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1

Denninger, U., J. J. Schneider, G. Wilke, R. Goddard, R. Krömer, and C. Krüger. "Transition metal complexes." Journal of Organometallic Chemistry 459, no. 1-2 (October 1993): 349–57. http://dx.doi.org/10.1016/0022-328x(93)86088-y.

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2

Reinholdt, Anders, and Jesper Bendix. "Transition Metal Carbide Complexes." Chemical Reviews 122, no. 1 (November 19, 2021): 830–902. http://dx.doi.org/10.1021/acs.chemrev.1c00404.

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3

Zhou, Wei, Wen-Jie Pan, Jie Chen, Min Zhang, Jin-Hong Lin, Weiguo Cao, and Ji-Chang Xiao. "Transition-metal difluorocarbene complexes." Chemical Communications 57, no. 74 (2021): 9316–29. http://dx.doi.org/10.1039/d1cc04029d.

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4

Braunschweig, Holger, Rian D. Dewhurst, and Viktoria H. Gessner. "Transition metal borylene complexes." Chemical Society Reviews 42, no. 8 (2013): 3197. http://dx.doi.org/10.1039/c3cs35510a.

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5

Starodub, Vladimir A., and T. N. Starodub. "Isotrithionedithiolate transition metal complexes." Russian Chemical Reviews 80, no. 9 (September 30, 2011): 829–53. http://dx.doi.org/10.1070/rc2011v080n09abeh004199.

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6

Ziessel, Raymond, Muriel Hissler, Abdelkrim El-ghayoury, and Anthony Harriman. "Multifunctional transition metal complexes." Coordination Chemistry Reviews 178-180 (December 1998): 1251–98. http://dx.doi.org/10.1016/s0010-8545(98)00060-5.

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7

Brothers, Penelope J., and Warren R. Roper. "Transition-metal dihalocarbene complexes." Chemical Reviews 88, no. 7 (November 1988): 1293–326. http://dx.doi.org/10.1021/cr00089a014.

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8

Cundari, Thomas R. "Transition metal imido complexes." Journal of the American Chemical Society 114, no. 20 (September 1992): 7879–88. http://dx.doi.org/10.1021/ja00046a037.

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9

Hall, Chris, and Robin N. Perutz. "Transition Metal Alkane Complexes†." Chemical Reviews 96, no. 8 (January 1996): 3125–46. http://dx.doi.org/10.1021/cr9502615.

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10

Werner, H., D. Schneider, and M. Schulz. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 451, no. 1-2 (June 1993): 175–82. http://dx.doi.org/10.1016/0022-328x(93)83024-p.

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11

Lappert, M. F. "Transition Metal Carbyne Complexes." Journal of Organometallic Chemistry 461, no. 1-2 (November 1993): C7—C8. http://dx.doi.org/10.1016/0022-328x(93)83302-c.

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12

B�tiu, C., I. Panea, L. Ghizdavu, L. David, and S. Ghizdavu Pellascio. "Divalent transition metal complexes." Journal of Thermal Analysis and Calorimetry 79, no. 1 (January 2005): 129–34. http://dx.doi.org/10.1007/s10973-004-0573-6.

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13

Kalt, Dominique, and Ulrich Schubert. "Transition metal silyl complexes." Inorganica Chimica Acta 306, no. 2 (August 2000): 211–14. http://dx.doi.org/10.1016/s0020-1693(00)00175-4.

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14

Barron, Andrew R., and Geoffrey Wilkinson. "Transition-metal aluminohydride complexes." Polyhedron 5, no. 12 (January 1986): 1897–915. http://dx.doi.org/10.1016/s0277-5387(00)87113-2.

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15

Hitchcock, Peter B., Michael F. Lappert, and Michael J. McGeary. "Dimetallostannylene-transition-metal complexes." Organometallics 9, no. 3 (March 1990): 884–86. http://dx.doi.org/10.1021/om00117a064.

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16

de Azevedo, Cristina G., and K. Peter C. Vollhardt. "Oligocyclopentadienyl Transition Metal Complexes." Synlett 2002, no. 07 (2002): 1019–42. http://dx.doi.org/10.1055/s-2002-32572.

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17

Brisdon, Brian J., and Richard A. Walton. "Transition metal butadienyl complexes." Polyhedron 14, no. 10 (May 1995): 1259–76. http://dx.doi.org/10.1016/0277-5387(95)00060-6.

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18

Hlatky, Gregory G., and Robert H. Crabtree. "Transition-metal polyhydride complexes." Coordination Chemistry Reviews 65 (July 1985): 1–48. http://dx.doi.org/10.1016/0010-8545(85)85020-7.

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19

Werner, H., J. Wolf, F. J. G. Alonso, M. L. Ziegler, and O. Serhadli. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 336, no. 3 (December 1987): 397–411. http://dx.doi.org/10.1016/0022-328x(87)85200-2.

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20

Knorr, Michael, and Ulrich Schubert. "Transition-metal silyl complexes." Journal of Organometallic Chemistry 365, no. 1-2 (April 1989): 151–61. http://dx.doi.org/10.1016/0022-328x(89)87175-x.

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21

Schubert, U. "Transition-metal silyl complexes." Transition Metal Chemistry 16, no. 1 (February 1991): 136–44. http://dx.doi.org/10.1007/bf01127889.

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22

Stevens, Raymond C., John S. Ricci, Thomas F. Koetzle, and Wolfgang A. Herrmann. "Transition metal methylene complexes." Journal of Organometallic Chemistry 412, no. 3 (July 1991): 425–34. http://dx.doi.org/10.1016/0022-328x(91)86087-7.

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23

Bysewski, Oliver, Maria Sittig, Andreas Winter, Benjamin Dietzek-Ivanšić, and Ulrich S. Schubert. "Photobasic transition-metal complexes." Coordination Chemistry Reviews 498 (January 2024): 215441. http://dx.doi.org/10.1016/j.ccr.2023.215441.

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24

Sydora, Orson L. "Transition metal benzoate complexes." Polyhedron 252 (April 2024): 116854. http://dx.doi.org/10.1016/j.poly.2024.116854.

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25

Mantri, S., H. C. Pradhan, T. Maharana, and A. K. Sutar. "Schiff Base Transition Metal Complexes for ROP of L-Lactide." International Journal of Chemical Engineering and Applications 8, no. 2 (April 2017): 122–26. http://dx.doi.org/10.18178/ijcea.2017.8.2.642.

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26

Gerasimov, O. V., and Valentin N. Parmon. "Photocatalysis by transition metal complexes." Russian Chemical Reviews 61, no. 2 (February 28, 1992): 154–67. http://dx.doi.org/10.1070/rc1992v061n02abeh000937.

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27

Brunner, Henri, Jürgen Klankermayer, and Manfred Zabel. "Optically active transition-metal complexes." Journal of Organometallic Chemistry 601, no. 2 (April 2000): 211–19. http://dx.doi.org/10.1016/s0022-328x(00)00064-4.

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28

Winkelmann, Ole, Christian Näther, and Ulrich Lüning. "Bimacrocyclic NHC transition metal complexes." Journal of Organometallic Chemistry 693, no. 6 (March 2008): 923–32. http://dx.doi.org/10.1016/j.jorganchem.2007.11.064.

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29

Xu, Wei, Jonathon P. Rourke, Jagadese J. Vittal, and Richard J. Puddephatt. "Transition Metal Rimmed-Calixresorcinarene Complexes." Inorganic Chemistry 34, no. 1 (January 1995): 323–29. http://dx.doi.org/10.1021/ic00105a050.

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30

Frohnapfel, David S., and Joseph L. Templeton. "Transition metal η2-vinyl complexes." Coordination Chemistry Reviews 206-207 (September 2000): 199–235. http://dx.doi.org/10.1016/s0010-8545(00)00269-1.

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31

Matos, Robson M., and Carlos A. L. Filgueiras. "Transition metal complexes of thioalcanamines." Transition Metal Chemistry 15, no. 4 (August 1990): 297–99. http://dx.doi.org/10.1007/bf01061938.

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32

Brunner, H., A. Köllnberger, T. Burgemeister, and M. Zabel. "Optically active transition metal complexes." Polyhedron 19, no. 12 (June 2000): 1519–26. http://dx.doi.org/10.1016/s0277-5387(00)00416-2.

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33

González-Maupoey, Marta, Vanessa Tabernero, and Tomás Cuenca. "Early transition metal fulvalene complexes." Coordination Chemistry Reviews 253, no. 13-14 (July 2009): 1854–81. http://dx.doi.org/10.1016/j.ccr.2009.02.013.

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34

Busetto, Luigi, Peter M. Maitlis, and Valerio Zanotti. "Bridging vinylalkylidene transition metal complexes." Coordination Chemistry Reviews 254, no. 5-6 (March 2010): 470–86. http://dx.doi.org/10.1016/j.ccr.2009.07.022.

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35

Feltham, R. D. "Transition metal complexes of NOx." Pure and Applied Chemistry 61, no. 5 (January 1, 1989): 943–46. http://dx.doi.org/10.1351/pac198961050943.

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36

Taw, Felicia L., Brian L. Scott, and Jaqueline L. Kiplinger. "Early Transition-Metal Perfluoroalkyl Complexes." Journal of the American Chemical Society 125, no. 48 (December 2003): 14712–13. http://dx.doi.org/10.1021/ja038527+.

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37

Meier, K. "Photopolymerization with transition metal complexes." Coordination Chemistry Reviews 111 (December 1991): 97–110. http://dx.doi.org/10.1016/0010-8545(91)84014-v.

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38

PANDEY, K. "Transition metal–σ-borane complexes." Coordination Chemistry Reviews 253, no. 1-2 (January 2009): 37–55. http://dx.doi.org/10.1016/j.ccr.2007.11.026.

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39

Salzer, A., H. Schmalle, R. Stauber, and S. Streiff. "Optically active transition-metal complexes." Journal of Organometallic Chemistry 408, no. 3 (May 1991): 403–24. http://dx.doi.org/10.1016/0022-328x(91)83211-l.

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40

Nishiyama, Hisao, Henri Brunner, and Peter G. Jones. "Optically active transition metal complexes." Journal of Organometallic Chemistry 405, no. 2 (March 1991): 247–55. http://dx.doi.org/10.1016/0022-328x(91)86278-x.

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41

Braunschweig, Holger. "Transition Metal Complexes of Boron." Angewandte Chemie International Edition 37, no. 13-14 (August 3, 1998): 1786–801. http://dx.doi.org/10.1002/(sici)1521-3773(19980803)37:13/14<1786::aid-anie1786>3.0.co;2-c.

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42

Jagirdar, Balaji R. "Transition metal complexes and catalysis." Resonance 4, no. 9 (September 1999): 63–81. http://dx.doi.org/10.1007/bf02834234.

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43

Barrera, Heribert, Joan Sola, and Josef M. Vi�as. "Transition metal complexes of ?-mercaptoalkylpiperidines." Transition Metal Chemistry 10, no. 6 (June 1985): 233–35. http://dx.doi.org/10.1007/bf00692635.

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44

Richers, Casseday P., Jeffery A. Bertke, and Thomas B. Rauchfuss. "Syntheses of transition metal methoxysiloxides." Dalton Transactions 46, no. 27 (2017): 8756–62. http://dx.doi.org/10.1039/c6dt04205h.

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45

Prananto, Yuniar P., Aron Urbatsch, Boujemaa Moubaraki, Keith S. Murray, David R. Turner, Glen B. Deacon, and Stuart R. Batten. "Transition Metal Thiocyanate Complexes of Picolylcyanoacetamides." Australian Journal of Chemistry 70, no. 5 (2017): 516. http://dx.doi.org/10.1071/ch16648.

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A variety of transition metal complexes involving picolylcyanoacetamides (pica = NCCH2CONH-R; R = 2-picolyl- (2pica), 3-picolyl- (3pica), 4-picolyl- (4pica)) and thiocyanate have been synthesised and their solid-state structures have been determined. The complexes were all obtained from reactions between the corresponding metals salts and pica ligands with sodium thiocyanate under ambient conditions. Both 3pica and 4pica coordinate to the metal solely through the nitrogen atom of the picolyl group and form discrete tetrahedral [M(NCS)2(pica)2] (3pica; M = Mn, Zn; 4pica; M = Co) and octahedral [M(NCS)2(3pica)4] (M = Co, Fe, Ni) complexes. In addition, one-dimensional N,S-thiocyanate-bridged coordination polymers poly-[M(µ-NCS)2(pica)2] (3pica; M = Cd; 4pica; M = Co, Cd) were obtained. The ligand 2pica gave the discrete octahedral complexes [Co(NCS)2(2pica)2] and [Cd(NO3)2(2pica)2] in which 2pica chelates in a bidentate fashion through its picolyl and carbonyl groups. Magnetic susceptibility measurements on the cobalt(ii) complexes were performed and showed short-range antiferromagnetic coupling for the [Co(NCS)2(4pica)2]n 1D polymer.
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46

Bullock, R. Morris, and Geoffrey M. Chambers. "Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 375, no. 2101 (July 24, 2017): 20170002. http://dx.doi.org/10.1098/rsta.2017.0002.

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This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.
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47

Collman, James P., and Roman Boulatov. "Heterodinuclear Transition-Metal Complexes with Multiple Metal–Metal Bonds." Angewandte Chemie International Edition 41, no. 21 (November 4, 2002): 3948–61. http://dx.doi.org/10.1002/1521-3773(20021104)41:21<3948::aid-anie3948>3.0.co;2-k.

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48

Yu, Xianghua, Laurel A. Morton, and Zi-Ling Xue. "Transition-Metal Silyl Complexes and Chemistry in the Reactions of Silanes with Transition-Metal Complexes." Organometallics 23, no. 10 (May 2004): 2210–24. http://dx.doi.org/10.1021/om049862p.

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49

Akef Ibrahim Alhmaideen, Akef Ibrahim Alhmaideen, Hamzeh M. Abdel Halim Hamzeh M Abdel Halim, and Assala A. Al Twal and Adnan S. Abu Surrah Assala A Al Twal and Adnan S Abu Surrah. "Synthesis of New Series of Transition Metal Complexes with Poly (Pyrazolyl) Borates." Journal of the chemical society of pakistan 45, no. 4 (2023): 294. http://dx.doi.org/10.52568/001289/jcsp/45.04.2023.

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In structuring catalysis enzyme and chemistry, tridentate ligands and Scorpionate ligands are of significant worth. This study presents the synthesis of a tris(pyrazolyl)borate ligand to be utilized in transition metal complexes as possible redox shuttles. Complexes of general formula [AgTp], [MIIITp (Cl2)] (M = Fe, Co), Tp = tri (1-pyrazolyl) borohydride and [AgTp*], [FeIIITp*(Cl2)], Tp* = tris (3, 5-dimethyl-1-pyrazolyl) borohydride were synthesized and characterized in solid state. The Tp ligands were considered triply coordinated with the metal center with two bounded chloride atoms as per the information gathered from spectroscopic information. Entire preparations and operations were performed under argon using common Schlenk procedures. Elemental analysis was performed using (the EURO EA instrument). Thermolysis shows that the Tp ligand decomposes around 100oC and above 300oC for some complexes. The composites were simple to compose, yielded high yields, and were reasonably air sensitive. This study has examined the synthesis of a tris(pyrazolyl)borohydride ligand to develop an iron complex. Further studies conducting electrochemical tests should be carried out to demonstrate the effectiveness of this likely redox mediator.
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50

Chatterjee, Suranjana. "Mechanistic Aspects of Redox Reactions of Transition Metal Complexes in Aqueous Media." International Journal of Science and Research (IJSR) 13, no. 4 (April 5, 2024): 644–50. http://dx.doi.org/10.21275/sr24408113730.

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