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Journal articles on the topic 'Sulphone chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Nishikubo, Tadatomi, Atsushi Kameyama, Yoshinari Hosono, and Youji Yamada. "Synthesis of Polymers in Aqueous Solutions: Heterogeneous Oxidation of Poly(Amide-Sulphide) in Water." High Performance Polymers 10, no. 1 (March 1998): 23–31. http://dx.doi.org/10.1088/0954-0083/10/1/004.

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The heterogeneous oxidation of N-(2-phenylthioethyl)benzamide in a dispersion of water was performed with twice the amount of hydrogen peroxide at 60 °C for 72 h as a model reaction of the oxidation of poly(amide-sulphide) (polymer 1), and the corresponding N-[2-(phenylsulphoxy)-ethyl]benzamide and N-[2-(phenylsulphonyl)ethyl]benzamide were obtained in 5% and 95% yields respectively. This suggests that the alkyl phenyl sulphide group was easily oxidized with time via the alkyl phenyl sulphoxide group into the alkyl phenyl sulphone group. On the other hand, when heterogeneous oxidation of diphenyl sulphide in a dispersion of water was carried out with twice the amount of hydrogen peroxide at 60 °C for 72 h, the corresponding diphenyl sulphoxide and diphenyl sulphone were obtained in 77% and 23% yields, respectively. Therefore, the oxidation rate of the diphenyl sulphide group was much slower than that of the alkyl phenyl sulphide group, and the heterogeneous oxidation of diphenyl sulphide with excess hydrogen peroxide in a dispersion of water primarily produced diphenyl sulphoxide under the same conditions. On the basis of these model reactions, the heterogeneous oxidation of polymer 1, which was prepared by the polyaddition of bis(4-mercaptophenyl)sulphide with m-phenylenebis(2-oxazoline), was performed with one to three times the amount of hydrogen peroxide in a dispersion of water at 60 °C, and the Tg of the resulting polymers gradually increased with reaction time from 111 °C to 165 °C. When the oxidization was carried out with three times the amount of hydrogen peroxide for 48 h, the polymer with major structure, poly(amide-sulphone) (polymer 3), was obtained. Polymer 3 was also easily prepared by the oxidization of polymer 1 with equivalent amounts of sodium periodate in a dispersion of water at 60 °C for 48 h.

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2

Giblin, Gerard M. P., Steve H. Ramcharitar, and Nigel S. Simpkins. "Synthesis and stereoselective chemistry of a novel cyclopentadienyl sulphone." Tetrahedron Letters 29, no. 33 (January 1988): 4197–200. http://dx.doi.org/10.1016/s0040-4039(00)80454-2.

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3

Grossert, J. Stuart, Jeffrey Hoyle, T. Stanley Cameron, Stephen P. Roe, and Beverly R. Vincent. "The structures of some sulphur-stabilized carbanions and stereoelectronic requirements for the formation of α-sulphonyl carbanions." Canadian Journal of Chemistry 65, no. 6 (June 1, 1987): 1407–15. http://dx.doi.org/10.1139/v87-238.

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Relatively few structure determinations of α-sulphonyl stabilized carbanions have been reported. The salient features of these are summarized and discussed in the light of the X-ray crystal structures of the potassium salt from bis(methylsulfonyl)-3-(2,6-dimethoxypyridyl)sulfonylmethane (5), the carbon acid bis(methylsulphonyl-4-(1,3-dimethoxyphenyl)sulphonylmethane (6), the triethylammonium salt of 2-methylsulphonyl-2-phenylthio-1-(3-pyridyl)-1-ethanone (7), the carbon acid 2-methyl-sulphonyl-2-phenylthio-1-phenylethanone (8), and its triethylammonium salt (9). Results of these structure determinations show that the α-sulphonyl carbanion has a significantly shorter −C—SO2 bond distance than the free sulphone, but that the S—O bond distances are essentially unchanged. The coordination about the carbanionic carbon atoms is planar; these atoms can be described as interacting with the sulphur atoms in an ylid-like manner, with a barrier to rotation about the −C—SO2 bond. The sulphonyl oxygen atoms do interact to a significant degree with the counterion, but there is no close contact between the counterion and the carbanionic carbon atom. A comparison of the structures of 6 and 5, or of 8 and 9, permits an assessment to be made concerning the stereoelectronics of deprotonation reactions on carbon atoms adjacent to sulphones.

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4

El-Dean, A. M. Kamal, A. A. Atalla, Th A. Mohamed, and A. A. Geies. "Synthesis of Some Pyrazolopyridine Sulphonamide Derivatives." Zeitschrift für Naturforschung B 46, no. 4 (April 1, 1991): 541–46. http://dx.doi.org/10.1515/znb-1991-0417.

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The diazonium salt of 3-aminopyrazolopyridine when treated with SO2 and CuCl2 produces the corresponding sulphonyl chloride. The sulphonyl chloride chloride easily reacts with hydrazine hydrate, ammonia, aromatic or heterocyclic amines to produce the corresponding sulphohydrazide, sulphonamide or N-sulphonamide derivatives. Sulphohydrazide reacts with acetylacetone to produce pyrazoly pyrazolopyridinyl sulphone which is also obtained by reaction of sulphonyl chloride with dimethylpyrazole. The aminopyrazolopyridine can be converte into pyrazolopyridinthiole by its reacting with ethyl dithioxanthate. The pyrazolopyridinthiole reacts with alkyl halides or acrylonitrile to produce S-alkylated derivatives.

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5

WahbaErian, Ayman. "1,1-Dicyano-2-Phenyl-3-Phenylsulphonylpropene: A Novel Reagent in Sulphone Chemistry." Synthetic Communications 28, no. 19 (October 1998): 3549–58. http://dx.doi.org/10.1080/00397919808004901.

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6

Vajda, E., I. Hargittai, and D. Hnyk. "Molecular structure of trans- and cis-methylchlorovinyl sulphone." Journal of Molecular Structure 162, no. 1-2 (November 1987): 75–86. http://dx.doi.org/10.1016/0022-2860(87)85024-x.

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7

Janarthanan, V., Frank E. Karasz, and William J. MacKnight. "Miscibility in polybenzimidazole/polyimide sulphone blends: a comparison of blends containing fluorinated and non-fluorinated polyimide sulphone." Polymer 33, no. 16 (January 1992): 3388–93. http://dx.doi.org/10.1016/0032-3861(92)91096-k.

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8

ABRAHAM, R., I. HAWORTH, A. BUNN, and R. HEARMON. "Substituent effects in the 13C nuclear magnetic resonance spectra of aryl ether copolymers: 2. Ether sulphone/ether ether sulphone and ether sulphone/ether ketone copolymers in deuterated dimethylsulphoxide." Polymer 29, no. 6 (June 1988): 1110–17. http://dx.doi.org/10.1016/0032-3861(88)90024-9.

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9

Cabiddu, Maria G., Salvatore Cabiddu, Claudia Fattuoni, Costantino Floris, Gioanna Gelli, and Stefana Melis. "METALATION REACTIONS. PART XVII. DILITHIATION OF PHENYL ISOPROPYL SULPHONE." Phosphorus, Sulfur, and Silicon and the Related Elements 70, no. 1 (January 1992): 139–43. http://dx.doi.org/10.1080/10426509208049162.

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10

Abraham Joseph, K., and M. Srinivasan. "Synthesis and characterization of polyesters containing sulphide, sulphone or carbonyl groups in their backbones." European Polymer Journal 29, no. 12 (December 1993): 1641–45. http://dx.doi.org/10.1016/0014-3057(93)90259-i.

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11

Pasha, Khalid, and John Anthony Taylor. "An Investigation into the In situ Preparation of Hetero Bifunctional Monochlorotriazinyl-Vinyl Sulphone Reactive Dyes for Cotton." Pakistan Journal of Scientific & Industrial Research Series A: Physical Sciences 59, no. 1 (February 26, 2016): 56–59. http://dx.doi.org/10.52763/pjsir.phys.sci.59.1.2016.56.59.

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An attempt has been made in in-situ preparation and application of two isomers (para and meta) of aminophenyl-b-sulphatoethyl sulphone reagents (PABSES and MABSES) with three dichlorotriazinyldyes i.e. CI Reactive Orange 86, CI Reactive Red 11 and CI Reactive Blue 168 to generate mixed hetero bifunctional dyes in dye bath. Dyeing results when compared with similar targeted type of commerciallyavailable Sumifix Supra dyes were found not up to the mark. Build up properties of all in situ prepared dyes were lower except for few light depth of shades as compared to preformed commercial Sumifix Supradyes. This could be because of inefficient condensation of dichlorotriazinyl dyes with the aminophenyl- b-sulphatoethyl sulphone. However, meta isomer of aminophenyl-b-sulphatoethyl sulphone appeared tobe more effective than the para isomer.

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12

Maes, C., J. Devaux, R. Legras, I. W. Parsons, and P. T. Mcgrail. "Characterization of novel modified amorphous poly (ether sulphone)s." Journal of Polymer Science Part A: Polymer Chemistry 32, no. 16 (December 1994): 3171–82. http://dx.doi.org/10.1002/pola.1994.080321618.

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13

Rajendiran, N., and M. Swaminathan. "Solvatochromism and prototropism of diaminodiphenyl sulphones and 2-aminodiphenyl sulphone: a comparative study by electronic spectra." Journal of Photochemistry and Photobiology A: Chemistry 90, no. 2-3 (September 1995): 109–16. http://dx.doi.org/10.1016/1010-6030(95)04078-t.

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14

Rudź, Wiesław, and Wawrzyniec Podkościelny. "Copolymerization of Bis(4-methacryloymethylphenyl) sulphone with styrene." International Journal of Polymeric Materials 51, no. 3 (January 2002): 257–63. http://dx.doi.org/10.1080/00914030213035.

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15

Abd-Ei-Aziz, Alaa S., Christine R. De Denus, Karen M. Epp, Simone Smith, Richard J. Jaeger, and David T. Pierce. "Effect of ligand structure, solvent, and temperature on the electrochemical behavior of polyarene–iron complexes." Canadian Journal of Chemistry 74, no. 5 (May 1, 1996): 650–57. http://dx.doi.org/10.1139/v96-070.

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The electrochemical investigation of a number of polyarene–iron complexes ([3]2+–[9]5+) containing etheric, sulphide, and sulphone bridges indicated that there were various degrees of interaction based on the nature of the bridging heteroatoms. While the electrochemical investigation of all etheric complexes showed that the metallic moieties behaved as isolated redox centers, it was found that there was electronic communication (ca. 70–80 mV) for the isomeric sulphide complexes [4]2+ and [6]2+. The rate constant of the following chemical reaction (kf) was calculated for some of these complexes and it was found that these rates were affected by the nature of the solvent, the bridging ligand, and the temperature. At various temperatures, kf indicated a higher degree of stability for complexes containing sulphide bridges than for those containing etheric bridges, especially at room temperature. The effect of a strong coordinating solvent, such as acetonitrile, on the kf of complex [3]2+ indicated that the substitution of the arene ligand with acetonitrile molecules proceeded as a dissociative mechanism. Controlled potential coulometry was also used to verify the transfer of two electrons in the first reduction process of the di-iron complexes. Key words: cyclopentadienyliron, cyclic voltammetry, arene complexes, isolated and interacting redox centers.

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16

Anitha, Mandala, and K. C. Kumara Swamy. "Highly functionalised (γ-azido/γ-fluoro-β-iodo/)vinyl derivatives from phosphorus based allenes or allenoates: I⋯O halogen bonding interactions." Organic & Biomolecular Chemistry 17, no. 23 (2019): 5736–48. http://dx.doi.org/10.1039/c9ob00715f.

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γ-Azido/γ-fluoro-β-iodo-vinyl phosphine oxides/phosphonates/esters/sulphone and a γ-diodoallene were synthesised from phosphorus-based allenes or allenoates or a sulphur based allene; in many cases, I⋯O halogen bonding is observed in the solid state.

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17

Krause, Mareli. "Peculiarities in the gas-liquid chromatographic analysis of fenamiphos sulphone." Analyst 110, no. 6 (1985): 673. http://dx.doi.org/10.1039/an9851000673.

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18

Clark, James H., James E. Denness, Andrew J. Wynd, and T. McGrail. "The preparation of a semicrystalline trifluoromethylated poly(aryl ether sulphone)." Journal of Polymer Science Part A: Polymer Chemistry 32, no. 6 (April 30, 1994): 1185–87. http://dx.doi.org/10.1002/pola.1994.080320621.

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19

Schneider, Hans Adam, Wu Jishan, Hans-Joachim Cantow, Brian C. Auman, and Virgil Percec. "Thermally reactive oligomers of aromatic poly(ether sulphone) containing poly(dimethylsiloxane): 2. Mechanical properties in the poly(ether sulphone) glass transition range." Polymer 28, no. 1 (January 1987): 132–38. http://dx.doi.org/10.1016/0032-3861(87)90327-2.

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20

Abraham, Raymond J., and Ian S. Haworth. "13—Lanthanide-induced shift (LIS) investigation of the conformation of aryl sulphones using a novel lanthanide-sulphone complexation model." Magnetic Resonance in Chemistry 26, no. 3 (March 1988): 252–59. http://dx.doi.org/10.1002/mrc.1260260314.

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21

Szeto, Yau Shan, Ching Shan Li, Xi Guang Wu, and Wing Lai Chan. "Transition temperature control of liquid crystalline poly(heptene sulphone)s." Polymer Bulletin 39, no. 2 (August 1997): 179–84. http://dx.doi.org/10.1007/s002890050136.

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22

Li, Ching Shan, Yiu Hung Wong, Yuen Wah Wong, and Yau Shan Szeto. "Triplet energy transport of liquid crystalline poly(dodecene sulphone)s." Polymer Bulletin 42, no. 3 (March 29, 1999): 313–20. http://dx.doi.org/10.1007/s002890050469.

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23

Zhou, Chuanzheng, Wimal Pathmasiri, Dmytro Honcharenko, Subhrangsu Chatterjee, Jharna Barman, and Jyoti Chattopadhyaya. "High-quality oligo-RNA synthesis using the new 2′-O-TEM protecting group by selectively quenching the addition of p-tolyl vinyl sulphone to exocyclic amino functions." Canadian Journal of Chemistry 85, no. 4 (April 1, 2007): 293–301. http://dx.doi.org/10.1139/v07-025.

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During the F–-promoted deprotection of the oligo–RNA, synthesized using our 2′-O-(4-tolylsulfonyl)ethoxymethyl (2′-O-TEM) group [Org. Biomol. Chem. 5, 333 (2007)], p-tolyl vinyl sulphone (TVS) is formed as a by-product. The TVS formed has been shown to react with the exocyclic amino functions of adenosine (A), guanosine (G), and cytidine (C) of the fully deprotected oligo–RNA to give undesirable adducts, which are then purified by HPLC and unambiguously characterized by 1H, 13C Heteronuclear Multiple Bond Correlation (HMBC) NMR and mass spectroscopic analysis. The relative nucleophilic reactivities of the nucleobases toward TVS have been found to be the following: N6–A > N4–C > N2–G > > N3–U. This reactivity of TVS toward RNA nucleobases to give various Michael adducts could, however, be suppressed by using various amines as scavengers. Among all these amines, morpholine and piperidine are the most efficient scavenger for TVS, which gave highly pure oligo–RNA even in the crude form and can be used directly in RNA chemical biology studies.Key words: RNA synthesis, RNA alkylation, p-tolyl vinyl sulphone, Michael addition.

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24

Rudź, Wiesław. "Copolymerization of methyl methacrylate with bis(4-methacryloylmethylphenyl)-sulphone." International Journal of Polymeric Materials 52, no. 3 (January 2003): 219–28. http://dx.doi.org/10.1080/00914030304893.

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25

Yamanaka, Keizo, and Takashi Inoue. "Structure development in epoxy resin modified with poly(ether sulphone)." Polymer 30, no. 4 (April 1989): 662–67. http://dx.doi.org/10.1016/0032-3861(89)90151-1.

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26

Chau, C. C., D. L. Fear, and R. A. Wessling. "Methanol diffusion and relaxation in uniaxially drawn poly(ether sulphone)." Polymer 30, no. 11 (November 1989): 2087–93. http://dx.doi.org/10.1016/0032-3861(89)90299-1.

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27

Ghafor, W. A. S. Abdul. "Schottky effect mechanism in poly(pyromellitic-4,4-diphenyl sulphone) films." Journal of Polymer Science Part B: Polymer Physics 38, no. 19 (2000): 2507–14. http://dx.doi.org/10.1002/1099-0488(20001001)38:19<2507::aid-polb20>3.0.co;2-0.

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28

Kendrick, John. "Calculated energetics of torsional motion in six diphenyl molecules: benzophenone, diphenyl ether, diphenyl sulphide, diphenyl sulphone, diphenylmethane and biphenyl." Journal of the Chemical Society, Faraday Transactions 86, no. 24 (1990): 3995. http://dx.doi.org/10.1039/ft9908603995.

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29

Malik, W. U., R. N. Goyal, and N. C. Mathur. "Electrochemical reduction of fast sulphone black-F, a bisazo dye." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 235, no. 1-2 (October 1987): 225–36. http://dx.doi.org/10.1016/0022-0728(87)85209-9.

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30

Muthu Lakshmi, R. T. S., R. Kumari, and I. K. Varma. "Structure and thermal characterisation of poly(arylene ether sulphone)s." Journal of Thermal Analysis and Calorimetry 78, no. 3 (January 2004): 809–19. http://dx.doi.org/10.1007/s10973-005-0449-0.

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31

Manisankar, P., C. Vedhi, and G. Selvanathan. "Synthesis and characterization of novel nano size electroactive poly 4,4?-diaminodiphenyl sulphone." Journal of Polymer Science Part A: Polymer Chemistry 43, no. 8 (2005): 1702–7. http://dx.doi.org/10.1002/pola.20643.

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32

Di, Yingwei, Domenico Acierno, Alberto D'Amore, Rossella Nobile, and Luigi Nicolais. "Capillary extrusion behavior of phenolphthalein poly(ether-ether-sulphone) (PES-C)." Journal of Applied Polymer Science 65, no. 5 (August 1, 1997): 951–58. http://dx.doi.org/10.1002/(sici)1097-4628(19970801)65:5<951::aid-app13>3.0.co;2-v.

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33

Saeed, Rehana, M. Javaid Mughal, M. Naeem, S. S. Nizami, and Tanzile H. Usmani. "Decolorisation of Remazol vinyl sulphone reactive dyes by potassium permanganate." Coloration Technology 125, no. 5 (November 9, 2009): 277–83. http://dx.doi.org/10.1111/j.1478-4408.2009.00207.x.

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34

Jurek, Michael J., and James E. McGrath. "Synthesis and characterization of amine terminated poly(arylene ether sulphone) oligomers." Polymer 30, no. 8 (August 1989): 1552–57. http://dx.doi.org/10.1016/0032-3861(89)90232-2.

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35

Qipeng, Guo. "Phase behaviour in epoxy resin containing phenolphthalein poly(ether ether sulphone)." Polymer 34, no. 1 (January 1993): 70–76. http://dx.doi.org/10.1016/0032-3861(93)90285-i.

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36

Conningham, Paul, Robert J. Roach, John B. Rose, and P. T. McGrail. "Synthesis of poly (phenylene ether sulphone)s containing aminated chain units." Polymer 33, no. 18 (September 1992): 3951–56. http://dx.doi.org/10.1016/0032-3861(92)90388-d.

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37

Lakshmi, R. T. S. Muthu, Jochen Meier-Haack, K. Schlenstedt, H. Komber, V. Choudhary, and I. K. Varma. "Synthesis, characterisation and membrane properties of sulphonated poly(aryl ether sulphone) copolymers." Reactive and Functional Polymers 66, no. 6 (June 2006): 634–44. http://dx.doi.org/10.1016/j.reactfunctpolym.2005.10.016.

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38

Foerch, Renate, and David S. Urch. "X-ray emission spectra and electronic structure of the sulphate and methyl sulphonate anions, dimethyl sulphone and the trimethylsulphoxonium cation [(CH3)nSO4–n]n–2, (n= 0, 1, 2 and 3)." Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 85, no. 5 (1989): 1139. http://dx.doi.org/10.1039/f19898501139.

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39

Qipeng, Guo. "Miscibility of poly(hydroxyether of phenolphthalein) with poly(ether sulphone)." European Polymer Journal 28, no. 11 (November 1992): 1395–97. http://dx.doi.org/10.1016/0014-3057(92)90281-6.

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40

Ludwig, Miroslav, Oldřich Pytela, and Miroslav Večeřa. "Solvent effects on dissociation of substituted benzenesulphonamides in acetone, 1,2-dichloroethane, tetramethylene sulphone, pyridine and some aqueous organic solvent mixtures." Collection of Czechoslovak Chemical Communications 51, no. 9 (1986): 1948–57. http://dx.doi.org/10.1135/cccc19861948.

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The potentiometric titration has been used to measure dissociation constants of fifteen substituted arenesulphonamides of general formula XC6H4SO2NH2 (or X2C6H3SO2NH2) in acetone, 1,2-dichloroethane, tetramethylene sulphone, pyridine, and mixtures water-ethanol (25, 50, 75, 90% by vol. of the organic component), water-dimethylformamide (25, 50, 75% by vol.), water-acetone (25% by vol.), and water-2-methoxyethanol (80% by wt.). The results are compared with those published earlier for water, methanol, ethanol, dimethylformamide, dimethyl sulphoxide, and acetonitrile.

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41

Zhang, Xiaoqing, and Yuanshen Wang. "Investigation on domain structure of poly(phenylene sulphide) and poly(ether sulphone) blends by solid-state nuclear magnetic resonance methods." Polymer 30, no. 10 (October 1989): 1867–71. http://dx.doi.org/10.1016/0032-3861(89)90360-1.

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42

Norrman, K., and F. C. Krebs. "Photodegradation of poly(ether sulphone) Part 2. Wavelength and atmosphere dependence." Surface and Interface Analysis 36, no. 12 (2004): 1542–49. http://dx.doi.org/10.1002/sia.1981.

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43

Spehar-Délèze, Anna-Maria, Salzitsa Anastasova, and Pankaj Vadgama. "Monitoring of Lactate in Interstitial Fluid, Saliva and Sweat by Electrochemical Biosensor: The Uncertainties of Biological Interpretation." Chemosensors 9, no. 8 (July 28, 2021): 195. http://dx.doi.org/10.3390/chemosensors9080195.

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Lactate electrochemical biosensors were fabricated using Pediococcus sp lactate oxidase (E.C. 1.1.3.2), an external polyurethane membrane laminate diffusion barrier and an internal ionomeric polymer barrier (sulphonated polyether ether sulphone polyether sulphone, SPEES PES). In a needle embodiment, a Pt wire working electrode was retained within stainless steel tubing serving as pseudoreference. The construct gave linearity to at least 25 mM lactate with 0.17 nA/mM lactate sensitivity. A low permeability inner membrane was also unexpectedly able to increase linearity. Responses were oxygen dependent at pO2 < 70 mmHg, irrespective of the inclusion of an external diffusion barrier membrane. Subcutaneous tissue was monitored in Sprague Dawley rats, and saliva and sweat during exercise in human subjects. The tissue sensors registered no response to intravenous Na lactate, indicating a blood-tissue lactate barrier. Salivary lactate allowed tracking of blood lactate during exercise, but lactate levels were substantially lower than those in blood (0–3.5 mM vs. 1.6–12.1 mM), with variable degrees of lactate partitioning from blood, evident both between subjects and at different exercise time points. Sweat lactate during exercise measured up to 23 mM but showed highly inconsistent change as exercise progressed. We conclude that neither tissue interstitial fluid nor sweat are usable as surrogates for blood lactate, and that major reappraisal of lactate sensor use is indicated for any extravascular monitoring strategy for lactate.

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44

Feng, Jiachun, Guian Wen, Wei Huang, En-Tang Kang, and Koon Gee Neoh. "Influence of oxygen plasma treatment on poly(ether sulphone) films." Polymer Degradation and Stability 91, no. 1 (January 2006): 12–20. http://dx.doi.org/10.1016/j.polymdegradstab.2005.05.001.

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45

Kozielski, K. A., G. A. George, N. A. St John, and N. C. Billingham. "Kinetic studies by FT-NIR of the curing reactions of two glycidyl ether epoxy resins mixed with stoichiometric quantities of 4,4′ - DDS." High Performance Polymers 6, no. 3 (June 1994): 263–86. http://dx.doi.org/10.1088/0954-0083/6/3/010.

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The crosslinking reactions of 4,4'-diaminodiphenyl sulphone with stoichiometric quantities of multifunctional epoxy resins were monitored using Fourier transform near infrared (FT-N1R) spectrophotometry. Manipulation of the pectral data enabled the concentrations of reactive groups throughout isothermal cure to be profiled. A kinetic model which included catalytic and diffusion-controlled reactions was developed to fit the data. Two glycidyl ether resins (Shell 1153 and Tactix 742) were chosen for this study to give an overview of this approach to commercial systems.

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46

Rudź, Wiesław. "SYNTHESIS OF THE TERPOLYMER METHYL METHACRYLATE- STYRENE-BIS(4-METHACRYLOYLMETHYLPHENYL)-SULPHONE." International Journal of Polymeric Materials 53, no. 5 (May 2004): 455–64. http://dx.doi.org/10.1080/0091403049044451.

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47

Gagnebien, D., P. J. Madec, and E. Maréchal. "Synthesis of poly(sulphone-b-siloxane)s — III. Synthesis of poly(sulphone-b-siloxane) by reaction of α,ω-diallyl oligosulphones with α,ω-disilane oligosiloxanes." European Polymer Journal 21, no. 3 (January 1985): 301–8. http://dx.doi.org/10.1016/0014-3057(85)90233-2.

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48

Hjertén, Stellan, Bo-Liang Wu, and Jia-Li Liao. "An high-performance liquid chromatography matrix based on agarose cross-linked with divinyl sulphone." Journal of Chromatography A 396 (January 1987): 101–13. http://dx.doi.org/10.1016/s0021-9673(01)94046-4.

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Puglisi, Concetto, Filippo Samperi, Gianluca Cicala, Antonino Recca, and Carmelo Luca Restuccia. "Combined MALDI–TOF MS and NMR characterization of copoly(arylen ether sulphone)s." Polymer 47, no. 6 (March 2006): 1861–74. http://dx.doi.org/10.1016/j.polymer.2006.01.045.

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Auman, Brian C., Virgil Percec, Hans A. Schneider, and Hans-Joachim Cantow. "Alternating block copolymers of aromatic poly(ether sulphone) and poly(dimethylsiloxane) by hydrosilylation." Polymer 28, no. 8 (July 1987): 1407–17. http://dx.doi.org/10.1016/0032-3861(87)90460-5.

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