Relevant bibliographies by topics / Supramolecular organic chemistry

Academic literature on the topic 'Supramolecular organic chemistry'

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Published: 10 December 2022
Last updated: 28 January 2023

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Journal articles on the topic "Supramolecular organic chemistry"

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Sherburn, Michael. "Introduction to Supramolecular Chemistry By Helena Dodziuk." Australian Journal of Chemistry 55, no. 5 (2002): 357. http://dx.doi.org/10.1071/ch02004_br.

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Introduction to Supramolecular ChemistryBy Helena DodziukKluwer Academic Publishers, The Netherlands.December 2001, 364 pp.ISBN 1402002149Hardcover, 82.00 GBP.Introduction to Supramolecular Chemistry by Dr Helena Dodziuk of the Institute of Physical Chemistry, Polish Academy of Sciences, is a broad summary of chemical aspects of supramolecular science. * Dr Michael Sherburn is a senior lecturer in organic chemistry at the School of Chemistry, the University of Sydney.
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Bose, Anima, and Prasenjit Mal. "Mechanochemistry of supramolecules." Beilstein Journal of Organic Chemistry 15 (April 12, 2019): 881–900. http://dx.doi.org/10.3762/bjoc.15.86.

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The urge to use alternative energy sources has gained significant attention in the eye of chemists in recent years. Solution-based traditional syntheses are extremely useful, although they are often associated with certain disadvantages like generation of waste as by-products, use of large quantities of solvents which causes environmental hazard, etc. Contrastingly, achieving syntheses through mechanochemical methods are generally time-saving, environmentally friendly and more economical. This review is written to shed some light on supramolecular chemistry and the synthesis of various supramolecules through mechanochemistry.
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Hr. "Supramolecular Chemistry." Journal of Molecular Structure 274 (November 1992): 315. http://dx.doi.org/10.1016/0022-2860(92)80171-d.

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Serpe, Michael J., and Stephen L. Craig. "Physical Organic Chemistry of Supramolecular Polymers." Langmuir 23, no. 4 (February 2007): 1626–34. http://dx.doi.org/10.1021/la0621416.

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Gasparini, Giulio, Eun-Kyoung Bang, Javier Montenegro, and Stefan Matile. "Cellular uptake: lessons from supramolecular organic chemistry." Chemical Communications 51, no. 52 (2015): 10389–402. http://dx.doi.org/10.1039/c5cc03472h.

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Jolliffe, Katrina (Kate) A., and Philip A. Gale. "The supramolecular chemistry of anions." Organic & Biomolecular Chemistry 20, no. 4 (2022): 713–14. http://dx.doi.org/10.1039/d1ob90183d.

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Haino, Takeharu, Ryo Sekiya, Kentaro Harada, and Natsumi Nitta. "Resorcinarene-Based Supramolecular Capsules: Supramolecular Functions and Applications." Synlett 33, no. 06 (October 27, 2021): 518–30. http://dx.doi.org/10.1055/a-1679-8141.

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AbstractA resorcinarene is a synthetic macrocycle consisting of four resorcinol molecules covalently linked by methylene bridges. The interannular bridges produce a cavitand that has a bowl-shaped structure. We have developed supramolecular capsules through Ag(I) or Cu(I) coordination-driven self-assembly of cavitands possessing 2,2′-bipyridyl arms in their upper rims. The self-assembled capsules accommodate various molecular guests and supramolecular assemblies possessing acetoxy groups. The host–guest chemistry of the molecular capsules has been applied in the fabrication of supramolecular polymers. This account describes recent developments in the supramolecular chemistry of resorcinarene-based coordination capsules and provides a brief history of resorcinarene-based capsules and related capsules.
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Saji, Viswanathan S. "Supramolecular concepts and approaches in corrosion and biofouling prevention." Corrosion Reviews 37, no. 3 (June 26, 2019): 187–230. http://dx.doi.org/10.1515/corrrev-2018-0105.

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AbstractSupramolecular chemistry is one of the exciting branches of chemistry where non-covalent interactions between molecules and the ensuing supramolecular structures have been studied for various applications. The present review provides a comprehensive outlook on the applications and potentials of supramolecular chemistry in corrosion and biofouling prevention. Reported works associating supramolecular chemistry with corrosion are systematically discussed under two sections: (i) surface coatings and (ii) corrosion inhibitors that include supramolecular polymers, host-guest inclusion compounds, organic-inorganic hybrid materials, and supramolecular structures of graphene, crown ethers, self-assembled monolayers, etc. Different strategies for making antifouling surfaces based on block copolymers/gel systems, host-guest systems, and metal-organic structures are briefed. Cyclodextrin and mesoporous silica-based host-guest systems are extensively discussed, as they are the most prominent materials of current research interest. Future potentials for developments are presented. The review is expected to be beneficial to enhance supramolecular chemistry-related research and development in corrosion and biofouling prevention.
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Haino, Takeharu. "Supramolecular Chemistry: From Host-guest Complexes to Supramolecular Polymers." Journal of Synthetic Organic Chemistry, Japan 71, no. 11 (2013): 1172–81. http://dx.doi.org/10.5059/yukigoseikyokaishi.71.1172.

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Li, Zhan-Ting. "Supramolecular chemistry: from aromatic foldamers to solution-phase supramolecular organic frameworks." Beilstein Journal of Organic Chemistry 11 (November 2, 2015): 2057–71. http://dx.doi.org/10.3762/bjoc.11.222.

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This mini-review covers the growth, education, career, and research activities of the author. In particular, the developments of various folded, helical and extended secondary structures from aromatic backbones driven by different noncovalent forces (including hydrogen bonding, donor–acceptor, solvophobicity, and dimerization of conjugated radical cations) and solution-phase supramolecular organic frameworks driven by hydrophobically initiated aromatic stacking in the cavity of cucurbit[8]uril (CB[8]) are highlighted.
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Dissertations / Theses on the topic "Supramolecular organic chemistry"

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Skabara, Peter John. "Functionalised tetrathiafulvalenes in supramolecular chemistry." Thesis, Durham University, 1994. http://etheses.dur.ac.uk/10491/.

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Using a range of functionalised tetrathiafulvalene (TTF) derivatives, developed at Durham, the first examples of covalently linked TTF-ferrocene systems have been prepared. The redox properties of these molecules, as studied by cyclic voltammetry, provide evidence that these species are efficient π-electron donors. Highly reactive 1,3-dithiole Wittig and Wittig-Homer reagents have been used in the synthesis of complex mixed redox-active systems containing ferrocenyl units. A series of [3]- and [4]-dendralenes has also been developed from this synthetic methodology. Cyclic voltammetry shows that tri- and tetracationic states can be achieved with these systems at relatively low potentials. The potential for vinyl-TTF compounds to undergo [4+2] cycloaddition has been investigated for the first time. The peripheral C=C unit of TTF, together with the adjacent vinylic substituent, is able to act as the diene functionality in Diels-Alder reactions. Remarkably, the π-delocalisation within the TTF moieties is readily disrupted by the addition of strong dienophiles. The reactivity of lithiated TTF towards aldehydes and ketones has established an array of hydroxy-functionalised TTF, bis-TTF and TTF-ferrocene derivatives. The conducting and magnetic properties of the chloranil charge transfer salt of one of these species is also reported.
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Rather, Elisabeth. "Supramolecular metal-organic and organic materials." [Tampa, Fla.] : University of South Florida, 2004. http://purl.fcla.edu/fcla/etd/SFE0000267.

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Roshandel, Sahar. "Supramolecular devices as selective receptors." Thesis, California State University, Long Beach, 2015. http://pqdtopen.proquest.com/#viewpdf?dispub=1597789.

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We have found that calixarenes are good receptors of choline (trimethylammonium group) and they have strong affinity to form host-guest complexes with a variety of molecules carrying this moiety. Furthermore, the ability of lower rim carboxylic acid calix[n]arenes and upper rim phosphonic acid functionalized calix[4]arene to transport choline-conjugated drugs through a liquid membrane was discovered. The results demonstrate that these systems are highly efficient toward transporting choline-conjugated targets, as well as neurotransmitters that possess ionizable amine termini. The breadth of compounds that are transported is significant, facing limitations only when the payloads become extremely lipophilic. These developments reveal new approaches towards attempting synthetic receptor mediated selective small molecule transport in vesicular and cellular systems.

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Sisson, Thomas Michael 1966. "Crosslinking polymerization in supramolecular assemblies." Diss., The University of Arizona, 1997. http://hdl.handle.net/10150/282566.

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Supramolecular assemblies are composed of noncovalently associated molecules which organize in water to yield 2-D and 3-D architectures. Crosslinking polymerization of supramolecular assemblies provides an effective means to modify their chemical and physical properties. Two methods of characterizing crosslinked polymeric assemblies were developed. These techniques rely on experimentally observed changes in polymer solubility and assembly stability in the presence of nonionic surfactants. The results show an inefficient crosslinking mechanism in organized media compared to isotropic polymerization. Two models rationalizing the inefficient crosslinking observed in organized media were proposed. Symmetrical crosslinking agents were synthesized to test the models. These results suggest intramolecular memorialization is an important process in the efficiency of crosslinking. The polymerization of a heterobifunctional lipid with two polymerizable groups in the same acyl chain separated by a six carbon spacer yielded a novel linear ladder-like polymer architecture. The two reactive groups are in regions of different polarity allowing for the simultaneous, selective, and sequential polymerization depending on the initiation chemistry employed. A second heterobifunctional lipid was designed and synthesized with a longer spacer between the two reactive groups. Polymerization of vesicles gave stable polymeric vesicles. The results from the crosslinking and redox polymerization studies on 2-D assemblies were applied to the inverted hexagonal and bicontinuous cubic phases. Phase behavior is characterized before and after crosslinking polymerization principally by variable temperature ³¹NMR. γ-Initiated polymerization of bis-lipids was studied to evaluate their sensitivity to ionizing radiation. The reactive moiety effects the initial rate of polymerization, extent of polymerization, and inhibition by oxygen. A preliminary investigation of polymerizable ion-paired amphiphiles (IPA) showed polymerization methods commonly used for zwitterionic lipids can be applied to IPA. This is the first report of polymerization of reactive groups in the anionic acyl chain of an ion-paired amphiphile.
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Childs, Laura Jennifer. "Supramolecular assemblies based on imine and azo chemistry." Thesis, University of Warwick, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269076.

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Young, Michael Christopher. "Self-Assembly of Functionalized Supramolecular Structures." Thesis, University of California, Riverside, 2014. http://pqdtopen.proquest.com/#viewpdf?dispub=3644049.

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Enzymes are capable of exquisite selectivity in catalysis chemical reactions because of a well-evolved mechanism that binds substrates in internal active sites based on size and shape complementarity. The cavities of these enzymes are decorated with organic or inorganic groups which can promote reactivity once the substrate is non-covalently bound. Synthetic molecular hosts to date have been able to bind to substrates in a similar, biomimetic fashion, but functionalized molecular hosts are still virtually unknown.

One convenient way to prepare molecular hosts is by the self-assembly of organic coordinating ligands with suitable metal salts. The reversible dative bonds holding these cage structures together allow incorrect products to break apart and reform, favoring creation of the most thermodynamically stable product. This leads to discrete, solution phase cages that can function as cavity-containing hosts. Some of these hosts have shown efficacy as catalysts for pericyclic reactions due to favorable transition states of the bound substrates. These cages, however, fail to orient reactive functional groups into their interiors. Truly biomimetic cages will require modifying traditional self-assembled targets to incorporate these reactive functionalities.

This work explores the self-assembly of metal-organic cages displaying covalent modifications on their interior. Incorporation of unreactive and poorly reactive groups was found to have a significant impact on the outcome of the self-assembly process. Cages with endohedral alcoholic functionality were found to have different binding properties than unfunctionalized analogs. Cages with introverted alcohol groups were also exploited for their ability to self-catalyze reactions on the interior of the hosts. The metal vertices themselves could also be used as functional groups, and showed the ability to sense neutral analytes in hybrid dative/hydrogen bonded self-assemblies.

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Lee, Youn-Sik. "Supramolecular assemblies of polymerizable phospholipids." Diss., The University of Arizona, 1992. http://hdl.handle.net/10150/185929.

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Novel polymerizable ether lipids, 1,2-O-bis[10-(2',4'-hexadienoyloxy)decyl]-rac, 1,2-O-bis(10,12-tricosadiynyl)-rac, and (S)-2,3-O-bis(10,12-tricosadiynyl)-sn-glycero-1-phosphocholine (PC), were successfully synthesized. Differential scanning calorimetry (DSC) showed that the gel to liquid crystalline phase transition of the ether lipid bilayers occurs at 11.4, 27.6, and 30.0°C (T(m)), respectively. The T(m) of the saturated analogs of the sorbyl ether and ester lipids, which were synthesized for the study of lipid phase behavior, were -15.4 and -7.5°C, respectively. The sorbyl and diacetylenic ether lipids in bilayers were readily polymerized with 254 nm light. The stability of sorbyl either lipid vesicles toward a detergent, Triton X-100, was somewhat enhanced by photopolymerization. The optically active diacetylenic ether lipid formed microtubules and helices which were observed by transmission electron and optical microscopy. Polymerizable ester lipids, 1-palmitoyl-2-(2-methylene)palmitoyl, 1,2-bis(2-methylenepalmitoyl), and 1-oleoyl-2-(2-methylene)palmitoyl PC were synthesized. The T(m) of these lipids were estimated to be 33.6, 25.3, and ∼-10°C, respectively, via DSC and X-ray diffraction. Thermal reaction of the mono-substituted lipid suspensions with a water-soluble initiator, azobis(2-amidinopropane) dihydrochloride (AAPD), yielded oligomers which were soluble in organic solvents. However, reaction of the bis-substituted ester lipid in bilayers produced cross-linked polymers which are not soluble in organic solvents. The ceiling temperature for the radical polymerization of these lipid systems appears to be near 70°C since the polymerization conversion at 60°C was greater than at 70°C. Finally, a polymerizable ester lipid, 1-oleoyl-2-(2-methylene)palmitoyl-sn-glycerol-3-phosphoethanolamine (PE) was synthesized. According to DSC and X-ray diffraction, this hydrated PE suspension undergoes the transition from the lamellar liquid crystalline to the nonlamellar inverted hexagonal (H(II)) phase at 45-50°C. This compound (T(m) = 11.6°C) is a promising candidate for future studies of the stabilization of the H(II) phase.
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Frankel, David Alan. "Supramolecular assemblies of diacetylenic amphiphiles." Diss., The University of Arizona, 1993. http://hdl.handle.net/10150/186384.

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Ever since the earliest studies, lipids have always been found in liposomal form. Recently, it was discovered that aqueous solutions of certain glycolipids, phospholipids, and glutamate lipids could form nonspherical morphologies such as tubules or helices when cooled below their liquid to gel phase transitions. We have developed new synthetic polymerizable lipids which form non-spheroidal morphologies when hydrated. The use of diacetylenes has several advantages which include facile incorporation into alkyl chains of amphiphiles, stabilization of assemblies, and the introduction of non-linear optical, and conducting properties into these assemblies. This research may also provide insight into the molecular basis of self-organization. Multistep synthesis of diacetylenic glycosurfactants was performed in which the headgroup was progressively varied by incorporation of different hepto, hexo, pento, and tetrose open chain sugars. The stereochemical, enantiomeric, and hydrophobic/hydrophilic balance of the lipids was investigated as a function of the supramolecular morphologies which they formed. Synthetic diacetylenic lipids based on a glutamic acid backbone were also prepared. These lipids formed liposomes which could be dehydrated under constant temperature and humidity to form cast films with properties similar to Langmuir-Blodgett films. These lipids could also be used as templates to order other compounds which do not otherwise form ordered assemblies. From the work we hope to gain some insight to the molecular components of lipids which are necessary to dictate specific supramolecular morphologies.
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Lin, Xiang. "The supramolecular chemistry of metal-organic coordination oligomers and polymers." Thesis, University of Nottingham, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.416395.

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Barker, Philip. "The introduction of supramolecular architectures into macromolecular arrays." Thesis, University of Warwick, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.250967.

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Books on the topic "Supramolecular organic chemistry"

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L, Atwood J., ed. Comprehensive supramolecular chemistry. Oxford: Pergamon, 1996.

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Siegel, Jay S. Supramolecular Stereochemistry. Dordrecht: Springer Netherlands, 1995.

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Tsoucaris, George. Current Challenges on Large Supramolecular Assemblies. Dordrecht: Springer Netherlands, 1999.

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L, Atwood J., Szejtli József, and Osa Tetsuo, eds. Comprehensive supramolecular chemistry. Oxford: Pergamon, 1996.

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Wipff, Georges. Computational Approaches in Supramolecular Chemistry. Dordrecht: Springer Netherlands, 1994.

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1935-, Schneider Hans-Jörg, and Dürr Heinz, eds. Frontiers in supramolecular organic chemistry and photochemistry. Weinheim, Federal Republic of Germany: VCH, 1991.

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Pifat-Mrzljak, Greta. Supramolecular Structure and Function. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986.

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K, Yatsimirsky Anatoly, ed. Principles and methods in supramolecular chemistry. New York: Wiley, 2000.

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Macrocyclic chemistry: Aspects of organic and inorganic supramolecular chemistry. Weinheim: VCH, 1993.

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Schalley, Christoph A. Analytical methods in supramolecular chemistry. Weinheim: Wiley-VCH, 2007.

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Book chapters on the topic "Supramolecular organic chemistry"

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Sun, Wei-Yin, Zheng-Shuai Bai, and Jin-Quan Yu. "Supramolecular Chemistry of Silver." In Silver in Organic Chemistry, 329–55. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470597521.ch11.

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Craig, Stephen L., and Donghua Xu. "Physical Organic Chemistry of Supramolecular Polymers." In Supramolecular Polymer Chemistry, 269–91. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527639786.ch12.

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Berscheid, R., I. Lüer, C. Seel, and F. Vögtle. "Molecules with Large Cavities -Selective Complexation of Inorganic and Organic Guests." In Supramolecular Chemistry, 71–86. Dordrecht: Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_5.

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Schoedel, Alexander, and Omar M. Yaghi. "Porosity in Metal-Organic Compounds." In Macrocyclic and Supramolecular Chemistry, 200–219. Chichester, UK: John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781119053859.ch9.

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Li, Zhan-Ting, Peter J. Stang, Liang Zhao, Mei-Xiang Wang, and Chen-Ho Tung. "Supramolecular Organic Chemistry: The Foldamer Approach." In Organic Chemistry - Breakthroughs and Perspectives, 477–535. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527664801.ch13.

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Sugiyasu, Kazunori, and Seiji Shinkai. "Supra-Macromolecular Chemistry: Toward Design of New Organic Materials from Supramolecular Standpoints." In Supramolecular Polymer Chemistry, 51–70. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527639786.ch3.

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Ariga, Katsuhiko, Gary J. Richards, Jonathan P. Hill, Ajayan Vinu, and Toshiyuki Mori. "Supramolecular Chemistry at the Mesoscale." In The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials, 11–36. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470552704.ch2.

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Vančik, Hrvoj. "Organic Supramolecular and Supermolecular Structures." In Basic Organic Chemistry for the Life Sciences, 187–96. Cham: Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-92438-6_12.

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Hathwar, Venkatesha R. "CHAPTER 5. Experimental Charge Density Analysis in Organic Solids." In Monographs in Supramolecular Chemistry, 159–88. Cambridge: Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788013086-00159.

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Aakeröy, Christer B., and Kanishka Epa. "Controlling Supramolecular Assembly Using Electronic Effects." In Electronic Effects in Organic Chemistry, 125–47. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/128_2011_155.

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Conference papers on the topic "Supramolecular organic chemistry"

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Tato, José, Mercedes Alcalde, Aida Jover, Francisco Meijide, Luciano Galantini, Nicolae Pavel, and Alvaro Antelo. "Host-Guest Supramolecular Dendrimers." In The 11th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01357.

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Antelo, Alvaro, Mercedes Alcalde, Aida Jover, Francisco Meijide, Luciano Galantini, and José Tato. "Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives." In The 12th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01270.

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Novo, Mercedes, and Wajih Al-Soufi. "Fluorescence Study of the Supramolecular Interactions between Coumarins and Serum Albumin." In The 11th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01358.

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Margetic, Davor, Douglas Butler, and Ronald Warrener. "Theoretical Study of Bis-Porphyrin-Fullerene Supramolecular Complex Designed for Photovoltaic Devices." In The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01646.

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Novo, Mercedes, Jorge Bordello, Daniel Granadero, Sonia Freire, and Wajih Al-Soufi. "Supramolecular host-guest complexes between coumarin 460 and cyclodextrins: a matter of size." In The 12th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01267.

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Isz, S., Maria-Victoria Martinez, S. Palacin, H. Perez, and A. Ruaudel-Teixier. "New molecules for supramolecular architecture in Langmuir-Blodgett films." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49435.

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Moral, M., A. de la Hoz, and A. Sánchez-Migallón. "Microwave Assisted Organic Synthesis of 1,3,5-triazine Dimmers with Their Application in Supramolecular Chemistry." In The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01638.

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Hagar, Mohamed E., and Hoda Ahmed. "Experimental and theoretical approaches of new nematogenic chair architectures of supramolecular H-bonded liquid crystals." In The 23rd International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2019. http://dx.doi.org/10.3390/ecsoc-23-06713.

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Romero, María J., Luis M. González-Barcia, Manuel R. Bermejo, M. Isabel Fernández, and Esther Gómez-Fórneas. "Supramolecular self-assembly of a symmetric imine ligand functionalized with a dansyl fluorophore moiety." In The 20th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-d002.

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Al-Soufi, Wajih, Mercedes Novo, Belén Reija, and Claus Seidel. "Fluorescence Correlation Spectroscopy as a Tool for the Study of the Dynamics of Supramolecular and Organized Systems." In The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01651.

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