Academic literature on the topic 'Sulfonate based ligands'

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Journal articles on the topic "Sulfonate based ligands"

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Yon, Marjorie, Claire Pibourret, Jean-Daniel Marty, and Diana Ciuculescu-Pradines. "Easy colorimetric detection of gadolinium ions based on gold nanoparticles: key role of phosphine-sulfonate ligands." Nanoscale Advances 2, no. 10 (2020): 4671–81. http://dx.doi.org/10.1039/d0na00374c.

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Specific interactions between sulfonate groups of phosphine-sulfonate ligands on the surface of Au nanoparticles and Gd3+ ions allow the colorimetric detection of Gd3+ ions at the μM level.
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Meng, Xing, Shu-Yan Song, Xue-Zhi Song, Min Zhu, Shu-Na Zhao, Lan-Lan Wu, and Hong-Jie Zhang. "A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands exhibiting high proton conduction properties." Chemical Communications 51, no. 38 (2015): 8150–52. http://dx.doi.org/10.1039/c5cc01732g.

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A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands has been synthesized. It possesses 1D irregular channels lined with sulfonate, carboxylate, and DMF molecules, which show a high proton conductivity of 7.4 × 10−4 S cm−1 at 95 °C and 95% relative humidity.
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Shankar, Ravi, Archana Jain, Gabriele Kociok-Köhn, and Kieran C. Molloy. "Diorganotin-Based Coordination Polymers Derived from Sulfonate/Phosphonate/Phosphonocarboxylate Ligands." Inorganic Chemistry 50, no. 4 (February 21, 2011): 1339–50. http://dx.doi.org/10.1021/ic1018423.

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Sun, Daofeng, Rong Cao, Wenhua Bi, Xiaoju Li, Yanqin Wang, and Maochun Hong. "Self-Assembly of Novel Silver Polymers Based on Flexible Sulfonate Ligands." European Journal of Inorganic Chemistry 2004, no. 10 (May 2004): 2144–50. http://dx.doi.org/10.1002/ejic.200300813.

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D'Vries, Richard F., German E. Gomez, Diego F. Lionello, M. Cecilia Fuertes, Galo J. A. A. Soler-Illia, and Javier Ellena. "Luminescence, chemical sensing and mechanical properties of crystalline materials based on lanthanide–sulfonate coordination polymers." RSC Advances 6, no. 111 (2016): 110171–81. http://dx.doi.org/10.1039/c6ra23516f.

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The relationship between the structural features with the mechanical, luminescent and sensing properties were studied in the compounds formed from lanthanide metals, 3-hydroxinaphthalene-2,7-disulfonate and 1,10-phenanthroline ligands.
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Wang, Qiu-Ya, Xue-Ling Zhang, Qing-Hua Meng, Dong Xue, Yun He, and Zun-Ting Zhang. "Metal–organic coordination polymers based on Cs(I), Rb(I) and isoflavone-3′-sulfonate ligands." Polyhedron 85 (January 2015): 953–61. http://dx.doi.org/10.1016/j.poly.2014.10.017.

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Shankar, Ravi, Archana Jain, Gabriele Kociok-Köhn, and Kieran C. Molloy. "Synthesis and characterization of diethyltin-based three dimensional self-assemblies derived from sulfonate–phosphonate ligands." Inorganica Chimica Acta 372, no. 1 (June 2011): 108–14. http://dx.doi.org/10.1016/j.ica.2011.01.084.

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Ahoulou, Samuel, Clara Richart, Cédric Carteret, Sébastien Pillet, Neus Vilà, and Alain Walcarius. "Weak Coordinating Character of Organosulfonates in Oriented Silica Films: An Efficient Approach for Immobilizing Cationic Metal-Transition Complexes." Molecules 27, no. 17 (August 25, 2022): 5444. http://dx.doi.org/10.3390/molecules27175444.

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Iron (II) tris(2,2′-bipyridine) complexes, [Fe(bpy)3]2+, have been synthesized and immobilized in organosulfonate-functionalized nanostructured silica thin films taking advantage of the stabilization of [Fe(H2O)6]2+ species by hydrogen bonds to the anionic sulfonate moieties grafted to the silica nanopores. In a first step, thiol-based silica films have been electrochemically generated on indium tin oxide (ITO) substrates by co-condensation of 3-mercaptopropyltrimethoxysilane (MPTMS) and tetraethoxysilane (TEOS). Secondly, the thiol function has been modified to sulfonate by chemical oxidation using hydrogen peroxide in acidic medium as an oxidizing agent. The immobilization of [Fe(bpy)3]2+ complexes has been performed in situ in two consecutive steps: (i) impregnation of the sulfonate functionalized silica films in an aqueous solution of iron (II) sulfate heptahydrate; (ii) dipping of the iron-containing mesostructures in a solution of bipyridine ligands in acetonitrile. The in situ formation of the [Fe(bpy)3]2+ complex is evidenced by its characteristic optical absorption spectrum, and elemental composition analysis using X-ray photoelectron spectroscopy. The measured optical and electrochemical properties of immobilized [Fe(bpy)3]2+ complexes are not altered by confinement in the nanostructured silica thin film.
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Zemke, Jennifer M., Thomas E. Novet, and David R. Tyler. "Investigation of ligand effects on exciton recombination in PbS nanoparticles." Canadian Journal of Chemistry 89, no. 3 (February 2011): 339–46. http://dx.doi.org/10.1139/v10-169.

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Multiple exciton generation (MEG) and exciton recombination were studied by femtosecond transient absorption spectroscopy in PbS nanoparticles (NPs) capped with oleic acid (PbS–OLA) and 2,3-dimercaptopropane sulfonate (PbS–DMPS) ligands. Analysis of the transient absorption data showed that the PbS–DMPS nanoparticles exhibit increased rates of multi- and single-exciton recombination compared with the PbS–OLA nanoparticles; however, the MEG yield for both sets of particles was the same within experimental error. The origin of the differences in the exciton recombination decay rates is unknown, but it is speculated that it may be due to the ionic functionality of DMPS or to the different ligating atoms of the OLA and DMPS ligands. The PbS–DMPS nanoparticles were highly sensitive to the presence of oxygen, which caused a dramatic increase in nonradiative decay pathways, which can be mistaken for multiexciton absorbance and decay. Removal of oxygen eliminated the nonradiative decay pathways. Overall, this study showed that the dynamics of MEG can be modified by changing the NP ligand shell, a result that may be useful in the development of NP-based thin-film solar devices.
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Wu, Hua, Xian-Wu Dong, Hai-Yan Liu, Jian-Fang Ma, Ying-Ying Liu, Yun-Yu Liu, and Jin Yang. "Construction of a series of inorganic–organic hybrid coordination polymers based on hexamethylenetetramine and sulfonate ligands." Inorganica Chimica Acta 373, no. 1 (July 2011): 19–26. http://dx.doi.org/10.1016/j.ica.2011.03.041.

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Dissertations / Theses on the topic "Sulfonate based ligands"

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Singla, Nisha. "Synthesis and characterization of diorganotin(IV) coordination polymers derived from silaalkylphosphonate and sulfonate based ligands." Thesis, IIT Delhi, 2016. http://localhost:8080/iit/handle/2074/7092.

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McConnell, Brendan Neil. "Fragment-based approaches to targeting EthR from mycobacterium tuberculosis." Thesis, University of Cambridge, 2019. https://www.repository.cam.ac.uk/handle/1810/290255.

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Tuberculosis affects millions of people worldwide every year. The current treatment for TB is divided into a regimen of both first- and second-line drugs, where first-line treatments are more tolerated and require shorter treatment lengths. With rising levels of resistance, alternative treatment regimes are urgently needed to fight this disease. Ethionamide, a second-line drug is administered as a prodrug which is activated in vivo by the enzyme EthA, which is in turn regulated by EthR. The disruption of the action of EthR could lead to novel therapeutics which could enhance the efficacy of ethionamide, and raise it to a first-line treatment. The work reported in this thesis examines the elaboration of three chemical scaffolds using fragment-based approaches to develop novel inhibitors capable of disrupting the EthR-DNA interaction. The first scaffold, 5-(furan-2-yl)isoxazole was investigated by fragment-merging approaches and produced compounds with the best of these having a KD of 7.4 uM. The second scaffold, an aryl sulfone was elaborated using fragment-merging strategies. This led to several modifications of the fragment, leading to several variants with KDs around 20 uM. With both of these series the affinity could not be improved below 10 uM and due to the synthetic complexity a further scaffold was prioritised. The third scaffold was explored was a 4-(4-(trifluoromethyl)phenyl)piperazine using fragmentgrowing from the NH of the piperazine to probe deeper into the EthR binding pocket. In addition to this, SAR around the 4-(trifluoromethyl)phenyl group was assessed to explore the interactions with EthR. These modifications led to compounds with nanomolar IC50s. A range of compounds were then screened by REMAssay to determine the boosting effect on ethionamide, and this identified compounds with up to 30 times boosting in the ethionamide MIC. The final chapter examines a concept where compounds were designed to exploit the dimeric nature of EthR by linking two chemical warheads with a flexible linker. These compounds are examined using mass spectrometry to investigate the stoichiometry of the interaction to provide insight into the binding of these extended compounds and exploring an alternative strategy to inhibit EthR. The work in this thesis demonstrated the successful use of fragment-based approaches for development of novel EthR inhibitors which showed significant ethionamide boosting effects.
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Jain, Archana. "Synthesis, characterization and structural studies of mixed-ligand diorganotin(IV) based coordination polymers bearing phosphonate/sulfonate/carboxyphosphonate ligands." Thesis, 2011. http://localhost:8080/iit/handle/2074/3707.

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