Tesis sobre el tema "Electrically conductive polymer"
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Rhodes, Susan M. "Electrically Conductive Polymer Composites". University of Akron / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=akron1194556747.
Texto completoZhao, Wei. "Flexible Transparent Electrically Conductive Polymer Films for Future Electronics". University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1297888558.
Texto completoNg, Yean Thye. "Electrically conductive melt-processed blends of polymeric conductive additives with styrenic thermoplastics". Thesis, Loughborough University, 2012. https://dspace.lboro.ac.uk/2134/11016.
Texto completoLi, Zhuo. "Rational design of electrically conductive polymer composites for electronic packaging". Diss., Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/53454.
Texto completoJan, Chien Sy Jason. "Layer-by-layer assembly of electrically conductive polymer thin films". Thesis, Texas A&M University, 2003. http://hdl.handle.net/1969.1/5979.
Texto completoTang, Qingmeng. "Preparation and Characterization of Electrically Conductive Graphene-Based Polymer Nanocomposites". Case Western Reserve University School of Graduate Studies / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=case1386260373.
Texto completoCruz-Estrada, Ricardo Herbe. "In-situ production of electrically conductive polyaniline fibres from polymer blends". Thesis, Brunel University, 2002. http://bura.brunel.ac.uk/handle/2438/2406.
Texto completoKim, Woo-Jin. "Design of electrically and thermally conductive polymer composites for electronic packaging /". Thesis, Connect to this title online; UW restricted, 1998. http://hdl.handle.net/1773/7055.
Texto completoOtto, Christian [Verfasser] y Volker [Akademischer Betreuer] Abetz. "Electrically Conductive Composite Materials from Carbon Nanotube Decorated Polymer Powder Particles / Christian Otto ; Betreuer: Volker Abetz". Hamburg : Staats- und Universitätsbibliothek Hamburg, 2017. http://d-nb.info/1150183748/34.
Texto completoLiang, Qizhen. "Preparation and properties of thermally/electrically conductive material architecture based on graphene and other nanomaterials". Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/44846.
Texto completoSouthward, Robin Elaine. "The synthesis of reflective and electrically conductive polyimide films via an in situ self-metallization procedure using silver(I) complexes". W&M ScholarWorks, 1997. https://scholarworks.wm.edu/etd/1539623903.
Texto completoBertolini, Mayara Cristina. "Flexible and 3D printable conductive composites for pressure sensor applications". Doctoral thesis, Università degli studi di Trento, 2022. https://hdl.handle.net/11572/360281.
Texto completoThe aim of this study was the development of flexible and highly electrically conductive polymer composites via compression molding and fused filament fabrication for possible applications as piezoresistive or piezoelectric materials for pressure sensors. Composites based on blends of poly(vinylidene fluoride)/thermoplastic polyurethane (PVDF/TPU) as matrix and containing various fractions of carbon black-polypyrrole (CB-PPy) as conductive filler were prepared. Several characterization techniques were performed in order to evaluate the mechanical, thermal, chemical and electrical properties, morphology and printability of the investigated materials. First, PVDF/TPU blends with different compositions were prepared by melt compounding followed by compression molding. The results showed that the flexibility aimed for the final materials was improved with the addition of TPU to PVDF composites. SEM images evidenced the achievement of a co-continuous blend comprising 50/50 vol% of PVDF/TPU. The blends composed of PVDF/TPU 38/62 vol% and the co-continuous blend of PVDF/TPU 50/50 vol% were selected as matrices for the preparation of compression molded and 3D printed composites in order to achieve an optimal compromise between electrical conductivity, mechanical properties and printability. Various amounts of carbon black-polypyrrole, from 0 up to 15%, were added to the selected blends in order to rise the electrical conductivity of the composites and to possible act as nucleating filler for the β crystalline phase of PVDF in order to increase its piezoelectric response. The addition of CB-PPy increased the electrical conductivity of all composites. However, the electrical conductivity of composites based on PVDF/TPU 50/50 vol% co-continuous blends was higher than those found for PVDF/TPU 38/62 vol% composites at the same filler content. Indeed, the electrical percolation threshold of the conductive co-continuous composite blends was 2%, while the electrical percolation threshold of the composites with the nonco-continuous composite blends was 5%. With respect to the mechanical properties, the incorporation of the filler into the blends leaded to more rigid materials with higher elastic modulus, lower elongation at break and higher storage modulus. The storage modulus (G’) and complex viscosity (η*) of the composites increased with the addition of CB-PPy. The rheological percolation threshold was found to be 3% for PVDF/TPU/CB-PPy 38/62 vol% and 1% for PVDF/TPU/CB-PPy 50/50 vol%, indicating that higher amount of filler could compromise the processability of the composites. The addition of CB-PPy also resulted in a reduction on the Tg and Tm values of the composites due to the reduction of the mobility of the polymeric chains. Based on the electrical conductivity and mechanical behavior of the composites, three different compositions were selected for the extrusion of filaments to be used in a 3D printing process. Overall, the 3D printed parts presented lower mechanical and electrical properties because of the presence of voids, defects and overlapping layers that can hinder the flow of electrons. The electrical conductivity values of PVDF/TPU/CB-PPy 38/62 vol% composites containing 5% and 6 wt% of CB-PPy 3D printed samples are one to seven orders of magnitude lower than those found for compression molded composites with the same composition. Even if the electrical conductivity value for PVDF/TPU 38/62 vol% compression molded composite with 6% of CB-PPy was as high as 1.94x10-1 S•m-1, the 3D printed composite with same composition showed a very low electrical conductivity of 6.01x10-8 S•m-1. On the other hand, the 3D printed co-continuous composite PVDF/TPU 50/50 vol% with 10% of filler displayed a high value of electrical conductivity of 4.14×100 S•m-1 even after the printing process. Moreover, the piezoresistive responses of the composites were investigated. For PVDF/TPU/CB-PPy 38/62 vol% composites, the compression molded and 3D printed samples with 5% and 6% of CB-PPy exhibited good piezoresistive response. However, only the composites with 6% displayed high sensitivity and gauge factor values, large pressure range and reproducible piezoresistive responses under 100 cycles for both methods. On the other hand, for PVDF/TPU/CB-PPy co-continuous composites only the compression molded sample with 5% of CB-PPy presented good and reproducible piezoresistive responses. The crystallinity and β phase content of PVDF were investigated for the composites. Althought the degree of crystallinity of the samples decreased with the addition of CB-PPy, the percentage of β phase in PVDF was increased. The piezoelectric coefficient d33 of the samples increased with the percentage of β phase. The addition of 6% or more of CB-PPy was necessary to increase significatively the piezoelectric coefficient (d33) of the composites. The β phase content and piezoelectric responses of PVDF were lower for samples prepared by FFF. Finally, as a collateral research, the electromagnetic interference shielding effectiveness (EMI-SE) were measured for all composites. Composites with higher electrical conductivity showed better shielding of the electromagnetic radiation. In addition, composites based on the co-continuous blend displayed higher EMI shielding efficiency than 38/62 vol% composites. The main mechanism of shielding was absorption for all composites. Specimens prepared by FFF displayed diminished EMI-SE responses when compared to compression molded samples.
Lo scopo di questo studio è lo sviluppo di compositi polimerici flessibili e ad elevata conducibilità elettrica tramite stampaggio a compressione e manifattura additiva (fused filament fabrication) per possibili applicazioni come materiali piezoresistivi o piezoelettrici in sensori di pressione. In particolare, sono stati preparati compositi a base di miscele di poli(vinilidene fluoruro)/poliuretano termoplastico (PVDF/TPU) come matrice e contenenti varie frazioni di nerofumo-polipirrolo (CB-PPy) come riempitivo conduttivo. Sono state utilizzate diverse tecniche di caratterizzazione al fine di valutare le proprietà meccaniche, termiche, chimiche ed elettriche, la morfologia e la stampabilità dei materiali ottenuti. In primo luogo, miscele PVDF/TPU con diverse composizioni sono state preparate mediante mescolatura allo stato fuso seguita da stampaggio a compressione. I risultati hanno mostrato che la flessibilità del PVDF viene notevolemente migliorata dall’aggiunta di TPU. Le immagini SEM hanno evidenziato il raggiungimento di una miscela co-continua per una composizione 50/50% in volume di PVDF/TPU. Le miscele composte da PVDF/TPU 38/62 vol% e la miscela co-continua di PVDF/TPU 50/50 vol% sono state selezionate come matrici per la preparazione di compositi per stampaggio a compressione e manifattura additiva al fine di ottenere un compromesso ottimale tra conducibilità, proprietà meccaniche e stampabilità. Alle miscele selezionate sono state aggiunte varie quantità di nerofumo-polipirrolo, dallo 0 al 15%, per aumentare la conducibilità elettrica dei compositi ed eventualmente fungere da additivo nucleante per la fase β cristallina del PVDF al fine di aumentarne la risposta piezoelettrica. L'aggiunta di CB-PPy ha aumentato la conduttività elettrica di tutti i compositi. Tuttavia, la conduttività elettrica dei compositi basati su miscele co-continue di PVDF/TPU 50/50% in volume era superiore a quella trovata per compositi PVDF/TPU 38/62% in volume con lo stesso contenuto di riempitivo. Infatti, la soglia di percolazione elettrica delle miscele conduttive era del 2%, mentre la soglia di percolazione elettrica dei compositi con miscele composite non continue era del 5%. Per quanto riguarda le proprietà meccaniche, l'incorporazione del riempitivo nelle mescole ha portato a materiali più rigidi con modulo elastico più elevato, allungamento a rottura inferiore e modulo conservativo più elevato. Il modulo conservativo (G') e la viscosità complessa (η*) dei compositi sono aumentate con l'aggiunta di CB-PPy. La soglia di percolazione reologica è risultata essere del 3% per PVDF/TPU/CB-PPy 38/62 vol% e dell'1% per PVDF/TPU/CB-PPy 50/50 vol%, indicando che una maggiore quantità di riempitivo potrebbe compromettere la processabilità dei compositi. L'aggiunta di CB-PPy ha comportato anche una riduzione dei valori di Tg e Tm dei compositi a causa della riduzione della mobilità delle catene polimeriche. Sulla base della conduttività elettrica e del comportamento meccanico dei compositi, sono state selezionate tre diverse composizioni per l'estrusione di filamenti da utilizzare in un processo di stampa 3D. Nel complesso, le parti stampate in 3D presentavano proprietà meccaniche ed elettriche inferiori a causa della presenza di vuoti, difetti e strati sovrapposti che possono ostacolare il flusso di elettroni. I valori di conducibilità elettrica dei compositi PVDF/TPU/CB-PPy 38/62 vol% contenenti il 5% e il 6% di CB-PPy di campioni stampati in 3D sono da uno a sette ordini di grandezza inferiori a quelli trovati per i compositi stampati a compressione con la stessa composizione. Anche se il valore di conducibilità elettrica per il composito stampato a compressione PVDF/TPU 38/62 vol% con il 6% di CB-PPy era pari a 1,94x10-1 S•m-1, il composito stampato in 3D con la stessa composizione ha mostrato un valore molto basso di conducibilità elettrica, pari a 6,01x10-8 S•m-1. D'altra parte, il composito PVDF/TPU 50/50 vol% stampato in 3D con il 10% di riempitivo ha mostrato un elevato valore di conducibilità elettrica, pari a 4,14 × 100 S•m-1, anche dopo il processo di stampa. Inoltre, sono state studiate le risposte piezoresistive dei compositi. Per i compositi PVDF/TPU/CB-PPy 38/62 vol%, i campioni stampati a compressione e stampati in 3D con il 5% e il 6% di CB-PPy hanno mostrato una buona risposta piezoresistiva. Tuttavia, solo i compositi con il 6% hanno mostrato valori di sensibilità e gauge factor elevati, ampio intervallo di pressione e risposte piezoresistive riproducibili in 100 cicli per entrambi i metodi. D'altra parte, per i compositi co-continui PVDF/TPU/CB-PPy solo il campione stampato a compressione con il 5% di CB-PPy ha presentato risposte piezoresistive adeguate e riproducibili. La cristallinità e il contenuto di fase β del PVDF sono stati studiati per i compositi. Sebbene il grado di cristallinità dei campioni diminuisca con l'aggiunta di CB-PPy, la percentuale di fase β in PVDF risulta aumentata. Il coefficiente piezoelettrico d33 dei campioni aumenta anch’esso con la percentuale di fase β. L'aggiunta del 6% o più di CB-PPy è stata necessaria per aumentare significativamente il coefficiente piezoelettrico (d33) dei compositi. Il contenuto di fase β e le risposte piezoelettriche del PVDF sono inferiori per i campioni ottenuti mediante stampa 3D. Infine, come ricerca collaterale, è stata misurata l'efficacia della schermatura contro le interferenze elettromagnetiche (EMI-SE) per tutti i compositi. I compositi con una maggiore conduttività elettrica hanno mostrato una migliore schermatura della radiazione elettromagnetica. Inoltre, i compositi basati sulla miscela co-continua hanno mostrato un'efficienza di schermatura EMI maggiore rispetto ai compositi a 38/62% in volume. Per tutti i compositi, il principale meccanismo di schermatura è l'assorbimento. I campioni preparati mediante manifattura additiva hanno mostrato risposte EMI-SE inferiori rispetto ai campioni stampati a compressione.
Tsotra, Panagiota. "Electrically conductive epoxy matrix composites /". Kaiserslautern : IVW, 2004. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=015387627&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.
Texto completoHolloway, Matthew James. "Electrically conducting composites formed from polymer blends". Thesis, Brunel University, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316533.
Texto completoMoody, David Jesse II. "Synthesis and characterization of novel electrically conductive polymers". Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/30270.
Texto completoKurosawa, Shutaro. "Supercritical Processing of Electrically Conducting Polymers". Diss., Georgia Institute of Technology, 2004. http://hdl.handle.net/1853/4988.
Texto completoPonsonby, Anna M. "Synthesis of crosslinked electrically conducting polymers". Thesis, Lancaster University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387471.
Texto completoHolland, Edward Robert. "Transport properties in electrically conductive polymeric materials". Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5233/.
Texto completoChen, Kun. "INVESTIGATION OF GRAPHENE-BASED MULTI-FILLER ELECTRICALLY CONDUCTIVE ADHESIVE MATERIAL". University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1555091658254182.
Texto completoDeng, Fenghua. "Coating of electrically conducting polymeric films on the surface of non-conducting substrate". Diss., Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/30435.
Texto completoChu, Der-Lun. "Synthesis and characterization of electrically conducting organic polymers". Diss., Georgia Institute of Technology, 1991. http://hdl.handle.net/1853/27893.
Texto completoFukushima, Motoo. "Synthesis and Electrical Conductive Properties of Organosilicon Polymers". Kyoto University, 1999. http://hdl.handle.net/2433/182375.
Texto completoÅkerfeldt, Maria. "Electrically conductive textile coatings with PEDOT:PSS". Doctoral thesis, Högskolan i Borås, Akademin för textil, teknik och ekonomi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:hb:diva-19.
Texto completoIsotalo, Heikki. "Thermopower in the characterization of electrically conducting polymers". [Hki] : Societas scientiarum Fennica, 1990. http://catalog.hathitrust.org/api/volumes/oclc/57960808.html.
Texto completoPrystaj, Laurissa Alia. "Effect of carbon filler characteristics on the electrical properties of conductive polymer composites possessing segregated network microstructures". Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/31667.
Texto completoCommittee Chair: Rosario Gerhardt; Committee Member: Gleb Yushin; Committee Member: Hamid Garmestani. Part of the SMARTech Electronic Thesis and Dissertation Collection.
Wood, Barry Richard. "Electrical conduction processes in metal-filled polymers". Thesis, Brunel University, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332839.
Texto completoKiani, Mohammad Saghir. "Structure and properties of pyrrole based electrically conducting polymers". Thesis, University of Reading, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316074.
Texto completoWu, Jen-Chieh. "Studies of Electrically Conducting Polymers and Biodegradable Polymers for Bone Tissue Engineering". The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1261512507.
Texto completoOu, Runqing. "Anisotropic structure and electrical properties of intrinsically conducting polymers". Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/9257.
Texto completoTaubert, Clinton J. "Low Percolation Threshold in Electrically Conductive Adhesives using Complex Dimensional Fillers". University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron1542727822099192.
Texto completoWebb, Kimberly F. "Formation of electrically condution polymer blends using supercritical carbon dioxide". Thesis, Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/10121.
Texto completoByrom, Joseph Robert. "Electrically Conductive Polymers and their Use as Novel Pigments in Advanced Coatings". Diss., North Dakota State University, 2018. https://hdl.handle.net/10365/27458.
Texto completoArmy Research Laboratory
Freebairn, David Alexander. "Electrical control of bacterial adherence to conducting polymers". Thesis, Queen's University Belfast, 2016. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.680117.
Texto completoAppello, Mario. "Real-time measurement of electrical properties during the processing of conductive polymers". Thesis, University of Warwick, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341559.
Texto completoLi, Jing. "Electrical conducting polymer nanocomposites containing graphite nanoplatelets and carbon nanotubes /". View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?MECH%202006%20LI.
Texto completoOlsson, Henrik. "Nanocomposites of Cellulose and Conducting Polymer for Electrical Energy Storage". Doctoral thesis, Uppsala universitet, Nanoteknologi och funktionella material, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-218815.
Texto completoHarris, Jeff. "The influence of adsorption layers on percolation characteristics of electrically conducting antimony-tin oxide/PMMA composites". Thesis, Brunel University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363512.
Texto completoRivers, Tyrell Jermaine. "Design, synthesis, and characterization of a novel biodegradable, electrically conducting biomaterial". Access restricted to users with UT Austin EID Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3035967.
Texto completoCao, Bin. "Development of Multifunctional and Electrical Conducting Carboxybetaine Based Polymers". University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1428534923.
Texto completoCakar, Ilknur. "Conductive Coating Materials". Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/2/12607410/index.pdf.
Texto completoKoysuren, Ozcan. "Preparation And Characterization Of Conductive Polymer Composites, And Their Assessment For Electromagnetic Interference Shielding Materials And Capacitors". Phd thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/12609452/index.pdf.
Texto completoKanbur, Yasin. "Conductive Polymer Nanocomposites Of Polypropylene And Organic Field Effect Transistors With Polyethylene Gate Dielectric". Phd thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613312/index.pdf.
Texto completos and fullerenes were surface functionalized with HNO3 : H2SO4 before composite preparation. The CNT and fullerene content in the composites were varied as 0.5, 1.0, 2.0 and 3.0 % by weight. For the composites which contain surface modified CNT and fullerene four different compatibilizers were used. These were selected as TritonX-100, Poly(ethylene-block-polyethylene glycol), Maleic anhydride grafted Polypropylene and Cetramium Bromide. The effect of surface functionalization and different compatibilizer on mechanical, thermal and electrical properties were investigated. Best value of these properties were observed for the composites which were prepared with maleic anhydride grafted polypropylene and cetramium bromide. Another aim of this study is to built and characterize transistors which have polyethylene as dielectric layers. While doing this, polyethylene layer was deposited on gate electrode using vacuum evaporation system. Fullerene , Pentacene ve Indigo were used as semiconductor layer. Transistors work with low voltage and high on/off ratio were built with Aluminum oxide - PE and PE dielectrics.
Bashir, Tariq. "Conjugated Polymer-based Conductive Fibers for Smart Textile Applications". Doctoral thesis, Högskolan i Borås, Institutionen Ingenjörshögskolan, 2013. http://urn.kb.se/resolve?urn=urn:nbn:se:hb:diva-3649.
Texto completoThesis for the Degree of Doctor of Philosophy to be presented on March 08, 2013, 10.00 in KA-salen, Kemigården 4, Chalmers University of Technology, Gothenburg
Yesil, Sertan. "Processing And Characterization Of Carbon Nanotube Based Conductive Polymer Composites". Phd thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/3/12611984/index.pdf.
Texto completoon the damage sensing capability of the epoxy/carbon nanotube/glass fiber composite panels during mechanical loadings were studied. Surface modification of the carbon nanotubes was performed by using hexamethylene diamine (HMDA). 4-octylphenol polyethoxylate (nonionic) (Triton X-100) and cetyl pyridinium chloride (cationic) (CPC) were used as surfactants during composite preparation. Electrical resistivity measurements which were performed during the impact, tensile and fatigue tests of the composite panels showed the changes in damage sensing capabilities of the composites. Surface treatment of carbon nanotubes and the use of surfactants decreased the carbon nanotube particle size and improved the dispersion in the composites which increased the damage sensitivity of the panels.
Goebel, Matthew L. "EVALUATING THE ELECTRICAL RESPONSE OF POLYANILINE TO MECHANICAL STRAIN". DigitalCommons@CalPoly, 2009. https://digitalcommons.calpoly.edu/theses/125.
Texto completoHands, Philip James Walton. "Vapour sensing applications and electrical conduction mechanisms of a novel metal-polymer composite". Thesis, Durham University, 2003. http://etheses.dur.ac.uk/4084/.
Texto completoChiguma, Jasper. "Conducting polymer nanocomposites loaded with nanotubes and fibers for electrical and thermal applications". Diss., Online access via UMI:, 2009.
Buscar texto completoWebb, Kimberly Faye. "Synthesis, blending, and doping of electrically conducting poly(3-undecylbithiophene) in supercritical carbon dioxide". Diss., Georgia Institute of Technology, 2000. http://hdl.handle.net/1853/10129.
Texto completoCui, Li. "Conducting polymer-based QCM-interdigitated electrode hybrid electronic nose system". Thesis, University of Glasgow, 1999. http://theses.gla.ac.uk/3974/.
Texto completoYahyaie, Iman. "Electrical characterization of microwire-polymer assemblies for solar water splitting applications". American Chemical Society, 2011. http://hdl.handle.net/1993/9225.
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