Academic literature on the topic 'Variably-enriched tholeiitic N- to E-MORB compositions'

AbstractThe incomplete Evros ophiolites in NE Greece form a NE–SW-oriented discontinuous belt in the Alpine orogen of the north Aegean. Field data, petrology and geochemistry are presented here for the intrusive section and associated mafic dykes of these ophiolites. Bodies of high-level isotropic gabbro and plagiogranite in the ophiolite suite are cross-cut by NE–SW-trending boninitic and tholeiitic–boninitic affinity dykes, respectively. The dykes fill tensile fractures or faults, which implies dyke emplacement in an extensional tectonic regime. The tholeiitic–transitional boninitic gabbro is REE- and HFS-depleted relative to N-MORB, indicating derivation from melting of a refractory mantle peridotite source. Associated boninitic dykes are slightly LREE-enriched, showing mineral and whole-rock geochemistry similar to the gabbro. The plagiogranite is a strongly REE-enriched high-silica trondhjemite, with textures and composition typical for an oceanic crust differentiate. Plagiogranite-hosted tholeiitic and transitional boninitic dykes are variably REE-enriched. Geochemical modelling indicates origin of the plagiogranite by up to 75 % fractional crystallization of basaltic magma similar to that producing the associated tholeiitic dykes. All mafic rocks have high LILE/HFSE ratios and negative Ta–Nb–Ti and Ce anomalies, typical for subduction zone-related settings. The mafic rocks show a similar trace-element character to the mafic lavas of an extrusive section in Bulgaria, suggesting they both form genetically related intrusive and extrusive suites of the Evros ophiolites. The field occurrence, the structural context, the petrology and geochemical signature of the studied magmatic assemblage provide evidence for its origin in a proto-arc (fore-arc) tectonic setting, thus tracing the early stages of the tectono-magmatic evolution of Jurassic arc-marginal basin system that has generated the supra-subduction type Evros ophiolites.

AbstractThe Proterozoic Chotanagpur Granite Gneiss Complex (CGGC) at the northern boundary of the Central Indian Tectonic Zone (CITZ) of the eastern Indian shield preserves relics of fossilized oceanic back-arc crust. We describe the field, petrographical and geochemical characteristics of the mafic rocks comprising pillow basalts and dolerites from the Bathani area of the northern fringe of the CGGC, eastern India. The basalts consist of plagioclase feldspar, hornblende, opaque minerals (Fe–Ti oxide) and chlorite, and the dolerite consists of plagioclase, hornblende and opaque minerals. Our data indicate that the Bathani mafic rocks have tholeiitic to transitional composition and are overprinted by greenschist facies metamorphic conditions; however, REE and fluid immobile elements preserve their primary geochemical signatures. The (La/Sm)N ratios (1.38–2.15) and chondrite-normalized REE patterns point to an enriched mid-ocean ridge basalt (E-MORB) mantle source. Geochemical characteristics indicate a mixed signature of MORB and arc tholeiite with enrichment of Ba, Th, Eu and Sr, similar to that of back-arc supra-subduction zone ophiolites. These mafic rocks are the product of MORB-like magma derived from a depleted mantle corresponding to < 2% partial melting of spinel lherzolite, enriched by subduction-induced slab metasomatism and melting. The Bathani mafic rocks are representative of the upper part of a supra-subduction zone columnar ophiolite section, which was emplaced onto the present-day northern margin of the CGGC during suturing of the northern and southern Indian block at c. 1.9 Ga during the Nuna amalgamation.

Shikoku Basin is unique as being located within a trench-ridge-trench triple junction. Here, we report mineral compositions, major, trace-element, and Sr-Nd-Pb isotopic compositions of bulk-rocks from Sites C0012 (>18.9 Ma) and 1173 (13–15 Ma) of the Shikoku Basin. Samples from Sites C0012 and 1173 are tholeiitic in composition and display relative depletion in light rare earth elements (REEs) and enrichment in heavy REEs, generally similar to normal mid-ocean ridge basalts (N-MORB). Specifically, Site C0012 samples display more pronounced positive anomalies in Rb, Ba, K, Pb and Sr, and negative anomalies in Th, U, Nb, and Ta, as well as negative Nb relative to La and Th. Site 1173 basalts have relatively uniform Sr-Nd-Pb isotopic compositions, close to the end member of depleted mantle, while Site C0012 samples show slightly enriched Sr-Nd-Pb isotopic signature, indicating a possible involvement of enriched mantle 1 (EM1) and EM2 sources, which could be attributed to the metasomatism of the fluids released from the dehydrated subduction slab, but with the little involvement of subducted slab-derived sedimentary component. Additionally, the Shikoku Basin record the formation of the back-arc basin was a mantle conversion process from an island arc to a typical MORB. The formation of the Shikoku Basin is different from that of the adjacent Japan Sea and Parece Vela Basin, mainly in terms of the metasomatized subduction-related components, the nature of mantle source, and partial melting processes.

The paper presents the very first data on concentrations of major and trace elements; Sr, Nd, and Pb isotopic ratios of rocks; and the composition of olivine phenocrysts of 38-Ma basalts recovered by Hole 513a (DSDP Leg 71) in the South Atlantic. The bulk-rock samples and the chilled glasses are mildly magnesian (7–8 wt % MgO) and bear elevated FeO and low Na2O concentrations, as is typical of MORB of the TOR-1 type. Olivine phenocrysts (Fo84.5–88) in these rocks contain concentrations of trace elements (Ni, Mn, Cr, and Zn) that are typical of classic MORB, which are produced by partial melting mantle peridotite. The rocks are strongly depleted in incompatible elements [(La/Sm)n ~ 0.6] but have elevated Ba/Nb, K/Nb, and Pb/Ce ratios and Cu, Ag, and Au concentrations that are 1.5–4 times higher than in typical depleted MORB (N-MORB) and in most rift basalts in the South Atlantic. Isotope compositions of the basalts (average ratios 206Pb/204Pb ~ 18.0; 207Pb/204Pb ~ 15.6, 208Pb/204Pb ~ 38.0, 143Nd/144 Nd ~ 0.5130, and 87Sr/86Sr ~ 0.7040) are close to those in modern tholeiites from the southern MAR segment (SMAR) north of the Agulhas Fracture Zone. The data indicate that the magmas were derived from a strongly depleted mantle source that contained a minor (~3%) admixture of an enriched component, which is discernible in the magmas of the Discovery hotspot. The composition of the source, which is more depleted than DM, and the high degrees of melting of this source explain why the basalts from DSDP Hole 513a are enriched in chalcophile elements. It is believed that spreading magmatism at 45°–48° S in SMAR as far back as 40 Ma was already affected by the Discovery hotspot. This hotspot might be related to the Tristan plume system, and its origin and long-lasting influence on spreading magmatism in the South Atlantic are regarded as evidence of the extensive effect of the Tristan plume.

The South Mid-Atlantic Ridge is a typical slow-spreading ridge that represents a modern example to understand mantle composition and the evolution of mid-ocean ridge magmatism. In this paper, we investigate basalt samples dredged from four locations along the South Mid-Atlantic Ridge ranging from 18.0° to 20.6°S. The basalts belong to the tholeiitic series and exhibit normal mid-ocean ridge basalt (N-MORB) geochemical features with variable enrichments of Rb, Th, U, and Pb and depletions of Ba and Sr relative to primitive mantle. Some samples have negative Nb–Ta anomalies whereas others have positive Na–Ta anomalies to average N-MORBs. Plagioclase phenocrysts, microphenocrysts, and microlites occur in the in the matrix; phenocrysts and microphenocrysts are bytownite and labradorite in composition. Olivine phenocrysts are forsterite (Fo87 to Fo96). Chemical zoning in phenocrysts are interpreted to record crystal fractionation and magma mixing. Cores of plagioclase phenocrysts have higher anorthite values (An72–83) and estimated crystallization temperatures (~1180–1240 °C) that may suggest a xenocrystic origin. The lower anorthite proportions of rims of plagioclase phenocrysts (An65–71) and microphenocrysts (An54–72) yield lower estimated crystallization temperatures of ~1090–1120 °C and ~980–1060 °C, respectively. Rims of plagioclase phenocrysts and microphenocrysts may be generated in different environments such as magma chambers or magma channels, respectively. The basalt samples probably originated from partial melting of a depleted mantle spinel lherzolite source with a minor contribution of enriched materials possibly derived from the Saint Helena plume and subcontinental lithospheric mantle in the asthenosphere. Variable compositions of the basalt samples suggest heterogeneous mantle that includes depleted and enriched components at the South Mid-Atlantic Ridge between 18.0°–20.6°S.

Study of petrological and geochemical characteristics of mantle peridotite xenoliths in Pliocene alkaline basalt in Nghia Dan (West Nghe An) was carried out. Rock-forming clinopyroxenes, the major trace element containers, were separated from the xenoliths to analyze for major, trace element and Sr-Nd isotopic compositions. The data were interpreted for source geochemical characteristics and geodynamic processes of the lithospheric mantle beneath the region. The peridotite xenoliths being mostly spinel-lherzolites in composition, are residual entities having been produced following partial melting events of ultramafic rocks in the asthenosphere. They are depleted in trace element abundance and Sr-Nd isotopic composition. Some are even more depleted as compared to mid-ocean ridge mantle xenoliths. Modelled calculation based on trace element abundances and their corresponding solid/liquid distribution coefficients showed that the Nghia Dan mantle xenoliths may be produced of melting degrees from 8 to 12%. Applying various methods for two-pyroxene temperature- pressure estimates, the Nghia Dan mantle xenoliths show ranges of crystallization temperature and pressure, respectively, of 1010-1044°C and 13-14.2 kbar, roughly about 43km. A geotherm constructed for the mantle xenoliths showed a higher geothermal gradient as compared to that of in the western Highlands (Vietnam) and a conductive model, implying a thermal perturbation under the region. The calculated Sm-Nd model ages for the clinopyroxenes yielded 127 and 122 Ma. 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AbstractThe Late Triassic to Late Cretaceous age mafic lavas from the Neotethyan suture zone ophiolites in western Turkey exhibit a wide diversity of geochemical signatures, indicating derivation from extremely heterogeneous mantle sources. The rocks as a whole can be divided into three broad subdivisions based on their bulk-rock geochemical characteristics: (1) mid-ocean ridge basalts (MORB) that range in composition from light rare earth element (LREE)-depleted varieties (N-MORB; (La/Sm)N<1) through transitional MORB to LREE enriched types (E-MORB; (La/Sm)N>1); (2) the ocean island basalt (OIB)-type alkaline volcanic rocks with significant enrichment in LILE, HFSE and L-MREE, and a slight depletion in HREE, relative to normal mid-ocean ridge basalts (N-MORB); and (3) the supra-subduction zone (SSZ)-type tholeiites originated from arc mantle sources that are characterized by selective enrichments in fluid-soluble large ion lithophile elements (LILE) and LREE relative to the high field strength elements (HFSE). The formation of MORB tholeiites with variable enrichments and depletions in incompatible trace elements is probably related to the processes of crust generation along an oceanic spreading system, and the observed MORB–OIB associations can be modelled by heterogeneous source contribution and mixing of melts from chemically discrete sources from sub-lithospheric reservoirs. Evaluation of trace element systematics shows that the inferred heterogeneities within the mantle source regions are likely to have originated from continuous processes of formation and destruction of enriched mantle domains by long-term plate recycling, convective mixing and melt extraction. The origin of SSZ-type tholeiites with back-arc basin affinities, on the other hand, can be attributed to the later intra-oceanic subduction and plate convergence which led to the generation of supra-subduction-type oceanic crust as a consequence of imparting a certain extent of subduction component into the mantle melting region. Mixing of melts from a multiply depleted mantle source, which subsequently received variable re-enrichment with a subduction component, is suggested to explain the generation of supra-subduction-type oceanic crust. The geodynamic setting in which much of the SSZ-type ophiolitic extrusive rocks from western Turkey were generated can be described as an arc-basin system that is characterized by an oceanic lithosphere generation most probably associated with melting of mantle material along a supra-subduction-type spreading centre.

The early Tertiary plateau basalts in East Greenland are situated on a continental margin and were erupted during continental break-up and initiation of sea-floor spreading in the North Atlantic. In the region stretching from Scoresby Sund southward to 69°N 40 000 km2of basalts with an average thickness of 1.5 km have been investigated by measuring and flow-to-flow sampling of 130 profiles, followed by major element geochemical analysis and microprobe analysis, trace element analysis and some Sr isotope data. The basalts rest on Mesozoic sediments in the east and on Precambrian gneiss in the west. Six basalt formations are defined: the Magga Dan, Milne Land and Geikie Plateau Formations form a lower regional sequence erupted in one volcanic episode from sites in the NW part of the region; the Rømer Fjord and Skrænterne Formations form an upper regional sequence erupted in a subsequent volcanic episode in which eruption sites moved SE to centres east of the present Atlantic coast; the Igtertivâ Formation and a coast-parallel dyke swarm formed in a third volcanic episode only recorded at the Atlantic coast. The lavas are essentially flat-lying; a narrow strip along the Atlantic coast is extensively block faulted. Single lava flows are extensive (max. 11 000 km2) and voluminous (max. 300 km3). They are well preserved, with metamorphism of the low zeolite facies. All the lavas and most of the dykes are fractionated tholeiitic basalts with Mg/(Mg+Fe2+) ratios of 0.66-0.39 and TiO2 = 1.2-4.5%. The major part (the 'main basalts', 96% by volume) have Mg ratios of 0.56-0.39, while only 4 vol.% are Mg-rich basalts with Mg ratios of 0.66-0.57. A nephelinitic tuff layer occurs at the base of the second sequence. A few dykes are alkaline. The Mg-rich basalts have microphenocrysts of olivine (FO90-70) and chromite, while the main basalts comprise both aphyric and porphyritic sequences. Phenocrysts of plagioclase (An88-37) are abundant, of olivine (FO80-57) are sparse but ubiquitous, and of augite (FS9-20) sparse and often absent. Groundmass phases are olivine (to FO3737), plagioclase (to An13, augite (to FS62), pigeonite (Fs26-50), titanomagnetite and ilmenite. All rocks contain several per cent fine-grained mesostasis. The phenocrysts frequently show disequilibrium textures and a wide range of compositions within one sample. Extrusion temperatures are calculated to 1280-1110°C, and densities to 2.68-2.78 g/cm3, increasing with fractionation. The volcanic episodes are demonstrated in systematic compositional variations with height in the basalt sequence. Each of the two major episodes started with a variety of lava compositions including Mg-rich basalts, followed by a thick sequence of 'main basalts' showing a systematic decrease of TiO2 and other incompatible elements with height, and ending with a reversal to higher TiO2 values. The third episode is not cyclic, and its products have changed incompatible element ratios. The Mg-rich basalts comprise depleted MORB type basalts, relatively enriched olivine tholeiites, and very enriched tholeiites (Mikis type basalt). Sr isotopes show 87Sr/86Sr ratios of 0.7034 in most basalts and 0.7045 in the Mikis type basalt, while some Si-rich basalts have ratios up to 0.7079. The East Greenland basalts are 'initial rifting' basalts very similar to those in Deccan. The magmas have equilibrated at low pressures in crustal magma chambers. The main basalts have fractionated ol + pl + cpx no matter whether they are aphyric or porphyritic. Simple crystal fractionation can account for sub-trends but not for the complete compositional variation of the main basalts. This is considered as resulting from fractionation in open magma chambers which were repeatedly filled, mixed and tapped. The decrease in TiO2 with height in each volcanic episode indicates increasing magma input rate and shorter residence time in the chamber, while the final reversal indicates the decline and cessation of activity. There is evidence for widespread crustal contamination (1-4%) in the magma chambers of the two lowest formations. Crustal contamination of magmas on the way to the surface occurred sporadically throughout both sequences. One case of magma mixing occurred when a Mg-rich basalt magma invaded the regional main basalt magma chamber. The Mg-rich basalts cannot be directly related to each other or to the main basalts. A petrogenetic scheme is suggested where the Mikis type basalt originated in, or contains an addition from, an undepleted or enriched mantle source. All the other magma types originated in a depleted mantle source by varying degrees and possibly depths of melting. Increasing degrees of melting are indicated for the types nephelinite - enriched olivine tholeiite – main basalt parent – MORB type basalt. The MORB type basalt may also be produced by melting of a residuum. The basalts of the third volcanic episode include another component of mantle or basaltic crust. The three recorded volcanic episodes are related to rifting events during the break-up of the North Atlantic continent, viewed as repeated attempts to straighten out a bend in the original line of opening. The two first rifting events failed while the third for a short while produced oceanic crust. Compared to other regions of the North Atlantic volcanic province the Scoresby Sund basalts are similar to basalts from Kangerdlugssuaq, northern East Greenland, West Greenland, the Faeroes, the Vøring Plateau and some basalts on lceland. The main magma source for the North Atlantic province was similar to that of the lceland hotspot, but enriched subcontinental lithosphere may also have participated in the stage of initial rifting. A correlation for the volcanic episodes throughout East Greenland and the Faeroes is proposed.

Geochemistry, petrology and tectonomagmatic significance of basaltic rocks from the ophiolite mélange at the NW External-Internal Dinarides junction (Croatia)At the NW inflexion of the Sava-Vardar Suture Zone ophiolite mélanges, known as the Kalnik Unit, form the surface of the slopes of several Pannonian inselbergs in the SW Zagorje-Mid-Transdanubian Zone. The Mt Samoborska Gora ophiolite mélange, thought to be a part of the Kalnik Unit, forms a separate sector obducted directly onto Dinaric Triassic carbonate sediments. Basaltic rocks, the only magmatic rocks incorporated in the mélange, include Middle-Triassic (Illyrian-Fassanian) alkali within-plate basalts and Middle Jurassic (uppermost Bathonian-Lower Callovian) tholeiitic basalts. The latter sporadically constitute composite olistoliths, and are geochemically divided into N-MORB-like (high-Ti basalts) and transitional MORB/IAT (medium-Ti basalts). These geochemically different rocks suggest crystallization at various tectonomagmatic settings, which is also indicated by the rock paragenesis and host clinopyroxene compositions. Alkali basalts reflect melts derived from an OIB-type enriched mantle source [Ti/V= 62.2-82.4; (La/Lu)cn= 6.4-12.8] with Nd-Sr isotope signatures close resembling the Bulk Earth [εNd(T=235 Ma)= + 1.6 to + 2.5]. They are recognized as preophiolite continental rift basin volcanic rocks that closely predate the opening of the Repno oceanic domain (ROD) of the Meliata-Maliac ocean system. The high-Ti and medium-Ti basalts from composite blocks derived from a similar depleted mantle source (εNd(T=165 Ma) = + 6.01 vs. + 6.35) succesively metasomatized by expulsion of fluids from a subducting slab leading to a more pronounced subduction signature in the latter [Ti/V=31.6-44.8 and (Nb/La)n=0.67-0.90 vs. Ti/V=21.5-33.9 and (Nb/La)n=0.32-0.49]. These composite blocks indicate crust formation in an extensional basin spreading over the still active subducting ridge. The majority of high-Ti basalts may represent the fragments of older crust formed at a spreading ridge and incorporated in the mélange of the accretionary wedge formed in the proto-arc-fore-arc region. The Mt Samoborska Gora ophiolite mélange represents the trailing edge of the Kalnik Unit as a discrete sector that records the shortest stage of tectonomagmatic evolution related to intraoceanic subduction in the ROD.

Abstract Where and how arc magmas are generated and differentiated are still debated and these questions are investigated in the context of part of the Andean arc (Chilean Southern Volcanic Zone) where the continental crust is thin. Results are presented for the La Picada stratovolcano (41°S) that belongs to the Central Southern Volcanic Zone (CSVZ) (38°S–41·5°S, Chile) which results from the subduction of the Nazca plate beneath the western margin of the South American continent. Forty-seven representative samples collected from different units of the volcano define a differentiation trend from basalt to basaltic andesite and dacite (50·9 to 65·6 wt % SiO2). This trend straddles the tholeiitic and calc-alkaline fields and displays a conspicuous compositional Daly Gap between 57·0 and 62·7 wt % SiO2. Interstitial, mostly dacitic, glass pockets extend the trend to 76·0 wt % SiO2. Mineral compositions and geochemical data indicate that differentiation from the basaltic parent magmas to the dacites occurred in the upper crust (∼0·2 GPa) with no sign of an intermediate fractionation stage in the lower crust. However, we have currently no precise constraint on the depth of differentiation from the primary magmas to the basaltic parent magmas. Stalling of the basaltic parent magmas in the upper crust could have been controlled by the occurrence of a major crustal discontinuity, by vapor saturation that induced volatile exsolution resulting in an increase of melt viscosity, or by both processes acting concomitantly. The observed Daly Gap thus results from upper crustal magmatic processes. Samples from both sides of the Daly Gap show contrasting textures: basalts and basaltic andesites, found as lavas, are rich in macrocrysts, whereas dacites, only observed in crosscutting dykes, are very poor in macrocrysts. Moreover, modelling of the fractional crystallization process indicates a total fractionation of 43% to reach the most evolved basaltic andesites. The Daly Gap is thus interpreted as resulting from critical crystallinity that was reached in the basaltic andesites within the main storage region, precluding eruption of more evolved lavas. Some interstitial dacitic melt was extracted from the crystal mush and emplaced as dykes, possibly connected to small dacitic domes, now eroded away. In addition to the overall differentiation trend, the basalts to basaltic andesites display variable MgO, Cr and Ni contents at a given SiO2. Crystal accumulation and high pressure fractionation fail to predict this geochemical variability which is interpreted as resulting from variable extents of fractional crystallization. Geothermobarometry using recalculated primary magmas indicates last equilibration at about 1·3–1·5 GPa and at a temperature higher than the anhydrous peridotite solidus, pointing to a potential role of decompression melting. However, because the basalts are enriched in slab components and H2O compared to N-MORB, wet melting is highly likely.