Bibliografías temáticas / Free radical copolymerisation

Literatura académica sobre el tema "Free radical copolymerisation"

Autor: Grafiati
Publicado: 4 de junio de 2021
Última modificación: 19 de febrero de 2023

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Artículos de revistas sobre el tema "Free radical copolymerisation"

1

Boulding, Natasha A., Jonathan M. Millican y Lian R. Hutchings. "Understanding copolymerisation kinetics for the design of functional copolymers via free radical polymerisation". Polymer Chemistry 10, n.º 41 (2019): 5665–75. http://dx.doi.org/10.1039/c9py01294j.

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Guo, Xiaopeng, Haihua Wang y Deqiang Li. "Free-radical graft copolymerisation of fluorine nanocellulose surfactants". Surface Innovations 7, n.º 3-4 (julio de 2019): 230–41. http://dx.doi.org/10.1680/jsuin.19.00009.

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Carlson, Rebecca K., Rachel A. Lee, Jed H. Assam, Rollin A. King y Megan L. Nagel. "Free-radical copolymerisation of acrylamides, acrylates, and α-olefins". Molecular Physics 113, n.º 13-14 (3 de marzo de 2015): 1809–22. http://dx.doi.org/10.1080/00268976.2015.1015641.

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Coote, M. L. y T. P. Davis. "The mechanism of the propagation step in free-radical copolymerisation". Progress in Polymer Science 24, n.º 9 (noviembre de 1999): 1217–51. http://dx.doi.org/10.1016/s0079-6700(99)00030-1.

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Ken Busfield, W., I. Darren Grice y Ian D. Jenkins. "Free radical initiation mechanisms in copolymerisation studied by the nitroxide trapping technique". Polymer International 27, n.º 2 (1992): 119–23. http://dx.doi.org/10.1002/pi.4990270205.

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Fellows, Christopher. "Preliminary observations on the copolymerisation of acceptor monomer:donor monomer systems under microwave irradiation". Open Chemistry 3, n.º 1 (1 de marzo de 2005): 40–52. http://dx.doi.org/10.2478/bf02476236.

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AbstractThe mechanistic rationalisation of specific ‘microwave effects’ previously reported in a range of chemical reactions suggests that they may be observable in the freeradical copolymerisation of comonomer pairs capable of forming donor-acceptor complexes. Polymerisation under microwave irradiation is carried out for several comonomer pairs with weak donor-acceptor interactions, and no acceleration in rate or change in degree of alternation attributable to changes in propagation are observed. An increase in reaction rate of 150–200 % is observed for all systems, with trends in molecular weight suggesting this was due to an increase in radical flux. This is consistent with earlier reports of rate enhancement for free-radical polymerisations using the initiator 2,2′-azobis-isobutyronitrile, and it is proposed that microwave irradiation may reduce the amount of geminate radical recombination.
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7

Grabchev, Ivo y Seher Sali. "Photophysical Properties of Fluorescent Copolymers of Methylmethacrylate for Use in Liquid Crystalline Systems". Zeitschrift für Naturforschung A 60, n.º 11-12 (1 de diciembre de 2005): 831–36. http://dx.doi.org/10.1515/zna-2005-11-1212.

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The free radical copolymerisation of five fluorescent 4-allylamino-N-phenyl-substituted 1,8-naphthalimide dyes (MDs) with methylmethacrylate (MMA) has been investigated. The utility of the copolymers prepared as fluorescent component in polymer/liquid crystal systems has been investigated. The basic photophysical properties of monomeric dyes, poly(MMA-co-MD) and poly(MMAco- MD)/liquid crystal mixtures are discussed. The influence of poly(MMA-co-MD) on the phase transition temperature from the nematic to the isotropic state of poly(MMA-co-MD)/liquid crystal mixtures have also been investigated.
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8

Favresse, Philippe, André Laschewsky, Claudia Emmermann, Leo Gros y Andreas Linsner. "Synthesis and free radical copolymerisation of new zwitterionic monomers: amphiphilic carbobetaines based on isobutylene". European Polymer Journal 37, n.º 5 (mayo de 2001): 877–85. http://dx.doi.org/10.1016/s0014-3057(00)00215-9.

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Mukherjee, Aparna, Deepshikha Datta y Gopinath Halder. "Synthesis and characterisation of rice-straw-based grafted polymer composite by free radical copolymerisation". Indian Chemical Engineer 61, n.º 2 (3 de julio de 2018): 105–19. http://dx.doi.org/10.1080/00194506.2018.1490930.

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Milovanovic, Milos, Snezana Trifunovic, Lynne Katsikas y Ivanka Popovic. "Preparation and modification of itaconic anhydride-methyl methacrylate copolymers". Journal of the Serbian Chemical Society 72, n.º 12 (2007): 1507–14. http://dx.doi.org/10.2298/jsc0712507m.

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The free radical copolymerisation of itaconic anhydride and methyl methacrylate in solution was studied at 60 ?C. The copolymer composition was determined by 1H-NMR spectroscopy and the obtained monomer reactivity ratios were calculated, rITA = 1.35?0.11; rMMA = 0.22?0.22 (by the Fineman-Ross method) and rITA = 1.27?0.38; rMMA = 0.10?0.05 (by the Mayo-Lewis method). The synthesised copolymers were modified by reaction with di-n-butyl amine. The copolymer composition after amidation was determined by elemental analysis via the nitrogen content. Amidation of the anhydride units in the copolymers with di-n-butyl amine resulted in complete conversion to itaconamic acid.
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Tesis sobre el tema "Free radical copolymerisation"

1

Grice, I. Darren y n/a. "Some New Aspects of Radical Trapping Using an Aminoxyl Radical Trap". Griffith University. School of Science, 1993. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20050915.150556.

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An investigation of the initiation mechanism in the free radical copolymerisation of acrylonitrile and vinyl acetate using the aminoxyl radical trapping technique, employing 1,1 ,3,3-tetramethyl-2,3-dihydro- 1 Hisoindol-2-yloxyl is reported. Based upon the experimental results, the mechanism of initiation is suggested as proceeding via the 'free monomer' mechanism. Additionally, the effect of Lewis acids on the initiation mechanism is reported. A study of the addition of phosphorus-centred radicals to alkenes and phenylacetylene, utilising the aminoxyl radical trapping technique is reported. The results indicate a decreased rate of addition by both diphenylphosphinyl and dimethoxyphosphinyl radicals to cyclic versus acyclic alkenes. In contrast to cyclic alkenes, both these phosphorus-centred radicals add readily to the triple bond of phenylacetylene. The stereochemistry of the addition of diphenyiphosphinyl and dimethoxyphosphinyl radicals and of the aminoxyl trap is discussed. The stereochemistry of the addition of benzoyloxyl radicals to a conformationally rigid alkene, trans-a2-octalin is reported. Attempts to examine the initiation mechanism in the free radical copolymerisation of styrene/maleic anhydride and of styrene/tetracyanoethylene utilising the aminoxyl radical trapping technique are described. Also described are attempts to synthesise some new phosphorus radical initiators.
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2

Dobie, Christopher George. "A Study of Bulk Free-Radical Photo Copolymerisation and Surfactant Free Emulsion Polymerisation Using Intensified Processing Methods". Thesis, University of Newcastle Upon Tyne, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.512198.

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Libros sobre el tema "Free radical copolymerisation"

1

Thongpine, C. Free-radical copolymerisation of styrene and methyl acrylate. Manchester: UMIST, 1993.

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2

KUCHANOV, S. I. Free Radical Copolimerization Dispersions Glassy State Relaxation (Advances in Polymer Science). Springer, 1992.

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3

Morley, Nicholas John. Simulation studies of multicomponent polymerisations involving tri-n-butyltin methacrylate: An experimental investigation of the kinetics of free radically initiated solution copolymerisations of tri-n-butyltin methacrylate with other acrylic monomers and a theoretical study of these processes by computer simulation. Bradford, 1986.

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