Tesis sobre el tema "Mediated support"
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Salem, Abed. "Computer-mediated environment and learner support". Thesis, University of Strathclyde, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.444426.
Texto completoArvanitis, Elena-Alexia. "Sulfone mediated synthesis of heterocycles on solid support". Thesis, Imperial College London, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.321910.
Texto completoBöhm, Thilo [Verfasser]. "System-Mediated Support of Explicit Collaboration in Information Retrieval / Thilo Böhm". Hagen : Fernuniversität Hagen, 2016. http://d-nb.info/1105567923/34.
Texto completoLukman, Heryawan. "A Computer-mediated Support for Writing Medical Notes with Coder's Perspective". Kyoto University, 2020. http://hdl.handle.net/2433/259072.
Texto completoKyoto University (京都大学)
0048
新制・課程博士
博士(情報学)
甲第22804号
情博第734号
新制||情||125(附属図書館)
京都大学大学院情報学研究科社会情報学専攻
(主査)教授 黒田 知宏, 教授 吉川 正俊, 教授 緒方 広明
学位規則第4条第1項該当
LoPinto, Frank Anthony. "An Agent-Based Distributed Decision Support System Framework for Mediated Negotiation". Diss., Virginia Tech, 2004. http://hdl.handle.net/10919/27401.
Texto completoPh. D.
Andersson, Stefan. "Information and Communication Technology - mediated support for working carers of older people". Doctoral thesis, Linnéuniversitetet, Institutionen för hälso- och vårdvetenskap (HV), 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-65220.
Texto completoRady, A. S. "A technology-mediated approach to support family groups learning of English in Egypt". Thesis, University of Brighton, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.406811.
Texto completoZanuttini, Jessica Zoe. "Using Embedded Peer-Mediated Time Delay to Support Social Communication Development in Autism". Thesis, The University of Sydney, 2018. http://hdl.handle.net/2123/19915.
Texto completoChilds, Liam. "Bioinformatics approaches to analysing RNA mediated regulation of gene expression". Phd thesis, Universität Potsdam, 2010. http://opus.kobv.de/ubp/volltexte/2010/4128/.
Texto completoDas Genom eines Organismus enthält alle Informationen für die Synthese aller strukturellen Komponenten und deren jeweiligen Funktionen. Lange Zeit wurde angenommen, dass Proteine, die auf definierten Abschnitten auf dem Genom – den Genen – kodiert werden, die alleinigen Träger der molekularen - und vor allem katalytischen - Funktionen sind. Im Prozess der Umsetzung der genetischen Information von Genen in die Funktion von Proteinen wurden RNA Moleküle als weitere zentrale Molekülklasse identifiziert. Sie fungieren dabei als Botenmoleküle (mRNA) und unterstützen als Trägermoleküle (in Form von tRNA) die Zusammenfügung der einzelnen Aminosäurebausteine zu nativen Proteine. Diese eher passiven Funktionen wurden lange als die einzigen Funktionen von RNA Molekülen angenommen. Jedoch führten neue Entdeckungen zu einer radikalen Neubewertung der Rolle von RNA. So wurden RNA-Moleküle mit katalytischen Eigenschaften entdeckt, sogenannte Ribozyme. Weiterhin wurde festgestellt, dass über proteinkodierende Abschnitte hinaus, weit mehr genomische Sequenzbereiche abgelesen und in RNA Moleküle transkribiert werden als angenommen. Darüber hinaus wurden sehr kleine und neuartige RNA Moleküle identifiziert, die entscheidend bei der Koordinierung der Genexpression beteiligt sind. Diese Entdeckungen rückten RNA als Molekülklasse in den Mittelpunkt moderner molekularbiologischen Forschung und führten zu einer Neubewertung ihrer funktionellen Rolle. Die vorliegende Promotionsarbeit versucht mit Hilfe bioinformatorischer Methoden einen Beitrag zum Verständnis RNA-bezogener Phänomene zu leisten. Zunächst wurde eine genomweite Suche nach Abschnitten im Genom der Modellpflanze Arabidopsis thaliana vorgenommen, deren veränderte chemische Struktur (dem Genotyp) die Ausprägung ausgewählter Merkmale (dem Phänotyp) entscheidend beeinflusst. Dabei wurden sogenannte Ganz-Genom Hybridisierungschips eingesetzt und eine bioinformatische Strategie entwickelt, Veränderungen der chemischen Struktur (Polymorphismen) anhand der veränderten Bindung von genomischer DNA aus verschiedenen Arabidopsis Kultivaren an definierte Proben auf dem Chip zu detektieren. In dieser Suche wurden nicht nur systematisch Genotyp-Phänotyp Assoziationen entdeckt, sondern dabei auch Bereiche identifiziert, die bisher nicht als proteinkodierende Abschnitte annotiert sind, aber dennoch die Ausprägung eines konkreten Merkmals zu bestimmen scheinen. Diese Bereiche wurden desweiteren auf mögliche neue RNA Moleküle untersucht, die in diesen Abschnitten kodiert sein könnten. Hierbei wurde ein neuer Algorithmus eingesetzt, der ebenfalls als Teil der vorliegenden Arbeit entwickelt wurde. Während es zum Standardrepertoire der Molekularbiologen gehört, die chemische Struktur (die Sequenz) eines RNA Moleküls zu bestimmen, ist die Aufklärung sowohl der Struktur als auch der konkreten Funktion des Moleküls weitaus schwieriger. Zu diesem Zweck wurde in dieser Arbeit ein neuer algorithmischer Ansatz entwickelt, der mittels Computermethoden eine Zuordnung von RNA Molekülen zu bestimmten Funktionsklassen gestattet. Hierbei wurde das Konzept der Beschreibung von RNA-Sekundärstrukturen als Graphen genutzt. Es konnte gezeigt werden, dass diese Abstraktion von der konkreten Struktur zu nützlichen Aussagen zur Funktion führt. Des weiteren konnte demonstriert werden, dass graphen-theoretisch abgeleitete Merkmale von RNA-Molekülen einen neuen Zugang zum Verständnis der Struktur-Funktionsbeziehungen ermöglichen. Die entwickelte Methode (Grapple) wurde als web-basierte Anwendung der wissenschaftlichen Welt zur Verfügung gestellt. RNA hat sich als ein zentraler Forschungsgegenstand der Molekularbiologie etabliert und neue Entdeckungen können erwartet werden, die die zentrale Rolle von RNA bei der Entstehung und Aufrechterhaltung des Lebens auf der Erde weiter untermauern. Bioinformatische Methoden werden dabei weiterhin eine essentielle Rolle spielen.
Furukawa, Ryoko. "Using video-mediated communication to support pregnant couples separated during satogaeri bunben in Japan". Diss., University of Iowa, 2011. https://ir.uiowa.edu/etd/2873.
Texto completoBrown, Deana. "Designing technologies to support migrants and refugees". Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/53849.
Texto completoWilson, Martina E. "Learning and teaching online : structuring computer-mediated communication systems to support interaction at a distance". Thesis, Open University, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.247054.
Texto completoRockefeller, Debra J. "An Online Academic Support Model for Students Enrolled in Internet-Based Classes". Thesis, University of North Texas, 2000. https://digital.library.unt.edu/ark:/67531/metadc2451/.
Texto completoScott, Susan Valerie. "Computer-mediated interpretation of risk : the introduction of decision support systems in a UK retail bank". Thesis, University of Cambridge, 1998. https://www.repository.cam.ac.uk/handle/1810/252321.
Texto completoMcWhite, Shireen. "Effect of transformational leadership on intention to quit as mediated by justice, trust and perceived support". Master's thesis, University of Cape Town, 2009. http://hdl.handle.net/11427/5836.
Texto completoLynch, John G. "Perceived Stress and the Buffering Hypothesis of Perceived Social Support on Facebook". Antioch University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=antioch1344533616.
Texto completoBrady, Elaine Mary. "Lifting the blaincéad on breastfeeding: Can mobile technology address the customer experience of shame in Ireland". Thesis, Queensland University of Technology, 2019. https://eprints.qut.edu.au/131607/1/Elaine_Brady_Thesis.pdf.
Texto completoPowell, Wendy. "Virtually walking : factors influencing walking and perception of walking in treadmill-mediated virtual reality to support rehabilitation". Thesis, University of Portsmouth, 2011. https://researchportal.port.ac.uk/portal/en/theses/virtually-walking(1c81024c-8242-45fb-8ca1-6c74b1a1956c).html.
Texto completoStuckey, Bronwyn. "Growing online community core conditions to support successful development of community in internet-mediated communities of practice /". Access electronically, 2007. http://www.library.uow.edu.au/adt-NWU/public/adt-NWU20080911.092048/index.html.
Texto completoHong, Hwajung. "Specializing social networking services to support the independence of adolescents and adults with autism". Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/53552.
Texto completoKehrwald, Benjamin. "Social presence and learner support: understanding learners' experiences with mediated social processes in text-based online learning environments". University of Southern Queensland, Faculty of Education, 2007. http://eprints.usq.edu.au/archive/00003555/.
Texto completoPullen, Grant. "The development of a model to effectively utilise computer mediated communication to support assessment in a virtual learning environment". Thesis, Port Elizabeth Technikon, 2001. http://hdl.handle.net/10948/54.
Texto completoDebenham, Margaret. "Computer mediated communication and disability support : addressing barriers to study for undergraduate distance learners with long-term health problems". Thesis, Open University, 2001. http://oro.open.ac.uk/46223/.
Texto completoBazydlo, Nadia y Sofia Wallin. "A lifebuoy that supports in deep water : A qualitative case study investigating how an external actor can support an organisation in crisis". Thesis, Uppsala universitet, Företagsekonomiska institutionen, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-324823.
Texto completoDiGiovanni, Craig. "Emotional and Informational Supportive Exchanges as Predictors of Relational Health and Well-Being in Computer-Mediated Support Groups for Individuals with a Traumatic Brain Injury". Thesis, Boston College, 2018. http://hdl.handle.net/2345/bc-ir:107712.
Texto completoTraumatic brain injury (TBI) survivors often experience isolation from their primary support network following their injury (Marsh, Kersel, Havill, & Sleigh, 1998). Computer-mediated support groups (CMSGs) offer a virtual platform for individuals with complex medical concerns to exchange emotional and informational support (Braithwaite, Waldron, & Finn, 1999). To date, no research has examined the use of CMSGs, such as TBI-related Facebook support groups, for TBI survivors. There is also limited research investigating how emotional and informational support provided and received (i.e., supportive exchanges) relate to well-being and online relational health (Liang et al., 2002). This study examined the relationship between four supportive exchanges and well-being and relational health for TBI survivors using TBI-related Facebook support groups, as well as whether a gender norm—emotional control—and network preference moderated these relationships. Participants included 191 TBI survivors recruited across 14 TBI-related Facebook support groups. Multiple regression analyses tested whether four supportive exchanges directly predicted well-being and relational health after controlling for age and extraversion. Results revealed that supportive exchanges did not predict well-being. However, emotional support provided, emotional support received, and informational support received all predicted higher levels of online relational health. Informational support provided predicted lower levels of online relational health. Additional multiple regression analyses tested whether emotional control and four aspects of network preference moderated the relationship between supportive exchanges and well-being and relational health. Although higher levels of emotional control directly predicted lower levels of relational health, and a preference for weak-tie support networks (e.g., online acquaintances) predicted lower levels of well-being, the moderating effects were generally not significant. The findings underscore the importance of supportive exchanges in developing online relational health for TBI survivors using Facebook support groups. It also suggests that this relationship was not dependent on emotional control and network preference. Future research should investigate other factors affecting supportive online communication for TBI survivors and when they may benefit most from online support
Thesis (PhD) — Boston College, 2018
Submitted to: Boston College. Lynch School of Education
Discipline: Counseling, Developmental and Educational Psychology
May, Madeth. "Using tracking data as reflexive tools to support tutors and learners in distance learning situations : an application to computer-mediated communications". Lyon, INSA, 2009. http://theses.insa-lyon.fr/publication/2009ISAL0106/these.pdf.
Texto completoThis research effort focuses particularly on the traces of synchronous and asynchronous interactions on Computer-Mediated Communication tools (CMC), in situations of discussions, negotiations and arguments among learners. The main objective is to study how to use the collected traces to design "reflexive tools" for the participants in the learning process. Reflexive tools refer to the useful data indicators computed from the collected traces that support the participants in terms of awareness, assessment and evaluation of their CMC activities. We explored different tracking approaches and their limitations regarding traces collection, traces structuring, and traces visualization. To improve upon these limitations, we have proposed (i) an explicit tracking approach to efficiently track the CMC activities, (ii) a generic model of CMC traces to answer to the problems of CMC traces structuring, interoperability and reusability, and (iii) a platform TrAVis (Tracking Data Analysis and Visualization tools), specifically designed and developed to assist the participants, both the tutors and learners in the task of exploiting the CMC traces. Another crucial part of this research is the design of data indicators. The main objective is to propose different sets of data indicators in graphical representations in order to enhance the visualization and analysis of the information of CMC activities. Three case studies and an experiment in an authentic learning situation have been conducted during this research work to evaluate the technical aspects of the tracking approach and the utility of TrAVis according to the pedagogical and learning objectives of the participants
Curradi, Giacomo <1977>. "Airway Basal Cell Vascular Endothelial Growth Factor-mediated Cross-Talk Regulates Endothelial Cell Dependent Growth Support of Human Airway Basal Cells". Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5925/1/Curradi_Giacomo_Tesi.pdf.
Texto completoI risultati preliminari dello studio suggeriscono che il vascular endothelial growth factor A(VEGFA) e’ attivamente secreto dalle cellule basali dell’epitelio bronchiale e svolge una funzione paracrina nell’attivazione della cascata delle mitogen-activated protein kinases (MAPKs) nelle cellule endoteliali mediata dal VEGF receptor type 2. Utilizzando un sistema di co-coltura di cellule basali primarie delle vie aeree umane con cellule endoteliali umane, abbiamo mostrato come il VEGFA secreto dalle cellule basali sia in grado di attivare le cellule endoteliale che a loro volta, esprimono mediatori capaci di stimolare e sostenere la proliferazione delle cellule basali stesse. Questi dati dimostrano un cross-talk mediato dal rilascio di VEGFA tra le cellule basali dell’epitelio bronchiale e l’endotelio, il cui scopo è di modulare l'attivazione endoteliale e, a sua volta stimolare e sostenere la crescita delle cellule basali.
Curradi, Giacomo <1977>. "Airway Basal Cell Vascular Endothelial Growth Factor-mediated Cross-Talk Regulates Endothelial Cell Dependent Growth Support of Human Airway Basal Cells". Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5925/.
Texto completoI risultati preliminari dello studio suggeriscono che il vascular endothelial growth factor A(VEGFA) e’ attivamente secreto dalle cellule basali dell’epitelio bronchiale e svolge una funzione paracrina nell’attivazione della cascata delle mitogen-activated protein kinases (MAPKs) nelle cellule endoteliali mediata dal VEGF receptor type 2. Utilizzando un sistema di co-coltura di cellule basali primarie delle vie aeree umane con cellule endoteliali umane, abbiamo mostrato come il VEGFA secreto dalle cellule basali sia in grado di attivare le cellule endoteliale che a loro volta, esprimono mediatori capaci di stimolare e sostenere la proliferazione delle cellule basali stesse. Questi dati dimostrano un cross-talk mediato dal rilascio di VEGFA tra le cellule basali dell’epitelio bronchiale e l’endotelio, il cui scopo è di modulare l'attivazione endoteliale e, a sua volta stimolare e sostenere la crescita delle cellule basali.
Steel, Anne Louise. "Understanding Posttraumatic Stress Disorder Among Victims of Intimate Partner Violence: The Roles of Perceived Social Support, Self-esteem, and Self-blame". University of Dayton / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1339074563.
Texto completoLeontescu, Mihai. "ePM: Project Management transposed online : The use of information communication tools to support inter-organizational project work". Thesis, Jönköping University, JIBS, Business Informatics, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:hj:diva-12460.
Texto completoThe purpose of this bachelor paper is to analyze the different technologies used for supporting inter-organizational project work and how these technologies influence the project’s overall success. The results of this research have proved that the main impact ePM tools (e-Project Management tools) have upon inter-organizational projects are in terms of time-savings and easiness of communication when in need for communicating abroad with different business partners. Various types of collaboration tools can help the communication process between organizations and provide the project participants with the means of creating and supporting a collaborative environment. Other perceived benefits of ePM tools have been resulted including: reduce project costs due to time-savings and quality of information which lowers the risks for deficiency occurrences; improve the decision-making process; improve internal and external communication; facilitate knowledge sharing and expertise exchange; and create an agile business environment characterized by innovation, flexibility, faster market reaction and ability to work efficiently. Global time zones and communication skills are challenges to creating an efficient collaborative inter-organizational environment.
Schaefer, John McDonald. "The Role of Context in Interaction Between Students With Significant Disabilities and Their Peers". The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1467976888.
Texto completoKahumuza, Juliet. "Examining the relationship between perceived support and intention to quit directly and indirectly when mediated by affective commitment, organisational citizenship behaviour and job satisfaction". Master's thesis, University of Cape Town, 2008. http://hdl.handle.net/11427/10972.
Texto completoThe objective of this study was to; firstly, investigate the construct validity of a three dimensional perceived support construct; secondly, establish the direct relationship between perceived support and intention to quit as well as the indirect relationship when mediated by affective commitment, organisational citizenship behaviour and job satisfaction; and finally, explore the relative importance of the constructs in relation to intention to quit.
Doodson, Lisa. "Understanding the stepmother's role : quantifying the impact on quality of life and mental health : how stepmothers' adaptability is mediated by coping style, social support and relationship satisfaction". Thesis, University of West London, 2009. https://repository.uwl.ac.uk/id/eprint/380/.
Texto completoEfstration, Katherine M. Keiley Margaret K. Smith Thomas A. (Thomas Alton) Mize Jacquelyn. "The effect of depressotypic attributions on marital satisfaction as mediated by spousal support and moderated by length of marriage in mothers of children with autism spectrum disorders". Auburn, Ala, 2009. http://hdl.handle.net/10415/1903.
Texto completoPasquini, Andrea de Moura Menezes. "Aprendizagem cooperativa mediada por computador". Universidade de São Paulo, 2002. http://www.teses.usp.br/teses/disponiveis/18/18140/tde-28032017-155830/.
Texto completoCooperative learning through computer mediated communication is becoming accessible to greater number of people and, as a integral part of linked student\'s environment, is an emergent area of importance for researching and practice in education. The research reported in this study explores and describes the effects of Computer Mediated Communication evidencing cognitive and cooperative activities. The not presencial interaction was investigated with the support of eGroups computational tool, having as dominity of application the SEP 5744 -Decision Support Systems and SEM 210 - Systems Analysis II courses, of Production Mechanics Engineering Program. The study was directed to research methods involving the content\'s qualitative analysis of communication, since in cooperative learning, verbal interaction among peers is the fundamental agent through which cognitive activity occurs. Interpersonal cognitive facilitation may arise as an essential link between verbal behavior in peer\'s discussions and the social construction of knowledge.
Nagel, Lynette. "The dynamics of learner participation in a virtual learning environment". Thesis, University of Pretoria, 2008. http://hdl.handle.net/2263/22951.
Texto completoThesis (PHD)--University of Pretoria, 2009.
Curriculum Studies
unrestricted
Zimmermann, Julia Antonia [Verfasser], Yolanda [Akademischer Betreuer] Demetriou, Yolanda [Gutachter] Demetriou y Doris [Gutachter] Holzberger. "The relationship of teachers’ multidimensional autonomy support in physical education and students’ leisure-time physical activity mediated by cognitive appraisals and achievement emotions / Julia Antonia Zimmermann ; Gutachter: Yolanda Demetriou, Doris Holzberger ; Betreuer: Yolanda Demetriou". München : Universitätsbibliothek der TU München, 2021. http://d-nb.info/124174033X/34.
Texto completoMay, Richard A. "Toward directly mediated interaction in computer supported environments /". Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/10684.
Texto completoSmutný, Zdeněk. "Metoda pro výběr portfolia nástrojů pro online marketingové aktivity a podporu jejich řízení". Doctoral thesis, Vysoká škola ekonomická v Praze, 2012. http://www.nusl.cz/ntk/nusl-204907.
Texto completoVan, Dyke Benjamin Prime. "Does perceived social support mediate the relationship between catastrophizing and pain response?" Thesis, The University of Alabama, 2015. http://pqdtopen.proquest.com/#viewpdf?dispub=1600906.
Texto completoObjective: The objective of the current investigation was to attempt to contribute to the limited body of literature regarding the role and importance of social context, in particular social support, to the experience of pain. Specifically, the current study proposed that some of the previously observed effects of pain catastrophizing on pain experience operate through a social mechanism of action by reducing available social resources to help people cope with the stress of pain. Thus, it was hypothesized that perceived social support would at least partially mediate the relationship between pain catastrophizing and pain experience or response variables (perceptions of pain intensity and unpleasantness and tolerance time).
Method: A sample of 285 college students enrolled in introductory psychology courses answered baseline questionnaires about dispositional variables before completing a fixed-time cold pressor task (60s) followed by an open-ended cold pressor task (to test pain tolerance). Questionnaires assessed perceived general social support (the Social Provisions Scale), dispositional and situational pain catastrophizing (Pain Catastrophizing Scale), and perceptions of pain intensity and unpleasantness (using visual analog scales).
Results: The final sample consisted of 285 college students (Age: M = 19.62, SD = 1.73), was primarily White (77.9%) and female (58.2%), and the majority denied having either chronic or recurrent pain (n = 160, 56.1%). Regression and SEM analyses demonstrated that the study mediation hypothesis was not supported.
Conclusion: Results of the current study suggest important revisions and considerations for future replications and similar studies.
Saarenkunnas, M. (Maarit). "Multidimensional participation in polycontextual computer-supported language learning". Doctoral thesis, University of Oulu, 2004. http://urn.fi/urn:isbn:9514274865.
Texto completoWang, Shoulei. "Approaches to Asymmetric Catalysis Mediated by Ploymer-Supported and Homogeneous Organocatalysts". Doctoral thesis, Universitat Rovira i Virgili, 2018. http://hdl.handle.net/10803/553237.
Texto completoEsta tesis se centra en la síntesis de organocatalizadores, especialmente los soportados en polímero, y su aplicación en diversas transformaciones asimétricas. En el Capítulo II, se ha desarrollado una cicloadición [4 + 2] eficiente, altamente regio- y estereoselectiva entre alquilidenpirazolonas y enales mediante catálisis vía dienamina dirigida por enlace de hidrógeno. El Capítulo III describe un organocatalizador de tipo isotiourea soportado en poliestireno (PS) robusto y altamente eficiente para una variedad de reacciones formales de cicloadición [4 + 2]. Además, también se demuestra la reciclabilidad del catalizador de isotiourea inmovilizado (11 ciclos, TON acumulado de 76,8) y su aplicación en un proceso de flujo continuo (sin disminución del rendimiento o ee después de 18 h). En el capítulo IV se investiga una cicloadición [8 + 2], de orden superior, asimétrica y periselectiva entre enolatos de amonio quiral y azaheptafulvenos, mediada por un catalizador de isotiourea inmovilizado. Los productos de cicloadición [8 + 2] resultantes son asimismo susceptibles de derivatización vía cicloadición [4 + 2] completamente regioselectiva con dienófilos activos para proporcionar productos policíclicos de una manera directa. El último capítulo se centra en una reacción en cascada consistente en desoligomerización de paraldehído/reacción aldólica cruzada de benzaldehídos pobres en electrones (o el complejo η6-benzaldehído Cr(CO)3), promovida por un sistema catalítico dual. Además, los productos obtenidos pueden derivatizarse fácilmente a medicamentos o intermedios de productos naturales.
This thesis focuses on the synthesis of organocatalysts, especially polymer-supported ones and their application in various asymmetric transformations. In Chapter II, an efficient, highly regio- and stereoselective [4+2] cycloaddition between alkylidene pyrazolones and enals through H-bond-directing dienamine catalysis has been developed. Chapter III describes a robust, highly efficient polystyrene-supported (PS) isothiourea organocatalyst in a variety of formal [4+2] cycloaddition reactions. In addition, recyclability of the immobilized isothiourea catalyst (11 cycles, accumulated TON of 76.8) and its application in continuous flow process (no decrease in yield or ee after 18 h) are also demonstrated. Chapter IV investigates an asymmetric periselective [8+2] higher-order cycloaddition between chiral ammonium enolates and azaheptafulvenes catalyzed by an immobilized isothiourea catalyst. The resulting [8+2] cycloadducts can also undergo completely regioselective [4+2] cycloaddition with active dienophiles to afford bridged polycyclic products in a straightforward manner. The last Chapter focuses on the cascade deoligomerization/cross-aldol reactions of electron-poor benzaldehydes or η6-benzaldehyde Cr(CO)3 complex with paraldehyde can be promoted by a dual catalytic system. Moreover, the obtained products can be easily transferred to medicinal drugs or natural product intermediates.
Treaster, Morgan K., Fuschia Sirois, Martin Offenbächer, Loren Touissant, Niko Kohls, Eberhard Nöfer y Jameson K. Hirsch. "Social Support and Psychological Distress in Cancer: Stress as a Mediator". Digital Commons @ East Tennessee State University, 2018. https://dc.etsu.edu/asrf/2018/schedule/33.
Texto completoWong, Jamie Lynne. "Social Support as a Mediator Between Attachment and Relapse in women". ScholarWorks, 2015. https://scholarworks.waldenu.edu/dissertations/1870.
Texto completoDucksworth, Letatia Bright. "Supporting Computer-Mediated Collaboration through User Customized Agents". Thesis, University of North Texas, 2001. https://digital.library.unt.edu/ark:/67531/metadc3055/.
Texto completoXia, Xuanshu y 夏轩庶. "Development of phosphorus-mediated reactions in organic synthesis / y Xia Xuanshu, B. Sc., Sun Yat-sen U". Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/209480.
Texto completopublished_or_final_version
Chemistry
Doctoral
Doctor of Philosophy
Atkins, Anthony B. "Mixed Media Richness and Computer-Mediated Communications". Thesis, Virginia Tech, 2006. http://hdl.handle.net/10919/31794.
Texto completoMedia Richness Theory (Daft & Lengel, 1984, 1986) defines the richness of a communication medium in terms of its ability to reduce uncertainty and equivocality. According to Daft and Lengelâ s task-media fit hypothesis, communications are most effective and satisfying when the media richness matches the level of uncertainty and equivocality in a task.
Social presence is the perceived ability of a medium to transmit the social cues that lead to a sense that the medium is â warm, personal, sensitive, and sociableâ (Short, Williams, & Christie, 1976). Social presence has been suggested to be a predictor of user satisfaction for computer-mediated communications (CMC), and has been used as measure of media richness in previous studies (Rice, 1993; Yoo & Alavi, 2001).
This study examined the effects of communication medium and task equivocality on task performance, communication effectiveness and sense of social presence. Pairs of participants were required to complete high and low equivocality collaborative tasks while communicating with each other using CMC. The communication media varied between participants. During some sessions, participants received and transmitted the same media (video-only or text-only). In other cases, participants transmitted text and received video or vice-versa.
From the recorded transcripts of each user session was extracted task performance in terms of task time-to-complete and communication effectiveness in terms of the frequency of communication breakdowns. Based on the task-media fit hypothesis, it was expected that task performance and communication effectiveness would be affected by the interaction between communication medium and task equivocality. For the most part, task-media fitness was not confirmed. Only one of the four hypotheses supporting task-media fitness was confirmed for time-to-complete, and none of the four hypotheses supporting task-media-fitness was confirmed for communication breakdown frequency. In the overall analysis of time to complete, Medium was found to have had a significant effect. Sending and receiving text was significantly slower than all other tested media. Sending and receiving video was significantly faster than all other tested media combinations.
After completing each task, participants completed a short questionnaire designed to measure the sense of social presence using the original scales developed by Short and Christie. The sense of social presence reported in video communications was significantly higher for all scales than the sense of social presence reported in mixed-richness environments. The sense of social presence reported in text communications was only significantly lower than mixed-richness environments for one scale, with no significant difference for all other scales.
Master of Science
Taylor, Jacqueline Ann. "Electronic mail, communication and social identity : a social psychological analysis of computer-mediated interactions". Thesis, University of Portsmouth, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282542.
Texto completoBurke, Moira. "Reading, Writing, Relationships: The Impact of Social Network Sites on Relationships and Well-Being". Research Showcase @ CMU, 2011. http://repository.cmu.edu/dissertations/185.
Texto completoBandy, Kenneth E. "Computer Supported Collaboration: Is the Transfer of Cognitive Structures Mediated by Mode of Communication?" Thesis, University of North Texas, 2002. https://digital.library.unt.edu/ark:/67531/metadc3162/.
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