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Academic literature on the topic 'Truxene based supramolecular cages'
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Journal articles on the topic "Truxene based supramolecular cages"
Benchohra, Amina, Simon Séjourné, Antoine Labrunie, Liam Miller, Enzo Charbonneau, Vincent Carré, Frédéric Aubriet, Magali Allain, Marc Sallé, and Sébastien Goeb. "Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages." Inorganics 10, no. 7 (July 19, 2022): 103. http://dx.doi.org/10.3390/inorganics10070103.
Full textRaee, Ehsan, Yuqing Yang, and Tianbo Liu. "Supramolecular structures based on metal-organic cages." Giant 5 (March 2021): 100050. http://dx.doi.org/10.1016/j.giant.2021.100050.
Full textLing, Qing-Hui, Jun-Long Zhu, Yi Qin, and Lin Xu. "Naphthalene diimide- and perylene diimide-based supramolecular cages." Materials Chemistry Frontiers 4, no. 11 (2020): 3176–89. http://dx.doi.org/10.1039/d0qm00540a.
Full textKniazeva, Mariia V., Alexander S. Ovsyannikov, Aida I. Samigullina, Daut R. Islamov, Aidar T. Gubaidullin, Pavel V. Dorovatovskii, Vladimir A. Lazarenko, Svetlana E. Solovieva, Igor S. Antipin, and Sylvie Ferlay. "Impact of flexible succinate connectors on the formation of tetrasulfonylcalix[4]arene based nano-sized polynuclear cages: structural diversity and induced chirality study." CrystEngComm 24, no. 3 (2022): 628–38. http://dx.doi.org/10.1039/d1ce01482j.
Full textYadav, Sarita, Palanisamy Kannan, and Guanyinsheng Qiu. "Cavity-based applications of metallo-supramolecular coordination cages (MSCCs)." Organic Chemistry Frontiers 7, no. 18 (2020): 2842–72. http://dx.doi.org/10.1039/d0qo00681e.
Full textZhang, Hai-Xia, Xiaodong Yan, Yu-Xin Chen, Shu-Heng Zhang, Tao Li, Wang-Kang Han, Ling-Yu Bao, Rui Shen, and Zhi-Guo Gu. "A zeolite supramolecular framework with LTA topology based on a tetrahedral metal–organic cage." Chemical Communications 55, no. 8 (2019): 1120–23. http://dx.doi.org/10.1039/c8cc08965e.
Full textDecker, Gerald E., Gregory R. Lorzing, Meaghan M. Deegan, and Eric D. Bloch. "MOF-mimetic molecules: carboxylate-based supramolecular complexes as molecular metal–organic framework analogues." Journal of Materials Chemistry A 8, no. 8 (2020): 4217–29. http://dx.doi.org/10.1039/c9ta12497g.
Full textTaylor, Christopher G. P., Jerico R. Piper, and Michael D. Ward. "Binding of chemical warfare agent simulants as guests in a coordination cage: contributions to binding and a fluorescence-based response." Chemical Communications 52, no. 37 (2016): 6225–28. http://dx.doi.org/10.1039/c6cc02021f.
Full textLu, Hui-Shu, Wang-Kang Han, Xiaodong Yan, Ya-Xin Xu, Hai-Xia Zhang, Tao Li, Yu Gong, Qing-Tao Hu, and Zhi-Guo Gu. "Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties." Dalton Transactions 49, no. 14 (2020): 4220–24. http://dx.doi.org/10.1039/d0dt00353k.
Full textLiu, Wen-Fang, Qi-Ming Qiu, Mo Zhang, Zhao-Min Su, Qingqing An, Hongjin Lv, Zhiyu Jia, and Guo-Yu Yang. "Two new Cu-based borate catalysts with cubic supramolecular cages for efficient catalytic hydrogen evolution." Dalton Transactions 49, no. 29 (2020): 10156–61. http://dx.doi.org/10.1039/d0dt01994a.
Full textDissertations / Theses on the topic "Truxene based supramolecular cages"
Allain, Magali. "Études structurales par diffraction des rayons X appliquées à des cages supramoléculaires et à des conducteurs moléculaires." Electronic Thesis or Diss., Rennes 1, 2022. http://www.theses.fr/2022REN1S081.
Full textThe discrete self-assembled metal assisted structures are big size edifices which do not crystallize easily and decompose rapidly. Moreover, the resolution of these structures is difficult because of the medium quality of the diffraction data sets. Different crystals selection techniques and a refinement method, applied to the supramolecular cages, are discussed, with a particular focus on the use of the Squeeze program which allows the suppression of the disordered atoms and molecules contributions. Two types of isolated and interlocked cages are structurally described. In the second part, a series of new organic conducting materials based on TMTSF and on TTF derivatives, incorporating a novel fluoro-tantalate anion, is described. The structure-conducting properties relationship is discussed. The first Bechgaard phase with a magnetic anion, namely hexafluororhenate, is described, together with its temperature dependent stability and conducting properties. TMTSF and BEDT-TTF have been associated to several mixed tantalum, rhenium or phosphorous hexafluoro anions to provide new conducting alloys. These syntheses also afforded crystalline materials with original anions. Two methods to estimate the oxydation state of the TMTSF donors are compared for several radical cation salts, either prepared during this PhD work or selected from a crystallographic data base
Versäumer, Marina. "Supramolecular coordination cages based on bispyridyl-ligands with redox properties." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-002B-7C2F-E.
Full textZhu, Rongmei. "Control over assembly and interpenetration of Pd-based coordination cages." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-0023-3DF1-8.
Full textLöffler, Susanne. "Host-Guest Chemistry of Acridone-based Coordiantion Cages." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E415-6.
Full textVersäumer, Marina [Verfasser], Guido [Akademischer Betreuer] [Gutachter] Clever, and Franc [Gutachter] Meyer. "Supramolecular coordination cages based on bispyridyl-ligands with redox properties / Marina Versäumer ; Gutachter: Guido Clever, Franc Meyer ; Betreuer: Guido Clever." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://d-nb.info/1116709775/34.
Full textHsu, Chia-Hui, and 徐佳慧. "Synthesis and Properites of C3-symmetric Truxene-Based Derivates and Their Application in Supramolecular Chemistry." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/40910775741093405794.
Full text國立臺灣大學
化學研究所
100
In our previous studies, we developed an unique 3D skeleton based on truxene moiety. With incorporating various functional structures onto C5, C10, and C15 position of the truxene core, the successful synthetical strategy giving intriguing molecules through orthogonally and distinguishably modify active sites provides us an efficient way to further inspect on the diversity of its 3D derivatives. As a result, via involving the 3D truxene core, the thesis extend the applications of these various derivatives in supramolecular chemistry. Herein, we synthesized newly 3D organic gelator TDMDA which constructed by amide groups with long hydrocarbon chains. The morphology of TDMDA was found in fibrillar and globular morphology when dissolved in cyclohexane and methanol respectively and are characterized by SEM and TEM for close view. Moreover, gelator TDMDA incorporating amphipathic groups whose self-assembly display in-situ reversible transformation of aggregate morphology between fibrillar and globular upon exposure to different solvent. On the other hand, we also develope halide anion receptors TPTB and TDMTB from click chemistry. Accroding to NMR titration experiment, we found both of them have the best affinity to chloride due to the proper size of inner cavity. At last, we functionalized pyrene moiety onto the 3D architecture to achieve TPTHP and TDMTHP as C60 receptors, expecting it has good affinity with C60 via donor-acceptor and π-π interaction.
Hsu, Ting-Wei, and 許庭瑋. "Self-Assembly of Functional Metallo-Supramolecular Cages Using Tritopic Terpyridine-Based Ligands." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/56541699435939278943.
Full text國立臺灣大學
化學研究所
104
In supramolecular chemistry, constructing a well-defined three-dimensional cage has attracted more and more attention. Herein, we explore the possibility of exterior functionalization for the self-assembled cages. A series of tritopic terpyridine-based ligands with various exterior functionalities was used to construct metallo-supramolecular cages. To investigate the self-assembly behavior of the predesigned tritopic ligand system, ligands with simple hydroxyl and alkyl substituents were synthesized and complexed with Cd(II) and Zn(II) ions to give supramolecular cubic cages that were well characterized by 1H-NMR, ESI-MS, and electron microscopes. Besides, changing connected positions between the terpyridine moieties and the central core to generate a bent version of the tritopic ligand was successfully used for constructing a smaller supramolecular structure, demonstrating a simple method to build variant metallo-supramolecular structures. To date, the polymer solar cells (PSCs) with P3HT and PCBM as an active layer suffer from a severe lifetime problem, which is partly caused by the macrophase separation from the aggregation of PCBM with time. Based on our new findings, the tritopic terpyridine-based ligand decorated with pendant fullerene groups was successfully synthesized and self-assembled into a functional metallocage via coordination. In addition, the fullerene-functionalized cage was used as a supramolecular crosslinker to alleviate the macrophase aggregation caused by the migration of the C60 acceptor, which significantly improved the stability of organic photovoltaics.
Wang, Yun-Chi, and 王允齊. "Self-Assembly of 3D Metallo-Supramolecular Cages from Terpyridine-Based Ligands with Crown Ethers as Central Units." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/49257698248297914021.
Full text國立臺灣大學
化學研究所
104
Molecular self-assembly using metal-ligand coordinative interaction has drawn much attention in recent years. Utilizing non-covalent interactions provides a facile way to construct large and complicated 2D/3D structures in contrast with the conventional organic chemistry. Moreover, incorporation of orthogonal host-guest and metal-coordination interactions into supramolecular structures will enhance their structural complexity and impart additional functions. In this research, we designed and synthesized a series of metallo-supramolecular cages possessing multiple