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Journal articles on the topic 'Transition metal complexes; Bisphosphines'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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1

Baranova, Kristina F., Aleksei A. Titov, Oleg A. Filippov, Alexander F. Smol’yakov, Alexey A. Averin, and Elena S. Shubina. "Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence." Crystals 10, no. 10 (September 29, 2020): 881. http://dx.doi.org/10.3390/cryst10100881.

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Two silver nitrate complexes with bisphosphines were obtained and characterized: [Ag(dcypm)]2(NO3)2 (1; dcypm = bis(dicyclohexylphosphino)methane) and [Ag(dppm)]2(Me2PzH)n(NO3)2 (n = 1, 2a; n = 2, 2b; dppm = bis(diphenylphosphino)methane, Me2PzH = 3,5-dimethylpyrazole). The steric repulsions of bulky cyclohexyl substituents prevent additional ligand coordination to the silver atoms in 1. Compounds obtained feature the bimetallic eight-member cyclic core [AgPCP]2. The intramolecular argenthophilic interaction (d(Ag···Ag) = 2.981 Å) was observed in complex 1. In contrast, the coordination of pyrazole led to the elongation of Ag···Ag distance to 3.218(1) Å in 2a and 3.520 Å in 2b. Complexes 1 and 2a possess phosphorescence both in the solution and solid state. Time-dependent density-functional theory (TD-DFT) calculations demonstrate the origin of their different emission profile. In the case of 1, upon excitation, the electron leaves the Ag–P bonding orbital and locates on the intramolecular Ag···Ag bond (metal-centered character). Complex 2a at room temperature exhibits a phosphorescence originating from the 3(M + LP+N)LPhCT state. At 77 K, the photoluminescence spectrum of complex 2a shows two bands of two different characters: 3(M + LP+N)LPhCT and 3LCPh transitions. The contribution of Ag atoms to the excited state in both complexes 2a and 2b decreased relative to 1 in agreement with the structural changes caused by pyrazole coordination.

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2

Rys, Evgeny G., Peter Lönnecke, Sven Stadlbauer, Valery N. Kalinin, and Evamarie Hey-Hawkins. "Chiral functionalized bisphosphine ligands: Transition metal complexes of 1,2-bis(tert-Butylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12)." Polyhedron 28, no. 16 (November 2009): 3467–72. http://dx.doi.org/10.1016/j.poly.2009.07.030.

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3

Kumar, Saurabh, and Maravanji S. Balakrishna. "Transition metal complexes of imidazole appended pyridyline linked bisphosphine, 2,6-bis(2-(diphenylphosphanyl)-1H-imidazol-1-yl)pyridine." Results in Chemistry 3 (January 2021): 100161. http://dx.doi.org/10.1016/j.rechem.2021.100161.

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4

Szalontai, G�bor, and G�bor Besenyei. "Solid-State Structure of Binuclear Transition Metal Bisphosphine Complexes. Rotation-rate-dependent MAS Spectra of Dipolar and Scalar Coupled Four-Spin Systems of Dimeric Palladium(I) Complexes." Monatshefte f�r Chemie - Chemical Monthly 136, no. 5 (March 14, 2005): 663–76. http://dx.doi.org/10.1007/s00706-004-0259-6.

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5

Fan, Jun, Jeffery A. Whiteford, Bogdan Olenyuk, Michael D. Levin, Peter J. Stang, and Everly B. Fleischer. "Self-Assembly of Porphyrin Arrays via Coordination to Transition Metal Bisphosphine Complexes and the Unique Spectral Properties of the Product Metallacyclic Ensembles." Journal of the American Chemical Society 121, no. 12 (March 1999): 2741–52. http://dx.doi.org/10.1021/ja9839825.

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6

Rys, Evgeny G., Peter Lönnecke, Sven Stadlbauer, Valery N. Kalinin, and Evamarie Hey-Hawkins. "Erratum to “Chiral functionalized bisphosphine ligands: Transition metal complexes of 1,2-bis(tert-butylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12)” [Polyhedron 28 (2009) 16]." Polyhedron 29, no. 3 (February 2010): 1190. http://dx.doi.org/10.1016/j.poly.2009.10.023.

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7

Denninger, U., J. J. Schneider, G. Wilke, R. Goddard, R. Krömer, and C. Krüger. "Transition metal complexes." Journal of Organometallic Chemistry 459, no. 1-2 (October 1993): 349–57. http://dx.doi.org/10.1016/0022-328x(93)86088-y.

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8

Bhat, Sajad A., Madhusudan K. Pandey, Joel T. Mague, and Maravanji S. Balakrishna. "Coordination of bis(azol-1-yl)methane-based bisphosphines towards RuII, RhI, PdII and PtII: synthesis, structural and catalytic studies." Dalton Transactions 46, no. 1 (2017): 227–41. http://dx.doi.org/10.1039/c6dt04094b.

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This paper describes the transition metal chemistry of three bis(X-diphenylphosphino-azol-1-yl)-based bisphosphines: bis(2-Ph₂P-imidazol-1-yl)methane (1), bis(5-Ph₂P-pyrazol-1-yl)methane (2) and bis(5-Ph₂P-1,2,4-triazol-1-yl)methane (3). These show versatility in their coordination behaviour.

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9

Brothers, Penelope J., and Warren R. Roper. "Transition-metal dihalocarbene complexes." Chemical Reviews 88, no. 7 (November 1988): 1293–326. http://dx.doi.org/10.1021/cr00089a014.

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10

Barron, Andrew R., and Geoffrey Wilkinson. "Transition-metal aluminohydride complexes." Polyhedron 5, no. 12 (January 1986): 1897–915. http://dx.doi.org/10.1016/s0277-5387(00)87113-2.

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11

Brisdon, Brian J., and Richard A. Walton. "Transition metal butadienyl complexes." Polyhedron 14, no. 10 (May 1995): 1259–76. http://dx.doi.org/10.1016/0277-5387(95)00060-6.

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12

Hlatky, Gregory G., and Robert H. Crabtree. "Transition-metal polyhydride complexes." Coordination Chemistry Reviews 65 (July 1985): 1–48. http://dx.doi.org/10.1016/0010-8545(85)85020-7.

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13

Ziessel, Raymond, Muriel Hissler, Abdelkrim El-ghayoury, and Anthony Harriman. "Multifunctional transition metal complexes." Coordination Chemistry Reviews 178-180 (December 1998): 1251–98. http://dx.doi.org/10.1016/s0010-8545(98)00060-5.

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14

Kalt, Dominique, and Ulrich Schubert. "Transition metal silyl complexes." Inorganica Chimica Acta 306, no. 2 (August 2000): 211–14. http://dx.doi.org/10.1016/s0020-1693(00)00175-4.

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15

Braunschweig, Holger, Rian D. Dewhurst, and Viktoria H. Gessner. "Transition metal borylene complexes." Chemical Society Reviews 42, no. 8 (2013): 3197. http://dx.doi.org/10.1039/c3cs35510a.

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16

Starodub, Vladimir A., and T. N. Starodub. "Isotrithionedithiolate transition metal complexes." Russian Chemical Reviews 80, no. 9 (September 30, 2011): 829–53. http://dx.doi.org/10.1070/rc2011v080n09abeh004199.

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17

Hall, Chris, and Robin N. Perutz. "Transition Metal Alkane Complexes†." Chemical Reviews 96, no. 8 (January 1996): 3125–46. http://dx.doi.org/10.1021/cr9502615.

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18

Cundari, Thomas R. "Transition metal imido complexes." Journal of the American Chemical Society 114, no. 20 (September 1992): 7879–88. http://dx.doi.org/10.1021/ja00046a037.

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19

Hitchcock, Peter B., Michael F. Lappert, and Michael J. McGeary. "Dimetallostannylene-transition-metal complexes." Organometallics 9, no. 3 (March 1990): 884–86. http://dx.doi.org/10.1021/om00117a064.

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20

de Azevedo, Cristina G., and K. Peter C. Vollhardt. "Oligocyclopentadienyl Transition Metal Complexes." Synlett 2002, no. 07 (2002): 1019–42. http://dx.doi.org/10.1055/s-2002-32572.

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21

Werner, H., J. Wolf, F. J. G. Alonso, M. L. Ziegler, and O. Serhadli. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 336, no. 3 (December 1987): 397–411. http://dx.doi.org/10.1016/0022-328x(87)85200-2.

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22

Knorr, Michael, and Ulrich Schubert. "Transition-metal silyl complexes." Journal of Organometallic Chemistry 365, no. 1-2 (April 1989): 151–61. http://dx.doi.org/10.1016/0022-328x(89)87175-x.

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23

Stevens, Raymond C., John S. Ricci, Thomas F. Koetzle, and Wolfgang A. Herrmann. "Transition metal methylene complexes." Journal of Organometallic Chemistry 412, no. 3 (July 1991): 425–34. http://dx.doi.org/10.1016/0022-328x(91)86087-7.

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24

Schubert, U. "Transition-metal silyl complexes." Transition Metal Chemistry 16, no. 1 (February 1991): 136–44. http://dx.doi.org/10.1007/bf01127889.

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25

Werner, H., D. Schneider, and M. Schulz. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 451, no. 1-2 (June 1993): 175–82. http://dx.doi.org/10.1016/0022-328x(93)83024-p.

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26

Lappert, M. F. "Transition Metal Carbyne Complexes." Journal of Organometallic Chemistry 461, no. 1-2 (November 1993): C7—C8. http://dx.doi.org/10.1016/0022-328x(93)83302-c.

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27

B�tiu, C., I. Panea, L. Ghizdavu, L. David, and S. Ghizdavu Pellascio. "Divalent transition metal complexes." Journal of Thermal Analysis and Calorimetry 79, no. 1 (January 2005): 129–34. http://dx.doi.org/10.1007/s10973-004-0573-6.

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28

Zhou, Wei, Wen-Jie Pan, Jie Chen, Min Zhang, Jin-Hong Lin, Weiguo Cao, and Ji-Chang Xiao. "Transition-metal difluorocarbene complexes." Chemical Communications 57, no. 74 (2021): 9316–29. http://dx.doi.org/10.1039/d1cc04029d.

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29

Burck, Sebastian, Imre Hajdók, Martin Nieger, Denis Bubrin, Simon Schulze, Dietrich Gudat, and Dietrich Gudat. "Activation of Polarized Phosphorus–Phosphorus Bonds by Alkynes: Rational Synthesis of Unsymmetrical 1,2-Bisphosphine Ligands and Their Complexes." Zeitschrift für Naturforschung B 64, no. 1 (January 1, 2009): 63–72. http://dx.doi.org/10.1515/znb-2009-0109.

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The reactions of 1,1-diamino-2,2-diphenyl-substituted diphosphines featuring various degrees of P-P bond polarization with different alkynes were investigated. All diphosphines reacted with alkynes carrying one or two electron withdrawing carboxylic ester moieties under cleavage of the P-P bond and stereospecific phosphinyl-phosphination at the triple bond to give unsymmetrical ethane-1,2- bisphosphines. Several of the products were further converted into chelate complexes upon reaction with group-10 metal dihalides. All isolated compounds were characterized by analytical and spectroscopic data, and several of the new ligands and complexes by single-crystal X-ray diffraction studies.

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30

Frohnapfel, David S., and Joseph L. Templeton. "Transition metal η2-vinyl complexes." Coordination Chemistry Reviews 206-207 (September 2000): 199–235. http://dx.doi.org/10.1016/s0010-8545(00)00269-1.

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31

Brunner, H., A. Köllnberger, T. Burgemeister, and M. Zabel. "Optically active transition metal complexes." Polyhedron 19, no. 12 (June 2000): 1519–26. http://dx.doi.org/10.1016/s0277-5387(00)00416-2.

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32

Meier, K. "Photopolymerization with transition metal complexes." Coordination Chemistry Reviews 111 (December 1991): 97–110. http://dx.doi.org/10.1016/0010-8545(91)84014-v.

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33

Xu, Wei, Jonathon P. Rourke, Jagadese J. Vittal, and Richard J. Puddephatt. "Transition Metal Rimmed-Calixresorcinarene Complexes." Inorganic Chemistry 34, no. 1 (January 1995): 323–29. http://dx.doi.org/10.1021/ic00105a050.

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34

Brunner, Henri, Jürgen Klankermayer, and Manfred Zabel. "Optically active transition-metal complexes." Journal of Organometallic Chemistry 601, no. 2 (April 2000): 211–19. http://dx.doi.org/10.1016/s0022-328x(00)00064-4.

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35

Winkelmann, Ole, Christian Näther, and Ulrich Lüning. "Bimacrocyclic NHC transition metal complexes." Journal of Organometallic Chemistry 693, no. 6 (March 2008): 923–32. http://dx.doi.org/10.1016/j.jorganchem.2007.11.064.

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36

Gerasimov, O. V., and Valentin N. Parmon. "Photocatalysis by transition metal complexes." Russian Chemical Reviews 61, no. 2 (February 28, 1992): 154–67. http://dx.doi.org/10.1070/rc1992v061n02abeh000937.

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37

Braunschweig, Holger. "Transition Metal Complexes of Boron." Angewandte Chemie International Edition 37, no. 13-14 (August 3, 1998): 1786–801. http://dx.doi.org/10.1002/(sici)1521-3773(19980803)37:13/14<1786::aid-anie1786>3.0.co;2-c.

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38

Feltham, R. D. "Transition metal complexes of NOx." Pure and Applied Chemistry 61, no. 5 (January 1, 1989): 943–46. http://dx.doi.org/10.1351/pac198961050943.

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39

Taw, Felicia L., Brian L. Scott, and Jaqueline L. Kiplinger. "Early Transition-Metal Perfluoroalkyl Complexes." Journal of the American Chemical Society 125, no. 48 (December 2003): 14712–13. http://dx.doi.org/10.1021/ja038527+.

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40

Barrera, Heribert, Joan Sola, and Josef M. Vi�as. "Transition metal complexes of ?-mercaptoalkylpiperidines." Transition Metal Chemistry 10, no. 6 (June 1985): 233–35. http://dx.doi.org/10.1007/bf00692635.

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41

Salzer, A., H. Schmalle, R. Stauber, and S. Streiff. "Optically active transition-metal complexes." Journal of Organometallic Chemistry 408, no. 3 (May 1991): 403–24. http://dx.doi.org/10.1016/0022-328x(91)83211-l.

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42

Nishiyama, Hisao, Henri Brunner, and Peter G. Jones. "Optically active transition metal complexes." Journal of Organometallic Chemistry 405, no. 2 (March 1991): 247–55. http://dx.doi.org/10.1016/0022-328x(91)86278-x.

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43

PANDEY, K. "Transition metal–σ-borane complexes." Coordination Chemistry Reviews 253, no. 1-2 (January 2009): 37–55. http://dx.doi.org/10.1016/j.ccr.2007.11.026.

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44

González-Maupoey, Marta, Vanessa Tabernero, and Tomás Cuenca. "Early transition metal fulvalene complexes." Coordination Chemistry Reviews 253, no. 13-14 (July 2009): 1854–81. http://dx.doi.org/10.1016/j.ccr.2009.02.013.

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45

Busetto, Luigi, Peter M. Maitlis, and Valerio Zanotti. "Bridging vinylalkylidene transition metal complexes." Coordination Chemistry Reviews 254, no. 5-6 (March 2010): 470–86. http://dx.doi.org/10.1016/j.ccr.2009.07.022.

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46

Jagirdar, Balaji R. "Transition metal complexes and catalysis." Resonance 4, no. 9 (September 1999): 63–81. http://dx.doi.org/10.1007/bf02834234.

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47

Matos, Robson M., and Carlos A. L. Filgueiras. "Transition metal complexes of thioalcanamines." Transition Metal Chemistry 15, no. 4 (August 1990): 297–99. http://dx.doi.org/10.1007/bf01061938.

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48

Collman, James P., and Roman Boulatov. "Heterodinuclear Transition-Metal Complexes with Multiple Metal–Metal Bonds." Angewandte Chemie International Edition 41, no. 21 (November 4, 2002): 3948–61. http://dx.doi.org/10.1002/1521-3773(20021104)41:21<3948::aid-anie3948>3.0.co;2-k.

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49

Yu, Xianghua, Laurel A. Morton, and Zi-Ling Xue. "Transition-Metal Silyl Complexes and Chemistry in the Reactions of Silanes with Transition-Metal Complexes." Organometallics 23, no. 10 (May 2004): 2210–24. http://dx.doi.org/10.1021/om049862p.

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50

Banerjee, Rupendranath. "Metal-ion catalysed aquation of transition metal complexes." Coordination Chemistry Reviews 68 (December 1985): 145–67. http://dx.doi.org/10.1016/0010-8545(85)80033-3.

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