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1

Berne, Dimitri, Vincent Ladmiral, Eric Leclerc, and Sylvain Caillol. "Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks." Polymers 14, no. 20 (October 21, 2022): 4457. http://dx.doi.org/10.3390/polym14204457.

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While the Michael addition has been employed for more than 130 years for the synthesis of a vast diversity of compounds, the reversibility of this reaction when heteronucleophiles are involved has been generally less considered. First applied to medicinal chemistry, the reversible character of the hetero-Michael reactions has recently been explored for the synthesis of Covalent Adaptable Networks (CANs), in particular the thia-Michael reaction and more recently the aza-Michael reaction. In these cross-linked networks, exchange reactions take place between two Michael adducts by successive dissociation and association steps. In order to understand and precisely control the exchange in these CANs, it is necessary to get an insight into the critical parameters influencing the Michael addition and the dissociation rates of Michael adducts by reconsidering previous studies on these matters. This review presents the progress in the understanding of the thia-Michael reaction over the years as well as the latest developments and plausible future directions to prepare CANs based on this reaction. The potential of aza-Michael reaction for CANs application is highlighted in a specific section with comparison with thia-Michael-based CANs.
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2

Guha, Chayan, Nayim Sepay, Tapas Halder, and Asok Mallik. "Remarkable Diastereoselectivity of the Thia-Michael Reaction on α,α′-Di[(E)-benzylidene]alkanones: Exclusive Formation of a meso Product." Synlett 29, no. 09 (March 22, 2018): 1161–66. http://dx.doi.org/10.1055/s-0036-1591961.

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Thia-Michael addition of thiophenol to α,α′-di[(E)-benzyl­idene]alkanones of both cyclic (six-membered) and acyclic varieties using anhydrous K2CO3 or amberlyst-15 as catalyst has been found to be highly diastereoselective at 15 °C. A one-pot protocol was developed for such reactions by a tandem aldol-thia-Michael process. The stereochemistry of the products was confirmed by X-ray crystallographic studies and in all cases formation of a meso product was observed.
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3

Wessig, Pablo, Tanja Schulze, Alexandra Pfennig, Steffen M. Weidner, Sascha Prentzel, and Helmut Schlaad. "Thiol–ene polymerization of oligospiroketal rods." Polymer Chemistry 8, no. 44 (2017): 6879–85. http://dx.doi.org/10.1039/c7py01569k.

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4

Lin, Ya-mei, Guo-ping Lu, Chun Cai, and Wen-bin Yi. "An odorless thia-Michael addition using Bunte salts as thiol surrogates." RSC Advances 5, no. 34 (2015): 27107–11. http://dx.doi.org/10.1039/c5ra01381j.

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5

Herbert, Katie M., Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, and Stuart J. Rowan. "Dynamic reaction-induced phase separation in tunable, adaptive covalent networks." Chemical Science 11, no. 19 (2020): 5028–36. http://dx.doi.org/10.1039/d0sc00605j.

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6

Bosica, Giovanna, Roderick Abdilla, and Alessio Petrellini. "Thia-Michael Reaction under Heterogeneous Catalysis." Organics 4, no. 1 (February 21, 2023): 86–96. http://dx.doi.org/10.3390/org4010007.

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Thia-Michael reactions between aliphatic and aromatic thiols and various Michael acceptors were performed under environmentally-friendly solvent-free conditions using Amberlyst® A21 as a recyclable heterogeneous catalyst to efficiently obtain the corresponding adducts in high yields. Ethyl acrylate was the main acceptor used, although others such as acrylamide, linear, and cyclic enones were also utilized successfully. Bifunctional Michael donor, 3-mercaptopropanoic acid, positively furnished the product, albeit in a lower yield and after leaving the reaction to take place for a longer time. The catalyst was easy and safe to handle and successfully recycled for five consecutive cycles.
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7

Qiu, Lin, Zhongqing Wen, Yuling Li, Kai Tian, Youchao Deng, Ben Shen, Yanwen Duan, and Yong Huang. "Stereoselective functionalization of platensimycin and platencin by sulfa-Michael/aldol reactions." Organic & Biomolecular Chemistry 17, no. 17 (2019): 4261–72. http://dx.doi.org/10.1039/c9ob00324j.

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8

Hayama, Noboru, Yusuke Kobayashi, Eriko Sekimoto, Anna Miyazaki, Kiyofumi Inamoto, Tetsutaro Kimachi, and Yoshiji Takemoto. "A solvent-dependent chirality-switchable thia-Michael addition to α,β-unsaturated carboxylic acids using a chiral multifunctional thiourea catalyst." Chemical Science 11, no. 21 (2020): 5572–76. http://dx.doi.org/10.1039/d0sc01729a.

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9

Mostardeiro, Vitor B., Marina C. Dilelio, Teodoro S. Kaufman, and Claudio C. Silveira. "Efficient synthesis of 4-sulfanylcoumarins from 3-bromo-coumarins via a highly selective DABCO-mediated one-pot thia-Michael addition/elimination process." RSC Advances 10, no. 1 (2020): 482–91. http://dx.doi.org/10.1039/c9ra09545d.

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10

Jain, Anshul, Sushobhan Maji, Khyati Shukla, Akanksha Kumari, Shivani Garg, Ramesh K. Metre, Sudipta Bhattacharyya, and Nirmal K. Rana. "Stereoselective synthesis of tri-substituted tetrahydrothiophenes and their in silico binding against mycobacterial protein tyrosine phosphatase B." Organic & Biomolecular Chemistry 20, no. 15 (2022): 3124–35. http://dx.doi.org/10.1039/d2ob00052k.

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DABCO catalysed highly diastereoselective cascade thia-Michael/aldol reaction was established for the construction of diversely functionalized tetrahydrothiophenes. Their in silico structure–function activities against MptpB have also been studied.
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11

Monnereau, Laure, Charlotte Grandclaudon, Thierry Muller, and Stefan Bräse. "Sulfur-based hyper cross-linked polymers." RSC Advances 5, no. 30 (2015): 23152–59. http://dx.doi.org/10.1039/c5ra01463h.

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The possibilities offered by sulphur-based chemistry to produce 3D-polymers based on a tetrakis(phenyl)methane core have been exploited: eight HCPs were generated by oxidation, nucleophilic substitution or thia-Michael additions.
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12

Kohyama, Aki, Michihiro Fukuda, Shunsuke Sugiyama, Hiroyuki Yamakoshi, Naoki Kanoh, Chikashi Ishioka, Hiroyuki Shibata, and Yoshiharu Iwabuchi. "Reversibility of the thia-Michael reaction of cytotoxic C5-curcuminoid and structure–activity relationship of bis-thiol-adducts thereof." Organic & Biomolecular Chemistry 14, no. 45 (2016): 10683–87. http://dx.doi.org/10.1039/c6ob01771a.

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A panel of GO-Y030-bis-thiol-adducts were synthesized and the structure–reactivity relationship regarding the retro thia-Michael reaction as well as the cell growth inhibitory activity against human colon cancer HCT116 were evaluated.
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13

Barakat, Assem, Abdullah M. Al-Majid, Hany J. AL-Najjar, Yahia N. Mabkhot, Hazem A. Ghabbour, and Hoong-Kun Fun. "Expression of concern: An efficient and green procedure for synthesis of rhodanine derivatives by aldol-thia-Michael protocol using aqueous diethylamine medium." RSC Advances 15, no. 2 (2025): 1335. https://doi.org/10.1039/d5ra90007g.

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Expression of concern for ‘An efficient and green procedure for synthesis of rhodanine derivatives by aldol-thia-Michael protocol using aqueous diethylamine medium’ by Assem Barakat et al., RSC Adv., 2014, 4, 4909–4916, https://doi.org/10.1039/C3RA46551A.
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14

Folgado, Enrique, Marc Guerre, Antonio Da Costa, Anthony Ferri, Ahmed Addad, Vincent Ladmiral, and Mona Semsarilar. "“One-pot” aminolysis/thia-Michael addition preparation of well-defined amphiphilic PVDF-b-PEG-b-PVDF triblock copolymers: self-assembly behaviour in mixed solvents." Polymer Chemistry 11, no. 2 (2020): 401–10. http://dx.doi.org/10.1039/c9py00970a.

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Novel amphiphilic PVDF-based triblock copolymer (PVDF50-b-PEG136-b-PVDF50) is synthesized using RAFT polymerization and a one-pot thia-Michael addition. Self-assembly of this ABA copolymer resulted in formation of original crystalline structures.
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15

Abdelli, Abderrahmen, Hedi M'rabet, Mohamed Lotfi Efrit, Anne Gaucher, and Damien Prim. "γ-Alkylsulfide phosphonates through the thia-Michael strategy." Journal of Sulfur Chemistry 35, no. 6 (September 1, 2014): 674–82. http://dx.doi.org/10.1080/17415993.2014.951856.

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16

Mazzolini, Jérôme, Olivier Boyron, Vincent Monteil, Franck D’Agosto, Christophe Boisson, Gemma C. Sanders, Johan P. A. Heuts, Rob Duchateau, Didier Gigmes, and Denis Bertin. "Polyethylene end functionalization using thia-Michael addition chemistry." Polymer Chemistry 3, no. 9 (2012): 2383. http://dx.doi.org/10.1039/c2py20199b.

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17

Liang, F., Y. Li, X. Bi, and Q. Liu. "Substituted Thiophenes via Intramolecular Thia-anti-Michael Addition." Synfacts 2007, no. 1 (January 2007): 0031. http://dx.doi.org/10.1055/s-2006-955741.

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18

Szczepański, Jacek, Helena Tuszewska, and Nazar Trotsko. "Synthesis of a New [3-(4-Chlorophenyl)-4-oxo-1,3-thiazolidin-5-ylidene]acetic Acid Derivative." Molbank 2020, no. 3 (July 28, 2020): M1150. http://dx.doi.org/10.3390/m1150.

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The new methyl [3-(4-chlorophenyl)-2-{[(2,4-dichloro-1,3-thiazol-5-yl)methylidene]hydrazinylidene}-4-oxo-1,3-thiazolidin-5-ylidene]acetate was synthesized from 4-(4-chlorophenyl)-1-(2,4-dichloro-1,3-thiazol-5-yl)methylidene-3-thiosemicarbazide using dimethyl acetylenedicarboxylate as thia-Michael reaction acceptor. New compounds (3 and 4) were characterized by IR, 1H and 13C NMR spectroscopy methods.
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19

Bibi, Rifhat, Amna Murtaza, Khalid Mohammed Khan, Zia ur Rehman, Aamer Saeed, Muhammad Nawaz Tahir, and Abbas Hassan. "E- and chemoselective thia-Michael addition to benzyl allenoate." Phosphorus, Sulfur, and Silicon and the Related Elements 195, no. 12 (July 30, 2020): 969–75. http://dx.doi.org/10.1080/10426507.2020.1799365.

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20

Abaee, M. Saeed, Somayeh Cheraghi, Somayeh Navidipoor, Mohammad M. Mojtahedi, and Soodabeh Forghani. "An efficient tandem aldol condensation-thia-Michael addition process." Tetrahedron Letters 53, no. 33 (August 2012): 4405–8. http://dx.doi.org/10.1016/j.tetlet.2012.06.040.

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21

Wadhwa, Preeti, Anupreet Kharbanda, and Anuj Sharma. "Thia-Michael Addition: An Emerging Strategy in Organic Synthesis." Asian Journal of Organic Chemistry 7, no. 4 (February 8, 2018): 634–61. http://dx.doi.org/10.1002/ajoc.201700609.

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22

Xiang, Yang, Jian Song, Yong Zhang, Da-Cheng Yang, Zhi Guan, and Yan-Hong He. "Enzyme-Catalyzed Asymmetric Domino Thia-Michael/Aldol Condensation Using Pepsin." Journal of Organic Chemistry 81, no. 14 (July 6, 2016): 6042–48. http://dx.doi.org/10.1021/acs.joc.6b01132.

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23

Sasmal, Pradip K., S. Sridhar, and Javed Iqbal. "Facile synthesis of thiazoles via an intramolecular thia-Michael strategy." Tetrahedron Letters 47, no. 49 (December 2006): 8661–65. http://dx.doi.org/10.1016/j.tetlet.2006.09.157.

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24

Chaudhuri, Mihir K., and Sahid Hussain. "Boric acid catalyzed thia-Michael reactions in water or alcohols." Journal of Molecular Catalysis A: Chemical 269, no. 1-2 (May 2007): 214–17. http://dx.doi.org/10.1016/j.molcata.2007.01.014.

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25

Lee, Way-Zen, Tzu-Li Wang, Hao-Ching Chang, Yi-Ting Chen, and Ting-Shen Kuo. "A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition." Organometallics 31, no. 11 (May 21, 2012): 4106–9. http://dx.doi.org/10.1021/om300275a.

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26

Fan, Ya-juan, Dan Wang, Liang Wang, and Yongsheng Zhou. "Thia-Michael addition in a Brønsted acidic deep eutectic solvent." Mendeleev Communications 34, no. 4 (July 2024): 561–62. http://dx.doi.org/10.1016/j.mencom.2024.06.030.

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27

Ye, Hexia, Xinyao Zhao, Yajie Fu, Haibo Liu, Junchen Li, and Xiaojing Bi. "Controllable Synthesis of Thioacetals/Thioketals and β-Sulfanyl Ketones Mediated by Methanesulfonic Anhydride and Sulfuric Acid Sulfuric Acid from Aldehyde/Acetone and Thiols." Molecules 29, no. 20 (October 10, 2024): 4785. http://dx.doi.org/10.3390/molecules29204785.

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A novel and controllable synthesis of thioacetals/thioketals and β-sulfanyl ketones mediated by the reaction of aldehyde/acetone with thiols has been developed. In this protocol, β-sulfanyl ketones can be generated without the prior preparation of α, β-unsaturated carbonyl compounds. A variety of thiols reacted with aldehyde/acetone and provided the corresponding thioacetals/thioketals and β-sulfanyl ketones in good to excellent yields, respectively. This protocol is operationally simple, mild, and atom-economical, providing controllable access to thioacetals/thioketals and thia-Michael addition products under mild conditions.
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28

Al-Khazragie, Zainab K., Adnan J. M. Al-Fartosy, and Bushra K. Al-Salami. "Biochemical Study of Some New Cephems and Selenacephems Based on 6H-1,3-Thiazines and 6H-1,3-selenazines." Biomedicine and Chemical Sciences 1, no. 2 (April 1, 2022): 93–109. http://dx.doi.org/10.48112/bcs.v1i2.161.

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Several new and know 6-(4-substituted phenyl)-4-(4-substituted phenyl)-2-phenyl-6H-1,3-thiazine (or selenazine) (Z4B7, Z4D5, Z4B7' and Z4D5') were prepared by the 1,4-Michael addition reaction of chalcone derivatives with thiobenzamide or phenylselenocarboxamide in basic medium (where the chalcones was formed by Claisen-Schimidt condensation of aromatic aldehydes with 4-substituted acetophenone in presence of sodium hydroxide). These 6H-1,3-thia- or selenazine were used to a new series of cephem and selenacephem compounds (i.e. 7-chloro-4-(4-substituted phenyl)-2-(4-substituted phenyl)-6-phenyl-5-thia (or 5-selena)-1-azabicyclo[4.2.0]oct-2-en-8-one; AZ4B7, AZ4D5, AZ4B7' and AZ4D5'). All new compound derivatives were characterized by IR, 1H NMR, 13C NMR, mass spectroscopic techniques and elemental analysis. The toxicity of new compounds was assayed via the determination of their LD50 value by using Dixon's up and down method. The antibacterial activity of cephem and selenacephem compounds were tested in vitro against Staphylococcus aureus, Bacillus, Escherichia coli and Pseudomonas aeruginosa. Furthermore, the antioxidant, anticancer and DNA cleavage efficiency of compounds were evaluated.
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29

Abaee, M. Saeed, Somayeh Cheraghi, Somayeh Navidipoor, Mohammad M. Mojtahedi, and Soodabeh Forghani. "ChemInform Abstract: An Efficient Tandem Aldol Condensation-thia-Michael Addition Process." ChemInform 43, no. 48 (November 8, 2012): no. http://dx.doi.org/10.1002/chin.201248066.

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30

Riadi, Yassine, Rachid Mamouni, Younes Abrouki, Mohammadine El Haddad, Nabil Saffaj, Said El Antri, Sylvain Routier, Gerald Guillaumet, and Said Lazar. "Animal Bone Meal (ABM): A Novel Natural Catalyst for Thia-Michael Addition." Letters in Organic Chemistry 7, no. 3 (April 1, 2010): 269–71. http://dx.doi.org/10.2174/157017810791112397.

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31

Huang, Hsin‐Yi, and Chien‐Fu Liang. "Sequential Ytterbium(III) Triflate Catalyzed One‐Pot Three‐Component Thia‐Michael Addition." Asian Journal of Organic Chemistry 7, no. 5 (April 10, 2018): 955–63. http://dx.doi.org/10.1002/ajoc.201800087.

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32

Rai, Vijai K., and Rahul K. Kosta. "One-pot cis-selective route to sugar-fused thiazines via a masking–unmasking strategy in basic ionic liquid." Canadian Journal of Chemistry 94, no. 10 (October 2016): 827–32. http://dx.doi.org/10.1139/cjc-2016-0155.

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A novel sequential Knoevenagel condensation, thia-Michael, and amino/mercaptoacetylative ring transformation reaction cascade for cis-selective synthesis of sugar-fused 1,3-thiazine is reported. The expeditious one-pot multicomponent annulation was performed using masked amino acid viz. 2-phenyl-1,3-oxazol-5-one or masked mercaptoacid viz. 2-methyl-2-phenyl-1,3-oxathiolan-5-one, d-xylose/d-glucose, and N-aryldithiocarbamic acid in ionic liquid [bmim]OH. The acetophenone obtained as a by-product and [bmim]OH itself could be easily recycled for further use without loss of efficiency. The envisaged method is operationally simple, high yielding, and excellent diastereoselective in favor of the cis-isomer of fused thiazines.
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33

Guerre, Marc, Bruno Ameduri, and Vincent Ladmiral. "One-pot synthesis of poly(vinylidene fluoride) methacrylate macromonomers via thia-Michael addition." Polymer Chemistry 7, no. 2 (2016): 441–50. http://dx.doi.org/10.1039/c5py01651g.

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34

Azizi, Najmedin, Zahra Yadollahy, and Amin Rahimzadeh-Oskooee. "An atom-economic and odorless thia-Michael addition in a deep eutectic solvent." Tetrahedron Letters 55, no. 10 (March 2014): 1722–25. http://dx.doi.org/10.1016/j.tetlet.2014.01.104.

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35

Lin, Ya-mei, Guo-ping Lu, Chun Cai, and Wen-bin Yi. "ChemInform Abstract: An Odorless Thia-Michael Addition Using Bunte Salts as Thiol Surrogates." ChemInform 46, no. 32 (July 24, 2015): no. http://dx.doi.org/10.1002/chin.201532066.

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36

Boynton, Nicholas R., Joseph M. Dennis, Neil D. Dolinski, Charlie A. Lindberg, Anthony P. Kotula, Garrett L. Grocke, Stephanie L. Vivod, Joseph L. Lenhart, Shrayesh N. Patel, and Stuart J. Rowan. "Accessing pluripotent materials through tempering of dynamic covalent polymer networks." Science 383, no. 6682 (February 2, 2024): 545–51. http://dx.doi.org/10.1126/science.adi5009.

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Pluripotency, which is defined as a system not fixed as to its developmental potentialities, is typically associated with biology and stem cells. Inspired by this concept, we report synthetic polymers that act as a single “pluripotent” feedstock and can be differentiated into a range of materials that exhibit different mechanical properties, from hard and brittle to soft and extensible. To achieve this, we have exploited dynamic covalent networks that contain labile, dynamic thia-Michael bonds, whose extent of bonding can be thermally modulated and retained through tempering, akin to the process used in metallurgy. In addition, we show that the shape memory behavior of these materials can be tailored through tempering and that these materials can be patterned to spatially control mechanical properties.
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37

Hartwig, Daniela, José E. R. Nascimento, Luana Bettanin, Thalita F. B. Aquino, Raquel G. Jacob, and Eder J. Lenardão. "Deep Eutectic Solvents: An Alternative Medium for the Preparation of Organosulfur Compounds." Current Green Chemistry 7, no. 2 (September 21, 2020): 179–200. http://dx.doi.org/10.2174/2213346107999200616110434.

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Deep Eutectic Solvent (DES) as a “green solvent” has been used as an alternative to replace Volatile Organic Compounds (VOCs) and traditional Ionic Liquids (ILs). In recent years, DES has gained much attention due to its excellent properties such as low cost, easy preparation, high viscosity, low vapor pressure, low volatility, high thermal stability, biodegradability and non-toxicity, among others. Other classes of compounds with increased interest are organosulfur compounds due to their applicability as synthetic intermediates in organic reactions and their high importance in pharmaceutical and agrochemical industries. This review describes the recent advances in the preparation of organosulfur compounds using DES as an alternative solvent, focusing on several types of organic reactions, including aromatic substitution reactions (SNAr), condensation, cyclocondensation, cyclization, ring-opening, thia-Michael addition, one-pot reactions and heterocyclodehydrations.
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38

Kumar, Varun, Rangan Mitra, Sanjay Bhattarai, and Vipin A. Nair. "Reaction on Water: A Greener Approach for the Thia Michael Addition onN-Aryl Maleimides." Synthetic Communications 41, no. 3 (January 25, 2011): 392–404. http://dx.doi.org/10.1080/00397910903576651.

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39

Azizi, Najmodin, Alireza Khajeh-Amiri, Hossein Ghafuri, and Mohammad Bolourtchian. "A highly efficient, operationally simple and selective thia-Michael addition under solvent-free condition." Green Chemistry Letters and Reviews 2, no. 1 (March 2009): 43–46. http://dx.doi.org/10.1080/17518250902998103.

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40

Anguo, Ying, Bai Linsheng, Hou Hailiang, Xu Songlin, Lu Xiaotong, and Wang Limin. "Research on Thia-Michael Addition Tandem Reactions Catalyzed by AlCl3@MNPs." Chinese Journal of Organic Chemistry 42, no. 11 (2022): 3843. http://dx.doi.org/10.6023/cjoc202205008.

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41

Tang, Jie, Dan Qian Xu, Ai Bao Xia, Yi Feng Wang, Jun Rong Jiang, Shu Ping Luo, and Zhen Yuan Xu. "An Organocatalytic Domino Thia-Michael/Aldol Condensation Reaction: Highly Enantioselective Synthesis of Functionalized Dihydrothiophenes." Advanced Synthesis & Catalysis 352, no. 13 (September 7, 2010): 2121–26. http://dx.doi.org/10.1002/adsc.201000245.

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42

Riadi, Yassine, Rachid Mamouni, Younes Abrouki, Mohammadine El Haddad, Nabil Saffaj, Said El Antri, Sylvain Routier, Gerald Guillaumet, and Said Lazar. "ChemInform Abstract: Animal Bone Meal (ABM): A Novel Natural Catalyst for Thia-Michael Addition." ChemInform 41, no. 39 (September 2, 2010): no. http://dx.doi.org/10.1002/chin.201039101.

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43

Kowalczyk, Rafał, and Przemysław J. Boratyński. "Stereoselective thia-Michael 1,4-Addition to Acyclic 2,4-Dienones and 2-En-4-ynones." Advanced Synthesis & Catalysis 358, no. 8 (March 2, 2016): 1289–95. http://dx.doi.org/10.1002/adsc.201501138.

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44

Sano, Shigeki, Michiyasu Nakao, Munehisa Toguchi, Ken Horikoshi, and Syuji Kitaike. "Synthesis of Novel 2,3-Disubstituted Thiophenes via Tandem Thia-Michael/Aldol Reaction of Allenyl Esters." HETEROCYCLES 104, no. 2 (2022): 379. http://dx.doi.org/10.3987/com-21-14575.

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45

Fruhmann, Philipp, Theresa Weigl-Pollack, Hannes Mikula, Gerlinde Wiesenberger, Gerhard Adam, Elisabeth Varga, Franz Berthiller, Rudolf Krska, Christian Hametner, and Johannes Fröhlich. "Methylthiodeoxynivalenol (MTD): insight into the chemistry, structure and toxicity of thia-Michael adducts of trichothecenes." Organic & Biomolecular Chemistry 12, no. 28 (2014): 5144. http://dx.doi.org/10.1039/c4ob00458b.

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46

Abrouki, Younes. "Response Surface Methodology for the Optimization of Thia-Michael Addition Reaction Catalyzed by Doped Fluorapatite." Open Journal of Advanced Materials Research 1, no. 2 (2013): 29. http://dx.doi.org/10.12966/ojamr.08.03.2013.

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47

Nicponski, Daniel, and Jennifer Marchi. "Selectivity Reversal during Thia-Michael Additions Using Tetrabutylammonium Hydroxide: Operationally Simple and Extremely High Turnover." Synthesis 46, no. 13 (April 11, 2014): 1725–30. http://dx.doi.org/10.1055/s-0033-1341106.

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48

Giacobazzi, Greta, Claudio Gioia, Martino Colonna, and Annamaria Celli. "Thia-Michael Reaction for a Thermostable Itaconic-Based Monomer and the Synthesis of Functionalized Biopolyesters." ACS Sustainable Chemistry & Engineering 7, no. 5 (February 8, 2019): 5553–59. http://dx.doi.org/10.1021/acssuschemeng.9b00063.

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49

Lauzon, Samuel, Hoda Keipour, Vincent Gandon, and Thierry Ollevier. "Asymmetric FeII-Catalyzed Thia-Michael Addition Reaction to α,β-Unsaturated Oxazolidin-2-one Derivatives." Organic Letters 19, no. 23 (November 20, 2017): 6324–27. http://dx.doi.org/10.1021/acs.orglett.7b03118.

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50

Nakao, Michiyasu, Munehisa Toguchi, Yuki Shimabukuro, and Shigeki Sano. "Tandem thia-Michael/Dieckmann condensation of allenyl esters for the regioselective synthesis of trisubstituted thiophenes." Tetrahedron Letters 61, no. 36 (September 2020): 152271. http://dx.doi.org/10.1016/j.tetlet.2020.152271.

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