Academic literature on the topic 'Sulfur deposits Western Australia Norseman'

A comparison of high-alumina mineral assemblages spatially associated with the Haile and Brewer gold deposits in the Paleozoic Carolina slate belt (CSB) of the southeast United States and the Sons of Gwalia and Mount Celia gold deposits in the Archean Norseman–Wiluna greenstone belt (NWGB) in Western Australia suggests a similar hydrothermal origin and subsequent metamorphic and deformational history. A common hydrothermal origin is supported by the striking similarity in whole-rock chemistry, even though there were probably significant variations in original unaltered protoliths. An analysis of rocks from each of the deposits that contain high-alumina minerals demonstrates that the protoliths were leached of alkalis with respect to aluminum and have a ratio of Al2O3/Na2O + CaO + K2O greater than three. Although the rocks contain abundant high-alumina minerals, the aluminum content in these rocks is not unusually high, and it does not appear that there has been any significant transport of aluminum either into or out of the rocks that were altered.The most common high-alumina minerals found in rocks affected by the feldspar destructive alteration event include andalusite, kyanite, pyrophyllite, kaolinite, and sericite. Other minerals present in variable amounts include diaspore, chloritoid, alunite, natroalunite, paragonite, and topaz. It is possible that some of these minerals formed during the early hydrothermal alteration event and were recrystallized during metamorphism. Regardless of when the high-alumina minerals formed, textural relations suggest that the rocks had been hydrothermally altered by the time the metamorphic minerals formed. A comparison of alteration from the deposits studied in the CSB and the NWGB suggests there are many similarities to acid-sulfate alteration associated with geothermal areas, such as Yellowstone Park, Wyoming, and with acid-sulfate gold deposits, such as Goldfield, Nevada. Thus, it is possible that the protolith of the metamorphosed rocks in the CSB and NWGB contained an alteration assemblage that included alunite, pyrophyllite, and kaolinite.A generalized paragenetic sequence determined from petrographic and field observations, beginning with regional metamorphism, follows: (i) formation of andalusite, kyanite, chloritoid, and topaz during prograde metamorphism, depending on whole rock chemistry, (ii) formation of pyrophyllite and quartz-rich pods during silicification of aluminosilicate-bearing rocks, (iii) bedding parallel schistosity and fracturing produced by a deformational event, (iv) fractures filled by quartz, sericite, pyrophyllite, or calcite, (v) folding of early layering in the rocks to form a crenulation cleavage accompanied by introduction of quartz veins at high angles to foliation; and (vi) retrograde metamorphism of andalusite–kyanite-pyrophyllite to produce an assemblage of kaolinite ± diaspore.The spatial association of the acid-sulfate alteration with gold mineralization, together with comparison of analogous alteration associated with younger unmetamorphosed acid-sulfate gold deposits, suggests that at least some of the gold was introduced during the early premetamorphic alteration event. The present location of gold in each deposit is a result of local changes brought about by later metamorphic and deformational events.

The Norseman mining district in the Archean Yilgarn Block, Western Australia, has produced 140 t of gold and about 90 t of silver from 11.24 × 106 t of ore. The district is located within a metamorphic terrane of mafic and minor ultramafic greenstones, intruded by granite cupolas and swarms of porphyry dykes. The orebodies consist of laminated quartz veins, controlled by narrow (0.5–5 m) reverse shear zones that, in general, follow the contacts of metapyroxenite or porphyry dykes. Petrological studies of four shear zones, exposed on the Regent shaft 14 level, Ajax shaft 10 level, and in the stope above the North Royal shaft 5 level, show that the host rocks were metamorphosed to hornblende–plagioclase amphibolites and actinolite–chlorite rocks at temperatures of 500–550 °C prior to mineralization.At the localities studied, intense wall-rock replacement and low-grade (0.5 g/t) gold mineralization are confined to ductile or brittle–ductile shear structures. Alteration is similar in both ultramafic and mafic greenstones, and consists of an inner zone of biotite–quartz–calcite–plagioclase rock with minor actinolitic hornblende and quartz–calcite–actinolite veinlets, and an outer zone, locally developed, of chlorite–calcite–quartz rock. At an estimated pressure of 3 kbar (300 MPa), fluid temperatures during wall-rock alteration are constrained by the hydrothermal mineral assemblages to 480 ± 30 °C in two shear zones on the Regent shaft 14 level, and to 450 ± 20 °C in one shear zone in the North Royal shaft 5 level stope. The mole fraction of CO2 of the fluids is estimated at [Formula: see text], and the sulphur fugacity at 10−6 bar (10−1 kPa) (at 450 °C), based on the assemblage pyrrhotite + pyrite ± arsenopyrite. The development of an outer chloritic alteration zone at North Royal is related to the lower fluid temperature at this locality.High-grade (up to 75 g/t Au, 283 g/t Ag) veins formed within three of the shear zones studied at fluid temperatures of 400 °C and less, by the successive accretion of quartz laminae, separated by films of retrograde chlorite and sericite. The assemblage of ore minerals in the veins differs from that in the altered wall rocks, and includes disseminated galena, Pb–Bi–Ag tellurides, and native gold, which coprecipitated with the quartz. The orebodies at Norseman show affinities to Phanerozoic and Archean gold skarn deposits.

The dry herbage yield increase (response) of subterranean clover (Trifolium subterraneum L.)-based pasture (>85% clover) to applications of different sources of sulfur (S) was compared in 7 field experiments on very sandy soils in the > 650 mm annual average rainfall areas of south-western Australia where S deficiency of clover is common when pastures grow rapidly during spring (August–November). The sources compared were single superphosphate, finely grained and coarsely grained gypsum from deposits in south-western Australia, and elemental S. All sources were broadcast (topdressed) once only onto each plot, 3 weeks after pasture emerged at the start of the first growing season. In each subsequent year, fresh fertiliser-S as single superphosphate was applied 3 weeks after pasture emerged to nil-S plots previously not treated with S since the start of the experiment. This was to determine the residual value of sources applied at the start of the experiment in each subsequent year relative to superphosphate freshly-applied in each subsequent year. In addition, superphosphate was also applied 6, 12 and 16 weeks after emergence of pasture in each year, using nil-S plots not previously treated with S since the start of the experiment. Pasture responses to applied S are usually larger after mid-August, so applying S later may match plant demand increasing the effectiveness of S for pasture production and may also reduce leaching losses of the applied S.At the same site, yield increases to applied S varied greatly, from 0 to 300%, at different harvests in the same or different years. These variations in yield responses to applied S are attributed to the net effect of mineralisation of different amounts of S from soil organic matter, dissolution of S from fertilisers, and different amounts of leaching losses of S from soil by rainfall. Within each year at each site, yield increases were mostly larger in spring (September–November) than in autumn (June–August). In the year of application, single superphosphate was equally or more effective than the other sources. In years when large responses to S occurred, applying single superphosphate later in the year was more effective than applying single superphosphate 3 weeks after pasture emerged (standard practice), so within each year the most recently applied single superphosphate treatment was the most effective S source. All sources generally had negligible residual value, so S needed to be applied each year to ensure S deficiency did not reduce pasture production.

Abstract The Golden Mile fault zone is a key controlling structure to the estimated 75 Moz gold endowment of the Kalgoorlie gold camp in the Yilgarn craton of Western Australia. The earliest structures in the fault are F1 folds that developed during D1 recumbent-fold and thrust deformation (<2685 ± 4 Ma). These F1 folds are overprinted by a pervasive NW- to NNW-striking S2 cleavage related to sinistral shearing beginning with 2680 ± 3 Ma D2a sinistral strike-slip and culminating with ca. 2660 Ma D2c sinistral-reverse movement. The majority of deformation in the fault zone correlates to ca. 2675 Ma D2b deformation, which is characterized by sinistral-normal kinematic indicators. Late, ca. 2650–2640 Ma D3 dextral-reverse kinematic indicators overprint the earlier D2 structures. Pyrrhotite-chalcopyrite-pyrite-sphalerite-galena assemblages were emplaced throughout the D2 event within NE-trending D2a tensile fractures, NW- to NNW-striking D2b normal faults and associated breccias, and NW- to NNW-striking D2c low-angle veins, with the latter D2b and D2c structures correlating to the Fimiston and Oroya mineralization types, respectively. All D2a-, D2b-, and D2c-related sulfides in the Golden Mile fault zone show similarly restricted δ34S (~1.0–4.5‰) and elevated Δ33S (~2.0–3.0‰) values that reflect strong local sulfur contribution from shales of the Lower Black Flag Group and host-rock buffering of hydrothermal fluids related to the Fimiston and Oroya mineralization events. This host-rock buffering decreased fluid fO2, favoring the development of pyrrhotite-pyrite stable sulfide assemblages and causing respective decreases and increases in fluid Au-Te and Pb-Bi-Sb concentrations. At the camp scale, the Golden Mile fault zone exerted a primary control on the distribution of porphyry dikes and gold deposits; however, magma and hydrothermal fluid circulation was favored in adjacent, higher-order structural sites due to the fault zone’s incompetent rheology and tendency for ductile deformation and diffuse fluid flow. Other Archean examples such as Au deposits of the Larder Lake-Cadillac deformation zone in the Superior craton illustrate that this type of diffuse fluid flow in large-scale crustal fault zones can result in disseminated economic mineralization. However, this study highlights that host-rock effects on fluid chemistry in large-scale crustal fault zones exercises a strong control on a fluid’s propensity to form ore. The results of this study emphasize that both the rheology and chemistry of rocks within and adjacent to large-scale deformation zones act as important controls on the formation of gold ore in Archean terranes.

[Formulae and special characters can only be approximated here. Please see the pdf version of the abstract for an accurate reproduction.] The formation of world-class Archean orogenic gold deposits in the Eastern Goldfields Province of Western Australia was the result of a critical combination of physical and chemical processes that modified a single and widespread ore-fluid along fluid pathways and at the sites of gold deposition. Increased gold endowment in these deposits is associated with efficient regional-scale fluid focusing mechanisms and the influence of multiple ore-depositional processes at the deposit-scale. Measurement of the complexity of geologic features, as displayed in high-quality geologic maps of uniform data density, can be used to highlight areas that influence regional-scale hydrothermal fluid flow. Useful measurements of geological complexity include fractal dimensions of map patterns, density and orientation of faults and lithologic contacts, and proportions of rock types. Fractal dimensions of map patterns of lithologic contacts and faults highlight complexity gradients. Steep complexity gradients, between domains of high and low fractal dimensions within a greenstone belt, correspond to district-scale regions that have the potential to focus the flow of large volumes of hydrothermal fluid, which is critical for the formation of significant orogenic gold mineralization. Steep complexity gradients commonly occur in greenstone belts where thick sedimentary units overly more complex patterns of lithologic contacts, associated with mafic intrusive and mafic volcanic units. The sedimentary units in these areas potentially acted as seals to the hydrothermal Mineral Systems, which resulted in fluid-pressure gradients and increased fluid flow. The largest gold deposits in the Kalgoorlie Terrane and the Laverton Tectonic Zone occur at steep complexity gradients adjacent to thick sedimentary units, indicating the significance of these structural settings to gold endowment. Complexity gradients, as displayed in surface map patterns, are an indication of three-dimensional connectivity along fluid pathways, between fluid source areas and deposit locations. Systematic changes in the orientation of crustal-scale shear zones are also significant and measurable map features. The largest gold deposits along the Bardoc Tectonic Zone and Boulder-Lefroy Shear Zone, in the Eastern Goldfields Province, occur where there are counter-clockwise changes in shear zone orientation, compared to the average orientation of the shear zone along its entire length. Sinistral movement along these shear zones resulted in the formation of district-scale dilational jogs and focused hydrothermal fluid-flow at the Golden Mile, New Celebration and Victory-Defiance deposits. Faults and lithologic contacts are the dominant fluid pathways in orogenic gold Mineral Systems, and measurements of the density of faults and contacts are also a method of quantifying the complexity of geologic map patterns on high-quality maps. Significantly higher densities of pathways in areas surrounding larger gold deposits are measurable within 20- and 5-kilometer search radii around them. Large variations in the sulfur isotopic composition of ore-related pyrites in orogenic gold deposits in the Eastern Goldfields Province are the result of different golddepositional mechanisms and the in-situ oxidation of a primary ore fluid in specific structural settings. Phase separation and wall-rock carbonation are potentially the most common mechanisms of ore-fluid oxidation and gold precipitation. The influence of multiple gold-depositional mechanisms increases the potential for significant ore-fluid oxidation, and more importantly, provides an effective means of increasing gold endowment. This explains the occurrence of negative δ34S values in ore-related pyrites in some world-class orogenic gold deposits. Sulfur isotopic compositions alone cannot uniquely define potential gold endowment. However, in combination with structural, hydrothermal alteration and fluid inclusion studies that also seek to identify multiple ore-forming processes, they can be a useful indicator. The structural setting of a deposit is also a potentially important factor controlling ore-fluid oxidation and the distribution of δ34S values in ore-related pyrites. At Victory-Defiance, the occurrence of negative δ34S(py) values in gently-dipping dilational structures, compared to more positive δ34S(py) values in steeply-dipping compressional structures, is potentially associated with different gold-depositional mechanisms that developed as a result of fluid-pressure fluctuations during different stages of the fault-valve cycle. During the pre-failure stage, when fluids are discharging from faults, fluid-rock interaction is the dominant gold-depositional mechanism. Phase separation and back-mixing of modified ore-fluid components are dominant during and immediately after faulting. Under appropriate conditions, any, or all, of these three mechanisms can oxidize orogenic gold fluids and cause gold deposition. The influence of multiple gold-depositional mechanisms during fault-valve cycles at dilational jogs, where fluid pressure fluctuations are interpreted to be most severe, can potentially explain both the large gold endowment of the giant to world-class Golden Mile, New Celebration and Victory-Defiance deposits along the Boulder-Lefroy Shear Zone, and the presence of gold-related pyrites with negative δ34S values in these deposits. This study highlights the interplay that exists between physical and chemical processes in orogenic gold Mineral Systems, during the transport of ore fluids in pathways from original fluid reservoirs to deposit sites. Potentially, a single and widespread orogenic ore-fluid could become oxidized, and lead to the formation of ore-related sulfides with variable sulfur isotopic compositions, depending on the nature and orientation of major fluid pathways, the nature of wall-rocks through which it circulates, and the precise ore-depositional processes that develop during fault-valve cycles.