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Relevant bibliographies by topics / Trifluoroacetate

Academic literature on the topic 'Trifluoroacetate'

Author: Grafiati

Published: 4 June 2021

Last updated: 3 February 2022

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Journal articles on the topic "Trifluoroacetate"

1

Gleghorn, J. T., and R. W. H. Small. "The trifluoroacetato (and trifluoroacetate) group, CF3COO-(TFA)." Acta Crystallographica Section A Foundations of Crystallography 49, s1 (August 21, 1993): c239. http://dx.doi.org/10.1107/s0108767378093368.

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Mirny, V. N., V. V. Trachevski, and T. A. Mimaya. "Nuclear Magnetic Resonance Study of Caesium-133 in Binary Molten Trifluoroacetate Salt Mixtures." Zeitschrift für Naturforschung A 56, no. 3-4 (April 1, 2001): 288–90. http://dx.doi.org/10.1515/zna-2001-0310.

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Abstract The chemical shifts of Cs+ in binary melts of caesium trifluoroacetate with lithium, sodium, potassium or thallium trifluoroacetates have been studied as a function of composition. An influence of added foreign cations on chemical shift of caesium nuclei has been found. The nature of the intra-and intermolecular paramagnetic contributions into the shifts of 133Cs is discussed.

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3

Smrčková, Svatava, Kristina Juricová, and Viktor Prutianov. "Study of Amino-Imino Tautomerism in Derivatives of 2-, 4- and 6-Aminonicotinic Acid." Collection of Czechoslovak Chemical Communications 59, no. 9 (1994): 2057–68. http://dx.doi.org/10.1135/cccc19942057.

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13C NMR spectra of p-nitrobenzoyl 2-, 4-, and 6-aminopyridine-3-carboxylates, their hydrochlorides, trifluoroacetates and 1-benzyl derivatives were studied. As found from the chemical shifts of pyridine carbon atoms C-2, C-4 and C-6, the free bases exist in the amino form whereas hydrochlorides and 1-substituted pyridinium derivatives in the imino form. Trifluoroacetates of the 2- and 6-amino derivatives have structure similar to that of amidiniumcarboxylates (parallel hydrogen bonds and partially ionic character) whereas trifluoroacetate of the 4-amino derivative is structurally close to the corresponding hydrochloride. The found structures were confirmed by 1H NMR and IR spectroscopy.

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4

Hietsoi, Oleksandr, Alexander S. Filatov, and Marina A. Petrukhina. "Building a two-dimensional network from mixed-valence copper units held together by acetone bridges." Acta Crystallographica Section C Crystal Structure Communications 69, no. 12 (November 8, 2013): 1416–20. http://dx.doi.org/10.1107/s0108270113025559.

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The mixed-valence supramolecular product di-μ2-acetone-di-μ3-trifluoroacetato-deca-μ2-trifluoroacetato-octacopper(I)dicopper(II), [Cu10(C2F3O2)12(C3H6O)2] or {[CuI4(O2CCF3)4]2–{μ2-OC(CH3)2}2–[CuII2(O2CCF3)4]}, was prepared by co-deposition of two building units, namely a bis-acetone adduct of [CuII2(O2CCF3)4] and a very electrophilic tetranuclear [CuI4(O2CCF3)4] complex. The asymmetric unit contains one molecule of the compound with a total of ten independent Cu atoms. Acetone molecules serve as bridges between the [CuII2(O2CCF3)4] and [CuI4(O2CCF3)4] units. Additionally, the tetracopper(I) trifluoroacetate units are involved in intermolecular Cu...O interactions, forming a layered two-dimensional network in the extended structure.

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Ng, S. W., H. K. Fun, and S. Shanmuga Sundara Raj. "Dicyclohexylammonium trifluoroacetate." Acta Crystallographica Section C Crystal Structure Communications 55, no. 12 (December 15, 1999): 2145–47. http://dx.doi.org/10.1107/s0108270199010999.

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6

Rodrigues, V. H., J. A. Paixão, M. M. R. R. Costa, and A. Matos Beja. "Glycinium trifluoroacetate." Acta Crystallographica Section C Crystal Structure Communications 58, no. 11 (October 22, 2002): o658—o660. http://dx.doi.org/10.1107/s010827010201778x.

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7

Frank, Hartmut, Armin Klein, and Dirk Renschen. "Environmental Trifluoroacetate." Nature 382, no. 6586 (July 1996): 34. http://dx.doi.org/10.1038/382034a0.

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8

Athimoolam, S., and S. Natarajan. "Nicotinium trifluoroacetate." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (April 25, 2007): o2656. http://dx.doi.org/10.1107/s1600536807019216.

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Rodrigues, V. H., J. A. Paixão, M. M. R. R. Costa, and A. Matos Beja. "Betainium trifluoroacetate." Acta Crystallographica Section C Crystal Structure Communications 57, no. 6 (June 12, 2001): 761–63. http://dx.doi.org/10.1107/s0108270101004966.

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Rodrigues, V. H., J. A. Paixão, M. M. R. R. Costa, and A. Matos Beja. "Sarcosinium trifluoroacetate." Acta Crystallographica Section C Crystal Structure Communications 56, no. 8 (August 1, 2000): 1053–55. http://dx.doi.org/10.1107/s010827010000809x.

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Dissertations / Theses on the topic "Trifluoroacetate"

1

Smit, Martin Francis. "Effect of trifluoroacetate, a persistent degradation product of halogenated hydrocarbons, on photosynthesis of C₃ and C₄ crop plants / Martin Francis Smit." Thesis, North-West University, 2006. http://hdl.handle.net/10394/1377.

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2

Dixon, Luke Ian. "Introduction of carbon isotopes into organic frameworks using alkynyiodonium salts." Thesis, University of Newcastle Upon Tyne, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.578554.

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3

Stillman, T. J. "A crystallographic investigation into the structure of the metal - trifluoroacetates." Thesis, Lancaster University, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383545.

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Harman, David Grant, and harmandg@hotmail com. "Mechanisms of the Intriguing Rearrangements of Activated Organic Species." The Australian National University. Faculty of Science, 2003. http://thesis.anu.edu.au./public/adt-ANU20031210.143110.

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The β-acyloxyalkyl radical rearrangement has been known since 1967 but its mechanism is still not fully understood, despite considerable investigation. Since the migration of a β-trifluoroacetoxy group generally proceeds more rapidly and with more varied regiochemistry than its less electronegative counterparts, this reaction was studied in the hope of understanding more about the subtleties of the mechanism of the β- acyloxyalkyl radical rearrangement. The mechanism of the catalysed rearrangement of Nalkoxy- 2(1H)-pyridinethiones was also explored because preliminary studies indicated that the transition state (TS) for this process was isoelectronic with TSs postulated for the β-acyloxyalkyl radical and other novel rearrangements. ¶ A kinetic study of the rearrangement of the 2-methyl-2-trifluoroacetoxy-1-heptyl radical in solvents of different polarity was undertaken using a radical clock method. Arrhenius equations for the rearrangement in each solvent were: hexane, log10[kr (s-1)] = 11.8±0.3 – (48.9±0.7)/ θ; benzene, log10[kr (s-1)] = 12.0±0.2 – (43.7±0.8)/ θ; and propionitrile, log10[kr (s-1)] = 11.9±0.2 – (42.0±0.3)/ θ. Rate constants at 75˚C were: hexane, kr = 2.9 × 104; benzene, kr = 2.8 × 105; and propionitrile, kr = 4.0 × 105 s-1. The equilibrium constant for the reversible rearrangement at 80°C in benzene was 15.1

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5

Waechtler, Thomas, Yingzhong Shen, Alexander Jakob, Ramona Ecke, Stefan E. Schulz, Lars Wittenbecher, Hans-Josef Sterzel, et al. "Evaluation of Phosphite and Phosphane Stabilized Copper(I) Trifluoroacetates as Precursors for the Metal-Organic Chemical Vapor Deposition of Copper." Universitätsbibliothek Chemnitz, 2006. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200600315.

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Copper has become the material of choice for metallization of high-performance ultra-large scale integrated circuits. As the feature size is continuously decreasing, metal-organic chemical vapor deposition (MOCVD) appears promising for depositing the Cu seed layer required for electroplating, as well as for filling entire interconnect structures. In this work, four novel organophosphane and organophosphite Cu(I) trifluoroacetates were studied as precursors for Cu MOCVD. Details are reported on CVD results obtained with Tris(tri-n-butylphosphane)copper(I)trifluoroacetate, (ⁿBu₃P)₃CuO₂CCF₃. Solutions of this precursor with acetonitrile and isopropanol were used for deposition experiments on 100 mm Si wafers sputter-coated with Cu, Cu/TiN, and Al(2 % Si)/W. Experiments were carried out in a cold-wall reactor at a pressure of 0.7 mbar, using a liquid delivery approach for precursor dosage. On Cu seed layers, continuous films were obtained at low deposition rates (0.5 to 1 nm/min). At temperatures above 320°C, hole formation in the Cu films was observed. Deposition on TiN led to the formation of single copper particles and etching of the TiN, whereas isolating aluminum oxyfluoride was formed after deposition on Al(Si)/W. It is concluded that the formation of CF₃ radicals during decarboxylation has a negative effect on the deposition results. Furthermore, the precursor chemistry needs to be improved for a higher volatility of the complex.

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6

Lin, Wei-Xin, and 林維信. "Synthesis the Pummerer reaction products using Phenyliodine(III) bis(trifluoroacetate)." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/10191426666051068240.

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Lin, Wei-Sing, and 林維信. "Synthesis the Pummerer reaction products using Phenyliodine(III) bis(trifluoroacetate)." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/40375107615312540262.

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碩士
高雄醫學院
天然藥物研究所
85
ABSTRACT In recent years, hypervalent iodine reagents have attracted much attention as useful synthetic reagents. These hypervalent iodine reagents have been ext-ensively used in oganic synthesis due to their low toxicity and easy handling . In the family of hypervalent iodine compounds, phenyliodine(III) diacetate (PIDA) and phenyliodine(III) bis(trifluoroacetate) (PIFA) are the most frequen-tly used and easily available reagents. It has been shown that that a-acylsulfoxides under Pummerer reaction cond-itions undergo carbon-carbon bond forming reaction such as the Friedel-Crafts reaction and olefin cyclization. According to Tamura et al., treatment of a-ac ylsulfides with phenyliodine (III) bis(trifluoroacetate) (PIFA) resulted in P- ummerer-type reaction to give the same products as obtained by the Pummerer re-action of the a-acylsulfoxides. In this work, Pummerer-type reaction of a-acylsulfides using PIFA was app-lied to prepare pellitorine and ibufenac.

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8

楊秋惠. "Bidentate and Unidentate Trifluoroacetato Ligand in Bis(trifluoroacetato)-(N-methyl-meso-tetraphenylrinato) Thallium(III), a New Fluxional 4:3 piano stool seven-Coordinate Geometry." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/89712167635226543197.

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Books on the topic "Trifluoroacetate"

1

Beskari, Mohamed Ali. Synthesis of trifluoroacetate derivatives of zirconium. Salford: University of Salford, 1992.

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2

S, Oremland R., and Geological Survey (U.S.), eds. Summary of research results on bacterial degradation of trifluoroacetate (TFA), November, 1994-May, 1995. Menlo Park, Calif: U.S. Dept. of the Interior, U.S. Geological Survey, 1995.

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3

J, Matheson Leah, Alternative Fluorocarbons Environmental Assessment Study, and Geological Survey (U.S.), eds. Summary of research results on bacterial degradation of trifluoroacetate (TFA), October, 1993 - October, 1995. Menlo Park, Calif: U.S. Geological Survey, 1996.

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Book chapters on the topic "Trifluoroacetate"

1

Holze, Rudolf. "Ionic conductivities of acetamide trifluoroacetate." In Electrochemistry, 138–39. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_112.

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2

Holze, Rudolf. "Ionic conductivities of azepanium trifluoroacetate." In Electrochemistry, 140. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_113.

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3

Holze, Rudolf. "Ionic conductivities of butyrolactam trifluoroacetate." In Electrochemistry, 1273. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1156.

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4

Holze, Rudolf. "Ionic conductivities of caprolactam trifluoroacetate." In Electrochemistry, 966. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_868.

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5

Holze, Rudolf. "Ionic conductivities of ethylmethylimidazolium trifluoroacetate." In Electrochemistry, 620. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_557.

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6

Holze, Rudolf. "Ionic conductivities of pyrrolidinium trifluoroacetate + H2O." In Electrochemistry, 1155. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1044.

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7

Holze, Rudolf. "Ionic conductivities of 1-methylpiperidinium trifluoroacetate." In Electrochemistry, 866. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_774.

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8

Holze, Rudolf. "Ionic conductivities of 1-methylpyrrolidinium trifluoroacetate." In Electrochemistry, 872. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_780.

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9

Holze, Rudolf. "Ionic conductivities of 1-methylimidazolium trifluoroacetate." In Electrochemistry, 880. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_788.

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10

Holze, Rudolf. "Ionic conductivities of 1-methylimidazolium trifluoroacetate." In Electrochemistry, 302. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_268.

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Conference papers on the topic "Trifluoroacetate"

1

She, Jiangbo, Rongzhi Nie, Xin Sun, and Bo Peng. "Crystal structure and optical properties of a neodymium trifluoroacetate complex for liquid laser." In Second International Conference on Photonics and Optical Engineering, edited by Chunmin Zhang and Anand Asundi. SPIE, 2017. http://dx.doi.org/10.1117/12.2260699.

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2

Martín-Rodríguez, María, Carmen Nájera, José M. Sansano, Abel de Cózar, and Fernando P. Cossío. "Binap-gold(I) vs Binap-silver trifluoroacetate complexes as catalysts in 1,3-dipolar cycloadditions of azomethine ylides." In 14th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0403-1.

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3

Arioğlu, Çağla, Ömer Tamer, Adil Başoğlu, Davut Avci, and Yusuf Atalay. "A theoretical study on 2-amino-5-nitroprydinium trifluoroaceta." In 9TH INTERNATIONAL PHYSICS CONFERENCE OF THE BALKAN PHYSICAL UNION (BPU-9). AIP Publishing LLC, 2016. http://dx.doi.org/10.1063/1.4944220.

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Reports on the topic "Trifluoroacetate"

1

Yu, S. K.-T., R. P. Vrana, and J. B. Green. Retention indices, relative response factors, and mass spectra of trifluoroacetate esters of phenolic compounds determined by capillary GC/MS: Topical report. Office of Scientific and Technical Information (OSTI), April 1989. http://dx.doi.org/10.2172/6421637.

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