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Tesis sobre el tema "Inorganic chemistry"

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1

Clancy, Gerald Patrick. "Synthetic inorganic chemistry : novel metallocenes and inorganic fullerenes." Thesis, University of Oxford, 2000. http://ora.ox.ac.uk/objects/uuid:9c7f7c35-bb8f-4117-8e2e-e56a9fbcbeab.

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This thesis is divided into two parts. The first part concerns the synthesis and characterisation of substituted metallocene complexes of the transition and main group metals. The second part describes the preparation and characterisation of inorganic fullerene (IF)-related materials. <strong>Chapter 1</strong> reviews the chemistry of dialkyl- and diaryl-phosphino substituted cyclopentadienyl complexes of the transition metals. <strong>Chapter 2</strong> describes the synthesis and characterisation of the new ligands [M(C<sub>5</sub>Me<sub>4</sub>)CH<sub>2</sub>PMe<sub>2</sub>] (M = H, Li, Na
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2

Hubert, Jason Dominic. "Studies in synthetic inorganic chemistry." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334376.

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3

Bown, M. "Organoruthenaborane chemistry." Thesis, University of Leeds, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377857.

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4

Smith, Paul David. "Arene-ruthenium chemistry." Thesis, University of Nottingham, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.357040.

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5

Grimes-Marchan, Thomas V. Cundari Thomas R. "Quantum perspectives on physical and inorganic chemistry." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-5172.

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6

Suman, Priya. "The inorganic and organometallic chemistry of paracyclophanes." Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299296.

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7

Davin, Thomas J. "Computational chemistry of organometallic and inorganic species." Thesis, University of Glasgow, 2009. http://theses.gla.ac.uk/925/.

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This thesis presents computational investigations of problems related to redox processes and structural rearrangement in inorganic systems. Density functional theory has been used to gain insight into the origin and nature of such reactions. The work presented concerns two main topics: hydrogenase-like systems containing an Fe2 core and carbonphosphorus cluster compounds. In chapters II and III, we describe the impact of reduction, an important phenomenon in the H2 production catalytic cycle, on a hydrogenase-like model. In collaboration with Talarmin and co-workers who have conducted careful
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8

Bihari, Shailja. "Bio-inorganic chemistry of manganese and titanium." Thesis, University of Edinburgh, 2002. http://hdl.handle.net/1842/9995.

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A wide range of metals are transported in the body by the protein transferrin, including both essential metal ions and probably also metals used in therapeutic agents. The metal binding sites on transferrin contain tyrosine, histidine and aspartate ligands. This thesis is concerned with studies of the essential metal ion manganese, and with titanium, which is used in anticancer agents. In order to aid the characterisation of Mn(III) and Ti(IV) transferrins, the Mn(III) and Ti(IV) complexes with the model ligand ethylenebis[(a-hydroxyphenyl)glycine](H₄EHPG) have been studied. The Mn(III) comple
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9

Grimes-Marchan, Thomas V. "Quantum Perspectives on Physical and Inorganic Chemistry." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc5172/.

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Applications of computational quantum chemistry are presented, including an analysis of the photophysics of cyclic trinuclear coinage metal pyrazolates, an investigation into a potential catalytic cycle utilizing transition metal scorpionates to activate arene C-H bonds, and a presentation of the benchmarking of a new composite model chemistry (the correlation consistent composite approach, ccCA) for the prediction of classical barrier heights. Modeling the pyrazolate photophysics indicates a significant geometric distortion upon excitation and the impact of both metal identity and substituen
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10

Wilson, David James. "Phosphaalkyne derived phosphaorganometallic chemistry." Thesis, University of Sussex, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324141.

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11

Anderson, Kirsty Mackenzie. "Structural transition metal chemistry." Thesis, University of Bristol, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251082.

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12

Keep, Ann Kathleen. "Ruthenium boron cluster chemistry." Thesis, University of Cambridge, 1990. https://www.repository.cam.ac.uk/handle/1810/272941.

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13

Balaraman, Lakshmi. "COORDINATION CHEMISTRY OF N,N’- AZODOXIDES." Cleveland State University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=csu1556986156564604.

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14

Rabinovich, Daniel. "Chemistry: “Biological Inorganic Chemistry. Structure and Reactivity”, Bertini, Gray, Stiefel and Valentine." Revista de Química, 2012. http://repositorio.pucp.edu.pe/index/handle/123456789/101357.

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15

Walker, Gary Lawrence Patrick. "Studies in imido molybdenum chemistry." Thesis, Imperial College London, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266639.

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16

Trussell, Stephen John. "Transition metal-mediated organosilicon chemistry." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298136.

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17

Michaelidou, Despo M. "Synthetic studies in organometallic chemistry." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358726.

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18

Speel, Robert S. "Synthetic studies in gallium chemistry." Thesis, University of Oxford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315771.

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19

Gardener, Martin. "Studies in sol-gel chemistry." Thesis, Nottingham Trent University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341276.

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20

Dost, Kenan. "Supercritical fluids in analytical chemistry." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324702.

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21

Richards, D. G. "Non-aqueous chemistry of polyoxometalates." Thesis, University of Newcastle Upon Tyne, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260951.

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22

Guigley, Robert. "Chemistry of some hexanuclear complexes." Thesis, University of Sussex, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.359105.

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23

Baghurst, David Richard. "Applications of microwave techniques in synthetic inorganic chemistry." Thesis, University of Oxford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306688.

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24

Liu, Sophie Ph D. Massachusetts Institute of Technology. "Harnessing inorganic coordination chemistry for novel sensing applications." Thesis, Massachusetts Institute of Technology, 2016. http://hdl.handle.net/1721.1/105029.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 2016.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>We explore strategies to exploit the rich chemical reactivity available to inorganic coordination complexes in order to realize chemiresistive detectors, electronic device elements that undergo a change in resistance in the presence of analyte, through either incorporation of a conductive material (i.e., carbon nanotubes) or reliance on intrinsic conductivity. We seek to elucidate fundamental principles that govern these chemi
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25

Arroyo, Mar C. "Inorganic Carbon Chemistry In East Antarctic Coastal Polynyas." W&M ScholarWorks, 2020. https://scholarworks.wm.edu/etd/1593091839.

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Polynyas are large areas of open water or reduced sea ice coverage that persistently form in polar environments and often experience enhanced rates of physical, chemical, and biological processes that impact ocean dynamics on local to global scales. Polynyas that form adjacent to the coast, known as coastal polynyas, play an important role in the global carbon cycle by regulating the exchange of CO2 between the ocean and atmosphere in the high latitudes. Because of their importance to the global carbon cycle, there is a particular interest to better characterize CO2 system processes in Antarct
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26

Zain, S. A. M. "Novel inorganic anion exchangers." Thesis, University of Salford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234769.

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27

Desmangles, Nathalie. "Chemistry of medium-valent vanadium amide complexes." Thesis, University of Ottawa (Canada), 1998. http://hdl.handle.net/10393/4519.

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The chemistry of low-valent vanadium was extensively investigated especially in the organometallic field. Apart from cyclopentadienyl and alkoxides (or aryloxides) derivatives, its chemistry is poorly developed. Among the supporting ligands for the stabilization of low-valent vanadium, alkylamides need to be studied in more details. By introducing bulky amides such as $\rm R\sb2N\sp-\ (R = \sp{i}Pr,$ Cy, $\rm SiMe\sb3,\ C\sb6H\sb5,$ 3,5-Me$\sb2$Ph and Ad) in chemistry of vanadium(III) and vanadium(IV), we have opened a new field in the coordination of this early transition metal. Synthetic met
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28

Yau, John. "The chemistry of gold(I) compounds." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338901.

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29

Kelland, Malcolm. "Organo-transition metal boron hydride chemistry." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.258164.

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30

Forward, Jennifer Mary. "Aspects of metallocarborane and gold chemistry." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316885.

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31

Walker, Susan M. "Structure evolution in hydrothermal uranium chemistry." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249301.

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32

King, Jennifer L. "Organometallic chemistry in supercritical fluid solution." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262952.

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33

Thompsett, Andrew Robert. "The coordination chemistry of unusual alkynes." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302650.

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34

Cathey, Christopher. "Some studies in osmium cluster chemistry." Thesis, University of Cambridge, 1994. https://www.repository.cam.ac.uk/handle/1810/272644.

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35

Botos, Ákos. "Inorganic materials in hollow carbon nanostructures." Thesis, University of Nottingham, 2016. http://eprints.nottingham.ac.uk/31915/.

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The interactions of metal-containing molecules and nanoparticles (NPs) with the interior of hollow graphitic carbon nanostructures (CNs) were investigated and their chemical transformations in the nanoscale channels of CNs appraised. The gas phase insertion of Group VI metal hexacarbonyl complexes (M(CO)6, M=Cr, Mo, W) into CNs was successfully developed and optimised to provide good filling rates as confirmed by transition electron microscopy (TEM). Infrared (IR) and Raman spectroscopy demonstrated that Group VI M(CO)6 complexes with greater polarisability exhibit stronger van der Waals inter
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36

Hernández, Sánchez Raúl. "Coordination Chemistry and Electronic Structure of Iron Clusters." Thesis, Harvard University, 2015. http://nrs.harvard.edu/urn-3:HUL.InstRepos:17467181.

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Mixed valence compounds have been recognized over the past five decades as a unique class of chemical species. Their distinctive spectral, electrochemical, physical and magnetic properties arise from electron delocalization into the sites with uneven valence. A primary consequence of this electron delocalization phenomenon is the stabilization of high spin multiplicities in certain dinuclear synthetic and polynuclear biological clusters. Therefore, the subject of this dissertation is to extend the current knowledge of the analysis of synthetic mixed valence clusters by systematically altering
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37

Schneider, William Frederich. "Applications of local-density-functional methods to inorganic chemistry /." The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487688973685734.

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38

Wheildon, Andrew R. "Novel nitrogen chemistry." Thesis, University of Nottingham, 1999. http://eprints.nottingham.ac.uk/13326/.

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Chapter One contains a brief overview of zeolites, their structure, uses and synthesis. Chapter Two relates to the attempted synthesis of quinuclidines via a novel 6-endo-trig radical cyclisation. Chapter Three contains a review of the 'Zip reaction' and the attempted synthesis of triazacyclopentadecane derivatives. Chapter Four relates to the synthesis of pyrrolidines via retro-Cope cyclisation methodology. Reviews of the Cope and retro-Cope reactions, nitrone synthesis and nucleophilic addition of carbon nucleophiles to nitrones are included. The synthetic work is split into three sections r
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39

Cowie, A. G. "Aspects of transition metal carbidocarbonyl cluster chemistry." Thesis, University of Cambridge, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356670.

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40

Trivedi, Madhuri Krashnakant. "The chemistry and application of strontium compounds." Thesis, Brunel University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337672.

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41

Fox, Judith M. "Synthetic and structural aspects of fullerene chemistry." Thesis, University of Oxford, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.361936.

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42

Metcalfe, John Edwin. "Studies in nickel and manganese coordination chemistry." Thesis, Queen's University Belfast, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263502.

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43

Odedra, Rajesh. "Chemistry of platinum and palladium agostic centres." Thesis, University of Salford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.244934.

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44

Macpherson, I. "Some metallaborane chemistry of molybdenum and tungsten." Thesis, University of Leeds, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376799.

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45

Nestor, Karl. "Some new chemistry of iridaboranes and iridaheteroboranes." Thesis, University of Leeds, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.330000.

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46

Al-Shamma, F. A. A. A. "Spectroscopic studies of the chemistry of silver." Thesis, Bucks New University, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376422.

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47

Champness, Neil Robert. "Studies in ruthenium and osmium coordination chemistry." Thesis, University of Southampton, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239648.

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48

Apte, S. C. "The aquatic chemistry of some metalloid elements." Thesis, University of Southampton, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304812.

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49

Orchard, Simon David. "Synthesis and coordination chemistry of telluroether ligands." Thesis, University of Southampton, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326303.

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50

Prior, Neville D. "Some organometallic chemistry of osmium carbonyl clusters." Thesis, University of Cambridge, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.257045.

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