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1

Loh, W. K., A. D. Crocombe, M. M. Abdel Wahab y I. A. Ashcroft. "Modelling interfacial degradation using interfacial rupture elements". Journal of Adhesion 79, n.º 12 (diciembre de 2003): 1135–60. http://dx.doi.org/10.1080/714906160.

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2

Turak, Ayse. "Interfacial degradation in organic optoelectronics". RSC Advances 3, n.º 18 (2013): 6188. http://dx.doi.org/10.1039/c2ra22770c.

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3

Crafton, Matthew J., Zijian Cai, Tzu-Yang Huang, Zachary M. Konz, Ning Guo, Wei Tong, Gerbrand Ceder y Bryan D. McCloskey. "Dialing in the Voltage Window: Reconciling Interfacial Degradation and Cycling Performance Decay with Cation-Disordered Rocksalt Cathodes". ECS Meeting Abstracts MA2023-01, n.º 2 (28 de agosto de 2023): 636. http://dx.doi.org/10.1149/ma2023-012636mtgabs.

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Lithium-excess, cation-disordered rocksalt (DRX) materials have received considerable interest as cathode materials for Li-ion batteries, owing to their high specific capacity and compositional flexibility. Despite these advantages, high interfacial reactivity of DRX materials causes extensive oxidative electrolyte degradation at the cathode-electrolyte interface. In addition to consuming electrolyte, this interfacial degradation is likely to lead to a cascade of deleterious effects throughout the cell, as reactive degradation products drive secondary degradation processes like dissolution of transition metals and decomposition of passivating interfacial species. While in-situ gas evolution measurements conducted by differential electrochemical mass spectrometry (DEMS) allow for the observation and quantification of the degradation processes occurring at the DRX surface, the customized cell configuration with which the technique is conducted is not well suited for capturing the performance decay driven by the interfacial degradation. In particular, a large excess of electrolyte and a large Li metal counter-electrode, both of which are necessary features of DEMS cells, serve to mask the deleterious effects of the interfacial degradation on electrochemical performance. In this work, we reconcile the degradation observed by DEMS with performance decay measured by extended cycling experiments in electrolyte-lean full cells. By comparing DRX outgassing and cycling performance in different voltage windows, we demonstrate a positive correlation between the extent of outgassing and the rate of DRX performance decay during cycling. This result provides a crucial link between the degradation measured by techniques like DEMS and the performance decay measured by cycling experiments, and it allows for the fine-tuning of a cycling voltage window which optimizes the tradeoff between initial performance and long-term stability. Furthermore, this work emphasizes the importance of cell design features, like electrolyte volume and counter-electrode material, and their impact on different electrochemical experiments.
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4

Chen, Yan Hua y Qing Jie Zhu. "Numerical Simulation of Interfacial Bonding Degradation of Composites under Two-Stage Loading". Materials Science Forum 575-578 (abril de 2008): 869–74. http://dx.doi.org/10.4028/www.scientific.net/msf.575-578.869.

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Bonding degradation at interface is one of main damage forms of composites, especially under fatigue loading. Interfacial bonding degradation of FRC under two-stage tension loading is studied, which is base for variable-amplitude cyclic loading existing widely in actual engineering. Based on the shear-lag model and considered the asymmetry of interfacial damage, the mechanical governing equations of fiber and matrix are established and related solutions are obtained firstly. Two kinds of loading models are chosen, one is low-high alternate loading, and the other is low early and high late loading. By the aid of the Paris law and the energy release theory, a relationship between debond rate and cycle number is established. Then the interfacial debonding is simulated under the two-stage tension loading. The rules of the crack growth are analyzed for low-high two-stage loadings. It is found that stress amplitude has great influence on interfacial debonding under two-stage loading. Low stress amplitude in a certain range can postpone interfacial bonding degradation. And interfacial damage extent is greater than that under constant-amplitude fatigue loading. Present study is helpful for analyzing the fatigue damage of engineering materials and structures.
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5

Perelmuter, M. "Kinetics of interfacial crack bridged zone degradation". Journal of Physics: Conference Series 451 (17 de julio de 2013): 012012. http://dx.doi.org/10.1088/1742-6596/451/1/012012.

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6

Jongwoo Park y D. G. Harlow. "Interfacial degradation of epoxy coated silicon nitride". IEEE Transactions on Components and Packaging Technologies 25, n.º 3 (septiembre de 2002): 470–77. http://dx.doi.org/10.1109/tcapt.2002.803651.

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7

Lee, Sunyoung, Hayoung Park, Jungwon Park y Kisuk Kang. "Crystal Orientation-Dependent Interface Compatibility in the Oxide Composite Cathode by in Situ Heating Transmission Electron Microscopy". ECS Meeting Abstracts MA2023-02, n.º 4 (22 de diciembre de 2023): 796. http://dx.doi.org/10.1149/ma2023-024796mtgabs.

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All-solid-state batteries (ASSBs) with oxide-based solid electrolytes are getting prominence as a forthcoming battery system capable of overcoming the drawbacks of current lithium-ion batteries by satisfying the expanding demand for high energy density and safety. However, the poor interfacial contact between cathode active materials and solid electrolytes, at which lithium ions diffuse and the charge transfer occurs, is a major concern for practical utilization. Although the co-sintering process at high temperatures is essential to achieve an intimate interface contact, excessive thermal energy reversely accelerates the interfacial degradation reaction, of which the mechanism has been still unexplored. Here, using an epitaxial model system in which the crystal orientations of the Li(Ni1/3Co1/3Mn1/3)O2 cathode and Li3xLa(2/3)-x⎕(1/3)-2xTiO3 solid electrolyte are controlled, we directly probe the interfacial reaction in real-time during heating by in situ heating transmission electron microscopy, and investigate the impact of the crystal orientation at the interface on the interfacial reaction mechanism and kinetics. In situ observation reveals that the interfacial reactions are highly dependent on the crystal orientation at the interface involving the onset temperature of the reaction, the diffusion behavior of lithium ions, the intermediate states, and the overall degradation mechanism between the active material and the solid electrolyte. The interfacial degradation during heating increases the charge transfer resistance between the cathode active material and the solid electrolyte, and the increasing tendency of the resistance is closely related to the crystal orientation-dependent interfacial degradation.
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8

Desta, Gidey Bahre Bahre y Yao Jane Hsu (b)*. "Using Synchrotron Techniques, Investigation of Electrochemical Interfaces in Ni-Rich NMC and Sulfide Electrolytes in All-Solid-State Lithium Metal Batteries". ECS Meeting Abstracts MA2022-02, n.º 7 (9 de octubre de 2022): 2610. http://dx.doi.org/10.1149/ma2022-0272610mtgabs.

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a Nano-electrochemistry Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan, R.O.C b National Synchrotron Radiation Research Center (NSRRC), Hsinchu, 30076, Taiwan, R.O.C In all-solid-state lithium metal batteries enable long cyclability of high voltage oxides cathode persistent problem for the large scale application as their underprivileged interfacial steadiness in contrast to sulfide solid-state electrolyte. In this context, the interfaces of the solid electrolyte and Ni-rich NMC811 active material are looked upon as interfacial chemical responses induced by delithiation. In this study, we monitor the impedance progress at the unstable electrode|electrolyte interface due to the electrochemical interfacial response and help us understand the complex nature of reactivity and degradation kinetics with the solid-solid interface redox decomposition, which makes decoupling each effect difficult. we investigated the interfacial phenomenon between LPSC and high voltage cathode NMC811. The effects of spontaneous retort by the side of the interface were separated, and the intrinsic electrochemical decomposition of LPSC was quantified. Moreover, we show that the notch of interfacial degradation surges and the presence of oxidation mechanisms. At the higher delithiation stage, the cathode might twitch structural defenselessness and oxygen utter and resulting in further stark degradation. This complex kinetic degradation behavior was investigated at the solid-solid interface in a delithiation NMC811 and SSE based on the local oxidation state of NMC811, and LPSC SE interfacial chemical response. In this work, we used various characterization techniques to investigate the interfacial phenomenon between LPSC|NMC811 combining EIS and advanced synchrotron techniques such as sXAS, XPS, XRF-XANES mapping, and In-situ Raman spectroscopy. Keywords: delithiation, Ni-rich cathode, Sulfide-solid-state electrolyte, interfacial reaction, Synchrotron XPS, XRF.
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9

Morey, Madison, Andrew Cannon, Trevor Melsheimer y Emily Ryan. "(Invited) The Importance of Modeling Interfacial Phenomena in Electrochemical Systems". ECS Meeting Abstracts MA2023-01, n.º 25 (28 de agosto de 2023): 1649. http://dx.doi.org/10.1149/ma2023-01251649mtgabs.

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Chemical-physical processes at material interfaces drive performance and degradation in various energy and environmental systems, such as high energy density batteries, fuel cells, and electrolyzers. Transport (mass, charge, heat) to and through interfaces combined with reactions on the surface dictate the performance and also the degradation of these systems. To understand the fundamental material behavior of electrochemical systems, and to improve their performance and lifetime meso-scale interfacial modeling is needed that can resolve both the surface phenomena and the transport within the interfacial region. In this talk, I will discuss our research into computational modeling of interfacial and surface phenomena that drive performance in high energy density lithium batteries. Over multiple charge/discharge cycles non-uniform lithium plating and secondary reactions at the interface drive performance degradation and pose safety risks. The interplay between local transport, surface conditions, and operating conditions dictate these interfacial changes. In our work we use multi-phase, meso-scale modeling of the interfacial region to understand the driving forces for these changes and the coupling between physical phenomena to better understand the critical physics at the interface and to design more stable, long lasting interfaces.
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10

Bersuker, G., J. Barnett, N. Moumen, B. Foran, C. D. Young, P. Lysaght, J. Peterson, B. H. Lee, P. M. Zeitzoff y H. R. Huff. "Interfacial Layer-Induced Mobility Degradation in High-kTransistors". Japanese Journal of Applied Physics 43, n.º 11B (15 de noviembre de 2004): 7899–902. http://dx.doi.org/10.1143/jjap.43.7899.

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11

Greenbank, William, Lionel Hirsch, Guillaume Wantz y Sylvain Chambon. "Interfacial thermal degradation in inverted organic solar cells". Applied Physics Letters 107, n.º 26 (28 de diciembre de 2015): 263301. http://dx.doi.org/10.1063/1.4938554.

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12

Carlson, P. A., M. H. Gelb y P. Yager. "Zero-order interfacial enzymatic degradation of phospholipid tubules". Biophysical Journal 73, n.º 1 (julio de 1997): 230–38. http://dx.doi.org/10.1016/s0006-3495(97)78063-9.

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13

Nakamura, Hiromi, Jaewoo Shim, Frank Butz, Hideki Aita, Vijay Gupta y Takahiro Ogawa. "Glycosaminoglycan degradation reduces mineralized tissue–titanium interfacial strength". Journal of Biomedical Materials Research Part A 77A, n.º 3 (2006): 478–86. http://dx.doi.org/10.1002/jbm.a.30624.

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14

Visscher, E. J. y R. C. Willemse. "Interfacial tension of polypropylene/polystyrene: Degradation of polypropylene". Polymer Engineering & Science 39, n.º 7 (julio de 1999): 1251–56. http://dx.doi.org/10.1002/pen.11512.

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15

Kim, Jinhyuk y Seung Jun Choi. "Improving the Stability of Lycopene from Chemical Degradation in Model Beverage Emulsions: Impact of Hydrophilic Group Size of Emulsifier and Antioxidant Polarity". Foods 9, n.º 8 (22 de julio de 2020): 971. http://dx.doi.org/10.3390/foods9080971.

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The chemical stability of the lipophilic bioactives encapsulated in emulsions can be influenced by emulsion droplet interfacial characteristics as well as by the ability of antioxidants incorporated in emulsion to prevent the degradation of the encapsulated compounds. Therefore, this study evaluated the effects of the interfacial characteristics of emulsions and the polarity of antioxidants on the storage stability of lycopene in emulsions. Emulsions with 5% (w/w) oil containing lycopene (30 µmol/kg emulsion) were prepared using a series of polyethylene glycol acyl ether-type emulsifiers through microfluidization. Change in lycopene content in emulsions was monitored by high performance liquid chromatography. Our findings show that the hydrophilic group size (or length) of emulsifiers and the emulsifier concentration at the interfacial film play a role, albeit minor, in controlling the storage stability of lycopene encapsulated in emulsions. Lipophilic (tert-butylhydroquinone (TBHQ)) and amphiphilic (lauryl gallate) antioxidants similarly improved the storage stability of lycopene in emulsions from acid- and radical-mediated degradation, independent of the characteristics of interfacial films of emulsions. However, TBHQ inhibited the degradation of lycopene in emulsions more effectively than lauryl gallate under conditions intended to accelerate the acid-mediated degradation of lycopene. Therefore, our findings can provide helpful information about what type of emulsifiers and antioxidants can be chosen for preparing food emulsions capable of maximizing the stability of lycopene encapsulated therein.
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16

Matikas, Theodore E. "Characterization of Interphase Environmental Degradation at Elevated Temperature of Fibre-Reinforced Titanium Matrix Composites". Advanced Composites Letters 16, n.º 6 (noviembre de 2007): 096369350701600. http://dx.doi.org/10.1177/096369350701600603.

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Fibre reinforced metallic composite materials are being considered for a number of applications because of their attractive mechanical properties as compared to monolithic metallic alloys. An engineered interphase, including the bond strength between the composite's constituents, contributes to a large extent to the improvement of strength and stiffness properties of this class of materials. However, in high temperature applications, where combination of cyclic loading with environmental effects is expected, consideration should be given to interphase degradation, especially in the vicinity of stress risers, such as notches and holes. The applicability of damage tolerance analysis in structural components made of titanium matrix composite materials designed to operate under high temperature environments would depend on the availability of adequate characterization methods for the evaluation of interfacial degradation. The objective of this paper is to provide a basic understanding of interfacial degradation mechanisms due to oxidation in environmentally exposed titanium-based composites subjected to cyclic stresses. A non-destructive method has been developed enabling high-resolution monitoring of interfacial damage initiation and accumulation as well as surface/subsurface cracking behaviour during interrupted fatigue tests. This nondestructive technique is based on surface acoustic wave propagation in the composites and can detect minute changes in elastic properties of the interfacial region due to elevated temperatures as well as oxygen effects.
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17

Amer, M. S., M. J. Koczak, C. Galiotis y L. S. Schadler. "Environmental Degradation Studies of the Interface in Single-Filament Graphite / Epoxy Composites using Laser Raman Spectroscopy". Advanced Composites Letters 3, n.º 1 (enero de 1994): 096369359400300. http://dx.doi.org/10.1177/096369359400300103.

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To design an interface with specific environmental resistance, it is essential to understand the fundamental mechanisms of interfacial degradation. To this end, Laser Raman Spectroscopy (LRS) has been used to monitor the interfacial behavior in graphite / epoxy single-filament composites as a function of environmental exposure. Preliminary results of the observed changes in the interfacial behavior after exposure of the composite to water and air at 100°C are reported.
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18

Yu, Kiwi, Wang, Pulgarin y Rtimi. "Duality in the Mechanism of Hexagonal ZnO/CuxO Nanowires Inducing Sulfamethazine Degradation under Solar or Visible Light". Catalysts 9, n.º 11 (2 de noviembre de 2019): 916. http://dx.doi.org/10.3390/catal9110916.

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This study presents the first evidence for the photocatalytic performance of ZnO/CuxO hexagonal nanowires leading to sulfamethazine (SMT) degradation. The chemical composition of the nanowires was determined by X-ray fluorescence (XRF). The sample with the composition ZnO/Cux = 1.25O led to faster SMT-degradation kinetics. The SMT-degradation kinetics were monitored by high performance liquid chromatography (HPLC). The morphology of the hexagonal nanowires was determined by scanning electron microscopy (SEM) and mapped by EDX. The redox reactions during SMT degradation were followed by X-ray photoelectron spectroscopy (XPS). The interfacial potential between the catalyst surface and SMT was followed in situ under solar and indoor visible light irradiation. SMT-degradation was mediated by reactive oxidative species (ROS). The interfacial charge transfer (IFCT) between ZnO and CuxO is shown to depend on the type of light used (solar or visible light). This later process was found to be iso-energetic due to the potential energy positions of ZnO and CuxO conduction bands (cb). The intervention of surface plasmon resonance (LSPR) species in the SMT degradation is discussed.
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19

Björklund, Erik, Chao Xu, Wesley M. Dose, Christopher Gordon Sole, Pardeep Kumar, Tien-Lin Lee, Michael F. L. De Volder, Clare P. Grey y Robert S. Weatherup. "Interfacial Degradation in NMC811-Graphite Batteries during Extended Cycling". ECS Meeting Abstracts MA2021-01, n.º 2 (30 de mayo de 2021): 103. http://dx.doi.org/10.1149/ma2021-012103mtgabs.

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20

Guerrero, Antonio, Jingbi You, Clara Aranda, Yong Soo Kang, Germà Garcia-Belmonte, Huanping Zhou, Juan Bisquert y Yang Yang. "Interfacial Degradation of Planar Lead Halide Perovskite Solar Cells". ACS Nano 10, n.º 1 (24 de diciembre de 2015): 218–24. http://dx.doi.org/10.1021/acsnano.5b03687.

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21

Liu, Xiao-rong, Guan-zhou Qiu y Yue-hua Hu. "Degradation of Lix984N and its effect on interfacial emulsion". Journal of Central South University of Technology 13, n.º 6 (diciembre de 2006): 668–72. http://dx.doi.org/10.1007/s11771-006-0028-2.

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22

Lam, D. C. C., Fan Yang y Pin Tong. "Chemical kinetic model of interfacial degradation of adhesive joints". IEEE Transactions on Components and Packaging Technologies 22, n.º 2 (junio de 1999): 215–20. http://dx.doi.org/10.1109/6144.774734.

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23

Devine, R. A. B., D. Mathiot, W. L. Warren y M. Rohr. "Mechanism for enhanced interfacial degradation in annealed based devices". Microelectronic Engineering 28, n.º 1-4 (junio de 1995): 341–44. http://dx.doi.org/10.1016/0167-9317(95)00072-g.

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24

Tian, Yu, Yu Wang, Xingxun Liu, Klaus Herburger, Peter Westh, Marie S. Møller, Birte Svensson, Yuyue Zhong y Andreas Blennow. "Interfacial enzyme kinetics reveals degradation mechanisms behind resistant starch". Food Hydrocolloids 140 (julio de 2023): 108621. http://dx.doi.org/10.1016/j.foodhyd.2023.108621.

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25

Kim, Eun Young, Jin-Kook Lee y Won Ki Lee. "Interfacial Degradation of Biodegradable Polyester Monolayers at the Air/Enzyme-Containing Water Interface". Journal of Nanoscience and Nanotechnology 8, n.º 9 (1 de septiembre de 2008): 4830–33. http://dx.doi.org/10.1166/jnn.2008.ic22.

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The initial enzymatic degradation behavior of Langmuir monolayer films of a series of biodegradable polyesters at a constant surface pressure was investigated at the air/water interface. The initial degradation of polyester monolayers strongly depended on the structural formula of the polyesters. By the co-polymerization of 3-hydroxyvalerate (3HV) into the poly[(R)-3-hydroxybutyrate] backbone, the critical surface pressure at which the degradation occurs was increased and the rate of enzymatic degradation was retarded because of the inactivity of the enzyme and the hydrophobicity of 3HV. The decrease in the optical purity of poly(l-lactide) (PLLA) delayed the time when the degradation occurred at a constant surface pressure. However, the degradation rate after the critical time was accelerated as the optical purity decreased. These results can be explained by the mutual competition of the preferential degradation of l-lactide units and the density.
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26

Karpuraranjith, Marimuthu, Yuanfu Chen, Ramadoss Manigandan, Katam Srinivas y Sivamoorthy Rajaboopathi. "Hierarchical Ultrathin Layered GO-ZnO@CeO2 Nanohybrids for Highly Efficient Methylene Blue Dye Degradation". Molecules 27, n.º 24 (11 de diciembre de 2022): 8788. http://dx.doi.org/10.3390/molecules27248788.

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Highly efficient interfacial contact between components in nanohybrids is a key to achieving great photocatalytic activity in photocatalysts and degradation of organic model pollutants under visible light irradiation. Herein, we report the synthesis of nano-assembly of graphene oxide, zinc oxide and cerium oxide (GO-ZnO@CeO2) nanohybrids constructed by the hydrothermal method and subsequently annealed at 300 °C for 4 h. The unique graphene oxide sheets, which are anchored with semiconducting materials (ZnO and CeO2 nanoparticles), act with a significant role in realizing sufficient interfacial contact in the new GO-ZnO@CeO2 nanohybrids. Consequently, the nano-assembled structure of GO-ZnO@CeO2 exhibits a greater level (96.66%) of MB dye degradation activity than GO-ZnO nanostructures and CeO2 nanoparticles on their own. This is due to the thin layers of GO-ZnO@CeO2 nanohybrids with interfacial contact, suitable band-gap matching and high surface area, preferred for the improvement of photocatalytic performance. Furthermore, this work offers a facile building and cost-effective construction strategy to synthesize the GO-ZnO@CeO2 nanocatalyst for photocatalytic degradation of organic pollutants with long-term stability and higher efficiency.
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27

Prasad, M., N. Obana, S. Z. Lin, S. Zhao, K. Sakai, C. Blanch-Mercader, J. Prost et al. "Alcanivorax borkumensis biofilms enhance oil degradation by interfacial tubulation". Science 381, n.º 6659 (18 de agosto de 2023): 748–53. http://dx.doi.org/10.1126/science.adf3345.

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During the consumption of alkanes, Alcanivorax borkumensis will form a biofilm around an oil droplet, but the role this plays during degradation remains unclear. We identified a shift in biofilm morphology that depends on adaptation to oil consumption: Longer exposure leads to the appearance of dendritic biofilms optimized for oil consumption effected through tubulation of the interface. In situ microfluidic tracking enabled us to correlate tubulation to localized defects in the interfacial cell ordering. We demonstrate control over droplet deformation by using confinement to position defects, inducing dimpling in the droplets. We developed a model that elucidates biofilm morphology, linking tubulation to decreased interfacial tension and increased cell hydrophobicity.
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28

Wang, Liang, Jiashun Liang, Xiaoyu Zhang, Shenzhou Li, Tanyuan Wang, Feng Ma, Jiantao Han, Yunhui Huang y Qing Li. "An effective dual-modification strategy to enhance the performance of LiNi0.6Co0.2Mn0.2O2 cathode for Li-ion batteries". Nanoscale 13, n.º 8 (2021): 4670–77. http://dx.doi.org/10.1039/d0nr09010g.

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29

Liu, Qunfeng, Guangdi Dai, Chang Wang, Xing Wu y Xiang Ren. "Interfacial Effect on Quantitative Concrete Stress Monitoring via Embedded PZT Sensors Based on EMI Technique". Buildings 13, n.º 2 (17 de febrero de 2023): 560. http://dx.doi.org/10.3390/buildings13020560.

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Sensing performance is crucial for real-world applications of the embedded piezoelectric lead zirconate titanate (PZT) sensors in concrete structures. Based on the electromechanical impedances (EMIs) obtained numerically and experimentally from the embedded PZT sensors, effects of installation orientation and interfacial roughness were investigated on their sensitivity and reliability for quantitative concrete stress monitoring. The numerical results suggest a better sensitivity in the embedded 90° PZT sensors, with planar normal perpendicular to the loading direction, where the conductance amplitude variation is 6.5 times of that of the 0° PZT sensors, with normal parallel to load direction. Further, the improved reliability of the PZT sensors with rough interfaces is observed experimentally, which makes them robust for concrete stress monitoring over a wider sensing range from 0 to 20 MPa. Based on the static analyses, it is noted that the sensing performance of the embedded sensor is significantly affected by the interfacial stiffness degradation induced by the enhanced strain surrounding the sensor. These findings suggest that delaying the interfacial stiffness degradation, i.e., with proper installation orientation and interfacial treatment, could improve the sensing performance of the embedded sensors for quantitative concrete stress monitoring.
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30

Wang, B., S. M. Eichfield, D. Wang, J. A. Robinson y M. A. Haque. "In situ degradation studies of two-dimensional WSe2–graphene heterostructures". Nanoscale 7, n.º 34 (2015): 14489–95. http://dx.doi.org/10.1039/c5nr03357h.

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Heterostructures of two-dimensional materials can be vulnerable to thermal degradation due to structural and interfacial defects as well as thermal expansion mismatch, yet a systematic study does not exist in the literature.
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31

Monticelli, F., R. Osorio, M. Toledano, F. R. Tay y M. Ferrari. "In Vitro Hydrolytic Degradation of Composite Quartz Fiber-post Bonds Created by Hydrophilic Silane Couplings". Operative Dentistry 31, n.º 6 (1 de noviembre de 2006): 728–33. http://dx.doi.org/10.2341/05-151.

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32

Zúñiga-Benítez, Henry, Jafar Soltan y Gustavo Peñuela. "Ultrasonic degradation of 1-H-benzotriazole in water". Water Science and Technology 70, n.º 1 (30 de abril de 2014): 152–59. http://dx.doi.org/10.2166/wst.2014.210.

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This paper reports on the effect of different parameters of ultrasonic power, pollutant initial concentration, pH and the presence of co-existing chemical species (oxygen, nitrogen, ozone, and radical scavengers) on the ultrasonic degradation of the endocrine disruptor 1-H-benzotriazole. Increasing the 1-H-benzotriazole initial concentration from 41.97 to 167.88 μM increased the pollutant degradation rate by 40%. Likewise, a high applied ultrasonic power enhanced the extent of 1-H-benzotriazole removal and its initial degradation rate, which was accelerated in the presence of ozone and oxygen, but inhibited by nitrogen. The most favorable pH for the ultrasonic degradation was acidic media, reaching ∼90% pollutant removal in 2 h. The hydroxyl free radical concentration in the reaction medium was proportional to the ultrasound power and the irradiation time. Kinetic models based on a Langmuir-type mechanism were used to predict the pollutant sonochemical degradation. It was concluded that degradation takes place at both the bubble–liquid interfacial region and in the bulk solution, and OH radicals were the main species responsible for the reaction. Hydroxyl free radicals were generated by water pyrolysis and then diffused into the interfacial region and the bulk solution where most of the solute molecules were present.
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33

Yamazaki, Yasuhiro y Katsu Kudo. "Effect of Water Immersion on Interfacial Strength of a Metal/Epoxy Joint". Key Engineering Materials 774 (agosto de 2018): 289–94. http://dx.doi.org/10.4028/www.scientific.net/kem.774.289.

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Metal/resin joints have been widely used for automotive, electrical device and others. The degradation of interfacial strength of the joints through the effects of moisture is one of the important deterioration mechanisms in their structure applications. In this study, the interfacial strength of an aluminum-alloy/epoxy-resin joint was evaluated by the indentation test using of the instrumented indentation machine developed by ourselves. The in-situ observations of delamination cracking were carried out during the indentation test. The interfacial fracture toughness of the joint was evaluated from the relationship between the indentation load and the crack length. The effect of immersion into service water on the evaluated interfacial strength of the joint was discussed.
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34

Omiya, Masaki, Hirotsugu Inoue, Kikuo Kishimoto, Masaaki Yanaka y Noritaka Ihashi. "UV-Irradiation Effects on Interfacial Strength between Thin Ceramic Film and Polymer Substrate". Key Engineering Materials 297-300 (noviembre de 2005): 2284–89. http://dx.doi.org/10.4028/www.scientific.net/kem.297-300.2284.

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This aim of this study is to investigate the effect of UV (Ultra Violet ray) irradiation on the interfacial adhesion strength between thin ceramic films and polymer substrate. Electric conductive films based on polymer substrates have attracted attention for use in flexible optoelectronic devices. It is well known that the mechanical properties of polymeric materials are degraded by UV irradiation. Therefore, it is considered that the UV irradiation also affects the interfacial adhesion strength between ceramic coating and polymer substrate. The interfacial adhesion strength was measured by Multi-stages peel test. The results show that the interfacial strength decreases with UV irradiation. However, if a filter layer is installed between ceramic and polymer substrate, the degradation ratio becomes small.
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35

Song, Yue-Xian, Yang Shi, Jing Wan, Shuang-Yan Lang, Xin-Cheng Hu, Hui-Juan Yan, Bing Liu, Yu-Guo Guo, Rui Wen y Li-Jun Wan. "Direct tracking of the polysulfide shuttling and interfacial evolution in all-solid-state lithium–sulfur batteries: a degradation mechanism study". Energy & Environmental Science 12, n.º 8 (2019): 2496–506. http://dx.doi.org/10.1039/c9ee00578a.

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36

Thampy, Sampreetha, Boya Zhang, Jong-Goo Park, Ki-Ha Hong y Julia W. P. Hsu. "Bulk and interfacial decomposition of formamidinium iodide (HC(NH2)2I) in contact with metal oxide". Materials Advances 1, n.º 9 (2020): 3349–57. http://dx.doi.org/10.1039/d0ma00624f.

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37

Wu, Zhigang, Xue Deng, Lifen Li, Xuedong Xi, Meifen Tian, Liping Yu y Bengang Zhang. "Effects of Heat Treatment on Interfacial Properties of Pinus Massoniana Wood". Coatings 11, n.º 5 (5 de mayo de 2021): 543. http://dx.doi.org/10.3390/coatings11050543.

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Understanding the interfacial changes of wood during heat treatment can facilitate the improvement of the bonding and coating processes of heat-treated wood. Steam was used as the medium to modify Pinusmassoniana wood through heat treatment at 160, 180, 200, and 220 °C. Changes to the surface characteristics after heat treatment were characterized by Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscope (SEM) and contact angle measurement. The results showed that: (1) hemicelluloses were the first to experience degradation at 160 °C, and this degradation was the most intense at 200 °C. The cellulose started experiencing obvious degradation at 200 °C, while there was less degradation of lignin at this temperature. (2) Oxygen-containing groups like hydroxyl and carbonyl were gradually reduced as temperature increased with deepened color and passivated surface. (3) Cellulose crystallinity presented a variable trend of increasing–decreasing–increasing. (4) Surface porosity and roughness of Pinus massoniana wood both increased after heat treatment. (5) The Pinus massoniana wood interface turned from hydrophilic to hydrophobic, and 180 °C was a turning point for the wettability of the Pinus massoniana wood interface.
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38

Roh, Hyun-gyoo, Sunghoon Kim, Jungmin Lee y Jongshin Park. "Effect of Low-Temperature Pyrolysis on the Properties of Jute Fiber-Reinforced Acetylated Softwood Kraft Lignin-Based Thermoplastic Polyurethane". Polymers 10, n.º 12 (3 de diciembre de 2018): 1338. http://dx.doi.org/10.3390/polym10121338.

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Short jute fiber-reinforced acetylated lignin-based thermoplastic polyurethane (JF reinforced ASKLTPU) was prepared and characterized as a short-fiber-reinforced elastomer with carbon-neutrality and biodegradability. The acetylated softwood kraft lignin-based thermoplastic polyurethane (ASKLTPU) was prepared with polyethylene glycol (PEG) as a soft segment. Short jute fiber was modified using low-temperature pyrolysis up to the temperatures of 200, 250, and 300 °C in order to remove non-cellulosic compounds of jute fibers for enhancing interfacial bonding and reducing hydrophilicity with the ASKLTPU matrix. JF-reinforced ASKLTPUs with fiber content from 5 to 30 wt % were prepared using a melt mixing method followed by hot-press molding at 160 °C. The JF-reinforced ASKLTPUs were characterized for their mechanical properties, dynamic mechanical properties, thermal transition behavior, thermal stability, water absorption, and fungal degradability. The increased interfacial bonding between JF and ASKLTPU using low-temperature pyrolysis was observed using scanning electron microscopy (SEM) and also proved via interfacial shear strength measured using a single-fiber pull-out test. The mechanical properties, thermal properties, and water absorption aspects of JF-reinforced ASKLTPU were affected by increased interfacial bonding and reduced hydrophilicity from low-temperature pyrolysis. In the case of the degradation test, the PEG component of ASKLPTU matrix highly affects degradation and deterioration.
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39

Momodu, D. Y., T. Tong, M. G. Zebaze Kana y W. O. Soboyejo. "Adhesion and Degradation of Organic and Hybrid Organic-Inorganic Light-Emitting Devices". Advanced Materials Research 1132 (diciembre de 2015): 185–203. http://dx.doi.org/10.4028/www.scientific.net/amr.1132.185.

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This paper presents the results of a combined analytical, computational and experimental study of adhesion and degradation of Organic Light Emitting Devices (OLEDs). The adhesion between layers that are relevant to OLEDs is studied using force microscopy during Atomic Force Microscopy. The interfacial failure mechanisms associated with blister formation in OLEDs and the addition of TiO2nanoparticles (into active regions) are then elucidated using a combination of fracture mechanics/finite element modeling and experiments. The blisters observed in the models are shown to be consistent with the results from adhesion and interfacial fracture mechanics models. The implications of the work are discussed for the future design of OLED structures with improved lifetimes and robustness.
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40

Devine, R. A. B. "SiO2/Si Interfacial Degradation and the Role of Oxygen Interstitials". Journal de Physique III 6, n.º 12 (diciembre de 1996): 1569–94. http://dx.doi.org/10.1051/jp3:1996203.

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41

Xin, Qing, Yi Zhang y Kaibin Wu. "Degradation of Microcystin-LR by Gas-Liquid Interfacial Discharge Plasma". Plasma Science and Technology 15, n.º 12 (diciembre de 2013): 1221–25. http://dx.doi.org/10.1088/1009-0630/15/12/11.

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42

Kim, Younggyu, Dongha Kim, Roland Bliem, Gülin Vardar, Iradwikanari Waluyo, Adrian Hunt, Joshua T. Wright, John P. Katsoudas y Bilge Yildiz. "Thermally Driven Interfacial Degradation between Li7La3Zr2O12 Electrolyte and LiNi0.6Mn0.2Co0.2O2 Cathode". Chemistry of Materials 32, n.º 22 (5 de noviembre de 2020): 9531–41. http://dx.doi.org/10.1021/acs.chemmater.0c02261.

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43

Li, Y., C. Carrera, R. Chen, J. Li, P. Lenton, J. D. Rudney, R. S. Jones, C. Aparicio y A. Fok. "Interfacial degradation in composite restorations challenged by multi-species biofilms". Dental Materials 29 (enero de 2013): e73-e74. http://dx.doi.org/10.1016/j.dental.2013.08.151.

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44

Mirletz, Heather M., Kelly A. Peterson, Ina T. Martin y Roger H. French. "Degradation of transparent conductive oxides: Interfacial engineering and mechanistic insights". Solar Energy Materials and Solar Cells 143 (diciembre de 2015): 529–38. http://dx.doi.org/10.1016/j.solmat.2015.07.030.

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45

Maljaee, Hamid, Bahman Ghiassi, Paulo B. Lourenço y Daniel V. Oliveira. "Moisture-induced degradation of interfacial bond in FRP-strengthened masonry". Composites Part B: Engineering 87 (febrero de 2016): 47–58. http://dx.doi.org/10.1016/j.compositesb.2015.10.022.

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46

Khadka, Dhruba B., Yasuhiro Shirai, Masatoshi Yanagida y Kenjiro Miyano. "Degradation of encapsulated perovskite solar cells driven by deep trap states and interfacial deterioration". Journal of Materials Chemistry C 6, n.º 1 (2018): 162–70. http://dx.doi.org/10.1039/c7tc03733c.

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47

Du, Xusheng, Feng Xu, Hong-Yuan Liu, Yinggang Miao, Wei-Guo Guo y Yiu-Wing Mai. "Improving the electrical conductivity and interface properties of carbon fiber/epoxy composites by low temperature flame growth of carbon nanotubes". RSC Advances 6, n.º 54 (2016): 48896–904. http://dx.doi.org/10.1039/c6ra09839h.

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Low temperature flame growth of CNTs on carbon fiber surface without degradation of fibers' tensile strength resulted into the improved interfacial and conductive properties of fiber reinforced composites.
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48

Ha, Y. C., J. H. Bae, T. H. Ha, H. G. Lee, D. K. Kim y B. I. Lee. "Electrochemical and Optical Characterization of the Corrosion Resistivity of Explosively Bonded Al-Cu Bimetal". Materials Science Forum 475-479 (enero de 2005): 2675–78. http://dx.doi.org/10.4028/www.scientific.net/msf.475-479.2675.

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With the usage of Al-Cu bimetals to connect aluminum and copper in power distribution systems growing persistently, efforts to mitigate the mechanical, electrical and electrochemical degradation are widely made. The explosive bonding technology has been considered as a countermeasure for the degradation. In this paper, electrochemical analysis and optical microscopic observation are carried out in order to compare the corrosion resistivity of the explosion type bimetal to the commonly used compression type bimetal. In particular, the effect of anions in the interfacial electrolyte on corrosion susceptibility was also investigated. The results show that the explosive bonding technology can prevent the interfacial corrosion caused by the formation of crevices and pits as well as by galvanic potential difference between aluminum and copper.
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49

Saha, Aditya, Ryuji Oshima, Daisuke Ohori, Takahiko Sasaki, Hirokazu Yano, Hidenori Okuzaki, Takashi Tokumasu, Kazuhiko Endo y Seiji Samukawa. "Effect of Interfacial Oxide Layers on Self-Doped PEDOT/Si Hybrid Solar Cells". Energies 16, n.º 19 (30 de septiembre de 2023): 6900. http://dx.doi.org/10.3390/en16196900.

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PEDOT:PSS/Si hybrid photovoltaic cells have been attracting attention as a potential way to simplify the manufacturing process and democratize solar energy production. Control of the PEDOT/Si interface is also one of the primary ways to ensure the improved performance and lifetimes of multijunction devices, such as perovskite/Si tandem solar cells. In this work, the effects of the interfacial silicon oxide layer were investigated by creating a novel and controllable neutral beam oxide interlayer with different thicknesses. A novel self-doped PEDOT (S-PEDOT) was used to improve interfacial contact and avoid the secondary doping of PEDOT:PSS. X-ray photoelectron spectroscopy (XPS) showed that the saturation of interfacial silicon atoms in SiOx-Si bonds as well as a very thin, (~1 nm) damage-free oxide interlayer were the keys to maintaining good passivation with a high tunneling current. Lifetime measurements also showed that the interlayers with the most SiO2 content degraded the least. The degradation of the devices was due to the continued growth of the oxide layer through reactions with silicon sub-oxides and the degradation of S-PEDOT.
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50

Feng, Tiantian, Hao Yin, Hao Jiang, Xin Chai, Xinle Li, Deyang Li, Jing Wu, Xuanhe Liu y Bing Sun. "Design and fabrication of polyaniline/Bi2MoO6 nanocomposites for enhanced visible-light-driven photocatalysis". New Journal of Chemistry 43, n.º 24 (2019): 9606–13. http://dx.doi.org/10.1039/c9nj01651a.

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PANI/Bi2MoO6 composites with improved photoelectrochemical performance and accessible interfacial active sites were fabricated for enhanced visible-light-driven photocatalytic degradation of RhB.
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