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1

Hilpert, Hans, Lienhard Hoesch, and Andr� S. Dreiding. "Triaziridine. 6. Mitteilung. Substituententransformationen an Triaziridinen." Helvetica Chimica Acta 69, no. 8 (December 10, 1986): 2087–97. http://dx.doi.org/10.1002/hlca.19860690833.

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2

Hilpert, Hans, and André S. Dreiding. "Triaziridine. 9. Mitteilung. Ringöffnungen von Triaziridinen." Helvetica Chimica Acta 71, no. 1 (February 3, 1988): 277–91. http://dx.doi.org/10.1002/hlca.19880710132.

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3

Hilpert, Hans, Lienhard Hoesch, and Andr� S. Dreiding. "Triaziridine 8. Mitteilung. Zur Acylierung Von Dialkyl-triaziridinen." Helvetica Chimica Acta 70, no. 2 (March 18, 1987): 390–95. http://dx.doi.org/10.1002/hlca.19870700217.

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4

Kaupp, Gerd, Oswald Dengler, Klaus Burger, and Silvia Rottegger. "Stabile Triaziridine." Angewandte Chemie 97, no. 4 (April 1985): 329–30. http://dx.doi.org/10.1002/ange.19850970420.

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5

Hilpert, Hans, Lienhard Hoesch, and Andr� S. Dreiding. "Triaziridine 7. Mitteilung. Stabile pyramidale Konfigurationen an den Stickstoff-Atomen von Dialkyl-und Trialkyl-triaziridinen." Helvetica Chimica Acta 70, no. 2 (March 18, 1987): 381–89. http://dx.doi.org/10.1002/hlca.19870700216.

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6

Kaupp, Gerd, Jens A. Döhle, Klaus Burger, Paul Rademacher, and Rainer Poppek. "The lone-pair orbitals of triaziridine." Journal of Physical Organic Chemistry 1, no. 5 (September 1988): 267–73. http://dx.doi.org/10.1002/poc.610010504.

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7

Kaupp, Gerd, and Jens A. Döhle. "An Azimine-Triaziridine Transformation by Laser Photolysis." Angewandte Chemie International Edition in English 25, no. 9 (September 1986): 828–30. http://dx.doi.org/10.1002/anie.198608281.

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8

Chi, Weijie, Butong Li, and Haishun Wu. "Density function theory study on energetic nitro-triaziridine derivatives." Structural Chemistry 24, no. 2 (July 3, 2012): 375–81. http://dx.doi.org/10.1007/s11224-012-0083-2.

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9

Hilpert, Hans, Lienhard Hoesch, and André S. Dreiding. "Triaziridine. 4. Mitteilung. Synthese voncis-2,3-Diisopropyltriaziridin-1-carbonsäureestern." Helvetica Chimica Acta 68, no. 6 (September 25, 1985): 1691–97. http://dx.doi.org/10.1002/hlca.19850680624.

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10

Karahodza, Anida, Karen J. Knaus, and David W. Ball. "Cyclic triamines as potential high energy materials. Thermochemical properties of triaziridine and triazirine." Journal of Molecular Structure: THEOCHEM 732, no. 1-3 (November 2005): 47–53. http://dx.doi.org/10.1016/j.theochem.2005.07.004.

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11

Chen, Po-Cheng, Shih-Chieh Wang, Chia-Yu Huang, Jen-Taut Yeh, and Kan-Nan Chen. "New crosslinked polymer from a rapid polymerization of acrylic acid with triaziridine-containing compound." Journal of Applied Polymer Science 104, no. 2 (2007): 809–15. http://dx.doi.org/10.1002/app.25548.

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12

Peverati, Roberto, Jay S. Siegel, and Kim K. Baldridge. "Ab initio quantum chemical computations of substituent effects on triaziridine strain energy and heat of formation." Physical Chemistry Chemical Physics 11, no. 14 (2009): 2387. http://dx.doi.org/10.1039/b816782f.

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13

Engel, Paul S., Li Pan, Kenton H. Whitmire, Ilse Guzman-Jimenez, M. Robert Willcott, and William B. Smith. "Mechanistic Studies of a Linear Trisazoalkane, a New Azimine, and a Bicyclic Triaziridine. Azoalkane Homolysis into Seven Fragments." Journal of Organic Chemistry 65, no. 4 (February 2000): 1016–21. http://dx.doi.org/10.1021/jo991439g.

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14

Song, Hua-Jie, He-Ming Xiao, Hai-Shan Dong, and Wei-Hua Zhu. "Cooperative Effects and Strengths of Hydrogen Bonds in Open-Chaincis-Triaziridine Clusters (n= 2−8): A DFT Investigation." Journal of Physical Chemistry A 110, no. 6 (February 2006): 2225–30. http://dx.doi.org/10.1021/jp055385s.

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15

Engel, Paul S., Li Pan, Kenton H. Whitmire, Ilse Guzman-Jimenez, M. Robert Willcott, and William B. Smith. "ChemInform Abstract: Mechanistic Studies of a Linear Trisazoalkane, a New Azimine, and a Bicyclic Triaziridine. Azoalkane Homolysis into Seven Fragments." ChemInform 31, no. 21 (June 8, 2010): no. http://dx.doi.org/10.1002/chin.200021072.

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16

Alcamí, Manuel, Otilia Mó, Manuel Yáñez, Ibon Alkorta, and José Elguero. "Triaziridine and tetrazetidine vs. cyclic water trimer and tetramer: A computational approach to the relationship between molecular and supramolecular conformational analysis." Physical Chemistry Chemical Physics 4, no. 11 (April 30, 2002): 2123–29. http://dx.doi.org/10.1039/b108270c.

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17

Kaupp, Gerd, Oswald Dengler, Klaus Burger, and Silvia Rottegger. "Stable Triaziridines." Angewandte Chemie International Edition in English 24, no. 4 (April 1985): 341–42. http://dx.doi.org/10.1002/anie.198503411.

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18

Hilpert, Hans, and Roger Hollenstein. "15N-NMR Spectroscopic Characterization of Triaziridines." Helvetica Chimica Acta 69, no. 1 (February 5, 1986): 136–40. http://dx.doi.org/10.1002/hlca.19860690116.

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19

Kaupp, Gerd, and Jens A. Döhle. "Eine Azimin-Triaziridin-Umwandlung durch Laserphotolyse." Angewandte Chemie 98, no. 9 (September 1986): 814–15. http://dx.doi.org/10.1002/ange.19860980911.

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20

Gleiter, Rolf, Christoph Sigwart, Hermann Irngartinger, Stefan Gries, Wolfgang Marterer, Otmar Klingler, and Horst Prinzbach. "cis,cis - Trialkyl-triaziridines photoelectron spectra - X-ray structural analysis." Tetrahedron Letters 29, no. 2 (January 1988): 185–88. http://dx.doi.org/10.1016/s0040-4039(00)80048-9.

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21

Marterer, Wolfgang, Hans Fritz, and Horst Prinzbach. "Stable cis,cis-trialkyl-triaziridines synthesis via azo/nitrene addition, n-oxidation." Tetrahedron Letters 28, no. 45 (January 1987): 5497–500. http://dx.doi.org/10.1016/s0040-4039(00)96763-7.

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22

Burger, Klaus, Silvia Rottegger, Gerd Kaupp, and Oswald Dengler. "Stabilization of small ring compounds by perfluoroalkyl groups synthesis of stable triaziridines." Journal of Fluorine Chemistry 29, no. 1-2 (August 1985): 133. http://dx.doi.org/10.1016/s0022-1139(00)83369-2.

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23

Kaneti, Jos�, Lienhard Hoesch, and Andr� S. Dreiding. "Triaziridines. Part V. A semiempirical MNDO study of nitrogen inversion and amide rotation in Formyltriaziridines." Helvetica Chimica Acta 69, no. 6 (September 10, 1986): 1461–68. http://dx.doi.org/10.1002/hlca.19860690618.

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24

Hadjichristidis, Nikos, Jieai Fan, Changzheng Ju, Songjie Fan, Xia Li, and Zhen Zhang. "Inverse Vulcanization of Aziridines: Enhancing Polysulfides for Superior Mechanical Strength and Adhesive Performance." Angewandte Chemie, November 19, 2024. http://dx.doi.org/10.1002/ange.202418764.

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This study introduces a novel approach to inverse vulcanization by utilizing a commercially available triaziridine crosslinker as an alternative to conventional olefin‐based crosslinkers. The model reactions reveal a self‐catalyzed ring‐opening of "unactivated" aziridine with elemental sulfur, forming oligosulfide‐functionalized diamines. The triaziridine‐derived polysulfides exhibit impressive mechanical properties, achieving a maximum stress of ~8.3 MPa and an elongation at break of ~107%. The incorporation of silicon dioxide (20 wt%) enhances the composite’s rigidity, yielding a Young's modulus of ~0.94 GPa. Furthermore, these polysulfides display excellent adhesion strength on various substrates, such as aluminum (~7.0 MPa), walnut (~9.6 MPa), and steel (~11.0 MPa), with substantial retention of adhesion strength (~3.3 MPa on steel) at −196 °C. The straightforward synthetic process, combined with the accessibility of the triaziridine crosslinker, emphasizes the potential for further innovations in sulfur polymer chemistry.
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25

Hadjichristidis, Nikos, Jieai Fan, Changzheng Ju, Songjie Fan, Xia Li, and Zhen Zhang. "Inverse Vulcanization of Aziridines: Enhancing Polysulfides for Superior Mechanical Strength and Adhesive Performance." Angewandte Chemie International Edition, November 19, 2024. http://dx.doi.org/10.1002/anie.202418764.

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Abstract:
This study introduces a novel approach to inverse vulcanization by utilizing a commercially available triaziridine crosslinker as an alternative to conventional olefin‐based crosslinkers. The model reactions reveal a self‐catalyzed ring‐opening of "unactivated" aziridine with elemental sulfur, forming oligosulfide‐functionalized diamines. The triaziridine‐derived polysulfides exhibit impressive mechanical properties, achieving a maximum stress of ~8.3 MPa and an elongation at break of ~107%. The incorporation of silicon dioxide (20 wt%) enhances the composite’s rigidity, yielding a Young's modulus of ~0.94 GPa. Furthermore, these polysulfides display excellent adhesion strength on various substrates, such as aluminum (~7.0 MPa), walnut (~9.6 MPa), and steel (~11.0 MPa), with substantial retention of adhesion strength (~3.3 MPa on steel) at −196 °C. The straightforward synthetic process, combined with the accessibility of the triaziridine crosslinker, emphasizes the potential for further innovations in sulfur polymer chemistry.
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26

NGUYEN MINH-THO, NGUYEN MINH-THO, J. KANETI, L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: TRIAZIRIDINES. PART III. TRIAZIRIDINE, AZIMINE, AND TRIAZENE: A SCF STUDY OF OF THE ENERGY AND STRUCTURE OF N3H3 ISOMERS." Chemischer Informationsdienst 16, no. 6 (February 12, 1985). http://dx.doi.org/10.1002/chin.198506049.

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27

KAUPP, G., and J. A. DOEHLE. "ChemInform Abstract: An Azimine-Triaziridine Transformation by Laser Photolysis." ChemInform 18, no. 3 (January 20, 1987). http://dx.doi.org/10.1002/chin.198703091.

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28

Naga, Naofumi, Tomoya Takenouchi, and Tamaki Nakano. "Ring-Opening Polymerization of Triaziridine Compounds in Water: An Extremely Facile Method to Synthesize a Porous Polymer through Polymerization-Induced Phase Separation." ACS Macro Letters, April 12, 2022, 603–7. http://dx.doi.org/10.1021/acsmacrolett.2c00110.

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29

HILPERT, H., L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 6. Substituent Transformations on Triaziridines." ChemInform 18, no. 16 (April 21, 1987). http://dx.doi.org/10.1002/chin.198716188.

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30

HILPERT, H., L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 8. Acylation of Dialkyl-triaziridines." ChemInform 18, no. 29 (July 21, 1987). http://dx.doi.org/10.1002/chin.198729152.

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31

HILPERT, H., and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 9. Ring-Openings of Triaziridines." ChemInform 19, no. 17 (April 26, 1988). http://dx.doi.org/10.1002/chin.198817084.

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32

KAUPP, G., O. DENGLER, K. BURGER, and S. ROTTEGGER. "ChemInform Abstract: STABLE TRIAZIRIDINES." Chemischer Informationsdienst 16, no. 31 (August 6, 1985). http://dx.doi.org/10.1002/chin.198531210.

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33

HILPERT, H., L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 7. Stable Pyramidal Configurations at the Nitrogen Atoms of Dialkyl- and Trialkyl-triaziridines." ChemInform 18, no. 28 (July 14, 1987). http://dx.doi.org/10.1002/chin.198728082.

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34

HILPERT, H., and R. HOLLENSTEIN. "ChemInform Abstract:15N NMR Spectroscopic Characterization of Triaziridines." Chemischer Informationsdienst 17, no. 18 (May 6, 1986). http://dx.doi.org/10.1002/chin.198618053.

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35

HILPERT, H., L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 4. Synthesis of cis-2,3-Diisopropyltriaziridine-1-carboxylic Esters." Chemischer Informationsdienst 16, no. 50 (December 17, 1985). http://dx.doi.org/10.1002/chin.198550161.

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36

KANETI, J., L. HOESCH, and A. S. DREIDING. "ChemInform Abstract: Triaziridines. Part 5. A Semiempirical MNDO Study of Nitrogen Inversion and Amide Rotation in Formyltriaziridines." Chemischer Informationsdienst 17, no. 52 (December 30, 1986). http://dx.doi.org/10.1002/chin.198652047.

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