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Literatura académica sobre el tema "Batterie Nickel-Zinc"

Autor: Grafiati

Publicado: 25 de mayo de 2024

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Artículos de revistas sobre el tema "Batterie Nickel-Zinc"

McBreen, James. "Nickel/zinc batteries". Journal of Power Sources 51, n.º 1-2 (agosto de 1994): 37–44. http://dx.doi.org/10.1016/0378-7753(94)01954-1.

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Yao, Shouguang, Xin Kan, Rui Zhou, Xi Ding, Min Xiao y Jie Cheng. "Simulation of dendritic growth of a zinc anode in a zinc–nickel single flow battery using the phase field-lattice Boltzmann method". New Journal of Chemistry 45, n.º 4 (2021): 1838–52. http://dx.doi.org/10.1039/d0nj05528j.

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Chang, H. y C. Lim. "Zinc deposition during charging nickel/zinc batteries". Journal of Power Sources 66, n.º 1-2 (mayo de 1997): 115–19. http://dx.doi.org/10.1016/s0378-7753(96)02536-0.

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Nazri, M. A., Anis Nurashikin Nordin, L. M. Lim, M. Y. Tura Ali, Muhammad Irsyad Suhaimi, I. Mansor, R. Othman, S. R. Meskon y Z. Samsudin. "Fabrication and characterization of printed zinc batteries". Bulletin of Electrical Engineering and Informatics 10, n.º 3 (1 de junio de 2021): 1173–82. http://dx.doi.org/10.11591/eei.v10i3.2858.

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Zinc batteries are a more sustainable alternative to lithium-ion batteries due to its components being highly recyclable. With the improvements in the screen printing technology, high quality devices can be printed with at high throughput and precision at a lower cost compared to those manufactured using lithographic techniques. In this paper we describe the fabrication and characterization of printed zinc batteries. Different binder materials such as polyvinyl pyrrolidone (PVP) and polyvinyl butyral (PVB), were used to fabricate the electrodes. The electrodes were first evaluated using three-electrode cyclic voltammetry, x-ray diffraction (XRD), and scanning electron microscopy before being fully assembled and tested using charge-discharge test and two-electrode cyclic voltammetry. The results show that the printed ZnO electrode with PVB as binder performed better than PVP-based ZnO. The XRD data prove that the electro-active materials were successfully transferred to the sample. However, based on the evaluation, the results show that the cathode electrode was dominated by the silver instead of Ni(OH)2, which leads the sample to behave like a silver-zinc battery instead of a nickel-zinc battery. Nevertheless, the printed zinc battery electrodes were successfully evaluated, and more current collector materials for cathode should be explored for printed nickel-zinc batteries.

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Hu, Hang, Anqiang He, Douglas Ivey, Drew Aasen, Sheida Arfania y Shantanu Shukla. "Failure Analysis of Nickel-Coated Anodes in Zinc-Air Hybrid Flow Batteries". ECS Meeting Abstracts MA2022-01, n.º 1 (7 de julio de 2022): 26. http://dx.doi.org/10.1149/ma2022-01126mtgabs.

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A zinc-air flow battery system pumps "fuel” (a zinc particle/KOH slurry) from a fuel tank to a fuel cell stack, where the zinc particles are combined with oxygen from the air to form zincate ions and produce electricity. The zincate-rich electrolyte is then returned to the fuel tank. During the charging cycle, the electrolyte is passed to the zinc regenerator, where electricity (from renewable sources such as solar or wind) is utilized to convert the zincate ions to zinc particles. The regenerated fuel is pumped back into the fuel tank for the discharge process. Nickel is considered for use as the anode during zinc regeneration as it has been shown to be an active catalyst for the oxygen evolution reaction (OER). However, nickel electrodes pose manufacturing challenges due to machinability issues. Alternatively, nickel can be coated on a machinable metal substrate to improve scalability. These electrodes are subjected to open circuit voltage (OCV), OER, and the hydrogen evolution reaction (HER) during operation of zinc-air flow batteries. The electrodes have been observed to fail during prolonged voltage cycling due to nickel coating delamination, which manifests itself as blistering, flaking, and discoloration. It is hypothesized that this may be due to electrolyte penetration into the pores of the nickel coating during operation. The present work is aimed at analyzing and mitigating the coating delamination process through characterization of various Ni coating recipes. As-fabricated and cycled electrodes are characterized using various microstructural techniques, including optical microscopy, x-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), and x-ray tomography. Coated electrodes are also evaluated electrochemically and the results are correlated with the microstructural analysis. The overall goal of the work is to understand the failure mechanisms and apply the knowledge to fabricate improved coatings for OER electrodes.

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Vahdattalab, Aydin, Ali Khani y Sajad Pirsa. "Study Nickel recycling and leaching of metals from Eco-Friendly Nickel-metal hydride battery by response surface method". Latin American Applied Research - An international journal 54, n.º 2 (11 de marzo de 2024): 201–11. http://dx.doi.org/10.52292/j.laar.2024.1235.

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In this research, nickel metal hydride batteries were designed in certain sizes and components. In order to evaluate the quality and quantity of the designed batteries, the metal mold was cut lengthwise from the inner layers of the battery. The active materials of the electrode used in this work were black powder and nickel alloy, which were manually separated from the batteries. Battery black powder was investigated by X-ray diffraction analyzes and the presence of nickel as the main constituent of black powder was confirmed. The results of atomic absorption showed that more than 99 % of the alloy were a nickel. In this study, black powder was leached with sulfuric acid. The influence of parameters such as temperature, sulfuric acid concentration and liquid to solid ratio (L/S) on nickel extraction in a discontinuous system at two-phase constant contact time were studied. According to the results, the parameters of sulfuric acid concentration, temperature, liquid to solid ratio and the interaction of acid concentration with itself were important in nickel extraction. Optimal leaching conditions included a temperature of 60 °C, an acid concentration of 1.42 mol/L and a liquid to solid ratio of 10 mL. Under optimal conditions, the leaching efficiency was 81.25%, which was better compared to the batteries with other models and brands. In the next step, the purification of the leaching solution was investigated by sodium carbonate and a combination of sodium carbonate and sodium hydroxide. The results of atomic absorption showed that more than 83% of cobalt, manganese and zinc were removed and more than 98% of nickel ions were recycled, which was better than commercial batteries of various brands. Because the return of cobalt, manganese and zinc to nature by other batteries is higher than the designed battery and the recycling percentage of nickel ions is lower, these results are very important in terms of environmental safety.

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Long, Jeffrey W., Ryan H. DeBlock, Christopher N. Chervin, Joseph F. Parker y Debra R. Rolison. "(Invited) Architected Zinc Anodes Enable Next-Generation Aqueous Rechargeable Batteries". ECS Meeting Abstracts MA2023-01, n.º 5 (28 de agosto de 2023): 900. http://dx.doi.org/10.1149/ma2023-015900mtgabs.

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Zinc-based batteries offer the compelling benefits of a high-capacity, abundant anode material and the use of aqueous electrolytes for ease of assembly and safe operation. To solve the standing roadblock to rechargeable zinc-based batteries—shape change and dendrite formation under demanding cycling conditions—we adapt lessons of 3D electrode design from our prior breakthroughs with energy-storing nanoarchitectures. Zinc “sponge” form factors are fabricated by fusing 50–100 mm zinc particles into a porous, monolithic structure. Electrochemical reaction fronts are distributed throughout these 3D-wired zinc architectures, effectively thwarting dendrite formation and homogeneously distributing reaction products, even at high current density [1,2]. Over the development course of the NRL Zn sponge anode, each successive generation has been further optimized with manufacturability as a foremost consideration, such that the current sponge formulation is readily and simply processed at increasing scale to sizes necessary for relevant energy-storage applications. Zinc sponges are evaluated in multiple battery configurations including zinc–air, nickel–zinc, and silver–zinc to validate such performance characteristics as cycle life and specific power. We are also expanding 3D architecture concepts to other metals of relevance for battery applications. [1] J.F. Parker, C.N. Chervin, E.S. Nelson, D.R. Rolison, J.W. Long, “Wiring zinc in three dimensions re-writes battery performance―Dendrite-free cycling.” Energy Environ. Sci., 7, 1117–1124 (2014). [2] J.F. Parker, C.N. Chervin, I.R. Pala, M. Machler, M.F. Burz, J.W. Long, and D.R. Rolison, “Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion.” Science, 356, 415–418 (2017).

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Illoul, Aboubaker Essedik, Vincent Caldeira, Marian Chatenet y Laetitia Dubau. "Approaches Towards Improving Zinc-Nickel Batteries Performance". ECS Meeting Abstracts MA2022-01, n.º 1 (7 de julio de 2022): 21. http://dx.doi.org/10.1149/ma2022-01121mtgabs.

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The zinc/nickel electrochemical system has long been proposed as a good candidate of secondary alkaline batteries due to its excellent performance versus other aqueous batteries, such as high practical specific energy, excellent specific power, high open circuit voltage, low cost and low toxicity [1,2]. These advantages make it suitable for replacing lead-acid and nickel-cadmium batteries [3]. However, the high solubility of zinc in concentrated alkaline electrolytes is still a significant problem that induces two main failure mechanisms: a shape-change of the zinc electrode and a redistribution of the zinc active material due to its dissolution/redeposition during cycling. Dendritic growth can occur as a consequence of zinc dissolution/redeposition, and if severe, may lead to separators’ perforation and internal electrical short-circuits [4]. These drawbacks reduce the cell's capacity and lifetime, especially compared to traditional competing systems [5]. In addition, since the hydrogen evolution reaction (HER) is thermodynamically possible (especially during charging), the coulombic efficiency of the zinc electrode can be lowered by this parasite reaction [6]. The undesirable HER consumes water and some of the active material, yielding zinc hydroxide which in turn can generate a passivation layer that lowers the usability of the zinc anode materials [7]. There are different approaches to overcome these problems, such as the integration of additives in the active material formulation and/or in the electrolyte. In this contribution, we will show how regeneration of the active material can be obtained via appropriate steps of rest submitted to the active material and without the need for additional energy input. The so-called “self-healing” of the active material allows to recover a substantial part of the electrochemical performance. The concept was deeply studied and monitored by scanning electron microscopy coupled with elemental mapping by X-ray energy dispersive spectrometry, and operando tomography. An increase in the coulombic efficiency has been demonstrated making this discovery very promising for the future of zinc-based alkaline batteries. Keywords: Zinc-nickel batteries, additives, self-healing References: [1] M. Ma et al., “Electrochemical performance of ZnO nanoplates as anode materials for Ni/Zn secondary batteries,” J. Power Sources, vol. 179, no. 1, pp. 395–400, 2008, doi: 10.1016/j.jpowsour.2008.01.026. [2] S. H. Lee, C. W. Yi, and K. Kim, “Characteristics and electrochemical performance of the TiO 2-coated ZnO anode for Ni-Zn secondary batteries,” J. Phys. Chem. C, vol. 115, no. 5, pp. 2572–2577, 2011, doi: 10.1021/jp110308b. [3] B. Yang, Z. Yang, R. Wang, and Z. Feng, “Silver nanoparticle deposited layered double hydroxide nanosheets as a novel and high-performing anode material for enhanced Ni-Zn secondary batteries,” J. Mater. Chem. A, vol. 2, no. 3, pp. 785–791, 2014, doi: 10.1039/c3ta14237j. [4] Q. Zhang, J. Luan, Y. Tang, X. Ji, and H. Wang, “Interfacial Design of Dendrite-Free Zinc Anodes for Aqueous Zinc-Ion Batteries,” Angew. Chemie - Int. Ed., vol. 59, no. 32, pp. 13180–13191, 2020, doi: 10.1002/anie.202000162. [5] C. Chemist and B. Hill, “Introduction,” pp. 191–192, 1800. [6] S. Bin Lai et al., “A promising energy storage system: rechargeable Ni–Zn battery,” Rare Met., vol. 36, no. 5, pp. 381–396, 2017, doi: 10.1007/s12598-017-0905-x. [7] H. Kim, G. Jeong, Y. U. Kim, J. H. Kim, C. M. Park, and H. J. Sohn, “Metallic anodes for next generation secondary batteries,” Chem. Soc. Rev., vol. 42, no. 23, pp. 9011–9034, 2013, doi: 10.1039/c3cs60177c. Figure 1

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Shi, Xiangze, Xiao Li, Zijian He y Hui Jiang. "Dynamic Evolution of the Zinc-Nickel Battery Industry and Evidence from China". Discrete Dynamics in Nature and Society 2021 (7 de agosto de 2021): 1–15. http://dx.doi.org/10.1155/2021/1992845.

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This paper analyzes the development prospects of zinc-nickel battery industry, further investigates the industry competition in existing markets by mathematical modeling, calculates the equilibrium price and profit of the oligarch competition by using the method of Stackelberg equilibrium and Nash equilibrium, and makes a comparison between them. Then, we study and model the case of renting and selling simultaneously. In addition, we also study the impact of futures prices on the zinc-nickel battery companies and carry out numerical simulation. At the end of this paper, we analyze the location of zinc-nickel battery enterprises and the industry development under the COVID-19 pandemic. The finding show that the reduction of raw material cost is of great help to the development of the zinc-nickel battery industry.

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Opitz, Martin y Seniz Sörgel. "Zinc Slurry Electrodes for Double Flow Zinc-Nickel Batteries". ECS Meeting Abstracts MA2023-02, n.º 4 (22 de diciembre de 2023): 709. http://dx.doi.org/10.1149/ma2023-024709mtgabs.

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Lithium-based systems are still the major storage technology especially in mobile applications like electromobility and consumer electronics. However, in the field of stationary energy storage devices, redox-flow batteries exhibit significant advantages because energy and power can be scaled independently and the device can be discharged up to 20 h, in contrast to lithium-ion batteries.[1] In the field of redox-flow batteries, the main focus is placed on vanadium-based systems. However, vanadium-based systems have some drawbacks due to the low gravimetric energy densities, the toxicity [2] and the high price of vanadium [3], as well as the short life span of the membrane separating the half-cells.[4] In our research project NiZi-Flow², a new concept of flow cells based on nickel and zinc is investigated, in which slurries of zinc and nickel-hydroxide particles are pumped through the flow battery, respectively. Our part in the project is the examination of the electrodeposition and dissolution of zinc under idealized conditions to obtain the influence of flow and current density parameters on the zinc surface morphology. To study the zinc half-cell, a stirred electrochemical cell was designed and cycling experiments with the zinc slurry were performed. M. Skyllas-Kazacos, M.H. Chakrabarti, S.A. Hajimolana, F.S. Mjalli, M. Saleem, J. Electrochem. Soc., 158 (2011) R55. A. Ciotola, M. Fuss, S. Colombo, W.-R. Poganietz, J. Energy Storage, 33 (2021) 102094. T. Nguyen, R.F. Savinell, Electrochem. Soc. Interface, 19 (2010) 54–56. A.Z. Weber, M.M. Mench, J.P. Meyers, P.N. Ross, J.T. Gostick, Q. Liu, J. Appl. Electrochem., 41 (2011) 1137–1164.

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Tesis sobre el tema "Batterie Nickel-Zinc"

Vidal, David. "Développement et évaluation de nouveaux séparateurs pour les batteries Nickel-Zinc". Electronic Thesis or Diss., CY Cergy Paris Université, 2023. http://www.theses.fr/2023CYUN1273.

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Les batteries nickel-zinc offrent des performances qui répondent aux exigences du stockage d'énergies renouvelables intermittentes. De plus, par rapport aux batteries lithium-ion, cette technologie est sûre, hautement recyclable et le zinc est un métal abondant. Dans ces batteries, les électrodes sont séparées par un séparateur polymère qui limite la diffusion des zincates de l'électrode de zinc vers celle de nickel tout en favorisant le transfert des ions hydroxyde. Cependant, la durée de vie de ces séparateurs limite actuellement les performances de la batterie. Il existe donc un besoin critique d'en développer des plus durables fonctionnant avec un électrolyte alcalin.Ce travail de thèse s'est d'abord axé sur l'étude des principales caractéristiques (diffusion aux ions hydroxyde, mouillabilité…) des séparateurs commerciaux Celgard traités par un revêtement hydrophile ou non, et sur leur évolution lors d'un vieillissement chimique. Cette étude a permis de corréler la désorption du revêtement hydrophile et la perte des performances observées en batterie.Afin d'améliorer leur stabilité dans le temps, un polymère hydrophile réticulé, l'alcool polyvinylique (PVA), a été introduit dans le volume poreux de plusieurs séparateurs, se différenciant par la présence ou non d'un revêtement hydrophile. La présence de ce polymère réticulé s'est avéré améliorer la mouillabilité du séparateur mais aussi la diffusion des ions hydroxyde. Ces propriétés sont conservées à la suite d'un vieillissement chimique accéléré dans l'eau ou l'électrolyte alcalin.L'introduction de surfactants en combinaison avec le PVA permet d'améliorer encore ces propriétés tandis que le PVA augmente la stabilité du séparateur au cours du vieillissement. Enfin, des tests en batterie Ni-Zn utilisant les séparateurs développés au cours de cette thèse ont confirmé ces résultats prometteurs
Nickel-Zinc based batteries offer performances that match the requirements of the storage of the intermittency of renewable energies. Moreover, compared to Lithium-ion batteries, this technology happens to be safe, highly recyclable and zinc is an abundant metal. In these batteries, electrodes are separated by a polymer separator restricting the diffusion of zincate ions from zinc electrode towards the nickel while promoting the transfer of hydroxide ions. However, the lifetime of these separators currently limits the battery's performance. Thus, there is a critical need to develop more durable separators for batteries operating in alkaline electrolyte.This PhD work first focused on the study of the main characteristics of commercially (hydroxide diffusion, wettability, etc.) of commercial Celgard® separators, treated with a hydrophilic coating or not, and on their evolution under a chemical ageing. This study allowed correlate the desorption of hydrophilic coating with the decay in battery performances.To improve the performance stability over time, a cross-linked hydrophilic polymer, polyvinyl alcohol (PVA), was introduced into the porous volume of several separators, differentiated by the presence or absence of a hydrophilic coating. The presence of this crosslinked polymer was found to improve the separator wettability and the hydroxide ion diffusion. These properties are preserved after an accelerated chemical ageing in water or alkaline electrolyte.The introduction of surfactants in combination with PVA further improves these properties, while PVA enhances the separator's stability during aging. Finally, Ni-Zn battery tests using the separators developed during this thesis have confirmed these promising results

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Qu, Cheng. "Novel Polymer Electrolyte Membranes for Nickel-Zinc Battery". University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1384534927.

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Turner, Jeff. "Modeling the behaviour of nickel- zinc batteries in a recreational-scale electric vehicle". Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=103564.

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The global effort to reduce the environmental impact of transportation has led to a renewed interest in electric vehicle technology. One of the factors limiting the success of electric vehicles is the high cost of current battery technology. Nickel-zinc batteries could potentially offer a low cost alternative for certain electric vehicle applications. This thesis explores the potential use of nickel-zinc batteries in a recreational-scale electric vehicle through the use of powertrain modeling and simulation. A methodology was established to analyze the performance of the batteries at various temperatures and an internal resistance battery model was developed. This model was then integrated into a previously validated powertrain model of an electric snowmobile in order to simulate the use of these batteries in a recreational vehicle application. The results of these simulations were recreated experimentally in a laboratory environment with reasonable accuracy, confirming the validity of the battery model and the employed methodology.
L'effort mené à l'échelle mondiale pour la réduction de l'impact environnemental des transports a mené à un renouveau de l'intérêt porté aux véhicules électriques. Un des facteurs importants qui limitent le succès de ces véhicules est le coût élevé des piles disponibles. Des piles au nickel-zinc pourraient potentiellement offrir une alternative abordable qui conviendrait aux besoins énergétiques de certains véhicules électriques. Ce mémoire explore le potentiel des piles au nickel-zinc pour les véhicules récréatifs électriques, en faisant de la modélisation et des simulations de motorisation. La performance des piles à différentes températures fut analysée afin de créer un modèle de leur résistance interne. Ce modèle fut intégré dans un modèle de la motorisation d'une motoneige électrique afin de simuler la performance des piles dans un véhicule récréatif. Des tests en laboratoire ont produit des résultats comparables à ceux produits par simulation virtuelle, confirmant ainsi la validité du modèle de pile et la méthodologie employée.

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De, Villiers Daniel. "The application of new generation batteries in old tactical radios / D. de Villiers". Thesis, North-West University, 2007. http://hdl.handle.net/10394/738.

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The power requirement for the soldier's equipment is largely supplied by batteries. Situational awareness is critical for a soldier to perform his tasks. Therefore the radio used by the soldier is a key element in situational awareness and also consumes the most power. The South African National Defence Force (SANDF) uses the A43 tactical radio specifically designed for them. The radios are regarded as old technology but will be in use for about another five years. The radios still use non-rechargeable alkaline batteries which do not last very long and are not cost effective. The purpose of this study is to research the new generation secondary batteries as a possible replacement for the alkaline battery packs. The new generation batteries investigated in this study are the latest rechargeable batteries, also called secondary batteries. They include nickel cadmium, nickel metal hydride, lithium ion, rechargeable alkaline manganese and zinc air. The main features of rechargeable cells are covered and the cell characteristics are defined to allow the technology to be matched to the user requirement. Li-ion technology was found to be the best choice. This research also showed that international trends in battery usage are towards Li-ion. A new Li-ion battery was designed based on commercial cells. Tests showed that commercial Li-ion cells can be used in the radio and that they outperform the current battery by far. The study also examined the design of a New Generation Battery System consisting of an intelligent battery, a charger which uses a Systems Management Bus and a battery 'state of health" analyser to assist the user to maintain the batteries. Tests were done to demonstrate that the battery can withstand typical military environmental conditions. Expected military missions for a battery system were defined and used to compare the cost between the existing batteries and the new batteries system. Important usage factors which will influence the client when using a New Generation Battery System were addressed. To summarise, this study showed that by using a New Generation Battery System, the SANDF could relieve the operational cost of the A43 radio while saving on weight and enabling the soldier to carry out longer missions.
Thesis (M.Ing. (Electronical Engineering))--North-West University, Potchefstroom Campus, 2008.

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Gourrier, Laure. "Contribution à l'étude de l'hydroxyde de Nickel : aspects fondamentaux et influence du Zinc". Thesis, Montpellier 2, 2011. http://www.theses.fr/2011MON20232/document.

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Ce travail est peut être séparé en deux parties. Dans la première, nous rapportons l'étude menée sur un composé modèle d'hydroxyde de Nickel. La caractérisation de ce composé par diffraction X montre qu'il possède une cristallinité supérieure aux hydroxydes de nickel habituellement utilisés. L'observation au microscope électronique à balayage révèle que la poudre est constituée de grains hexagonaux, de dimension supérieure au micromètre, formés de monocristaux, eux aussi hexagonaux, empilés de façon très ordonnée. Les mesures électrochimiques montrent quant à elles que les composés modèles présentent des propriétés redox intéressantes. La morphologie très particulière de ce composé confère à cet hydroxyde de nickel un comportement de type monocristal en spectroscopie Raman. Des mesures in-situ, couplant voltamétrie cyclique et spectroscopie Raman, réalisées sur ce composé modèle, ont donc été mises en place. Les premiers résultats montrent que ces expériences pourraient nous aider à améliorer notre compréhension des mécanismes redox fondamentaux mis en jeu.Dans la deuxième partie, nous étudions le comportement électrochimique d'une électrode de nickel lorsque l'électrolyte (i.e. KOH 7N) est saturé en zinc. Des électrodes de type industriel ont été préparées à partir d'un hydroxyde de Nickel standard et non dopé, puis cyclées en condition galvanostatique. Les échantillons ainsi obtenus ont ensuite été caractérisés par MEB, DRX, IR et EXAFS. Cette dernière technique qui s'est avérée être la plus appropriée pour l'analyse de ces matériaux d'électrodes très hétérogènes nous a ainsi permis d'apporter des réponses pertinentes sur l'insertion du zinc dans la structure cristalline de Ni(OH)2
This work may be separated in two parts. First, we report the study of a model compound of nickel hydroxide. X-ray diffraction shows that this compound has a better crystallinity than the standard nickel hydroxides used in commercial battery. Scanning Electron Microscopy revealed that the powder of this model hydroxide is composed of hexagonal grains whose dimension is larger than micrometer and who are formed of single-crystals, also hexagonal, stacked in a well ordered way. The electrochemical measurements show that this nickel hydroxide exhibit interesting redox properties. The particular morphology of the compound gives single-crystal type behavior in Raman spectroscopy. Therefore, in-situ measurements combining electrochemical measurements and Raman spectroscopy, performed on a single microscopic hexagonal plate, are proposed. Preliminary results emphasize that this experiment may help us to improve our understanding of the fundamental redox mechanism taking place in nickel hydroxide.Secondly, we study the electrochemical behavior of a nickel electrode in the presence of Zinc in the electrolyte. Industrial-type electrodes were prepared from a standard undoped nickel hydroxide. Then, samples obtained after electrochemical test were characterized by SEM, XRD, IR and EXAFS. The later which turned out to be the most appropriate for the analysis of our electrode materials, allowed us to get deeper insights in the insertion of zinc in the structure of Ni(OH)2

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Hariprakash, B. "Studies On Lead-Acid, Nickel-Based And Silver-Zinc Rechargeable Batteries". Thesis, 2004. https://etd.iisc.ac.in/handle/2005/2207.

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Hariprakash, B. "Studies On Lead-Acid, Nickel-Based And Silver-Zinc Rechargeable Batteries". Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/2207.

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Sitindaon, Rina Se y 瑟琳娜. "Zn-MnO2 Nanomaterials on Nickel Foam as Cathode Electrode in Zinc Ion Batteries (ZIBs)". Thesis, 2019. http://ndltd.ncl.edu.tw/handle/m89v3n.

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碩士
國立中興大學
化學系所
107
This thesis discuss the MnO2 nanomaterials composited zinc ion on nickel foam as cathode electrode in Zinc Ion Battery. The materials fabricated by electrodechemical deposition from aqueouse 1 M Na2SO4 solution and 0.01 M MnSO4 solution as soure of MnO2 and ZnSO4 solution as source of zinc ion on nickel foam substrate. The electrodeposited MnO2 composite zinc (Zn-MnO2) result MnO2 gamma plane. The Zn-MnO2 electrochemical properties has been characterize by using cyclic votammetry and galvanostic charge/discharge analysis on coin cell 2032 type with potential range 1.0-1.8 V. The cyclic voltammograms shows of Zn-MnO2 is higher than pristine MnO2 as cathode on Zinc ion battery. Galvanostatic charge shows specific capacity of Zn-MnO2 ( 77.59 mAh/g) almost three times higher than pristine MnO2 (28.34 mAh/g) at current density 0.05 mA/cm2. The zinc composite improving the electrochemical activity of MnO2 conduce the specific capacity in Zinc Ion Battery. The Zn-MnO2 is a promissing cathode material for used in Zinc ion batteries.

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Chien, Yu Ju y 簡佑如. "Ternary Spinel Nickel-Cobalt-Based Oxides for the Air Electrode of Rechargeable Zinc-Air Batteries". Thesis, 2016. http://ndltd.ncl.edu.tw/handle/41522026190665281911.

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碩士
國立清華大學
化學工程學系
104
There are two parts in this research. In the first part, partially substituted MxNi1-xCo2O4 (M = Mn, Fe, Cu, and Zn, x=0.1) spinel oxides, labeled as MNCO-01, FNCO-01, CNCO-01, and ZNCO-01, were synthesized via a facilely hydrothermal method. The effects of the metal partially substitution in the Ni site of the spinel oxide on the morphology and electrocatalytic properties of the materials toward the ORR and OER were investigated and compared by using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), inductively coupled plasma-mass spectrometer (ICP-MS), X-ray photoelectron spectroscopy (XPS), surface area analyzer and electrochemical techniques including cyclic voltammetry (CV), linear sweep voltammetry (LSV), tafel plot, and galvanodynamic charge-discharging. As a result, the iron-substituted nickel-cobalt based oxides (FNCO-01) displayed a significant electrocatalytic activity towards both the ORR and OER in comparison with the Mn-substituted, Cu-substituted, and Zn-substituted nickel-cobalt based oxides. In the second part, the spinel-type ternary transition metal oxides of nickel, cobalt, and iron with the composition FexNi1-xCo2O4 (0 ≤ x ≤ 1) were prepared and tested as promising electrocatalysts for the ORR and OER in alkaline solution. The structural, morphological and electrocatalytic performances confirmed that substitution of Ni by Fe increases the electrocatalytic activity of the resulting material significantly. The highest activity was achieved for FexNi1-xCo2O4 with 0.1 ≤ x ≤ 0.3. The practicality of the catalyst were corroborated by testing in a realistic rechargeable zinc-air battery utilizing atmospheric air in ambient conditions, where FexNi1-xCo2O4 (x=0.3) demonstrated superior charge and discharge voltages and long-term cycle stability with virtually no battery voltage fading. The excellent electrochemical results presented in this study highlight the FexNi1-xCo2O4 as highly efficient and commercially viable bifunctional catalyst for rechargeable metal-air battery application.

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Tsai, Yi-Ying y 蔡宜穎. "Nickel iron layered double hydroxide derived bifunctional oxygen electrode catalyst for rechargeable zinc/air batteries". Thesis, 2018. http://ndltd.ncl.edu.tw/handle/qwd872.

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碩士
國立臺灣科技大學
化學工程系
106
In recent years, rechargeable zinc-air batteries have attracted much attention owing to its high energy density, promising safety, and economic viability. In air electrode, bi-functional electrocatalysts are desirable since the dual functionality of the oxygen evolution reaction (OER) and oxygen oxygen reduction reaction (ORR) are required on the same electrode under charging and discharging processes, respectively. Unfortunately, both ORR catalyst Pt/C and OER catalyst IrO2 don’t have bifunctional property. The high cost of precious Pt/C and IrO2 catalysts also limit their wide spread application. In the light of this, this work provides a promising bi-functional electrocatalyst with earth-abundant elements to enable the oxygen conversion reaction efficiently. Carbon supported NiFe layered double hydroxide (NiFe LDH/C) can be synthesized by a facile hydrothermal method which can precisely control the catalyst’s composition. Then, the optimal NiFe LDH/C was used as precursor and further reduced to bi-functional catalyst by hydrogen reduction and thermal ammonolysis. The results show that NiFe/NiFeN/NC nanocomposites, characterized by duel electroactive sites for OER and ORR, can be simultaneously derived by thermal ammonolysis process. According to the electrochemical measurements by linear sweep voltammetry (LSV), NiFe/NiFeN/NC nanocomposite calcined in ammonia at 500 oC demonstrates excellent activities for oxygen conversion reaction, when compared to NiFe LDH and NiFe/C. Its overpotential △E between the ORR current density of 3 mA cm−2 and OER current density of 10 mA cm−2 is 0.91 (V). In the stability test, a chronoamperometry method was used in 0.1 M KOH. After 6 hours, NiFe/NiFeN/NC catalyst calcined at 500 oC showed high stability with a decline of current of 8.9% and 14.1% in OER and ORR, comparable to 29.1% for IrO2 and 7.7% for Pt/C, respectively. In addition, the ORR stability test in 1 M KOH showed that the activity decayed 18.4% for NiFe/NiFeN/NC, whereas 23.1% for Pt/C. This indicates that the composite catalyst is more suitable for operations under harsh environments. This study further attempts to establish a rechargeable zinc-air battery test platform and analyze material performance. NiFe/NiFeN/NC shows good stability and its performance is comparable to that of Pt/C+IrO2, confirming its bi-functional property. Considering the cost and mass production, NiFe/NiFeN/NC offers more advantages than the combination of noble materials with Pt/C and IrO2. Keywords:Alkaline, Bifunctional electrocatalyst, Layered double hydroxide, N-doped carbon, Rechargeable zinc-air battery.

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Capítulos de libros sobre el tema "Batterie Nickel-Zinc"

Li, Xiang, Kang Li, Zhile Yang y Chikong Wong. "A Novel RBF Neural Model for Single Flow Zinc Nickel Batteries". En Communications in Computer and Information Science, 386–95. Singapore: Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-6364-0_39.

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Li, Yihuan, Kang Li, Shawn Li y Yanxue Li. "FRA and EKF Based State of Charge Estimation of Zinc-Nickel Single Flow Batteries". En Communications in Computer and Information Science, 183–91. Singapore: Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-13-2381-2_17.

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Lai, Qinzhi, Chenhui Wang, Yang Song, Xianfeng Li y Huamin Zhang. "Zinc–Nickel Single Flow Battery". En Redox Flow Batteries, 355–72. CRC Press, 2017. http://dx.doi.org/10.1201/9781315152684-10.

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Cairns, E. J. "SECONDARY BATTERIES – NICKEL SYSTEMS | Nickel–Zinc". En Encyclopedia of Electrochemical Power Sources, 528–33. Elsevier, 2009. http://dx.doi.org/10.1016/b978-044452745-5.00156-8.

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Fetcenko, M., J. Koch y M. Zelinsky. "Nickel–metal hydride and nickel–zinc batteries for hybrid electric vehicles and battery electric vehicles". En Advances in Battery Technologies for Electric Vehicles, 103–26. Elsevier, 2015. http://dx.doi.org/10.1016/b978-1-78242-377-5.00006-6.

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Thun, Michael. "Kidney Dysfunction in Cadmium Workers". En Case Studies in Occupational Epidemiology, 105–26. Oxford University PressNew York, NY, 1992. http://dx.doi.org/10.1093/oso/9780195068313.003.0008.

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Abstract In May 1985, workers at a cadmium production plant in Denver, Colorado, requested that the National Institute for Occupational Safety and Health (NIOSH) further evaluate health effects due to cadmium at their plant. The plant had produced cadmium since 1925. Airborne exposures to cadmium dust and fume were extremely high in the past, but had decreased because of engineering controls and required use of respirators. The main function of the plant was to recover cadmium from “bag house” dust, a waste by-product of zinc smelters. Cadmium metal, oxide, and sulfide were sold for use in electroplating, pigments, plastics, nickel-cadmium batteries, and brazing. Small amounts of other metals (copper, selenium, thallium, arsenic, indium, and lead) had also been processed in localized areas of the plant, but the predominant exposure was to cadmium.

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Stoyanova-Ivanova, Angelina y Stanislav Slavov. "RESEARCH OF MULTIFUNCTIONAL CERAMIC MATERIALS FOR THEIR APPLICATION". En Ceramic Materials - Present and Future [Working Title]. IntechOpen, 2023. http://dx.doi.org/10.5772/intechopen.1002615.

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A new challenge is obtaining and researching ceramic multifunctional materials containing phases with various properties, as well as Aurivillius phases, which determine their application. They show potential for use in electrochemical applications and ferroelectric and piezoelectric devices, sensors, and non-volatile memories. Presented are our studies of volumetric nonmonophasic ceramics from the RE-Ba-Cu-O (ReBCO, RE = rare-earth; Y, Dy) and Bi-Pb-Sr-Ca-Cu-O (B(Pb) SCCO) systems that are superconductors, obtained via solid phase synthesis. A bulk ceramic composite Y123/BaCuO2 was synthesized with starting stoichiometry of 1:3:4(Y:Ba:Cu) via a one-step procedure. It has superconducting and magnetic properties at low temperatures. DyBCO bulk ceramic with a nano-Fe3O4 additive was synthesized and characterized to identify the phase and elemental composition, the microstructure, and the superconducting transition temperature. The Aurivillius phases were synthesized via solid-phase synthesis and a melt-quench method. B(Pb)SCCO ceramics (2223, 2212, and 2201), with conductive properties, have been used as an addition to the active mass of a Zn electrode. The method of mixing the materials was also investigated. Their behavior in an alkaline environment and positive influence on the properties and longevity of the nickel-zinc battery has been studied. Part of the obtained ceramic systems was patented.

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Actas de conferencias sobre el tema "Batterie Nickel-Zinc"

Coates, Dwaine y Allen Charkey. "Nickel-Zinc Batteries for Commercial Applications". En 34th Intersociety Energy Conversion Engineering Conference. 400 Commonwealth Drive, Warrendale, PA, United States: SAE International, 1999. http://dx.doi.org/10.4271/1999-01-2512.

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Coates, D. y A. Charkey. "Electrical characterization testing of sealed nickel-zinc batteries". En IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203). IEEE, 1997. http://dx.doi.org/10.1109/iecec.1997.661881.

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Liu, Xuehu, Zili Xie, Jie Cheng, Pengcheng Zhao y Weidong Gu. "Mathematical modeling of the nickel electrode for the single flow zinc-nickel battery". En 2009 World Non-Grid-Connected Wind Power and Energy Conference (WNWEC 2009). IEEE, 2009. http://dx.doi.org/10.1109/wnwec.2009.5335869.

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Li, X., C. K. Wong y Z. L. Yang. "A novel flowrate control method for single flow zinc/nickel battery". En 2016 International Conference for Students on Applied Engineering (ICSAE). IEEE, 2016. http://dx.doi.org/10.1109/icsae.2016.7810156.

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Zhang, Li, Kang Li, Zhile Yang, Xiang Li, Yuanjun Guo, Dajun Du y Chikong Wong. "Compact Neural Modeling of Single Flow Zinc-Nickel Batteries Based on Jaya Optimization". En 2018 IEEE Congress on Evolutionary Computation (CEC). IEEE, 2018. http://dx.doi.org/10.1109/cec.2018.8477707.

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Yao, Shouguang, Yunhui Zhao, Zhenhao Zhang, Min Xiao, Jie Cheng y Yaju Shen. "MULTIPHYSICS-COUPED FIELD ANALYSIS FOR ZINC-NICKEL SINGLE- FLOW BATTERY CELL STACK". En International Heat Transfer Conference 16. Connecticut: Begellhouse, 2018. http://dx.doi.org/10.1615/ihtc16.ecl.023229.

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Li, Yan-Xue, Man-Chung Wong, Weng-Fai Ip, Peng-Cheng Zhao, Chi-Kong Wong, Jie Cheng y Zi-Yang You. "Modeling of novel single flow zinc-nickel battery for energy storage system". En 2014 IEEE 9th Conference on Industrial Electronics and Applications (ICIEA). IEEE, 2014. http://dx.doi.org/10.1109/iciea.2014.6931427.

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Cao, Frank, Allen Charkey y Keith Williams. "Thermal behavior and end-of-life characteristics of the nickel-zinc battery". En 35th Intersociety Energy Conversion Engineering Conference and Exhibit. Reston, Virigina: American Institute of Aeronautics and Astronautics, 2000. http://dx.doi.org/10.2514/6.2000-2975.

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Shahi, Shashi K. y G. Gary Wang. "Plug-In Hybrid Electric Vehicle Battery Selection for Optimum Economic and Environmental Benefits Using Pareto Set Points and PSAT™". En ASME 2010 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. ASMEDC, 2010. http://dx.doi.org/10.1115/detc2010-28972.

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Plug-in hybrid electric vehicles (PHEVs) have the potential to reduce green house gases emissions and provide a promising alternative to conventional internal combustion engine vehicles. However, PHEVs have not been widely adopted in comparison to the conventional vehicles due to their high costs and short charging intervals. Since PHEVs rely on large storage batteries relative to the conventional vehicles, the characteristics and design issues associated with PHEV batteries play an important role in the potential adoption of PHEVs. Consumer acceptance and adoption of PHEVs mainly depends on fuel economy, operating cost, operation green house gas (GHG) emissions, power and performance, and safety among other characteristics. We compare the operational performance of PHEV20 (PHEV version sized for 20 miles of all electric range) based on fuel economy, operating cost, and greenhouse gas (GHG) emissions through Pareto set point identification approach for 15 different types of batteries, including lithium-ion, nickel metal hydride (NiMH), nickel zinc (NiZn), and lead acid batteries. It is found that two from 15 batteries dominate the rest. Among the two, a NiMH (type ess_nimh_90_72_ovonic) gives the highest fuel economy, and a lithium-ion (type ess_li_7_303) yields the lowest operating cost and GHG emissions. From comparing nine batteries that are either on or close to the Pareto frontier, one can see that lithium-ion and NiMH batteries offer better fuel economy than lead-acid batteries. Though lithium-ion batteries bear clear advantage on operating costs and GHG emissions, NiMH and lead-acid batteries show similar performances from these two aspects.

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Vidakovic, Miodrag, Bruno Rente, Matthias Fabian, Xiang Li, Peter Fisher, Kang Li, Tong Sun y Kenneth Grattan. "Flow measurement inside a zinc-nickel flow cell battery using FBG based sensor system". En Seventh European Workshop on Optical Fibre Sensors (EWOFS 2019), editado por Kyriacos Kalli, Gilberto Brambilla y Sinead O. O'Keeffe. SPIE, 2019. http://dx.doi.org/10.1117/12.2539875.

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