Dissertations / Theses on the topic 'Wood structure'
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Kultikova, Elena V. "Structure and Properties Relationships of Densified Wood." Thesis, Virginia Tech, 1999. http://hdl.handle.net/10919/35810.
Full textSpecimens of both mature and juvenile southern pine (Pinus taeda) and yellow-poplar (Liriodendron tulipifera) were compressed radially at three different temperature, and moisture content conditions relevant to the glass transition of wood.
Ultimate tensile stress and longitudinal modulus of elasticity were obtained by testing compressed, uncompressed and control samples in tension parallel-to-grain. Strain measurements were performed using laboratory-built clip-on strain gauge transducers. Results of the tensile tests have shown an increase in the ultimate tensile stress and modulus of elasticity after all densification treatments.
Scanning electron microscopy was employed for observing changes in cellular structure of densified wood. Existence of the cell wall fractures was evaluated using image processing and analysis software. Changes in cellular structure were correlated with the results of the tensile test.
Chemical composition of wood samples before and after desorption experiments was determined by acid hydrolysis followed by high performance liquid chromatography (HPLC). The results of the chemical analysis of the wood specimens did not reveal significant changes in chemical composition of wood when subjected to 160 °C, pure steam for up to 8 hours.
The results of this research will provide information about modifications that occur during wood compression and will result in better understanding of material behavior during the manufacture of wood-based composites. In the long run, modification of wood with inadequate mechanical properties can have a significant effect on the wood products industry. Low density and juvenile wood can be used in new high-performance wood-based composite materials instead of old-growth timber.
Master of Science
Donkor, Ben N. "Stem wood structure of four Ghanaian Khaya species." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0004/MQ33365.pdf.
Full textDoroudiani, Saeed. "Microcellular wood-fibre thermoplastic composites, processing-structure-properties." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq41016.pdf.
Full textHsu, Ching Yi. "Radiata pine wood anatomy structure and biophysical properties." Thesis, University of Canterbury. Forestry, 2003. http://hdl.handle.net/10092/7202.
Full textJoffre, Thomas. "Structure and Mechanical Behaviour of Wood-Fibre Composites." Doctoral thesis, Uppsala universitet, Tillämpad mekanik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-229290.
Full textOwens, Elis M. "Fungal community structure and functioning in decomposing wood." Thesis, Cardiff University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375959.
Full textFeeney, F. "Ultrasonic characterisation of the structure and properties of wood." Thesis, University of Surrey, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300305.
Full textShi, Jingbo. "Water sorption hysteresis and wood cell wall nanopore structure." Thesis, University of British Columbia, 2017. http://hdl.handle.net/2429/61782.
Full textForestry, Faculty of
Wood Science, Department of
Graduate
Uhlin, Karen Ingegerd. "The influence of hemicelluloses on the structure of bacterial cellulose." Diss., Available online, Georgia Institute of Technology, 1990:, 1990. http://etd.gatech.edu/theses/available/ipstetd-11/uhlin%5Fki.pdf.
Full textRotsaert, Frederik A. J. "Structure-function studies on the flavocytochrome cellobiose dehydrogenase from phanerochaete chrysosporium /." Full text open access at:, 2003. http://content.ohsu.edu/u?/etd,18.
Full textNordin, Lars-Olof. "Wood fiber composites : from processing and structure to mechanical performance." Doctoral thesis, Luleå : Univ, 2004. http://epubl.ltu.se/1402-1544/2004/09/.
Full textHibberd, Martin Sidney. "The technology and structure of the British wood furniture industry." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323015.
Full textSaumure, Raymond A. "Growth, mutilation, and age structure of two populations of wood turtles, Clemmys insculpta, in southern Québec." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq29779.pdf.
Full textHowell, Caitlin L. "Understanding Wood Biodegradation through the Characterization of Crystalline Cellulose Nanostructures." Fogler Library, University of Maine, 2008. http://www.library.umaine.edu/theses/pdf/HowellCL2008.pdf.
Full textAshaari, Zaidon. "The structure and properties of rattan in relation to treatment with boron preservatives." Thesis, University of Aberdeen, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282681.
Full textGriffith, G. S. "Fungal community structure and development in attached angiosperm twigs." Thesis, Cardiff University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305126.
Full textZhou, Yonghui. "Interface optimisation and bonding mechanism of rubber-wood-plastic composites." Thesis, Brunel University, 2018. http://bura.brunel.ac.uk/handle/2438/16095.
Full textTank, Jennifer Leah. "Microbial activity on wood in streams : exploring abiotic and biotic factors affecting the structure and function of wood biofilms /." Diss., This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-06062008-144954/.
Full textVisscher, George E. "Wood Anatomy of Metasequoia - Separation from Glyptostrobus and Function/Structure Considerations." Fogler Library, University of Maine, 2002. http://www.library.umaine.edu/theses/pdf/VisscherGH2002.pdf.
Full textFigueroa, Michael. "Dynamic Analysis of a Light Wood-Framed Structure during Fire Conditions." Digital WPI, 2016. https://digitalcommons.wpi.edu/etd-theses/777.
Full textHenman, G. S. "'Shake' defects and wood structure variations in British oaks (Quercus spp.)." Thesis, Bangor University, 1991. https://research.bangor.ac.uk/portal/en/theses/shake-defects-and-wood-structure-variations-in-british-oaks-quercus-spp(124e6162-d6f4-4e61-a985-ad5e4edef257).html.
Full textMandlekar, Neeraj Kumar. "Integration of wood waste to develop multifunctional fully biobased textile structure." Thesis, Lille 1, 2019. http://www.theses.fr/2019LIL1I062/document.
Full textIt has been chosen to study valorization of low-cost industrial lignin as additive in designing the flame retardant (FR) system for polyamide 11 (PA) to develop biobased textile structure. The main focus of this thesis work is to consider lignin as carbon source and introduce in a textile structure in combination with phosphinate salt (FR agent). In the primary study, chemically different industrial lignins were incorporated in PA by extrusion to investigate the charring and fire retardant behaviour of the prepared binary blends. In addition, the introduction of sulphonated lignins significantly reduced the peak of the heat release rate (PHRR) and of the total heat release (THR), and a noticeable increase of the char residue was observed after forced combustion test. In the next approach, lignin was exploited as carbon source in combination with commercially available phosphinate FR (i.e., ZnP and AlP). To achieve this objective, a preliminary study carried out with laboratory grade lignin (LS) combined with ZnP to investigate the thermal stability and fire performance as well as the possible synergy between lignin and ZnP and with the polymer matrix. The results obtained in this study permitted to continue further, the practical implementation of lignin and multifilament production. In the next step, flame retarded blends were developed with direct addition of low-cost industrial lignins (LL and DL) with phosphinate FR. For the systematic understanding, various FR formulations were developed by varying the lignin and FR loading and characterized. Thermal decomposition analysis showed that the presence of lignin decreases the initial decomposition temperature (T5%) due to the decomposition of lignin which starts at a lower temperature region with the evolution of less thermally stable compounds and the maximum decomposition temperature (Tmax) shifts to higher temperature region, at this stage the formation of phenolic, carbonyls, hydrocarbons and CO2 along with phosphinate compounds occurs. Meanwhile, in the condensed phase thermally stable aromatic charred layer is formed because of lignin decomposition and phosphate compounds formation due to the presence of phosphinate metal salt. A higher amount of char residue is obtained when LL combined with ZnP/AlP as compared to the DL and ZnP/AlP blends. It is assumed that, during decomposition of LL, the sulfonate compounds release SO2 and transformed into thermally stable Na2SO4, hence giving rise to the stable char residue. The fire properties were assessed by cone calorimeter tests revealed the combination of lignin and phosphinate FR significantly reduced the PHRR and other fire-related parameters due to the formation of a protective char layer. The presence of lignin not only improve fire retardancy but also reduced the evolution of carbon monoxide (CO). More enhanced fire retardant properties were obtained with LL and ZnP/AlP combination reaches to 10 wt% in ternary blends, which not only promotes char formation but also confer the stability to char in the condensed phase. Furthermore, the most enhanced forced combustion results were obtained with LL and AlP (in particular, PA80-LL10-AlP10). Multifilament yarns were successfully produced for PA-DL-ZnP and PA-LL-ZnP combinations. However, the blends of AlP with lignin were not spinnable because of low compatibility and dispersion level of AlP in the polymer. Optical microscopy and tensile tests were performed to study the physical properties of multifilaments. A double layer (interlock structure) knitted fabrics were developed to evaluate fire behaviour analysis on fabric samples
Gu, Hongmei. "Structure Based, Two-dimensional, Anisotropic, Transient Heat Conduction model for Wood." Diss., Virginia Tech, 2001. http://hdl.handle.net/10919/28938.
Full textPh. D.
Maryoko, Hadi. "Earthquake Resisting Timber Structure System Composed of Indonesian Engineered Wood Products." Kyoto University, 2013. http://hdl.handle.net/2433/175087.
Full textLi, Ruonan. "Surface properties and pore structure of superheated steam dried paper." Thesis, McGill University, 1993. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=55414.
Full textTMP paper dried in superheated steam has a slightly higher surface roughness, by about 0.5 $ mu$m at a roughness around 8 $ mu$m. This difference decreases with drying fluid temperature. It is also reduced by about half after a very light blade coating. Surface roughness of paper from 50/50 TMP/kraft blend is unaffected.
Superheated steam drying reduces substantially the linting propensity of TMP paper, by about 30%-60% depending on the criteria used. Improved lignin softening by higher web temperature from the beginning of drying in superheated steam drying is believed an important mechanism in improving bonding of surface fines and short fibre fragments.
The Z-direction bond strength of TMP paper after surface treatment with water is about 20% higher for sheets dried in steam. Time for water absorption is 100%-150% longer for superheated steam dried TMP paper and contact angle of water is also substantially increased.
Superheated steam drying substantially reduces the volume of micropores of diameter 0.2-0.6 $ mu$m while having no significant effect on larger pores. Thus superheated steam drying affects only the pore structure of the micronetwork. The decrease of micropore volume in superheated steam drying is associated with an increase of Z-direction bond strength and a decrease of light scattering coefficient.
Tsai, K. T. "An investigation into the fatigue behaviour of wood : Laminates for Wind Energy Converter blade design." Thesis, University of Bath, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.379572.
Full textDu, Han. "An Extension to Östasiatiska museet ----- transforming from traditional Asian wood structure language." Thesis, KTH, Arkitektur, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-241458.
Full textLi, Guizhen. "Wood structure and properties of clonal plantlets and seedlings of Pinus radiata." Thesis, University of Canterbury. Plant and Microbial Sciences, 2000. http://hdl.handle.net/10092/5927.
Full textGonzalez, Rubio Hector Larsen David R. "Stand structure development effects on wood quality of Melina (Gmelina arborea roxb.)." Diss., Columbia, Mo. : University of Missouri--Columbia, 2009. http://hdl.handle.net/10355/6171.
Full textForbes, Craig L. "Competitive strategy and structure in the United States wood household furniture industry." Diss., This resource online, 1995. http://scholar.lib.vt.edu/theses/available/etd-02052007-081246/.
Full textJackson, Asti Joy. "Structure of Sound." Thesis, Virginia Tech, 2016. http://hdl.handle.net/10919/73778.
Full textMaster of Architecture
Beatini, Salvatore J. "Using DNA fingerprinting to assess genetic structure of the vernal pool amphibian rana sylvatica." Link to electronic thesis, 2003. http://www.wpi.edu/Pubs/ETD/Available/etd-0428103-153026.
Full textKeywords: wood frog; vernal pool conservation; fragmented habitat; Rana sylvatica; DNA fingerprinting. Includes bibliographical references (p. 38-40).
Burgers, Agnès. "Caractérisations physico-mécaniques de bois "sans défauts" pour la conception mécanique : application aux pins de la région méditerranéenne française." Thesis, Montpellier, 2016. http://www.theses.fr/2016MONTS014/document.
Full textUsing wood for mechanical engineering as solid wood or glued solid timber (or glued laminated timber) requires a good knowledge of the properties of each elementary piece. Due to this lack of knowledge, woods are still not used in modern mechanical design.In the Languedoc-Roussillon French region, pines are the dominant forest resource (approx. 30 % of standing wood). The development of this resource is a major interest for the inter-branch organisation. The aim of this PhD work is to examine the possibility to predict basic useful properties of pine clear wood, based on available non-destructive methods. The study has been made on four of the most present species: Laricio black pine, Maritime pine, Mountain pine and Scots pine.Basic relevant indicators are the density (obtained by mass and volume measurements), the specific modulus of elasticity (obtained by vibrational measurements) and indicators from Near Infrared Resonance Spectroscopy (NIRS). Technological properties are the nine components of the elastic matrix (obtained by resonant ultrasonic measurements on a single specimen), hygroscopic dilatations and compressive breaking strength along the fibres (obtained in standard testing conditions).Data analysis allows to build some predictive models, unique for the whole pine selection, of basic properties, from indicators measured on each specimen of clear wood.Therefore it is possible to associate to a given piece of wood, a technical specification sheet of useful properties for mechanical design. Selected indicators are common measurements in industry and knowledge transfer is conceivable. Each interesting piece of wood (i.e. with few defects) could be rapidly characterized. Related to a good traceability this process could lead to identify clearly each piece and its properties, giving the possibility to the designer to select the best materials to his or her needs
Ljungdahl, Jonas. "Structure and properties of Vasa oak." Licentiate thesis, Stockholm : Royal Institute of Technology, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4016.
Full textFilchev, Ivan. "Buckling and geometric nonlinear FE analysis of pitched large-spanroof structure of wood." Thesis, Linnéuniversitetet, Institutionen för byggteknik (BY), 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-54324.
Full textSchreiner, Linda [Verfasser]. "Characterization of conifer wood regarding its odor-active constituents, their structure-odor relationships, and the influence of wood odors on humans / Linda Schreiner." München : Verlag Dr. Hut, 2020. http://d-nb.info/1220568031/34.
Full textAebischer, Danille P. "Basic density and shrinkage of oak in relation to wood structure and cambial age." Thesis, Bangor University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285465.
Full textEriksson, Daniel. "Wood - an anatomical structure in the tree and an engineering material in industry : prediction of material properties in managed Scots pine stands in the forest /." Umeå : Dept. of Forest Ecology and Management, Swedish University of Agricultural Sciences, 2008. http://epsilon.slu.se/200873.pdf.
Full textBahrani, Babak. "Effects of weathering on performance of intumescent coatings for structure fire protection in the wildland-urban interface." Thesis, The University of North Carolina at Charlotte, 2015. http://pqdtopen.proquest.com/#viewpdf?dispub=1606131.
Full textThe objective of this study was to investigate the effects of weathering on the performance of intumescent fire-retardant coatings on wooden products. The weathering effects included primary (solar irradiation, moisture, and temperature) and secondary (environmental contaminants) parameters at various time intervals.
Wildland urban interface (WUI) fires have been an increasing threat to lives and properties. Existing solutions to mitigate the damages caused by WUI fires include protecting the structures from ignition and minimizing the fire spread from one structure to another. These solutions can be divided into two general categories: active fire protection systems and passive fire protection systems. Passive systems are either using pre-applied wetting agents (water, gel, or foam) or adding an extra layer (composite wraps or coatings). Fire-retardant coating treatment methods can be divided into impregnated (penetrant) and intumescent categories. Intumescent coatings are easy to apply, economical, and have a better appearance in comparison to other passive fire protection methods, and are the main focus of this study.
There have been limited studies conducted on the application of intumescent coatings on wooden structures and their performance after long-term weathering exposure. The main concerns of weathering effects are: 1) the reduction of ignition resistance of the coating layer after weathering; and 2) the fire properties of coatings after weathering since coatings might contribute as a combustible fuel and assist the fire growth after ignition.
Three intumescent coatings were selected and exposed to natural weathering conditions in three different time intervals. Two types of tests were performed on the specimens: a combustibility test consisted of a bench-scale performance evaluation using a Cone Calorimeter, and a thermal decomposition test using Simultaneous Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) method (also known as SDT). For each coating type and weathering period, three different radiative heat flux levels were used in the combustibility tests. Data obtained from the tests, including flammability and thermal properties, were gathered, analyzed, and compared to non-weathered specimens.
The results revealed visible effects of weathering on pre (and up to)-ignition flammability and intumescent properties, especially decreases in Time-to-Ignition (TTI), Time-to-Intumescence (tintu.), and (maximum) Intumescence Height (Hintu.) values in weathered specimens. These results showed that the ignition resistance of the coating layers decreased after weathering exposure. On the other hand, the obtained results from weathered specimens for the post-ignition flammability properties, especially Peak Heat Release Rate (PHRR) and Effective Heat of Combustion (EHC) did not show a significant difference in comparison to the non-weathered samples. These results demonstrated that the weathered coating layer would not likely to act as an additional combustible fuel to increase fire spread.
Zafra-Camón, Guillermo. "Calculation of global properties of a multi-layered solid wood structure using Finite Element Analysis." Thesis, Uppsala universitet, Tillämpad mekanik, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-298677.
Full textJonsson, Christian. "Detection of annual rings in wood." Thesis, Linköping University, Department of Science and Technology, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-15804.
Full textThis report describes an annual line detection algorithm for the WoodEye quality control system. The goal with the algorithm is to find the positions of annual lines on the four surfaces of a board. The purpose is to use this result to find the inner annual ring structure of the board. The work was done using image processing techniques to analyze images collected with WoodEye. The report gives the reader an insight in the requirements of quality control systems in the woodworking industry and the benefits of automated quality control versus manual inspection. The appearance and formation of annual lines are explained on a detailed level to provide insight on how the problem should be approached. A comparison between annual rings and fingerprints are made to see if ideas from this area of pattern recognition can be adapted to annual line detection. This comparison together with a study of existing methods led to the implementation of a fingerprint enhancement method. This method became a central part of the annual line detection algorithm. The annual line detection algorithm consists of two main steps; enhancing the edges of the annual rings, and tracking along the edges to form lines. Different solutions for components of the algorithm were tested to compare performance. The final algorithm was tested with different input images to find if the annual line detection algorithm works best with images from a grayscale or an RGB camera.
Osei, Nana Akwasi. "Large wood in fluvial systems : quantity, structure and landforms, sediment retention, and riparian seed bank development." Thesis, Queen Mary, University of London, 2014. http://qmro.qmul.ac.uk/xmlui/handle/123456789/8813.
Full textGirardon, Stéphane. "Amélioration des performances mécaniques des assemblages bois sur bois vissés par préparation des interfaces : application à la réalisation d'éléments de structure." Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0188/document.
Full textPlank bonding connection is used to produce efficient structural timber. The bonding achieves excellent rigidity and connection resistance. However, these products are often pollutants and are incompatible with industrial production rates due to the pressing time. Their performances collapse when the adhesive connection is replaced by rodlike fasteners, such as nails, screws or wooden dowels, but these connections allow a quick assembly. In these assemblies the contact surfaces between planks are not used for transmitting loads. The purpose of this study is to point out how mechanical preparation of the interfaces improves the performance of timber connections. The aim is to produce structural members without volatile organic compounds (VOC), achievable by an industrial robot allowing for flexibility, and using mixed wood local species. The first part of this study consists in identifying and analyzing reconstituted wood systems, as well as showing how to conduct a design by taking into account the partial composite action of connectors. This part explains that the chosen behavior of the mechanical connections in reconstituted systems is frequently very imprecise and leads to significant differences in design. The second part describes a methodology to overcome this lack, developed from the nonlinear modeling of a beamtype component. This approach leads to determine the fastener's secant stiffness for an exact linear calculation for engineers. The outcome of this methodology is the quantification of the fastener's secant stiffness by a related behavior rather than a general normative behavior. Due to the flexibility of members, a third part presents a reflection on the use of the contact surfaces for transmitting loads. The plank interfaces were machined in order to obtain grooves. This binding allows the transmission of shear and torsion forces in the intersection plane of the planks. Maintaining the contact is managed by the development of a wooden conical screw. To validate these principles, test campaigns were carried out to measure the performance of the groove, the wooden conical screw and their simultaneous use. The last section deals with the implementation of the improved assembly in structural members in order to confirm its potential. The first element type is a castellated beams and the second one is a bracing wall. Experimental results are compared with numerical models including the nonlinear grooved screwed connection behavior. Furthermore, these full scale elements validate the feasibility by an industrial robot
Chowdhury, Sudip. "Advancing characterization techniques for structure-property determination of in-situ lignocelluloses." Diss., Virginia Tech, 2011. http://hdl.handle.net/10919/39189.
Full textPh. D.
Lin, Wing Shan Linda. "Effect of moisture and other volatiles on the cellular structure of plastic/wood-fiber composite foams." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/MQ63121.pdf.
Full textNord, Tomas. "Structure and developments in the solid wood value chain : dominant saw milling strategies and industrialized housing." Licentiate thesis, Luleå, 2005. http://epubl.luth.se/1402-1757/2005/57.
Full textHult, Eva-Lena. "CP/MAS ¹³C-NMR spectroscopy applied to structure and interaction studies on wood and pulp fibers /." Stockholm, 2001. http://media.lib.kth.se:8080/kthdisseng.html.
Full textOchieng, Judith Auma. "The role of disturbances in mangrove wood formation and forest structure: Effect of large sedimentation events." Doctoral thesis, Universite Libre de Bruxelles, 2016. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/232475.
Full textDoctorat en Sciences
Author's maiden name: Judith Auma OKELLO
Due to a technical Di-Fusion bug it was not possible to input the correct date of the defense. The correct date is Thursday 30 June 2016.
info:eu-repo/semantics/nonPublished
Macias, Diego. "Topological (Bio)Timber: An Algorithm and Data Approach to 3d Printing a Bioplastic and Wood Architecture." University of Cincinnati / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1491305462260965.
Full textForsström, Jennie. "Fundamental Aspects on the Re-use of Wood Based Fibres : Porous Structure of Fibres and Ink Detachment." Doctoral thesis, KTH, Fibre and Polymer Technology, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-84.
Full textIn this work, different aspects on the re-use of wood based fibres have been studied, focusing on ink detachment of flexographic ink from model cellulose surfaces and changes in porous structure of kraft fibres following different treatments. New model systems for evaluation of ink detachment and ink-cellulose interactions were used. Ink detachment was studied using Impinging jet cell equipment, taking into consideration the influence of storage conditions, surface roughness and surface energy of the cellulose substrate. A micro adhesion measurement apparatus (MAMA) was used to directly study ink-cellulose interactions, from which the adhesive properties between ink and cellulose, having various surface energies, could be derived. UV-light, elevated temperatures, longer storage time, decreased surface energy, i.e. making the cellulose surface more hydrophobic, and high surface roughness all negatively affected ink detachment. Attenuated total reflectance - fourier transform infra red (ATR-FTIR) and atomic force microscopy (AFM) was used to evaluate structural and chemical changes of ink and cellulose upon storage at elevated temperature or under UV-light. After storage at elevated temperatures, ATR-FTIR spectra indicated that a hydrolysis or an oxidative reaction took place as a peak at 1710 cm-1 appeared. AFM revealed that storage at elevated temperatures caused the latex particles present in the ink to form a film, most likely due to annealing. Less ink detached from hydrophobic cellulose surfaces. Ink detachment decreased for rougher cellulose substrates due to an increased molecular contact area.
Fibre pore structure and water retaining ability influenced fibre/fibre joint strength and different paper strength properties. Investigations took into account the effect of pulp yield, counter-ion types, pH, salt, hornification and strength enhancing additives. Nuclear magnetic resonance relaxation (NMR), inverse size exclusion chromatography (ISEC) and water retention value (WRV) measured the changes that occur in the fibre wall upon varying the conditions. Each different measuring technique contained unique information such that a combination of the techniques was necessary to give as complete a picture as possible over the changes that occurred in the fibre wall upon varying the conditions for the fibre. A correlation between fibre pore radius and sheet strength properties was found, suggesting that fibres with larger pores allow for a larger molecular contact area between fibres to be formed during drying and consolidation of the paper. Fibre/fibre joint strength, fibre flexibility, and the number of efficient fibre/fibre contacts also controlled sheet strength. The effect of different strength enhancing additives on fibre pore structure and paper strength was investigated. Larger pores in the fibres allowed for additives to penetrate into the fibre wall. Additives with low molecular mass (Mw) penetrated into the fibre wall to a larger extent than additives with a high Mw, causing an embrittlement of the fibre. However, low Mw additives gave higher sheet tensile strength despite a leveling out in strength at high additions, indicating that the fibre wall can only adsorb a limited amount of chemical. Polyallylamine hydrochloride (PAH) and polyelectrolyte complexes (PEC) of PAH and polyacrylic acid (PAA) were added separately to the pulp. PEC significantly improved both tensile strength and Z-strength, whereas PAH alone did not increase the strength properties to the same extent unless the sheets were heated to 150°C for 10 minutes. The results suggested that the effect of PEC was dominated by an improvement in fibre/fibre joint strength, whereas the effect of PAH was significantly affected by an improvement of the intra-fibre bond strength