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Artículos de revistas sobre el tema "Versatile intermediates"

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Publicado: 6 de septiembre de 2023

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1

Boeske, Juergen, Edgar Niecke, Edgar Ocando-Mavarez, Jean Pierre Majoral y Guy Bertrand. "Phosphonitriles: versatile intermediates". Inorganic Chemistry 25, n.º 16 (julio de 1986): 2695–98. http://dx.doi.org/10.1021/ic00236a008.

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2

Belletire, J. L. "Acylcyanamides: Versatile Synthetic Intermediates". Synthetic Communications 18, n.º 16-17 (noviembre de 1988): 2063–71. http://dx.doi.org/10.1080/00397918808068275.

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3

R. Katritzky, Alan, Adam S. Vincek y Peter J. Steel. "Triphenylphosphoranylidene Substituted Heterocycles as Versatile Intermediates". HETEROCYCLES 76, n.º 2 (2008): 1401. http://dx.doi.org/10.3987/com-08-s(f)12.

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4

Britten, Thomas K., Paul D. Kemmitt, Nathan R. Halcovitch y Susannah C. Coote. "1,2-Dihydropyridazines as Versatile Synthetic Intermediates". Synlett 31, n.º 05 (13 de febrero de 2020): 459–62. http://dx.doi.org/10.1055/s-0039-1690825.

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The reactivity of 1,2-dihydropyridazines under various conditions is described, leading to the formation of a variety of products, including 2-aminopyrroles, phenylenediamines, and several novel heterocyclic motifs.
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5

Bari, Ahmed. "Monosaccharidic Push-pull Butadienes: Versatile Synthetic Intermediates". Zeitschrift für Naturforschung B 69, n.º 1 (1 de enero de 2014): 98–102. http://dx.doi.org/10.5560/znb.2014-3179.

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Monosaccharidic push-pull butadienes are interesting building blocks for the synthesis of various heterocyclic and natural products due to their biological prevalence and significant p-electron interactions between donor and acceptor groups. A series of 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy- 2-formyl-D-arabino-hex-1-enitol (2) and 1,5-anhydro-3,4-di-O-benzyl-2-deoxy-2-formyl-L-erythrohex- 1-enitol (4) derived push-pull branched chain sugars have been synthesized by condensation with active methylene compounds using basic aluminum oxide (Al2O3) or anhydrous sodium acetate (NaOAc) at room temperature. The compounds have been fully characterized by spectroscopic techniques and elemental analyses.
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6

Attanasi, Orazio A. y Luciano Caglioti. "CONJUGATED AZOALKENES: ATTRACTIVE PRODUCTS AND VERSATILE INTERMEDIATES". Organic Preparations and Procedures International 18, n.º 5 (octubre de 1986): 299–327. http://dx.doi.org/10.1080/00304948609356836.

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7

Flashman, Emily y Christopher J. Schofield. "The most versatile of all reactive intermediates?" Nature Chemical Biology 3, n.º 2 (febrero de 2007): 86–87. http://dx.doi.org/10.1038/nchembio0207-86.

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8

Zellner, Armin y Manfred Schlosser. "Pentadienyltitaniums as Versatile Intermediates: Regio- and Stereoselectivities". Synlett 2001, Special Issue (2001): 1016–18. http://dx.doi.org/10.1055/s-2001-14650.

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9

Barrett, Anthony G. M. y Gregory G. Graboski. "Conjugated nitroalkenes: versatile intermediates in organic synthesis". Chemical Reviews 86, n.º 5 (octubre de 1986): 751–62. http://dx.doi.org/10.1021/cr00075a002.

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10

Michael, J. P., C. B. de Koning, D. Gravestock, G. D. Hosken, A. S. Howard, C. M. Jungmann, R. W. M. Krause, A. S. Parsons, S. C. Pelly y T. V. Stanbury. "Enaminones: versatile intermediates for natural product synthesis". Pure and Applied Chemistry 71, n.º 6 (30 de junio de 1999): 979–88. http://dx.doi.org/10.1351/pac199971060979.

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11

Joergensen, M., K. A. Lerstrup y K. Bechgaard. "Mesoions as versatile intermediates in tetrathiafulvalene synthesis". Journal of Organic Chemistry 56, n.º 19 (septiembre de 1991): 5684–88. http://dx.doi.org/10.1021/jo00019a041.

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12

Chemla, Fabrice. "α-Oxy sulfones and sulfoximines: versatile intermediates". Journal of the Chemical Society, Perkin Transactions 1, n.º 3 (10 de enero de 2002): 275–99. http://dx.doi.org/10.1039/b009523k.

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13

Lamberth, Clemens. "Organic Isocyanates and Isothiocyanates: Versatile Intermediates in Agrochemistry". Synthesis 54, n.º 05 (26 de octubre de 2021): 1250–60. http://dx.doi.org/10.1055/a-1678-8528.

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AbstractIn recent decades, organic isocyanates and isothiocyanates have been often applied as reactive intermediates in research syntheses or manufacturing routes of many agrochemicals. These heterocumulenes allowed the installation of crucial carboxylic functions, such as carbamates, ureas, and semicarbazones, but have also been used for the construction of five- and six-membered heterocycles, such as tetrazolones, thiazoles, and uracils.1 Introduction2 Preparation of Carboxylic Acid Functions3 Preparation of Heterocyclic Rings4 Conclusion
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14

Warkentin, John. "Δ3-1,3,4-Oxadiazolines.† Versatile sources of reactive intermediates". Journal of the Chemical Society, Perkin Transactions 1, n.º 14 (2000): 2161–69. http://dx.doi.org/10.1039/b000930j.

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15

Redely, D. Bhaskar, M. V. Ramana Redely y V. Padmavathi. "Cyclohexanone Gem-Dicarboxylates - Versatile Intermediates for Fused Heterocycles". Synthetic Communications 29, n.º 4 (febrero de 1999): 667–76. http://dx.doi.org/10.1080/00397919908085815.

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16

Havel, Václav, Tereza Sadilová y Vladimír Šindelář. "Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates". ACS Omega 3, n.º 4 (27 de abril de 2018): 4657–63. http://dx.doi.org/10.1021/acsomega.8b00497.

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17

Krafft, Grant A., Ester A. Garcia, Anil Guram, Brian O'Shaughnessy y Xialong Xu. "Simplified cytochalasins. 1. Synthesis of versatile perhydroisoindolone intermediates." Tetrahedron Letters 27, n.º 24 (1986): 2691–94. http://dx.doi.org/10.1016/s0040-4039(00)84618-3.

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18

van de Wouw, Heidi L. y Rebekka S. Klausen. "BN Polystyrenes: Emerging Optical Materials and Versatile Intermediates". Journal of Organic Chemistry 84, n.º 3 (8 de enero de 2019): 1117–25. http://dx.doi.org/10.1021/acs.joc.8b02921.

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19

Irwin, Jacob L. y Michael S. Sherburn. "Monolithiocavitands: Versatile Intermediates for New Cavitand-Based Hosts". Organic Letters 3, n.º 2 (enero de 2001): 225–27. http://dx.doi.org/10.1021/ol006881w.

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20

Waldvogel, Siegfried R. y Sabine Möhle. "Versatile Electrochemical CH Amination via Zincke Intermediates". Angewandte Chemie International Edition 54, n.º 22 (12 de mayo de 2015): 6398–99. http://dx.doi.org/10.1002/anie.201502638.

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21

Zhang, Shu Xin. "Research on Synthesis of Benzoic Acids Intermediates". Applied Mechanics and Materials 192 (julio de 2012): 270–74. http://dx.doi.org/10.4028/www.scientific.net/amm.192.270.

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This article briefly describes the development of dye intermediates in China and the research and development situation on synthetic 2 - amino-5 - nitrobenzoic acids. It also tries two more new routes to practice synthesis of them, for which it focuses on speculation of the reaction mechanism of the former route and on research of process conditions of the latter, getting the optimal conditions of the synthetic 5 - nitro-isatin. 2 - Amino - 5 - nitro benzoic acid is a versatile organic intermediate, which is seldom reported both home and abroad, but research on its synthesis method and process conditions are significant to the development of China's fine intermediates industry.
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22

Roy, Tony y Akkattu T. Biju. "Recent advances in molecular rearrangements involving aryne intermediates". Chemical Communications 54, n.º 21 (2018): 2580–94. http://dx.doi.org/10.1039/c7cc09122b.

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A concise account on the recent developments in molecular rearrangements proceeding via the aryne intermediate is presented thereby shedding light on the synthetic potential of this versatile intermediate.
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23

Ducrot, Paul-Henri, Anne-Claire Hervier y Jean-Yves Lallemand. "Stereoselective Synthesis of Versatile Intermediates for Clerodanes Total synthesis". Synthetic Communications 26, n.º 23 (diciembre de 1996): 4447–57. http://dx.doi.org/10.1080/00397919608003847.

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24

Cordero, Franca M., Francesco De Sarlo y Alberto Brandi. "5-Spirocyclopropane Isoxazolidines as Versatile Intermediates in Organic Synthesis". Monatshefte f�r Chemie / Chemical Monthly 135, n.º 6 (1 de junio de 2004): 649–69. http://dx.doi.org/10.1007/s00706-003-0150-x.

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25

Mukaiyama, Teruaki y Hokuto Yamabe. "Alkyl Phosphinites: Versatile Synthetic Intermediates for Dehydration Condensation Reactions". Chemistry Letters 36, n.º 1 (enero de 2007): 2–7. http://dx.doi.org/10.1246/cl.2007.2.

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26

Schmidt, Richard R. "Functionally Substituted Vinyl Carbanions Versatile Intermediates in Heterocyclic Synthesis". Bulletin des Sociétés Chimiques Belges 92, n.º 9 (1 de septiembre de 2010): 825–36. http://dx.doi.org/10.1002/bscb.19830920909.

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27

Michael, Joseph P., Charles B. De Koning, David Gravestock, Gladys D. Hosken, Arthur S. Howard, Christa M. Jungmann, Rui W. M. Krause, Andrew S. Parsons, Stephen C. Pelly y Trevor V. Stanbury. "ChemInform Abstract: Enaminones: Versatile Intermediates for Natural Product Synthesis". ChemInform 31, n.º 4 (11 de junio de 2010): no. http://dx.doi.org/10.1002/chin.200004280.

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28

Zellner, Armin y Manfred Schlosser. "ChemInform Abstract: Pentadienyltitaniums as Versatile Intermediates: Regio- and Stereoselectivities." ChemInform 32, n.º 40 (24 de mayo de 2010): no. http://dx.doi.org/10.1002/chin.200140064.

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29

JOERGENSEN, M., K. A. LERSTRUP y K. BECHGAARD. "ChemInform Abstract: Mesoions as Versatile Intermediates in Tetrathiafulvalene Synthesis." ChemInform 23, n.º 6 (22 de agosto de 2010): no. http://dx.doi.org/10.1002/chin.199206174.

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30

Chemla, Fabrice. "ChemInform Abstract: α-Oxy Sulfones and Sulfoximines: Versatile Intermediates". ChemInform 33, n.º 24 (21 de mayo de 2010): no. http://dx.doi.org/10.1002/chin.200224251.

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31

Evano, Gwilherm, Morgan Lecomte, Pierre Thilmany y Cédric Theunissen. "Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis". Synthesis 49, n.º 15 (17 de julio de 2017): 3183–214. http://dx.doi.org/10.1055/s-0036-1588452.

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Keteniminium ions have been demonstrated to be remarkably useful and versatile reactive intermediates in chemical synthesis. These unique heterocumulenes are pivotal electrophilic species involved in a number of efficient and selective transformations. More recently, even more reactive ‘activated’ keteniminium ions bearing an additional electron-withdrawing group on the nitrogen atom have been extensively investigated. The chemistry of these unique reactive intermediates, including representative methods for their in situ generation, will be overviewed in this review article.1 Introduction2 The Chemistry of Keteniminium Ions3 The Chemistry of Activated Keteniminium Ions4 Keteniminium Ions: Pivotal Intermediates for the Synthesis of Natural and/or Biologically Relevant Molecules5 Conclusions and Perspectives
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32

Tian, Feitao, Guobing Yan y Jian Yu. "Recent advances in the synthesis and applications of α-(trifluoromethyl)styrenes in organic synthesis". Chemical Communications 55, n.º 90 (2019): 13486–505. http://dx.doi.org/10.1039/c9cc06465f.

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33

Iwanejko, Jakub y Elżbieta Wojaczyńska. "Cyclic imines – preparation and application in synthesis". Organic & Biomolecular Chemistry 16, n.º 40 (2018): 7296–314. http://dx.doi.org/10.1039/c8ob01874j.

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34

Dong, Kuiyong, Mengting Liu y Xinfang Xu. "Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates". Molecules 27, n.º 10 (11 de mayo de 2022): 3088. http://dx.doi.org/10.3390/molecules27103088.

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As one of the abundant and inexpensive metals on the earth, copper has demonstrated broad applications in synthetic chemistry and catalysis. Among these copper-catalyzed advances, copper carbenes are versatile and reactive intermediates that can mediate a variety of transformations, which have attracted much attention in the past decades. The present review summarizes two different reaction models that take place between a copper carbene intermediate and alkyne species, including the cross-coupling reaction of copper carbene intermediate with terminal alkyne, and the addition of copper carbene intermediate onto the C–C triple bond. This article will cover the profile from 2010 to 2021 by placing emphasis on the detailed catalytic models and highlighting the synthetic applications offered by these practical and mild methods.
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35

Liew, Sean K., Aleksandra Holownia, Diego B. Diaz, Philip A. Cistrone, Philip E. Dawson y Andrei K. Yudin. "Borylated oximes: versatile building blocks for organic synthesis". Chem. Commun. 53, n.º 81 (2017): 11237–40. http://dx.doi.org/10.1039/c7cc06579e.

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36

Berger, Olivier y Jean-Luc Montchamp. "General synthesis of P-stereogenic compounds: the menthyl phosphinate approach". Organic & Biomolecular Chemistry 14, n.º 31 (2016): 7552–62. http://dx.doi.org/10.1039/c6ob01413e.

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37

Bayer, Patrick, Josef Schachtner, Michal Májek y Axel Jacobi von Wangelin. "Visible light-mediated photo-oxygenation of arylcyclohexenes". Organic Chemistry Frontiers 6, n.º 16 (2019): 2877–83. http://dx.doi.org/10.1039/c9qo00493a.

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38

Santamaría, Javier y Enrique Aguilar. "Beyond Fischer and Schrock carbenes: non-heteroatom-stabilized group 6 metal carbene complexes – a general overview". Organic Chemistry Frontiers 3, n.º 11 (2016): 1561–88. http://dx.doi.org/10.1039/c6qo00206d.

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39

Hearne, Zoë y Chao-Jun Li. "Palladium-catalysed atom-economical synthesis of conjugated dienals from terminal acetylenes and acrolein". Chemical Communications 53, n.º 45 (2017): 6136–39. http://dx.doi.org/10.1039/c7cc02767b.

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40

Iftikhar, Ramsha, Aqsa Mazhar, Muhammad Saqlain Iqbal, Faiza Zahid Khan, Syed Hassan Askary y Hifza Sibtain. "Ring forming transformations of ynamides via cycloaddition". RSC Advances 13, n.º 16 (2023): 10715–56. http://dx.doi.org/10.1039/d3ra00139c.

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41

Turrini, Nikolaus G., Răzvan C. Cioc, Daan J. H. van der Niet, Eelco Ruijter, Romano V. A. Orru, Mélanie Hall y Kurt Faber. "Biocatalytic access to nonracemic γ-oxo esters via stereoselective reduction using ene-reductases". Green Chemistry 19, n.º 2 (2017): 511–18. http://dx.doi.org/10.1039/c6gc02493a.

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42

Prasad, Sure Siva, Dirgha Raj Joshi, Jeong Hwa Lee y Ikyon Kim. "One-pot access to 2-amino-3-arylbenzofurans: direct entry to polyheterocyclic chemical space". Organic & Biomolecular Chemistry 18, n.º 40 (2020): 8119–40. http://dx.doi.org/10.1039/d0ob01715a.

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43

Lynch, Dylan M. y Eoin M. Scanlan. "Thiyl Radicals: Versatile Reactive Intermediates for Cyclization of Unsaturated Substrates". Molecules 25, n.º 13 (7 de julio de 2020): 3094. http://dx.doi.org/10.3390/molecules25133094.

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Sulfur centered radicals are widely employed in chemical synthesis, in particular for alkene and alkyne hydrothiolation towards thioether bioconjugates. The steadfast radical chain process that enables efficient hydrothiolation has been explored in the context of cascade reactions to furnish complex molecular architectures. The use of thiyl radicals offers a much cheaper and less toxic alternative to the archetypal organotin-based radical methods. This review outlines the development of thiyl radicals as reactive intermediates for initiating carbocyclization cascades. Key developments in cascade cyclization methodology are presented and applications for natural product synthesis are discussed. The review provides a chronological account of the field, beginning in the early seventies up to very recent examples; a span of almost 50 years.
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44

X. Xiang, Alan, Ricardo Lira, Konstantinos A. Agrios, Thomas Doundoulakis, Klaus B. Simonsen y Stephen E. Webber. "An Efficient Synthesis of (±)-Myxopyronin B via Versatile Pyridone Intermediates". HETEROCYCLES 68, n.º 6 (2006): 1099. http://dx.doi.org/10.3987/com-06-10733.

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45

Barcelo, Gérard, Jean-Pierre Senet y Gérard Sennyey. "1,2,2,2-Tetrachloroethyl Carbamates: Versatile Intermediates for the Synthesis ofN-Nitrosoureas". Synthesis 1987, n.º 11 (1987): 1027–29. http://dx.doi.org/10.1055/s-1987-28160.

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46

Dondoni, Alessandro y Alberto Marra. "Thiazolylketoses: a new class of versatile intermediates for glycoside synthesis". Chemical Communications, n.º 21 (1999): 2133–45. http://dx.doi.org/10.1039/a903758f.

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47

Maduli, Elvis J. M., Steven J. Edeson, Stephen Swanson, Panayiotis A. Procopiou y Joseph P. A. Harrity. "2-Iodoisatogens: Versatile Intermediates for the Synthesis of Nitrogen Heterocycles". Organic Letters 17, n.º 2 (23 de diciembre de 2014): 390–92. http://dx.doi.org/10.1021/ol503487f.

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48

Kataja, Antti O. y Géraldine Masson. "Imine and iminium precursors as versatile intermediates in enantioselective organocatalysis". Tetrahedron 70, n.º 46 (noviembre de 2014): 8783–815. http://dx.doi.org/10.1016/j.tet.2014.06.101.

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49

Wu, Chien-Hsin, Li-Yun Chen, Ru-Jong Jeng y Shenghong A. Dai. "100% Atom-Economy Efficiency of Recycling Polycarbonate into Versatile Intermediates". ACS Sustainable Chemistry & Engineering 6, n.º 7 (28 de mayo de 2018): 8964–75. http://dx.doi.org/10.1021/acssuschemeng.8b01326.

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50

Martin, Stephen F. y Michael P. Dwyer. "Iodocyclopropanes as versatile intermediates for the synthesis of substituted cyclopropanes". Tetrahedron Letters 39, n.º 12 (marzo de 1998): 1521–24. http://dx.doi.org/10.1016/s0040-4039(98)00072-0.

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