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Artículos de revistas sobre el tema "Molecular Charge"

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Publicado: 6 de septiembre de 2023

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1

Zhu, Xin, Xiao Jie Li, Yang Liu, Xi Shan Guo y Yin Fei Zheng. "Numerical Study of Single Molecular Charge Sensing by FET-Integrated Nanopore Biosensor". Materials Science Forum 1058 (5 de abril de 2022): 99–104. http://dx.doi.org/10.4028/p-8kmke2.

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This report studies the charge-based sensing modality of FET-embedded nanopore biosensors through FEM simulation. PNP equation is solved to analyze the mirror charge introduced by charged biomolecule while threading through the nanopore-FET sensor. Negative and positive charged molecules are analyzed respectively. Obvious local potential change induced by the presenting of charged molecules nearby is observed. In addition, the transport-induced descreening effect is observed under intensive bias, which might explain the capability of charge sensing even under high concentrations such as 1 M for FET-nanopore biosensors.
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2

Hinze, Juergen, F. Biegler-Konig y A. G. Lowe. "Molecular charge density analysis". Canadian Journal of Chemistry 74, n.º 6 (1 de junio de 1996): 1049–53. http://dx.doi.org/10.1139/v96-117.

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It is proposed to analyse the first-order reduced density matrix of a molecular wave function in terms of the first-order reduced density matrices of different states of the constituent atoms. With this an unambiguous partitioning of the molecular charge distribution in terms of the atomic charge distributions is obtained. Simple practical formulae are derived, such that in many ab initio molecular wave function calculations the analysis proposed can be carried out routinely. The results obtained should be useful for the interpretation of molecular wave functions in terms of their atomic constituents, as well as for the determination of atomic form factors to be used in X-ray molecular structure determination. Some simple examples are given, and the results obtained are compared with those obtained using other methods of analysis. Key words: charge density, density matrix, goodness-of-fit, correlation coefficient, standard deviation.
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3

Alavi, Ali, Luis J. Alvarez, Stephen R. Elliott y Ian R. McDonald. "Charge-transfer molecular dynamics". Philosophical Magazine B 65, n.º 3 (marzo de 1992): 489–500. http://dx.doi.org/10.1080/13642819208207645.

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4

Strohriegl, P. y J. V. Grazulevicius. "Charge-Transporting Molecular Glasses". Advanced Materials 14, n.º 20 (16 de octubre de 2002): 1439–52. http://dx.doi.org/10.1002/1521-4095(20021016)14:20<1439::aid-adma1439>3.0.co;2-h.

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5

Wörner, Hans Jakob, Christopher A. Arrell, Natalie Banerji, Andrea Cannizzo, Majed Chergui, Akshaya K. Das, Peter Hamm et al. "Charge migration and charge transfer in molecular systems". Structural Dynamics 4, n.º 6 (noviembre de 2017): 061508. http://dx.doi.org/10.1063/1.4996505.

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6

Klumpp, Douglas A. "Molecular rearrangements of superelectrophiles". Beilstein Journal of Organic Chemistry 7 (23 de marzo de 2011): 346–63. http://dx.doi.org/10.3762/bjoc.7.45.

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Superelectrophiles are multiply charged cationic species (dications, trications, etc.) which are characterized by their reactions with weak nucleophiles. These reactive intermediates may also undergo a wide variety of rearrangement-type reactions. Superelectrophilic rearrangements are often driven by charge–charge repulsive effects, as these densely charged ions react so as to maximize the distances between charge centers. These rearrangements involve reaction steps similar to monocationic rearrangements, such as alkyl group shifts, Wagner–Meerwein shifts, hydride shifts, ring opening reactions, and other skeletal rearrangements. This review will describe these types of superelectrophilic reactions.
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7

Hersam, M. C. y R. G. Reifenberger. "Charge Transport through Molecular Junctions". MRS Bulletin 29, n.º 6 (junio de 2004): 385–90. http://dx.doi.org/10.1557/mrs2004.120.

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AbstractIn conventional solid-state electronic devices, junctions and interfaces play a significant if not dominant role in controlling charge transport. Although the emerging field of molecular electronics often focuses on the properties of the molecule in the design and understanding of device behavior, the effects of interfaces and junctions are often of comparable importance. This article explores recent work in the study of metal–molecule–metal and semiconductor–molecule–metal junctions. Specific issues include the mixing of discrete molecular levels with the metal continuum, charge transfer between molecules and semiconductors, electron-stimulated desorption, and resonant tunneling. By acknowledging the consequences of junction/interface effects, realistic prospects and limitations can be identified for molecular electronic devices.
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8

Hopper, A. K. "MOLECULAR BIOLOGY:Nuclear Functions Charge Ahead". Science 282, n.º 5396 (11 de diciembre de 1998): 2003–4. http://dx.doi.org/10.1126/science.282.5396.2003.

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9

Fletcher, Liz. "Roche leads molecular diagnostics charge". Nature Biotechnology 20, n.º 1 (enero de 2002): 6–7. http://dx.doi.org/10.1038/nbt0102-6b.

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10

Jan van der Molen, Sense y Peter Liljeroth. "Charge transport through molecular switches". Journal of Physics: Condensed Matter 22, n.º 13 (17 de marzo de 2010): 133001. http://dx.doi.org/10.1088/0953-8984/22/13/133001.

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11

Miller, Joel S., Arthur J. Epstein y William M. Reiff. "Ferromagnetic molecular charge-transfer complexes". Chemical Reviews 88, n.º 1 (enero de 1988): 201–20. http://dx.doi.org/10.1021/cr00083a010.

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12

Chittipeddi, Sailesh R., Arthur J. Epstein, Jian H. Zhang, William M. Reiff, Ivar Hamberg, David B. Tanner, David C. Johnson y Joel S. Miller. "Magnetic molecular charge transfer complexes". Synthetic Metals 19, n.º 1-3 (marzo de 1987): 731–35. http://dx.doi.org/10.1016/0379-6779(87)90444-9.

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13

Seo, Hitoshi y Hidetoshi Fukuyama. "Charge ordering in molecular solids". Synthetic Metals 135-136 (abril de 2003): 673–75. http://dx.doi.org/10.1016/s0379-6779(02)00774-9.

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14

Siegle, Viktor, Chen-Wei Liang, Bernd Kaestner, Hans Werner Schumacher, Florian Jessen, Dieter Koelle, Reinhold Kleiner y Siegmar Roth. "A Molecular Quantized Charge Pump". Nano Letters 10, n.º 10 (13 de octubre de 2010): 3841–45. http://dx.doi.org/10.1021/nl101023u.

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15

Furuhashi, Osamu, Tohru Kinugawa, Nobuyuki Nakamura, Suomi Masuda, Chikashi Yamada y Shunsuke Ohtani. "Doubly Charged Molecular Ions Studied by Double Charge Transfer Spectroscopy". Journal of the Chinese Chemical Society 48, n.º 3 (junio de 2001): 531–34. http://dx.doi.org/10.1002/jccs.200100080.

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16

French, S. A. y C. R. A. Catlow. "Molecular mechanics simulations of charge-transfer molecular superconductors". Journal of Materials Chemistry 11, n.º 9 (2001): 2102–7. http://dx.doi.org/10.1039/b009960k.

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17

Braswell, Emory H. "Polyelectrolyte Charge Corrected Molecular Weight and Effective Charge by Sedimentation". Biophysical Journal 51, n.º 2 (febrero de 1987): 273–81. http://dx.doi.org/10.1016/s0006-3495(87)83333-7.

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18

Korchowiec, Jacek y Piotr Kowalski. "Charge polarization of molecular systems. Charge sensitivity and MNDO study". Chemical Physics Letters 208, n.º 1-2 (junio de 1993): 135–38. http://dx.doi.org/10.1016/0009-2614(93)80090-c.

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19

Martı́nez Morales, Evangelina, Claudio M. Zicovich-Wilson, Jorge E. Sánchez Sánchez y Luis Javier Alvarez. "Charge distribution in NaY zeolite from charge-transfer molecular dynamics". Chemical Physics Letters 327, n.º 3-4 (septiembre de 2000): 224–29. http://dx.doi.org/10.1016/s0009-2614(00)00790-9.

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20

Matsubara, Masahiko y Carlo Massobrio. "An Extensive Study of Charge Effects in Silicon Doped Heterofullerenes". Solid State Phenomena 129 (noviembre de 2007): 95–103. http://dx.doi.org/10.4028/www.scientific.net/ssp.129.95.

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We present an analysis of charge effects on the highly silicon doped heterofullerenes C30Si30. Structural and electronic properties are investigated by the inclusion of an extra pos- itive and negative charge in the neutral system. The calculations are performed based on the framework of Car-Parrinello molecular dynamics within the spin density version of density functional theory. Structural properties are not significantly affected by adding to or extracting from the C30Si30 heterofullerene one electron. However, the change of charge states has some ef- fects on the electronic properties of heterofullerenes. In the negatively charged system, negative charges are found in the inner part of the Si region, thereby suggesting potential applications of Si-based heterofullerenes as anionic systems.
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21

von Döhren, Hans. "Charged tRNAs charge into secondary metabolism". Nature Chemical Biology 5, n.º 6 (junio de 2009): 374–75. http://dx.doi.org/10.1038/nchembio0609-374.

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22

Rys, Paul, Ruth Weber y Qinglan Wu. "Light-induced change of the molecular charge in a spironaphthoxazine compound". Canadian Journal of Chemistry 71, n.º 11 (1 de noviembre de 1993): 1828–33. http://dx.doi.org/10.1139/v93-228.

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To evaluate the experimental conditions for the light-induced change of the molecular charge, the dependence of the photochromic reaction behaviour of the indolino spiro naphthoxazine compound 1,3,3-trimethyl-spiro[2H-indol 2,3′-[3H]naphth[2,1-b]-[1,4]oxazine] on the pH value of the solution is investigated. In the absence of UV light an acid–base equilibrium between the spiro form and a protonated closed form is established. By irradiation under appropriate acidic conditions the spiro form can be transformed into an open cationic form through the merocyanine form. Between the two open forms an acid–base equilibrium is established. Except for the closed protonated form the structures are confirmed by mean of NMR. The kinetics of the thermal ring-closing reaction of both forms are investigated by flash photolysis. It is shown that the ring-closing reaction proceeds exclusively via the merocyanine form. The pK values determined for both equilibria give the pH range, in which the light-induced change of the molecular charge occurs.
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23

Nespolo, Massimo y Benoît Guillot. "CHARDI2015: charge distribution analysis of non-molecular structures". Journal of Applied Crystallography 49, n.º 1 (1 de febrero de 2016): 317–21. http://dx.doi.org/10.1107/s1600576715024814.

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The charge distribution method describes non-molecular crystal structures in a Madelung-type approach in which the formal oxidation number (`charge') of each atom is distributed among its neighbours. The sum of the distributed charges gives back the input charge when a structure is correctly refined and well balanced, so that the method can be used for structure validation and for the analysis of over- and underbonding effects. A new version of the software used to compute the charge distribution is presented, now with a CIF parser and graphical user interface.
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24

Richard, Ann M. y James R. Rabinowitz. "Modified molecular charge similarity indices for choosing molecular analogues". International Journal of Quantum Chemistry 31, n.º 2 (febrero de 1987): 309–23. http://dx.doi.org/10.1002/qua.560310211.

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25

Bonn, Annabell G. y Oliver S. Wenger. "Photoinduced Charge Accumulation in Molecular Systems". CHIMIA International Journal for Chemistry 69, n.º 1 (25 de febrero de 2015): 17–21. http://dx.doi.org/10.2533/chimia.2015.17.

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26

KUSHMERICK, J. J., S. K. POLLACK, J. C. YANG, J. NACIRI, D. B. HOLT, M. A. RATNER y R. SHASHIDHAR. "Understanding Charge Transport in Molecular Electronics". Annals of the New York Academy of Sciences 1006, n.º 1 (diciembre de 2003): 277–90. http://dx.doi.org/10.1196/annals.1292.019.

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27

Xu, Beibei, Zheng Li, Shuquan Chang y Shenqiang Ren. "Multifunctional molecular charge-transfer thin films". Nanoscale 11, n.º 46 (2019): 22585–89. http://dx.doi.org/10.1039/c9nr08637d.

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28

Leypoldt, John K. y Lee W. Henderson. "Molecular charge influences transperitoneal macromolecule transport". Kidney International 43, n.º 4 (abril de 1993): 837–44. http://dx.doi.org/10.1038/ki.1993.118.

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29

Gong, Xiaojing, Jingyuan Li, Hangjun Lu, Rongzheng Wan, Jichen Li, Jun Hu y Haiping Fang. "A charge-driven molecular water pump". Nature Nanotechnology 2, n.º 11 (21 de octubre de 2007): 709–12. http://dx.doi.org/10.1038/nnano.2007.320.

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30

Wang, Yu, Yanjiao Zhao y Jiping Huang. "A charge-driven molecular flip-flop". European Physical Journal Applied Physics 61, n.º 3 (26 de febrero de 2013): 30401. http://dx.doi.org/10.1051/epjap/2013120355.

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31

Wood, Jonathan. "Single charge points to molecular transistor". Materials Today 8, n.º 8 (agosto de 2005): 10. http://dx.doi.org/10.1016/s1369-7021(05)71020-8.

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32

Borsenberger, P. M., L. Pautmeier y H. Bässler. "Charge transport in disordered molecular solids". Journal of Chemical Physics 94, n.º 8 (15 de abril de 1991): 5447–54. http://dx.doi.org/10.1063/1.460506.

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33

Rappe, Anthony K. y William A. Goddard. "Charge equilibration for molecular dynamics simulations". Journal of Physical Chemistry 95, n.º 8 (abril de 1991): 3358–63. http://dx.doi.org/10.1021/j100161a070.

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34

Carlson, Christin N., Christopher J. Kuehl, Ryan E. Da Re, Jacqueline M. Veauthier, Eric J. Schelter, Ashley E. Milligan, Brian L. Scott et al. "Ytterbocene Charge-Transfer Molecular Wire Complexes". Journal of the American Chemical Society 128, n.º 22 (junio de 2006): 7230–41. http://dx.doi.org/10.1021/ja058667e.

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35

Borsenberger, Paul M. "Charge Transport in Disordered Molecular Solids". Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 228, n.º 1 (mayo de 1993): 167–73. http://dx.doi.org/10.1080/10587259308032155.

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36

Prins, P., F. C. Grozema y L. D. A. Siebbeles. "Charge transport along phenylenevinylene molecular wires". Molecular Simulation 32, n.º 9 (agosto de 2006): 695–705. http://dx.doi.org/10.1080/08927020600835657.

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37

Mühlbacher, L. y J. Ankerhold. "Correlated charge transfer along molecular chains". New Journal of Physics 10, n.º 6 (30 de junio de 2008): 065023. http://dx.doi.org/10.1088/1367-2630/10/6/065023.

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38

Zhou, Jiawang, Sravan K. Surampudi, Arthur E. Bragg y Rebekka S. Klausen. "Photoinduced Charge Separation in Molecular Silicon". Chemistry - A European Journal 22, n.º 18 (9 de marzo de 2016): 6204–7. http://dx.doi.org/10.1002/chem.201600846.

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39

Brady, Patrick V., Randall T. Cygan y Kathryn L. Nagy. "Molecular Controls on Kaolinite Surface Charge". Journal of Colloid and Interface Science 183, n.º 2 (noviembre de 1996): 356–64. http://dx.doi.org/10.1006/jcis.1996.0557.

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40

Burin, Alexander L. y Mark A. Ratner. "Charge injection into disordered molecular films". Journal of Polymer Science Part B: Polymer Physics 41, n.º 21 (8 de octubre de 2003): 2601–21. http://dx.doi.org/10.1002/polb.10651.

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41

Awais, Mohammad Ahmad, Zhengxu Cai, Na Zhang y Luping Yu. "Molecular Design towards Controlling Charge Transport". Chemistry - A European Journal 24, n.º 65 (27 de septiembre de 2018): 17180–87. http://dx.doi.org/10.1002/chem.201803054.

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42

García-Sucre, M. "Nuclear-charge scaling in molecular systems". Journal of Molecular Structure: THEOCHEM 199 (septiembre de 1989): 271–82. http://dx.doi.org/10.1016/0166-1280(89)80059-4.

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43

Ma, Ying y Stephen H. Garofalini. "Iterative fluctuation charge model: A new variable charge molecular dynamics method". Journal of Chemical Physics 124, n.º 23 (21 de junio de 2006): 234102. http://dx.doi.org/10.1063/1.2206578.

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44

Saethre, Leif J., Michele R. F. Siggel y T. Darrah Thomas. "Molecular charge distribution, core-ionization energies, and the point-charge approximation". Journal of the American Chemical Society 113, n.º 14 (julio de 1991): 5224–30. http://dx.doi.org/10.1021/ja00014a014.

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45

Aoki, Kozo, Shigenori Tanaka y Tatsuya Nakano. "Molecular geometry-dependent atomic charge calculation with modified charge equilibration method". Chem-Bio Informatics Journal 9 (2009): 30–40. http://dx.doi.org/10.1273/cbij.9.30.

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46

Bei-Bei, YUAN, ZHOU Bei-Bei, ZHANG Yue-Biao y SHI Jian-Lin. "Charge-switchable Metal-organic Framework for Size/Charge-selective Molecular Inclusions". Journal of Inorganic Materials 33, n.º 3 (2018): 352. http://dx.doi.org/10.15541/jim20170163.

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47

LIMA, Francisco José Santos, Roseane Maria de MELO, Ademir Oliveira da SILVA y Cláudio César de Medeiros BRAGA. "MOLECULAR REACTIVITY PARAMETERS". Periódico Tchê Química 07, n.º 4 (20 de enero de 2007): 7–15. http://dx.doi.org/10.52571/ptq.v4.n07.2007.janeiro/1_pgs_7_15.pdf.

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The distribution of charge partial depends critically of the geometry and of the environment chemical. The parameters of reactivity molecular evaluate the contribution relative of the charge of either atom in the molecule in relation the all too much elements present. The association of these parameters with the geometry of the molecules becomes useful in the evaluation of the reactivities of the substances and in the interpretation of yours respective properties physical-chemistries. In this present work, were developed arguments theoretical for the parameters of reactivity molecular (PRM), that were compared with properties physical-chemistries acquaintances of the solvents selected: water, ethanol, acetone, nitromethane and some solutions of these, because are strategic in the synthesis of compounds inorganic. Through of the program WebLab ViewerPro, were accomplished the modelling molecular, the determination of the angles, of the distance of bond and the calculation of charge partial. The values of the parameters generated by the evaluations of the charges partials, together with the geometry molecular, they provided the analisys qualitative of the possible places more reactive in the surface of the structures of the systems chemical that favour areas of potential interaction the level molecular.
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48

Feizabadi, Mitra Shojania, Ramiz S. Alejilat, Alexis B. Duffy, Jane C. Breslin y Ibukunoluwa I. Akintola. "A Confirmation for the Positive Electric Charge of Bio-Molecular Motors through Utilizing a Novel Nano-Technology Approach In Vitro". International Journal of Molecular Sciences 21, n.º 14 (13 de julio de 2020): 4935. http://dx.doi.org/10.3390/ijms21144935.

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Molecular motors are microtubule-based proteins which contribute to many cell functions, such as intracellular transportation and cell division. The details of the nature of the mutual interactions between motors and microtubules still needs to be extensively explored. However, electrostatic interaction is known as one of the key factors making motor-microtubule association possible. The association rate of molecular motors to microtubules is a way to observe and evaluate the charge of the bio-motors in vivo. Growing evidence indicates that microtubules with distinct structural compositions in terms of beta tubulin isotypes carry different charges. Therefore, the electrostatic-driven association rate of motors–microtubules, which is a base for identifying the charge of motors, can be more likely influenced. Here, we present a novel method to experimentally confirm the charge of molecular motors in vitro. The offered nanotechnology-based approach can validate the charge of motors in the absence of any cellular components through the observation and analysis of the changes that biomolecular motors can cause on the dynamic of charged microspheres inside a uniform electric field produced by a microscope slide-based nanocapacitor. This new in vitro experimental method is significant as it minimizes the intracellular factors that may interfere the electric charge that molecular motors carry.
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49

Liu, Yuru, Xinkai Qiu, Saurabh Soni y Ryan C. Chiechi. "Charge transport through molecular ensembles: Recent progress in molecular electronics". Chemical Physics Reviews 2, n.º 2 (junio de 2021): 021303. http://dx.doi.org/10.1063/5.0050667.

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50

Naka, Makoto y Hitoshi Seo. "Long-Period Charge Correlations in Charge-Frustrated Molecular θ-(BEDT-TTF)2X". Journal of the Physical Society of Japan 83, n.º 5 (15 de mayo de 2014): 053706. http://dx.doi.org/10.7566/jpsj.83.053706.

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