Bibliografías temáticas / Catecholate Monoanion

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Literatura académica sobre el tema "Catecholate Monoanion"

Autor: Grafiati
Publicado: 6 de septiembre de 2023

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Artículos de revistas sobre el tema "Catecholate Monoanion"

1

Greaves, Sarah J., and William P. Griffith. "Vibrational spectra of catechol, catechol-d2 and -d6 and the catecholate monoanion." Spectrochimica Acta Part A: Molecular Spectroscopy 47, no. 1 (1991): 133–40. http://dx.doi.org/10.1016/0584-8539(91)80185-l.

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Persson, Christina, Åke Oskarsson, and Carlaxel Andersson. "Tungsten(VI) complexes with bidentate coordination of the catecholate monoanion. Synthesis of [W(O)Cl3(O,HOC6H4)·O(C2H5)2] and synthesis and crystal structure of [W(O)Cl(O2C6H4)(O,HOC6H4)·O(C2H5)2]." Polyhedron 11, no. 16 (1992): 2039–44. http://dx.doi.org/10.1016/s0277-5387(00)83159-9.

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Wang, Peng, Glenn P. A. Yap, and Charles G. Riordan. "Iron(II)–alkoxide and –aryloxide complexes of a tris(thioether)borate ligand: synthesis, molecular structures, and implications on the origin of instability of their iron(II)–catecholate counterpart." Acta Crystallographica Section C Structural Chemistry 77, no. 9 (2021): 544–50. http://dx.doi.org/10.1107/s2053229621008500.

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The phenyltris[(tert-butylthio)methyl]borate ligand, [PhTt tBu], has been studied extensively as a platform for coordination, organometallic, and bioinorganic chemistry, especially with 3d metals. While [PhTt tBu]Co(3,5-DBCatH) (3,5-DBCatH is 3,5-di-tert-butylcatecholate), a CoII–monoanionic catecholate complex, was successfully isolated to model the active site of cobalt(II)-substituted homoprotocatechuate 2,3-dioxygenase (Co-HPCD) [Wang et al. (2019). Inorg. Chim. Acta, 488, 49–55], its iron(II) counterpart, [PhTt tBu]Fe(3,5-DBCatH), was not accessible via similar synthetic routes. Switching the nucleophile from catecholate to alkoxide or aryloxide, however, led to the successful isolation of three highly air-sensitive FeII–alkoxide and –aryloxide complexes, namely, (triphenylmethoxo){tris[(tert-butylsulfanyl)methyl]phenylborato-κ3 S,S′,S′′}iron(II), [Fe(C21H38BS3)(C19H15O)], (2), (2,6-dimethylphenolato){tris[(tert-butylsulfanyl)methyl]phenylborato-κ3 S,S′,S′′}iron(II), [Fe(C21H38BS3)(C8H9O)], (3), and bis{μ-tris[(tert-butylsulfanyl)methyl]phenylborato-κ3 S,S′:S′′}bis[(phenolato-κO)iron(II)] toluene disolvate, [Fe2(C21H38BS3)2(C6H5O)2]·2C7H8, (4). In the solid state, compounds (2) and (3) are monomeric, with [PhTt tBu] acting as a tridentate ligand. In contrast, compound (4) crystallizes as a dimeric complex, wherein each [PhTt tBu] ligand binds to an iron centre with two thioethers and binds to the other iron centre with the third thioether. The molecular structures of (2)–(4) demonstrate a diversity in the binding modes of [PhTt tBu] and highlight its potential use for assembling multinuclear complexes. In addition, the successful isolation of (2)–(4), as well as the structural information of a [PhTt tBu] modification product, namely, bis{μ-tris[(tert-butylsulfanyl)methyl](2-oxidophenolato)borato-κO,O′,S,S′:O′}dicobalt(II), [Co2(C21H37BO2S3)2], (5), obtained from the reaction of [PhTt tBu]CoCl with potassium monoanionic catecholate, shed light on the origin of the instability of [PhTt tBu]Fe(3,5-DBCatH).
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Adhikari, Sangita, Arnab Banerjee, Sandip Nandi, Matilde Fondo, Jesús Sanmartín-Matalobos та Debasis Das. "Structure, magnetism and catecholase activity of the first dicopper(ii) complex having a single μ-alkoxo bridge". RSC Advances 5, № 15 (2015): 10987–93. http://dx.doi.org/10.1039/c4ra14603d.

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Pyridine-2,6-dimethanol shows a neutral, monoanionic and dianionic coordination behaviour with two different coordination modes viz. tridentate and bidentate towards Cu(ii), leading to three different geometric environments around Cu(ii) centers.
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5

Jo, Du-Hwan, Yu-Min Chiou, and Lawrence Que. "Models for Extradiol Cleaving Catechol Dioxygenases: Syntheses, Structures, and Reactivities of Iron(II)−Monoanionic Catecholate Complexes." Inorganic Chemistry 40, no. 13 (2001): 3181–90. http://dx.doi.org/10.1021/ic001185d.

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6

Pattison, David I., Aviva Levina, Michael J. Davies, and Peter A. Lay. "An Investigation of the Chromium Oxidation State of a Monoanionic Chromium Tris(catecholate) Complex by X-ray Absorption and EPR Spectroscopies." Inorganic Chemistry 40, no. 2 (2001): 214–17. http://dx.doi.org/10.1021/ic000298u.

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7

Bhattacharyya, Debabrata, and Sai Ganesh Ramesh. "Multidimensional H-atom Tunneling in Catecholate Monoanion." Physical Chemistry Chemical Physics, 2022. http://dx.doi.org/10.1039/d1cp04590c.

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Bhattacharyya, Debabrata, and Sai Ganesh Ramesh. "Wavepacket dynamical study of H-atom tunneling in catecholate monoanion: Role of intermode couplings and energy flow." Physical Chemistry Chemical Physics, 2022. http://dx.doi.org/10.1039/d2cp03803j.

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We present a study of H-atom tunneling in catecholate monoanion through wavepacket dynamical simulations. In our earlier study of this symmetrical double-well system [Phys. Chem. Chem. Phys. 24, 10887 (2022)],...
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