Tesis sobre el tema "Mécanismes de transfert de chaleur"
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Simon, Pascal. "Modélisation et simulation des mécanismes de la combustion hybride dans un système propulsif". Poitiers, 1996. http://www.theses.fr/1996POIT2384.
Texto completoPeregrina-Cambero, Carlos-Alberto. "Traitement des boues par friture : des mécanismes physiques à l'éco-conception d'un procédé". Lyon, INSA, 2005. http://theses.insa-lyon.fr/publication/2005ISAL0089/these.pdf.
Texto completoLe procédé de séchage par friture consiste à mettre en contact une phase solide humide divisée (la boue d'épuration) et une phase liquide non miscible (une huile alimentaire usagée), chauffée entre 120 et 180°C, pour obtenir un solide granulaire stable, hygiénisé et valorisable notamment comme combustible. Une étude expérimentale à l'échelle du laboratoire a permis d'identifier les différents mécanismes de transfert de chaleur et de masse mis en jeu lors de l'opération de friture de boue et d'optimiser les paramètres opératoires. Aux temps courts, les phénomènes limitants sont d'origine thermique. Aux temps longs, la limitation des transferts provient du transport d'huile au sein de la matrice poreuse puis du transfert de matière en phase vapeur. Une Analyse de Cycle de Vie (ACV) a été mise en œuvre pour évaluer les performances environnementales d'une filière thermique " séchage + incinération " de valorisation des boues. Le scénario de référence fait appel à un séchage par contact avec agitation tandis que le scénario alternatif prévoit un séchage par friture. Parmi les quatre catégories d'impact retenues, le séchage par friture s'avère extrêmement performant en terme de consommation des ressources non renouvelables et d'impact sur le changement climatique. Enfin, la simulation d'un procédé continu, fonctionnant sur la base d'une production d'une tonne par heure de boues auto-combustibles, avec différents systèmes de récupération de l'énergie contenue dans les buées a été réalisée à l'aide d'un logiciel du commerce. Ce dimensionnement a servi de base à une évaluation économique des coûts d'investissement et de fonctionnement de l'installation
Hoang, Hong Minh. "Analyse des mécanismes turbulents au sein d'un écoulement anisotherme entre parois ondulées : influence sur le transfert thermique". Chasseneuil-du-Poitou, Ecole nationale supérieure de mécanique et d'aéronautique, 2009. http://www.theses.fr/2009ESMA0011.
Texto completoKnowledge of of turbulent mechanisms in wavy channel so far is still limited despite the work done in the past decade because of the complexity of geometrical factors and the small size which makes experiments difficult. This thesis examines the role played by turbulence inwavy channel and its influence on heat transfer. The dynamic behaviour is characterized by the mean and fluctuating flow through PIV measurements (rapid and standard) and large eddy simulation (LES). Quantification of heat transfer is obtained by wall thermocouples while temperature fields are described by LES. The wavy induces the average behaviour of the flow. Indeed, the longitudinal and transverse components are periodic, while the vertical component is related to confinement. In steady state, the flow presents specific areas: a shear layer is generated below the crest, accompanied by strong correlated longitudinal and transverse fluctuations, the development of this layer occurs in the concave part of the wavy-channel (called through) ; in the downstream of the through, the shear layer impacts on the wall and a significant increase in vertical fluctuations is observed. The analysis of turbulent kinetic energy showed a complex behaviour: production is related to the shear layer, dissipation occurs in the through, but some energy is diffused or convected towards the wall or the central flow. Although fluctuations of temperature are mostly located in the shear layer, the maximum heat transfer occurs in the impact zone. To complete the study, experimental and numerical work were carried out for different spacings between walls, and different wavy amplitudes. These results have extended the knowledge of the role of these parameters and quantified their influence on the dynamic and thermal behaviour: the increase of turbulence intensity and of heat transfer is obtained with a geater waviness or a larger distance between wavy walls. These results are essential to optimize performance of wavy fins compact heat exchangers
Brun, Emmanuel Camille Marius. "De l'imagerie 3D des structures à l'étude des mécanismes de transport en milieux cellulaires". Aix-Marseille 1, 2009. http://www.theses.fr/2009AIX11014.
Texto completoFew works deals with real geometry to study the impact of structure on transport properties of cellular material. Tools developed during this phd permit a precise geometrical characterization os cellular solids. Our approach is based on the combined use of the morphological analysis software 3D developed during the phd (iMorph) and numerical simulation of heat and mass transfer on real geometry obtained by X-ray tomography. With this approaches, and the study on a wide range of metallic foams, we identify the geometrical relevant criteria for the transport properties understanding (Conductivity, Fluid flow and Radiative transfer). Moreover we estimate Representative Volume Element for both geometrical and fluid flow properties. We developed a multi object segmentation algorithm based on local inertia moments. This original method allow a classification of a trabecular bone database based on the plate volume ratio
Thomas, Anthony. "Transfert d'eau et de chaleur dans une pile à combustible à membrane : mise en évidence expérimentale du couplage et analyse des mécanismes". Thesis, Université de Lorraine, 2012. http://www.theses.fr/2012LORR0143/document.
Texto completoProton exchange membrane fuel cells (PEMFC) make it possible to convert efficiently chemical energy into electricity. For this, hydrogen is oxidized at one of the electrodes of the cell, created protons pass through the electrolyte (membrane) while electrons flow across the external circuit provide the electrical energy. All these elements recombine at the second electrode, with oxygen, to produce water. Performance is not perfect within a cell and a part of the reactants energy is also degraded as heat. Despite recent advances, the large scale commercialization of PEMFC is still hampered by durability issues, some of them being related to water and thermal management. In order to quantify the thermal behavior and its effect on the water transport, a fuel cell has been instrumented for the electrodes temperature, water and heat fluxes measurement. The results show that high temperature gradients (up to about 30 K/mm) can exist in a cell operating under standard conditions. It was observed a clear influence of the temperature field in the cell on the water transport. Water flows towards the coldest part of the cell (usually the channels), passing through the porous layers in vapor phase in our experimental conditions
Bennai, Fares. "Étude des mécanismes de transferts couplés de chaleur et d’humidité dans les matériaux poreux de construction en régime insaturé". Thesis, La Rochelle, 2017. http://www.theses.fr/2017LAROS013/document.
Texto completoThe aim of this work is to understand the influence of the geometric parameters of envelope eco-materials, such as hemp concrete, on the mechanisms of coupled heat, air and moisture transfers, in order to predict behavior of the building to control and improving it in its durability. For this a multi-scale approach is implemented. It consists of mastering the dominant physical phenomena and their interactions on the microscopic scale. Followed by a dual-scale modeling, microscopic-macroscopic, of coupled heat, air and moisture transfers that takes into account the intrinsic properties and microstructural topology of the material using X-ray tomography combined with the correlation of 2D and 3D images. A characterization campaign of physical and hydrothermal properties of the hemp concrete manufactured in the laboratory was carried. It focused on studying the impact of aging, thermal and hydric state of the material on these intrinsic properties. The results show an excellent thermal insulation and natural moisture regulation capacity of hemp concrete. Then, a microscopic characterization by different imaging techniques was performed. The 3D reconstructions of the real material scanned with X-ray tomography at different resolutions show that hemp concrete has several scales of porosity, ranging from micro-porosity within the binder and hemp shiv to the inter-particle macro-porosity. The hydromorphic behavior under hydric solicitations was studied. The results of the 2D digital image correlation and X-ray tomography coupled with the volumetric image correlation show the nature of the behavior of hemp concrete subjected to different relative humidities. In fact, the hemp shiv undergoes greater deformations than the binder, thus causing changes in the microstructure of the material. On the modeling part, a model of coupled heat, air and moisture transfer in porous building materials was developed using the periodic homogenization technique. The homogenized tensors of diffusion and thermal conductivity were determined numerically. Then, a confrontation between the results of the calculation of the macroscopic diffusion coefficients and the experimental results obtained at the LaSIE was carried out. It highlights the quality of the prediction. In addition, the thermal conductivity of the solid phase was thus deduced. The results obtained in the framework of this PhD thesis have highlighted the influence of the hydric and thermal state of the hemp concrete on these intrinsic properties and its very heterogeneous microstructure. They also revealed the limitations of phenomenological approaches based on the establishment of the balances of mass, amount of motion and energy
Arlabosse, Patricia. "Etude des transferts de chaleur et de masse par effet Marangoni : application à la compréhension du mécanisme de l'ébullition en apesanteur". Aix-Marseille 1, 1997. http://www.theses.fr/1997AIX11024.
Texto completoLottin, Olivier. "Étude du fonctionnement des réacteurs d'une pompe à chaleur à compression-absorption : modélisation des mécanismes de changement d'état d'un fluide binaire zéotrope s'écoulant en film tombant sur une plaque plane verticale". Nancy 1, 1996. http://www.theses.fr/1996NAN10315.
Texto completoThis report is a study of the absorber and the desorber of an absorptioncompression heat pump, which are falling film type reactors using vertical plates geometry. Two kinds of models with coupled heat and mass transfers are detailled. The first one is based on local equations using thermal and molecular diffusivities ; it allows the calculation of Nusselt and Sherwood numbers. The second one is based on equations using heat and mass transfer coefficient. Both models give heat flux and mass flux in the liquid solution and in the vapor. The influence of the value of heat and mass coefficients that appear in the second, model on the global performances of the absorption-compression cycle is presented. Sorne results are compared with measurements made on an experimental heat pump. A second experimental study is made to compare the efficiency of different corrugated plates used in the reactors
Lefebvre, Xavier. "Analyse des mécanismes physico-chimiques et biochimiques en vue d'optimiser le traitement biologique aérobie des résidus lipidiques". Toulouse, INSA, 2001. http://www.theses.fr/2001ISAT0022.
Texto completoGrease residues are high concentrated semi-solid waste, treated by sequential batch reactor. Foaming makes the treatment process unreliable. Physical, chemical and biochemical processes evolving during the grease residues degradation are analysed for the design of optimal reactor monitoring. Insoluble fatty acids are main compounds. Semi-solid grease sorbs to water/air and water/flocs interfaces. In reactor operation conditions (pH = 7, Substrate/Micro-organisms (S/X) = 0. 1 g/g), more than 97% of grease is sorbed to biomass and must be solubilised by a pH-dependent process (pKa = 8) before their biological assimilation. The degradation kinetics is controlled by the sorbed grease solubilisation. The reaction order is 0 (k = 0. 5 day-1, T = 25ʿC). Two foaming mechanisms are identified. The inhibition conditions are determined (pH < 7,5 ; S/X < 0. 3 g VS/g HEM ; Ssoluble < CMC). Different optimal operation modes, based on modelling, are proposed. A partial parameters sensitivity analysis (degradation and biomass yield) is performed
Thomas, Anthony. "Transferts d'eau et de chaleur dans une pile à combustible à membrane : mise en évidence expérimentale du couplage et analyse des mécanismes". Phd thesis, Université de Lorraine, 2012. http://tel.archives-ouvertes.fr/tel-00820468.
Texto completoWirth, David. "Etude de la distillation membranaire sous vide pour le dessalement d'eau de mer : de l'analyse des mécanismes de transfert à l'optimisation énergétique du procédé". Toulouse, INSA, 2002. http://www.theses.fr/2002ISAT0040.
Texto completoThe aim of this thesis was to study the feasibility of vacuum membrane distillation process for seawater desalination. The first part shows different experimental results obtained with hollow fibre modules containing macro-porous membranes. Two module configurations, inside/out and outside/in, were investigated in order to determine the influence of hydrodynamics on heat and mass transfer. The influence of concentration and temperature polarisation on permeate flux was characterised. In a second part of the study, a modelling of transfer phenomena was developed and validated by experimental results. Longitudinal profiles of temperature and concentration were considered. Two plant design were considered and an analysis of energy consumption, for these plants, allow us to conclude on the potentiality of VMD for water desalination, in comparison with reverse osmosis
Maquet, Jean. "Contribution à l'étude des mécanismes de surstabilité d'une surface libre chauffée par un laser ou un fil chaud". Rouen, 1987. http://www.theses.fr/1987ROUES047.
Texto completoSimo, tala Jules voguelin. "Analyse des structures tourbillonnaires et des mécanismes de transfert thermique dans les échangeurs de chaleur multi-rangs de tubes ailetés : Amélioration et optimisation des performances thermoaérauliques". Phd thesis, Université de Valenciennes et du Hainaut-Cambresis, 2012. http://tel.archives-ouvertes.fr/tel-00718623.
Texto completoSimo, Tala Jules Voguelin. "Analyse des structures tourbillonnaires et des mécanismes de transfert thermique dans les échangeurs de chaleur multi-rangs de tubes ailetés : Amélioration et optimisation des performances thermoaérauliques". Thesis, Valenciennes, 2012. http://www.theses.fr/2012VALE0015.
Texto completoIn this thesis, we analyze the flow and convective heat transfer in multi-row plain fin and tube heat exchangers. The aeraulic phenomena that occur in these devices are first highlighted by means of PIV and LDA measurements. A local study of horseshoe vortices production, development, spatial evolution and dissipation is therefore performed. Secondly, Unsteady RANS modeling of the flow is carried out by means of numerical simulations and the results are validated by comparing theflow structure and the vortex dynamics with experimental data. In a third step, the influence of these vortices on heat transfer is highlighted. The thermalhydraulic performances are characterized on the basis of an analysis of synergy between the velocity field, velocity gradients and temperature gradients.The thermal and viscous entropy rate generated in the flow are locally characterized. In a fourth step, an analysis of the influence of the tube pattern on thermalhydraulic performances is performed by considering the first and the second law of thermodynamics. The convective heat transfer and wallviscous friction losses are evaluated as well as thermal and viscous entropy production rates. Finally an overall geometrical optimization process based on the factorial analysis of TAGUCHI is used to select the major parameters that affect the thermalhydraulic performances aiming to optimize the design ofmultirow plain fin-and-tube heat exchangers for HVAC applications in rail transport
Cornet, Jean-Michel. "Approche modale des transferts aérauliques dans le bâtiment : mécanismes d’instabilité, bifurcations et dynamique non-linéaire". Lyon, INSA, 1995. http://www.theses.fr/1995ISAL0117.
Texto completo[Thermal comfort relies on a set of fundamental parameters such as the velocity and temperature fields, However the remains a lack of knowledge regarding g the transition between the air flow regimes, we intend to establish a methodology suited to the search of bifurcation of convective flows using a linear stability analysis, followed by a non-linear approach allowing us to definite a relation between amplitude an d frequency of the perturbation, Th e combination of the various numerical methods to compute on one band the basic solution and on the other hand the perturbation, is validated using the case study of double convective boundary layer flow. A generalisation of this set of numerical procedures is applied to the search of the bifurcation in e thermally-driven cavity. This method shows a good agreement with available experimental and numerical data. ]
Léal, Laetitia. "Étude des mécanismes de nucléation par action simultanée de l'ébullition et de la cavitation". Toulouse 3, 2012. http://thesesups.ups-tlse.fr/1928/.
Texto completoBoiling is used in heat transfer enhancement techniques due to the high heat transfer coefficient which can be reached. However, the onset of boiling requires high wall temperatures. A technique to control the onset of nucleation is proposed. It consists in the dynamic deformation of a confinement wall which induces oscillations of the liquid pressure over time. This technique provides nucleation by simultaneous cavitation and boiling. The experimental device developed shows the efficiency of this technique: the temperature required for boiling incipience is greatly decreased. In addition, the physical mechanisms involved in this configuration differ from those predicted by existing theories of nucleation: some dynamic effects have a major effect on the conditions of nucleation. A theoretical study identified the physics governing the evolution of an embryo trapped in a cavity where it is subjected to a heat flux and where the liquid pressure oscillates. Furthermore, the effects of the dynamics and the hysteresis of the contact angle on nucleation incipience conditions have been approached from a theoretical point of view. It seems that these phenomena can be dominant mechanisms of nucleation by the simultaneous action of boiling and cavitation. Parallel to this study, a prototype of a compact heat exchanger incorporating the pumping function of the fluid has been designed
Reiss, Corentin. "Modélisation des écoulements bouillants en réacteur nucléaire par CFD : application à la prédiction du flux critique". Electronic Thesis or Diss., Université de Toulouse (2023-....), 2024. http://www.theses.fr/2024TLSEP080.
Texto completoUnder incidental conditions in pressurized water reactors, the water used to cool the nuclear fuel can start to boil. It is essential to predict the dynamics of such multi-phase flows to guarantee reactor safety. The methods currently used in the industry today are focused on the large-scale characteristics of the flows and require specific experiments for every geometry and flow configuration. The aim of the present work is to build a numerical tool and a set of physical models to predict the characteristics of boiling flows in nuclear reactor conditions at a local scale, in a framework called computational fluid dynamics (CFD). In the future, this will enable us to simulate configurations where no experiment is available. We develop a multiphase module in CEA's TrioCFD open-source CFD code. A Reynolds averaged Navier-Stokes two-fluid framework that can solve a mass, momentum and energy equation for an arbitrary number of phases is implemented in two different numerical schemes: one that enables good performance on Cartesian and axisymmetric grids and one that can handle arbitrary polynomial meshes. For multiphase flows, standard drag, lift, turbulent dispersion and wall repulsion forces are coded. The software is validated on standard atmospheric-pressure adiabatic databases where the simulations agree with experimental data. A condensation term and a heat flux partition are added to this set of closures to simulate boiling flows. We first use the DEBORA database, a Freon-filled tube, to evaluate the performance of our set of closures. The experimental bubble diameter is enforced in the code along the whole length of the test section, enabling simulations without the uncertainty of interfacial area transport equations. The predicted void fraction profiles are far from the experimental results, often too high in the near-wall region. This prompts us to investigate the onset of significant void (OSV) in CFD codes. Using experimental data from a dozen different sources, we construct an OSV database. Combining this database with experimental liquid temperature measurements in boiling flows, we show that the OSV in a stationary developed flow occurs when the turbulent boundary layer reaches saturation temperature. This criterion is used to develop a simple heat flux partition that improves results on the DEBORA database compared with the closures from the literature. We then work on improving the bulk closure terms adapted to high-pressure, heat flux, mass flux and void fraction conditions of nuclear reactors. We show that in this situation, bubbles are deformable, i‧e. non-spherical. We use this to construct our own lift coefficient and condensation term, and combine them with references from the literature for drag and turbulent dispersion. Innovatively, no interfacial area equation or population balance is required. This set of closures provides good agreement with the DEBORA experiment. To extend the validation, we built a database that includes recent and ancient high-pressure (>40bar) local void fraction measures in pipes, annulus and channels. The results obtained in 114 test conditions are close to experimental data. We then simulate critical heat flux (CHF) experiments to obtain physical quantities in the near-wall region at the boiling crisis. By analyzing these results, we build an empirical CHF criterion for stationary flows where the liquid remains subcooled in the near-wall region. It predicts the CHF with ~10% precision
Rivière, Lisa. "Analyse des mécanismes de conduction thermique dans les composites structuraux PEEK/particules submicroniques d'argent". Thesis, Toulouse 3, 2016. http://www.theses.fr/2016TOU30200/document.
Texto completoThis work deals with the optimization of thermal transport mechanisms in polymer-based composites. It has been demonstrated that the introduction of conductive particles in a polymer matrix contributes to thermal conductivity enhancement. At macroscopic scale, resistive mechanisms are ruled by a complex set of parameters: constituents' nature, dispersed phase morphology and matrix/particles interactions. The influence of these parameters on PEEK/silver submicron particles composites has been studied. Experimental data have been compared to models to analyse the structural origin of thermal conductivity evolution. A global approach to study heat transport mechanisms imply the multiscale understanding of capacitive and diffusive contributions. Heat capacity, thermal diffusivity and thermal conductivity have been studied as a function of particles content and temperature
Chapuis, Sylvie. "Mécanismes d'intéraction entre un jet gazeux chargé de particules et une surface solide, en vue de dépôt de couches minces sur verre chaud". Vandoeuvre-les-Nancy, INPL, 1991. http://www.theses.fr/1991INPL061N.
Texto completoMansour, Mounir. "Etude expérimentale et modélisation de l'oxydation sèche d'une poudre de nanoparticules de cuivre". Phd thesis, Ecole Nationale Supérieure des Mines de Saint-Etienne, 2013. http://tel.archives-ouvertes.fr/tel-00846994.
Texto completoKannengieser, Olivier. "Étude de l'ébullition sur plaque plane en microgravité, application aux réservoirs cryogéniques des fusées Ariane V". Thesis, Toulouse, INPT, 2009. http://www.theses.fr/2009INPT068H/document.
Texto completoBetween the different propulsion phases, the Ariane V rocket passes through microgravity periods and solar radiation can induce boiling in its cryogenics tanks. Experiments were performed during 6 parabolic flights and in a sounding rocket to study pool boiling in microgravity. In the parabolic flight experiments, the influence of pressure, subcooling and surface roughness was studied. It is showed that subcooling has a weak effect on microgravity boiling heat transfer, and that roughness is an important factor also in microgravity. Detailed results on the behavior of bubbles and on the superheated liquid layer show that the heat transfer mechanisms can be divided in two groups : the primary mechanisms which directly take energy from the wall and the secondary mechanisms which transport the energy stored in the fluid by the primary mechanisms, from the vicinity of the wall to the bulk liquid. The secondary mechanisms appear not to limit primary mechanism heat transfer which explains the weak influence of gravity on heat transfer. From the study of equations governing primary mechanisms and the definition of new scales, a correlation is built to predict heat transfer in microgravity for a wide variety of fluids. In the sounding rocket experiment, the influence of non-condensable gases was studied. The existence of two regimes of boiling heat transfer with non-condensable gas is established. The temperature in the primary bubble is directly measured and the influences of both Marangoni convection and non-condensable gas on both heat transfer and bubble growth are also considered
Yoshida, Yukihiro. "Effet élastocalorique dans le caoutchouc naturel et le terpolymère : Mécanismes responsables de la variation de température et bilan énergétique sous déformation". Thesis, Lyon, 2016. http://www.theses.fr/2016LYSEI070.
Texto completoCaloric effects (CEs), which are the phenomena that temperature variation is caused by entropy change, have been investigated for the novel system which might be able to replace conventional vapor compression refrigeration system. In the present thesis, the elastocaloric effect (ElCE) of natural rubber (NR) and terpolymer, poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) (P(VDF-TrFE-CTFE)), was focused. First of all, NR, which is an excellent candidate material for ElCE, was evaluated in cyclic deformation with different strain levels. It was found that NR exhibits temperature variation of around 4.0 °C. In general, the relation between stress/strain versus temperature variation is used to evaluate ElCE. The unsuitability of such evaluation method for NR was demonstrated. The evaluation method for ElCE which uses energy balance was then proposed. A linear relation between the temperature variation caused by ElCE and the applied mechanical energy by deformation was experimentally found. This fact verifies the suitability of the proposed method. Using the energy balance, besides, not only the conversion efficiency but also the influences of the Mullins effect and the strain-induced crystallization on the ElCE of NR were discussed. ElCE of P(VDF-TrFE-CTFE) was also evaluated in order to find out the potential of polymer. It was found that present terpolymer which is not one of the elastomers can also exhibit a large temperature variation, 2.1 °C, caused by ElCE if a large pre-stretch such as more than 1050 % is applied in advance. By comparison with other materials for ElCE, it was demonstrated that P(VDF-TrFE-CTFE) can be a high potential material for ElCE. It was also shown that P(VDF-TrFE-CTFE) converts most of the applied mechanical energy into the heat energy
Mansour, Mounir. "Etude expérimentale et modélisation de l’oxydation sèche d’une poudre de nanoparticules de cuivre". Thesis, Saint-Etienne, EMSE, 2013. http://www.theses.fr/2013EMSE0697/document.
Texto completoThe oxidation of copper nanoparticles at 120 – 145°C was investigated using TGA, DSC, XRD, SEM, TEM and nitrogen adsorption techniques (BET, BJH,..). Isothermal and isobaric studies of the oxidation reaction were carried out under various oxygen partial pressures 1 kPa – 40 kPa. The cuprous oxide (Cu2O) (the unique product of the reaction) grows in an anisotropic manner by outward diffusion of the copper. A considerable decrease of the specific surface area and the porosity of the powder during the transformation was highlighted.It was found that working under P(O2) ≤ 4 kPa leads to reaction where nucleation of Cu2O is in competition with its growth. The study of the dependency of the growth rate on the oxygen partial pressure has shown the adsorption of oxygen to be the rate-determining step. However, when the reaction is conducted under P(O2) ≥ 20 kPa, the nucleation occurs instantaneously in the early beginning of the reaction which will be governed by the growth process. Under these latter conditions of oxygen partial pressure the diffusion of copper ionized vacancies becomes the rate determining step. Hence, two kinetic models have been established to interpret the experimental curves in the two different oxygen partial pressure ranges. The expression of the extent of conversion was successfully confronted to the kinetic data up to an extent of conversion corresponding to the slowdown of the reaction. The kinetic model for P(O2) ≤ 4 kPa was coupled with mass and heat transfer within the porous agglomerate to verify if the diffusion of oxygen molecules in pores is in the origin of the reaction slowdown, this latter hypothesis was found not satisfactory
Canini, Frédéric. "Mécanismes centraux du coup de chaleur". Lyon 1, 1998. http://www.theses.fr/1998LYO1T149.
Texto completoLin, Thibault. "Mécanismes du transfert intercellulaire des homéoprotéines". Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066346/document.
Texto completoHomeoproteins belong to a family of transcription factors which all share a common DNA binding domain, the homeodomain. Beside their action as transcription factors, homeoproteins are also able to be transferred between cells by unconventional means. The two consecutive steps of this intercellular transfer (secretion then internalisation) require sequences located in the homeodomain. Thanks to studies previously lead by our laboratory, we know that subcellular localisation of ENGRAILED-2 (EN-2) homeoprotein is a crucial step in its subsequent secretion. On this basis, we showed that EN-2 interacts directly with a certain subtype of phospholipids, phosphoinositides [e.g. PI(4,5)P2]. Then, we demonstrated than these lipids are involved in the association of EN-2 protein with membraneous compartments within the cell. PI(4,5)P2 located in the inner leaflet of the plasma membrane are also involved in the direct translocation of EN-2 across plasma membrane. This work is also focused on the role of proteoglycans, and more precisely syndecans, in EN-2 cell surface accumulation after both secretion and internalisation. At last, we also established the implication of EN-2 interaction domain with PBX in EN-2 intercellular transfer
Lin, Thibault. "Mécanismes du transfert intercellulaire des homéoprotéines". Electronic Thesis or Diss., Paris 6, 2015. http://www.theses.fr/2015PA066346.
Texto completoHomeoproteins belong to a family of transcription factors which all share a common DNA binding domain, the homeodomain. Beside their action as transcription factors, homeoproteins are also able to be transferred between cells by unconventional means. The two consecutive steps of this intercellular transfer (secretion then internalisation) require sequences located in the homeodomain. Thanks to studies previously lead by our laboratory, we know that subcellular localisation of ENGRAILED-2 (EN-2) homeoprotein is a crucial step in its subsequent secretion. On this basis, we showed that EN-2 interacts directly with a certain subtype of phospholipids, phosphoinositides [e.g. PI(4,5)P2]. Then, we demonstrated than these lipids are involved in the association of EN-2 protein with membraneous compartments within the cell. PI(4,5)P2 located in the inner leaflet of the plasma membrane are also involved in the direct translocation of EN-2 across plasma membrane. This work is also focused on the role of proteoglycans, and more precisely syndecans, in EN-2 cell surface accumulation after both secretion and internalisation. At last, we also established the implication of EN-2 interaction domain with PBX in EN-2 intercellular transfer
Draoui, Abdeslam. "Etudes numériques des transferts de chaleur couples rayonnement-conduction et rayonnement-convection dans un milieu semi-transparent bidimensionnel". Lyon, INSA, 1989. http://www.theses.fr/1989ISAL0012.
Texto completoThe works we present here are a numerical approach of heat transfer coupling radiation-conduction and radiation-convection within semi-transparent two-dimensional medium ; The first part deals with a view of equation of radiative transfer and introduces three numerical methods (P1, P2, Hottel's zone) which enable one to solve this problem in a two dimensional environment. After comparing the three methods in the case where radiation is the only mode of transfer, we introduce in the second chapter a study of the coupling of radiation with conduction. So, a fourth method is used to solve the problem. These comparisons lead us to various methods which enable us to show the interest of the spherical harmonics approximations. In the third part, the P1 approximations is kept because it is simple to use, moreover it enables us to introduce both the coupling of radiative transfers with laminar convective equations in a thermally driven two-dimensional cavity. The results show a significant influence of the radiative participation of the fluid on heat and dynamic transfer we met in this type of problem
Hamza, Anis. "Amélioration du transfert de chaleur à l’interface solide/fluide des échangeurs de Soleil". Thesis, Reims, 2013. http://www.theses.fr/2013REIMS026/document.
Texto completoThe purpose of this Ph. D. thesis is to develop a methodology and an experimental set-up for the study of the heat transfer problem in the cooling of the light beam absorber used in Synchrotron SOLEIL. Three different prototypes of the heat sink with mini-channels and diamond shaped pin fins were manufactured and tested experimentally. The test facility allows the measurements in both atmospheric conditions and under low pressure in a vacuum chamber.Measurement of the thermal contact resistance were also conducted for the heat sinks. This is an important issue in the cooling of the optics on their back side. These resistances have been minimized by the application of a silver thin layer coating.We have proposed here also a basis of a new technique for the resolution of the inverse problem by a combination of several tests with localized heat excitation. This technique has greatly reduced the number of numerical calculations in the adjoint problem and achieved a rapid convergence to the solution. It should be improved for minimizing the effects of the measurement errors on the heat transfer coefficient curve
Abbassi, Mohamed Ammar. "Modélisation des transferts de chaleur par convention-rayonnement dans un four d'incinération des fumées de carbonisation du bois". Perpignan, 2009. http://www.theses.fr/2009PERP0938.
Texto completoThis work deals with a theoretical study of heat and mass transfer by combined mixed convection, radiation and chemical kinetics in an incinerator of wood carbonization with recovery and incineration of the pyrolysis fumes. A thermochemical model was elaborated to predict the temperatures, molar flows (in particular molar flow responsible for the racing of the incineration reaction) and the concentrations in each zone of the pilot plant. The radiative transfers in the gas phase and soot are modelled by applying the weighted sum of the grey gases model. We applied the finite volume method and the "blocked-off-region" procedure to handle the complex geometries. The equations governing the transfers by combined mixed convection, radiation and the chemical kinetics are solved by the finite volume method, TDMA and the SIMPLE algorithms. We analyzed the shadow effect caused by the baffles, the fumes optical thickness, the Boltzmann number, the conduction-radiation parameter, Reynolds number and the Richardson number. We determined the best configuration of the baffles and shown that the increase in the soot volume fraction causes an increase in radiative heat flux and the presence of soot at a temperature different from that of the fume causes a radiative thermal non equilibrium. The partial pressure ratio of H2O and CO2 does not effect the radiative heat flux on the walls of the incinerator. The heat generated by the incineration of the fumes causes intensification and homogenisation of the transfers in a forced convection mode. The results of the thermochemical model are in qualitative and quantitative good agreement with the experimental results
Tonnet, Nicolas. "Dissociation des hydrates de méthane sédimentaires - Couplage transfert de chaleur / transfert de masse". Phd thesis, Ecole Nationale Supérieure des Mines de Saint-Etienne, 2007. http://tel.archives-ouvertes.fr/tel-00326878.
Texto completoDans cette étude, les transferts de masse et de chaleur ont été étudiés numériquement et expérimentalement. Un modèle numérique 2D est proposé dans lequel les transferts de chaleur et de masse gouvernent la dissociation des hydrates de méthane. Les résultats numériques montrent la présence de gradients de pression et de température au sein du milieu poreux et l'évolution de la frontière de dissociation selon le type de sédiment utilisé. Ce modèle est utilisé afin de dimensionner un dispositif expérimental de dissociation de carottes sédimentaires partiellement saturées en hydrates de méthane qui permet un suivi précis de la cinétique de dissociation.
Le montage expérimental est composé de cinq zones cylindriques de même diamètre (1/2 inch) mais de tailles différentes (pour une longueur totale de 2,6 m). Chaque zone est contrôlée en pression et en température. Chaque expérience consiste en une cristallisation d'hydrates de méthane au sein d'un milieu poreux, puis en une dissociation de ces mêmes hydrates par une méthode de contrôle de la pression à une extrémité du dispositif. La cinétique de dissociation est étudiée par le suivi de la pression dans un ballast (situé en aval du dispositif). Les résultats obtenus, via une étude paramétrique, permettent de cibler les paramètres clés de la dissociation de ces hydrates sédimentaires et d'observer leur impact sur la cinétique de dissociation. Deux régimes bien distincts de dissociation sont mis en évidence et caractérisés selon les propriétés du sédiment partiellement saturé en hydrates de méthane. Le rôle de la glace au cours de la dissociation est également étudié pour ces deux types de dissociation.
Enfin, la correspondance des résultats numériques et expérimentaux est mise en évidence par comparaison de courbes de cinétique de dissociation et de courbes d'évolution de la pression au sein du milieu poreux.
Aimar, Pierre. "Mécanismes de transfert de matière en ultrafiltration". Toulouse 3, 1987. http://www.theses.fr/1987TOU30166.
Texto completoLORENZO, THIERRY de. "Transfert de chaleur par convection naturelle en regime variable". Reims, 2000. http://www.theses.fr/2000REIMS016.
Texto completoMathioulakis, Emmanouil. "Contribution à l'étude des transferts de masse et de chaleur en convection naturelle sur une paroi verticale". Paris 12, 1989. http://www.theses.fr/1989PA120015.
Texto completoAlhabobi, Munir. "Étude des échanges thermiques et de la structure turbulente de l'écoulement en convection naturelle à nombre de Rayleigh elevé dans une cavité cubique chauffée par le bas". Paris 12, 1991. http://www.theses.fr/1991PA120018.
Texto completoDelarochelambert, Thierry. "Etude expérimentale et théorique des transferts thermiques couples en convection naturelle à travers une double paroi verticale à haute densité de flux de chaleur". Mulhouse, 1997. http://www.theses.fr/1997MULH0506.
Texto completoGrassi, Henri. "Études expérimentales et théoriques du complexe de transfert de charge TEA (TCNQ)₂". Nice, 1987. http://www.theses.fr/1987NICE4116.
Texto completoSahraoui, Nour-Eddine. "Contribution à l'étude en régime transitoire d'un nouveau modèle approché pour caractériser le comportement thermique d'un local : étude expérimentale des transferts dans les locaux". Lille 1, 1985. http://www.theses.fr/1985LIL10091.
Texto completoMetzger, Thomas. "Dispersion thermique en milieux poreux : caractérisation expérimentale par technique inverse". Vandoeuvre-les-Nancy, INPL, 2002. http://www.theses.fr/2002INPL065N.
Texto completoFoisy, Benoît. "Étude du transfert thermique par convection naturelle autour d'une source de chaleur pulsée dans un réservoir cylindrique isolé". Sherbrooke : Université de Sherbrooke, 2000.
Buscar texto completoGünther, Stéphane. "Étude du comportement des échangeurs de chaleur utilisant des thermosiphons comme mode de transfert thermique". Sherbrooke : Université de Sherbrooke, 2000.
Buscar texto completoMikasser, Siham. "Transfert de masse et de chaleur dans les Injecteurs-condenseurs". Lyon, INSA, 2004. http://theses.insa-lyon.fr/publication/2004ISAL0008/these.pdf.
Texto completoThis study develops a physic and thermodynamic investigation of the condensing-injector that allows understanding the assumption of operating and the various physics phenomena intervening. Then, an experimental study concerning the small size condensing-injector was proposed. Lastly, the modelling of the flows were approached in two forms: a total modelling 0D of the condensing-injector and a modelling 1D of the mixing chamber. Thus, 3 analytical formulations were employed for distinct flow patterns in the mixing chamber. The 1st part is a two-phase flow model based on a system in 6 equations of transport coupled with an equation of the witness fraction. The 2nd part resumes the homogeneous mode that composed of 3 equations of transport. The occurrence of shock phenomena is possible in the throat of the mixing chamber, so the analytical formulation of the condensation shock is described according to conditions shock
Kaemmerlen, Aurélie. "Transfert de chaleur à travers les isolants thermiques du bâtiment". Thesis, Nancy 1, 2009. http://www.theses.fr/2009NAN10102/document.
Texto completoThe objective of this study is to better understand the mechanisms of the coupling radiative-conductive heat transfer of thermal building insulators used in a transient regime. Two insulating materials were studied in this work: extruded polystyrene foam (XPS) and wood wool. The radiative properties were determined using the inverse method. We demonstrated that the contribution of the radiative heat transfer of the wood wool was quite small. For XPS, radiative properties are more significant and are a function of the foam morphological structure as well as the optical indices of the polymer matrix. A model was developed for isotropic XPS material, however additional developments are needed to better characterize the effects of the foam anisotropy. The coupling radiative-conductive heat transfer in a transient regime was analyzed and validated with the heat flux meter measurement. The experiments were performed with a single insulating element and with various combinations of them. For building thermal insulation in a transient regime, we demonstrated the heat fluxes at the borders of insulators, determined by the coupling solution, are identical when considering the total thermal conductivity which includes radiative and conductive heat transfer. The individual contribution of radiative and conductive heat transfer was not noticeable, however the thermal inertia of the material contributed to delay the heat peak
Jain, Pankaj. "Étude du transfert de chaleur convectif dans un four circulaire /". Thèse, Chicoutimi : Université du Québec à Chicoutimi, 1996. http://theses.uqac.ca.
Texto completoMikasser, Siham Lallemand André Léone Jean-François. "Transfert de masse et de chaleur dans les Injecteurs-condenseurs". Villeurbanne : Doc'INSA, 2005. http://docinsa.insa-lyon.fr/these/pont.php?id=mikasser.
Texto completoGhorayeb, Kassem. "Étude des écoulements de convection thermosolutale en cavité rectangulaire". Toulouse 3, 1997. http://www.theses.fr/1997TOU30111.
Texto completoZeghmati, Belkacem. "Etude du couplage entre les équations de Luikov et celles de la couche limite laminaire en convection naturelle au-dessus d'une plaque plane inclinée". Perpignan, 1988. http://www.theses.fr/1988PERP0053.
Texto completoRetiel, Noureddine. "Etude numérique de la convection thermosolutale en cavité annulaire : solutions stationnaires et instationnaires". Poitiers, 1995. http://www.theses.fr/1995POIT2279.
Texto completoDemasles, Hélène. "Etude des transferts de chaleur d'un fluide frigoporteur diphasique à changement de phase liquide-solide dans un échangeur à plaques lisses". Lyon, INSA, 2002. http://theses.insa-lyon.fr/publication/2002ISAL0022/these.pdf.
Texto completoThe purpose of the work is to study diphasique mixture heat exchange composed of water particles suspended in siliconed oil circulating in a closed loop. Water, contained in polymer porous matrix, is freezing by successive passages in plane plate heat exchanger. Thermo-hydraulic literature data analysis about these fluids in exchangers shows important blanks in exchange coefficient and pressure drop forecast methods and in experimental data. Experimental results, issued of global energy balance on a test section specifically conceived and made for this study, show doping effect on exchange coefficient. Before phase change, microconvective effects of rotating particles improve exchange coefficient of 2,3 factor. Supplementary enhancement included between 2 and 16 appeared during phase change. Trial measured discrepancy are certainly induced by bed layer formation due to low flow speed. At the end of particle freezing, when latent heat is not involved anymore in exchange enhancement, important heat transfer reduction is observed. This is attributed to the cooling suspension rheological evolution and the change of flow particle distribution. Modelling results corroborate heat exchange improvement due to phase change : particles act as sources when discharging there latent heat. They stop fluid temperature dropping and enable to keep a high wall temperature gradient. A deepened suspension rheological study is necessary for a better understanding of observed phenomenon, nevertheless these first results show already an important energetic profit brings by particles in range temperature of 0 and –6 °C
Ngohe-Ekam, Paul-Salomon. "Etude expérimentale des propriétés thermophysiques des bois tropicaux". Lyon 1, 1992. http://www.theses.fr/1992LYO10146.
Texto completoRullié, Laurent. "Etude expérimentale de l'écoulement confiné entre deux protubérances chauffées et de grandes dimensions - effet des parois externes". Poitiers, 1997. http://www.theses.fr/1997POIT2287.
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