Literatura académica sobre el tema "Homolytic cleavage of diborons"
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Artículos de revistas sobre el tema "Homolytic cleavage of diborons"
Verma, Piyush Kumar, Naresh Kumar Meher y K. Geetharani. "Homolytic cleavage of diboron(4) compounds using diazabutadiene derivatives". Chemical Communications 57, n.º 64 (2021): 7886–89. http://dx.doi.org/10.1039/d1cc02881b.
Texto completoWang, Pengfei, Yuli Li y Guangwei Wang. "Tetrahydroxydiboron-Initiated Atom-Transfer Radical Cyclization". Synthesis 53, n.º 19 (19 de abril de 2021): 3555–63. http://dx.doi.org/10.1055/a-1485-4956.
Texto completoCao, Levy L. y Douglas W. Stephan. "Homolytic Cleavage Reactions of a Neutral Doubly Base Stabilized Diborane(4)". Organometallics 36, n.º 16 (9 de agosto de 2017): 3163–70. http://dx.doi.org/10.1021/acs.organomet.7b00522.
Texto completoWang, Jiaoyang, Wenrui Zheng y Yuanyuan Zheng. "Theoretical study on homolytic B–B cleavages of diboron(4) compounds". RSC Adv. 7, n.º 78 (2017): 49251–72. http://dx.doi.org/10.1039/c7ra09006d.
Texto completoTsurugi, Hayato, Kazushi Mashima, Luis C. Misal Castro y Ibrahim Sultan. "Pyridine-Mediated B–B Bond Activation of (RO)2B–B(OR)2 for Generating Borylpyridine Anions and Pyridine-Stabilized Boryl Radicals as Useful Boryl Reagents in Organic Synthesis". Synthesis 53, n.º 18 (20 de abril de 2021): 3211–26. http://dx.doi.org/10.1055/a-1486-8169.
Texto completoWeng, Zhiqiang y Lai Yoong Goh. "Homolytic Cleavage and Aggregation Processes in Cyclopentadienylchromium Chemistry". Accounts of Chemical Research 37, n.º 3 (marzo de 2004): 187–99. http://dx.doi.org/10.1021/ar030003r.
Texto completoDing, Lanlan, Wenrui Zheng y Yingxing Wang. "Homolytic C–O Cleavage in Phosphates and Sulfonates". Journal of Physical Chemistry A 119, n.º 14 (27 de marzo de 2015): 3488–99. http://dx.doi.org/10.1021/acs.jpca.5b00569.
Texto completoKampmeier, Jack A. "Regioselectivity in the Homolytic Cleavage of S-Adenosylmethionine". Biochemistry 49, n.º 51 (28 de diciembre de 2010): 10770–72. http://dx.doi.org/10.1021/bi101509u.
Texto completoNome, Faruk, Marcos Caroli Rezende, Claudia Maria Sabóia y Arlindo Clemente Da Silva. "Kinetics of the thermolysis of para-substituted benzylcobalamins and derivatives". Canadian Journal of Chemistry 65, n.º 9 (1 de septiembre de 1987): 2095–99. http://dx.doi.org/10.1139/v87-347.
Texto completoBajaj, Ashima, Rishu Khurana y Md Ehesan Ali. "Quantum interference and spin filtering effects in photo-responsive single molecule devices". Journal of Materials Chemistry C 9, n.º 34 (2021): 11242–51. http://dx.doi.org/10.1039/d1tc02200h.
Texto completoTesis sobre el tema "Homolytic cleavage of diborons"
Verma, Piyush Kumar. "Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions". Thesis, 2021. https://etd.iisc.ac.in/handle/2005/5241.
Texto completoWu, Yi-Wen y 吳翌彣. "The Study of Electronic Structures of Five-coordinate Saddled Iron(III) Porphyrin Radical Cation and O-O Bond Homolytic Cleavage of (OETPP)FeIIIO(H)OtBu". Thesis, 2018. http://ndltd.ncl.edu.tw/handle/n6af3q.
Texto completo國立中興大學
化學系所
106
In this study, paramagnetic NMR spectroscopy, X-ray diffraction, magnetic susceptibility and DFT calculation are employed to elucidate the strong bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals of [Fe(OMTPP∙)Cl]SbCl6 and [Fe(OETPP∙)Cl]SbCl6. Their crystal structures clearly indicate that their saddle deformations are increased compared to those prior to oxidations. Their 1H NMR data present the S = 2 states for such one-electron oxidation states, and demonstrate that their structures in solutions remain strong saddle deformations. In light of 1H NMR spectroscopy of [Fe(TPP∙)Cl]SbCl6 resembling to the above cases, we postulate that the ring structure of [Fe(TPP∙)Cl]+ may possess strongly saddle to have great bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals. In the DFT calculations, the degrees of phenyl ring rotation and saddled deformation will also affect their NMR spectra. In another topic, we observe O-O bond homolytic cleavage of (OETPP)FeIIIO(H)OtBu formed in the reaction of Fe(OETPP)ClO4 with TBHP and its activation parameters (ΔH≠ = 47(2) kJ mol-1, ΔS≠ = 83(9)J mol-1K-1) is measured by low-temperature UV-vis spectral data. The corresponding one-electron oxidation product is identified as [Fe(OETPP∙)OH]+, which is an isoelectronic structure as oxoiron(IV) porphyrin, by UV-vis, NMR spectroscopy and ESI-MS spectrometry. According to the experiments of NMR and ESI-MS, we also find that ·OtBu radical will convert Fe(OETPP)ClO4 to [Fe(OETPP∙)OtBu]+. Furthermore, these related iron(III) porphyrin radical cations can be carried out one more electron oxidation to isoporphyrins, an isoelectronic structure as Compound I. These iron(III) saddled isoporphyrins are shown to be reactive for highly selective chlorination of cyclohexene.
Mala, Deep. "Chemistry of Ru(II) Complexes Bearing N-heterocyclic Carbene, Hydride, and Dihydrogen Ligands : Synthesis, Mechanistic Insights, and Applications". Thesis, 2016. http://etd.iisc.ac.in/handle/2005/4162.
Texto completoCapítulos de libros sobre el tema "Homolytic cleavage of diborons"
James, B. R. y M. T. Ashby. "Homolytic Cleavage to Give Metal-Hydrides". En Inorganic Reactions and Methods, 66–71. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch29.
Texto completoKühn, F. E., C. C. Romäo y W. A. Herrmann. "Homolytic Cleavage". En Compounds of Groups 7-3 (Mn..., Cr..., V..., Ti..., Sc..., La..., Ac...), 1. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-002-00209.
Texto completo"Oxidative Degradation". En Organic Chemistry of Drug Degradation, 48–109. The Royal Society of Chemistry, 2012. http://dx.doi.org/10.1039/bk9781849734219-00048.
Texto completo"S-Adenosyl Methionine: One Electron and Two Electron Reaction Manifolds in Biosyntheses". En Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 524–68. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00524.
Texto completo"Energy of a Homolytic Cleavage of Communication OH in Replaced 2,6-di-tert.Butylphenols". En Chemistry and Physics of Complex Materials, 225–34. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b16302-13.
Texto completo"Carbon-based Radicals in C–C Bond Formations in Natural Products". En Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 456–522. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00456.
Texto completoKlärner, F. G., M. K. Diedrich, G. Dierkes y J. S. Gehrke. "Organic Reactions at High Pressure: the Effect of Pressure on cyclizations and Homolytic Bond Cleavage". En High Pressure Food Science, Bioscience and Chemistry, 3–11. Elsevier, 1998. http://dx.doi.org/10.1533/9781845698379.1.3.
Texto completo"Carbon Radicals". En The Chemical Biology of Carbon, 402–37. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839169502-00402.
Texto completoMartinho Simões, José A. y Manuel Minas da Piedade. "Electrochemical Measurements". En Molecular Energetics. Oxford University Press, 2008. http://dx.doi.org/10.1093/oso/9780195133196.003.0020.
Texto completoFrey, Perry A. y Adrian D. Hegeman. "Decarboxylation and Carboxylation". En Enzymatic Reaction Mechanisms. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195122589.003.0012.
Texto completoActas de conferencias sobre el tema "Homolytic cleavage of diborons"
Jeremić, Svetlana R., Jelena R. Đorović Jovanović, Marijana S. Stanojević Pirković y Zoran S. Marković. "THERMODYNAMICALLY INVESTIGATIONS OF FREE RADICAL SCAVENGER POTENCY OF 1,2,4-TRIHYDROXYTHIOXANTHONE". En 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.414j.
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