Academic literature on the topic 'Supramolecular level'

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Journal articles on the topic "Supramolecular level"

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Credi, Alberto, Belén Ferrer Ribera, and Margherita Venturi. "From supramolecular electrochemistry to molecular-level devices." Electrochimica Acta 49, no. 22-23 (2004): 3865–72. http://dx.doi.org/10.1016/j.electacta.2003.12.063.

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Eckel, Rainer, Robert Ros, Bj�rn Decker, Jochen Mattay, and Dario Anselmetti. "Supramolecular Chemistry at the Single-Molecule Level." Angewandte Chemie International Edition 44, no. 3 (2005): 484–88. http://dx.doi.org/10.1002/anie.200461382.

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Lin, Huirong, Shuang Li, Junqing Wang, et al. "A single-step multi-level supramolecular system for cancer sonotheranostics." Nanoscale Horizons 4, no. 1 (2019): 190–95. http://dx.doi.org/10.1039/c8nh00276b.

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A multi-level supramolecular system produced by single-step Fe<sup>3+</sup>-mediated ionic crosslinking self-assembly can overcome the critical issues of current sonodynamic therapy (SDT) and address the need to monitor therapeutic effects in vivo with a non-invasive approach.
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Schäfer, Christian, Björn Decker, Matthias Letzel, et al. "On the way to supramolecular photochemistry at the single-molecule level." Pure and Applied Chemistry 78, no. 12 (2006): 2247–59. http://dx.doi.org/10.1351/pac200678122247.

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Two examples of artificial supramolecular host-guest systems derived from resorc[4]arenes (calix[n]arenes based on resorcinol) and ammonium ions as guests have been studied by atomic force microscopy (AFM). For the first time, real single-molecule events have been determined for this type of supramolecular complexes and off-rates as well as molecular parameters of single-molecule aggregates such as the depths of the binding pocket (molecular length parameter) could be measured by applying the methods of dynamic force spectroscopy. In addition, this technique was also applied to differentiate b
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Dawn, Arnab. "Supramolecular Gel as the Template for Catalysis, Inorganic Superstructure, and Pharmaceutical Crystallization." International Journal of Molecular Sciences 20, no. 3 (2019): 781. http://dx.doi.org/10.3390/ijms20030781.

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A supramolecular gel is a fascinating combination of flexibility and orderliness. While the supramolecular nature of crosslinking contributes towards the adaptivity and the reversibility of the system, orderliness at the molecular level amplifies the functional output and induces extraordinary selectivity into the system. Therefore, use of supramolecular gels as the soft template is an emerging area of research, which includes but not limited to catalysis of a chemical or a photochemical process, transcription of gel property to a substrate, or even controlling the nucleation of drug molecules
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Shestimerova, T. A., M. A. Bykov, Z. Wei, E. V. Dikarev, and A. V. Shevelkov. "Crystal structure and two-level supramolecular organization of glycinium triiodide." Russian Chemical Bulletin 68, no. 8 (2019): 1520–24. http://dx.doi.org/10.1007/s11172-019-2586-0.

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Pijper, Dirk, and Ben L. Feringa. "Control of dynamic helicity at the macro- and supramolecular level." Soft Matter 4, no. 7 (2008): 1349. http://dx.doi.org/10.1039/b801886c.

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Yang, Lin, Lan She, Jian-Guo Zhou, Ying Cao, and Xiao-Ming Ma. "Interaction of lysozyme during calcium carbonate precipitation at supramolecular level." Inorganic Chemistry Communications 9, no. 2 (2006): 164–66. http://dx.doi.org/10.1016/j.inoche.2005.05.026.

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Wei, Chengpeng, Mingyang Liu, Yifei Han, Hua Zhong, and Feng Wang. "Supramolecular Chirogenesis Engineered by Pt(II)···Pt(II) Metal–Metal Interactions." Organic Materials 03, no. 02 (2021): 274–80. http://dx.doi.org/10.1055/a-1512-5965.

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Supramolecular chirogenesis represents an effective way to induce chirality at the supramolecular level. For the previous host–guest chirogenic systems, metal–ligand coordination, hydrogen bonding, π–π stacking and hydrophobic interactions have been mainly employed as the non-covalent driving forces. In this study, Pt(II)···Pt(II) metal–metal interactions have been engineered to induce supramolecular chirogenesis, by forming non-covalent clipping structures between chiral platinum receptors and achiral platinum guests together. This results in the emergence of Cotton effects in the metal–metal
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Chen, Miao, Weimin Lin, Le Hong, Ning Ji, and Hang Zhao. "The Development and Lifetime Stability Improvement of Guanosine-Based Supramolecular Hydrogels through Optimized Structure." BioMed Research International 2019 (June 13, 2019): 1–18. http://dx.doi.org/10.1155/2019/6258248.

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Guanosine is an important building block for supramolecular gels owing to the unique self-assembly property that results from the unique hydrogen bond acceptors and donor groups. Guanosine-derived supramolecular hydrogels have promise in the fields of drug delivery, targeted release, tissue engineering applications,etc.However, the property of poor longevity and the need for excess cations hinder the widespread applications of guanosine hydrogels. Although guanosine-derived supramolecular hydrogels have been reviewed previously by Dash et al., the structural framework of this review is differe
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Dissertations / Theses on the topic "Supramolecular level"

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Campos, E. Menezes Jorge Ramalhete Susana. "Molecular level understanding of supramolecular gels." Thesis, University of East Anglia, 2017. https://ueaeprints.uea.ac.uk/67676/.

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Supramolecular gels are complex materials which have an expanding scope of industrial and biomedical applications, due to their unique viscoelastic properties, high biocompatibility and possibility of functionalisation. The hierarchical structure of molecular materials combines domains with drastically different degrees of ordering and molecular mobility. This makes their full characterisation a significant methodological and experimental challenge. The focus of this work was therefore the understanding of a variety of supramolecular semicrystalline gels in which very rigid solid components co
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Diniz, Ana Marta Correia Alves. "Multiresponsive supramolecular systems for information processing at the molecular level." Doctoral thesis, Faculdade de Ciências e Tecnologia, 2013. http://hdl.handle.net/10362/11291.

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Dissertação para obtenção do Grau de Doutor em Química Sustentável<br>Information processing at the molecular level requires systems able to move between several states under control of specific inputs. Flavylium salts (2-phenyl-1-benzopyrylium salts)analogues of naturally occurring anthocyanin dyes, are a versatile family of molecules that illustrates the multistate/multiresponsive concept. On the basis of the pH and light dependent network of chemical reactions of the flavylium network, different forms can be obtained by external stimuli exhibiting different properties. The research work
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Jaabar, Ilhem Lilia. "Surface characterizations to investigate osteoarticular mesenchymal tissues : new insights to monitor the extracellular matrix remodeling at the supramolecular level." Electronic Thesis or Diss., Sorbonne université, 2022. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2022SORUS145.pdf.

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Un tissu conjonctif est un ensemble coopératif de cellules différenciées enchevêtrées dans une matrice extracellulaire (ECM). Cette dernière, particulièrement abondante, se compose principalement de protéines, telles que les collagènes, et d'un gel visqueux constitué d'eau et de protéoglycanes chargés négativement. Tous les tissus conjonctifs subissent un renouvellement constant de leur ECM, préservant ainsi l'intégrité et les propriétés des tissus. Des perturbations dans le remodelage de l'ECM, en termes de composition ou de structure supramoléculaire, peuvent avoir un impact significatif sur
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Afsari, Mamaghani Sepideh. "The Formation of Two Dimensional Supramolecular Structures and Their Use in Studying Charge Transport at the Single Molecule Level at the Liquid-Solid Interface." Diss., Temple University Libraries, 2015. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/350915.

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Chemistry<br>Ph.D.<br>Understanding charge transport through molecular junctions and factors affecting the conductivity at the single molecule level is the first step in designing functional electronic devices using individual molecules. A variety of methods have been developed to fabricate metal-molecule-metal junctions in order to evaluate Single Molecule Conductance (SMC). Single molecule junctions usually are formed by wiring a molecule between two metal electrodes via anchoring groups that provide efficient electronic coupling and bind the organic molecular backbone to the metal electrode
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Book chapters on the topic "Supramolecular level"

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Fink, D., V. Hnatowicz, and P. Yu Apel. "Modifications on the Molecular and Supramolecular Level." In Fundamentals of Ion-Irradiated Polymers. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-07326-1_8.

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Balzani, V., A. Credi, and M. Venturi. "Molecular-Level Devices." In Supramolecular Science: Where It Is and Where It Is Going. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4554-1_1.

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Chambron, Jean-Claude. "Rotaxanes: From Random to Transition Metal-Templated Threading of Rings at the Molecular Level." In Perspectives in Supramolecular Chemistry. John Wiley & Sons, Ltd., 2007. http://dx.doi.org/10.1002/9780470511510.ch6.

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Rotello, Vincent, Qing Feng, Jong-In Hong, and Julius Rebek. "Competition, Reciprocity and Mutation at the Molecular Level: Irradiation of a Synthetic Replicator Generates a Superior Species." In Self-Production of Supramolecular Structures. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0754-9_27.

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Şener, Melih K., and Klaus Schulten. "From Atomic-Level Structure to Supramolecular Organization in the Photosynthetic Unit of Purple Bacteria." In The Purple Phototrophic Bacteria. Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-1-4020-8815-5_15.

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Balzani, Vincenzo, and Alberto Credi. "Molecular‐Level Machines." In Encyclopedia of Supramolecular Chemistry. CRC Press, 2004. http://dx.doi.org/10.1081/e-esmc-120012829.

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Casimiro, Lorenzo. "The butterfly effect of photochromes." In Photochemistry. Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781837672301-00509.

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Beyond their application in switchable optical materials, photochromic molecules are also solid building blocks to make nanoscopic objects light-responsive, in order to control molecular motions, convert and store light into chemical energy, or drive chemical reactions. An outstanding quality, in these regards, is the possibility of operating a minor variation on the photochrome structure, such as via covalent or supramolecular strategies, that can ultimately result in a large tuning of the photoresponsivity, both at the molecular and material level. The PhD manuscript here highlighted, titled “Novel Photo- and Electro-responsive Supramolecular Systems and Molecular Machines” and awarded the 2020 European Photochemistry Association PhD Prize, covered several studies on how azobenzene- and terarylene-based photochromes can be employed as photoresponsive components of smart materials and how minor adjustments on their molecular structure can generate drastic changes in their performance, in a sort of butterfly effect fashion.
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Chavan, Rahul B., and Nalini R. Shastri. "Overview of Multicomponent Solid Forms." In Alternative Pain Management. IGI Global, 2020. http://dx.doi.org/10.4018/978-1-7998-1680-5.ch004.

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Multi-drug therapy involves the simultaneous or sequential administration of two or more drugs with similar or different mechanisms of action and is efficient in combating various ailments such as cancer, diabetes, and rheumatoid arthritis. It has emerged advantageous due to larger therapeutic benefits, an increase in patient compliance, lower administrative costs, and reduced number of prescriptions. In the recent past, the clinical success of the Novartis product Entresto (sacubitril, disodium valsartan and water) and Esteve product E-58425 (tramadol and celecoxib) has boosted the development of multi-drug . The present article is hence designed to provide an overview of different multicomponent addicts which provide option of combining the drugs at a supramolecular level (nano-sized level). Key features of multi-drug cocrystal, co-amorphous system and eutectics are described with major emphasis on screening tools, preparation methods, characterization techniques, biopharmaceutical aspects and scale up.
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Desai, Aamod V., Yong-Sheng Wei, Sujit K. Ghosh, and Satoshi Horike. "Structure, Design and Synthesis." In Flexible Metal–Organic Frameworks. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781839166617-00001.

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Flexible metal–organic frameworks (MOFs) form an attractive class of solid-state materials that exhibit structural softness and a discernible response to external stimulus, physical or chemical. These features make them suitable for several applications for energy, environment and biomedicine, with the ability to tune their characteristics at the molecular level. This chapter provides a detailed analysis of their synthesis and structural properties, with the aim to derive design principles. The flexibility is stated at two levels: one part with the focus on the building blocks of such systems, and the other considering the topological viewpoint in their supramolecular assemblies. The role of metals, ligands and guest molecules in influencing their dynamic nature is discussed with several examples from a range of MOFs. The chapter closes with a perspective on the factors that can enable complete understanding of flexibility in MOFs and thereby lead to a greater understanding in terms of designing such materials.
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Chandra, Girish, Ujala Rani, Birkishore Mahto, and Gopal Kumar Mahato. "Azobenzenes: Photoswitching and Their Chemical Sensor Application." In Dye Chemistry - Exploring Colour From Nature to Lab [Working Title]. IntechOpen, 2024. http://dx.doi.org/10.5772/intechopen.1005351.

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Azobenzene is a well-known dye that undergoes fast trans-cis photoisomerization and has been widely studied and used in the development of organic functional materials. Due to its selective isomeric distribution in the excited state, azobenzene has been used as a photoswitch in the storage of information on a molecular level, photo-controllable catalysis, solar light harvesting, photo-pharmacology, optical-to-mechanical energy conversion, molecular electronic, and photonic devices. Furthermore, the characteristic and distinguishable photoelectronic properties of trans and cis azobenzene have been recently used in the sensing properties of different ions and the recognition of molecules. Here, we are going to review the recent literature where different intermolecular forces show the supramolecular properties under the stimuli of photo-light.
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Conference papers on the topic "Supramolecular level"

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Georgakilas, Vasilios. "Control of Supramolecular Shapes at Nanometer Level." In STRUCTURAL AND ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES: XVI International Winterschool on Electronic Properties of Novel Materials. AIP, 2002. http://dx.doi.org/10.1063/1.1514163.

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Bräuchle, C. "Bacteriorhodopsin - Optical Processor Molecules from Nature." In Spectral Hole-Burning and Related Spectroscopies: Science and Applications. Optica Publishing Group, 1994. http://dx.doi.org/10.1364/shbs.1994.fa3.

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The field of molecular electronics is characterized by an attempt to engineer and use devices on a molecular level. Supramolecular chemistry is one way to produce such molecular devices. However, long before supramolecular chemists tried to synthesize highly organized artificial systems often employing principles of living nature, nature itself has produced and optimized biological systems on a molecular device level during a long period of evolution.
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Tballad, V. R., S. Brasselet, G. R. Desiraju, and J. Zyss. "Octupolar Crystalline Structures for Quadratic Nonlinear Optics : A Dual Crystal and Propagative Engineering Approach." In The European Conference on Lasers and Electro-Optics. Optica Publishing Group, 1998. http://dx.doi.org/10.1364/cleo_europe.1998.ctuj4.

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Crystal engineering is increasingly turning towards functional materials. Octupolar . NLO active substances are expected to overcome many of the disadvantages posed by dipolar species. While octupolar non-linearity has been demonstrated at the molecular level, its demonstration in supramolecular crystalline systems remains a challenge. Trigonal, non- centrosymmetric assemblies of trigonal molecules lead to supramolecular octupolar networks. However, most trigonal molecules do not assemble into trigonal networks. In this work, the principles of crystal engineering have been used in the carry-ov
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"Stress resistance on the example of supramolecular-genetic level of plant development." In Plant Genetics, Genomics, Bioinformatics, and Biotechnology. Novosibirsk ICG SB RAS 2021, 2021. http://dx.doi.org/10.18699/plantgen2021-082.

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Priimagi, Arri, Stefano Cattaneo, Robin H. A. Ras, Sami Valkama, Olli Ikkala, and Martti Kauranen. "Supramolecular guest-host systems: combining high dye doping level with low aggregation tendency." In SPIE Optics + Photonics, edited by Robert A. Norwood. SPIE, 2006. http://dx.doi.org/10.1117/12.680475.

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Aguiar, Antônio S. N., Jaqueline E. Queiroz, Pollyana P. Firmino, et al. "Experimental and theoretical study of the chalcone molecule (E)-3-(2,6-difluorophenyl)-1-(furan-2-yl)-prop-2-en-1-one." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol202033.

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In this work, we synthesized chalcone (E)-3-(2,6-difluorophenyl)-1-(furan-2-yl)-prop-2-en-1-one (DTP) via Claisen-Schmidt condensation. The supramolecular arrangement of the obtained compound was characterized by X-ray diffraction and Hirshfeld surface, and its crystalline structure was determined. The DTP molecule was studied using the Density Functional Theory, at the theoretical level M06-2X/6-311G ++G, in order to obtain information about its structural and electronic properties. A map of molecular electrostatic potential was obtained to predict the types of interactions and their acid-bas
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Park, Jiyong, Byungnam Kahng та Wonmuk Hwang. "Supramolecular Structure and Stability of the GNNQQNY β-Sheet Bilayer Filament: A Computational Study". У ASME 2007 Summer Bioengineering Conference. American Society of Mechanical Engineers, 2007. http://dx.doi.org/10.1115/sbc2007-175588.

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Self-assembly of β-sheet forming peptides into filaments has drawn great interests in biomedical applications [1,2]; Hydrogels formed by filaments self-assembled from de novo designed peptides possess potential applications for cell culture scaffolds [3]. On the other hand, peptides derived from amyloidogenic proteins in neurodegenerative diseases such as Alzheimer’s and Parkinson’s also form similar β-sheet filaments in vitro. They share little sequence homology, yet filaments formed by these self-assembling peptides commonly have the cross-β structure, the key signature of the amyloid fibril
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Corredig, Milena. "Processing plant proteins colloidal structures." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/cyqr3105.

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Food systems need to be designed to better fit within planetary boundaries. It is not only important to find more sustainable protein sources, but also to create fully circular, robust supply chains. But this is only the beginning: new formulations will need to fit common dietary expectations. The utilization of plant-based protein ingredients present significant challenges in relation to their nutritional and technological functionalities. Today these proteins do not measure up when used as ingredients in conventional processes. Plant protein streams contain polydisperse colloids, and detaile
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Bourne, Jonathan W., and Peter A. Torzilli. "Collagen Molecular Conformation Exhibits Strain-Rate Dependent Response to Axial Deformation in Silico." In ASME 2009 Summer Bioengineering Conference. American Society of Mechanical Engineers, 2009. http://dx.doi.org/10.1115/sbc2009-205534.

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Fibrillar collagens are a group of structural proteins that self assemble into a complex ordered structure of interconnected molecules to form supramolecular fibril structures. These collagens have three subgroups based on sequence similarity, of which clade A includes the most abundant fibrillar collagens, types I, II, and III. The fibrous hierarchical structures starts with individual collagen molecules that are crosslinked by enzymes to other collagen molecules to form micro fibrils, which aggregate and link to form sub fibrils, then larger fibrils and in some tissues continuing to assemble
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Reports on the topic "Supramolecular level"

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Kirchhoff, Helmut, and Ziv Reich. Protection of the photosynthetic apparatus during desiccation in resurrection plants. United States Department of Agriculture, 2014. http://dx.doi.org/10.32747/2014.7699861.bard.

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In this project, we studied the photosynthetic apparatus during dehydration and rehydration of the homoiochlorophyllous resurrection plant Craterostigmapumilum (retains most of the photosynthetic components during desiccation). Resurrection plants have the remarkable capability to withstand desiccation, being able to revive after prolonged severe water deficit in a few days upon rehydration. Homoiochlorophyllous resurrection plants are very efficient in protecting the photosynthetic machinery against damage by reactive oxygen production under drought. The main purpose of this BARD project was
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