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Journal articles on the topic 'Unitised regenerative fuel cells'

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Author: Grafiati

Published: 4 June 2021

Last updated: 12 February 2022

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1

Altmann, Sebastian, Till Kaz, and Kaspar Andreas Friedrich. "Bifunctional electrodes for unitised regenerative fuel cells." Electrochimica Acta 56, no. 11 (April 2011): 4287–93. http://dx.doi.org/10.1016/j.electacta.2011.01.077.

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2

Chen, Jun Jie, and De Guang Xu. "Recent Development and Applications in Electrodes for URFC." International Letters of Chemistry, Physics and Astronomy 47 (February 2015): 165–77. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.47.165.

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The design of electrodes for URFC (unitised regenerative polymer electrolyte fuel cells) requires a delicate balancing of transport media. Gas transport, electrons and protons must be carefully optimised to provide efficient transport to and from the electrochemical reaction sites. This review is a survey of recent literature with the objective to identify common components and design and assembly methods for URFC electrodes, focusing primarily on the development of a better performing bifunctional electrocatalyst for the oxygen reduction and water oxidation. Advances in unitised regenerative fuel cells study have yielded better performing oxygen electrocatalysts capable of improving energy efficiency with longer endurance and less performance degradation over time. Fuel cells using these electrocatalyst have a possible future as a source of energy.

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3

Wittstadt, U., E. Wagner, and T. Jungmann. "Membrane electrode assemblies for unitised regenerative polymer electrolyte fuel cells." Journal of Power Sources 145, no. 2 (August 2005): 555–62. http://dx.doi.org/10.1016/j.jpowsour.2005.02.068.

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4

Doddathimmaiah, A., and J. Andrews. "Theory, modelling and performance measurement of unitised regenerative fuel cells." International Journal of Hydrogen Energy 34, no. 19 (October 2009): 8157–70. http://dx.doi.org/10.1016/j.ijhydene.2009.07.116.

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5

Pettersson, J., B. Ramsey, and D. J. Harrison. "Fabrication of bifunctional membrane electrode assemblies for unitised regenerative polymer electrolyte fuel cells." Electronics Letters 42, no. 25 (2006): 1444. http://dx.doi.org/10.1049/el:20062620.

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6

Pettersson, J., B. Ramsey, and D. Harrison. "A review of the latest developments in electrodes for unitised regenerative polymer electrolyte fuel cells." Journal of Power Sources 157, no. 1 (June 2006): 28–34. http://dx.doi.org/10.1016/j.jpowsour.2006.01.059.

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7

Wang, Yifei, Dennis Y. C. Leung, Jin Xuan, and Huizhi Wang. "A review on unitized regenerative fuel cell technologies, part-A: Unitized regenerative proton exchange membrane fuel cells." Renewable and Sustainable Energy Reviews 65 (November 2016): 961–77. http://dx.doi.org/10.1016/j.rser.2016.07.046.

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8

Omrani, Reza, and Bahman Shabani. "Review of gas diffusion layer for proton exchange membrane-based technologies with a focus on unitised regenerative fuel cells." International Journal of Hydrogen Energy 44, no. 7 (February 2019): 3834–60. http://dx.doi.org/10.1016/j.ijhydene.2018.12.120.

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9

Gayen, Pralay, Xinquan Liu, Cheng He, Sulay Saha, and Vijay K. Ramani. "Bidirectional energy & fuel production using RTO-supported-Pt–IrO2 loaded fixed polarity unitized regenerative fuel cells." Sustainable Energy & Fuels 5, no. 10 (2021): 2734–46. http://dx.doi.org/10.1039/d1se00103e.

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A fixed-polarity unitized regenerative fuel cell using Pt–IrO₂/RTO as a bifunctional OER- and HOR-electrocatalyst as an anode exhibits high PGM-mass-specific activity and high round-trip efficiency (40.2% at 1 A cm⁻²).

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10

Baglio, V., C. D'Urso, A. Di Blasi, R. Ornelas, L. G. Arriaga, V. Antonucci, and A. S. Aricò. "Investigation of IrO2/Pt Electrocatalysts in Unitized Regenerative Fuel Cells." International Journal of Electrochemistry 2011 (2011): 1–5. http://dx.doi.org/10.4061/2011/276205.

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IrO2/Pt catalysts (at different concentrations) were synthesized by incipient wetness technique and characterized by XRD, XRF, and SEM. Water electrolysis/fuel cell performances were evaluated in a 5 cm2single cell under Unitized Regenerative Fuel Cell (URFC) configuration. The IrO2/Pt composition of 14/86 showed the highest performance for water electrolysis and the lowest one as fuel cell. It is derived that for fuel cell operation an excess of Pt favours the oxygen reduction process whereas IrO2promotes oxygen evolution. From the present results, it appears that the diffusion characteristics and the reaction rate in fuel cell mode are significantly lower than in the electrolyser mode. This requires the enhancement of the gas diffusion properties of the electrodes and the catalytic properties for cathode operation in fuel cells.

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11

Rivera-Gavidia, L. M., I. Fernández de la Puente, M. A. Hernández-Rodríguez, V. Celorrio, D. Sebastián, M. J. Lázaro, E. Pastor, and G. García. "Bi-functional carbon-based catalysts for unitized regenerative fuel cells." Journal of Catalysis 387 (July 2020): 138–44. http://dx.doi.org/10.1016/j.jcat.2020.04.007.

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12

Chen, Guoying, Simon R. Bare, and Thomas E. Mallouk. "Development of Supported Bifunctional Electrocatalysts for Unitized Regenerative Fuel Cells." Journal of The Electrochemical Society 149, no. 8 (2002): A1092. http://dx.doi.org/10.1149/1.1491237.

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13

Dhar, Hari P. "A unitized approach to regenerative solid polymer electrolyte fuel cells." Journal of Applied Electrochemistry 23, no. 1 (January 1993): 32–37. http://dx.doi.org/10.1007/bf00241572.

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14

Peng, Xiong, Zachary Taie, Jiangjin Liu, Yaqian Zhang, Xinxing Peng, Yagya N. Regmi, Julie C. Fornaciari, et al. "Hierarchical electrode design of highly efficient and stable unitized regenerative fuel cells (URFCs) for long-term energy storage." Energy & Environmental Science 13, no. 12 (2020): 4872–81. http://dx.doi.org/10.1039/d0ee03244a.

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15

Ioroi, Tsutomu, Kazuaki Yasuda, Zyun Siroma, Naoko Fujiwara, and Yoshinori Miyazaki. "Thin film electrocatalyst layer for unitized regenerative polymer electrolyte fuel cells." Journal of Power Sources 112, no. 2 (November 2002): 583–87. http://dx.doi.org/10.1016/s0378-7753(02)00466-4.

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16

Ioroi, Tsutomu, Naohisa Kitazawa, Kazuaki Yasuda, Yoshifumi Yamamoto, and Hiroyasu Takenaka. "Iridium Oxide/Platinum Electrocatalysts for Unitized Regenerative Polymer Electrolyte Fuel Cells." Journal of The Electrochemical Society 147, no. 6 (2000): 2018. http://dx.doi.org/10.1149/1.1393478.

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17

Regmi, Yagya N., Xiong Peng, Julie C. Fornaciari, Max Wei, Deborah J. Myers, Adam Z. Weber, and Nemanja Danilovic. "A low temperature unitized regenerative fuel cell realizing 60% round trip efficiency and 10 000 cycles of durability for energy storage applications." Energy & Environmental Science 13, no. 7 (2020): 2096–105. http://dx.doi.org/10.1039/c9ee03626a.

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18

Carvela, Mireya, Alexandra Raschitor, Manuel A. Rodrigo, and Justo Lobato. "Recent Progress in Catalysts for Hydrogen-Chlorine Regenerative Fuel Cells." Catalysts 10, no. 11 (October 30, 2020): 1263. http://dx.doi.org/10.3390/catal10111263.

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The increasing energy demand and the subsequent climate change consequences are supporting the search for sustainable alternatives to fossil fuels. In this scenario, the link between hydrogen and renewable energy is playing a key role and unitized hydrogen-chlorine (H2-Cl2) regenerative cells (RFCs) have become promising candidates for renewable energy storage. Described herein are the recent advances in cell configurations and catalysts for the different reactions that may take place in these systems, that work in both modes: electrolysis and fuel cell. It has been found that platinum (Pt)-based catalysts are the best choice for the electrode where hydrogen is involved, whereas for the case of chlorine, ruthenium (Ru)-based catalysts are the best candidates. Only a few studies were found where the catalysts had been tested in both modes and recent advances are focused on decreasing the amount of precious metals contained in the catalysts. Moreover, the durability of the catalysts tested under realistic conditions has not been thoroughly assessed, becoming a key and mandatory step to evaluate the commercial viability of the H2-Cl2 RFC technology.

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19

García, G., M. Roca-Ayats, A. Lillo, J. L. Galante, M. A. Peña, and M. V. Martínez-Huerta. "Catalyst support effects at the oxygen electrode of unitized regenerative fuel cells." Catalysis Today 210 (July 2013): 67–74. http://dx.doi.org/10.1016/j.cattod.2013.02.003.

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20

Park, Ji Eun, Mohanraju Karuppannan, Oh Joong Kwon, Yong-Hun Cho, and Yung-Eun Sung. "Development of high-performance membrane-electrode assembly in unitized regenerative fuel cells." Journal of Industrial and Engineering Chemistry 80 (December 2019): 527–34. http://dx.doi.org/10.1016/j.jiec.2019.08.029.

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21

Sadhasivam, T., K. Dhanabalan, Sung-Hee Roh, Tae-Ho Kim, Kyung-Won Park, Seunghun Jung, Mahaveer D. Kurkuri, and Ho-Young Jung. "A comprehensive review on unitized regenerative fuel cells: Crucial challenges and developments." International Journal of Hydrogen Energy 42, no. 7 (February 2017): 4415–33. http://dx.doi.org/10.1016/j.ijhydene.2016.10.140.

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22

Sadhasivam, T., Sung-Hee Roh, Tae-Ho Kim, Kyung-Won Park, and Ho-Young Jung. "Graphitized carbon as an efficient mesoporous layer for unitized regenerative fuel cells." International Journal of Hydrogen Energy 41, no. 40 (October 2016): 18226–30. http://dx.doi.org/10.1016/j.ijhydene.2016.08.092.

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23

Albiter, Luis A., Jose Fernando Godinez Salomon, Michael E. Urena, Zachary G. Naymik, and Christopher P. Rhodes. "Niobium Oxide Aerogel-Supported Bifunctional Oxygen Electrocatalysts for Unitized Regenerative Fuel Cells." ECS Meeting Abstracts MA2021-01, no. 38 (May 30, 2021): 1235. http://dx.doi.org/10.1149/ma2021-01381235mtgabs.

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24

Omrani, Reza, and Bahman Shabani. "Gas Diffusion Layers in Fuel Cells and Electrolysers: A Novel Semi-Empirical Model to Predict Electrical Conductivity of Sintered Metal Fibres." Energies 12, no. 5 (March 5, 2019): 855. http://dx.doi.org/10.3390/en12050855.

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This paper introduces novel empirical as well as modified models to predict the electrical conductivity of sintered metal fibres and closed-cell foams. These models provide a significant improvement over the existing models and reduce the maximum relative error from as high as just over 30% down to about 10%. Also, it is shown that these models provide a noticeable improvement for closed-cell metal foams. However, the estimation of electrical conductivity of open-cell metal foams was improved marginally over previous models. Sintered porous metals are widely used in electrochemical devices such as water electrolysers, unitised regenerative fuel cells (URFCs) as gas diffusion layers (GDLs), and batteries. Having a more accurate prediction of electrical conductivity based on variation by porosity helps in better modelling of such devices and hence achieving improved designs. The models presented in this paper are fitted to the experimental results in order to highlight the difference between the conductivity of sintered metal fibres and metal foams. It is shown that the critical porosity (maximum achievable porosity) can play an important role in sintered metal fibres to predict the electrical conductivity whereas its effect is not significant in open-cell metal foams. Based on the models, the electrical conductivity reaches zero value at 95% porosity rather than 100% for sintered metal fibres.

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25

Bhosale, Amit C., Prakash C. Ghosh, and Loïc Assaud. "Preparation methods of membrane electrode assemblies for proton exchange membrane fuel cells and unitized regenerative fuel cells: A review." Renewable and Sustainable Energy Reviews 133 (November 2020): 110286. http://dx.doi.org/10.1016/j.rser.2020.110286.

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26

Dutta, K., D. Rana, H. S. Han, and P. P. Kundu. "Unitized Regenerative Fuel Cells: A Review on Developed Catalyst Systems and Bipolar Plates." Fuel Cells 17, no. 6 (November 27, 2017): 736–51. http://dx.doi.org/10.1002/fuce.201700018.

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27

Roca-Ayats, M., G. García, J. L. Galante, M. A. Peña, and M. V. Martínez-Huerta. "Electrocatalytic stability of Ti based-supported Pt3Ir nanoparticles for unitized regenerative fuel cells." International Journal of Hydrogen Energy 39, no. 10 (March 2014): 5477–84. http://dx.doi.org/10.1016/j.ijhydene.2013.12.187.

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28

Roh, Sung-Hee, T. Sadhasivam, Hansung Kim, Jeong-Hun Park, and Ho-Young Jung. "Carbon free SiO2–SO3H supported Pt bifunctional electrocatalyst for unitized regenerative fuel cells." International Journal of Hydrogen Energy 41, no. 45 (December 2016): 20650–59. http://dx.doi.org/10.1016/j.ijhydene.2016.09.062.

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29

Ganesan, Prabhu, Shenyang Huang, and Branko N. Popov. "Preparation and Characterization of Pt/NbTiO2 Cathode Catalysts for Unitized Regenerative Fuel Cells (URFCs)." ECS Transactions 16, no. 2 (December 18, 2019): 1143–50. http://dx.doi.org/10.1149/1.2981956.

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30

Vincent, Immanuel, Eun-Chong Lee, and Hyung-Man Kim. "Solutions to the water flooding problem for unitized regenerative fuel cells: status and perspectives." RSC Advances 10, no. 29 (2020): 16844–60. http://dx.doi.org/10.1039/d0ra00434k.

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31

Zhang, Yubin, Yichao Ding, and Xueqin Zhao. "Improvement of electrochemical properties of modified unitized regenerative fuel cells through a fluorination technique." Journal of Renewable and Sustainable Energy 10, no. 4 (July 2018): 044302. http://dx.doi.org/10.1063/1.5024702.

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32

Rhodes, Christopher P., Fernando Godinez-Salomon, and Luis Albiter. "Active and Stable Bifunctional Oxygen Electrocatalysts and Catalyst Layers for Unitized Regenerative Fuel Cells." ECS Meeting Abstracts MA2020-02, no. 38 (November 23, 2020): 2488. http://dx.doi.org/10.1149/ma2020-02382488mtgabs.

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33

Wang, Lulu, Hang Guo, Fang Ye, and Chongfang Ma. "Two-Dimensional Simulation of Mass Transfer in Unitized Regenerative Fuel Cells under Operation Mode Switching." Energies 9, no. 1 (January 15, 2016): 47. http://dx.doi.org/10.3390/en9010047.

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34

Dihrab, Salwan S., K. Sopian, M. A. Alghoul, and M. Y. Sulaiman. "Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells." Renewable and Sustainable Energy Reviews 13, no. 6-7 (August 2009): 1663–68. http://dx.doi.org/10.1016/j.rser.2008.09.029.

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35

Ioroi, Tsutomu, Takanori Oku, Kazuaki Yasuda, Naokazu Kumagai, and Yoshinori Miyazaki. "Influence of PTFE coating on gas diffusion backing for unitized regenerative polymer electrolyte fuel cells." Journal of Power Sources 124, no. 2 (November 2003): 385–89. http://dx.doi.org/10.1016/s0378-7753(03)00795-x.

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36

Zhuo, Xiaolong, Sheng Sui, and Junliang Zhang. "Electrode structure optimization combined with water feeding modes for Bi-Functional Unitized Regenerative Fuel Cells." International Journal of Hydrogen Energy 38, no. 11 (April 2013): 4792–97. http://dx.doi.org/10.1016/j.ijhydene.2013.01.137.

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37

Dihrab, Salwan, Tamer Khatib, Kamaruzzaman Sopian, Habeeb Al-Ani, and Saleem H. Zaidi. "On the Performance of Hybrid PV/Unitized Regenerative Fuel Cell System in the Tropics." International Journal of Photoenergy 2012 (2012): 1–7. http://dx.doi.org/10.1155/2012/942784.

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Solar hydrogen system is a unique power system that can meet the power requirements for future energy demands. Such a system uses the hydrogen as the energy carrier, which produces energy through the electrolyzer with assistance of the power from the PV during the sunny hours, and then uses stored hydrogen to produce energy through the fuel cell after sunset or on cloudy days. The current study has used premanufactured unitized regenerative fuel cells in which the electrolyzer and the fuel cell function within one cell at different modes. The system components were modeled and the one-day real operational and simulated data has been presented and compared. The measured results showed the ability of the system to meet the proposed load, and the total efficiency was about 4.5%.

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38

Kim, In Gyeom, In Wook Nah, In-Hwan Oh, and Sehkyu Park. "Crumpled rGO-supported Pt-Ir bifunctional catalyst prepared by spray pyrolysis for unitized regenerative fuel cells." Journal of Power Sources 364 (October 2017): 215–25. http://dx.doi.org/10.1016/j.jpowsour.2017.08.015.

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39

Guarnieri, Massimo, Piergiorgio Alotto, and Federico Moro. "Modeling the performance of hydrogen–oxygen unitized regenerative proton exchange membrane fuel cells for energy storage." Journal of Power Sources 297 (November 2015): 23–32. http://dx.doi.org/10.1016/j.jpowsour.2015.07.067.

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40

Hunsom, M., D. Kaewsai, and A. M. Kannan. "Recent developments in bifunctional air electrodes for unitized regenerative proton exchange membrane fuel cells – A review." International Journal of Hydrogen Energy 43, no. 46 (November 2018): 21478–501. http://dx.doi.org/10.1016/j.ijhydene.2018.09.152.

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41

Grigoriev, S. A., P. Millet, K. A. Dzhus, H. Middleton, T. O. Saetre, and V. N. Fateev. "Design and characterization of bi-functional electrocatalytic layers for application in PEM unitized regenerative fuel cells." International Journal of Hydrogen Energy 35, no. 10 (May 2010): 5070–76. http://dx.doi.org/10.1016/j.ijhydene.2009.08.081.

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42

Millet, P., R. Ngameni, S. A. Grigoriev, and V. N. Fateev. "Scientific and engineering issues related to PEM technology: Water electrolysers, fuel cells and unitized regenerative systems." International Journal of Hydrogen Energy 36, no. 6 (March 2011): 4156–63. http://dx.doi.org/10.1016/j.ijhydene.2010.06.106.

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43

Wang, Yan-Jie, Baizeng Fang, Xiaomin Wang, Anna Ignaszak, Yuyu Liu, Aijun Li, Lei Zhang, and Jiujun Zhang. "Recent advancements in the development of bifunctional electrocatalysts for oxygen electrodes in unitized regenerative fuel cells (URFCs)." Progress in Materials Science 98 (October 2018): 108–67. http://dx.doi.org/10.1016/j.pmatsci.2018.06.001.

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44

Jung, Ho-Young, Sehkyu Park, Prabhu Ganesan, and Branko N. Popov. "Electrochemical Studies of Unsupported PtIr Electrocatalyst as Bi-Functional Oxygen Electrode in Unitized Regenerative Fuel Cells (URFCs)." ECS Transactions 16, no. 2 (December 18, 2019): 1117–21. http://dx.doi.org/10.1149/1.2981953.

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45

Huang, Sheng-Yang, Prabhu Ganesan, Peng Zhang, and Branko Popov. "Development of Novel Metal Oxide Supported Pt catalysts for Polymer Electrolyte Membrane and Unitized Regenerative Fuel Cells Applications." ECS Transactions 25, no. 1 (December 17, 2019): 1893–902. http://dx.doi.org/10.1149/1.3210744.

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46

Sadhasivam, T., Kanalli V. Ajeya, Yoong Ahm Kim, and Ho-Young Jung. "An experimental investigation of the feasibility of Pb based bipolar plate material for unitized regenerative fuel cells system." International Journal of Hydrogen Energy 45, no. 23 (April 2020): 13101–7. http://dx.doi.org/10.1016/j.ijhydene.2020.03.023.

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47

Sui, Sheng, Lirong Ma, and Yuchun Zhai. "TiC supported Pt–Ir electrocatalyst prepared by a plasma process for the oxygen electrode in unitized regenerative fuel cells." Journal of Power Sources 196, no. 13 (July 2011): 5416–22. http://dx.doi.org/10.1016/j.jpowsour.2011.02.058.

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48

Lim, Ahyoun, Ju Sung Lee, Suji Lee, So Young Lee, Hyoung-juhn Kim, Sung Jong Yoo, Jong Hyun Jang, Yung-Eun Sung, and Hyun S. Park. "Polymer electrolyte membrane unitized regenerative fuel cells: Operational considerations for achieving high round trip efficiency at low catalyst loading." Applied Catalysis B: Environmental 297 (November 2021): 120458. http://dx.doi.org/10.1016/j.apcatb.2021.120458.

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49

Peng, Qiong, Pengfei Shu, Xiaosi Qi, Yanli Chen, and Xiu Gong. "Solving the Trifunctional Activity Challenge of Catalysts in Unitized Regenerative Fuel Cells via 1T-MoS2-Coordinated Single Pd Atoms." ACS Omega 6, no. 38 (September 20, 2021): 24731–38. http://dx.doi.org/10.1021/acsomega.1c03575.

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50

Lee, Byung-Seok, Hee-Young Park, Min Kyung Cho, Jea Woo Jung, Hyoung-Juhn Kim, Dirk Henkensmeier, Sung Jong Yoo, et al. "Development of porous Pt/IrO2/carbon paper electrocatalysts with enhanced mass transport as oxygen electrodes in unitized regenerative fuel cells." Electrochemistry Communications 64 (March 2016): 14–17. http://dx.doi.org/10.1016/j.elecom.2016.01.002.

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