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Academic literature on the topic 'Sunderland A.F.C'

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Published: 25 July 2024
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Journal articles on the topic "Sunderland A.F.C"

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Olmstead, Richard. "Plant Systematics: A Phylogenetic Approach, 2nd ed.—W. S. Judd, C. S. Campbell, E. A. Kellogg, P. F. Stevens, and M. J. Donoghue. 2002. Sinauer Associates, Sunderland, MA. 576 pp. ISBN 0–87893–403–0. $89.95 hardcover." Systematic Biology 53, no. 3 (June 1, 2004): 517–18. http://dx.doi.org/10.1080/10635150490445878.

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Alford, Ross A. "Herpetology." Phyllomedusa: Journal of Herpetology 15, no. 1 (July 1, 2016): 95. http://dx.doi.org/10.11606/issn.2316-9079.v15i1p95-97.

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Pough, F. H., R. M. Andrews, M. L. Crump, A.H. Savitzky, K. D. Wells, and M. C.Brandley. 2016. Herpetology. FourthEdition. 591 pp. Sinauer Associates, Inc.,Sunderland, MA, USA.ISBN-10: 1605352330ISBN-13: 978-1605352336Price: USD 88.36www.sinauer.com
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Donovan, G., S. Wilkes, J. Ling, and F. Smith. "Exploration of a community pharmacy delivered mobile health intervention to support medication taking for patients with multiple long-term conditions." International Journal of Pharmacy Practice 30, Supplement_2 (November 30, 2022): ii18—ii19. http://dx.doi.org/10.1093/ijpp/riac089.020.

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Abstract Introduction Up to half of people with long-term conditions (LTCs) do not take their medicines as prescribed. Mobile health interventions, such as text messaging, have been shown to have positive impact on medication adherence.1 However, interventions for patients with multiple LTCs are lacking, and there are limited examples of their delivery from community pharmacy settings. We have developed a new intervention which combines a pharmacist consultation and automated two-way text messaging to support medicines taking. This has been developed using peer-reviewed literature and focus groups with patients and healthcare professionals (GPs, pharmacists, nurses). The intervention is tailored to the individual using a questionnaire and delivers content for up to eight LTCs. Aim To explore the acceptability of our new intervention with patients. Methods The new intervention was delivered to patients in a simulated environment, including a consultation with a pharmacist and two weeks of text messaging. Diary-interviews were used to gather feedback from eight patients, recruited through a public, patient and carer involvement group based at a university. Patients kept a diary during the period of text messaging and follow-up semi-structured interviews were conducted. Interviews were audio recorded and transcribed verbatim for analysis. Transcripts were coded for aspects of the intervention that the patients liked and ideas on how the intervention could be changed, including the impact of delivering the intervention from community pharmacies. Ethical approval for this study was granted by the University of Sunderland Research Ethics Committee. Results The intervention had good acceptability with patients. Patients were happy to interact with the text messaging content, including providing information about symptoms of their long-term condition and result of home monitoring. Patients liked that the intervention was linked to a pharmacist consultation, where there were opportunities to identify medication issues which text messaging could not solve. Delivering the intervention from a community pharmacy setting was felt to promote stronger engagement with the text messaging component, including the opportunity to build rapport with the pharmacist who would be overseeing the intervention. The mechanism to monitor medication adherence using two-way text messaging was suggested to be made more streamlined, and patients also wanted more examples of text message responses included in the patient information leaflet for the intervention. Discussion/Conclusion We found that our intervention to support medication taking from community pharmacies has initial acceptability with patients. Whilst others have trialled similar technologies from community pharmacies2 our intervention focussed solely on medication taking, and this seemed to result in positive attitudes towards its delivery from community pharmacies. The consultation was found to be an important component alongside the text messaging, how combining digital and non-digital components work together to support medication adherence was a gap highlighted in our previous review of similar interventions.3 Our intervention now requires changes based on the feedback gathered in this study and further testing in a larger and more diverse group. References 1. Thakkar J, Kurup R, Laba T-L, Santo K, Thiagalingam A, Rodgers A, et al. Mobile Telephone Text Messaging for Medication Adherence in Chronic Disease: A Meta-analysis. JAMA Intern Med. 2016;176:340–9. 2. Cork T, Sanzeri D, Chambers R, Chamber C. Can pharmacists promote self-care using digital technology? Prescriber. 2018;29:21–4. 3. Donovan G, Hall N, Ling J, Smith F, Wilkes S. Influencing medication taking behaviors using automated two-way digital communication: A narrative synthesis systematic review informed by the Behavior Change Wheel. Br J Health Psychol. n/a n/a. https://doi.org/10.1111/bjhp.12580.
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Belousov, L. V. "Scott F. Gilbert—Developmental Biology, 2010, Sinauer Associates, Inc., Sunderland, MA Ninth Edition." Russian Journal of Developmental Biology 42, no. 5 (September 2011): 349. http://dx.doi.org/10.1134/s1062360411050043.

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McGuire, Jimmy A. "Herpetology. Fourth Edition. By F. Harvey Pough, Robin M. Andrews, Martha L. Crump, Alan H. Savitzky, Kentwood D. Wells, and Matthew C. Brandley. Sunderland (Massachusetts): Sinauer Associates. $99.95. xvi + 591 p.; ill. + G-1 - G-8; LC-1 - LC-92; TI-1 - TI-12; SI-1 - SI-16. ISBN: 978-1-60535-233-6. [A companion website is available.] 2016." Quarterly Review of Biology 93, no. 1 (March 2018): 55. http://dx.doi.org/10.1086/696786.

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Herrera-Alvarez, Cesar, Simón Hernández-Ortega, and David Morales-Morales. "C—H...F, C—F...π and C—F...F—C interactions in a palladium(II) benzenethiolate complex." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (April 25, 2007): m1490—m1491. http://dx.doi.org/10.1107/s1600536807019605.

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Walsh, Tim. "‘Signs and Wonders That Lie’: Unlikely Polemical Outbursts Against the Early Pentecostal Movement in Britain." Studies in Church History 41 (2005): 410–22. http://dx.doi.org/10.1017/s0424208400000358.

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The phenomenon of speaking in tongues was manifested at All Saints’ Parish Church, Monkwearmouth, Sunderland, during the autumn of 1907. This outbreak rapidly became the object of criticism and opposition from a variety of sources, but one of the most vehement, if unexpected, emanated from an organization known as the Pentecostal League of Prayer. This non-denominational body had been established by Reader Harris Q. C. in 1891, and integral to its aims was the promotion of ‘Holiness’ teaching which advocated an experience of sanctification distinct from, and subsequent to, conversion. A network of branches had been established across England, and the Revd Alexander A. Boddy, vicar of All Saints’, had been actively involved in its Sunderland branch prior to 1907. Harris, who was in Sunderland at the time of this new departure in All Saints’, objected to the identification of the ‘gift of tongues’ with what he perceived to be genuine Pentecostal experience. One of the principal ironies of the situation is that his opposition was promulgated in the Pentecostal League’s periodical Tongues of Fire. It is contested that this local controversy represents not only a curious chapter in the history of Protestant polemics against the miraculous, but that it embodied broader ramifications than might first appear, not least in the impetus generated toward the establishment of distinctive Pentecostal identity and orthodoxy.
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Anzeneder, Sofia, Valentin Benzing, and Mirko Schmidt. "Designed acute physical activity to benefit primary school children’s cognition: Effects of cognitive challenge, bout duration and positive affect." Current Issues in Sport Science (CISS) 8, no. 2 (February 14, 2023): 025. http://dx.doi.org/10.36950/2023.2ciss025.

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Introduction Acute bouts of physical activity (PA) have the potential to transiently enhance children’s cognition (Ludyga et al., 2016). Although these positive results seem to be relatively consistent, there is considerable heterogeneity in the magnitude of effects (Lubans et al., 2022). Cognitive benefits are largely influenced by the interaction of quantitative and qualitative PA task characteristics (Lubans et al., 2022; Pesce, 2012), as well as by individual differences in responsiveness to PA bouts (Herold et al., 2021). Understanding the individual and joint effects of moderators is of great practical importance in the educational setting (Schmidt et al., 2021). This information could help to design and individualize PA breaks to enhance cognitive functions that are essential for learning and academic achievement, such as executive functions (EFs; responsible for self-regulation and goal-directed behavior) and attention (responsible for allocation of resources). Among PA task characteristics, the level of cognitive challenge has attracted increasing interest; however, a low comparability of PA studies varying in both quantitative parameters and qualitative modality do not allow for definitive conclusions (Paschen et al., 2019; Schmidt et al., 2021). Moreover, preliminary evidence highlights that positive affect induced by the PA bout may mediate PA effects on cognition (Schmidt et al., 2016). Thus, the aim of the research program was threefold: (1) shed light on which cognitive challenge level in acute PA may affect children’s EFs and attention (“cognitive challenge” study); (2) investigate which bout duration of the identified optimal cognitive challenge level is necessary to reap largest benefits (“bout duration” study); and (3) manipulate positive affect through supportive feedback (and music) to elucidate its influence on cognitive performance (“positive affect” study). Methods Three studies with within-subjects experimental design were conducted with 5th-6th graders (N = 110, N = 114, N = 102; determined by a-priori power analyses). Each study used an exergame (i.e., active video game that involves gross-motor PA) as intervention, performed at 65% maximum heart rate (HR). For the studies, the following experimental conditions were used: “Cognitive challenge” study: three sessions (15-min) with different cognitive challenge levels (low, mid, high), continuously adapted to the individual ongoing performance by an ascending number of distracting stimuli and misleading cues. “Bout duration” study: four sessions with the same, individually adapted cognitive challenge level (chosen according to “cognitive challenge” study) and different PA durations (5-, 10-, 15-, 20-min). “Positive affect” study: three sessions with the same cognitive challenge level and duration of the PA bout (chosen according to “cognitive challenge” and “bout duration” studies) and different affect-inducing feedback (no feedback, music with sound effects, music with sound effects and verbal supportive feedback). Each exergame session was performed individually during school hours (once a week). Children wore motion-based trackers and a HR sensor, while playing a virtual game that required performing different movements (e.g., jumps, squats, punches). During each session (every 5 minutes), perceived physical and cognitive challenge, as well as affective states were assessed. After the exergame, executive control (flanker effect), attentional alerting and orienting, and their interactive functioning were assessed by a child-adapted attention network test (ANT-R; Fan et al., 2009). Repeated measures ANOVAs were calculated to analyze intervention effects on reaction times (RTs) and accuracy data, with subsequent post-hoc Bonferroni-adjusted comparisons. Results “Cognitive challenge” study. A significant interaction for RTs between cognitive challenge and flanker conditions emerged [F(2, 100) = 4.16, p = .018, ƞ2p = .07], with no effects for accuracy. Post-hoc analyses of RT difference data (incongruent – congruent, i.e., flanker effect) revealed best performance after the high-challenge condition (ps < .045; ƞ2ps > .01). Regarding differential effects, adding sex to the model showed that it moderated the effect of cognitive challenge on the interactive functioning of executive control and attentional orienting [F(6, 96) = 2.33, p = .038, ƞ2p = .12]. “Bout duration” study. A significant effect of duration on overall RTs emerged [F(3, 101) = 4.04, p = .009, ƞ2p = .11], with no effects on accuracy. Post-hoc comparisons revealed significantly faster RTs after the 15-min compared to the 10-min condition (p = .019, ƞ2p = .09). Regarding differential effects, adding habitual PA level to the model showed that it moderated the effect of duration on the interactive functioning of executive control and attentional orienting [F(3, 100) = 4.81, p = .004, ƞ2p = .13]. “Positive affect” study. Ongoing – results will be presented at the SGS-meeting. Discussion The high-challenging bout benefited children’s executive control the most (“cognitive challenge” study), supporting the hypothesis that PA designed to generate cognitive engagement may facilitate performance in subsequent EF tasks (i.e., cognitive stimulation hypothesis; Pesce, 2012). However, attentional alerting and orienting were unaffected in the current study, which is in line with the absence of effects found for aerobic PA bouts (van den Berg et al., 2018). The 15-min cognitively high-challenging bout benefited children’s overall information processing speed the most, with no duration-dependent differences for executive control, alerting or orienting (“bout duration” study). Results extend to acute cognitively challenging PA the duration-dependent effects that have been found for acute high-intensity or aerobic PA bouts on overall information processing, but neither on EFs (Hatch et al., 2021), nor on alerting and orienting (van den Berg et al., 2018). Interestingly, in both “cognitive challenge” and “bout duration” studies an intriguing interplay between individual and tasks characteristics on the interactive functioning of executive control and orienting networks emerged. Indeed, the high-challenging bout benefited – for males only – also the efficiency of executive control under disadvantageous spatial attention conditions, consistent with previous adult studies without PA (Li et al., 2021). Whereas, the 15-min duration benefited the same interactive functioning for more active children only, which is in line with evidence that cognitively challenging PA bouts benefit EF efficiency more in children who are physically and cognitively better equipped to capitalize on it (Jäger et al., 2015). The added value of the present studies within an inconsistent evidence base (Paschen et al., 2019; Schmidt et al., 2021) is threefold. The studies allowed to (1) disentangle cognitive from physical challenge effects, while individualizing cognitive challenge; (2) identify the optimal duration for learning contexts; and (3) further the understanding of the interplay between individual and task characteristics. The “positive affect” study will complement the investigation of individual- and task-level moderators with information on positive affect as potential mediator for the acute PA-cognition relation. Results of the research program may inform the design of acute and chronic PA studies implemented in the school context, to capitalize jointly on physical and cognitive benefits of PA. References Fan, J., Gu, X., Guise, K. G., Liu, X., Fossella, J., Wang, H., & Posner, M. I. (2009). Testing the behavioral interaction and integration of attentional networks. Brain and Cognition, 70(2), 209–220. https://doi.org/10.1016/j.bandc.2009.02.002 Hatch, L. M., Dring, K. J., Williams, R. A., Sunderland, C., Nevill, M. E., & Cooper, S. B. (2021). Effect of differing durations of high-intensity intermittent activity on cognitive function in adolescents. International Journal of Environmental Research and Public Health, 18(21), Article 11594. https://doi.org/10.3390/ijerph182111594 Herold, F., Törpel, A., Hamacher, D., Budde, H., Zou, L., Strobach, T., Müller, N. G., & Gronwald, T. (2021). Causes and consequences of interindividual response variability: A call to apply a more rigorous research design in acute exercise-cognition studies. Frontiers in Physiology, 12, Article 682891. https://doi.org/10.3389/fphys.2021.682891 Jäger, K., Schmidt, M., Conzelmann, A., & Roebers, C. M. (2015). The effects of qualitatively different acute physical activity interventions in real-world settings on executive functions in preadolescent children. Mental Health and Physical Activity, 9, 1–9. https://doi.org/10.1016/j.mhpa.2015.05.002 Li, Y., Wang, Y., Jin, X., Niu, D., Zhang, L., Jiang, S. Y., Ruan, H. D., & Ho, G. W. (2021). Sex differences in hemispheric lateralization of attentional networks. Psychological Research, 85(7), 2697–2709. https://doi.org/10.1007/s00426-020-01423-z Lubans, D. R., Leahy, A. A., Mavilidi, M. F., & Valkenborghs, S. R. (2022). Physical activity, fitness, and executive functions in youth: Effects, moderators, and mechanisms. Current Topics in Behavioral Neurosciences, 53, 103–130. https://doi.org/10.1007/7854_2021_271 Ludyga, S., Gerber, M., Brand, S., Holsboer-Trachsler, E., & Pühse, U. (2016). Acute effects of moderate aerobic exercise on specific aspects of executive function in different age and fitness groups: A meta-analysis. Psychophysiology, 53(11), 1611–1626. https://doi.org/10.1111/psyp.12736 Paschen, L., Lehmann, T., Kehne, M., & Baumeister, J. (2019). Effects of acute physical exercise with low and high cognitive demands on executive functions in children: A systematic review. Pediatric Exercise Science, 31(3), 267–281. https://doi.org/10.1123/pes.2018-0215 Pesce, C. (2012). Shifting the focus from quantitative to qualitative exercise characteristics in exercise and cognition research. Journal of Sport & Exercise Psychology, 34(6), 766–786. https://doi.org/10.1123/jsep.34.6.766 Schmidt, M., Benzing, V., & Kamer, M. (2016). Classroom-based physical activity breaks and children's attention: Cognitive engagement works! Frontiers in Psychology, 7, Article 1474. https://doi.org/10.3389/fpsyg.2016.01474 Schmidt, M., Egger, F., Anzeneder, S., & Benzing, V. (2021). Acute cognitively challenging physical activity to promote children’s cognition. In R. Bailey (Ed.), ICSSPE perspectives. Physical activity and sport during the first ten years of life: Multidisciplinary perspectives (pp. 141–155). Routledge. van den Berg, V., Saliasi, E., Jolles, J., de Groot, R. H., Chinapaw, M. J. M., & Singh, A. S. (2018). Exercise of varying durations: No acute effects on cognitive performance in adolescents. Frontiers in Neuroscience, 12, Article 672. https://doi.org/10.3389/fnins.2018.00672
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Maroulis, G. "On the Electric Dipole (hyper)polarizability of Difluorodiacetylene (F-C≡C-C≡C-F)." Computing Letters 2, no. 1-2 (March 6, 2006): 15–19. http://dx.doi.org/10.1163/157404006777491936.

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We report static dipole polarizability and hyperpolarizability values difluoroacetylene obtained from finite-field density functional theory and conventional ab initiocalculations with especially designed flexible basis sets of Gaussian-type functions. Our results show that electron correlation has a small effect on the dipole polarizability but a strong one on the hyperpolarizability. The widely used B3LYP method yields molecular properties fairly close to the ab initio ones. The effect of the fluorination on the molecular properties is quite obvious at the self-consistent field level of theory: ᾱ (FCCCCF) < ᾱ (HCCCCF) < ᾱ (HCCCCH) and γ̄ (FCCCCF) < γ̄ (HCCCCF) < γ̄ (HCCCCH).
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Raza, Amra. "F. C. Canal." South Asian Review 31, no. 3 (December 2, 2010): 45–46. http://dx.doi.org/10.1080/02759527.2010.11932766.

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Dissertations / Theses on the topic "Sunderland A.F.C"

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Perry, Ian B. (Ian Brooks). "Transition metal-facilitated C-C and C-F bond forming." Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/112449.

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Thesis: S.B., Massachusetts Institute of Technology, Department of Chemistry, 2017.
Cataloged from PDF version of thesis. "June 2017."
Includes bibliographical references.
Chapter 1. Copper-Catalyzed Asymmetric Addition of Olefin-Derived Nucleophiles to Ketones A copper (I) catalyzed coupling olefins and ketones has been developed for the diastereo- and enantioselective generation of homopropargyl alcohols bearing vicinal stereocenters. This method allows for the generation of enantioenriched tertiary alcohols with a high degree of functional group compatibility. The utility of the process is further illustrated by a large scale synthesis with extremely low catalyst loading as well as the late stage modification of several pharmaceuticals. Chapter 2. Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines We describe the catalytic generation of amines bearing vicinal stereocenters with a moderate degree of diastereoselectivity. The stereoselective hydrocupration of an unactivated olefinic component is followed by nucleophilic addition of the organocuprate to an N-phosphinoyl protected imine. The mild and general process tolerates a broad-range of functionality, and the process was shown to be successful at a gram-scale synthesis. Chapter 3. Palladium-facilitated Regioselective Nucleophilic Fluorination of Aryl and Heteroaryl Halides. The preliminary findings regarding an aryl and heteroaryl halide fluorination process facilitated by palladium as a reagent is described. Stoichiometric studies illustrate the utility of the method in producing aryl fluorides with unprecedented regioselectivity, and preliminary studies into the fluorination of five- and six-membered heteroaryl bromides are described. Halogen atom substitution as a route to irreversible oxidative addition of aryl and heteroaryl halides is discussed. This strategy may serve to facilitate the fluorination of particularly problematic heteroaryl bromide and chloride substrates.
by Ian B. Perry.
S.B.
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LAUFFER, FRIANT ARMELLE. "De l'ozone aux c. F. C. : approche industrielle." Nancy 1, 1993. http://www.theses.fr/1993NAN1P073.

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Neurrisse, André. "Le Franc C. F. A." Paris 2, 1987. http://www.theses.fr/1987PA021018.

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Monnaie forte ou monnaie faible selon que l'on se refere a l'environnement geographique ou a son statut garanti, le franc c. F. A. Constitue un modele unique de monnaie commune a plusieurs etats. L'analyse de ce phenomene contemporain s'effectue selon trois axes : historique, institutionnel et dynamique. Le milieu monetaire africain presente cette particularite d'offrir en moins d'un siecle un raccourci exemplaire de l'evolution generalement d'ordre millenaire de la forme de l'instrument monetaire. Il n'y a guere, les paleo-monnaies etaient encore en usage et les techniques et institutions monetaires de l'occident industrialise se sont trouvees en situation concurrentielle delicate. Il a fallu les remous economiques et politiques de la deuxieme guerre mondiale pour consacrer un statut institutionnel original. C'est en effet en 1945 que le franc c. F. A. A ete cree, marquant a la fois l'autonomie et la dependance monetaire des territoires interesses. Fidelise a la valeur du franc francais, il a subi dans sa mouvance l'erosion due aux tensions contradictoires du mirage centrifuge de l'autonomie politique et du centralisme economique. Neanmoins il a ete conforte par l'esprit associationniste africain et par l'integration concertee des politiques monetaires. En fait, le franc c. F. A. Tire sa force du concours qu'il apporte au developpement des pays concernes, sa vitalite de la maniere dont, sur la base des preferentialites economiques, il fait fonction de reducteur des divergences economiques. Des lors, la question emerge de cerner les conditions optimales d'existence d'une monnaie commune et de s'interroger, finalement sur l'avenir d'une monnaie europeenne.
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Rogers, Joshua Peter. "Photoelectron spectroscopy of (C₆F₆)-ₙ and C₆F₆ · I-clusters in a novel instrument." Thesis, Durham University, 2017. http://etheses.dur.ac.uk/12364/.

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The capabilities of a new photoelectron spectrometer are characterised in the study of (C6F6)n– and (C6F6)I– clusters. The photoelectron spectrometer consists of a series of vacuum chambers that facilitate a molecular beam of gas-phase anions. These anions and clusters are generated at the point of intersection between an electron beam and the supersonic expansion produced by a high temperature Even-Lavie pulsed valve. The anions are extracted orthogonally and mass-separated in a Wiley-McLaren time-of-flight mass spectrometer. The analyte is addressed by a laser pulse produced by either a tuneable nanosecond OPO for one-photon frequency-resolved measurements or a femtosecond pump-probe regime for two-photon time-resolved measurements. The kinetic energy of the resulting photoelectrons are measured in a velocity-map imaging spectrometer. C6F6- is of interest due to the prediction that it ought to host a meta-stable binding mode of the excess electron known as a correlation-bound state (CBS). Similar to other non-valence binding modes, such as the dipole-bound state, this CBS is thought to act as a doorway state in the mechanism of low energy electron capture. The CBS is characterised by a large and diffuse orbital in which the excess electron is bound primarily through charge:induced-dipole interactions with the molecule’s valence orbital system. In the CBS, C6F6- is predicted to adopt a planar geometry like that of the neutral species, in contrast to the buckled geometry adopted when the excess electron occupies a valence orbital. Frequency- and time-resolved measurements of the anion were made in an effort to generate and observe the CBS. Initially, frequency resolved measurements of (C6F6)n– revealed a vertical detachment energy of 1.60 ± 0.07 eV for n = 1, increasing by 200 meV per additional cluster unit up to n = 5. The broad shape of the direct detachment peak confirms the disparity in geometry between the anion and neutral species. However, no evidence of the CBS was evident in these data. In subsequent explorations, an in-situ electron donor was employed to mimic the electron impact process. An I– ion was introduced to the neutral C6F6 molecule to produce clusters of (C6F6)I–. Frequency-resolved measurements of this cluster revealed a mechanism for electron loss below the threshold for the single-photon direct detachment process. This suggested the presence of a charge-transfer channel centred around hv = 3.3 eV. Time-resolved measurements of (C6F6)I– confirmed the presence of the charge-transfer state and revealed an instantaneous and coherent transfer of the electron onwards into the valence orbital system of the C6F6 molecule. This transfer of charge causes the molecule to vibrate as its geometry changes from planar to buckled. The oscillations observed in the photoelectron spectra are coherent and sinusoidal and have a frequency of 121 ± 2 cm−1. This compares very favourably to the frequency of 122 cm−1 calculated by time-dependent density functional theory for the bending mode of C6F6 along the coordinate between the planar and buckled geometries. I argue that this charge-transfer state exhibits the predicted characteristics of a CBS.
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Kervarec, Maëva-Charlotte. "Reactivity of Aluminium chlorofluoride (ACF) towards C−F bond activations and C−F bond formations." Doctoral thesis, Humboldt-Universität zu Berlin, 2021. http://edoc.hu-berlin.de/18452/24074.

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Der Fokus dieser Dissertation lag in der Untersuchung des Potentials von Aluminium-chlorofluorid (ACF) als Katalysator für die Synthese von fluorierten Verbindungen. Insbesondere die C−F-Aktivierung von verschiedenen polyfluorierten Stoffen wurde untersucht, welches die Effizienz des festen Lewis-Säure-Katalysators für diesen Reaktionstyp zeigte. Das potente Treibhausgas 2-Chlor-1,1,1,2-tetrafluorpropan wurde erfolgreich in das dehydrofluorierte Produkt. Weiterhin wurden Umsetzungen von Pentafluorpropan-Isomeren wie z.B. 1,1,1,3,3-Pentafluorpropan, 1,1,1,2,2-Pentafluorpropan und 1,1,1,2,3-Pentafluorpropan mit ACF als Katalysator untersucht. Es konnte gezeigt werden, dass die Aktivierung der primären CH2F-Gruppe in schnell stattfindet und dabei keine Wasserstoffquelle erfordert. Im Kontrast dazu, wurde für die Aktivierung von CF2-Gruppen eine Wasserstoffquelle wie etwa HSiEt3 benötigt und resultierte in der Bildung eines Produktgemischs. Alternativ wurden Hydrofluorierungsreaktionen von mehreren Substraten durch die Synthese und den Einsatz eines neuen Materials erreicht, welches auf der Immobilisierung von HF auf der Oberfläche von ACF beruht. Dieses HF-ACF wurde unter der Verwendung von vielfältigen Charakterisierungsmethoden umfassend untersucht. Die innere Struktur des Festkörpers, wurden mit MAS-NMR-Spektroskopie, FTIR, Inelastische Neutronenstreuung, XRD und Thermoanalyse analysiert Dadurch konnte gezeigt werden, dass eine geringfügige Reorganisation des bulks zu einer besser geordneten Matrix und die Bildung einer mit der ACF-Oberfläche wechselwirkenden Polyfluorid-Struktur vorliegt. Zur Bestimmung der Oberflächengröße wurde das BET-Modell genutzt und zur Analyse der Porengröße wurde die NLDFT verwendet. Abschließend wurden verschiedene Probeverbindungen an der Oberfläche des HF-ACFs adsorbiert um die Azidität der Oberfläche zu bestimmen und es konnte gezeigt werden, dass eine signifikante Reduktion der Lewis- und Brønsted-Azidität vorliegt.
The main focus of this thesis lies in the study of the potential of aluminum chlorofluoride (ACF) as a catalyst for the synthesis of fluorinated compounds. In particular, C−F bond activations of various polyfluorinated compounds were studied, showing the efficiency of this solid Lewis acid catalyst for this type of reaction. The potent greenhouse gas 2-chloro-1,1,1,2-tetrafluoropropane was successfully transformed into the dehydrofluorination product 2-chloro-3,3,3-trifluoropropene under mild conditions. Similarly, transformation of pentafluoropropane isomers, such as 1,1,1,3,3-pentafluoropropane, 1,1,1,2,2- pentafluoropropane and 1,1,1,2,3-pentafluoropropane was also investigated using ACF as a catalyst. It was evidenced that the primary CH2F group present in 1,1,1,2,3-pentafluoropropane was easily activated without the need for a hydrogen source. In contrast, to activate CF2 groups, a hydrogen source such as HSiEt3 was required, generating a variety of products. Alternatively, successful hydrofluorination reactions of several substrates were conducted by synthesizing a new material, based on the loading of hydrogen fluoride (HF) at the surface of ACF. This HF-loaded ACF was deeply studied using a wide range of characterization methods. For the bulk, MAS NMR spectroscopy, Fourier Transform Infrared spectroscopy (FTIR), Inelastic Neutron Scattering (INS), Powder X-Ray Diffraction (P-XRD), and thermoanalysis were performed, revealing a slight reorganization of the bulk towards a better-ordered matrix and the formation of polyfluoride structure interacting with the surface of ACF. The BET model was used for the surface area determination, and the pore size analysis was established using the non local density functional theory (NLDFT). Finally, various probe molecules were adsorbed at the surface of HF-loaded ACF to determine the acidity of the surface, revealing a significantly reduced Lewis and Brønsted acidity.
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Pleyer, Marcus C. F. [Verfasser]. "Föderative Gleichheit. / Marcus C. F. Pleyer." Berlin : Duncker & Humblot, 2019. http://d-nb.info/1238344577/34.

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Roucaute, Yves. "Le P. C. F face à l'état." Paris 10, 1985. http://www.theses.fr/1985PA100232.

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Herbaut, Audrey. "C. F. Ramuz ou l'esthétique du refaire." Artois, 2007. http://www.theses.fr/2007ARTO0007.

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Que ce soit dans ses ouvrages fictifs, critiques ou biographiques, C. F. Ramuz témoigne d’un incessant besoin de réécrire ses œuvres, de les refaire. Qui plus est, le sème du refaire est très présent, voire obsédant, et notre sujet se propose donc d’en explorer les diverses acceptions pour montrer comment la refabrication à l’œuvre dans la création ramuzienne vise à retrouver un cosmos édénique et pérenne, où homme et nature seraient en harmonie, démarche transfiguratrice autant pour l’œuvre que pour l’auteur. Tout d’abord, le paradoxe d’une écriture et d’un écrivain cherchant à atteindre l’élévation par l’humilité, qui prétendent se faire en se défaisant, régresser pour progresser, témoigne du lien intime entre l’éthique et l’esthétique. Ensuite, le sème plastique du refaire et les résonances picturales de l’œuvre sont à lire comme autant de manifestations de la volonté solidificatrice de l’auteur, voire comme un remède à la fugitivité de l’écriture. Puis, l’humanisation de la nature permet à l’auteur de revaloriser la « taille de l’homme » et d’accéder à la grandeur cosmique, dans une relation d’émulation. Enfin, le souffle mythique du cosmos montagnard et la dimension mystique qu’acquiert ainsi l’auteur ont révélé la proximité de la genèse chrétienne et de la génétique ramuzienne. C. F. Ramuz ambitionne donc, à travers le chant de son Rhône , retrouver la « raison d’être » d’ « un pays et d’un homme intimement mêlés ».
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Richou, Françoise. "La J. O. C. F. Dans l'Ouest." Nantes, 1986. http://www.theses.fr/1986NANT3012.

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De mille-neuf-cent-vingt-sept a mille-neuf-cent-quatre-vingt-cinq, le mouvement de la jeunesse ouvriere chretienne, dans ses deux organisations, masculine (j. O. C. ), feminine (j. O. C. F. ), a change. Dans ses adherents : de mouvement de jeunesse, il est devenu organisation de jeunes militants. Dans ses objectifs : de la " rechristianisation ", il est passe a la construction de " l'eglise en classe ouvriere ". Ayant forme, avec ses homologues, la majeure partie du personnel " politique " des annees cinquante et soixante, il est toujours " ecole de militants ". " ouvrier " au sens strict avant-guerre (la quasi-totalite des adherents et des responsables sont de jeunes salaries), l'est-il encore a partir des annees soixante ou les scolaires penetrent en force l'organisation? telles sont les questions et les analyses que suggere l'etude historique et sociologique, constamment placee dans une perspective nationale, de quelques federations jocistes de l'ouest
From nineteen-twenty-seven to nineteen-eighty-five, the youth movement " jeunesse ouvriere chretienne ", with its two organizations, male (joc), female (jocf), has changed. In its recruitment : from youth movement to young militants's organization. In its plans : from the conversion of the working class to christianity to the settling of church in the working class. It has formed most of the political staff of the sixties with the other youth movements. It is always school of militants. According to its militants's social status, is it ever a working class organization nowadays where it is so present in schools? the historical and sociological study of some federations "joc f" in west of france, always placed in a national viewpoint, leads to these questions and analysis
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Zhang, Qi. "Transition-metal-catalyzed C-F bond formation." Diss., University of Iowa, 2016. https://ir.uiowa.edu/etd/3228.

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Fluorine atom plays a very important role in pharmaceuticals, agricultural chemicals, and medical imaging and it has become one of the most popular area in organic chemistry. For example, in modern medicinal chemistry introducing fluorine atom could potentially improve absorption, metabolism and potency of drug candidates. As a result, methods that allow the selective and efficient formation of the carbon-fluorine bond are highly desirable. An evolving approach is the utilization of transition-metals to catalyze the nucleophilic substitution of fluoride ion. This thesis described several novel and efficient methods to generate allylic and benzylic C-F bonds using rhodium/iridium catalyst.
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Books on the topic "Sunderland A.F.C"

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Harsdorff, C. F. C. F. Harsdorff. København: Arkitektens Forlag, 2007.

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Persson, Jonas. ¹⁸F/¹⁹F and ¹¹C/¹⁴C kinetic isotope effects in nucleophilic substitution reactions. Uppsala: Acta Universitatis Upsaliensis, 1995.

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Stéphane, Pétermann, ed. Vies de C. F. Ramuz. Genève: Slatkine, 2013.

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Lehmann, Hans-Ulrich. The Rings by C.-F. Dau. Frankfurt am Main: Verlag Form, 1999.

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Reid, Brian Holden. J. F. C Fuller: Military Thinker. London: Palgrave Macmillan UK, 1987. http://dx.doi.org/10.1007/978-1-349-11742-0.

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Reid, BrianHolden. J. F. C. Fuller: Military thinker. London: Macmillan in association with King's College, London, 1987.

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Català, Agustí Rodes i. Los fundadores del F. C. Barcelona. [Barcelona]: Edicions Joica, 2000.

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Naval Education and Training Program Management Support Activity (U.S.), ed. Aviation boatswain's mate F 1 & C. [Pensacola, Fla: Naval Education and Training Program Management Support Activity], 1989.

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Ahlen, Kunst-Museum, ed. Katrin Wegemann - 37°C - 98,6°F. Bönen]: Verlag Kettler, 2011.

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Tynan, Timothy J. C/F, what else is new? Rapid City, SD: Foley's Custom Print, 1988.

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Book chapters on the topic "Sunderland A.F.C"

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Sánchez-González, José C., José C. Loredo-Narciandi, Peggy Brady-Amoon, Vincent W. Hevern, John A. Mills, Roger K. Thomas, Alan J. Feldman, et al. "Bartlett, F. C." In Encyclopedia of the History of Psychological Theories, 97–98. New York, NY: Springer US, 2012. http://dx.doi.org/10.1007/978-1-4419-0463-8_185.

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Evans, Rand B., Adrian C. Brock, Harris Winitz, David C. Devonis, David C. Devonis, David J. Murray, Nancy Felipe Russo, et al. "Donders, F. C." In Encyclopedia of the History of Psychological Theories, 349–50. New York, NY: Springer US, 2012. http://dx.doi.org/10.1007/978-1-4419-0463-8_59.

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Sánchez-González, José C., José C. Loredo-Narciandi, Peggy Brady-Amoon, Vincent W. Hevern, John A. Mills, Roger K. Thomas, Alan J. Feldman, et al. "Brentano, F. C." In Encyclopedia of the History of Psychological Theories, 131–33. New York, NY: Springer US, 2012. http://dx.doi.org/10.1007/978-1-4419-0463-8_66.

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Syme, Don, Adam Granicz, and Antonio Cisternino. "Interoperating with C and COM." In Expert F#, 491–522. Berkeley, CA: Apress, 2007. http://dx.doi.org/10.1007/978-1-4302-0285-1_17.

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Bagodo, Obarè B. "Holl, Augustin F. C." In Encyclopedia of Global Archaeology, 5228–32. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-30018-0_3389.

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Bagodo, Obarè B. "Augustin F. C. Holl." In Encyclopedia of Global Archaeology, 1–5. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-51726-1_3389-1.

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Hekma, Gert. "Last, Joseph C. F." In Who's Who in Gay and Lesbian History, 255–56. 2nd ed. London: Routledge, 2020. http://dx.doi.org/10.4324/9781003070900-267.

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Syme, Don, Adam Granicz, and Antonio Cisternino. "Interoperating with C and COM." In Expert F# 2.0, 491–521. Berkeley, CA: Apress, 2010. http://dx.doi.org/10.1007/978-1-4302-2432-7_17.

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Smart, Bruce E. "Characteristics of C-F Systems." In Organofluorine Chemistry, 57–88. Boston, MA: Springer US, 1994. http://dx.doi.org/10.1007/978-1-4899-1202-2_3.

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Hiyama, Tamejiro, and Hisashi Yamamoto. "Reactions of C-F Bonds." In Organofluorine Compounds, 119–35. Berlin, Heidelberg: Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04164-2_4.

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Conference papers on the topic "Sunderland A.F.C"

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Cermak-Sassenrath, Daniel, Jenna Gavin, and Matthew Martin. "Makin' f *¢&|# cake." In C&C '13: Creativity and Cognition 2013. New York, NY, USA: ACM, 2013. http://dx.doi.org/10.1145/2466627.2481208.

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FROLOV, S. M. "SPHERICAL DIFFUSION FLAME IN MICROGRAVITY CONDITIONS: FIRST RESULTS OF JOINT RUSSIAN-AMERICAN SPACE EXPERIMENT “FLAME DESIGN - ADAMANT”." In 9TH INTERNATIONAL SYMPOSIUM ON NONEQUILIBRIUM PROCESSES, PLASMA, COMBUSTION, AND ATMOSPHERIC PHENOMENA. TORUS PRESS, 2020. http://dx.doi.org/10.30826/nepcap9a-17.

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The joint NASA-Roscosmos Flame Design (Adamant) spaceflight experiment [1, 2] is one of six International Space Station (ISS) investigations which are currently part of the Advanced Combustion via Microgravity Experiments (ACME) project. It is developed by the U.S. science team including R. L. Axelbaum of Washington University in St. Louis, P. B. Sunderland of the University of Maryland, and D. L. Urban of the NASA Glenn Research Center. The experiment is conducted in collaboration with N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences (S. M. Frolov, V. Ya. Basevich, A. A. Belyaev, F. S. Frolov, S. N. Medvedev, V. S. Posvyanskii, M. Yu. Sinev, and P. A. Vlasov).
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Shamma, David A. "Session details: Keynote 2 by Elizabeth F. Churchill." In C&C '17: Creativity and Cognition. New York, NY, USA: ACM, 2017. http://dx.doi.org/10.1145/3256060.

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Kim, Kisub, Dongsun Kim, Tegawendé F. Bissyandé, Eunjong Choi, Li Li, Jacques Klein, and Yves Le Traon. "F a C o Y." In ICSE '18: 40th International Conference on Software Engineering. New York, NY, USA: ACM, 2018. http://dx.doi.org/10.1145/3180155.3180187.

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Parsch, Jörg, and Joachim W. Engels. "C–F···H–C hydrogen bonds in crystals of fluorobenzene ribonucleosides." In XIth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902011.

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Majid, Abdelfattah, El Mehdi Abdeddine, Khalid Zarbane, and Zitouni Beidouri. "GEOMETRICALLY NON-LINEAR FREE AND FORCED VIBRATION OF C-F-C-F RECTANGULAR PLATE AT LARGE TRANSVERSE AMPLITUDES." In XI International Conference on Structural Dynamics. Athens: EASD, 2020. http://dx.doi.org/10.47964/1120.9018.19213.

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Okino, F., S. Yajima, and H. Touhara. "Fluorination of fullerenes C/sub 60/ and C/sub 70/ and electrochemical properties of C/sub 60/F/sub x/ and C/sub 70/F/sub x/." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835562.

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Wu, Xiugang, and Liang-Liang Xie. "A unified relay framework with both D-F and C-F relay nodes." In 2013 13th Canadian Workshop on Information Theory (CWIT). IEEE, 2013. http://dx.doi.org/10.1109/cwit.2013.6621597.

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Nguyen, Thao-My, Xuan-Tien Le, and Minh-Tam K. Nguyen. "Chemical constituents of Breynia vitis-idaea (Burm. f.) C. E. C. Fischer." In INTERNATIONAL CONFERENCE ON CHEMICAL ENGINEERING, FOOD AND BIOTECHNOLOGY (ICCFB2017): Proceedings of the 3rd International Conference on Chemical Engineering, Food and Biotechnology. Author(s), 2017. http://dx.doi.org/10.1063/1.5000209.

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Archvadze, Natela, and Merab Pkhovelishvili. "Reforming the trees — C# and F# comparison." In 2012 IV International Conference "Problems of Cybernetics and Informatics" (PCI). IEEE, 2012. http://dx.doi.org/10.1109/icpci.2012.6486287.

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Reports on the topic "Sunderland A.F.C"

1

Trowbridge, L. D. Potential Hazards Relating to Pyrolysis of c-C{sub 4}F{sub 8}O, n-C{sub 4}F{sub 10}, and c-C{sub 4}F{sub 8} in Selected Gaseous Diffusion Plant Operations. Office of Scientific and Technical Information (OSTI), March 2000. http://dx.doi.org/10.2172/814073.

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Trowbridge, L. D., and M. G. Otey. Vapor pressures of mixtures of CFC-114 with the potential replacement coolants C{sub 4}F{sub 10} and c-C{sub 4}F{sub 8}. Office of Scientific and Technical Information (OSTI), September 1994. http://dx.doi.org/10.2172/10103734.

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Smith, Matthew L. J. F. C. Fuller: His Methods, Insights, and Vision. Fort Belvoir, VA: Defense Technical Information Center, April 1999. http://dx.doi.org/10.21236/ada363919.

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Ozerov, Oleg V. New Horizons in C-F Activation by Main Group Electrophiles. Office of Scientific and Technical Information (OSTI), February 2016. http://dx.doi.org/10.2172/1237898.

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Dumont, R. Residual total magnetic field, aeromagnetic survey of northern Boothia Peninsula, NTS 57-C/14, 57-C/15, 57-F/2 and 57-F/3, Nunavut. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 2014. http://dx.doi.org/10.4095/293445.

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Bhandari, Vartika, and Nitin H. Vaidya. Capacity of Multi-Channel Wireless Networks with Random (c,f) Assignment. Fort Belvoir, VA: Defense Technical Information Center, June 2007. http://dx.doi.org/10.21236/ada486638.

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Morgan, Randall. Record of Decision Remedial Alternative Selection for the C, F, K, and P-Area Coal Pile Runoff Basins (189-C, 289-F, 189-K, and 189-P). Office of Scientific and Technical Information (OSTI), July 1998. http://dx.doi.org/10.2172/881506.

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Dumont, R. First vertical derivative of the magnetic field, aeromagnetic survey of northern Boothia Peninsula, NTS 57-C/14, 57-C/15, 57-F/2 and 57-F/3, Nunavut. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 2014. http://dx.doi.org/10.4095/293450.

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Trowbridge, L. D., and E. C. Angel. Gas-phase chemical reactivity of CFC-114 and potential replacements. Part 4, Reactivity of c-C{sub 4}F{sub 8} with F{sub 2} and UF{sub 6}. Office of Scientific and Technical Information (OSTI), July 1992. http://dx.doi.org/10.2172/10170246.

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Trowbridge, L. D. Potential Hazards Relating to Pyrolysis of c-C{sub 4}F{sub 8} in Selected Gaseous Diffusion Plant Operations. Office of Scientific and Technical Information (OSTI), March 1999. http://dx.doi.org/10.2172/5824.

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