Tesis sobre el tema "Endives"
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Accary, Pierre. "Dermites de contact aux endives". Amiens, 1992. http://www.theses.fr/1992AMIEM122.
Texto completoYoung, Nicholas. "Endings". Tallahassee, Florida : Florida State University, 2010. http://etd.lib.fsu.edu/theses/available/etd-04082010-160817/.
Texto completoAdvisor: James Kimbrell, Florida State University, College of Arts and Sciences, Dept. of English. Title and description from dissertation home page (viewed on July 26, 2010). Document formatted into pages; contains vi, 46 pages.
Sellin, Claudine. "Recherche de chicorées à café (Cichorium intybus L. Var. Magdebourg) résistantes aux herbicides (glyphosate et glufosinate) par cultures cellulaires". Lille 1, 1991. http://www.theses.fr/1991LIL10118.
Texto completoBouvard, Elisabeth. "Implication d'Erwinia sp. Dans une pourriture molle de Cichorium intybus L. Au forçage". Paris 11, 1987. http://www.theses.fr/1987PA112095.
Texto completoThe bacterial flora isolated from chicory rot during forcing was characterized. Typical well-known symptoms as well as atypical symptoms encountered during present studies, were investigated on roots and chicons. Isolates were mainly related to Erwinia carotovora subsp. Atroseptica. They formed an homogeneous group from a biochemical point of view and an heterogeneous one with respect to their serological characteristics. Methods for assessing pathogenicity of the isolated bacterial strains were tested on whole plants during forcing and also on isolated organs in order to deter m ne the effect of the physiological stage of plants, of inoculum level and of modes of inoculation. The life cycle of bacteria was investigated by studying the penetration in plant tissues of spontaneous and artificial E. C. A. Inocula; the inoculation of strains during the vegetative growth of C. Intybus did not lead to expression of bacteriosis. Inoculations during forcing produced much variable results which were especially dependent on temperature. Observations of bacteriosis in most of the experimental control lots suggest that Erwinia was potentially present in all roots during forcing: this bacteriosis is an opportunistic disease. The use of a chemical (copper sulphate in the form of Bordeaux mixture) able to modify the bacterial flora both qualitatively and quantitatively, indicated that E. C. A. Could possibly penetrate into plants during vegetative growth. It also demonstrated the presence of bacterial infection in leaf residues (left after harvesting of roots) which accounts for subsequent rot during forcing. The study of the influence of some agro-climatic factors on disease expression showed that previous growing conditions of roots (nitrogen fertilization in the field) were positively correlated to chicon mortality, and that the disease expression was highly dependent on the conditions of root storage and forcing temperature
Hobson, Christopher Parker. "PRETTY SAD ENDINGS". UKnowledge, 2018. https://uknowledge.uky.edu/english_etds/70.
Texto completoBouazza, Abdelhamid. "Etude des activités peroxydasique et auxine-oxydasique au cours de la morphogenèse de tissus de racine de Cichorium intybus L. Cultivés in vitro". Lille 1, 1993. http://www.theses.fr/1993LIL10187.
Texto completoLeonard, Stephen. "Death and Other Endings". ScholarWorks@UNO, 2010. http://scholarworks.uno.edu/td/1163.
Texto completoSaksi, Nassima. "Culture et potentialités de régénération de protoplastes de feuilles de Cichorium intybus L. Var. Witloof". Lille 1, 1985. http://www.theses.fr/1985LIL10094.
Texto completoScheuhammer, Joseph Edward. "Contour completion at edge endings". Thesis, Massachusetts Institute of Technology, 1988. http://hdl.handle.net/1721.1/17228.
Texto completoMurray, Jessica E. "The good death, happy endings". [Gainesville, Fla.] : University of Florida, 2006. http://purl.fcla.edu/fcla/etd/UFE0013893.
Texto completoLüddecke, Kathrin L. G. "The beginnings of narrative closure in Homeric epic". Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312611.
Texto completoBoeuf, Grégory. "Influence des conditions de culture sur les peroxydases apoplastiques de Cichorium intybus : étude biochimique et moléculaire de l'isoperoxydase Cicpx". Lille 1, 1999. https://pepite-depot.univ-lille.fr/LIBRE/Th_Num/1999/50376-1999-239.pdf.
Texto completoDuminy-Dubreucq, Anne. "Caractérisation des cytoplasmes 411, 523 et 524 provenant de chicorées mâle stériles transférés par rétrocroisements chez la chicorée Witloof : suivi de leur descendance". Lille 1, 1998. https://pepite-depot.univ-lille.fr/LIBRE/Th_Num/1998/50376-1998-265.pdf.
Texto completoSalman, Abir. "Étude de l'expression de la PAL, de la PPO et de l'HSP90 en réponse au choc thermique chez l'endive (Cichorium intybus L. ) en quatrième gamme". Avignon, 2009. http://www.theses.fr/2009AVIG0616.
Texto completoMarketing possibilities for fresh-cut endive are limited by the rapid red discoloration of the leaves after cutting. This work proposes an alternative approach to prolong the shelf life of fresh-cut endive by inhibiting or delaying the red discoloration of pieces: the application of a heat shock at 46°C for 120 sec. The effect of heat shock on the activity of enzymes involved in the process of enzymatic browning and the accumulation of phenolic compounds were analyzed. The expression of genes involved PAL1, PAL2, PPO and Hsp90 was performed by following the accumulation of mRNA by real-time quantitative PCR. This work has shown that heat shock induces overexpression of Hsp90 and inhibits the activity of PAL, PPO, the accumulation of phenolic compounds and gene expression of PAL1 which consequently inhibition of discoloration for 8 days at 4°C. The controlled atmosphere (4%O2 + 5%CO2) is not sufficient to inhibit the red discoloration. The application of inhibitors of synthesis (AVG) and action of ethylene (1-MCP) has shown that ethylene is not involved in the inhibition of the synthesis of PAL in response to heat shock
Fragkiadaki, Evangelia. "Loss separation termination : a portfolio on endings". Thesis, City University London, 2008. http://openaccess.city.ac.uk/8597/.
Texto completoSmith, Jennifer. "Theorizing Digital Narrative: Beginnings, Endings, and Authorship". VCU Scholars Compass, 2012. http://scholarscompass.vcu.edu/etd/316.
Texto completoJensen, Sara Lyn. "Learning Russian Case Endings Through Model Sentences". Diss., CLICK HERE for online access, 2007. http://contentdm.lib.byu.edu/ETD/image/etd2000.pdf.
Texto completoBurt, Kathleen R. "Beginnings, middles, and endings in Horace's Odes". [Gainesville, Fla.] : University of Florida, 2006. http://purl.fcla.edu/fcla/etd/UFE0014327.
Texto completoMacDowell, James. "The final couple : happy endings in Hollywood cinema". Thesis, University of Warwick, 2011. http://wrap.warwick.ac.uk/49034/.
Texto completoWatson, Sonia. "Glutamate pharmacology of mammalian primary mechanosensory nerve endings". Thesis, University of Aberdeen, 2015. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=225803.
Texto completoWalsh, Fiona. "Bartók's altered endings : contexts, case studies, and constructs /". [St. Lucia, Qld.], 2001. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16330.pdf.
Texto completoGoupy, Pascale. "Le brunissement enzymatique de la scarole (Cichorium endivia) : composés phénoliques et enzymes d'oxydation des feuilles chlorophylliennes et étiolées". Montpellier 2, 1989. http://www.theses.fr/1989MON20014.
Texto completoOyebode, Oyinlola R. O. "Protection of neuromuscular sensory endings by the WldS gene". Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/4234.
Texto completoHanif, Ayshah. "Therapists' experiences of therapy endings with mental health patients". Thesis, University of Birmingham, 2018. http://etheses.bham.ac.uk//id/eprint/8546/.
Texto completoEvans, Elliott. "The Origin, Functions, and Histories of Germanic Adjective Endings". Thesis, Indiana University, 2019. http://pqdtopen.proquest.com/#viewpdf?dispub=13858651.
Texto completoThe purpose of this dissertation is to provide an account for why Germanic languages inflect adjectives along the adjective declension choice (ADC)—i.e. as strong or weak—in addition to the typical parameters of gender, number, and case. Specifically, I examine the origin, functions, and histories of Germanic adjective endings.
The ADC, which developed in prehistoric times, could not have arisen from the Proto-Indo-European individualizing suffix as is typically assumed, since early runic examples directly contradict that account. Instead, geographically peripheral Swedish attest nominal incorporation to express definiteness, which finds corresponding examples in both Runic Germanic and other Indo-European languages and provides a more likely origin for the ADC.
The modern Germanic languages exhibit different functions for the ADC. In German it conveys syntactic nominal features that would otherwise remain unvalued and result in a crash. In Dutch and Norwegian, it conveys semantic definiteness features.
The function of the ADC in Proto-Germanic, as demonstrated through a comparison of early Germanic translations of Matthew’s Gospel, was syntactic, though distinct from German. In Proto-Germanic, weak adjectives were bound by determiners and strong adjectives were free and occupied the elsewhere environment. A series of developments happened in the history of German, attested from approximately 800 to 1300 CE. First, possessives and the indefinite article grammaticalized from adjectives into determiners. Second, many nominative inflections phonologically reduced to zero, making most predicate adjectives appear uninflected. Finally, strong attributive adjectives adopted the pronominal paradigm to replace the zero endings. In Norwegian, the system shifted from a syntactic one to a semantic one, with the two competing systems vacillating from approximately 1100 to 1500 CE. The newer semantic system, which eventually won out, aligned weak adjectives with definiteness instead of the older syntactic system in which weak adjectives were bound by a determiner.
By examining the ADC, I provide an account of a phenomenon that morphosyntactically identifies nearly all Germanic languages, while showing that significant variation in function and historical trajectory exists across the Germanic languages—both past and present.
Yun, Xiao. "Tonal Enigmas: A Study of Problematic Openings and Endings". Thesis, University of North Texas, 2018. https://digital.library.unt.edu/ark:/67531/metadc1248491/.
Texto completoGruber-Miller, Ann Marie. "Internal developments in the loss of Arabic case endings /". The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487694389395422.
Texto completoPolson, Richard. "Shocked by Flannery O'Connor the possibility of new endings /". Online full text .pdf document, available to Fuller patrons only, 2002. http://www.tren.com.
Texto completoQuaintrell, Cecilia. "Testing boundaries : a cross cultural study of musical endings". Thesis, University of Bristol, 2017. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.742987.
Texto completoCocksworth, Hannah May. "Beginnings, endings, and the narrative unity of Luke and Acts". Thesis, University of Cambridge, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.707956.
Texto completoAparicio, López María del Rosario 1975. "Violencia de género en México = una aproximación a partir de la ENDIREH-2006 = Violência contra a mulher - México : uma aproximação a partir da ENDIREH-2006". [s.n.], 2013. http://repositorio.unicamp.br/jspui/handle/REPOSIP/279647.
Texto completoDissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Filosofia e Ciências Humanas
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Resumo: Essa dissertação tem o objetivo de refletir sobre a violência de gênero no México por meio da Encuesta Nacional sobre las Dinámicas de las Relaciones en los Hogares 2006 (ENDIREH-2006). A análise desse fenômeno será realizada a partir de três eixos: 1) descrição das características sociodemográficas e socioeconômicas das mulheres casadas e unidas que vivenciaram violência física ao lado dos seus cônjuges; 2) análise dos episódios de violência física mais comuns entre os casais mexicanos e os possíveis fatores associados à violência física; 3) análise das dinâmicas conjugais através dos motivos que causam raiva nos casais e suas possíveis reações
Abstract: This dissertation reflects on gender violence in Mexico through the Encuesta Nacional sobre la Dinámica de las Relaciones en los Hogares, edition 2006 (ENDIREH-2006). The analysis of this phenomenon will be from three aspects: through a description of the sociodemographic and socioeconomic married women who lived physical violence by their husbands or spouses; presenting episodes of physical violence more common among Mexican couples and the associated factors for physical life and, finally, discusses marital dynamics through the reasons that cause anger in couples and their possible reactions
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Diemer, Étienne. "Intensification du procédé d’extraction, de purification et de fonctionnalisation des acides caféoylquiniques à partir de coproduits de la culture de l’endive". Electronic Thesis or Diss., Compiègne, 2024. http://www.theses.fr/2024COMP2821.
Texto completoForced chicory root is a by-product of Belgian endive culture, a typical crop of northern France, Belgium and the Netherlands. Currently under-utilized in methanation or animal feed, this by-product contains molecules of interest: caffeoylquinic acids. These molecules have antioxidant and anti-inflammatory properties, and a potential for reducing metabolic disorders. This thesis aims to intensify the pre-treatment, extraction, purification and functionalization of caffeoylquinic acids from forced chicory roots to develop new bioactive biosourced molecules of potential interest to the cosmetics and nutraceutical sectors. The final part of the thesis deals with a technico-economical study of the process to estimate its economic profitability in relation to the targeted application sector. The first part focuses on the effect of conventional pretreatments (cutting and drying) and the effect of pulsed electric field pretreatment on caffeoylquinic acid content in biomass. The effect of adding an antioxidant solution during extraction is also investigated. Secondly, extraction optimization is carried out using dry or fresh biomass. The influence of factors such as temperature, solid/liquid ratio and solvent type were studied. In addition, extraction kinetics were performed to study kinetic parameters using empirical models. As the purity of the extract obtained is low, purification steps are needed. The thesis then focused on purifying the crude extract obtained using macroporous resins and liquid/liquid extraction. For resin purification, resin screening was carried out, followed by optimization of the purification operating conditions with the chosen resin. Models of adsorption phenomena are carried out to identify the limiting stages and the maximum adsorption capacity. For liquid/liquid extraction, green solvent screening is carried out on aqueous and hydro-ethanolic media, followed by optimization of operating conditions with the best solvent. The penultimate part of the thesis seeks to functionalize caffeoylquinic acids by esterification, starting with a model solution and then a real extract. Esterification conditions are optimized to increase both reaction speed and conversion rate. Esters with different chain lengths were obtained, and biological activities such as antioxidant activity and anti-UV properties were studied. Functionalization is also performed with real extract. A technico-economic study concludes the thesis, opening up prospects for the industrialization of the forced chicory roots valorization process
Lester, Satara J. ""I sort of feel that one is meant to say how important endings always are ..." : counsellors' experiences of endings in primary care : an interpretative phenomenological analysis". Thesis, London Metropolitan University, 2016. http://repository.londonmet.ac.uk/1158/.
Texto completoDankinas, Denisas. "Sensorinių nervinių galūnėlių tyrimas pelės širdyje". Master's thesis, Lithuanian Academic Libraries Network (LABT), 2014. http://vddb.library.lt/obj/LT-eLABa-0001:E.02~2011~D_20140627_171215-11827.
Texto completoThere are two types of cardiac sensory endings – complex unencapsulated endings and end-nets. The aim of this study was to examine morphology of sensory terminals in the basis of mouse heart and ability of different antibodies to visualize these terminals. Our results showed that both end-net and complex unencapsulated endings can be visualized with PGP 9.5 (AbD Serotec, USA). Complex unencapsulated endings are localized in heart wall epicardium near the apertures of caudal, right cranial and left cranial veins in the right atrium. End-net terminals are diffusely distributed in all three layers (endocardium, myocardium, epicardium) of heart wall. Complex unencapsulated endings near the caudal vein aperture have the lowest area compared with the sensory endings near the other two veins apertures.
Walker, Gareth. "The phonetic design of turn endings, beginnings and continuations in conversation". Thesis, University of York, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.422531.
Texto completoTether, Leah Roseann. "Suspended endings : the mechanics of medieval continuation in the perceval continuations". Thesis, Durham University, 2009. http://etheses.dur.ac.uk/107/.
Texto completoFraccaro, Annalisa. "Price endings of luxury handbags : managerial practices customers' perceptions and preferences". Thesis, Paris 1, 2017. http://www.theses.fr/2017PA01E071.
Texto completoDrawing from existing literature on price endings and luxury pricing, this thesis highlights the paradox of adopting odd prices (i.e., prices just below a round number) in a luxury context, where, intuitively, prices should mostly be round numbers. Price endings practices are investigated in the product category of luxury women handbags. In a first empirical analysis, different types of price endings and the determinants of their use by pricing managers are identified. In a second part, the results of two experiments measure customers’ perceptions of different facets of luxury and overall perceived luxury itself. In the last part, a conjoint analysis reveals customers’ preferences for odd price endings. The findings of this thesis challenge previous research on price endings practices, in that they show that well-know low-price, low-quality, low-prestige connotations typical of odd prices in a non-luxury context, might not subsist in a luxury environment, at least for the handbag product category and for an intermediate level of luxury
Knowles, Joanne Louise. "The key to patience : endings and completeness in Henry James's novels". Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367507.
Texto completoBell, Stuart. "'Don't stop' : re-thinking the function of endings in narrative television". Thesis, University of Glasgow, 2015. http://theses.gla.ac.uk/7282/.
Texto completoSoares, Carlos Dornelles Ferreira. "Qualidade de escarola minimamente processada em função de métodos de conservação". Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/11/11136/tde-29092016-104312/.
Texto completoEscarole is one of the most consumed leafy vegetal in salads, it is considered a rich source of nutrients and antioxidant compounds. Due to his arduous preparation for consumption or preparation of dishes, this vegetable shows a strong potential for fresh cut products market, however, this product exhibits browning on its leaves during storage. The objective of this work was to evaluate the influence of refrigerated storage, passive modified atmosphere and the application of antioxidants on quality aspects of fresh cut escarole. Three experiments were carried out. The first experiment evaluated the effect of four storage temperatures 0, 5, 10 and 15° C, for 20 days to 90-95% RH. In the second one, the effect of the use of passive modified atmosphere was evaluated by four plastic packaging: polyvinyl chloride (PVC), low density polyethylene (LDPE), polypropylene (PP) and bi-oriented polypropylene (BOPP), during storage at 0° C and 90-95% RH for 20 days. The last experiment aimed to check the effects of the application of following antioxidants: ascorbic acid 1%, citric acid 1%, oxalic acid 1% and etilenodiamino tetra-acetic acid (EDTA) 2% for a period of 21 days of storage at 0° C and 90-95% RH. In all experiments were performed the following analysis: color by L, C and °h and observation of browning index, ascorbic acid content, total chlorophyll content, total carotenoids content, total phenolic compounds content and weight loss. For the temperature experiment, the analysis of respiratory rate and ethylene production were also carried out. In the passive modified atmosphere and the antioxidants experiments, the monitoring of concentrations of O2 and CO2 in headspace of the packages and the activity of polyphenoloxidase and peroxidase enzymes were also made, and for the last experiment, were carried out microbiological analysis concerning the absence or presence of Salmonella and total coliforms and psychrotrophic bacteria counts during storage. The temperature of 0°C is the most recommended for the reduction of losses in the fresh cut escarole quality, that temperature provided respiratory rate reduction and reduction of the weight loss as well as was the one that kept the highest contents of ascorbic acid and pigments. Symptoms of chilling injury were not observed on the product during the storage. Among the films studied, it was found that concentrations of 16% oxygen and 3% carbon dioxide generated inside the PVC film, provided the minor browning index of the leaves and better conservation of levels of ascorbic acid, chlorophyll and carotenoids. It was observed that the fresh cut escarole is sensitivity to high CO2 concentrations. In the last experiment, the presence of Salmonella was not detected on the treatments. Between antioxidants applied, it was found that the treatment of citric acid 1% is the most suitable for the conservation of the fresh cut escarole quality attributes, for keeping low browning index, the highest concentrations of pigments and high content of ascorbic acid, as well as having provided low weight loss and microbiological development within the limits.
Gilfillan, Upton Bridget. "Hearing Mark's endings : listening to ancient popular texts through speech act theory /". Leiden : Brill, 2006. http://catalogue.bnf.fr/ark:/12148/cb401781307.
Texto completoTracy, Thomas J. "Comic plots with tragic endings : the British writing of Ireland, 1800-1870 /". view abstract or download file of text, 2002. http://wwwlib.umi.com/cr/uoregon/fullcit?p3045097.
Texto completoTypescript. Includes vita and abstract. Includes bibliographical references (leaves 210-217). Also available for download via the World Wide Web; free to University of Oregon users.
Hoel, Camilla Ulleland. "The completion of Edwin Drood : endings and authority in finished and unfinished narratives". Thesis, University of Edinburgh, 2012. http://hdl.handle.net/1842/7572.
Texto completoCoelho, Alessia. "Saying goodbye : a phenomenological investigation into the therapist's experience of significant therapeutic endings". Thesis, Regent's University, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.646070.
Texto completoCASOTTE, L. D. H. "A PRODUÇÃO ACADÊMICA SOBRE ESTÁGIO SUPERVISIONADO NA FORMAÇÃO DE PROFESSORES: O QUE REVELAM OS TEXTOS DOS ENDIPES DE 2000 a 2012". Universidade Federal do Espírito Santo, 2016. http://repositorio.ufes.br/handle/10/8590.
Texto completoNesta pesquisa propomos mapear, descrever e analisar a produção acadêmica sobre Estágio Supervisionado na formação de professores, apresentada nos Encontros Nacionais de Didática e Prática de Ensino (Endipes). O foco da pesquisa pautou-se na elaboração de um estado do conhecimento sobre o referido tema no período de 2000 a 2012. Desenvolvemos uma pesquisa documental bibliográfica, de base qualitativa e quantitativa, na qual realizamos um estudo de mapeamento sobre a temática Estágio Supervisionado nos Endipes do referido período, assumindo-a como problemática de relevância significativa no campo científico da educação. O Estágio Supervisionado tem se destacado no cenário das pesquisas sobre formação de professores por sua pujante contribuição tanto para a promoção da articulação entre a teoria e a prática na formação e no trabalho docente, quanto para a constituição da identidade docente e para o desenvolvimento de ações colaborativas entre universidade e escolas de educação básica, uma vez que, por ocasião dos estágios, os licenciandos têm a oportunidade de vivenciar situações de ensino e aprendizagem e de refletir sobre a prática educativa ao mesmo tempo em que se formam como professor e pesquisador de sua atividade profissional. Desse modo, dialogamos com as produções de Pimenta (2001, 2002 e 2011), Pimenta e Lima (2004 e 2011), Lima (2012) e Nóvoa (1992, 2004 e 2009). Os resultados da materialidade evidenciam a colaboração dos Endipes para a socialização das produções, uma vez que congrega resultados dos trabalhos de pesquisadores de todo país. Nesse panorama, por meio dos textos apresentados na modalidade painel no período de 2000 a 2012, o Estágio Supervisionado ganha destaque como significativo componente curricular, eficaz para a promoção da articulação entre a teoria e prática e das ações colaborativas entre Universidade e escola, bem como para a formação do professor reflexivo, para a constituição da identidade docente e para a composição dos saberes da docência. Além dessas questões, os autores também trataram das experiências do Estágio Supervisionado e ocuparam-se em analisar as racionalidades subjacentes às concepções de formação docente.
Stoeber, Franziska Susann [Verfasser]. "Individual Endings: The Extension of the Personal Future and Developmental Deadlines / Franziska Susann Stoeber". Aachen : Shaker, 2011. http://d-nb.info/1071528718/34.
Texto completoSuggitt, Kelsey Fleur. "Impossible endings? : reimagining the end of the French empire in the Sahara, 1951-1962". Thesis, University of Portsmouth, 2019. https://researchportal.port.ac.uk/portal/en/theses/impossible-endings(d19d3fbc-f3fa-47ef-8b47-63252f7f5039).html.
Texto completoTIRONE, Alfonso. "CONDIZIONAMENTO E UTILIZZAZIONE DI SCARTI E SOTTOPRODOTTI DELL'INDUSTRIA AGRUMARIA NELLA COLTIVAZIONE DI “CICHORIUM ENDIVIA”". Doctoral thesis, Università degli Studi di Palermo, 2015. http://hdl.handle.net/10447/108229.
Texto completoGonzález, Molina Iván. "Síntesi i reactivitat de nous macrocicles nitrogenats poliinsaturats". Doctoral thesis, Universitat de Girona, 2008. http://hdl.handle.net/10803/8049.
Texto completoS'han preparat macrocicles de quinze i setze baules triacetilènics i de quinze baules contenint dos triples i un doble enllaç a l'estructura. S'ha estudiat la ciclotrimerització [2+2+2] d'aquests macrocicles catalitzada per metalls de transició en dissolvents orgànics convencionals o en sals foses.
S'han sintetitzat complexos de rodi contenint un lligand carbènic N-heterocíclic per tal d'utilitzar-los com a catalitzadors alternatius al complex de Wilkinson en les reaccions de ciclotrimerització dels macrocicles poliinsaturats i d'altres anàlegs oberts. Els complexos carbènics sintetitzats han presentat una eficiència lleugerament superior a la del catalitzador de Wilkinson.
També s'ha iniciat un estudi mecanístic de la cicloisomerització d'aquests macrocicles induïda tèrmicament.
Finalment, s'han preparat macrocicles de catorze i dinou baules contenint un nucli endiínic a més d'altres insaturacions i s'ha estudiat la corresponent ciclació de Bergman en estat sòlid.
In this work different sized polyunsaturated azamacrocicles were synthesized and their reactivity was studied. 15- and 16-membered triacetylenic macrocycles and 15-membered macrocycles containing two acetylenes and one olefin were synthesized. The transition metal catalyzed [2+2+2] cyclotrimerization of the polyunsaturated macrocycles was studied in organic solvents or molten salts.
Rhodium complexes containing a N-heterocyclic carbene (NHC) ligand were prepared in order to be used as alternatives to the Wilkinson's catalyst in the cyclotrimerization reaction of the polyunsaturated macrocycles and other open-chained analogues. The yields were slightly higher to those previously obtained with the Wilkinson's catalyst, showing that NHC can be used as alternative ligands to the phosphanes.
A mechanistic study of the thermally induced cycloisomerization of the above-mentioned macrocycles was initiated.
Finally, 14- and 19-membered azamacrocycles containing an enediyne system and other unsaturations were synthesized and their solid-state Bergman cyclization was studied.
Dias, Mariana de Alvarenga Vieira. "Estudo do desempenho de filmes biodegradáveis numa cultura de ciclo curto - escarola (Cichorium endivia L.)". Master's thesis, ISA/UL, 2015. http://hdl.handle.net/10400.5/11168.
Texto completoIn this dissertation, the aim was to evaluate and compare the performance of biodegradable mulch relatively to conventional polyethylene. For this purpose three different “mulches” were tested: polyethylene (PE) and two biodegradable "Short Cycle" (SC) and "Salads" (S) developed from the Mater-Bi™ matrix. Escarole (Cichorium endivia L.) crop cycle was monitored along the experimental study implemented at real scale. The monitoring plan was developed to evaluate the crop productivity and the impact of the different “mulches” in terms of moisture and soil temperature. The results achieved during this study showed the adaptability of biodegradable plastics to the soil and weather conditions, checking a significant difference in productivity of plants covered with plastic S relative to the other two modes (PE and SC). Given that to date there is no biodegradation studies in the Alentejo region of Portugal soils, it was also important to check the level of biodegradability of these new plastic films following the norm DIN EN ISO 17556. The results obtained in this work can be concluded that biodegradable plastics seem like a good solution to replace the PE, yet research and development of these new plastics should continue to hold