Dissertations / Theses on the topic 'Surface stress'

An introduction to surface structure and plane wave density functional theory (DFT) is presented along with theoretical studies of seven adsorbate systems. A new energetically favourable structure of low symmetry is found for furan on Pd(111) that is entirely consistent with previous experimental findings from scanned-energy mode photoelectron diffraction (PhD). In addition, it is found that the C3H3 decomposition product of furan on the same surface is likely to be adsorbed in a propargyle conformation (CH-C-CH2) although some cooccupation of the molecule in a half benzene conformation (CH-CH-CH) is also possible. Methoxy is found to adsorb at local short bridge sites only on Cu(110), occupying locations both above the clean surface and above pairs of surface Cu adatoms. Simulated scanning tunneling microscope (STM) images of the (5×2) reconstruction are found to be in qualitative agreement with previous images recorded experimentally. The experimentally determined local structure of cytosine on the same surface is confirmed and models are proposed for the (6×6) reconstruction. An increased tensile surface stress is found to be associated with the Ir(001)(1×1) ! Ir(001)(5×1)-hex phase transition, thus confirming that the reconstruction is not a consequence of the large surface stress of bulk terminated Ir(001). In contrast, H adsorption on Ir(001) (5×1)-hex does lead to a reduction of the surface stress in the range 1.76-2.06 Nm−1 for a H coverage range 0.6-0.8 ML in excellent agreement with the experimentally-determined value of 1.7 Nm−1. The energetically favourable structure for methanethiolate adsorption on Cu(100) is found to be a c(6×2) missing row structure that allows effective relief of surface stress. On Cu(111) several complex overlayer models for methanethiolate adsorption have similar associated surface energy, suggesting that the local structure is dependent on the availability of Cu adatoms. For adsorption on both surfaces, agreement with previous STM images and MEIS results is discussed.

Electrochemically-induced changes in surface stress at the solid-liquid interface are measured using a differential cantilever-based sensor. The simultaneous, in situ measurements of the current (charge) and interfacial stress changes are performed by employing an AFM cantilever as both the working electrode (in a conventional three-probe electrochemical cell configuration) and as the mechanical transducer (bending of the cantilever). The custom-built instrument achieves a surface stress sensitivity of 1x10-4 N/m and a dynamic range of 5x105. Combining electrochemistry with cantilever-based sensing provides the extra surface characterization capability essential for the interpretation of the origin of the surface stress.
The objective of the present study is to gain a better understanding of the mechanisms responsible for the nanomechanical motion of cantilever sensors during adsorption and absorption processes. The study of these simple model systems will lead to a general understanding of the cantilever-based sensor's response and provide insights into the physical origin of the measured surface stress.
The surface stress generated by the electrochemically-controlled absorption of ions into a thin polypyrrole film is investigated. A compressive change in surface stress of about -2 N/m is measured when the polymer is electrochemically switched between its oxidized and neutral (swollen) state. The volume change of the polymer phase with respect to the gold-coated cantilever is shown to be responsible for the mechanical motion observed.
The potential-induced surface stress and surface energy change on an Au(111)-textured cantilever, in a 0.1 M HClO4 electrolyte, are simultaneously measured. These measurements revealed that for solid electrodes these two thermodynamic parameters are significantly different. In the double layer region, a surface stress change of -0.55 +/-0.06 N/m is measured during ClO4- adsorption whereas the surface energy variation is smaller by one order of magnitude. The origin of the surface stress change at the metal-electrolyte interface is understood by the variation in electron density at the surface which alters the inter-atomic bonds strength between surface atoms, while the specificity of adsorption of ions is found to be mostly responsible for the fine structure of the surface stress profile.

Purpose of this work is to provide a comprehensive picture of thin film (interconnect) and solid droplet surface evolution under the several external applied forces with anisotropic physical properties so that one can eventually be able to predict main reasons and conditions under which stability of surface is defined. A systematic study based on the self-consistent dynamical simulations is presented for the spontaneous surface evolution of an thin film and isolated thin solid droplet on a rigid substrate, which is driven by the surface drift diffusion induced by the anisotropic diffusivity, the anisotropic capillary forces (surface stiffness) and mismatch stresses under electron winding. The effect of surface free energy anisotropies (weak and strong (anomalous)) on the development kinetics of the Stranski-Krastanow island type morphology are studied. Although, various tilt angles and anisotropy constants were considered during simulations, the main emphasis was given on the effect of rotational symmetries associated with the surface Helmholtz free energy topography in 2D space. The investigations of dynamics of surface roughness on concurrent actions of the appliedelasto- and electro- static fields clearly indicate that applied misfit stress level is highly important effect on resultant surface form which may be smooth wave like or crack like. The droplet simulations revealed the formation of an extremely thin wetting layer during the development of the bell-shaped Stranski-Krastanow island through the mass accumulation at the central region of the droplet via surface drift-diffusion. The developments in the peak height, in the extension of in the wetting layer beyond the domain boundaries, and the change in triple junction contact angle, one clearly observes that these quantities are reaching certain saturation limits or plateaus, when the growth mode turned-off. Islanding differences for weak anisotropy constant levels and the strong (anomalous) anisotropy constant domains are discussed.

A series of experiments was performed in an attempt to measure the effects of surface residual stresses on the stress corrosion cracking/hydrogen embrittlement (SCC/HE) behavior of AISI 4340 steel. Stress corrosion tests were performed under load control on cylindrical and notched tensile specimens in acidified 3.5% NaCl solution. The electrochemical potential of the specimens was maintained at -0.7 V versus a saturated calomel reference electrode. Time to failure for specimens tested at various applied and residual stress levels was measured. Stress relieved specimens as well as specimens containing mechanically induced residual stresses were tested. Residual stresses were estimated using Neuber's rule and were measured using an x-ray diffraction technique. In all cases, the sum of the applied and residual stresses was greater than zero. Test results showed the initiation of SCC/HE cracks to be insensitive to the effects of surface residual stresses under the conditions evaluated. This is probably a result of the total time to failure criterion used to evaluate the SCC/HE tests. The extremely aggressive environment used in these experiments apparently led to rapid crack initiation, even in specimens containing compressive residual stresses. Another possible explanation of the insensitivity of this series of tests is crack initiation in the interior of the specimens below the depth of the mechanically induced residual stresses.
Master of Science

The surface stress induced during the formation of alkanethiol [HS(CH 2)nCH3] self-assembled monolayers (SAMs) on gold from the vapor phase was measured using a differential cantilever-based sensor. This custom-built system is capable of surface stress measurements with a sensitivity of 5 x 10-5 N/m using commercially-available atomic force microscopy cantilevers. A second system combining cantilever-based sensing and ellipsometry was also designed and built, capable of yielding simultaneous in situ surface stress and film thickness measurements. Scanning tunneling microscopy (STM) with molecular resolution was also performed ex situ in order to characterize the structure of the resulting SAMs. The complementary use of these tools has provided an all-around view of the self-assembly process.
These measurements were performed in order to gain insight into the mechanisms involved in the self-assembly process and into the origins of the associated surface stress. Moreover, these studies were used to characterize and optimize the response of cantilever-based sensors based on functionalized SAM technology in terms of reliability, sensitivity, and reproducibility.
The evolution of the surface stress induced during alkanethiol SAM formation reveals features associated with coverage-dependent structural phase transitions. These results show that both the kinetics of SAM formation and the resulting SAM structure are strongly influenced by the surface structure of the underlying gold substrate, by the impingement rate of the alkanethiol molecules onto the gold surface, and by the cleanliness of the gold surface. In particular, it was found that a minimum gold grain size is necessary in order for the SAM to achieve the standing-up phase, for which large compressive surface stresses (~10 N/m) are measured. In addition, these results show that alkanethiol SAMs can become kinetically trapped in metastable intermediate states (lying-down phase) for formation on small-grained gold surfaces and/or at low alkanethiol vapor concentrations. Theoretical modeling of the origins of the induced surface stress reveals that inter-molecular Lennard-Jones interactions and electrostatic repulsion between adsorbed species play minimal roles in the development of the surface stress. Changes in the electronic structure of the underlying gold substrate are more likely to account for the large compressive surface stresses observed during alkanethiol SAM formation.

Residual stress exists in most structures and although it has been recognised for a long time, its complex mechanism and characteristics are still being intensively studied. Residual stress can be stratified into damaging residual stress and beneficial residual stress. Surface tensile residual stresses are generally known to reduce the mechanical properties of materials while compressive residual stresses improve the fatigue performance of components. This Ph.D. thesis reports the analytical and experimental work conducted to investigate both the damaging and beneficial effects of residual stress on fatigue crack growth in structural components. The detrimental effect of tensile residual stresses is studied through large scale fatigue testing of T-butt welded plates fabricated from High Strength Steels (HSS). Despite the growing use of HSSs in the offshore industry, the fatigue performance and corrosion resistance of welded joints made from such steels are still not clear. Due to their complex metallurgy and relatively poor weldability, there is still a lack of understanding of the residual stresses that arise from the welding process. This study involved modification and development conducted on a variable amplitude (VA) load-time sequence generator for the investigation of long life fatigue performance of HSS. Emphasis was given to the generation of a stationary load-time history and numerous analyses were presented to demonstrate the importance of the long term statistical nature of the load-time sequence on fatigue testing. Fatigue test results obtained were extensively compared with previous HSS corrosion fatigue studies. The effect of tensile residual stress on fatigue crack growth was investigated using a SIF weight function-based fatigue crack growth model. Two newly developed preferential cold working techniques termed stitch cold rolling and stitch shot peening were explored to investigate the beneficial effect of surface compressive residual stress on fatigue crack growth in mild steel plates. One of the main objectives of this study was to control the fatigue crack shape by the manipulation of surface residual stress fields. The stitch cold rolling technique was implemented using a custom-built cold rolling jig. The feasibility of preferential cold working techniques was further investigated by the fatigue testing of stitch shot peened specimens. Both experimental programmes yielded unprecedented fatigue crack growth results. A residual stress monitoring programme was conducted to study the residual stress relaxation behaviour under cyclic loading. The experimental test results enabled the investigation of SIF solutions in non-uniform stress fields. A novel fatigue crack growth evolution model, which takes into account residual stress relaxation effects, was developed using the powerful SIF weight function methods.

Three models for surface stress loading effect on a micromechanical cantilever are proposed as concentrated moment acting at the free end (Model I), concentrated moment plus axial force acting at the free end (Model II), and uniformly distributed surface force acting along the microcantilever (Model III). Solution to Model I loading is based on the Stoney formula, assuming that the microcantilever is subjected to pure bending and deformed with a constant curvature. Model II takes into account the clamping effect in such a way that an additional axial force is introduced. The deflections resulting from Models I and II surface stress loading effect are solved by Euler-Bernoulli beam theory. In Model III, the effect of surface stress is modeled as uniformly distributed surface force that causes both uniformly distributed bending moment and axial force acting along the axis of the microcantilever. The energy method is then used to obtain the governing equation and boundary conditions for Model III displacement. Comparison of the results obtained by the three models with those by the finite element method and experiment indicates that Model III is the most realistic model for surface stress loading effect to obtain the deflection of a microcantilever.

Model III for surface stress loading effect is then used to demonstrate the applications of a microcantilever in sensor technology through the measurement of tip deflection under an atomic adsorption as the source of surface stress. Dual attractive or repulsive characteristics of interactions between a pair of mercury atoms are described in terms of Lennard-Jones potential. The force per unit atomic spacing induced by the adjacent free surface atoms of a monolayer is then computed using the potential. The sensitivities of atomic spacing and monolayer thickness to the tip-deflection of a microcantilever are studied in this research.
Master of Science

Les phénomènes de mouillage et la rhéologie des fluides à seuil sont deux domaines de la physique des matériaux mous dans lesquels de grandes avancées ont été faites lors des derniers siècles. De plus ces questions sont d'une grande importance au niveau des applications industrielles, ce qui contribue à leur dynamisme. En revanche, le mouillage des fluides à seuil a été peu étudié, alors que c'est une situation fréquente. En effet, presque tous les fluides rencontrés dans l'industrie et la vie quotidienne sont des fluides à seuil. D'autre part, la connaissance des propriétés de mouillage est cruciale lors de leur manipulation car la plupart des processus font intervenir des interfaces.Dans ma thèse, je m'intéresse aux questions suivantes : comment la tension de surface apparente est-elle affectée par le seuil ? Comment le seuil influence-t-il la dynamique du mouillage, habituellement décrite par la loi de Tanner ? Pourquoi l'angle de contact d'une goutte de fluide à seuil n'est-il pas prédit par la loi d'Young-Dupré ?J'ai réalisé des expériences sur un fluide à seuil modèle appelé carbopol. La première expérience a consisté à mesurer la force d'adhésion d'un pont capillaire, qui a été comparée au cas des fluides simples. Les résultats ont montré l'importance de l'histoire de la déformation et de l'élasticité du fluide. La seconde expérience a porté sur l'étalement de gouttes sur une surface hydrophile. J'ai étudié la dynamique d'étalement, ainsi que l'angle de contact final. Alors que la dynamique est contrôlée par la viscoélasticité, l'état final est déterminé par le seuil
Wetting phenomena and yield-stress fluids rheology are subfields of soft matter physics where big understanding steps have been made during the last centuries. In addition, these two fields have very important potential implications for industry, which contributes to their dynamism. But their combination, the wetting of yield-stress fluids, has received little interest until the very last years, although it is a situation that happens all the time. Indeed, yield-stress fluids gather nearly all the fluids encountered in food industry, cosmetics, building industry, oil and gas industry… and wetting properties are crucial when processing or using the fluids, as many processes involve interfaces with air or a solid surface.In this thesis, I consider the following questions: how is the apparent surface tension affected by yield stress? How does the yield stress influence the wetting dynamics, classically described by Tanner’s law? Why can the final contact angle of a sessile drop of yield-stress fluid not be predicted by Young-Dupré’s theory?I performed experiments with a model yield-stress fluid called carbopol. The first experiment consisted in measuring the adhesion force of a capillary bridge and comparing it to the case of simple fluids. The main results show the importance of the deformation history and of the fluid elasticity. The second main experiment concerned spreading of drops on a hydrophilic surface. I studied the short-time dynamics and the long-time dynamics, as well as the final contact angle. The first regime is controlled by viscoelasticity, whereas the final state is determined by the yield stress

Micropitting is a contact initiated fatigue failure on the scale of surface roughness features that occurs in lubricated concentrated contacts which are subject to combined sliding and rolling motion. It is a significant problem in hardened and ground gears which, due to the surface roughness, operate in a micro-elastohydrodynamic lubrication (micro-EHL) regime, causing cyclic loads as the roughness features interact. To gain a much clearer understanding of the failure mechanism that is associated with rough surface elastohydrodynamic lubrication (EHL), a full theoretical model of the lubrication of gear contacts under rough surface and micro-EHL conditions is presented in this thesis. In addition, the study offers some important insights in to the influence of residual stresses on the fatigue life of rough surfaces. This significant residual stress, resulting from plastic deformation of rough surface asperities during the initial running-in process, has been instrumental in our understanding of the micropitting phenomenon. The Abaqus FEA package has been used to perform a full elastic-plastic contact analysis of real rough surfaces using profiles taken from the surfaces of unrun test disks, which are used in micropitting tests. The analysis provides a detailed view of the plastic deformation, and the magnitude and distribution of the residual stress fields at the asperity level. The residual geometry and stress field obtained over a range of applied loads are then used to introduce the residual stress in elastic fatigue calculations based on Micro-EHL simulations. Fatigue damage and fatigue life is then obtained at the scale of the surface roughness asperities by using multiaxial and variable amplitude fatigue models based on a critical plane approach. The results obtained allow the effects of the residual stress due to running-in to be quantified. The analysis method is also applied to test disk experiments to compare the predicted fatigue life with the observed onset of micropitting.

Two methods for the measurement of micro-scale stressvariations of press felt surfaces were developed. The methodswere based on a thin plastic film that was coated with anopaque stress-sensitive layer (Cronapress conversion film). Thefilm was compressed between a felt and a smooth surface. Uponapplication of load the opaque layer became partiallytransparent at the locations where load was applied by thesurface fibres of the felt. The degree of transparency was afunction of the locally applied stress. The spatial resolutionof the method was 6.3 µm, which means that even details ofthe order of the diameter of a batt fibre diameter can beresolved.

Parameters characterising the stress variations were used toquantitatively describe the extent of the stress variations,the size of the contact areas and the distance between them.The applicability of these contact characterisation parameterswas evaluated in laboratory wet pressing experiments and inpilot paper machine trials for two sets of specially designedpress felts. In general, the dewatering result was mainlyinfluenced by the diameter of the felt surface batt fibres andby the web grammage. For a specific pulp type and operatingconditions a multivariate model was formulated based on themeasured web dryness, web grammage and each contactcharacterisation parameter. The model was able to describe thedewatering capability of the different felts tested. Contactcharacterisation parameters related to contact properties (e.g.contact area ratio) gave the best prediction for low grammagewebs, while parameters related to flow properties (e.g. size ofopenings) gave the best prediction for high grammage webs.

Furthermore it was found that at a certain web grammage, thesurface batt fibre diameter did not have an influence on thedewatering result. This grammage was termed "transitiongrammage". Below the transition grammage a fine surface gavesignificantly better dewatering, while the opposite trend wasobserved above the transition grammage. Based on these results,a modified dewatering hypothesis was formulated. Thishypothesis links the non-uniform compression of the wet webwith different dewatering situations for low and high grammagewebs.

KeywordsPress felts, Roughness, Smoothness, SurfaceStructure, Uniformity, Wet pressing, Batt fibre, Base weave,Stress variations, Micro-scale.

Thesis (Ph. D.)--West Virginia University, 2006.
Title from document title page. Document formatted into pages; contains xiii, 105 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 97-98).

The aim of this thesis is to investigate how material surfaces are affected by various surface treatments and how this relates to the adhesion of the coating. The materials that were studied were WC-Co and Cermets and the surface treatments used were polishing, grinding with coarser and finer abrasive grains, and finally wet blasting and dry blasting. Focus was on deformations and residual stresses in the surface, surface roughness and cracks. The test methods used for examining the samples included surface roughness measurements, residual stress measurements, adhesion tests using Rockwell indentation and SEM images of the surface and the cross section.

The results concluded that polishing gives very good adhesion. Additionally, the adhesion for ground surfaces was good for WC-Co but very poor for Cermets. Furthermore, it was observed that finer abrasive grains did not result in better adhesion. In fact, the coarser grains gave slightly better results. Finally, it was concluded that wet blasting has a clear advantage over dry blasting and results in much better adhesion, especially for the Cermets. The results for the WC-Co were a bit inconsistent and so further research is required.

Defective alkanethiol monolayers were studied as a model system to understand the stress changes observed in microcantilever-based DNA hybridization experiments. An exponential relationship between defect density and surface stress was found by performing simultaneous electrochemical/stress-sensing experiments. Microcantilevers with a range of defective alkylthiol self assembled monolayers were prepared and stress change/electrochemical data were collected in perchlorate, chloride, and bromide-containing electrolytes. Defects were probed using a ferrocene-thiol labeling technique which provides quantitative measurement of defect area. Using defects and solutions containing charge transferring adsorbates is suggested as a method for enhancing the surface stress signals in cantilever sensor systems. The best response from this study was obtained in bromide, as its exponential function had the sharpest increase with defect density.

The use of an ocean surface velocity dependent wind stress is examined in the context of a 3-layer double-gyre quasigeostrophic wind-driven ocean circulation model. The new wind stress formulation results in a large reduction of the power input by the wind into the oceanic circulation. This wind stress is proportional to a quadratic function of Ua--u o, where Ua is the wind at 10m above the ocean surface and uo is the ocean surface current. Because the winds are typically faster than the ocean currents, the impact of the ocean surface velocity on the wind stress itself is relatively small. However, the power input is found to be greatly reduced with the new formulation. This is shown by simple scaling argument and numerical simulations in a square basin. Our results suggest that the wind power input may be as much as 35% smaller than is typically assumed.
The ocean current signature is clearly visible in the scatterometer-derived wind stress fields. We argue that because the actual ocean velocity differs from the modeled ocean velocities, care must be taken in directly applying scatterometer-derived wind stress products to the ocean circulation models. This is not to say that the scatterometer-derived wind stress is not useful. Clearly the great spatial and temporal coverage make these data sets invaluable. Our point is that it is better to separate the atmospheric and oceanic contribution to the stresses.
Finally, the new wind stress decreases the sensitivity of the solution to the (poorly known) bottom friction coefficient. The dependence of the circulation strength on different values of bottom friction is examined under the standard and the new wind stress forcing for two topographic configurations. A flat bottom and a meridional ridge case are studied. In the flat bottom case, the new wind stress leads to a significant reduction of the sensitivity to the bottom friction parameter, implying that inertial runaway occurs for smaller values of bottom friction coefficient. The ridge case also gives similar results. In the case of the ridge and the new wind stress formulation, no real inertial runaway regime has been found over the range of parameters explored.

An experimental study was conducted to explore the possible application of dynamically actuated nanowires to effectively disturb the wall layer in fully developed, turbulent channel flow. Actuated nanowires have the potential to be used for the mixing and filtering of chemicals, enhancing convective heat transfer and reducing drag. The first experimental evidence is presented suggesting it is possible to manipulate and subsequently control turbulent flow structures with active nanowires. An array of rigid, ultra-long (40 μm) TiO2 nanowires was fabricated and installed in the bounding wall of turbulent channel flow then oscillated using an attached piezoelectric actuator. Flow velocity and variance measurements were taken using a single sensor hot-wire with results indicating the nanowire array significantly influenced the flow by increasing the turbulent kinetic energy through the entire wall layer.

The heat transfer coefficients in even relatively simple components varies significantly at different points on the surface. Although this has been known for some time the amount of work which has been done is limited to the relationship between these variable thermal conditions and the generation of stress and strain during the quench. The object of the work was to investigate the relationship between the variables using standard quenchants. The variation in the surface heat transfer coefficients has been determined at points along the horizontal and vertical axes of a stainless steel plate and upper and lower surface of a plate held vertically and horizontally in water. Photographic studies of the appearance of the quenchant in contact with the surface of the plate have been carried out in conjunction with the horizontal and vertical quenches which are mentioned above. The data obtained have been used in the determination of the variation in stress and strain generated in the plate during the quench by involving a 2-D finite element analysis using the PAFEC package.

Laser cladding is a process that is used to improve the properties of a metal surface. The properties in question may include hardness, wear-, corrosion- and/or fatigue-resistance. The process involves fusing a thin layer of additional metal to the original surface, using a laser as the heat source. Unfortunately, residual stresses are generated due to the rapid and highly localised thermal expansion and contraction that occur during the heating-melting-solidification-cooling cycle. These residual stresses can have a detrimental effect on the final performance of the clad component, especially with respect to corrosion resistance. Detrimental tensile residual stresses can be mitigated through the use of post-processing techniques such as laser shock peening (LSP). LSP is a process that uses a pulsed laser to generate intense spots of recoil pressure on a surface, thereby introducing compressive residual stresses. Post weld heat treatment (PWHT) is another process that could be also used in laser cladding in order to relieve tensile residual stresses. In this work, laser cladding was carried out by depositing a clad layer of AISI grade 316L stainless steel on to either a S275 steel substrate or an AISI grade 316L stainless steel substrate, using different process parameters. The hardness and residual stresses in the overlay and substrate were assessed for each laser clad sample before and after being treated with LSP and PWHT. The corrosion rate and microstructure were also assessed in each case. The novelty of this work is two-fold. Firstly, to the author's knowledge, it is the first study that attempts to link process parameters to both the residual stresses and the corrosion performance of austenitic stainless steel overlays deposited by laser cladding. The second novel aspect is based on the application of both LSP and PWHT to the deposited overlay in order to investigate whether an improvement in the mechanical properties and the corrosion resistance can be realised. In this study, tensile residual stresses were generated in the clad layers. However, the magnitude of the residual stresses did not appear to be particularly sensitive to the deposition parameters. Indeed, it was found that the number of layers that is deposited is more important than the choice of process parameters. LSP was effective in reducing the tensile residual stresses and in fact it introduced compressive stresses to all the samples that were treated. In contrast, PWHT only led to satisfactory stress relief when the AISI grade 316L stainless steel was deposited on to a matching substrate material. This was related to the fact that a difference between the thermal expansion coefficients of the overlay and substrate led to the development of significant tensile residual stresses on cooling down after PWHT. The corrosion tests on the clad coupons led to the development of pits and cracks. However, after LSP only pits were found, without any sign of cracking, for the test durations that were investigated owing to the fact that compressive stresses were generated. Similar results were found after PWHT for the clad samples in which the overlay material matched the substrate material. However, signs of cracking were observed after PWHT in samples where AISI grade 316L stainless steel was deposited on to an S275 steel substrate due to tensile residual stresses remaining within the overlay. This result suggests that there may be little benefit in carrying out PWHT for components in which grade 316L stainless steel is deposited on to a steel substrate. In contrast, there appear to be clear benefits associated with carrying out LSP in order to mitigate the residual stresses and retard the onset of cracking.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Um sistema de medição e controle foi desenvolvido para o estudo de respostas fisiológicas de aves sujeitas a mudanças térmicas como meio de alívio de estresse térmico. O sistema faz o controle automático da temperatura (t a,SP ±0,2 oC) e da umidade relativa do ar (RH SP ±2 %); sendo que a velocidade do ar foi controlada manualmente (V SP ±0,1 m· s -1 ); e contínuo armazenamento das termografias (ex., temperatura superficial, t surf ) e da temperatura corporais (t b ) dos animais. As condições térmicas controladas na zona de ocupação animal (AZO) são atingidas pela operação de um pequeno túnel de vento (V = 0 to 1,5 m· s -1 ) colocado no interior de uma sala ambiental com t a e RH controlados (5,0 m comprimento × 3,5 m largura × 3,0 m altura). Os valores desejados de t a e RH foram alcançados por meio de aquecedores e umidificadores controlados em dois estágios via um módulo de controle e medição programável, e periféricos. Termografias (discernabilidade de 0.06°C) são adquiridas com uma camera infravermelho cuja operação é controlada remotamente por um PC. t b (±0.1°C) é armazenado em uma unidade de telemetria, sem a necessidade de intervenção cirurgica, que também é conectado a um PC. Em adição, um sistema de video tem sido usado para observar e arquivar os comportamentos do animal. A instrumentação desenvolvida foi usada em um experimento para ajustar equações empíricas para descrever as necessidades de molhamento parcial da superfície em galinhas poedeiras (Hy-Line W98, com 34 ± 1 semanas) sujeitas a condições de estresse térmico. A água necessária para limitar o aumento da temperatura superficial das galinhas foi expressada em termos de intervalo de aspersão (SI 10 , min) para uma dosagem constante (10 ml· aspersão -1 ) ou para uma taxa de evaporação (ER, ml.min -1 ) de água aspergida. As exposições térmicas consistiram de uma combinação fatorial de 3 temperaturas de bulbo seco (t db ) (35, 38 e 41 °C) x 2 temperaturas de ponto de orvalho (t dp ) (21,1 e 26,7 °C) x 3 velocidades do ar (V) (0,2, 0,7 e 1,2 m· s -1 ). As condições ambientais foram expressas como 18 combinações de déficit de vapor de pressão do ar (VPD air ) x V. ER foi diretamente proporcional ao produto VPD air · V . As relações podem servir como a base para a otimizar o sistema de resfriamento superficial intermitente para alívio de estresse térmico em galinhas criadas em gaiolas. Ademais, um índice de desconforto térmico (TDI) foi derivado com base nas respostas fisiológicas, temperatura superficial (t surf ) e temperatura corporal (t b ), de galinhas sujeitas a exposições térmicas. Com base no aumento da t b aos 50 min de exposição térmica (Δt b,50 ), um TDI foi relacionado ao VPD air e a V da seguinte forma: TDI = -15.17 + 18.62 (t db ) n – 0.92 · (VPD air · V ) n . Usando TDI, quatro zonas de desconforto térmico (segura, alerta, perigo e fatal) foram definidas para as várias combinações de condições térmicas. Um modelo teórico de transferência de calor e massa em regime transiente também foi proposto para predizer Δt b,50 em função das condições ambientais, das condições fisiológicas das aves e do nível de molhamento (β). O modelo proporciona uma ferramenta conveniente e interativa para determinar Δt b,50 nas galinhas submetidas ou não ao molhamento superficial para t db variando de 35 a 38 °C.
A control and measurement system was developed for studying physiological responses of poultry to thermal challenges and means of thermal stress relief. The system features automatic control of air temperature (t a,SP ±0.2 oC) and relative humidity (RH SP ± 2 %); manual setting of air velocity (V SP ± 0.1 m· s -1 ); and continuous recording of thermographs (i.e., core body temperature (t b ) of the animal. surface temperature, t surf ) and The controlled thermal conditions in the animal-occupied zone (AOZ) are achieved through operation of a small wind tunnel (V = 0 to 1.5 m· s -1 ) inside a t a - and RH-controlled environmental room (5 m L × 3.5 m W × 3.0 m H). Target t a and RH values are achieved by controlling auxiliary heaters and humidifiers in two stages via a programmable measurement and control module and peripherals. Thermographs (0.06°C discernability) are acquired with an infrared (IR) imager whose operation is remotely controlled by a PC. Core body temperature (t b , ±0.1°C) is recorded with a surgery-free telemetric sensing unit that is also interfaced with a PC. In addition, a video monitoring system is used to observe and archive animal behaviors. The instrumentation developed was used in an experiment to establish empirical equations to describe the need of partial surface wetting for cooling laying hens (Hy-Line W-98, 34 ±1 wk old) subjected to a range of thermal stress conditions. The thermal exposures consisted of a factorial combination of 3 dry bulb temperatures (t db ) (35, 38 and 41 °C) × 2 dew point temperatures (t dp ) (21.1 and 26.7 ° C) × 3 air velocities (V) (0.2, 0.7 and 1.2 m· s - ). The environmental conditions were expressed as 18 combinations of air vapor pressure deficit (VPD air ) × V. The water necessary to limit hen surface temperature from rising was expressed in terms of sprinkle interval (SI 10 , min) for a constant spray dosage (10 ml· spray -1 ) or evaporation rate (ER, ml· min -1 ) of the sprayed water. ER was directly proportional to VPD air · V . The relationships may serve as the basis for optimizing an intermittent partial surface cooling system for thermal stress relief of caged layers. Also from the study, a thermal discomfort index (TDI) was derived based on physiological responses, surface temperature (t surf ) and core body temperature (t b ) of the control (non-cooled) hens. Based on t b rise after 50 min of thermal exposure (Δt b,50 ), TDI related to VPD air and V as: TDI = -15.17 + 18.62 (t db ) n – 0.92· (VPD air · was V ) n . Using TDI, four zones of thermal discomfort (safe, alert, danger, and fatal) were defined for various combinations of thermal conditions. Furthermore, theoretical transient heat and mass transfer model was proposed to predict Δt b,50 as a function of environmental conditions, physiological responses of the hens and surface wetness level (β). The model provides a convenient, interactive tool for determining Δt b,50 on wetted and non-wetted hens for t db ranging from 35 to 38 °C.

A study of the stability of bicontinuous nanoporous metals is presented. Atomic scale simulations are used to probe the dominant mechanisms of geometric relaxation in these materials. A method is presented for generating model bicontinuous metal / void structures for use in atomistic simulations of bicontinuous nanoporous solids. The structures are generated with periodic boundary conditions using a phase-field model to simulate the spinodal decomposition of an ideal system. One phase in the model is then associated with the pore volume while the other phase is associated with the metal ligaments. Small angle neutron scattering was used to quantitatively compare experimental samples to those generated by the phase field method. EAM results using model structures with experimentally accessible length scales are presented which demonstrate the potential of such simulations in understanding the behavior of nanoporous metals. Simulated relaxations of these structures, as well as the relaxation of model spherical clusters, indicate that the surface relaxation effect dominates the overall dimensional relaxation of np-metals post processing. Capillary effects play a secondary role in the overall relaxation. The simulation results presented also identify a maximum surface area to volume ratio necessary to maintain mechanical stability beyond which the pore structure collapses.
Ph. D.

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2017.
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 153-161).
Gallium Nitride (GaN) belongs to a class of materials called wide band-gap semiconductors. In recent years, the versatile nature of this material has been exploited for a wide range of applications from solid state lighting to RF and microwave communication, as well as high power switching. The first part of this thesis discusses planar AlGaN/GaN transistors. GaN is a piezoelectric material, and changes in mechanical stress result in a change in the charge density which in turn affects the maximum current in AlGaN/GaN transistors. Finite element modelling techniques were applied to quantify the mechanical stress distribution in planar AlGaN/GaN RF transistors resulting from device fabrication, and operation in the on- and off-state. Thereafter, two important surface and interface effects were studied in this thesis. In the first one, the impact of surface cleanings, surface treatments and plasma-based dry etch conditions on two different types of ohmic contact technologies was investigated. Contact resistance measurements were correlated with surface characterization results. The second was that of interface positive charges at the Al₂O₃-GaN interface and the increase in electron density in the device resulting from them. In both these problems, a combination of device electrical measurements and material characterization techniques was used to establish direct correlations between device behavior and material properties. The second part of the thesis deals exclusively with nano-ribbon (NR) or fin-like AlGaN/GaN transistors. Fundamental transport properties of charge density and mobility in NR devices were studied in order to understand the difference in behavior of these devices from planar devices. The influence of passivation films on the charge density in these structures was investigated, using Al₂O₃ passivation as a specific example. Electron mobility degradation due to sidewall-scattering in NR devices was quantified using different mobility extraction methods based on device measurements. The thesis concludes with a potential application of NR AlGaN/GaN transistors for high linearity power amplification. A new kind of transistor with varying threshold voltages along the gate width is proposed to improve the DC and RF linearity of GaN-based devices.
by Sameer Jayanta Joglekar.
Ph. D.

An analytical model on the size and fraction dependent thermal conductivity, elastic modulus and thermal stress of nanowire-composites are developed, and the theoretical prediction agrees with the experimental results of Si nanowires. And the model proposes that the high thermal shock strength of ceramics can be achieved by surface nanostructurization, which is related to the low thermal conductivity and thermal stress of the nanostructures and voids. The theory will be helpful to guide design of thermal barrier coatings. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/34880

The aim of this thesis is to investigate the effects of bulging and deep drawing processes on St4 cold rolled steel by simulation and experimental characterization. In the simulations, commercial software programs MSC Marc and Simufact.forming were used. The experimental studies cover metallographic investigations, hardness measurements, and residual stress measurements. Residual stress measurements were carried out by different non- destructive characterization methods
X-ray diffraction and Magnetic Barkhausen Noise. The experimental and simulation results were correlated with each other.

Previous studies have shown that soil erodibility and critical shear stress are highly influenced by weathering processes such as freeze-thaw cycling and wet-dry cycling. Despite over forty years of research attributing changes in soil properties over time to climate-dependent variables, little quantitative information is available on the relationships between streambank erodibility and critical shear stress and environmental conditions and processes that enhance streambank erosion potential. The goal of this study was to investigate temporal changes in streambank erodibility and critical shear stress due to surface weathering. Soil erodibility and critical shear stress were measured monthly in situ using a multi-angle submerged jet test device. Environmental and soil data were also collected directly at the streambank surface to determine freeze-thaw cycles, soil moisture, soil temperature, bulk density, soil erodibility, critical shear stress, and other atmospheric conditions that could impact bank erosion potential. Statistical tests, including a nonparametric alternative to ANOVA and multiple comparison tests, were used to determine if temporal changes in soil erosion potential were greater than spatial differences. Regression analyses were also utilized to identify the factors contributing to possible changes in soil erodibility, critical shear stress, and bulk density. The nonparametric alternative to ANOVA in combination with Dunnâ s nonparametric multiple comparison test showed soil erodibility was significantly higher (p=0.024) during the winter (November - March) and the spring/fall (April - May, September - October). Regression analyses showed 70 percent of soil erodibility variance was attributed to freeze-thaw cycling alone. Study results also indicated that bulk density is highly influenced by climate changes since gravimetric water content and freeze-thaw cycles combined explain as much as 86 percent of the variance in bulk density measurements. Results of this study show significant amounts of variation in the resistance of streambank soils to fluvial erosion can be attributed to subaerial processes, specifically changes in soil moisture and temperature. These results have potential implications for streambank modeling and restoration projects that assume constant values for soil erodibility. Watershed models and restoration designs should consider the implications of changing soil erodibility during the year in model development and stream restoration designs.
Master of Science

Word processed copy.
Includes bibliographical references.
In this work, the effect of krypton implantation on the morphology of titanium samples is investigated through scanning electron microscopy (SEM). Rutherford backscattering spectrometry (RBS) was also used to determine the dose and depth of implanted krypton. The krypton profiile in titanium, and the associated damage profile, was modelled with TRIM calculations. In addition, metallurgical techniques were also used to examine the microstructure details of the as-received, unimplanted titanium sample.

The objective of this thesis project was to compare the stress behaviour in thermal barrier coatings (TBCs) with FE analyses in both 2D and 3D. The main focus was to analyse the vertical stresses in the topcoat (TC) and how they varied in relation to different thicknesses of the thermally grown oxide (TGO), spraying methods of the bondcoat (BC) and the topography of the BC. For the 2D simulations six samples were used; three with BCs sprayed with high-velocity oxy-fuel spraying and three sprayed with atmospheric plasma spraying. The samples had been exposed to isothermal heat treatment at 1150 °C for 0, 100 and 200 hours. Five images of each sample were taken with a scanning electron microscope, resulting in a total of 30 images. FE simulations based on these 30 images were done simulating a cooling from 1100 °C to 100 °C. The 3D simulations were based on surfaces created from coordinates measured with stripe projection technique on three samples consisting of only substrate and BC. Three domains of each sample had been measured and three CAD models based on randomly selected surfaces of each domain were made, resulting in 27 CAD models. The CAD models were used in the 3D FE simulations also simulating a cooling from 1100 °C to 100 °C. The results showed that the 2D simulations corresponds to published assertions about a stress inversion after TGO growth and that cracking will propagate from one peak to another, presuming the roughness of the TGO can be expressed as a wave. No conclusions of differences between spraying methods of the BC could be drawn. The stress inversion phenomenon was also found in the 3D simulations. By inspecting the TGO/TC-interface profile in different sections of a 3D model, difficulties in predicting the stress behaviour in a TBC with 2D were explained. No differences in stresses in relation to the BC roughness could be stated.

The prediction of settlements in infrastructural design puts high demands on the numerical analysis of the subsoil and the associated constitutive model: complex installation processes and the repetitive character of live loads pose considerable challenges. Although in this context the main focus is on the analytical requirements of a geotechnical problem in order to realistically capture soil behaviour, the needs of engineering practice should not be neglected in constitutive modelling. Along these lines, a new soil model for non-cohesive soils has been developed in the theoretical framework of elastoplasticity. Based on the concept of bounding surface plasticity according to Manzari and Dafalias (1997), soil properties such as strength, stiffness and dilatancy depend on the distance between the current stress state and a corresponding model surface in stress space. This way the multi surface model correctly reproduces elementary behavioural patterns of soil, including for example shear related phenomena such as hardening/softening, contraction/dilation and attainment of critical state (constant volume shear strength). Moreover, the model captures the state dependence of soil behaviour (barotropy and pycnotropy). Thus, with only one set of material parameters, the mechanical behaviour of a wide range of initial soil states with respect to stress and void ratio can be simulated (unified modelling). The kinematic hardening mechanism of the conical yield surface contributes to a realistic stiffness evolution in un- and reloading and is hence essential for stress or strain accumulation due to load reversals. Since the chosen modelling framework is suitable for further development, the original formulation has been extended to adapt the model to the defined needs. In order to adequately simulate geotechnically relevant stress paths of low and higher complexity, first of all, a cap shaped yield surface was added to allow for plastic straining not only in shear, but also in constant stress ratio loading (e. g. isotropic or oedometric compression). When it comes to stress paths of unconventional orientation, to load reversals or composed stress paths with changes in loading direction, a supplementary stiffness increase at small strains and its subsequent strain dependent degradation have proven valuable. Furthermore, an additional mechanism accounts for a regressive accumulation of stresses or strains with increasing number of load cycles (in terms of dissipated energy). In view of its suitability for practical use, all model extensions are structured in a modular fashion, so that the complexity of the model (and hence the amount of parameters) can be adapted to the complexity of the geotechnical problem by activating or deactivating certain features. Most model parameters can be determined by conventional laboratory testing. An internal routine optionally facilitates the parameter choice by calibrating certain bounding surface related parameters from an alternative user input, which is more oriented towards experimental outcome. Since a good understanding of a material model is crucial for its reasonable and responsible use, the present thesis aims at offering a sound documentation. Thus, the first part gives an outline of the underlying bounding surface concept and describes the innovations on the constitutive level with reference to theoretical considerations. It is followed by a detailed analysis of capabilities and limitations of the extended model. The next part is dedicated to the numerical implementation of the soil model and its calibration procedure on the basis of laboratory test results. Moreover, the embedded calibration routine including the applied optimisation algorithm is presented. The subsequent section serves model validation: by means of element test simulations, generation of response envelopes as well as the reproduction of more general (e. g. composed) stress paths the performance of the extended bounding surface model is demonstrated. Finally, the last chapter draws conclusions and discloses potential future perspectives.:1 Introduction 1.1 General aspects on constitutive modelling 1.2 Motivation and outline of the thesis 1.3 Basic assumptions and terminology 2 Literature review 2.1 From elastoplasticity to bounding surface plasticity 2.1.1 Bounding surface model according to Manzari and Dafalias (1997) 2.2 Further development of the original model 2.2.1 Papadimitriou and Bouckovalas (2002) 2.2.2 Taiebat and Dafalias (2008) 2.3 Small strain stiffness 2.3.1 Observations 2.3.2 Micromechanical considerations 2.3.3 Very small strain shear modulus G0 2.3.4 Constitutive modelling approaches 2.4 Dilatancy 3 The extended bounding surface model 3.1 Fundamental capabilities of the bounding surface concept 3.1.1 Elastic region 3.1.2 Critical state 3.1.3 Shear strength 3.1.4 Shear stiffness (monotonic) 3.1.5 Contractancy and dilatancy 3.1.6 Barotropy and pycnotropy 3.1.7 Compressive stiffness 3.1.8 Shear stiffness in reversed loading 3.1.9 Additional features 3.2 New features of the extended bounding surface model 3.2.1 Minor modifications 3.2.2 Dilatancy formulation 3.2.3 Cap yield surface 3.2.4 Small strain stiffness mechanism 3.2.5 Cyclic loading mechanism 3.2.6 Summary 3.3 Limitations of the bounding surface model 3.3.1 Intrinsic insuffciencies of the bounding surface concept 3.3.2 Remaining shortcomings of the advanced model version 3.3.3 Newly introduced deficiencies 4 The numerical model and its calibration procedure 4.1 Octave implementation of an element test programme 4.2 Calibration procedure 4.2.1 Sands for calibration 4.2.2 Calibration of basic parameters 4.2.3 Calibration of extended model parameters 4.3 User friendly calibration routine 4.3.1 Conceptual background 4.3.2 Optimisation algorithm 5 Performance of the extended bounding surface model 5.1 Model performance in element tests 5.1.1 Monotonic drained triaxial compression test 5.1.2 Monotonic undrained triaxial compression test 5.1.3 Monotonic eta-constant tests 5.2 Model performance in non-standard triaxial testing 5.2.1 Concept of response envelopes 5.2.2 Simulation of response envelopes 5.3 Model performance on general stress paths 5.3.1 Triaxial compression at small strains 5.3.2 Cyclic triaxial loading 6 Conclusions and perspectives 6.1 Conclusions 6.2 Future perspectives Bibliography Appendices A Mathematical background A.1 Fundamental equations of elastoplasticity A.2 Compilation of major constitutive equations (multiaxial formulation) A.3 Elastoplastic stiffness matrix for singular yield surfaces A.4 Coefficient matrices S and E for loading constraints A.5 Derivation of Mcap and Hcap A.6 Intergranular strain adjustment A.7 Intergranular strain correlation B Details on particle swarm optimisation C Compilation of simulation results C.1 Monotonic triaxial loading C.1.1 Toyoura sand C.1.2 Sacramento River sand C.1.3 Hostun sand C.2 Monotonic eta-constant loading C.2.1 Sacramento River sand C.2.2 Hostun sand C.3 Cyclic triaxial loading
Die Prognose von Setzungen für die Bemessung von Infrastrukturbauwerken stellt hohe Anforderungen an die numerische Untersuchung des Baugrunds und das damit verbundene Stoffgesetz: komplexe Herstellungsprozesse und zyklisch wiederkehrende Verkehrslasten stellen beachtliche Herausforderungen dar. Während das Hauptaugenmerk zumeist auf der realitätsnahen Abbildung des Bodenverhaltens liegt und damit die analytischen Anforderungen des geotechnischen Problems im Fokus stehen, sollten die Bedürfnisse der Ingenieurspraxis in der Stoffgesetzmodellierung nicht außer Acht gelassen werden. In diesem Sinne wurde im Rahmen der Elastoplastizität ein neues Materialmodell für nichtbindige Böden entwickelt. Auf dem Konzept der Bounding Surface Plastizität nach Manzari und Dafalias (1997) beruhend, sind Eigenschaften wie Festigkeit, Steifigkeit und Dilatanz Funktion des Abstands zwischen aktuellem Spannungszustand und einer zugeordneten Modellfläche im Spannungsraum. Auf diese Weise bildet das Mehrflächenmodell fundamentale Verhaltensmuster von Boden korrekt ab, einschließlich beispielsweise scherbezogener Phänomene wie Ver- und Entfestigung, Kontraktanz und Dilatanz oder das Erreichen des kritischen Zustands (Scherfestigkeit bei konstantem Volumen). Des Weiteren erfasst das Modell die Zustandsabhängigkeit des Bodenverhaltens (Barotropie und Pyknotropie). So kann mit nur einem Parametersatz das mechanische Verhalten einer großen Spannweite unterschiedlicher Anfangszustände hinsichtlich Spannung und Lagerungsdichte simuliert werden. Der kinematische Verfestigungsmechanismus der konusförmigen Fließfläche trägt bei Ent- und Wiederbelastungen zu einer realistischeren Steifigkeitsentwicklung bei und ist damit von essenzieller Bedeutung für die Akkumulation von Spannungen oder Verformungen infolge von Lastwechseln. Da sich der gewählte konstitutive Rahmen für Weiterentwicklungen eignet, wurde die ursprüngliche Formulierung des Stoffgesetzes erweitert, um das Modell an die definierten Anforderungen anzupassen. Um geotechnisch relevante Spannungspfade niedriger und höherer Komplexität adäquat reproduzieren zu können, wurde zunächst eine kappenförmige Fließfläche ergänzt. So können irreversible Verformungen nicht nur bei Scherung, sondern auch bei Belastungen ohne Änderung des Spannungsverhältnisses, wie z. B. bei isotroper oder ödometrischer Kompression, auftreten. Bei Spannungspfaden ungewöhnlicher Orientierung, bei Lastwechseln oder zusammengesetzten Spannungspfaden mit Änderung der Belastungsrichtung hat sich eine erhöhte Steifigkeit bei kleinen Dehnungen mit anschließendem dehnungsabhängigen Abfall als nützlich erwiesen. Darüber hinaus berücksichtigt ein zusätzlicher Mechanismus die rückläufige Akkumulation von Spannung oder Verformung mit zunehmender Zyklenanzahl (mittels dissipierter Energie). Im Hinblick auf die Eignung des Stoffgesetzes für die Praxis ist das Modell modular aufgebaut. So kann die Komplexität des Modells (und damit die Anzahl der Parameter) durch Ein- und Ausschalten bestimmter Erweiterungen an die Komplexität des geotechnischen Problems angepasst werden. Die Mehrzahl der Modellparameter wird mit Hilfe konventioneller Laborversuche bestimmt. Eine interne Routine erleichtert durch die Kalibrierung bestimmter Bounding Surface bezogener Größen anhand eines alternativen, stärker an Versuchsergebnissen orientierten User-Inputs bei Bedarf die Parameterwahl. Da die Kenntnis eines Stoffgesetzes entscheidend ist für dessen vernünftigen und verantwortungsvollen Einsatz, soll die vorliegende Arbeit eine fundierte und umfassende Dokumentation bieten. Der erste Teil vermittelt daher zunächst einen Überblick über das zugrunde liegende Bounding Surface Konzept und beschreibt die Neuerungen auf konstitutiver Ebene mit Bezug auf theoretische Hintergründe. Er wird gefolgt von einer detaillierten Darlegung von Potenzialen und Einschränkungen für die Nutzung des erweiterten Modells. Der nächste Abschnitt widmet sich der numerischen Implementierung des Stoffgesetzes und seiner Kalibrierung auf Basis von Versuchsergebnissen. Des Weiteren wird die Kalibrierungsroutine einschließlich des verwendeten Optimierungsalgorithmus präsentiert. Der nachfolgende Teil dient der Modellvalidierung: durch die Simulation von Elementversuchen, die Erzeugung von Antwortellipsen sowie die Abbildung allgemeinerer (beispielsweise zusammengesetzter) Spannungspfade wird die Leistungsfähigkeit des erweiterten Bounding Surface Modells demonstriert. Abschließend werden Schlussfolgerungen gezogen und potenzielle Perspektiven aufgezeigt.:1 Introduction 1.1 General aspects on constitutive modelling 1.2 Motivation and outline of the thesis 1.3 Basic assumptions and terminology 2 Literature review 2.1 From elastoplasticity to bounding surface plasticity 2.1.1 Bounding surface model according to Manzari and Dafalias (1997) 2.2 Further development of the original model 2.2.1 Papadimitriou and Bouckovalas (2002) 2.2.2 Taiebat and Dafalias (2008) 2.3 Small strain stiffness 2.3.1 Observations 2.3.2 Micromechanical considerations 2.3.3 Very small strain shear modulus G0 2.3.4 Constitutive modelling approaches 2.4 Dilatancy 3 The extended bounding surface model 3.1 Fundamental capabilities of the bounding surface concept 3.1.1 Elastic region 3.1.2 Critical state 3.1.3 Shear strength 3.1.4 Shear stiffness (monotonic) 3.1.5 Contractancy and dilatancy 3.1.6 Barotropy and pycnotropy 3.1.7 Compressive stiffness 3.1.8 Shear stiffness in reversed loading 3.1.9 Additional features 3.2 New features of the extended bounding surface model 3.2.1 Minor modifications 3.2.2 Dilatancy formulation 3.2.3 Cap yield surface 3.2.4 Small strain stiffness mechanism 3.2.5 Cyclic loading mechanism 3.2.6 Summary 3.3 Limitations of the bounding surface model 3.3.1 Intrinsic insuffciencies of the bounding surface concept 3.3.2 Remaining shortcomings of the advanced model version 3.3.3 Newly introduced deficiencies 4 The numerical model and its calibration procedure 4.1 Octave implementation of an element test programme 4.2 Calibration procedure 4.2.1 Sands for calibration 4.2.2 Calibration of basic parameters 4.2.3 Calibration of extended model parameters 4.3 User friendly calibration routine 4.3.1 Conceptual background 4.3.2 Optimisation algorithm 5 Performance of the extended bounding surface model 5.1 Model performance in element tests 5.1.1 Monotonic drained triaxial compression test 5.1.2 Monotonic undrained triaxial compression test 5.1.3 Monotonic eta-constant tests 5.2 Model performance in non-standard triaxial testing 5.2.1 Concept of response envelopes 5.2.2 Simulation of response envelopes 5.3 Model performance on general stress paths 5.3.1 Triaxial compression at small strains 5.3.2 Cyclic triaxial loading 6 Conclusions and perspectives 6.1 Conclusions 6.2 Future perspectives Bibliography Appendices A Mathematical background A.1 Fundamental equations of elastoplasticity A.2 Compilation of major constitutive equations (multiaxial formulation) A.3 Elastoplastic stiffness matrix for singular yield surfaces A.4 Coefficient matrices S and E for loading constraints A.5 Derivation of Mcap and Hcap A.6 Intergranular strain adjustment A.7 Intergranular strain correlation B Details on particle swarm optimisation C Compilation of simulation results C.1 Monotonic triaxial loading C.1.1 Toyoura sand C.1.2 Sacramento River sand C.1.3 Hostun sand C.2 Monotonic eta-constant loading C.2.1 Sacramento River sand C.2.2 Hostun sand C.3 Cyclic triaxial loading

Ester liquids including natural ester and synthetic ester are considered as potential substitutes for mineral oil, due to their good biodegradability and high fire points. Although these liquids have been widely used in distribution and traction transformers, research efforts are required for the purposes of design and manufacture of high voltage and large power transformers which are filled by esters. Indeed, it would be risky to apply esters in large power transformers without thorough understandings of their behaviours in large gaps and/or when combined with pressboard insulation. Therefore, investigations of creepage discharges along the surface of pressboard in esters are vitally important and their behaviours should be compared with those of mineral oils. This thesis is aimed to investigate the creepage discharges along pressboard in esters and mineral oil under ac divergent electric field. Apparent charges, current signals and images of streamer channels were obtained synchronously to identify whether and how the introduction of pressboard surface would influence the inception and propagation of discharges as compared to tests in open gap. When over-stressed by higher voltages, the surface tracking along the pressboard-ester interface, triggered by sustaining creepage discharges, was studied and the evolutions of accompanying creepage discharge patterns were investigated. In these experiments, both esters and mineral oil impregnated pressboards were comparatively studied. The test results indicated that at the inception stage, the presence of pressboard or any other solid types in different liquids under test do not influence the PD inception voltages; in the propagation stage, solid surface tends to promote the development of discharges, especially those occurring in negative half cycles, and shifts more discharges towards the zero-crossing phase angles. This discharge promotion effect is much more evident in esters than in mineral oil, probably because of higher discharge intensity in esters and higher viscosity of esters. The space charge effect and the residual low density channel effect are proved as the mechanisms best explaining the influences of solids on creepage discharges. Under higher voltages, it was found that the impregnated pressboard is susceptible to discharge erosion characterized by “white and carbonized tree-shaped marks”, due to intense discharges occurring on or near the pressboard surface. The “white mark” appears at a lower voltage and propagates more easily on ester impregnated pressboard. The gaseous “white mark” channels will attract the subsequent discharges to follow the same discharge routes; the accumulative energy dissipation in these channels will then result in the carbonization of the channels. Once formed, the surface tree-shaped mark can continue to grow even under reduced voltage levels until it bridges the gap and causes the final flashover.

Surface integrity is of great significance in grinding performance since grinding process is often used as a finishing step. For metallic materials, residual stresses play an important role in surface integrity for its strong effect on fatigue life, corrosion resistance, and part distortion. For ceramic materials, the surface damage induced by grinding process could greatly affect the mechanical strength and surface finish of the component. The functional behavior of machined components can be enhanced or impaired by the grinding process. Because of this, understanding the surface integrity imparted by grinding is very important. The use of fluid is common in grinding process, however, the high cost and environmental impact of the conventional flood cooling is very undesirable. The minimum quantity lubrication (MQL) have been introduced in industry for about two decades as a promising alternative to conventional flood cooling for economical and environmental advantages. A comprehensive understanding of the MQL effect on the process performances and surface integrity is of great value to the implementation of MQL technique in industrial situation. Grinding-induced residual stress prediction has been a topic of research since the 1970’s while the studies of MQL grinding is still on the early stage with experimental investigations. A comprehensive study and quantitative description of MQL effect on the residual stress generation in grinding is highly demanded. On the other hand, although there has been significant research in the area of surface damage in ceramic grinding, there are still opportunities for advancing predictive methods. Therefore, the objectives of the current research are set as follows: (1) develop a method of predicting residual stress based on an analytical description of the grinding process under MQL condition, (2) develop a method of predicting surface finish and damage in ceramic grinding, and (3) validate the model with experimental data. The research will first focus on predicting residual stresses in MQL grinding based on first principles. This includes predictive models of grinding forces, and grinding temperature stemmed from grinding kinematics and dynamics principles as part of the overall modeling effort. The effect of MQL on both lubrication and cooling aspects has been integrated into these models. The mechanical and thermal output parameters will serve as the basis for determining the loading history which generate residual stresses. The research will also aim at surface roughness modeling in ceramic grinding. A ductile-brittle mixed surface generation is predicted based on the nature of ceramic materials and grinding kinematics. The crack system developed from indentation fracture mechanics approach will be utilized in evaluating the brittle mode surface generation. The modeling techniques will be applied to a range of grinding conditions and materials. This research would aid in evaluating various surface integrities in grinding of metallic and ceramic materials with little experimental efforts. The output could be used to machine these materials effectively to order to improve the functionality of the component.

ABSTRACT A review of annual monitoring reports for stream restoration projects on surface coal mines in the central Appalachian Mountains found that the criteria used for judging the success of the projects was generally based on visual assessments of habitat structure which were evaluated using the Rapid Bioassessment Protocol (RBP) (Palmer and Hondula, 2014). In recent years the Hydrogeomorphic Approach (HGM), which was originally developed to evaluate wetlands, has been adapted for stream evaluations as well (Summers, et al., 2017). Both of these methods are primarily a means to determine if suitable habitat structure and riparian growth are present to support aquatic life. It is assumed that if habitat structure is suitable then macroinvertebrate and other life will be present. However, each of these two methods place emphasis on different aspects of habitat and riparian structure. The primary purpose of this project is to compare and contrast how effective these two methods are at evaluating reconstructed streams on surface coal mines. A secondary objective is to determine if macroinvertebrate assemblages in reconstructed streams is significantly different from that of reference streams not impacted by mining. Research on benthic community structure downstream of coal mining activities suggests that even after many decades taxa richness and abundance still have not recovered from indirect impacts (Petty, et al., 2010). Information on reconstructed streams directly impacted is lacking. This project evaluates streams that were reconstructed five years prior using the RBP and HGM methods, and compares them to local reference streams that have minimal to no mining impacts. Multiple benthic metrics are also used to evaluate community structure. REFERENCES Petty, J. Todd, Jennifer B. Fulton, Michael P. Strager, George T. Merovich Jr., James M. Stiles, and Paul F. Ziemkiewicz. 2010. Lanscape indicators and thresholds of stream ecological impairment in an intensely mined Appalachian watershed. Journal of the North American Benthological Society, 29(4): 1292-1309. Palmer, Margaret A., and Kelly L. Hondula. 2014. Restoration as mitigation: analysis of stream mitigation for coal mining impacts in southern Appalachia. Environmental Science and Technology 48: 10552-10560. Summers, Elizabeth A., Chris V. Noble, Jacob F. berkowitz, and Frank J. Spilker. 2017. Operational Draft Regional Guidebook for the Functional Assessment of High-Gradient Headwater Streams and Low-Gradient Perennial Streams in Appalachia. ERDC/EL TR-17-1.