Bibliografías temáticas / Polymerization induced phase separation

Literatura académica sobre el tema "Polymerization induced phase separation"

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Publicado: 6 de septiembre de 2023

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Artículos de revistas sobre el tema "Polymerization induced phase separation"

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LEE, J. C. "POLYMERIZATION-INDUCED PHASE SEPARATION: INTERMEDIATE DYNAMICS". International Journal of Modern Physics C 11, n.º 02 (marzo de 2000): 347–58. http://dx.doi.org/10.1142/s0129183100000328.

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When phase separation is induced by polymerizating monomers in a mixture of monomers and nonreacting molecules, the dynamics is different depending on the time scale of polymerization τpl and the time scale of phase separation τps. Previous studies have explored the dynamic regimes where τpl ≪ τps and that where τpl ≫ τps. In the former, a spanning gel emerges before the phase separation and the phase separation is driven largely by activation. In the latter, phase separation occurs first between polymers and nonbonding molecules and then the polymers turn into a gel, and therefore the driving mechanism is the same as in the usual liquid–liquid demixing processes. Using Molecular Dynamics simulations, we explore in this paper the intermediate dynamic regime where the two time scales are comparable. When the polymerization is done by means of the thermal condensation reaction, we observe the expected crossover, one limit behavior at early times and then the other at late times. When the polymerization is done by means of the radical addition reaction, the results suggest that the driving mechanism changes more than once.
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Lee, J. C. "Polymerization-induced phase separation". Physical Review E 60, n.º 2 (1 de agosto de 1999): 1930–35. http://dx.doi.org/10.1103/physreve.60.1930.

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Kuboyama, Keiichi. "Polymer Blend ―Polymerization-induced Phase Separation―". Seikei-Kakou 30, n.º 8 (20 de julio de 2018): 419–23. http://dx.doi.org/10.4325/seikeikakou.30.419.

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Shu-Hsia Chen y Wei-Jou Chen. "Kinetics of polymerization-induced phase separation". Physica A: Statistical Mechanics and its Applications 221, n.º 1-3 (noviembre de 1995): 216–22. http://dx.doi.org/10.1016/0378-4371(95)00245-3.

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Boots, H. M. J., J. G. Kloosterboer, C. Serbutoviez y F. J. Touwslager. "Polymerization-Induced Phase Separation. 1. Conversion−Phase Diagrams". Macromolecules 29, n.º 24 (enero de 1996): 7683–89. http://dx.doi.org/10.1021/ma960292h.

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Zaremski, Mikhail Yu, Elena Yu Kozhunova, Sergey S. Abramchuk, Maria E. Glavatskaya y Alexander V. Chertovich. "Polymerization-induced phase separation in gradient copolymers". Mendeleev Communications 31, n.º 2 (marzo de 2021): 277–79. http://dx.doi.org/10.1016/j.mencom.2021.03.045.

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Chan, Philip K. y Alejandro D. Rey. "Polymerization-Induced Phase Separation. 2. Morphological Analysis". Macromolecules 30, n.º 7 (abril de 1997): 2135–43. http://dx.doi.org/10.1021/ma961078w.

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Yue, Jun, Honglei Wang, Qian Zhou y Pei Zhao. "Reaction-Induced Phase Separation and Morphology Evolution of Benzoxazine/Epoxy/Imidazole Ternary Blends". Polymers 13, n.º 17 (31 de agosto de 2021): 2945. http://dx.doi.org/10.3390/polym13172945.

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Introducing multiphase structures into benzoxazine (BOZ)/epoxy resins (ER) blends via reaction-induced phase separation has proved to be promising strategy for improving their toughness. However, due to the limited contrast between two phases, little information is known about the phase morphological evolutions, a fundamental but vital issue to rational design and preparation of blends with different phase morphologies in a controllable manner. Here we addressed this problem by amplifying the difference of polymerization activity (PA) between BOZ and ER by synthesizing a low reactive phenol-3,3-diethyl-4,4′-diaminodiphenyl methane based benzoxazine (MOEA-BOZ) monomer. Results indicated that the PA of ER was higher than that of BOZ. The use of less reactive MOEA-BOZs significantly enlarged their PA difference with ER, and thus increased the extent of phase separation and improved the phase contrast. Phase morphologies varied with the content of ER. As for the phase morphological evolution, a rapid phase separation could occur in the initial homogeneous blends with the polymerization of ER, and the phase morphology gradually evolved with the increase in ER conversion until the ER was used up. The polymerization of ER is not only the driving-force for the phase separation, but also the main factor influencing the phase morphologies.
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Sicher, Alba, Rabea Ganz, Andreas Menzel, Daniel Messmer, Guido Panzarasa, Maria Feofilova, Richard O. Prum et al. "Structural color from solid-state polymerization-induced phase separation". Soft Matter 17, n.º 23 (2021): 5772–79. http://dx.doi.org/10.1039/d1sm00210d.

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Inspired by living organisms that exploit phase separation to assemble structurally colored materials from macromolecules, we show that solid-state polymerization-induced phase separation can produce stable structures at optical length scales.
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Okada, Mamoru y Toshiki Sakaguchi. "Thermal-History Dependence of Polymerization-Induced Phase Separation". Macromolecules 32, n.º 12 (junio de 1999): 4154–56. http://dx.doi.org/10.1021/ma981744o.

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Tesis sobre el tema "Polymerization induced phase separation"

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Oh, Junsuk. "Computational simulation and morphological analysis of polymerization-induced phase separation". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0031/MQ64240.pdf.

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Luo, Xiaofan. "Polymerization induced phase separation (PIPS) in epoxy/poly([epsilon]-caprolactone) systems". online version, 2008. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=case1189443918.

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Luo, Xiaofan. "Polymerization Induced Phase Separation (PIPS) in Epoxy / Poly(ε-Caprolactone) Systems". Case Western Reserve University School of Graduate Studies / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=case1189443918.

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Gao, Ziyao. "Study of Shape Memory Polymer Composites from Polymerization Induced Phase Separation Process". Thesis, University of Louisiana at Lafayette, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10681918.

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Polymer composites are taking the place of traditional materials in many fields. They are preferred in engineering structures due to the advantages in strength, stiffness, thermostability, corrosion resistance, and ductility at high temperatures. Study of PCL-based shape memory polymer composite can expand its application. And in order to fully understand SMP properties, a series of comprehensive testing is required.

Samples with different PCL percentages must be made by using a standard and optimized procedure to eliminate unwanted variables, and to ensure the amount of PCL in samples is the only variable.

The DSC test on the SMP samples shows that there are two transition phases. One is at 53 °C and indicated as PCL melting temperature; another one is at 138.5 °C, indicated to be the glass transition phase.

Shape memory behavior tests on the SMP samples show that the PCL-based polymer composite has significant shape recovery ability. The ability of recovery is proportional with the amount of PCL in the sample. And the recovery performance is shown in both strain and stress recovery.

The mechanical properties of SMP composite are determined by compression tests. Tests are performed on each specimen with different PCL percentages. The maximum compressive stress is higher in specimens that have a higher amount of PCL, and this result agrees with results from the shape memory test.

Finally, the SMP composites are observed with SEM. A unique globule structure is shown in the specimens regardless of their PCL percentages. This globule structure is totally different from the structure in pure epoxy. The reason for this difference is still unknown and needs to be determined with further research.

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Lee, Jeongwoo. "Fabrication of polymer/metal oxide composites through polymerization-induced phase separation and characterization of their mechanical and electrochemical properties". University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1446217264.

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Elhaj, Ahmed. "Porous Polymeric Monoliths by Less Common Pathways : Preparation and Characterization". Doctoral thesis, Umeå universitet, Kemiska institutionen, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-89322.

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This thesis focuses on my endeavors to prepare new porous polymeric monoliths that are viable to use as supports in flow-through processes. Polymer monoliths of various porous properties and different chemical properties have been prepared utilizing the thermally induced phase separation (TIPS) phenomenon and step-growth polymerization reactions. The aim has been to find appropriate synthesis routes to produce separation supports with fully controlled chemical, physical and surface properties. This thesis includes preparation of porous monolithic materials from several non-cross-linked commodity polymers and engineering plastics by dissolution/precipitation process (i.e. TIPS). Elevated temperatures, above the upper critical solution temperature (UCST), were used to dissolve the polymers in appropriate solvents that only dissolve the polymers above this critical temperature. After dissolution, the homogeneous and clear polymer-solvent solution is thermally quenched by cooling. A porous material, of three dimensional structure, is then obtained as the temperature crosses the UCST. More than 20 organic solvents were tested to find the most compatible one that can dissolve the polymer above the UCST and precipitate it back when the temperature is lowered. The effect of using a mixture of two solvents or additives (co-porogenic polymer or surfactant) in the polymer dissolution/precipitation process have been studied more in depth for poly(vinylidine difluoride) (PVDF) polymers of two different molecular weight grades. Monolithic materials showing different pore characteristics could be obtained by varying the composition of the PVDF-solvent mixture during the dissolute­ion/precipitation process. Step-growth polymerization (often called polycondensat­ion reaction) combined with sol-gel process with the aid of porogenic polymer and block copolymer surfactant have also been used as a new route of synthesis for production of porous melamine-formaldehyde (MF) monoliths. In general, the meso- and macro-porous support materials, for which the synthesis/preparation is discussed in this thesis, are useful to a wide variety of applications in separation science and heterogeneous reactions (catalysis).
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Venkateshan, Karthik Johari G. P. "Polymerization and phase separation studies in liquids". *McMaster only, 2006.

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Jordan, Alexander Thomas. "Liquid phase plasma technology for inkjet separation". Thesis, Georgia Institute of Technology, 2013. http://hdl.handle.net/1853/47543.

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Currently most deinking technologies are dependent upon flotation and dissolved air flotation (DAF) technology in order to separate inkjet ink from fiber and water. Much of this technology is based on ink that is extremely hydrophobic. This made flotation and DAF very easy to use because the ink in the water would very easily move with the air in flotation and be brought to the surface, after which the ink can be skimmed and the pulp can be used. Now that small scale printing has become the norm, there has been a move to high quality, small scale printing. This involves the use of a hydrophilic ink. Hydrophilic ink cannot be easily separated from water and fiber the same way the hydrophobic ink can be. With low concentrations of hydrophilic ink in the process water stream, it can be absorbed into the process but as the hydrophilic ink concentration rises alternative methods will be needed in order to separate inkjet ink from water. One solution is to find a method to effectively increase ink particle size. This will enable the ink particles to be filtered or to have an increase ecacy of removal during flotation. In this thesis, one solution is discussed about how electric field and electric plasma technologies can be used to increase particle size and help purify process water in recycle mills. This plasma treatment can very effectively bring ink particles together so that they may be separated by another method. There are two methods by which this may take place. One is polymerization and the other is electro-coagulation. These processes can work side by side to bring ink particles together. This plasma treatment process creates free radicals by stripping off hydrogen atoms from surrounding organic matter. These free radicals then react with the high alkene bond content within the ink to create a very large covalently bonded molecule. This is the new mechanism that is being investigated in this thesis. The other action that is taking place is electro-coagulation. Plasma treated ink can be filtered out using a cellulose acetate or cellulose nitrate membrane or they can be filtered using paper or fiber glass filters as well. The extent at which these can be filtered out is dependent on the size of the pores of the filter. In this study, it was shown that the plasma treatment was able to clean water with a fairly small amount of energy. It was also found that treatment time and concentration had very little eect on the outcome of the treatment ecacy. One factor that did have an effect was the pH. At very high pH values the process became noticeably less eective. The high pH essentially eliminated the electro-coagulation aspect of the treatment process and also hurt the polymerization aspect as well because of lower amount of hydrogen atoms available for the plasma to create free radicals. A model of the process was used to try to give the reader an idea of the ecacy that the process would have in an industrial scale process. The model assumes that two types of ink particles exist. One is ink that has a radical and another in which the ink does not have a radical. The model also assumes that if ink is at all polymerized, ink is filtered out with the 0.8 micron filter. The model assumes three reactions; initialization, propagation and partial termination. The partial termination is a result from the general chemical structure of ink. Ink has many double bonds in its general structure which makes termination very unlikely to occur, so the model assumes that on average when two radials interact that only one is eliminated. This model is only supposed to give the reader an idea of the ecacy of the process. The numbers provided in the model will change very significantly in a different system. The evidence behind polymerization aspect of the process comes from two main sources. One is the small molecule analysis from methanol after being exposed to the plasma and the other from the plasma being exposed to allyl alcohol. The small molecule analysis shows that the process generates free radicals on organic molecules. Methanol was exposed to the plasma and then the resulting GC/MS analysis showed that 1,2-ethanediol was present, this showed that the electric discharge process was able to create free radicals on organic molecules in the liquid phase. Using a similar process the plasma discharge process was exposed to a mixture of allyl alcohol, water and propanol and water in two separate experiments. The difference between these two molecules is an alkene bond that is between the carbon two and carbon three atoms. The particle size of both samples was then analyzed and it was shown that the solution with allyl alcohol had an average particle size about an order of magnitude larger than the solution with propanol in it. Because of all the evidence discussed here and in the rest of the thesis we believe that the plasma treatment of ink has both polymerization and electro-coagulation aspect. This process could also be a potential solution to the water soluble ink problem that will soon face the recycling industry.
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Kulkarni, Amit. "Reaction induced phase-separation controlled by molecular topology.*". Cincinnati, Ohio : University of Cincinnati, 2004. http://www.ohiolink.edu/etd/view.cgi?acc%5Fnum=ucin1108001435.

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Munshi, Imran. "Reaction-induced phase separation in modified epoxy resins". Thesis, University of Manchester, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.493906.

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Studies have been carried out on reaction-induced phase separation in epoxy networks, formed from a DGEBA-type epoxy resin prepolymer, DER332, and m-xylylene diamine, MXDA, containing as modifiers either (i) butyl laurate (B) or (ii) m-cardura (C), (synthesised from Cardura El0 and 2-ethyUiexanoic acid). The reactants and modifiers were characterised using end-group analysis, Fourier transform infra-red spectroscopy (FTIR), differential scanning calorimetry (DSC), nuclear magnetic resonance and viscometry.
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Libros sobre el tema "Polymerization induced phase separation"

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Cheng, Alison. Formation of hybrid particles by phase separation-induced heterocoagulation of a polyferrocenylsilane polyelectrolyte with silica. Ottawa: National Library of Canada, 2003.

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Partition of cell particles and macromolecules: Separation and purification of biomolecules, cell organelles, membranes, and cells in aqueous polymer two-phase systems and their use in biochemical analysis and biotechnology. 3a ed. New York: Wiley, 1986.

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Tanaka, H. Phase separation in soft matter: the concept of dynamic asymmetry. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780198789352.003.0015.

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In this article, we review the basic physics of viscoelastic phase separation including fracture phase separation. We show that with an increase in the ratio of the deformation rate of phase separation to the slowest mechanical relaxation rate the type of phase separation changes from fluid phase separation, to viscoelastic phase separation, to fracture phase separation. We point out that there is a physical analogy of this to the transition of the mechanical fracture behaviour of materials under shear from liquid-type, to ductile, to brittle fracture. This allows us to discuss phase separation and shear-induced instability of disordered materials including soft matter, on the same physical ground. Finally it should be noted that what we are going to describe in this article has not necessarily been firmly established and there still remain many open problems to be studied in the future.
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Capítulos de libros sobre el tema "Polymerization induced phase separation"

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Kirby, Brian J. y Anup K. Singh. "In-situ Fabrication of Dialysis Membranes in Glass Microchannels Using Laser-induced Phase-Separation Polymerization". En Micro Total Analysis Systems 2002, 742–44. Dordrecht: Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0504-3_47.

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Ray, Suprakas Sinha, Amanuel Geberekrstos, Tanyaradzwa Sympathy Muzata y Jonathan Tersur Orasugh. "Phase Separation, Heterogeneous Behavior and Prevention of Phase Separation". En Process-Induced Phase Separation in Polymer Blends, 15–39. München: Carl Hanser Verlag GmbH & Co. KG, 2023. http://dx.doi.org/10.3139/9781569909195.002.

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Takahashi, Yoshiaki. "Flow-Induced Phase Separation in Polymer Blends". En Encyclopedia of Polymeric Nanomaterials, 1–8. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-36199-9_70-1.

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Takahashi, Yoshiaki. "Flow-Induced Phase Separation in Polymer Blends". En Encyclopedia of Polymeric Nanomaterials, 782–88. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-29648-2_70.

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Ray, Suprakas Sinha, Amanuel Geberekrstos, Tanyaradzwa Sympathy Muzata y Jonathan Tersur Orasugh. "Processing of Phase-Separated Blends". En Process-Induced Phase Separation in Polymer Blends, 83–109. München: Carl Hanser Verlag GmbH & Co. KG, 2023. http://dx.doi.org/10.3139/9781569909195.005.

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Figoli, Alberto. "Thermally Induced Phase Separation (TIPS) for Membrane Preparation". En Encyclopedia of Membranes, 1889–90. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_1866.

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Figoli, Alberto. "Thermally Induced Phase Separation (TIPS) for Membrane Preparation". En Encyclopedia of Membranes, 1–2. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-40872-4_1866-1.

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Matsuki, Nobutake Tamai Masaki Goto and Hito. "Phase Separation in Phospholipid Bilayers Induced by Cholesterol". En Encyclopedia of Biocolloid and Biointerface Science 2V Set, 825–40. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2016. http://dx.doi.org/10.1002/9781119075691.ch68.

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Tjerneld, Folke, Patricia A. Alred, Richard F. Modlin, Antoni Kozlowski y J. Milton Harris. "Purification of Biomolecules Using Temperature-Induced Phase Separation". En Aqueous Biphasic Separations, 119–31. Boston, MA: Springer US, 1995. http://dx.doi.org/10.1007/978-1-4615-1953-9_10.

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Williams, Roberto J. J., Boris A. Rozenberg y Jean-Pierre Pascault. "Reaction-induced phase separation in modified thermosetting polymers". En Polymer Analysis Polymer Physics, 95–156. Berlin, Heidelberg: Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/3-540-61218-1_7.

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Actas de conferencias sobre el tema "Polymerization induced phase separation"

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Jisha, Chandroth P., Kuei-Chu Hsu, YuanYao Lin, Ja-Hon Lin, Kai-Ping Chuang, Chao-Yi Tai y Ray-Kuang Lee. "Phase separation and pattern instability of laser-induced polymerization in liquid-crystal-monomer mixtures". En CLEO: Science and Innovations. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/cleo_si.2012.ctu1j.2.

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Hsu, Kuei-Chu y Ja-Hon Lin. "Ultrashort pulse induced nonlinear photo-polymerization and phase separation in liquid crystal and monomer mixtures". En SPIE MOEMS-MEMS, editado por Winston V. Schoenfeld, Jian Jim Wang, Marko Loncar y Thomas J. Suleski. SPIE, 2011. http://dx.doi.org/10.1117/12.871443.

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Yu, Shudong, Junchi Chen, Kejian Wu, Yong Tang y Zongtao Li. "Highly scattering porous films by polymerization-induced phase separation and application on light-emitting diodes". En Optical Devices and Materials for Solar Energy and Solid-state Lighting. Washington, D.C.: OSA, 2020. http://dx.doi.org/10.1364/pvled.2020.pvm2g.3.

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Jones, Brad, Samuel Leguizamon, Sara Dickens, Juhong Ahn y Sangwoo Lee. "Polymerization-Induced Phase Separation in Epoxy-Amine Networks with Broadly and Systematically Tunable Length Scales." En Proposed for presentation at the American Physical Society March Meeting 2021. US DOE, 2021. http://dx.doi.org/10.2172/1855706.

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Latifa, Zair, Maschke Ulrich, Berrayah Abdelkader y Hadjou Belaid Zakia. "Dynamical behavior and density of the Polymer / Liquid Crystal blends prepared by polymerization induced phase separation". En 2014 North African Workshop on Dielectric Materials for Photovoltaic Systems (NAWDMPV). IEEE, 2014. http://dx.doi.org/10.1109/nawdmpv.2014.6997603.

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Wu, Kejian, Jiadong Yu, Yong Tang, Zongtao Li, Guanwei Liang y Shudong Yu. "Highly reflective porous films via polymerization-induced phase separation and application on phosphor-converted light-emitting diodes". En 2020 21st International Conference on Electronic Packaging Technology (ICEPT). IEEE, 2020. http://dx.doi.org/10.1109/icept50128.2020.9202919.

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Paquet, Chantal, Bhavana Deore, Hendrick W. de Haan, Antony Orth, Thomas Lacelle, Yujie Zhang y Katie Sampson. "Diffusion and phase separation in vat polymerization 3D printing". En Advanced Fabrication Technologies for Micro/Nano Optics and Photonics XV, editado por Georg von Freymann, Eva Blasco y Debashis Chanda. SPIE, 2022. http://dx.doi.org/10.1117/12.2607132.

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Peng, Siying, Andrew Meng, Wanliang Tan, Michael Braun, Balreen Saini, Kayla Severson, Ann Marshall y Paul C. McIntyre. "Imaging light-induced phase separation dynamics of inorganic halide perovskites". En CLEO: Science and Innovations. Washington, D.C.: OSA, 2020. http://dx.doi.org/10.1364/cleo_si.2020.sf3f.6.

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SAARELA, M. y F. V. KUSMARTSEV. "DOPING INDUCED ELECTRONIC PHASE SEPARATION AND COULOMB BUBBLES IN LAYERED SUPERCONDUCTORS". En Proceedings of the 32nd International Workshop. WORLD SCIENTIFIC, 2009. http://dx.doi.org/10.1142/9789814289153_0021.

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Shimizu, Masahiro, Kiyotaka Miura, Masaaki Sakakura, Masayuki Nishi, Yasuhiko Shimotsuma, Shingo Kanehira y Kazuyuki Hirao. "Localized phase separation inside glass by femtosecond laser-induced elemental migration". En Fundamentals of Laser Assisted Micro- and Nanotechnologies 2010, editado por Vadim P. Veiko y Tigran A. Vartanyan. SPIE, 2010. http://dx.doi.org/10.1117/12.887428.

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