Academic literature on the topic 'Supramolecular Gelator'

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Journal articles on the topic "Supramolecular Gelator"

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Alegre-Requena, Juan V., Marleen Häring, Isaac G. Sonsona, et al. "Synthesis and supramolecular self-assembly of glutamic acid-based squaramides." Beilstein Journal of Organic Chemistry 14 (August 6, 2018): 2065–73. http://dx.doi.org/10.3762/bjoc.14.180.

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We describe the preparation and characterization of two new unsymmetrical squaramide-based organogelators. The synthesis of the compounds was carried out by subsequent amine condensations starting from dimethyl squarate. The design of the gelators involved a squaramide core connected on one side to a long aliphatic chain and on the other side to a glutamic acid residue. The gelator bearing the free carboxylic groups showed a lower gelation capacity than its precursor diester derivative. Some selected gels were further studied by infrared spectroscopy, rheology and electron microscopy. Critical
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Haldar, Saubhik, та Koninika Karmakar. "A systematic understanding of gelation self-assembly: solvophobically assisted supramolecular gelation via conformational reorientation across amide functionality on a hydrophobically modulated dipeptide based ambidextrous gelator, N-n-acyl-(l)Val-X(OBn), (X = 1,ω-amino acid)". RSC Advances 5, № 81 (2015): 66339–54. http://dx.doi.org/10.1039/c5ra10209j.

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Gelator backbone conformational flexibility plays an important role in a supramolecular self-assembly which is synergistically assisted by solvophobic interaction leading to a gelation of three sets of hydrophobically modulated dipeptidic gelators.
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Yin, Chunyu, Fengrui Jiang, Bao Li, and Lixin Wu. "Multiple modulations for supramolecular hydrogels of bola-form surfactants bearing rigid and flexible groups." Soft Matter 15, no. 25 (2019): 5034–41. http://dx.doi.org/10.1039/c9sm00782b.

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Supramolecular hydrogels of bola-form surfactants were modulated by light irradiation and chemical additives to achieve reversible and unidirectional transitions between the gel and sol while a non-gelator boosts the gelation of the gelators.
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Kowalczuk, Joanna, Oleg M. Demchuk, Mariusz Borkowski, and Michał Bielejewski. "Stabilisation of Nanosilver Supramolecular Hydrogels with Trisodium Citrate." Molecules 30, no. 7 (2025): 1613. https://doi.org/10.3390/molecules30071613.

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Designing supramolecular gelators with targeted properties is very difficult and mainly relies on structural modifications of known gelator molecules. However, very often, even minor modifications can result in the complete loss of gelation capabilities. In the present work, we have studied the influence and role of the silver nanoparticles (AgNPs) and trisodium citrate (TSC) additives on the self-assembly process of alanine derivative gelator (C12Ala) and intermolecular interactions resulting in hydrogel systems of enhanced stability and sustainability. The effect of phase separation and dive
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Ghosh, Dipankar, Matthew T. Mulvee, and Krishna K. Damodaran. "Tuning Gel State Properties of Supramolecular Gels by Functional Group Modification." Molecules 24, no. 19 (2019): 3472. http://dx.doi.org/10.3390/molecules24193472.

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The factors affecting the self-assembly process in low molecular weight gelators (LMWGs) were investigated by tuning the gelation properties of a well-known gelator N-(4-pyridyl)isonicotinamide (4PINA). The N―H∙∙∙N interactions responsible for gel formation in 4PINA were disrupted by altering the functional groups of 4PINA, which was achieved by modifying pyridyl moieties of the gelator to pyridyl N-oxides. We synthesized two mono-N-oxides (INO and PNO) and a di-N-oxide (diNO) and the gelation studies revealed selective gelation of diNO in water, but the two mono-N-oxides formed crystals. The
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Azyat, Khalid, Darren Makeiff, Bradley Smith, et al. "The Effect of Branched Alkyl Chain Length on the Properties of Supramolecular Organogels from Mono-N-Alkylated Primary Oxalamides." Gels 9, no. 1 (2022): 5. http://dx.doi.org/10.3390/gels9010005.

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Mono-N-alkylated primary oxalamide derivatives with different sized branched alkyl tail-groups were excellent low molecular weight gelators for a variety of different organic solvents with different polarities and hydrogen-bonding abilities. Solvent-gelator interactions were analyzed using Hansen solubility parameters, while 1H NMR and FTIR spectroscopy were used to probe the driving forces for the supramolecular gelation. The molecular structures of the twin tail-groups did not significantly affect the supramolecular gelation behavior in different solvents. However, for select solvents, the m
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Patterson, Anna K., and David K. Smith. "Two-component supramolecular hydrogel for controlled drug release." Chemical Communications 56, no. 75 (2020): 11046–49. http://dx.doi.org/10.1039/d0cc03962d.

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Liu, Shao Zhu, Wei Li Liu, Zhi Gang Liu, et al. "A Phase-Selective Supramolecular Gelator as Oil Solidifier." Applied Mechanics and Materials 457-458 (October 2013): 284–87. http://dx.doi.org/10.4028/www.scientific.net/amm.457-458.284.

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A simple sugar-derived supramolecular gelator of 1,6-dicaprylate sorbitan ester was designed and prepared as new oil solidifier. The gelation tests revealed that the gelator can gel or phase-selectively gel fuel oils, edible oils and some organic solvents. And the SEM images showed the structure of 3D fiber network was formed in the process of gelation. What’s more, the rate of oil removal in water was 85% and the recovery rate of spilled oils reached up to 60.29%.
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Ghosh, Dipankar, Ragnar Bjornsson, and Krishna K. Damodaran. "Role of N–Oxide Moieties in Tuning Supramolecular Gel-State Properties." Gels 6, no. 4 (2020): 41. http://dx.doi.org/10.3390/gels6040041.

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The role of specific interactions in the self-assembly process of low molecular weight gelators (LMWGs) was studied by altering the nonbonding interactions responsible for gel formation via structural modification of the gelator/nongelator. This was achieved by modifying pyridyl moieties of bis(pyridyl) urea-based hydrogelator (4–BPU) and the isomer (3–BPU) to pyridyl N–oxide compounds (L1 and L2, respectively). The modification of the functional groups resulted in the tuning of the gelation properties of the parent gelator, which induced/enhanced the gelation properties. The modified compound
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Alegre-Requena, Juan V., Santiago Grijalvo, Diego Sampedro, et al. "Sulfonamide as amide isostere for fine-tuning the gelation properties of physical gels." RSC Advances 10, no. 19 (2020): 11481–92. http://dx.doi.org/10.1039/d0ra00943a.

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Dissertations / Theses on the topic "Supramolecular Gelator"

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Abreu, Marlon de Freitas 1978. "Géis supramoleculares : aspectos químicos e físicos de redes nanofibrilares constituídas por agentes gelificantes baseados em glicosídeos." [s.n.], 2012. http://repositorio.unicamp.br/jspui/handle/REPOSIP/249043.

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Orientador: Paulo Cesar Muniz de Lacerda Miranda<br>Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-21T09:25:32Z (GMT). No. of bitstreams: 1 Abreu_MarlondeFreitas_D.pdf: 21101958 bytes, checksum: 66d47016a4102485845b17df067519a7 (MD5) Previous issue date: 2012<br>Resumo: O trabalho versa sobre a síntese de doze gelificantes (LMOGs) e um estudo sobre automontagem supramolecular dos LMOGs na construção de nanofibras. Foram sintetizadas duas séries de compostos derivados do metil 4,6-O-benzilideno-a-D-glicopiranosideo substituído
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Simões, Thiago Augusto 1985. "Reologia de organogéis baseados em glicosídeos aromáticos." [s.n.], 2014. http://repositorio.unicamp.br/jspui/handle/REPOSIP/250158.

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Orientador: Edvaldo Sabadini<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-27T01:55:14Z (GMT). No. of bitstreams: 1 Simoes_ThiagoAugusto_M.pdf: 2543594 bytes, checksum: 7e559c17b32f95f43db82455a855492b (MD5) Previous issue date: 2014<br>Resumo: Materiais nanoestruturados apresentam-se em muitas formas diferentes. Um grupo de compostos ainda pouco investigado é o grupo dos organogéis, especialmente aqueles cuja estrutura tridimensional de rede é baseada na auto-organização de compostos orgânicos de baixa massa molecu
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Piana, Francesca. "Urea-based supramolecular gelators : molecular structure-gelation relationship and sensing of organophosphorus compounds." Thesis, University of Southampton, 2015. https://eprints.soton.ac.uk/387350/.

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The aim of this thesis was to study the phenomenon of supramolecular gelation of urea-based gelators and their application as sensors for neutral organophosphorus species such as nerve agents. The work was therefore naturally divided into two major parts. The first part consisted in an investigation of the structure-gelation relationship of a series of urea gelators, in an effort to overcome the serendipitous approach that is widely applied to their discovery. Among the components of the common gelator scaffold that were optimised to deliver the best gelation performance, particular attention
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Maity, A. "Tailoring the optical properties and morphology of low molecular weight based supramolecular gelators." Thesis(Ph.D.), CSIR- National Chemical Laboratory, Pune, 2018. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/4507.

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Foster, Jonathan Andrew. "The design and application of bis-urea derived supramolecular gelators." Thesis, Durham University, 2012. http://etheses.dur.ac.uk/3598/.

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A series of amino-acid derived bis-urea gelators were synthesised, some of which show strong gelation in a wide variety of solvents. The gels were probed at the molecular, microscopic and macroscopic levels to gain insights into the gelation behaviour observed. Mixtures of different gelators also result in gels, some of which show different fibre morphologies and X-ray powder patterns to the pure gelators. The series was extended to include fluorescent 1- and 2-pyrenylalanine derived gelators and the fluorescence behaviour of the gels in solution, the gel state, in mixed gels and with the addi
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Zaupa, Alessandro. "Physical crosslinking of gelatin : a supramolecular approach to biomaterials." Phd thesis, Universität Potsdam, 2010. http://opus.kobv.de/ubp/volltexte/2011/5288/.

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This work describes the realization of physically crosslinked networks based on gelatin by the introduction of functional groups enabling specific supramolecular interactions. Molecular models were developed in order to predict the material properties and permit to establish a knowledge-based approach to material design. The effect of additional supramolecular interactions with hydroxyapaptite was then studied in composite materials. The calculated properties are compared to experimental results to validate the models. The models are then further used for the study of physically crosslinked n
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Williams, Kristopher Aaron. "Synthesis and Characterization of Monosaccharide-derived Low Molecular Weight Gelators." ScholarWorks@UNO, 2011. http://scholarworks.uno.edu/td/135.

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Low molecular weight gelators (LMWGs) are interesting materials whose applications are as diverse and wide ranging as their molecular structures. These materials self-assemble through the formation of non-covelent intermolecular forces and interactions to form supramolecular assemblies that trap solvent within their matrices. Because of the non-covalent nature of the forces of self-assembly, the gelation process is typically thermally reversible. In addition, low molecular weight gelators can also be modified to respond to various stimuli, such as change in pH, presence of enzymes or metal cat
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Pi, i. Boleda Bernat. "Supramolecular studies on the behaviour of different chiral cycloalkane-based compounds as receptors, gelators and surfactants." Doctoral thesis, Universitat Autònoma de Barcelona, 2016. http://hdl.handle.net/10803/400575.

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En aquesta tesi, s’han estudiat quatre diferent sistemes supramoleculars com a receptors, gelificadors o tensioactius. S’ha analitzat la influència de diferents factors estructurals de la molècula senzilla en la seva propietat supramolecular final. S’han utilitzat diferents estratègies per a preparar els compostos estudiats. La combinació de diferents tècniques ens ha permès entendre millor aquests sistemes obtenint un resultat sinèrgic. Els resultats d’aquesta tesi estan dividits en quatre capítols: 1) Diferents receptors d’anions tripodals s’han sintetitzat i la seva complexació amb difer
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Zaupa, Alessandro [Verfasser], and Andreas [Akademischer Betreuer] Lendlein. "Physical crosslinking of gelatin : a supramolecular approach to biomaterials / Alessandro Zaupa. Betreuer: Andreas Lendlein." Potsdam : Universitätsbibliothek der Universität Potsdam, 2010. http://d-nb.info/1014619084/34.

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Pleines, Maximilian. "Viscosity-control and prediction of microemulsions." Thesis, Montpellier, 2018. http://www.theses.fr/2018MONTS139.

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La viscosité est une propriété fondamentale des fluides complexes et qui reste encore difficile à prédire quantitativement. Cette propriété macroscopique provient de propriétés moléculaires et mésoscopiques. La compréhension et l’estimation de l'évolution de la viscosité avec des paramètres variables est important pour plusieurs applications, entre autres pour l’extraction liquide-liquide et pour la formulation de systèmes tensioactifs aqueux.Dans ce travail, un modèle "minimal" prenant en compte les énergies libres mises en jeu a été développé pour aider à comprendre, contrôler et prédire l'é
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Books on the topic "Supramolecular Gelator"

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Frédéric, Fages, and Araki K, eds. Low molecular mass gelators: Design, self-assembly, function. Springer, 2005.

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Fages, Frederic. Low Molecular Mass Gelators: Design, Self-Assembly, Function. Springer Berlin / Heidelberg, 2010.

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Fages, Frederic. Low Molecular Mass Gelators : Design, Self-Assembly, Function (Topics in Current Chemistry) (Topics in Current Chemistry). Springer, 2005.

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Book chapters on the topic "Supramolecular Gelator"

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Rubio-Magnieto, Jenifer, and Beatriu Escuder. "Chapter 5. Exploring Gelator Efficiency." In Monographs in Supramolecular Chemistry. Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788013147-00129.

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Dastidar, Parthasarathi, Uttam Kumar Das, Tapas Kumar Adalder, Joydeb Majumder, and Rajdip Roy. "Designing Charge-Assisted Hydrogen Bonded Supramolecular Gelators." In Lecture Notes in Chemistry. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-45780-1_4.

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Esch, Jan, Franck Schoonbeek, Maaike Loos, E. Marc Veen, Richard M. Kellogg, and Ben L. Feringa. "Low Molecular Weight Gelators for Organic Solvents." In Supramolecular Science: Where It Is and Where It Is Going. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4554-1_14.

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Loh, X. J. "Supramolecular Gelators in a Biomedical Context." In Comprehensive Supramolecular Chemistry II. Elsevier, 2017. http://dx.doi.org/10.1016/b978-0-12-409547-2.12567-3.

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Herning, T., I. Pezron, G. Takerkart, S. Tournier-Dumas, and M. Djabourov. "Structure of gelatin solutions and gels." In Gums and stabilisers for the Food industry 6. Oxford University PressOxford, 1992. http://dx.doi.org/10.1093/oso/9780199632848.003.0006.

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Abstract We have investigated gelatin solutions and gels by using a variety of scattering techniques : light and small angle neutron scattering, together with dynamic light scattering. These experiments allow us to fully characterize the conformation of gelatin chains and their dynamic behavior. In dilute solutions, the radius of gyration, the persistence length, the virial coefficient and the self-diffusion coefficient have been measured. With increasing concentrations, in the semi-dilute state, we determined the typical hydrodynamic and static correlation lengths, but we also point out that
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Bhattacharya, Santanu. "Design of amphiphiles for the modulation of catalytic, membranous and gelation properties." In Supramolecular Organization and Materials Design. Cambridge University Press, 2001. http://dx.doi.org/10.1017/cbo9780511564987.006.

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Conference papers on the topic "Supramolecular Gelator"

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Yegin, Cengiz, Cenk Temizel, Yagmur Yegin, et al. "Improving Reservoir Conformance Control Through Next-Generation Supramolecular Gelators and Their Use in Hydraulic Fracturing." In SPE Annual Caspian Technical Conference and Exhibition. Society of Petroleum Engineers, 2017. http://dx.doi.org/10.2118/188997-ms.

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Yegin, Cengiz, Cenk Temizel, Yagmur Yegin, et al. "Improving Reservoir Conformance Control Through Next-Generation Supramolecular Gelators and their Use in Hydraulic Fracturing (Azeri)." In SPE Annual Caspian Technical Conference and Exhibition. Society of Petroleum Engineers, 2017. http://dx.doi.org/10.2118/188997-az.

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Almeida, Ekmagage Don N., Leela Rakesh, Stanley Hirschi, and Anja Mueller. "Solution Rheology of Saline and Polysaccharide Systems." In ASME 2006 International Mechanical Engineering Congress and Exposition. ASMEDC, 2006. http://dx.doi.org/10.1115/imece2006-15906.

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The problem of the characterization of the solution properties of water soluble polymers is long-standing. These polymers tend to form aggregated supramolecular gels that are resistant to molecular dispersion. These materials are being widely used in a variety of industrial applications. Their principle functions are as rheological modifiers, where they thicken or gel solutions in products such as hair-care, detergents, air fresheners and foods; as flocculants for particle separation as applied to water clarification, sewage, and effluent treatment, and as stabilizers to control the properties
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