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Artículos de revistas sobre el tema "Thermochemistry - Chemical Hydrogen Storage"

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Autor: Grafiati

Publicado: 7 de septiembre de 2023

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1

Ja'o, Aliyu M., Derek A. Wann, Conor D. Rankine, Matthew I. J. Polson y Sarah L. Masters. "Utilizing the Combined Power of Theory and Experiment to Understand Molecular Structure – Solid-State and Gas-Phase Investigation of Morpholine Borane". Australian Journal of Chemistry 73, n.º 8 (2020): 794. http://dx.doi.org/10.1071/ch19492.

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The molecular structure of morpholine borane complex has been studied in the solid state and gas phase using single-crystal X-ray diffraction, gas electron diffraction, and computational methods. Despite both the solid-state and gas-phase structures adopting the same conformation, a definite decrease in the B–N bond length of the solid-state structure was observed. Other structural variations in the different phases are presented and discussed. To explore the hydrogen storage potential of morpholine borane, the potential energy surface for the uncatalyzed and BH3-catalyzed pathways, as well as the thermochemistry for the hydrogen release reaction, were investigated using accurate quantum chemical methods. It was observed that both the catalyzed and uncatalyzed dehydrogenation pathways are favourable, with a barrier lower than the B–N bond dissociation energy, thus indicating a strong propensity for the complex to release a hydrogen molecule rather than dissociate along the B–N bond axis. A minimal energy requirement for the dehydrogenation reaction has been shown. The reaction is close to thermoneutral as demonstrated by the calculated dehydrogenation reaction energies, thus implying that this complex could demonstrate potential for future on-board hydrogen generation.

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2

Chen, Yuzhu y Meng Lin. "(Digital Presentation) Photo-Thermo-Electrochemical Cells for on-Demand Solar Power and Hydrogen Generation". ECS Meeting Abstracts MA2022-01, n.º 36 (7 de julio de 2022): 1560. http://dx.doi.org/10.1149/ma2022-01361560mtgabs.

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Converting solar energy into power and hydrogen provides a promising pathway to fulfilling instantaneous electricity demand (power generation) as well as continuous demand via storing energy in chemical bonds (hydrogen generation). Co-generation of power and hydrogen is of great interest due to its potential to overcome expensive electricity storage in conventional PV plus battery systems. Both solar thermochemistry processes and photo-electrochemical cells (PECs) are extensively explored technologies to produce solar hydrogen. The key challenges for solar thermochemistry processes are extremely high operating temperature (~ 1500 oC) and low demonstrated efficiency (< 1% for hydrogen generation). For PECs, the limited solar absorption together with sluggish electrochemical reactions, especially for OER, leads to limited theoretical solar fuel generation. Operating PECs at high temperature will lead to decreased photovoltage and interface stability. Inspired by the thermally regenerative batteries, we propose a photo-thermo-electrochemical (PTEC) device that uses the solid oxide-based moderate high temperature cell (~1000 ℃) as the photo-absorber for simultaneously converting concentrated solar radiation into heat and generating fuel or power electrochemically driven by the discharging power from the low temperature cell (~700 ℃). PTEC device enables full solar spectrum utilization, highly favorable thermodynamics and kinetics, and cost-effectiveness. A continuous PTEC device has two working modes, which are voltage differential (VD) mode and current differential (CD) mode. The current-voltage characteristics of a PTEC device are shown in Figure 1. It mainly consists of five parts. A high temperature cell (HTC) serves as a solar absorber and a low temperature cell (LTC) serves as heat recovery. Besides, the opposite electrochemical reactions take place in two cells meaning that HTC and LTC can also function as a hydrogen production as well as an electricity generator component, respectively. Heat exchanger(s) is placed between the HTC and LTC and hot fluids pass through a heat exchanger before entering LTC to reduce heat losses to environment as well as reducing input solar energy. The VD mode and CD mode can be realized in PTECs via controlling of DC-DC converter. In order to identify the main parameters, we develop a multi-physics model based on finite element method, including mass, heat and charge transfer, and electrochemical reactions. In addition, heat exchange is modeled by solving energy balance equation, DC-DC convertor is assumed by constant efficiency, and a lumped parameter model is used to describe solar receiver including energy losses of conduction and reradiation. This framework also allows us to provide design guidelines for PTEC devices with high solar-to-electricity (STE) efficiency and solar-to-hydrogen (STH) efficiency. The maximum STE and STH efficiency under reference conditions of PTEC device was found to be 4 % and 2 %. A further improved performance in terms of STE and STH efficiency are about 19 % and 16 %, respectively, via optimizing temperature configuration between HTC and LTC and material properties. It is also interesting to note that STH can reach higher than 80 % of STE at a large temperature difference, which shows a promising energy storage device by storing excessive electrical power in form of hydrogen. The main results show that the temperature of HTC and efficiency of heat exchange are key parameters to optimize PTEC efficiency. The performance of DC-DC convertor dominates STH efficiency. Besides, ionic conductivity of electrolyte can contribute to significantly expanding the operating current density range. The PTEC is a promising technology for solar energy conversion and storage as it is able to produce electricity and hydrogen in a single device. The solar conversion efficiency predicted with our numerical model supports that by optimizing the design and operational conditions, this technology can compete with existing solar fuel pathways. Figure 1

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3

Verevkin, Sergey P., Maria E. Konnova, Kseniya V. Zherikova y Aleksey A. Pimerzin. "Sustainable hydrogen storage: Thermochemistry of amino-alcohols as seminal liquid organic hydrogen carriers". Journal of Chemical Thermodynamics 163 (diciembre de 2021): 106591. http://dx.doi.org/10.1016/j.jct.2021.106591.

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4

Wong, Bryan M., David Lacina, Ida M. B. Nielsen, Jason Graetz y Mark D. Allendorf. "Thermochemistry of Alane Complexes for Hydrogen Storage: A Theoretical and Experimental Investigation". Journal of Physical Chemistry C 115, n.º 15 (30 de marzo de 2011): 7778–86. http://dx.doi.org/10.1021/jp112258s.

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5

Wong, Hsi-Wu, Juan Carlos Alva Nieto, Mark T. Swihart y Linda J. Broadbelt. "Thermochemistry of Silicon−Hydrogen Compounds Generalized from Quantum Chemical Calculations". Journal of Physical Chemistry A 108, n.º 5 (febrero de 2004): 874–97. http://dx.doi.org/10.1021/jp030727k.

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6

Miyaoka, Hiroki, Takayuki Ichikawa y Yoshitsugu Kojima. "Chemical Hydrogen Storage of Carbon Material". Journal of the Japan Institute of Metals and Materials 77, n.º 12 (2013): 552–58. http://dx.doi.org/10.2320/jinstmet.jc201301.

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7

Yang, Xinchun, Dmitri A. Bulushev, Jun Yang y Quan Zhang. "New Liquid Chemical Hydrogen Storage Technology". Energies 15, n.º 17 (31 de agosto de 2022): 6360. http://dx.doi.org/10.3390/en15176360.

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The liquid chemical hydrogen storage technology has great potentials for high-density hydrogen storage and transportation at ambient temperature and pressure. However, its commercial applications highly rely on the high-performance heterogeneous dehydrogenation catalysts, owing to the dehydrogenation difficulty of chemical hydrogen storage materials. In recent years, the chemists and materials scientists found that the supported metal nanoparticles (MNPs) can exhibit high catalytic activity, selectivity, and stability for the dehydrogenation of chemical hydrogen storage materials, which will clear the way for the commercial application of liquid chemical hydrogen storage technology. This review has summarized the recent important research progress in the MNP-catalyzed liquid chemical hydrogen storage technology, including formic acid dehydrogenation, hydrazine hydrate dehydrogenation and ammonia borane dehydrogenation, discussed the urgent challenges in the key field, and pointed out the future research trends.

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8

Cheng, Gongzhen, Cheng Du, Wei Luo y Xiuze Hei. "formic acid for chemical hydrogen storage". SCIENTIA SINICA Chimica 46, n.º 5 (1 de mayo de 2016): 487–95. http://dx.doi.org/10.1360/n032015-00232.

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9

Tan, Yingbin y Xuebin Yu. "Chemical regeneration of hydrogen storage materials". RSC Advances 3, n.º 46 (2013): 23879. http://dx.doi.org/10.1039/c3ra44103b.

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10

Yadav, Mahendra y Qiang Xu. "Liquid-phase chemical hydrogen storage materials". Energy & Environmental Science 5, n.º 12 (2012): 9698. http://dx.doi.org/10.1039/c2ee22937d.

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11

Vajo, John J. y Gregory L. Olson. "Hydrogen storage in destabilized chemical systems". Scripta Materialia 56, n.º 10 (mayo de 2007): 829–34. http://dx.doi.org/10.1016/j.scriptamat.2007.01.002.

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12

Matus, Myrna H., Kevin D. Anderson, Donald M. Camaioni, S. Thomas Autrey y David A. Dixon. "Reliable Predictions of the Thermochemistry of Boron−Nitrogen Hydrogen Storage Compounds: BxNxHy,x= 2, 3". Journal of Physical Chemistry A 111, n.º 20 (mayo de 2007): 4411–21. http://dx.doi.org/10.1021/jp070931y.

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13

Verevkin, Sergey P., Irina V. Andreeva, Maria E. Konnova, Svetlana V. Portnova, Kseniya V. Zherikova y Aleksey A. Pimerzin. "Paving the way to the sustainable hydrogen storage: Thermochemistry of amino-alcohols as precursors for liquid organic hydrogen carriers". Journal of Chemical Thermodynamics 163 (diciembre de 2021): 106610. http://dx.doi.org/10.1016/j.jct.2021.106610.

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14

Moury, Romain, Umit B. Demirci, Takayuki Ichikawa, Yaroslav Filinchuk, Rodica Chiriac, Arie van der Lee y Philippe Miele. "Sodium Hydrazinidoborane: A Chemical Hydrogen-Storage Material". ChemSusChem 6, n.º 4 (27 de febrero de 2013): 667–73. http://dx.doi.org/10.1002/cssc.201200800.

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15

Eberle, Ulrich, Michael Felderhoff y Ferdi Schüth. "Chemical and Physical Solutions for Hydrogen Storage". Angewandte Chemie International Edition 48, n.º 36 (24 de agosto de 2009): 6608–30. http://dx.doi.org/10.1002/anie.200806293.

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16

Moussa, Georges, Romain Moury, Umit B. Demirci, Tansel Şener y Philippe Miele. "Boron-based hydrides for chemical hydrogen storage". International Journal of Energy Research 37, n.º 8 (2 de marzo de 2013): 825–42. http://dx.doi.org/10.1002/er.3027.

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17

RITTER, STEVE. "HYDROGEN STORAGE GETS A BOOST". Chemical & Engineering News 85, n.º 1 (enero de 2007): 11. http://dx.doi.org/10.1021/cen-v085n001.p011.

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18

Strobel, Timothy A., Yongkwan Kim, Gary S. Andrews, Jack R. Ferrell III, Carolyn A. Koh, Andrew M. Herring y E. Dendy Sloan. "Chemical−Clathrate Hybrid Hydrogen Storage: Storage in Both Guest and Host". Journal of the American Chemical Society 130, n.º 45 (12 de noviembre de 2008): 14975–77. http://dx.doi.org/10.1021/ja805492n.

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19

Singh, Sanjay Kumar, Xin-Bo Zhang y Qiang Xu. "Room-Temperature Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage". Journal of the American Chemical Society 131, n.º 29 (29 de julio de 2009): 9894–95. http://dx.doi.org/10.1021/ja903869y.

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20

Jiang, Hai-Long, Sanjay Kumar Singh, Jun-Min Yan, Xin-Bo Zhang y Qiang Xu. "Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions". ChemSusChem 3, n.º 5 (8 de abril de 2010): 541–49. http://dx.doi.org/10.1002/cssc.201000023.

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21

Subrahmanyam, K. S., P. Kumar, U. Maitra, A. Govindaraj, K. P. S. S. Hembram, U. V. Waghmare y C. N. R. Rao. "Chemical storage of hydrogen in few-layer graphene". Proceedings of the National Academy of Sciences 108, n.º 7 (31 de enero de 2011): 2674–77. http://dx.doi.org/10.1073/pnas.1019542108.

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22

Wagemans, Rudy W. P., Joop H. van Lenthe, Petra E. de Jongh, A. Jos van Dillen y Krijn P. de Jong. "Hydrogen Storage in Magnesium Clusters: Quantum Chemical Study". Journal of the American Chemical Society 127, n.º 47 (noviembre de 2005): 16675–80. http://dx.doi.org/10.1021/ja054569h.

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23

Otsuka, K., T. Kaburagi, C. Yamada y S. Takenaka. "Chemical storage of hydrogen by modified iron oxides". Journal of Power Sources 122, n.º 2 (julio de 2003): 111–21. http://dx.doi.org/10.1016/s0378-7753(03)00398-7.

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24

Lang, Chengguang, Yi Jia y Xiangdong Yao. "Recent advances in liquid-phase chemical hydrogen storage". Energy Storage Materials 26 (abril de 2020): 290–312. http://dx.doi.org/10.1016/j.ensm.2020.01.010.

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25

Wahab, M. A., Huijun Zhao y X. D. Yao. "Nano-confined ammonia borane for chemical hydrogen storage". Frontiers of Chemical Science and Engineering 6, n.º 1 (9 de febrero de 2012): 27–33. http://dx.doi.org/10.1007/s11705-011-1171-3.

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26

Umegaki, Tetsuo, Jun-Min Yan, Xin-Bo Zhang, Hiroshi Shioyama, Nobuhiro Kuriyama y Qiang Xu. "Boron- and nitrogen-based chemical hydrogen storage materials". International Journal of Hydrogen Energy 34, n.º 5 (marzo de 2009): 2303–11. http://dx.doi.org/10.1016/j.ijhydene.2009.01.002.

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27

van Hassel, Bart A., Randolph C. McGee, Allen Murray y Shiling Zhang. "Engineering technologies for fluid chemical hydrogen storage system". Journal of Alloys and Compounds 645 (octubre de 2015): S41—S45. http://dx.doi.org/10.1016/j.jallcom.2015.01.241.

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28

Safronov, Alexander V., Satish S. Jalisatgi, Han Baek Lee y M. Frederick Hawthorne. "Chemical hydrogen storage using polynuclear borane anion salts". International Journal of Hydrogen Energy 36, n.º 1 (enero de 2011): 234–39. http://dx.doi.org/10.1016/j.ijhydene.2010.08.120.

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29

Guardamagna, Cristina, Andrea Cavallari, Veronica Malvaldi, Silvia Soricetti, Alberto Pontarollo, Bernardo Molinas, Diego Andreasi et al. "Innovative Systems for Hydrogen Storage". Advances in Science and Technology 72 (octubre de 2010): 176–81. http://dx.doi.org/10.4028/www.scientific.net/ast.72.176.

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One of the main challenges in the perspective of a hydrogen economy is the development of a storage system both safe and with high weight capacity. Among the most promising systems are the storage in metals and chemical hydrides and the high pressure storage in tanks made of composite materials. Both these technologies allow volumetric densities equal or higher than that of liquid hydrogen. The present work deals with the results obtained in a Italian national project, whose objectives have been the development of innovative technologies in specific applications: large scale energy storage, stationary applications in distributed generation, and automotive (with a particular attention to the fluvial and the sea transportation in protected areas). The theoretical, modellistic and experimental activities have been oriented to the development of innovative high capacity metal hydrides, the study of a regeneration method for chemical hydrides, the integration of intermediate pressure electrolyzers with advanced compressors and, finally, the development of thermomechanical models for executive design of storage systems. A number of prototypes has been realised and installed in a test facility in the Fusina (Venezia) power plant. The activity has been completed with an executive feasibility evaluation, in the perspective of industrial applications.

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30

Zhang, Xiaoqing, Bingqing Xu, Yan Xu, Shuyong Shang y Yongxiang Yin. "Research of Hydrogen Preparation with Catalytic Steam-Carbon Reaction Driven by Photo-Thermochemistry Process". International Journal of Chemical Engineering 2013 (2013): 1–7. http://dx.doi.org/10.1155/2013/870384.

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An experiment of hydrogen preparation from steam-carbon reaction catalyzed by K2CO3was carried out at 700°C, which was driven by the solar reaction system simulated with Xenon lamp. It can be found that the rate of reaction with catalyst is 10 times more than that without catalyst. However, for the catalytic reaction, there is no obvious change for the rate of hydrogen generation with catalyst content range from 10% to 20%. Besides, the conversion efficiency of solar energy to chemical energy is more than 13.1% over that by photovoltaic-electrolysis route. An analysis to the mechanism of catalytic steam-carbon reaction with K2CO3is given, and an explanation to the nonbalanced [H2]/[CO + 2CO2] is presented, which is a phenomenon usually observed in experiment.

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31

Hu, Lin, Rui-hua Nan, Jian-ping Li, Ling Gao y Yu-jing Wang. "Phase Transformation and Hydrogen Storage Properties of an La7.0Mg75.5Ni17.5 Hydrogen Storage Alloy". Crystals 7, n.º 10 (18 de octubre de 2017): 316. http://dx.doi.org/10.3390/cryst7100316.

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32

Ayar, Barış y Muhammed Bora Akın. "Hydrogen Production and Storage Methods". International Journal of Advanced Natural Sciences and Engineering Researches 7, n.º 4 (10 de mayo de 2023): 179–85. http://dx.doi.org/10.59287/ijanser.647.

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Conventional fuels are not renewable resources and are getting depleted day by day. In addition, the by-products of the combustion of these fuels cause environmental problems. This situation, which threatens the world, has led to the search for new energy sources. Hydrogen, as an energy carrier, creates a potential for solving these problems. Hydrogen is the most abundant element in the universe, with the highest energy content per weight of all conventional fuels. But unlike conventional fuels, hydrogen is not easily found in nature and is produced from primary energy sources. Therefore, it is a renewable fuel. When used in a fuel cell, only water is produced as a by-product. From this point of view, when compared to any fuel, it stands out as a fuel with the highest energy content and does not contain carbon. The biggest problem in using hydrogen gas as a fuel is that it is not found in nature and economically cheap production methods are needed. Hydrogen can be produced in two different ways, biological and chemical. Chemical methods are not preferred because they are costly. Biological methods, on the other hand, are low-cost, sustainable, environmentally friendly methods. In this study, information of hydrogen energy and its historical development is given. Thus, a projection is made for the importance and future of hydrogen energy. Then, hydrogen production methods are explained and compared. In addition, information about hydrogen storage types is given.

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33

Rufford, T. E., Z. H. Zhu y G. Q. Lu. "Technology Options for Onboard Hydrogen Storage". Developments in Chemical Engineering and Mineral Processing 14, n.º 1-2 (15 de mayo de 2008): 85–99. http://dx.doi.org/10.1002/apj.5500140107.

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34

Singh, Ashish Kumar, Suryabhan Singh y Abhinav Kumar. "Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system". Catalysis Science & Technology 6, n.º 1 (2016): 12–40. http://dx.doi.org/10.1039/c5cy01276g.

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35

Li, Pei-Zhou y Qiang Xu. "Metal-Nanoparticle Catalyzed Hydrogen Generation from Liquid-Phase Chemical Hydrogen Storage Materials". Journal of the Chinese Chemical Society 59, n.º 10 (9 de agosto de 2012): 1181–89. http://dx.doi.org/10.1002/jccs.201200033.

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36

Hartman, Miloslav, Karel Svoboda, Bohumír Čech, Michael Pohořelý y Michal Šyc. "Decomposition of Potassium Hydrogen Carbonate: Thermochemistry, Kinetics, and Textural Changes in Solids". Industrial & Engineering Chemistry Research 58, n.º 8 (4 de febrero de 2019): 2868–81. http://dx.doi.org/10.1021/acs.iecr.8b06151.

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37

Joó, Ferenc. "Breakthroughs in Hydrogen Storage-Formic Acid as a Sustainable Storage Material for Hydrogen". ChemSusChem 1, n.º 10 (24 de octubre de 2008): 805–8. http://dx.doi.org/10.1002/cssc.200800133.

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38

Fakirov, S. "Hydrogen storage and polymers". Express Polymer Letters 11, n.º 3 (2017): 162. http://dx.doi.org/10.3144/expresspolymlett.2017.17.

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39

Semelsberger, Troy, Jason Graetz, Andrew Sutton y Ewa C. E. Rönnebro. "Engineering Challenges of Solution and Slurry-Phase Chemical Hydrogen Storage Materials for Automotive Fuel Cell Applications". Molecules 26, n.º 6 (19 de marzo de 2021): 1722. http://dx.doi.org/10.3390/molecules26061722.

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We present the research findings of the DOE-funded Hydrogen Storage Engineering Center of Excellence (HSECoE) related to liquid-phase and slurry-phase chemical hydrogen storage media and their potential as future hydrogen storage media for automotive applications. Chemical hydrogen storage media other than neat liquid compositions will prove difficult to meet the DOE system level targets. Solid- and slurry-phase chemical hydrogen storage media requiring off-board regeneration are impractical and highly unlikely to be implemented for automotive applications because of the formidable task of developing solid- or slurry-phase transport systems that are commercially reliable and economical throughout the entire life cycle of the fuel. Additionally, the regeneration cost and efficiency of chemical hydrogen storage media is currently the single most prohibitive barrier to implementing chemical hydrogen storage media. Ideally, neat liquid-phase chemical hydrogen storage media with net-usable gravimetric hydrogen capacities of greater than 7.8 wt% are projected to meet the 2017 DOE system level gravimetric and volumetric targets. The research presented herein is a collection of research findings that do not in and of themselves warrant a dedicated manuscript. However, the collection of results do, in fact, highlight the engineering challenges and short-comings in scaling up and demonstrating fluid-phase ammonia borane and alane compositions that all future materials researchers working in hydrogen storage should be aware of.

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40

Makaryan, I. A., I. V. Sedov y A. L. Maksimov. "Hydrogen Storage Using Liquid Organic Carriers". Russian Journal of Applied Chemistry 93, n.º 12 (diciembre de 2020): 1815–30. http://dx.doi.org/10.1134/s1070427220120034.

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41

Biris, A. R., D. Lupu, E. Dervishi, Z. Li, V. Saini, D. Saini, S. Trigwell, M. K. Mazumder, R. Sharma y A. S. Biris. "Hydrogen Storage in Carbon-Based Nanostructured Materials". Particulate Science and Technology 26, n.º 4 (29 de julio de 2008): 297–305. http://dx.doi.org/10.1080/02726350802084051.

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42

Zhang, Linxi. "Hydrogen Storage Methods, Systems and Materials". Highlights in Science, Engineering and Technology 58 (12 de julio de 2023): 371–78. http://dx.doi.org/10.54097/hset.v58i.10125.

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With the world energy crisis constantly developing and petrol resources reducing, hydrogen is recovered as an ideal substitute for its excellent characteristics. Despite its abundance, abilities for easy regeneration and less pollution emissions, hydrogen energy has lower energy density in standard conditions, which means hydrogen storage needs lots of space.Among all techniques,hydrogen storage technology is the hottest topic.High efficient hydrogen storage technology is highly wanted for the application in energy storage system.This paper reviews the hydrogen storage technology from varied main principles of hydrogen storage process. It makes concise comparison and analysis mainly on physical hydrogen storage (high pressure,high pressure with low temperature and liquid storage) and absorption storage (physical absorption,chemical absorption). This paper does some research on the main technical features of these two hydrogen storage technologies to find the most economic method. And the comparison shows advantages and disadvantages on each method. Physical hydrogen has weaknesses on high hydrogen storage conditions and poor security, meanwhile, chemical hydrogen storage is weak in the process of dehydrogenation.

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43

Dutta, Gargi, Umesh V. Waghmare, Tinku Baidya y M. S. Hegde. "Hydrogen Spillover onCeO2/Pt: Enhanced Storage of Active Hydrogen". Chemistry of Materials 19, n.º 26 (diciembre de 2007): 6430–36. http://dx.doi.org/10.1021/cm071330m.

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44

Hagemann, Hans. "Boron Hydrogen Compounds: Hydrogen Storage and Battery Applications". Molecules 26, n.º 24 (7 de diciembre de 2021): 7425. http://dx.doi.org/10.3390/molecules26247425.

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About 25 years ago, Bogdanovic and Schwickardi (B. Bogdanovic, M. Schwickardi: J. Alloys Compd. 1–9, 253 (1997) discovered the catalyzed release of hydrogen from NaAlH4. This discovery stimulated a vast research effort on light hydrides as hydrogen storage materials, in particular boron hydrogen compounds. Mg(BH4)2, with a hydrogen content of 14.9 wt %, has been extensively studied, and recent results shed new light on intermediate species formed during dehydrogenation. The chemistry of B3H8−, which is an important intermediate between BH4− and B12H122−, is presented in detail. The discovery of high ionic conductivity in the high-temperature phases of LiBH4 and Na2B12H12 opened a new research direction. The high chemical and electrochemical stability of closo-hydroborates has stimulated new research for their applications in batteries. Very recently, an all-solid-state 4 V Na battery prototype using a Na4(CB11H12)2(B12H12) solid electrolyte has been demonstrated. In this review, we present the current knowledge of possible reaction pathways involved in the successive hydrogen release reactions from BH4− to B12H122−, and a discussion of relevant necessary properties for high-ionic-conduction materials.

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45

Sharma, Pankaj, Jinhyup Han, Jaehyun Park, Dong Yeon Kim, Jinho Lee, Dongrak Oh, Namsu Kim et al. "Alkali-Metal-Mediated Reversible Chemical Hydrogen Storage Using Seawater". JACS Au 1, n.º 12 (3 de noviembre de 2021): 2339–48. http://dx.doi.org/10.1021/jacsau.1c00444.

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46

Semelsberger, Troy A. y Kriston P. Brooks. "Chemical hydrogen storage material property guidelines for automotive applications". Journal of Power Sources 279 (abril de 2015): 593–609. http://dx.doi.org/10.1016/j.jpowsour.2015.01.040.

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47

Huang, Hui, Hengchao Zhang, Yang Liu, Zheng Ma, Hai Ming, Haitao Li y Zhenhui Kang. "(Pt-C60)@SiO2 nanocomposites for convenient chemical hydrogen storage". Journal of Materials Chemistry 22, n.º 38 (2012): 20153. http://dx.doi.org/10.1039/c2jm35406c.

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Moury, Romain y Umit Demirci. "Hydrazine Borane and Hydrazinidoboranes as Chemical Hydrogen Storage Materials". Energies 8, n.º 4 (20 de abril de 2015): 3118–41. http://dx.doi.org/10.3390/en8043118.

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Demirci, Umit B. y Philippe Miele. "Chemical hydrogen storage: ‘material’ gravimetric capacity versus‘system’ gravimetric capacity". Energy & Environmental Science 4, n.º 9 (2011): 3334. http://dx.doi.org/10.1039/c1ee01612a.

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LI, HuiZhen, XueNian CHEN y PengYuan WANG. "Ammonia borane: A high capacity chemical hydrogen storage material". Chinese Science Bulletin 59, n.º 19 (1 de julio de 2014): 1823–37. http://dx.doi.org/10.1360/972013-1221.

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