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Journal articles on the topic 'Supramolecular Nano-composites'

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Author: Grafiati
Published: 7 September 2023

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1

Li, Fei, Kevin G. Yager, Noel M. Dawson, Ying-Bing Jiang, Kevin J. Malloy, and Yang Qin. "Nano-structuring polymer/fullerene composites through the interplay of conjugated polymer crystallization, block copolymer self-assembly and complementary hydrogen bonding interactions." Polymer Chemistry 6, no. 5 (2015): 721–31. http://dx.doi.org/10.1039/c4py00934g.

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2

Shokrollahi, Parvin, Mohammad Mehmanchi, Mohammad Atai, Hossein Omidian, and Fateme Shokrolahi. "Effect of interface on mechanical properties and biodegradation of PCL HAp supramolecular nano-composites." Journal of Materials Science: Materials in Medicine 25, no. 1 (September 13, 2013): 23–35. http://dx.doi.org/10.1007/s10856-013-5039-6.

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3

Fujii, Kazuko, Manas Kumar Bera, Dines Chandra Santra, and Masayoshi Higuchi. "Nanocomposites of Fe(II)-Based Metallo-Supramolecular Polymer and a Layered Inorganic–Organic Hybrid for Improved Electrochromic Materials." Polymers 14, no. 5 (February 25, 2022): 915. http://dx.doi.org/10.3390/polym14050915.

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Fe-based metallo-supramolecular polymer (polyFe), composed of Fe(II) ions and bis(terpyridyl)benzene, is known as a good electrochromic (EC) material. For the first time, to improve the EC properties, we prepared nanocomposites comprising polyFe and a layered inorganic–imidazoline covalently bonded hybrid (LIIm) by simply mixing them in methanol and then examined the effect of the nanocomposition on EC properties. The obtained blue/purple-colored composites (polyFe/LIIm composites) were demonstrated by scanning electron microscopy (SEM) to comprise a structure of LIIm nanoparticles coated with amorphous polyFe. Interestingly, X-ray diffraction (XRD) measurements suggested that there was no intercalation of polyFe in the interlayer space of LIIm. Ultraviolet-visible (UV-vis) spectroscopy measurements demonstrated that light absorption close to 600 nm was attributed to metal-to-ligand charge transfer (MLCT) from the Fe(II) ion to the bisterpyridine ligand and was influenced by LIIm in the composites. The composites exhibited a pair of redox waves, assigned to the redox between Fe(II) and Fe(III), in the cyclic voltammograms; moreover, the composites were estimated to be diffusion controlled. Thin composite films demonstrated reversible EC changes, triggered by the redox reaction of the metal. Furthermore, the results show that the nano-scale composition of the metallo-supramolecular polymers with LIIm can effectively improve the memory properties without reducing the contrast in transmittance (ΔT) of 70–76% in EC changes after applying 1.2 V vs. Ag/Ag+. The EC properties varied with varying ratios (3/0.1, 0.5, 1, and 5) of the polyFe/LIIm, and the ratio of 3/1 exhibited the longest memory and largest MLCT absorption peak among composites. The results show that the polyFe/LIIm composites are useful EC materials for dimming glass applications, such as smart windows.
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4

Majumdar, Santanu, Gerald Lepcha, Rajib Sahu, and Biswajit Dey. "Exploring an aromatic dicarboxylic acid-grafted supramolecular Cd(II)-metallogel: The mechanically flexible stuff for achieving MoS2, MoSe2, WS2, GO, and h(BN) 2D nanosheets-dispersed versatile supramolecular gel-nano composites." Journal of Physics and Chemistry of Solids 170 (November 2022): 110903. http://dx.doi.org/10.1016/j.jpcs.2022.110903.

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5

Tachibana, Junichi, Midori Chiba, Masaru Ichikawa, Taira Imamura, and Yoichi Sasaki. "Supramolecular hybrid composites of metalloporphyrins and fullerene encapsulated in the ordered nano-channels of FSM-16 as oxygen carriers, and photo-catalysis for selective propene oxidation towards acetone." Supramolecular Science 5, no. 3-4 (July 1998): 281–87. http://dx.doi.org/10.1016/s0968-5677(98)00020-0.

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6

Maldonado, Noelia, and Pilar Amo-Ochoa. "Advances and Novel Perspectives on Colloids, Hydrogels, and Aerogels Based on Coordination Bonds with Biological Interest Ligands." Nanomaterials 11, no. 7 (July 20, 2021): 1865. http://dx.doi.org/10.3390/nano11071865.

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This perspective article shows new advances in the synthesis of colloids, gels, and aerogels generated by combining metal ions and ligands of biological interest, such as nucleobases, nucleotides, peptides, or amino acids, among other derivatives. The characteristic dynamism of coordination bonds between metal center and biocompatible-type ligands, together with molecular recognition capability of these ligands, are crucial to form colloids and gels. These supramolecular structures are generated by forming weak van der Waals bonds such as hydrogen bonds or π–π stacking between the aromatic rings. Most gels are made up of nano-sized fibrillar networks, although their morphologies can be tuned depending on the synthetic conditions. These new materials respond to different stimuli such as pH, stirring, pressure, temperature, the presence of solvents, among others. For these reasons, they can trap and release molecules or metal ions in a controlled way allowing their application in drug delivery as antimicrobial and self-healable materials or sensors. In addition, the correct selection of the metal ion enables to build catalytic or luminescent metal–organic gels. Even recently, the use of these colloids as 3D-dimensional printable inks has been published. The elimination of the solvent trapped in the gels allows the transformation of these into metal–organic aerogels (MOAs) and metal–organic xerogels (MOXs), increasing the number of possible applications by generating new porous materials and composites useful in adsorption, conversion, and energy storage. The examples shown in this work allow us to visualize the current interest in this new type of material and their perspectives in the short-medium term. Furthermore, these investigations show that there is still a lot of work to be done, opening the door to new and interesting applications.
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7

Majumdar, Santanu, Madhuri Ghosh, Suprabhat Mukherjee, Biswarup Satpati, and Biswajit Dey. "DNA mediated graphene oxide (GO)-nanosheets dispersed supramolecular GO-DNA hydrogel: An efficient soft-milieu for simplistic synthesis of Ag-NPs@GO-DNA and Gram + ve/-ve bacteria-based Ag-NPs@GO-DNA-bacteria nano-bio composites." Journal of Molecular Liquids 342 (November 2021): 117482. http://dx.doi.org/10.1016/j.molliq.2021.117482.

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8

Antesberger, Jochen, Gareth W. V. Cave, Matthew C. Ferrarelli, Michael W. Heaven, Colin L. Raston, and Jerry L. Atwood. "Solvent-free, direct synthesis of supramolecular nano-capsules." Chemical Communications, no. 7 (2005): 892. http://dx.doi.org/10.1039/b412251h.

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9

Wang, Kaiya, Jacobs H. Jordan, and Bruce C. Gibb. "Molecular protection of fatty acid methyl esters within a supramolecular capsule." Chemical Communications 55, no. 78 (2019): 11695–98. http://dx.doi.org/10.1039/c9cc06501f.

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10

Jiang, Yuhang, Edoardo Jun Mattioli, Matteo Calvaresi, and Zhiyong Wang. "Theoretical design of an ultrafast supramolecular rotor composed of carbon nano-rings." Chemical Communications 56, no. 79 (2020): 11835–38. http://dx.doi.org/10.1039/d0cc04806b.

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11

Li, Die, Jing Chen, Xiaoling Xu, Chunyang Bao, and Qiang Zhang. "Supramolecular assemblies of glycoclusters with aggregation-induced emission for sensitive phenol detection." Chemical Communications 56, no. 87 (2020): 13385–88. http://dx.doi.org/10.1039/d0cc05301e.

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12

Hsieh, Yu-Yu, Rafael S. Sánchez, Guillaume Raffy, Jing-Jong Shyue, Lionel Hirsch, André Del Guerzo, Ken-Tsung Wong, and Dario M. Bassani. "Supramolecular gating of TADF process in self-assembled nano-spheres for high-resolution OLED applications." Chemical Communications 58, no. 8 (2022): 1163–66. http://dx.doi.org/10.1039/d1cc06120h.

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13

Au-Yeung, Ho-Leung, Sammual Yu-Lut Leung, and Vivian Wing-Wah Yam. "Supramolecular assemblies of dinuclear alkynylplatinum(ii) terpyridine complexes with double-decker silsesquioxane nano-cores: the role of isomerism in constructing nano-structures." Chemical Communications 54, no. 33 (2018): 4128–31. http://dx.doi.org/10.1039/c8cc00557e.

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14

Matsumoto, Shinji, Satoshi Yamaguchi, Atsuhiko Wada, Toshihiro Matsui, Masato Ikeda, and Itaru Hamachi. "Photo-responsive gel droplet as a nano- or pico-litre container comprising a supramolecular hydrogel." Chemical Communications, no. 13 (2008): 1545. http://dx.doi.org/10.1039/b719004b.

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15

Tsai, Chia-Chen, Kai-Chi Chang, I.-Ting Ho, Jean-Ho Chu, Ying-Tsai Cheng, Li-Ching Shen, and Wen-Sheng Chung. "Evolution of nano- to microsized spherical assemblies of fluorogenic biscalix[4]arenes into supramolecular organogels." Chemical Communications 49, no. 29 (2013): 3037. http://dx.doi.org/10.1039/c3cc40334c.

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16

Pan, Jingjing, and Jingyang Wang. "Temperature-mediated supramolecular assemblies give rise to hierarchical boron nitride nano-ribbon networks with different micro-topology." Journal of Materials Science & Technology 96 (January 2022): 160–66. http://dx.doi.org/10.1016/j.jmst.2021.03.084.

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17

Asthana, Deepak, Anil Kumar, Abhishek Pathak, Pradip Kumar Sukul, Sudip Malik, Ratnamala Chatterjee, Satyabrata Patnaik, Kari Rissanen, and Pritam Mukhopadhyay. "An all-organic steroid–D–π-A modular design drives ferroelectricity in supramolecular solids and nano-architectures at RT." Chemical Communications 47, no. 31 (2011): 8928. http://dx.doi.org/10.1039/c1cc12398j.

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18

Zhu, Yulin, Wei Huang, Zhaoliang Liu, and Daobo Wang. "Application of Supramolecular Nano-Material Adsorbent in the Treatment of Heavy Metal Pollution in Acid Selenium-Rich Soils in South China." Integrated Ferroelectrics 217, no. 1 (June 13, 2021): 69–81. http://dx.doi.org/10.1080/10584587.2021.1911297.

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19

Lepcha, Gerald, Rajib Sahu, Santanu Majumdar, Saikat Banerjee, Arpita Bhowmick, Samya Sen, Bholanath Panda, Debasis Dhak, Keka Sarkar, and Biswajit Dey. "MoS2 and MoSe2 2D nanosheets-based bio-active supramolecular nano-structural scaffold-capped potent Ag-NPs: Exploring morphological, anti-bacterial and anticancer property." New Journal of Chemistry, 2023. http://dx.doi.org/10.1039/d3nj00383c.

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Different nano-structural composites-capped silver nano-particles (i.e., Ag-NPs@SHGel-MoX2, here, X = S, Se) have been explored. Nano-composites, made by 2D metal dichalcogenides (i.e., MoS2, MoSe2, and MoS2-MoSe2) nanosheets-dispersed supramolecular hydrogel (SHGel)...
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20

Suggs, Kelvin, Vernecia Person, Chantel Nicolas, and Xiao-Qian Wang. "Multiscale Modeling of Reinforced Epoxy Resins by Carbon Nanotubes and Graphene." MRS Proceedings 1312 (2011). http://dx.doi.org/10.1557/opl.2011.263.

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ABSTRACTNanocomposites are of increasing interest due to their unique structural, electronic, and thermal properties. Simultaneously, multiscale molecular modeling is becoming more robust. Therefore computational models are able to be examined with increased accuracy, complexity, and dimension. Graphene based molecules are lauded for their conductive properties as well as their architecture-like geometry which may allow bottom up nanoscale fabrication of nanoscopic structures. Furthermore, these macrocycled molecules allow high interactivity with other molecules including highly tensiled polymers that yield other novel supramolecular structures when interacted. These supramolecular structures are being investigated in lieu of a variety of potential applications. Nanocomposites of cured epoxy resin reinforced by single-walled carbon nanotubes exhibit a plethora of interesting behavior at the molecular level. A fundamental issue is how the self-organized dynamic structure of functional molecular systems affects the interactions of the nano-reinforced composites. A combination of force-field based molecular dynamics and local density-functional calculations shows that the stacking between the aromatic macrocycle and the surface of the SWNTs manifests itself via increased interfacial binding. First-principles calculations on the electronic structures further reveal that there exists distinct level hybridization behavior for metallic and semiconducting nanotubes. In addition there is a monatomic increase in binding energy with an increase in the nanotube diameter. The simulation studies suggest that graphene nanoplatelets are potentially the best fillers of epoxy matrices. The implications of these results for understanding dispersion mechanism and future nanocomposite developments are discussed.
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21

Yang, Manman, Ke Yang, Bingling Gao, Peng Wang, Tianjiao Li, Yi Zheng, Yuxin Pei, Zhichao Pei, and Yinghua Lv. "A supramolecular nano-delivery system based on AIE PARP inhibitor prodrug and glycosylated pillar[5]arene for drug-resistance therapy." Chemical Communications, 2022. http://dx.doi.org/10.1039/d2cc04238j.

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A supramolecular nano-delivery system GP5⊃Pro-ANI based on the host-guest complex of glycosylated pillar[5]arene (GP5) and an amide linked fluorescent PARP inhibitor (4-Amino-1,8-Naphthimide, ANI) was constructed. The PARP inhibitor ANI, capable...
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22

Chao, Shuang, Ziyan Shen, Bowen Li, Yuxin Pei, and Zhichao Pei. "L-arginine-Functionalized Pillar[5]arene-based Supramolecular Photosensitizer for Synergistically Enhanced Cancer Therapeutic Effectiveness." Chemical Communications, 2023. http://dx.doi.org/10.1039/d3cc00123g.

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A L-arginine-functionalized pillar[5]arene-based supramolecular photosensitizer LAP5⊃NBSPD was constructed by the host-guest interactions, which could self-assemble into nano-micelles to achieve effective delivery and selective release of LAP5 and NBS in tumour...
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23

Tang, Lei, Feng Qin, Deying Gong, Yu Dong, Lili Pan, Changcui Zhou, Qinqin Yin, et al. "Long-term sciatic nerve block lead by supramolecular arrangement of self-delivery local anesthetic nano systems." Chemical Communications, 2023. http://dx.doi.org/10.1039/d3cc02269b.

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Classical local anesthetics are unsuitable to treat regional pain lasting several days due to their limited duration and systemic toxicity. Self-delivery nano system without excipients were designed for long-term sensory...
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