Academic literature on the topic 'Titanium Vanadium Nitride'

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Journal articles on the topic "Titanium Vanadium Nitride"

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Glaser, A., S. Surnev, F. P. Netzer, N. Fateh, G. A. Fontalvo, and C. Mitterer. "Oxidation of vanadium nitride and titanium nitride coatings." Surface Science 601, no. 4 (February 2007): 1153–59. http://dx.doi.org/10.1016/j.susc.2006.12.010.

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Yeung, Wing Yiu, Richard Wuhrer, and Darren Attard. "Structural Refinement in High Temperature Annealing of Magnetron Sputtered Titanium Vanadium Nitride Coatings." Solid State Phenomena 118 (December 2006): 299–304. http://dx.doi.org/10.4028/www.scientific.net/ssp.118.299.

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Development of advanced ternary nitride coatings such as titanium aluminium nitride and titanium vanadium nitride has attracted significant industrial interest in recent years. Titanium vanadium nitride is considered one of the advanced ternary nitride coatings of great commercial potential. It is believed with the additional element, the oxidation resistance of the coatings can be greatly improved at elevated temperatures. Furthermore, the type of elements selected can produce unique coating properties that can be beneficial to machining of different materials. This paper is to report a study on the structural stability of nanostructured titanium vanadium nitride coatings in high temperature annealing. Nanostructured titanium vanadium nitride coatings were produced by reactive magnetron co-sputtering on AISI H13 tool steel substrates at 240oC. Heat treatment was applied to the coatings at temperatures up to 1000oC. It was found that an unexpected grain refinement of the coatings occurred in the heat treatment process. Grain size of the coatings was found to decrease from ~200-300 nm to ~150 nm after the heat treatments. A strong TiN/TiVN (200) component was found to exist at temperatures up to 700oC but was depleted at higher annealing temperatures. With a finer and densified grain structure, the hardness of the coatings substantially increased from ~800 HV to ~1700 HV.
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Wei, Binbin, Fangwang Ming, Hanfeng Liang, Zhengbing Qi, Wenshen Hu, and Zhoucheng Wang. "All nitride asymmetric supercapacitors of niobium titanium nitride-vanadium nitride." Journal of Power Sources 481 (January 2021): 228842. http://dx.doi.org/10.1016/j.jpowsour.2020.228842.

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Achour, A., R. Lucio-Porto, M. Chaker, A. Arman, A. Ahmadpourian, M. A. Soussou, M. Boujtita, L. Le Brizoual, M. A. Djouadi, and T. Brousse. "Titanium vanadium nitride electrode for micro-supercapacitors." Electrochemistry Communications 77 (April 2017): 40–43. http://dx.doi.org/10.1016/j.elecom.2017.02.011.

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Sun, Weiwei, Yu Xie, and Paul R. C. Kent. "Double transition metal MXenes with wide band gaps and novel magnetic properties." Nanoscale 10, no. 25 (2018): 11962–68. http://dx.doi.org/10.1039/c8nr00513c.

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Latella, B. A., B. K. Gan, K. E. Davies, D. R. McKenzie, and D. G. McCulloch. "Titanium nitride/vanadium nitride alloy coatings: mechanical properties and adhesion characteristics." Surface and Coatings Technology 200, no. 11 (March 2006): 3605–11. http://dx.doi.org/10.1016/j.surfcoat.2004.09.008.

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Sowa, Mark J., Ling Ju, Alexander C. Kozen, Nicholas C. Strandwitz, Guosong Zeng, Tomas F. Babuska, Zakaria Hsain, and Brandon A. Krick. "Plasma-enhanced atomic layer deposition of titanium vanadium nitride." Journal of Vacuum Science & Technology A 36, no. 6 (November 2018): 06A103. http://dx.doi.org/10.1116/1.5037463.

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Cui, Guanglei, Lin Gu, Arne Thomas, Lijun Fu, Peter A. van Aken, Markus Antonietti, and Joachim Maier. "A Carbon/Titanium Vanadium Nitride Composite for Lithium Storage." ChemPhysChem 11, no. 15 (September 30, 2010): 3219–23. http://dx.doi.org/10.1002/cphc.201000537.

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Maznichevsky, Alexander N., Yuri N. Goikhenberg, and Radii V. Sprikut. "Influence of Nitrogen and Nitride-Forming Elements on Properties of Boron-Treated Steel." Solid State Phenomena 284 (October 2018): 621–26. http://dx.doi.org/10.4028/www.scientific.net/ssp.284.621.

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Microalloying has received increased attention in recent years. The aims of the study were to identify and to examine the influence of nitrogen concentration in steel and small additions of nitride-forming elements on the hardenability of a boron-treated manganese-vanadium steel 40GF-VI. The study has shown that the increase in nitrogen concentration from 0.004% to 0.015% increases the hardenability of steel. It was found that a small amount of titanium (about 0.02%) in steel with low concentration of nitrogen (0.004%) is sufficient to bind it to nitrides, which makes it possible to save the most of boron in an active state (in a solid solution). A residual amount of titanium and aluminum in the range of 0.015-0.020% of each in steel with nitrogen concentration in the range of 0.010-0.015%, which is typical of an electric arc melting steel, is insufficient to bind all nitrogen. As a result, a part of nitrogen is spent on the formation of boron nitrides, which reduces the effect of boron on the hardenability of manganese-vanadium steel microalloyed with boron. Some methods of protecting boron in steel are briefly described. The study has established that grain refinement is observed with increasing nitrogen content in steel. Introduction of boron, in absence of titanium, does not change the size of the austenite grain in the entire range of the investigated temperatures. The optimum combination of strength, plastic and ductility characteristics in steel microalloyed with boron and additives of aluminum and titanium was obtained.
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Saidakhmedov, R. Kh, M. G. Karpman, and G. P. Fetisov. "Multicomponent ion-plasma nitride coatings based on titanium, vanadium, and chromium." Metal Science and Heat Treatment 35, no. 9 (September 1993): 495–98. http://dx.doi.org/10.1007/bf00774915.

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Dissertations / Theses on the topic "Titanium Vanadium Nitride"

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Taylor, Matthew Bruce, and matthew taylor@rmit edu au. "A Study of Aluminium Nitride and Titanium Vanadium Nitride Thin Films." RMIT University. Applied Science, 2007. http://adt.lib.rmit.edu.au/adt/public/adt-VIT20080529.151820.

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Thin film coatings are used to improve the properties of components and products in such diverse areas as tool coatings, wear resistant biological coatings, miniature integrated electronics, micro-mechanical systems and coatings for optical devices. This thesis focuses on understanding the development of intrinsic stress and microstructure in coatings of the technologically important materials of aluminium nitride (AlN) and titanium vanadium nitride (TiVN) deposited by filtered cathodic arc deposition. Thin films of AlN are fabricated under a variety of substrate bias regimes and at different deposition rates. Constant substrate bias was found to have a significant effect on the stress and microstructure of AlN thin films. At low bias voltages, films form with low stress and no preferred orientation. At a bias voltage of -200 V, the films exhibited the highest compressive stress and contained crystals preferentially oriented with their c axis in the plane of the film. At the highest bias of -350 V, the film forms with low stress yet continue to contain crystallites with their c axis constrained to lie in the plane of the film. These microstructure changes with bias are explained in terms of an energy minimisation model. The application of a pulsed high voltage bias to a substrate was found to have a strong effect on the reduction of intrinsic stress within AlN thin films. A model has been formulated that predicts the stress in terms of the applied voltage and pulsing rate, in terms of treated volumes known as thermal spikes. The greater the bias voltage and the higher the pulse rate, the greater the reduction in intrinsic stress. At high pulsing and bias rates, a strong preference for the c axis to align perpendicular to the substrate is seen. This observation is explained by dynamical effects of the incident ions on the growing film, encouraging channelling and preferential sputtering. For the first time, the effect of the rate of growth on AlN films deposited with high voltage pulsed bias was investigated and found to significantly change the stress and microstructure. The formation of films with highly tensile stress, highly compressive stress and nano-composites of AlN films containing Al clusters were seen. These observations are explained in terms of four distinct growth regions. At low rates, surface diffusion and shadowing causes highly porous structures with tensile stress; increased rates produced Al rich films of low stress; increasing the growth rate further led to a dense AlN film under compressive stress and the highest rates produce dense, low stress, AlN due to increased levels of thermal annealing. Finally this thesis analyses the feasibility of forming ternary alloys of high quality TiVN thin films using a dual cathode filtered cathodic arc. The synthesised films show exceptional hardness (greater than either titanium nitride or vanadium nitride), excellent mixing of the three elements and interesting optical properties. An optimum concentration of 23% V content was found to give the highest stress and hardness.
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Clem, William Charles. "Mesenchymal stem cell interaction with nanonstructured biomaterials for orthopaedic applications." Birmingham, Ala. : University of Alabama at Birmingham, 2008. https://www.mhsl.uab.edu/dt/2009r/clem.pdf.

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Thesis (Ph. D.)--University of Alabama at Birmingham, 2008.
Additional advisors: Yogesh K. Vohra, Xu Feng, Jack E. Lemons, Timothy M. Wick. Description based on contents viewed July 8, 2009; title from PDF t.p. Includes bibliographical references.
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Elwin, Gareth Steven. "Atmospheric pressure chemical vapour deposition of the nitrides and oxynitrides of vanadium, titanium and chromium." Thesis, University College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322369.

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Sharma, Giriraj. "Modeling of selective catalytic reduction (SCR) of nitric oxide with ammonia using four modern catalysts." Texas A&M University, 2004. http://hdl.handle.net/1969.1/2785.

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In this work, the steady-state performance of zeolite-based Cu-ZSM-5, vanadium based honeycomb monolith catalysts (V), vanadium-titanium based pillared inter layered clay catalyst (V-Ti PLIC) and vanadium-titanium-tungsten-based honeycomb monolith catalysts (V-Ti-W) was investigated in the selective catalytic reduction process (SCR) for NO removal using NH3 in presence of oxygen. The objective is to obtain the expression that would predict the conversion performance of the catalysts for different values of the SCR process parameters, namely temperature, inlet oxygen concentration and inlet ammonia concentration. The NOx emission, its formation and control methods are discussed briefly and then the fundamentals of the SCR process are described. Heat transfer based and chemical kinetics based SCR process models are discussed and widely used rate order based model are reviewed. Based on the experimental data, regression analysis was performed that gives an expression for predicting the SCR rate for the complete temperature range and the rate order with respect to inlet oxygen and ammonia concentration. The average activation energy for the SCR process was calculated and optimum operating conditions were determined for each of the catalyst. The applicable operating range for the catalyst depends on the NO conversion as well as on the ammonia slip and the N2O and NO2 emission. The regression analysis was repeated for the applicable range and an expression was obtained that can be used to estimate the catalyst performance. For the Cu-ZSM-5, the best performance was observed for 400oC, 660 ppm inlet ammonia concentration and 0.1% inlet oxygen concentration. For the V based honeycomb monolith catalyst, the best performance was observed for 300oC, 264 ppm inlet ammonia concentration and 3% inlet oxygen concentration. For the V-Ti based PLIC catalyst, the best performance was observed for 350oC, 330 ppm inlet ammonia concentration and 3% inlet oxygen concentration. For the V-Ti-W based honeycomb monolith catalyst, the best performance was observed for 300oC, 330 ppm inlet ammonia concentration and 3% inlet oxygen concentration. The conversion performance of all of these catalysts is satisfactory for the industrial application. At the operating conditions listed above, the N2O emission is less than 20 ppm and the NO2 emission is less than 10 ppm. The results were validated by comparing the findings with the similar work by other research groups. The mechanism of SCR process is discussed for each of the catalyst. The probable reactions are listed and adsorption and desorption process are studied. The various mechanisms proposed by the researchers are discussed briefly. It is concluded that V-Ti-W and Cu-ZSM-5 catalyst are very promising for SCR of NOx. The expressions can be used to estimate the conversion performance and can be utilized for optimal design and operation. The expressions relate the SCR rate to the input parameters such as temperature and inlet oxygen and ammonia concentration hence by controlling these parameters desired NOx reduction can be achieved with minimal cost and emission.
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PENA, DONOVAN ALEXANDER. "DEVELOPMENT AND CHARACTERIZATION OF MIXED OXIDE CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITRIC OXIDE FROM STATIONARY SOURCES USING AMMONIA." University of Cincinnati / OhioLINK, 2003. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1054307250.

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Constable, Christopher Paul. "Raman microscopic studies of PVD deposited hard ceramic coatings." Thesis, Sheffield Hallam University, 2000. http://shura.shu.ac.uk/19498/.

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PVD hard ceramic coatings grown via the combined cathodic arc/unbalance magnetron deposition process were studied using Raman microscopy. Characteristic spectra from binary, multicomponent, multilayered and superlattice coatings were acquired to gain knowledge of the solid-state physics associated with Raman scattering from polycrystalline PVD coatings and to compile a comprehensive spectral database. Defect-induced first order scattering mechanisms were observed which gave rise to two pronounced groups of bands related to the acoustical (150-300cm[-1]) and optical (400-750cm[-1]) parts of the phonon spectrum. Evidence was gathered to support the theory that the optic modes were mainly due to the vibrations of the lighter elements and the acoustic modes due to the vibrations of the heavier elements within the lattice. A study into the deformation and disordering on the Raman spectral bands of PVD coatings was performed. TiAIN and TiZrN coatings were intentionally damaged via scratching methods. These scratches were then analysed by Raman mapping, both across and along, and a detailed spectral interpretation performed. Band broadening occurred which was related to "phonon relaxation mechanisms" as a direct result of the breaking up of coating grains resulting in a larger proportion of grain boundaries per-unit-volume. A direct correlation of the amount of damage with band width was observed. Band shifts were also found to occur which were due to the stresses caused by the scratching process. These shifts were found to be the largest at the edges of scratches. The Raman mapping of "droplets", a defect inherent to PVD deposition processes, found that higher compressive stresses and large amounts of disorder occurred for coating growth onto droplets. Strategies designed to evaluate the ability of Raman microscopy to monitor the extent of real wear on cutting tools were evaluated. The removal of a coating layer and subsequent detection of a base layer proved successful. This was then expanded to real wear situations in which tools were monitored after 3,6,12,64,120 and 130 minutes-in-cut. A PCA chemometrics model able to distinguish between component layers and oxides was developed. Raman microscopy was found to provide structural and compositional information on oxide scales formed on the surfaces of heat-treated coatings. Wear debris, generated as a consequence of sliding wear tests on various coatings, was also found to be primarily oxide products. The comparison of the oxide types within the debris to those formed on the surface of the same coating statically oxidised, facilitated a contact temperature during sliding to be estimated. Raman microscopy, owing to the piezo-spectroscopic effect, is sensitive to stress levels. The application of Raman microscopy for the determination of residual compressive stresses within PVD coatings was evaluated. TiAlN/VN superlattice coatings with engineered stresses ranging -3 to -11.3 GPa were deposited onto SS and HSS substrates. Subsequent Raman measurements found a correlation coefficient of 0.996 between Raman band position and stress (determined via XRD methods). In addition, there was also a similar correlation coefficient observed between hardness and Raman shift (cm-1). The application of mechanical stresses on a TiAlCrN coating via a stress rig was investigated and tensile and compressive shifts were observed.
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Laval, Stéphane. "Nouveaux systèmes réducteurs utilisant des hydrosiloxanes comme substituts des hydrures d’aluminium et de bore : application à la réduction des fonctions amides et nitriles." Thesis, Lyon 1, 2011. http://www.theses.fr/2011LYO10193/document.

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Ces dernières années, les recherches industrielles et académiques ont connu des bouleversements sans précédents liés à la notion de Développement Durable. Les exigences en matière de santé et d’environnement ont poussé les chimistes à concevoir des produits et procédés chimiques qui permettent de réduire ou d’éliminer les substances dangereuses. Les travaux de recherche décrits dans cette thèse s’inscrivent dans ce contexte et concernent la mise au point de nouveaux systèmes réducteurs utilisant des hydrosiloxanes comme substituts des hydrures d’aluminium et de bore. Dans cet objectif, des systèmes associant le 1,1,3,3-tétraméthyldisiloxane (TMDS) ou le polyméthylhydrosiloxane (PMHS) avec des complexes de titane ou de vanadium ont été développés pour la réduction des fonctions amides et nitriles. La nature de l’association hydrosiloxane – métal et du substrat étudié a joué un rôle important sur la performance et la sélectivité des réactions misent en oeuvre. D’une part, les réductions sélectives d’amides (tertiaires et secondaires) et de nitriles en aldéhydes ont été réalisées respectivement en présence du tétraisopropylate de titane(IV) et du triisopropylate d’oxyde de vanadium(V). D’autre part, les réductions d’amides primaires et de nitriles ont conduit aux amines primaires en présence de tétraisopropylate de titane(IV). Enfin, ces systèmes réducteurs ont été utilisés pour la synthèse d’hétérocycles azotés saturés. La réduction de composés dinitriles donne lieu à une réaction d’alkylation réductrice intramoléculaire qui conduit à la formation de dérivés de la pipéridine, de la pyrrolidine et de l’azétidine en une étape
In recent years, industrial and academic researches have experienced unprecedented changes related to the concept of sustainable development. Health and environment new requirements have prompted chemists to develop chemical products and processes that reduce or eliminate hazardous substances. The research work described in this thesis is focused on the development of new reducing systems using hydrosiloxanes as substitutes for aluminum and boron hydrides. In order to achieve this goal, reducing systems combining 1,1,3,3-tetramethyldisiloxane (TMDS) or polymethylhydrosiloxane (PMHS) with titanium or vanadium complexes have been developed for the reduction of amides and nitriles. The nature of both the association “hydrosiloxane – metal” as well as the studied substrate played an important role on the performance and the selectivity of the reaction. On the one hand, selective reductions of amides (tertiary and secondary) and nitriles to aldehydes were carried out respectively in the presence of titanium(IV) tetraisopropoxide and vanadium(V) triisopropoxide oxide. On the other hand, reductions of amides (primary) and nitriles afforded the corresponding primary amines in the presence of titanium(IV) tetraisopropoxide. Finally, these systems have been applied for the synthesis of saturated N-heterocycles. Reduction of dinitrile compounds led, in one step, to piperidine, pyrrolidine and azetidine derivatives through an intramolecular reductive alkylation reaction
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Bai, Guangcai. "New methods for the syntheses of amido, imido, nitrido and dinitrogen metal complexes and organometallic hydrides and oxides." Doctoral thesis, [S.l.] : [s.n.], 2001. http://webdoc.sub.gwdg.de/diss/2002/bai/bai.pdf.

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Srnak, Thomas Zvonimir. "Temperature programmed desorption studies of selective catalytic reduction of nitric oxide by ammonia over titania, vanadia, and titania-supported vanadia catalysts." 1990. http://catalog.hathitrust.org/api/volumes/oclc/22424701.html.

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Thesis (Ph. D.)--University of Wisconsin-Madison, 1990.
Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 253-272).
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Book chapters on the topic "Titanium Vanadium Nitride"

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Yeung, Wing Yiu, Richard Wuhrer, and Darren Attard. "Structural Refinement in High Temperature Annealing of Magnetron Sputtered Titanium Vanadium Nitride Coatings." In Solid State Phenomena, 299–304. Stafa: Trans Tech Publications Ltd., 2006. http://dx.doi.org/10.4028/3-908451-25-6.299.

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Valade, L., R. Choukroun, P. Cassoux, F. Teyssandier, L. Poirier, M. Ducarroir, R. Feurer, P. Bonnefond, and F. Maury. "Single-source precursors for the chemical vapor deposition of titanium and vanadium carbide and nitride." In The Chemistry of Transition Metal Carbides and Nitrides, 290–310. Dordrecht: Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-1565-7_15.

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Dumesic, J. A., N. Y. Topsoe, T. Slabiak, P. Morsing, B. S. Clausen, E. Törqvist, and H. Topsoe. "Microiunetic Analysis of the Selective Catalytic Reduction (SCR) of Nitric Oxide Over Vanadia/Titania-Based Catalysts." In Studies in Surface Science and Catalysis, 1325–37. Elsevier, 1993. http://dx.doi.org/10.1016/s0167-2991(08)64454-7.

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Conference papers on the topic "Titanium Vanadium Nitride"

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Klopotov, Anatolii, Yurii Kakushkin, Alexandr Potekaev, Oleg Volokitin, Sergei Kislitsyn, and Valentina Kulagina. "Effect Of Irradiation With Low-Energy Alpha Particles On The Structural-Phase State Of Coatings Of Triple Nitride Systems Based On Titanium And Vanadium On Steel." In 2020 7th International Congress on Energy Fluxes and Radiation Effects (EFRE). IEEE, 2020. http://dx.doi.org/10.1109/efre47760.2020.9242104.

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Narayanan, Badri K., Noel Brady, Yong-Yi Wang, and Jon Ogborn. "Effect of Strain Ageing on Yield Strength and Post Yield Behavior of FCAW-G Ferritic Weld Metal." In 2010 8th International Pipeline Conference. ASMEDC, 2010. http://dx.doi.org/10.1115/ipc2010-31371.

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Ferritic weld metal was deposited with gas shielded flux cored arc welding (FCAW-G) process. The nitrogen level in the deposited weld metal varies typically between 20 to 100 ppm. Nitrogen is a fast diffusing solute element that is known to cause strain ageing affecting both strength and toughness. Weld metal was produced with intentional additions of two strong nitride formers, titanium and vanadium. All-weld metal tensile samples were subjected to varying levels of strain, aged at 170°C for 20 minutes and reloaded to failure. Both the yield and tensile strength increased with increase in pre-strain confirming the presence of strain ageing. The strain hardening rate is also seen to change with strain ageing. There is also a corresponding decrease in the uniform elongation with increase in nitrogen and prestrain. The effect of strain ageing treatment on weld metal toughness was also evaluated. A nominal 2%–3% strain was imposed on the weld metal by straining it in the direction of welding and Charpy V-Notch toughness of the weld was measured. The ductile to brittle transition temperature (DBTT) of the weld metal was estimated by measuring the percent shear and the weld metal toughness at different temperatures. The DBTT of the weld metal is seen to shift slightly to higher temperatures with increase in pre-strain. However there was a dramatic drop in the upper shelf energy and a consistent decrease in the average toughness of the weld metal at all temperatures. The as-welded and reheat microstructure of the weld metal was characterized using optical and electron microscopy techniques. The possible implications of strain ageing on pipeline girth weld procedure qualification and inservice integrity are discussed.
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