Journal articles on the topic 'Superglasse'

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1

Ameen, Ahmed W., Peter M. Budd, and Patricia Gorgojo. "Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help?" Membranes 10, no. 12 (December 10, 2020): 413. http://dx.doi.org/10.3390/membranes10120413.

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Superglassy polymers have emerged as potential membrane materials for several gas separation applications, including acid gas removal from natural gas. Despite the superior performance shown at laboratory scale, their use at industrial scale is hampered by their large drop in gas permeability over time due to physical aging. Several strategies are proposed in the literature to prevent loss of performance, the incorporation of fillers being a successful approach. In this work, we provide a comprehensive economic study on the application of superglassy membranes in a hybrid membrane/amine process for natural gas sweetening. The hybrid process is compared with the more traditional stand-alone amine-absorption technique for a range of membrane gas separation properties (CO2 permeance and CO2/CH4 selectivity), and recommendations for long-term membrane performance are made. These recommendations can drive future research on producing mixed matrix membranes (MMMs) of superglassy polymers with anti-aging properties (i.e., target permeance and selectivity is maintained over time), as thin film nanocomposite membranes (TFNs). For the selected natural gas composition of 28% of acid gas content (8% CO2 and 20% H2S), we have found that a CO2 permeance of 200 GPU and a CO2/CH4 selectivity of 16 is an optimal target.
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2

Kleemann, Wolfgang, and Jan Dec. "Relaxor ferroelectrics and related superglasses." Ferroelectrics 553, no. 1 (December 10, 2019): 1–7. http://dx.doi.org/10.1080/00150193.2019.1683489.

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3

Hunt, B., E. Pratt, V. Gadagkar, M. Yamashita, A. V. Balatsky, and J. C. Davis. "Evidence for a Superglass State in Solid 4He." Science 324, no. 5927 (April 30, 2009): 632–36. http://dx.doi.org/10.1126/science.1169512.

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4

Golemme, Gianni, Andrea Bruno, Raffaella Manes, and Daniela Muoio. "Preparation and properties of superglassy polymers — zeolite mixed matrix membranes." Desalination 200, no. 1-3 (November 2006): 440–42. http://dx.doi.org/10.1016/j.desal.2006.03.396.

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5

Andrady, Anthony L., Timothy C. Merkel, and Lora G. Toy. "Effect of Particle Size on Gas Permeability of Filled Superglassy Polymers." Macromolecules 37, no. 11 (June 2004): 4329–31. http://dx.doi.org/10.1021/ma049510u.

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6

Kleemann, Wolfgang, and Jan Dec. "Ferroic superglasses: Relaxor ferroelectrics PMN and SBN vs. CoFe superspin glass." Ferroelectrics 534, no. 1 (October 3, 2018): 1–10. http://dx.doi.org/10.1080/00150193.2018.1473454.

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7

Muzzi, Chiara, Alessio Fuoco, Marcello Monteleone, Elisa Esposito, Johannes C. Jansen, and Elena Tocci. "Optical Analysis of the Internal Void Structure in Polymer Membranes for Gas Separation." Membranes 10, no. 11 (November 5, 2020): 328. http://dx.doi.org/10.3390/membranes10110328.

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Global warming by greenhouse gas emissions is one of the main threats of our modern society, and efficient CO2 capture processes are needed to solve this problem. Membrane separation processes have been identified among the most promising technologies for CO2 capture, and these require the development of highly efficient membrane materials which, in turn, requires detailed understanding of their operation mechanism. In the last decades, molecular modeling studies have become an extremely powerful tool to understand and anticipate the gas transport properties of polymeric membranes. This work presents a study on the correlation of the structural features of different membrane materials, analyzed by means of molecular dynamics simulation, and their gas diffusivity/selectivity. We propose a simplified method to determine the void size distribution via an automatic image recognition tool, along with a consolidated Connolly probe sensing of space, without the need of demanding computational procedures. Based on a picture of the void shape and width, automatic image recognition tests the dimensions of the void elements, reducing them to ellipses. Comparison of the minor axis of the obtained ellipses with the diameters of the gases yields a qualitative estimation of non-accessible paths in the geometrical arrangement of polymeric chains. A second tool, the Connolly probe sensing of space, gives more details on the complexity of voids. The combination of the two proposed tools can be used for a qualitative and rapid screening of material models and for an estimation of the trend in their diffusivity selectivity. The main differences in the structural features of three different classes of polymers are investigated in this work (glassy polymers, superglassy perfluoropolymers and high free volume polymers of intrinsic microporosity), and the results show how the proposed computationally less demanding analysis can be linked with their selectivities.
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8

Boninsegni, Massimo, Nikolay Prokof’ev, and Boris Svistunov. "Superglass Phase ofHe4." Physical Review Letters 96, no. 10 (March 16, 2006). http://dx.doi.org/10.1103/physrevlett.96.105301.

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9

Larson, Derek, and Ying-Jer Kao. "Tuning the Disorder in Superglasses." Physical Review Letters 109, no. 15 (October 9, 2012). http://dx.doi.org/10.1103/physrevlett.109.157202.

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10

Yu, Xiaoquan, and Markus Müller. "Mean field theory of superglasses." Physical Review B 85, no. 10 (March 19, 2012). http://dx.doi.org/10.1103/physrevb.85.104205.

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11

Biroli, Giulio, Claudio Chamon, and Francesco Zamponi. "Theory of the superglass phase." Physical Review B 78, no. 22 (December 8, 2008). http://dx.doi.org/10.1103/physrevb.78.224306.

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12

Tam, Ka-Ming, Scott Geraedts, Stephen Inglis, Michel J. P. Gingras, and Roger G. Melko. "Superglass Phase of Interacting Bosons." Physical Review Letters 104, no. 21 (May 25, 2010). http://dx.doi.org/10.1103/physrevlett.104.215301.

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13

Gordillo, M. C., and J. Boronat. "H2 superglass on an amorphous carbon substrate." Physical Review B 107, no. 6 (February 23, 2023). http://dx.doi.org/10.1103/physrevb.107.l060505.

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14

Hertkorn, J., J. N. Schmidt, M. Guo, F. Böttcher, K. S. H. Ng, S. D. Graham, P. Uerlings, T. Langen, M. Zwierlein, and T. Pfau. "Pattern formation in quantum ferrofluids: From supersolids to superglasses." Physical Review Research 3, no. 3 (August 6, 2021). http://dx.doi.org/10.1103/physrevresearch.3.033125.

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15

Angelone, Adriano, Fabio Mezzacapo, and Guido Pupillo. "Superglass Phase of Interaction-Blockaded Gases on a Triangular Lattice." Physical Review Letters 116, no. 13 (April 1, 2016). http://dx.doi.org/10.1103/physrevlett.116.135303.

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16

Piekarska, Anna M., and Tadeusz K. Kopeć. "Emergence of a superglass phase in the random-hopping Bose-Hubbard model." Physical Review B 105, no. 17 (May 10, 2022). http://dx.doi.org/10.1103/physrevb.105.174203.

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17

Kleemann, Wolfgang, and Jan Dec. "Ferroic superglasses: Polar nanoregions in relaxor ferroelectric PMN versus CoFe superspins in a discontinuous multilayer." Physical Review B 94, no. 17 (November 18, 2016). http://dx.doi.org/10.1103/physrevb.94.174203.

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18

Almansour, Faiz, Monica Alberto, Andrew B. Foster, Sajjad Mohsenpour, Peter Martin Budd, and Patricia Gorgojo. "Thin film nanocomposite membranes of superglassy PIM-1 and amine-functionalised 2D fillers for gas separation." Journal of Materials Chemistry A, 2022. http://dx.doi.org/10.1039/d2ta06339e.

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