Bibliografías temáticas / Transition metal complexes

Literatura académica sobre el tema "Transition metal complexes"

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Publicado: 4 de junio de 2021
Última modificación: 7 de septiembre de 2023

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Artículos de revistas sobre el tema "Transition metal complexes"

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Denninger, U., J. J. Schneider, G. Wilke, R. Goddard, R. Krömer y C. Krüger. "Transition metal complexes". Journal of Organometallic Chemistry 459, n.º 1-2 (octubre de 1993): 349–57. http://dx.doi.org/10.1016/0022-328x(93)86088-y.

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Reinholdt, Anders y Jesper Bendix. "Transition Metal Carbide Complexes". Chemical Reviews 122, n.º 1 (19 de noviembre de 2021): 830–902. http://dx.doi.org/10.1021/acs.chemrev.1c00404.

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Zhou, Wei, Wen-Jie Pan, Jie Chen, Min Zhang, Jin-Hong Lin, Weiguo Cao y Ji-Chang Xiao. "Transition-metal difluorocarbene complexes". Chemical Communications 57, n.º 74 (2021): 9316–29. http://dx.doi.org/10.1039/d1cc04029d.

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Braunschweig, Holger, Rian D. Dewhurst y Viktoria H. Gessner. "Transition metal borylene complexes". Chemical Society Reviews 42, n.º 8 (2013): 3197. http://dx.doi.org/10.1039/c3cs35510a.

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Starodub, Vladimir A. y T. N. Starodub. "Isotrithionedithiolate transition metal complexes". Russian Chemical Reviews 80, n.º 9 (30 de septiembre de 2011): 829–53. http://dx.doi.org/10.1070/rc2011v080n09abeh004199.

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Ziessel, Raymond, Muriel Hissler, Abdelkrim El-ghayoury y Anthony Harriman. "Multifunctional transition metal complexes". Coordination Chemistry Reviews 178-180 (diciembre de 1998): 1251–98. http://dx.doi.org/10.1016/s0010-8545(98)00060-5.

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Brothers, Penelope J. y Warren R. Roper. "Transition-metal dihalocarbene complexes". Chemical Reviews 88, n.º 7 (noviembre de 1988): 1293–326. http://dx.doi.org/10.1021/cr00089a014.

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Cundari, Thomas R. "Transition metal imido complexes". Journal of the American Chemical Society 114, n.º 20 (septiembre de 1992): 7879–88. http://dx.doi.org/10.1021/ja00046a037.

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Hall, Chris y Robin N. Perutz. "Transition Metal Alkane Complexes†". Chemical Reviews 96, n.º 8 (enero de 1996): 3125–46. http://dx.doi.org/10.1021/cr9502615.

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Werner, H., D. Schneider y M. Schulz. "Vinylidene transition-metal complexes". Journal of Organometallic Chemistry 451, n.º 1-2 (junio de 1993): 175–82. http://dx.doi.org/10.1016/0022-328x(93)83024-p.

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Tesis sobre el tema "Transition metal complexes"

1

Barron, Andrew Ross. "Transition metal aluminohydride complexes". Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/37935.

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Jasim, Naseralla. "Transition metal bifluoride complexes". Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323538.

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Veighy, Clifford Robert. "Novel cyclopentadienyl transition metal complexes". Thesis, University of Southampton, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327366.

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Zard, P. W. "Transition metal complexes with pyrimidinethiones". Thesis, Imperial College London, 1988. http://hdl.handle.net/10044/1/47322.

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Johnson, Donald Martin. "Cyanoscorpionates and Transition Metal Complexes". Digital Commons @ East Tennessee State University, 2010. https://dc.etsu.edu/etd/1725.

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The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.
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Holder, Alan John. "Studies on transition metal macrocyclic complexes". Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10961.

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Cheung, Wai Man. "Transition metal complexes with dichalcogenoimidodiphosphinate ligands /". View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20CHEUNG.

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Redfern, C. M. "Electronic structure of transition metal complexes". Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.235094.

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Mobbs, B. E. "Arene transition metal complexes in synthesis". Thesis, University of Oxford, 1985. http://ora.ox.ac.uk/objects/uuid:4c7030d4-297e-4af8-a622-d5b4963fc0a3.

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This thesis deals with the applications of organopalladium and organochromium chemistry to the functionalisation of the benzopyran ring system, at a variety of oxidation levels. Section I demonstrates the functionalisation of 3-, 6-, and 8-bromochromones via palladium (0) insertion into the C-Br bond. The resultant arylpalladium species are shown to undergo addition to the least substituted end of a variety of olefins including methyl acrylate, acrylonitrile and styrene. Subsequent palladium-hydride elimination leads to overall palladium catalysed vinylation of the chromone and the synthesis of a number of novel compounds. Vinylation occurs regiospecifically at the site of chromone bromination and is shown to allow clean substituent introduction into each of the three sites. The palladium catalysed reaction of 3,6-dibromo-chromone with methyl acrylate leads to vinylation at both the C3 and C6 positions. Carbonylation of the 6-bromochromone in ethanol or butanol leads to the 6-ethyl or 6-butyl esters respectively. The palladium catalysed vinylation of the 6-bromochromone with ethyl vinyl ether leads to a mixture of products from addition of the chromone to either end of the olefin. With p-bromophenol or p-bromo-N,N-dimethylaniline the reaction gives exclusively the acetylated product arising from addition to the more substituted end of the olefin. This change in orientation is rationalised by considering the polarisation of the olefin and the arylpalladium species. Section II demonstrates the functionalisation of chroman and 4-chromanol via coordination to the Cr(CO)3 moiety. (η6-Chroman)Cr(CO)3 is synthesised and is shown to undergo regiospecific ring deprotonation at C8 under kinetic conditions or regiospecific benzylic deprotonation at C4 under thermodynamic conditions. The resultant anions are quenched with alkyl halides, aldehydes, Eschenmoser's salt and methyl disulphide resulting in selective functionalisation of either site. No mixed products are observed. The uncomplexed arene is shown to be totally unreactive under identical conditions. (η6-4-Chromanol)Cr(CO)3 is synthesised and is shown to undergo regiospecific C8 ring deprotonation by comparison with authentic samples of the C5 and C8 methylated alcohols. Protection of the hydroxyl group as its methyl, t-butyldimethylsilyl or methoxymethyl ethers is found not to alter the regiochemistry of deprotonation. The 4-chromanol t-butyldimethylsilyl and tri-i-propylsilyl ethers are synthesised and coordinated to the metal unit. Cleavage of the silyl ethers is shown to proceed with loss of stereochemistry, indicating C-0 bond cleavage.
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Bridgewater, Brian Michael. "Sterically hindered chiral transition metal complexes". Thesis, Durham University, 1998. http://etheses.dur.ac.uk/5022/.

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This thesis describes the synthesis, characterization and study of a series of organometallic compounds which all contain the same new ligand, l-phenyl-3-methyl-4,5,6,7-tetrahydroindenyl. The ligand forms a chiral complex once coordinated, and is relatively bulky when compared with ligands such as cyclopentadienyl or 4,5,6,7-tetrahydroindenyl.Chapter one of this thesis introduces cyclopentadienyl ligand chirality, cyclopentadienyl metal complex chirality and sterically demanding cyclopentadienyl systems. The synthesis and chemistry of tetrahydroindenes and some applications of chiral cyclopentadienyl metal complexes and their bulky analogues are also reviewed. Chapter two describes modifications to a literature preparation of the tetrahydroindenone precursor of the new tetrahydroindenyl ligand which lead to higher yields. The synthesis of the ligand itself is described, as well as the synthesis of a benzylidene-substituted hexahydroindene, which demonstrates a limitation in the flexibility of the synthetic route chosen. The synthesis, characterization and various properties of the following iron(II) compounds are discussed in chapter two; bis-l-phenyl-3-methyl- 4,5,6,7-tetrahydroindenyl iron (II), 2.3, l-phenyl-3-methyl-4,5,6,7-tetrahydroindenyl iron(II) dicarbonyl dimer, 2.4, and l-phenyl-3-methyl-4,5,6,7-tetrahydroindaiyl methyl dicarbonyl iron(II), 2.5. For all these iron complexes, the solid state molecular structures and the absolute configuration of the chiral ligand were determined using single crystal X-ray d iffraction. For 23 and 2.4, three isomers are possible, two enantiomers that are collectively termed the rac-isomer and a third isomer, the meso- isomer. Cyclic voltammetric studies on 2.3 indicate that it has a reversible one electron oxidation at 0.187 V (with respect to a non-aqueous Ag/AgCl standard electrode). The difference between this and the reversible one electron oxidation for (η-C(_5)H(_5))(_2)Fe (with respect to the same standard) is -0.314 V, therefore 2.3 is shown to be much more easily oxidized than (η-C(_5)H(_5))(_2)Fe. The solution-state infi-a-red spectrum of 2.4 is explained, with reference to a literature analysis of the unsubstituted analogue [CpFe(CO)(_2)](_2). The steric forces present in the various molecular environments are discussed in connection with the degree of phenyl-ring tilt relative to the cyclopentadienyl mean plane and the deviation of the other cyclopentadimyl substituents away from the metal centre. Subsequent reactions of compounds 2.4 and 2.5 are described. Attempts to make linked analogues of the new ligand are summarized in chapter two. In chapter three, two Zr(rV) compounds are prepared, bis (l-phenyl-3-methyl-4,5,6,7-tetrahydroindenyi) zirconium(fV) dichloride, 3.1, and bis (l-phenyl-3-methyl-4,5,6,7-tetrahydroindenyl) dimethyl zirconium(TV), 3.2. Upon crystallization, rac-3.1 spontaneously resolves into crystals containing only one enantiomer. The similarities and differences in the spectroscopic data for the iron(n) compounds of chapter two and the zirconium(IV) compounds of chapter three are discussed and possible explanations offered . The solid state molecular structures of 3.1 and 3.2 were determined by single crystal X-ray diffraction. Experimental details are given in chapter four, whilst the characterizing data are presented in chapter five. Details of the X-ray structure determinations are given in Appendix A.
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Libros sobre el tema "Transition metal complexes"

1

Nishibayashi, Yoshiaki, ed. Transition Metal-Dinitrogen Complexes. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527344260.

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Kreißl, F. R., ed. Transition Metal Carbyne Complexes. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4.

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Yam, Vivian W. W., ed. Photofunctional Transition Metal Complexes. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-36810-6.

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NATO Advanced Research Workshop on Transition Metal Carbyne Complexes (1992 Kreuth, Germany). Transition metal carbyne complexes. Dordrecht: Kluwer Academic, 1993.

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W, Yam Vivian W. y Balch Alan L, eds. Photofunctional transition metal complexes. Berlin: Springer Verlag, 2007.

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Qiu, Zaozao. Late Transition Metal-Carboryne Complexes. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-24361-5.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Hoboken, N.J: Wiley, 2009.

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Jean, Yves. Molecular orbitals of transition metal complexes. Oxford: Oxford University Press, 2005.

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Kettle, Sidney. The theory of transition metal complexes. London: Royal Society of Chemistry. Educational Techniques Group Trust, 1994.

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Dahl, Jens Peder, P. Day y D. M. P. Mingos. Molecular electronic structures of transition metal complexes. Heidelberg: Springer, 2012.

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Capítulos de libros sobre el tema "Transition metal complexes"

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Hendrickson, David N., David M. Adams, Chi-Cheng Wu y Sheila M. J. Aubin. "Bistable Transition Metal Complexes". En Magnetism: A Supramolecular Function, 357–82. Dordrecht: Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-015-8707-5_19.

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Atwood, David A. "(II) Transition Metal Complexes". En Inorganic Reactions and Methods, 176. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch169.

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Harrod, John F. y Bruce Arndtsen. "Transition Metal Hydride Complexes". En Inorganic Reactions and Methods, 337–41. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch238.

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Farrell, Nicholas. "Metals, Metal Complexes, and Radiation". En Transition Metal Complexes as Drugs and Chemotherapeutic Agents, 183–207. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-011-7568-5_9.

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Huang, Xin y Zhengyang Lin. "Transition Metal Catalyzed Borations". En Catalysis by Metal Complexes, 189–212. Boston, MA: Springer US, 2002. http://dx.doi.org/10.1007/0-306-47718-1_8.

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Raubenheimer, H. G., S. Cronje, R. Otte, W. Zyl, I. Taljaard y P. Olivier. "Towards the Synthesis of Carbine Complexes of Gold and Copper: New Carbene Complexes". En Transition Metal Carbyne Complexes, 169–73. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_21.

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Seino, Hidetake y Yuji Kajita. "Group 4 Transition Metal-Dinitrogen Complexes". En Transition Metal-Dinitrogen Complexes, 79–158. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527344260.ch2.

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Duman, Leila M. y Lawrence R. Sita. "Group 5 Transition Metal-Dinitrogen Complexes". En Transition Metal-Dinitrogen Complexes, 159–220. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527344260.ch3.

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Mézailles, Nicolas. "Group 6 Transition Metal-Dinitrogen Complexes". En Transition Metal-Dinitrogen Complexes, 221–69. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527344260.ch4.

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Piascik, Adam D. y Andrew E. Ashley. "Group 8 Transition Metal-Dinitrogen Complexes". En Transition Metal-Dinitrogen Complexes, 285–335. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527344260.ch6.

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Actas de conferencias sobre el tema "Transition metal complexes"

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Lee, Taewoo, Christian Reich, Christopher M. Laperle, Xiaodi Li, Margaret Grant, Christoph G. Rose-Petruck y Frank Benesch-Lee. "Ultrafast XAFS of transition metal complexes". En International Conference on Ultrafast Phenomena. Washington, D.C.: OSA, 2006. http://dx.doi.org/10.1364/up.2006.wd4.

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Slinker, Jason, Dan Bernards, Samuel Flores-Torres, Stefan Bernhard, Paul L. Houston, Héctor D. Abruña y George G. Malliaras. "Light emitting diodes from transition metal complexes". En Frontiers in Optics. Washington, D.C.: OSA, 2003. http://dx.doi.org/10.1364/fio.2003.wnn2.

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Latouche, Camille, Vincenzo Barone y Julien Bloino. "ANHARMONIC VIBRATIONAL SPECTROSCOPY ON METAL TRANSITION COMPLEXES". En 69th International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2014. http://dx.doi.org/10.15278/isms.2014.rc08.

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Xu, Wenying, James N. Demas y Benjamin A. DeGraff, Jr. "Highly luminescent transition metal complexes as sensors". En OE/LASE '94, editado por James A. Harrington, David M. Harris, Abraham Katzir y Fred P. Milanovich. SPIE, 1994. http://dx.doi.org/10.1117/12.180739.

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Petrović, Biljana. "TRANSITION METAL ION COMPLEXES AS POTENTIAL ANTITUMOR AGENTS". En 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac,, 2021. http://dx.doi.org/10.46793/iccbi21.009p.

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Discovery of the antitumor activity of platinum complex, cisplatin, cis-Pt(NH3)2Cl2, and later carboplatin and oxaliplatin, led to the intensive investigation of the potential antitumor activity of the huge number of platinum complexes. Furthermore, it is well-known that platinum complexes express toxicity, numerous side effects and resistance, so the scientists make a lot of efforts to synthetize, beside Pt(II) and Pt(IV), other non-platinum compounds with potential antitumor activity, such as Pd(II), Ru(II/III) and Au(III) complexes. The goal of this study is to summarize the results of the investigation of the interactions between some mononuclear, homo- and hetero-polynuclear Pt(II), Pd(II), Ru(II/III) and Au(III) complexes with different sulfur- and nitrogen-donor biologically relevant nucleophiles. Among mononuclear complexes, the compounds with aromatic terpy (tepyridine) or bpma (bis-(2- pyridylmethyl)amine) and aliphatic dien (diethylentriamine) nitrogen-containing inert ligands were studied. Different homo- and hetero-polynuclear complexes with pz (pyrazine) or 4,4’-bipy (4,4’- bipyridine) as bridging and mostly en (ethylenediamine), bipy (2,2’-bipyridine) and dach (trans-1,2- diaminocyclohexane) as inert ligands were studied as well. The research was focused on the connection between the structure and the mechanisms of interactions with different biomolecules, such as L- cysteine (L-Cys), L-methionine (L-Met), tripeptide glutathione (GSH), guanosine-5’-monophosphate (5’-GMP), DNA and bovine serum albumin (BSA). Some of these complexes were selected for in vitro studies of the cytotoxicity on different tumor cell lines. Observed results contribute a lot as a guidance for the future design and determination of the structure-activity relationship (SAR) of different transition metal ion complexes.
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Malliaras, George G. "Light Emitting Devices from Ionic Transition Metal Complexes". En Frontiers in Optics. Washington, D.C.: OSA, 2005. http://dx.doi.org/10.1364/fio.2005.smb3.

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Chi-Chiu, Ko, Han Jingqi, Cheng Shun-Cheung y Ng Chi-On. "SSpectroscopic study on luminescent mechanochromic transition metal complexes". En Asian Spectroscopy Conference 2020. Institute of Advanced Studies, Nanyang Technological University, 2020. http://dx.doi.org/10.32655/asc_8-10_dec2020.13.

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Demas, J. N. y B. A. DeGraff. "Design Of Transition Metal Complexes As Luminescence Probes". En OE/FIBERS '89, editado por Robert A. Lieberman y Marek T. Wlodarczyk. SPIE, 1990. http://dx.doi.org/10.1117/12.963191.

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Pietschnig, Rudolf, Carmen Moser, Stefan Spirk y Sven Schäfer. "Synthesis and Structure of Transition Metal Bisalkinylselenolato Complexes". En The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01518.

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Crosby, G. A., K. J. Jordan y G. R. Gamble. "Designing Energy Migration Barriers Into Transition-Metal Complexes". En 1988 Los Angeles Symposium--O-E/LASE '88, editado por E. R. Menzel. SPIE, 1988. http://dx.doi.org/10.1117/12.945458.

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Informes sobre el tema "Transition metal complexes"

1

White, Carter James. Selenophene transition metal complexes. Office of Scientific and Technical Information (OSTI), julio de 1994. http://dx.doi.org/10.2172/10190649.

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Sharp, P. R. Late transition metal oxo and imido complexes. Office of Scientific and Technical Information (OSTI), diciembre de 1992. http://dx.doi.org/10.2172/7017245.

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Sharp, P. R. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), enero de 1990. http://dx.doi.org/10.2172/6332549.

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Sharp, P. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), enero de 1990. http://dx.doi.org/10.2172/7003275.

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Norton, Jack. The Activation of Hydrogen by First-Row Transition-Metal Complexes. Office of Scientific and Technical Information (OSTI), marzo de 2020. http://dx.doi.org/10.2172/1604425.

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Du, Guodong. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes. Office of Scientific and Technical Information (OSTI), enero de 2003. http://dx.doi.org/10.2172/835301.

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Krishnan Balasubramanian. Electronic Structure of Transition Metal Clusters, Actinide Complexes and Their Reactivities. Office of Scientific and Technical Information (OSTI), julio de 2009. http://dx.doi.org/10.2172/959347.

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Meyer, T. J. Excited state processes in transition metal complexes: Redox splitting in soluble polymers. Office of Scientific and Technical Information (OSTI), marzo de 1992. http://dx.doi.org/10.2172/5573491.

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Meyer, T. J. y J. M. Papanikolas. Excited State Processes in Transition Metal Complexes, Redox Splitting in Soluble Polymers. Office of Scientific and Technical Information (OSTI), agosto de 2002. http://dx.doi.org/10.2172/830013.

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Schmehl, Russell H. Energy, Electron Transfer and Photocatalytic Reactions of Visible Light Absorbing Transition Metal Complexes. Office of Scientific and Technical Information (OSTI), marzo de 2016. http://dx.doi.org/10.2172/1240023.

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