Catalyst by Active Learning Combined with Experiments (Adv. Mater. 19/2022) ». Advanced Materials 34, no 19 (mai 2022) : 2270147. http://dx.doi.org/10.1002/adma.202270147.

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Treat, Neil D., Michael A. Brady, Gordon Smith, Michael F. Toney, Edward J. Kramer, Craig J. Hawker et Michael L. Chabinyc. « Correction : Interdiffusion of PCBM and P3HT Reveals Miscibility in a Photovoltaically Active Blend (Adv. Energy Mater. 2/2011) ». Advanced Energy Materials 1, no 2 (16 mars 2011) : 145. http://dx.doi.org/10.1002/aenm.201190008.

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Ren, Beitao, Gancheong Yuen, Sunbin Deng, Le Jiang, Dingjian Zhou, Leilei Gu, Ping Xu et al. « Multifunctional Optoelectronic Devices : Multifunctional Optoelectronic Device Based on an Asymmetric Active Layer Structure (Adv. Funct. Mater. 17/2019) ». Advanced Functional Materials 29, no 17 (avril 2019) : 1970114. http://dx.doi.org/10.1002/adfm.201970114.

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Duncan, Bradley, Robert D. Weeks, Benjamin Barclay, Devon Beck, Patrick Bluem, Roberto Rojas, Maxwell Plaut et al. « Low‐Loss Graded Dielectrics via Active Mixing of Nanocomposite Inks during 3D Printing (Adv. Mater. Technol. 3/2023) ». Advanced Materials Technologies 8, no 3 (février 2023) : 2370011. http://dx.doi.org/10.1002/admt.202370011.

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