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Journal articles on the topic 'Thiocarbonyl Group'

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Published: 6 September 2023

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1

Kirby, Christopher W., Michael D. Lumsden, and Roderick E. Wasylishen. "A solid-state 13C NMR and theoretical investigation of carbonyl and thiocarbonyl carbon chemical shift tensors." Canadian Journal of Chemistry 73, no. 4 (April 1, 1995): 604–13. http://dx.doi.org/10.1139/v95-078.

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The carbon chemical shift tensors of the carbonyl and thiocarbonyl groups of acetamide, thioacetamide, thioacetanilide, 4′-methoxyacetanilide, and 4′-methoxythioacetanilide have been experimentally determined using dipolar – chemical shift solid-state 13C NMR spectroscopy. The magnitudes of the three principal components of the carbon chemical shift tensors are found to exhibit marked variations between the carbonyl and thiocarbonyl functionalities. However, in contrast to the conclusions of an earlier comparative investigation involving benzophenone and thiobenzophenone, the orientations of the principal axis systems of these chemical shift tensors are found to be similar. These experimental results represent the first complete characterizations of the carbon chemical shift tensor in organic thiocarbonyls. The results of our ab initio GIAO and LORG calculations of carbon chemical shielding tensors in formaldehyde, thioformaldehyde, formamide, and thioformamide as well as in acetamide and thioacetamide are in qualitative agreement with experiment. The findings of the present investigation provide conclusive evidence that the well-known isotropic deshielding of the carbon nucleus in the C=S group relative to C=O is primarily attributable to the decreased energy associated with the σ ↔ π* excitation within the thiocarbonyl fragment. This result is in contrast with the conventional interpretation that the deshielding originates from a red shift in the C=S HOMO–UMO n → π* transition. Keywords: chemical shift tensors, solid-state 13C NMR, carbonyls, thiocarbonyls, ab initio calculations.
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2

MOLINA, M. T., M. YANEZ, O. MO, R. NOTARIO, and J. L. M. ABBOUD. "ChemInform Abstract: The Thiocarbonyl Group." ChemInform 29, no. 13 (June 23, 2010): no. http://dx.doi.org/10.1002/chin.199813281.

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3

Fernandez, José Manuel García, and Carmen Ortiz Mellet. "The Thiocarbonyl Group in Carbohydrate Chemistry." Sulfur reports 19, no. 1 (September 1996): 61–159. http://dx.doi.org/10.1080/01961779608047905.

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4

Corsaro, Antonino, and Venerando Pistarà. "Conversion of the thiocarbonyl group into the carbonyl group." Tetrahedron 54, no. 50 (December 1998): 15027–62. http://dx.doi.org/10.1016/s0040-4020(98)00880-1.

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5

Crich, David, and Leticia Quintero. "Radical chemistry associated with the thiocarbonyl group." Chemical Reviews 89, no. 7 (November 1989): 1413–32. http://dx.doi.org/10.1021/cr00097a001.

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6

Kook Sohn, Chang, Eun Kyung Ma, Chang Kon Kim, Hai Whang Lee, and Ikchoon Lee. "Theoretical studies on thiocarbonyl group transfer reactions." New Journal of Chemistry 25, no. 6 (2001): 859–63. http://dx.doi.org/10.1039/b010202o.

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7

Huang, Chun-Hao, Pei-Jhen Wu, Kun-You Chung, Yi-An Chen, Elise Y. Li, and Pi-Tai Chou. "Room-temperature phosphorescence from small organic systems containing a thiocarbonyl moiety." Physical Chemistry Chemical Physics 19, no. 13 (2017): 8896–901. http://dx.doi.org/10.1039/c7cp00074j.

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8

Abram, Ulrich, and Bernd Lorenz. "Thiocarbonyl Complexes of Rhenium. Part I." Zeitschrift für Naturforschung B 48, no. 6 (June 1, 1993): 771–77. http://dx.doi.org/10.1515/znb-1993-0611.

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Novel rhenium complexes with terminal thiocarbonyl groups have been synthesized from ReCl3(Me2PhP)3 and sodium diethyldithiocarbamate. mer-(Diethyldithiocarbamato)tris-(dimethylphenylphosphine)(thiocarbonyl)rhenium(I), mer-[Re(CS)(Me2PhP)3(Et2dtc)], and tris(diethyldithiocarbamato)(thiocarbonyl)rhenium(III), [Re(CS)(Et2dtc)3] have been studied by infrared and NMR spectroscopy, mass spectrometry and X-ray diffraction.mer-[Re(CS)(Me2PhP)3(Et2dtc)] crystallizes orthorhombic in the space group Pna21 with a = 1516.1(2), b = 2189.8(2) and c = 1035.6(1) pm. Structure solution and refinement converged at R = 0.042. The coordination geometry is a distorted octahedron. The Re—C bond length is found to be 184(2) pm.[Re(CS)(Et2dtc)3] crystallizes monoclinic in the space group P21/c with a = 962.2(6), b = 1744.0(2), c = 1537.4(6) pm and β = 96.21(1)°. The final R value is 0.028. In the monomeric complex the rhenium atom is seven-coordinate with an approximate pentagonal-bipyramidal coordination sphere and a rhenium-carbon distance of 181(1) pm.
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9

Barton, Derek H. R., Peter I. Dalko, and Stephan D. Géro. "Radical cation reactions associated with the thiocarbonyl group." Tetrahedron Letters 33, no. 14 (March 1992): 1883–86. http://dx.doi.org/10.1016/s0040-4039(00)74167-0.

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10

GARCIA FERNANDEZ, J. M., and C. ORTIZ MELLET. "ChemInform Abstract: The Thiocarbonyl Group in Carbohydrate Chemistry." ChemInform 28, no. 28 (August 3, 2010): no. http://dx.doi.org/10.1002/chin.199728234.

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11

Gouran, Ali Asghar, and Sakineh Asghari. "On Searching for a Stepwise Channel for the Mechanism of a 1,3-Dipolar Cycloaddition between a Thiocarbonyl S-Oxide and C20 Fullerene using Born–Oppenheimer ab Initio QM/MM Molecular Dynamics." Progress in Reaction Kinetics and Mechanism 42, no. 3 (September 2017): 282–88. http://dx.doi.org/10.3184/146867817x14954764850315.

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The probability of existence of a stepwise route which is in parallel with the well-known concerted pathway for the mechanism of 1,3-dipolar cycloaddition is debated by many researchers. As the route is stepwise, it would lead to emergence of at least a metastable intermediate which would produce some stereoisomers such as enantiomers and diastereomers. In 1986 the first clear stepwise example for a 1,3-dipolar cycloaddition was reported by Huisgen where an electron-poor alkene was reacted with a thiocarbonyl ylide. Since then, researchers have focused on the thiocarbonyl ylide 1,3-dipolar group in finding more stepwise examples. It was found that some reactions of a thiocarbonyl ylide with some dipolarophiles proceeded by a stepwise route, while others did not. This situation led us to investigate the probability of existence a stepwise route in parallel with the concerted path for the reaction of methyl thiocarbonyl S-oxide and C20 fullerene as a chemically active and nano-dimension electronegative alkene. To give more reliable data, Born–Oppenheimer ab initio QM/MM molecular dynamics was used.
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12

Corsaro, Antonio, and Venerando Pistara. "ChemInform Abstract: Conversion of the Thiocarbonyl Group into the Carbonyl Group." ChemInform 30, no. 17 (June 16, 2010): no. http://dx.doi.org/10.1002/chin.199917302.

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13

Zhang, Zhong, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer. "Iron Carbonyl Thiocarbonyls: Effect of Substituting a Thiocarbonyl Group for a Carbonyl Group in Mononuclear and Binuclear Iron Carbonyl Derivatives." Inorganic Chemistry 48, no. 5 (March 2, 2009): 1974–88. http://dx.doi.org/10.1021/ic8016276.

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14

Reepmeyer, John C., and D. Andr d'Avignon. "Use of a Hydrolytic Procedure and Spectrometric Methods in the Structure Elucidation of a Thiocarbonyl Analogue of Sildenafil Detected as an Adulterant in an Over-the-Counter Herbal Aphrodisiac." Journal of AOAC INTERNATIONAL 92, no. 5 (September 1, 2009): 1336–42. http://dx.doi.org/10.1093/jaoac/92.5.1336.

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Abstract A sildenafil-related compound was detected in an herbal dietary supplement marketed as an aphrodisiac. The compound was identified as an analogue of sildenafil in which the carbonyl group in the pyrimidine ring of sildenafil was substituted with a thiocarbonyl group, and the methyl group on the piperazine ring was substituted with a hydroxyethyl group. Based on this structure, the compound was named thiohydroxyhomosildenafil. The structure of the compound was established using HPLC/MS, UV spectrometry, electrospray ionization-MS/MS, NMR spectrometry, and a hydrolytic process. One key product of hydrolysis was 1-(2-hydroxyethyl)-piperazine; the identification of this product defined the amine portion of the compound. Another key product of hydrolysis was hydroxyhomosildenafil, generated by hydrolysis of the thiocarbonyl group to a carbonyl group (C S C O). Hydroxyhomosildenafil was detected as a minor component in the dietary supplement.
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15

Narasimhamurthy, N., and A. G. Samuelson. "Thiocarbonyl to carbonyl group transformation using CuCl and NaOH." Tetrahedron Letters 27, no. 33 (January 1986): 3911–12. http://dx.doi.org/10.1016/s0040-4039(00)83914-3.

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16

BARTON, D. H. R., P. I. DALKO, and S. D. GERO. "ChemInform Abstract: Radical Cation Reactions Associated with the Thiocarbonyl Group." ChemInform 23, no. 41 (August 21, 2010): no. http://dx.doi.org/10.1002/chin.199241068.

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17

Tanaka, Y., K. Taguchi, and H. Utsumi. "Toxicity assessment of 255 chemicals to pure cultured nitrifying bacteria using biosensor." Water Science and Technology 46, no. 11-12 (December 1, 2002): 331–35. http://dx.doi.org/10.2166/wst.2002.0758.

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The bioassay has been attracting attention as a method of toxicity assessments of micropollutants in the environment. In this study, we report the characteristics (selectivity and sensitivity) of the nitrifying bacteria biosensor for 255 kinds of chemicals as a model of chemical contaminant in the environment and the results of evaluation of mixed samples of several substances. In the nitrifying bacteria respiration inhibition test using the biosensor, 56 chemicals were detected. It was found that this biosensor is especially sensitive to seven chemicals that have a thiocarbonyl functional group (>C=S), such as a thioamide group of thiocarbamate group. These chemicals are considered to specifically inhibit AMO by chelation of copper. The samples consisted of a mixture of seven types of anilines that inhibit respiration in the bacteria, a mixture of five types of chlorophenols, and a mixture of eight types of substances that contain thiocarbonyl groups were examined. All of the mixed samples inhibited the respiration of the nitrifying bacteria more than 10% by the inhibition rate, and observed a synergistic effects of the substances in the samples.
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18

Yetra, Santhivardhana Reddy, Zhigao Shen, Hui Wang, and Lutz Ackermann. "Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical." Beilstein Journal of Organic Chemistry 14 (June 25, 2018): 1546–53. http://dx.doi.org/10.3762/bjoc.14.131.

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Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic studies provided strong support for a facile organometallic C–H activation manifold.
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19

Balyueva, Yuliya, Nina Sosnovskaya, and Igor' Rozencveyg. "GLOSS-FORMING EFFECT OF TRICHLOROETHYL AMIDES WITH THIOAMIDE FUNCTIONS IN ELECTROCHEMICAL NICKEL PLATING TECHNOLOGY." Modern Technologies and Scientific and Technological Progress 2022, no. 1 (May 16, 2022): 11–12. http://dx.doi.org/10.36629/2686-9896-2022-1-11-12.

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The effect of trichloroethylamides on the possibility of obtaining shiny coatings in a nickel-plating sulfate electrolyte is investigated. The presence of trichloramide fragments and substituents containing a thiocarbonyl group in the structure of the additive makes it possible to obtain shiny and semi-shiny nickel coatings without the introduction of additional reagents
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20

Quiclet-Sire, Beatrice, and Samir Z. Zard. "A Convenient, High Yielding Cleavage of the Thiocarbonyl Group in Xanthates." Bulletin of the Korean Chemical Society 31, no. 3 (March 20, 2010): 543–44. http://dx.doi.org/10.5012/bkcs.2010.31.03.543.

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21

Pogorilyy, Viktor, Petr Ostroverkhov, Valeria Efimova, Ekaterina Plotnikova, Olga Bezborodova, Ekaterina Diachkova, Yuriy Vasil’ev, Andrei Pankratov, and Mikhail Grin. "Thiocarbonyl Derivatives of Natural Chlorins: Synthesis Using Lawesson’s Reagent and a Study of Their Properties." Molecules 28, no. 10 (May 20, 2023): 4215. http://dx.doi.org/10.3390/molecules28104215.

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The development of sulfur-containing pharmaceutical compounds is important in the advancement of medicinal chemistry. Photosensitizers (PS) that acquire new properties upon incorporation of sulfur-containing groups or individual sulfur atoms into their structure are not neglected, either. In this work, a synthesis of sulfur-containing derivatives of natural chlorophyll a using Lawesson’s reagent was optimized. Thiocarbonyl chlorins were shown to have a significant bathochromic shift in the absorption and fluorescence bands. The feasibility of functionalizing the thiocarbonyl group at the macrocycle periphery by formation of a Pt(II) metal complex in the chemotherapeutic agent cisplatin was shown. The chemical stability of the resulting conjugate in aqueous solution was studied, and it was found to possess a high cytotoxic activity against sarcoma S37 tumor cells that results from the combined photodynamic and chemotherapeutic effect on these cells.
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22

Shurupov, Dmitriy, Yuliya Andreeva, Yuliya Balyueva, Nina Sosnovskaya, and Igor' Rozencveyg. "PROSPECTS FOR THE USE OF TRICHLOROETHYL AMIDES WITH THIOAMIDE FUNCTIONS IN THE TECHNOLOGY OF BRILLIANT NICKEL PLATING." Modern Technologies and Scientific and Technological Progress 1, no. 1 (May 17, 2021): 101–2. http://dx.doi.org/10.36629/2686-9896-2021-1-1-101-102.

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The influence of organic additives in the nickel-plating sulfate electrolyte on the pos sibility of obtaining shiny coatings is investigated. The presence in the structure of the additive of trichloramide fragments and substituents containing a thiocarbonyl group-a residue of thiourea or rubeanoic acid, allows to obtain shiny nickel coatings without the introduction of additional reagents.
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23

Yamada, Shinji, Tomoko Misono, and Seiji Tsuzuki. "Cation−π Interactions of a Thiocarbonyl Group and a Carbonyl Group with a Pyridinium Nucleus." Journal of the American Chemical Society 126, no. 31 (August 2004): 9862–72. http://dx.doi.org/10.1021/ja0490119.

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24

Sereda, Oksana, Nicole Clemens, Tatjana Heckel, and René Wilhelm. "Imidazolinium and amidinium salts as Lewis acid organocatalysts." Beilstein Journal of Organic Chemistry 8 (October 18, 2012): 1798–803. http://dx.doi.org/10.3762/bjoc.8.205.

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The application of imidazolinium and amidinium salts as soft Lewis acid organocatalysts is described. These salts were suitable catalysts for the activation of unsaturated thioesters in a Diels–Alder reaction and in the ring opening of thiiranes and epoxides. The products were isolated in good yields. The mild catalysts did not cause desulfurization of the products containing a thiol or thiocarbonyl group.
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25

Nakayama, Juzo, Taku Kitahara, Yoshiaki Sugihara, and Akihiko Ishii. "Ambident Reactivities of Carbenium Salts Possessing a Thiocarbonyl Group at theβ-Position." Chemistry Letters 28, no. 2 (February 1999): 187–88. http://dx.doi.org/10.1246/cl.1999.187.

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26

Yamada, Shinji, and Tomoko Misono. "Intra- and intermolecular interactions between a thiocarbonyl group and a pyridinium nucleus." Tetrahedron Letters 42, no. 32 (August 2001): 5497–500. http://dx.doi.org/10.1016/s0040-4039(01)01066-8.

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27

Sugimoto, Toyonari, Yukishi Yamamoto, and Zen-ichi Yoshida. "Synthesis and Electrical Conductive Property of New Tellurium Polymers Containing Thiocarbonyl Group." Chemistry Letters 19, no. 11 (November 1990): 2111–14. http://dx.doi.org/10.1246/cl.1990.2111.

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28

Petz, Wolfgang, and Frank Weller. "Thiocarbonylkomplexe des Eisens, VII [1] / Thiocarbonyl Complexes of Iron, VII [1]." Zeitschrift für Naturforschung B 46, no. 8 (August 1, 1991): 971–77. http://dx.doi.org/10.1515/znb-1991-0801.

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Slow addition of Fe(CO)4CS (1) to an excess of P(NMe2)3 (2) in pentane produces S=P(NMe2)3 (3) and a tar-like material from which small amounts of violet crystals of (4) could be isolated. 4 crystallizes in the space group P 21/c, Z = 4, a = 13.124(1), b = 14.131(2), c = 14.070(1) Å; β = 91.71(1)°. The iron atom is trigonal-bipyramidally coordinated and bears a chelating ligand formed by C–C coupling between the former CS group and one CO group of 1 and an additional S atom, incorporated probably via the sulfide 3. One P(NMe2)3 unit coordinates at the iron atom and the other one at the former thiocarbonyl carbon atom.
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29

Mohammadpoor-Baltork, Iraj, Majid M. M. Sadeghi, and Karim Esmayilpour. "Convenient transformation of thiocarbonyl to carbonyl group using benzyltriphenylphosphonium and n-butyltriphenylphosphonium peroxodisulfates." Journal of Chemical Research 2003, no. 6 (June 1, 2003): 348–50. http://dx.doi.org/10.3184/030823403103174074.

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30

Quiclet-Sire, Beatrice, and Samir Z. Zard. "ChemInform Abstract: A Convenient, High Yielding Cleavage of the Thiocarbonyl Group in Xanthates." ChemInform 41, no. 30 (July 1, 2010): no. http://dx.doi.org/10.1002/chin.201030036.

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31

Kinemuchi, Haruki, and Bungo Ochiai. "Synthesis of Hydrophilic Sulfur-Containing Adsorbents for Noble Metals Having Thiocarbonyl Group Based on a Methacrylate Bearing Dithiocarbonate Moieties." Advances in Materials Science and Engineering 2018 (2018): 1–8. http://dx.doi.org/10.1155/2018/3729580.

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Novel hydrophilic sulfur-containing adsorbents for noble metals were prepared by the radical terpolymerization of a methacrylate bearing dithiocarbonate moieties (DTCMMA), hydrophilic monomers, and a cross-linker. The resulting adsorbents efficiently and selectively adsorbed noble metals (Au, Ag, and Pd) from various multielement aqueous solutions at room temperature owing to the thiocarbonyl group having high affinity toward noble metals. The metal adsorption by the adsorbents was proceeded by simple mixing followed by filtration. The noble metal selectivity of the adsorbent obtained from DTCMMA and N-isopropylacrylamide was higher than that of the adsorbent obtained from DTCMMA and N,N-dimethylacrylamide due to the lower nonspecific adsorption.
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32

Kiran, Kuppalli R., Toreshettahally R. Swaroop, Kodipura P. Sukrutha, Jeegundipattana B. Shruthi, Seegehally M. Anil, Kanchugarakoppal S. Rangappa, and Maralinganadoddi P. Sadashiva. "Acid-Catalyzed Condensation of o-Phenylenediammines and o-Aminophenols with α-Oxodithioesters: A Divergent and Regio­selective Synthesis of 2-Methylthio-3-aryl/Heteroarylquinoxalines and 2-Acylbenzoxazoles." Synthesis 51, no. 22 (September 23, 2019): 4205–14. http://dx.doi.org/10.1055/s-0039-1690616.

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o-Phenylenediammines and o-aminophenols were reacted with α-oxodithioesters in a highly regioselective fashion to give 2-methylthio-3-aryl/heteroarylquinoxalines and 2-acylbenzoxazoles in 55–94% and 45–86%, respectively, in the presence of p-toluene sulfonic acid catalyst. Control experiments involving reaction of aniline with a α-oxodithioester indicated that the thiocarbonyl group is more reactive than the carbonyl group. Based on this, probable mechanisms for the formation of quinoxalines and benzoxazoles are given. Biological targets of the quinoxalines and benzoxazoles were identified by bioinformatics. It was found that quinoxalines have good binding affinity with human dual-specificity tyrosine-phosphorylation-regulated kinase 1A and benzoxazoles with human carboxylesterase.
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33

Masuda, Ryōichi, Masaru Hojo, Tadaaki Ichi, Shigetoshi Sasano, Tatsuya Kobayashi, and Chihiro Kuroda. "An alternative efficient method for transformation of thiocarbonyl to carbonyl group using trifluoroacetic anhydride." Tetrahedron Letters 32, no. 9 (February 1991): 1195–98. http://dx.doi.org/10.1016/s0040-4039(00)92042-2.

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34

Barnabas, Mary V., Krishnan Venkateswaran, and David C. Walker. "Comparison of muonium and positronium with hydrogen atoms in their reactions towards solutes containing amide and peptide linkages in water and micelle solutions." Canadian Journal of Chemistry 67, no. 1 (January 1, 1989): 120–26. http://dx.doi.org/10.1139/v89-020.

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Rate constants have been sought for the reaction of muonium (Mu) and o-positronium (Ps) with solutions of thirteen solutes containing [Formula: see text] the groups. Values of k range from <105 M−1 s−1 to 3 × 1010 M−1 s−1 and show a variety of trends. For instance, Mu adds across the carbonyl group much faster than does H, but abstracts from an adjacent methyl group more slowly. Mu adds exceptionally efficiently to the thiocarbonyl group. Abstraction reactions are identified by large enhancements in reaction rates when localized in micelles. Ps behaves quite differently to the others in neither abstracting nor adding to these compounds, consistent with it not being a pseudo-isotope of hydrogen. Keywords: muonium, positronium, hydrogen, hydrated electrons, micelles.
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35

Seidelmann, Oliver, Lothar Beyer, and Rainer Richter. "N,N-Disubstituierte Nʹ-Ferrocenoylthioharnstoffe als zweizähnige Komplexliganden für Übergangsmetallionen. Kristallstruktur von Bis-(N,N-diethyl-Nʹ-ferrocenoylthioureato)nickel(II) / N,N-Disubstituted Nʹ-Ferrocenoyl Thioureas as Bidentate Ligands for Transition Metal Ions. Crystal Structure of Bis-(N,N-diethyl-Nʹ-ferrocenoylthioureato)nickel(II)." Zeitschrift für Naturforschung B 50, no. 11 (November 1, 1995): 1679–84. http://dx.doi.org/10.1515/znb-1995-1115.

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N,N-diethyl-Nʹ-ferrocenoyl-thiourea and N-(morpholino-thiocarbonyl)ferrocenecarboxylic amide have been prepared by the reaction of ferrocenoyl chloride with potassium thiocyanate and the respective amine in dry acetone. These bidentate ligands yield neutral heterometalIic complexes with Ni(II), Cu(II), Mn(II) and Co(III). The dark brown air stable crystals of bis-(N,N-diethyl-Nʹ-ferrocenoylthioureato)nickel(II) were characterized by X-ray structure de­termination. Lattice dimensions: a = 1870.9(1), 6= 1161.5(1), c = 1491.4(1) pm; space group Pca21, Z = 4, R = 0.030 for 5707 observed reflections.
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36

Babashkina, Maria G., and Damir A. Safin. "Zn(II), Co(II) and Ni(II) complexes of a phosphorylthiourea derivative of 4-[(EtO)2P(O)CH2]-C6H4-NHC(S)NHP(O)(OiPr)2." Collection of Czechoslovak Chemical Communications 75, no. 5 (2010): 507–15. http://dx.doi.org/10.1135/cccc2009074.

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The reaction of O,O′-diisopropyl phosphorisothiocyanatidate, (iPrO)2P(O)NCS, with diethyl-(4-aminobenzyl)phosphonate leads to the new N-phosphorylated thiourea derivative, 4-[(EtO)2P(O)CH2]-C6H4NHC(S)NHP(O)(OiPr)2 (HL). The reaction of its potassium salt KL with Zn(II) or Co(II) in aqueous EtOH leads to the complexes of formulae M(L-O,S)2 (ZnL2, CoL2). The metal cation in all complexes is coordinated by two deprotonated ligands through the sulfur atoms of the thiocarbonyl groups and the oxygen atoms of the phosphoryl groups. The reaction of KL with Ni(II) leads to the formation of two types of complexes: the blue Ni(L-N,S)2 complex, where the ligand is coordinated through the nitrogen atom of the phosphorylamide group and the sulfur atom of the thiocarbonyl groups and light red Ni(L-O,S)2 complex with the same coordination of L– anion as it was observed for ZnL2 and CoL2. According to UV/Vis spectral data, it was established that the metal cation of Ni(L-N,S)2 is in a square-planar environment in CH2Cl2, whereas the Ni(L-O,S)2 complex shows features of tetrahedral complexes.
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37

Selvakumar, N., Mohammed A. Raheem, Manoj Kumar Khera, Trideep V. Rajale, Magadi Sitaram Kumar, Sreenivas Kandepu, Jagattaran Das, R. Rajagopalan, Javed Iqbal, and Sanjay Trehan. "Influence of ethylene-Oxy spacer group on the activity of linezolid: Synthesis of potent antibacterials possessing a thiocarbonyl group." Bioorganic & Medicinal Chemistry Letters 13, no. 23 (December 2003): 4169–72. http://dx.doi.org/10.1016/j.bmcl.2003.08.068.

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38

Elhady, Omar M., Erian S. Mansour, M. M. Elwassimy, Sameh A. Zawam, and Ali M. Drar. "Synthesis and characterization of some new tebufenozide analogues and study their toxicological effect against Spodoptera littoralis (Boisd.)." Current Chemistry Letters 11, no. 1 (2022): 63–68. http://dx.doi.org/10.5267/j.ccl.2021.9.005.

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Many of mimic analogues synthesized before depending on the change in the structure of aromatic rings. In this work, the carbonyl group in the structure of compounds 1-4 converted to thiocarbonyl group, and then studying the toxicological activity due to chemical change in the active center of mimic analogues was performed for compounds N-tert-butyl-2,4-dichloro-N'-(2,4-dichlorobenzoyl)benzohydrazide (2) and N-tert-butyl-2,4-dichloro-N'-[(2,4-dichlorophenyl)carbonothioyl]benzenecarbothiohydrazide (6). The toxicological study was done by using 2nd and 4th instar larvae of the cotton leaf worm, Spodoptera littoralis (Boisd.). Five concentration levels (600, 300, 150, 75 and 37.5 ppm) of compounds (2) and (6) were applied on the fresh plant food to the newly grown (2nd and 4th) instar larvae.
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39

Nakayama, Juzo, Taku Kitahara, Yoshiaki Sugihara, and Akihiko Ishii. "ChemInform Abstract: Ambident Reactivities of Carbenium Salts Possessing a Thiocarbonyl Group at the β-Position." ChemInform 30, no. 27 (June 15, 2010): no. http://dx.doi.org/10.1002/chin.199927147.

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40

Caracelli, Ignez, Paulo R. Olivato, Henrique J. Traesel, Jéssica Valença, Daniel N. S. Rodrigues, and Edward R. T. Tiekink. "Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone." Acta Crystallographica Section E Crystallographic Communications 71, no. 9 (August 15, 2015): o657—o658. http://dx.doi.org/10.1107/s2056989015014565.

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In the title β-thiocarbonyl compound, C16H16O3S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the methoxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H...O(carbonyl) interactions that lead to a supramolecular chain with a zigzag topology along thecaxis. Chains pack with no specific intermolecular interactions between them.
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41

Ketcham, Roger, Ernst Schaumann, and Gunadi Adiwidjaja. "The Reaction of Cyanothioformamide with Isocyanates − Formation of a Disulfide by Reduction of a Thiocarbonyl Group." European Journal of Organic Chemistry 2001, no. 9 (May 2001): 1695–99. http://dx.doi.org/10.1002/1099-0690(200105)2001:9<1695::aid-ejoc1695>3.0.co;2-0.

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42

BARLUENGA, J., E. RUBIO, and M. TOMAS. "ChemInform Abstract: Functions Containing a Thiocarbonyl Group Bearing Two Heteroatoms Other than a Halogen or Chalcogen." ChemInform 27, no. 35 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199635271.

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43

MASUDA, R., M. HOJO, T. ICHI, S. SASANO, T. KOBAYASHI, and C. KURODA. "ChemInform Abstract: An Alternative Efficient Method for Transformation of Thiocarbonyl to Carbonyl Group Using Trifluoroacetic Anhydride." ChemInform 22, no. 52 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199152111.

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44

Janssen, M. J. "Physical properties of organic thiones: Part IV. The basicity of the thiocarbonyl group in various thiones." Recueil des Travaux Chimiques des Pays-Bas 81, no. 8 (September 2, 2010): 650–60. http://dx.doi.org/10.1002/recl.19620810803.

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45

Eccles, Kevin, Robin Morrison, Abhijeet Sinha, Anita Maguire, and Simon Lawrence. "Halogen Bonding with Sulfur Functional Groups." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C651. http://dx.doi.org/10.1107/s2053273314093486.

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Crystal engineering has been defined as "the understanding of intermolecular interactions in the context of crystal packing and the utilisation of such understanding in the design of new solids with desired physical and chemical properties".[1] Halogen bonding is a significant type of intermolecular interaction involving a halogen atom with neutral or anionic components which has recently been exploited for the formation of multicomponent crystalline materials. Sulfur can exist in a variety of different oxidation states, giving rise to a wide variety of different functional groups that are potentially available for halogen bonding. We have recently reported our investigations with sulfoxide,[2] sulfone[2] and sulfinamide functional groups.[3] Herein we extend this work to include the thioamide functional group and compare it with its more extensively studied amide analogue. Investigation into the propensity for primary aromatic thioamides to form halogen interactions through the thiocarbonyl (C=S) functional group. A range of substituent aromatic primary thioamides containing different electronic substituents on the aromatic ring were synthesized and investigated for cocrystallisation. These cocrystals are held together by a combination of weak hydrogen bonding (N–H···S=C) and strong halogen interactions (C–X···S=C).
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46

López-Pérez, Liliana, Hortensia Maldonado-Textle, Luis Ernesto Elizalde-Herrera, J. Guadalupe Telles-Padilla, Ramiro Guerrero-Santos, Scott Collins, Enrique Javier Jiménez-Regalado, and Claude St Thomas. "Methylation of poly(acrylic acid), prepared using RAFT polymerization, with trimethylsilyldiazomethane: A metamorphosis of the thiocarbonyl group to a thiol-end group." Polymer 168 (April 2019): 116–25. http://dx.doi.org/10.1016/j.polymer.2019.02.025.

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47

Lanterna, Anabel E., María F. Torresan, Rodrigo A. Iglesias, Eduardo A. Coronado, and Alejandro M. Granados. "Remarkable effect of the dithiafulvene structures on their capacity as reducing agents: Influence of conjugated thiocarbonyl group." Applied Surface Science 465 (January 2019): 1061–65. http://dx.doi.org/10.1016/j.apsusc.2018.09.243.

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48

Sakamoto, Masami, Hiroya Kawanishi, Takashi Mino, and Tsutomu Fujita. "Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group." Chemical Communications, no. 18 (2008): 2132. http://dx.doi.org/10.1039/b801524d.

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49

Mereshchenko, Andrey S., Alexey V. Ivanov, Viktor I. Baranovskii, Grzegorz Mloston, Ludmila L. Rodina, and Valerij A. Nikolaev. "On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation." Beilstein Journal of Organic Chemistry 11 (April 20, 2015): 504–13. http://dx.doi.org/10.3762/bjoc.11.57.

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The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,E-conformers and leads to the formation of transient thiocarbonyl ylides in two stages. The thermodynamically favorable further transformation of C=S ylides bearing at least one acyl group is identified as the 1,5-electrocyclization into 1,3-oxathioles. However, in the case of diazomalonates, the dominating process is 1,3-cyclization into thiiranes followed by their spontaneous desulfurization yielding the corresponding alkenes. Finally, carbocyclic diazodiketones are much less reactive under similar conditions due to the locked cyclic structure and are unfavorable for the 1,3-dipolar cycloaddition due to the Z,Z-conformation of the diazo molecule. This structure results in high, positive values of the Gibbs free energy change for the first stage of the cycloaddition process.
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50

Coleman, Robert S., and James M. Siedlecki. "Synthesis of a 4-thio-2'-deoxyuridine containing oligonucleotide. Development of the thiocarbonyl group as a linker element." Journal of the American Chemical Society 114, no. 23 (November 1992): 9229–30. http://dx.doi.org/10.1021/ja00049a089.

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