Academic literature on the topic 'Sulfidation reaction'

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Journal articles on the topic "Sulfidation reaction"

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Li, Cun Xiong, Chang Wei, Yan Song, Zhi Gan Deng, Ji Qiang Liao, Hong Sheng Xu, Min Ting Li, and Xin Bing Li. "Hydrothermal Sulfidation of White Lead with Elemental Sulfur." Advanced Materials Research 396-398 (November 2011): 624–30. http://dx.doi.org/10.4028/www.scientific.net/amr.396-398.624.

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Hydrothermal sulfidation of pure white lead with elemental sulfur has been studied in the present paper. The variables considered in the study were temperature, time, particle size and elemental sulfur fraction in the reacting mixture. Temperature and time were the most two important factors, with an increase in temperature and holding time the sulfidation extent of lead improved greatly and the constituent of products changed a lot. At temperatures above 140°C, PbS and PbSO4 were the only stable reaction products in the sulfidation of white lead. The experimental data indicated that under the hydrothermal conditions with a particle size of -58+48 μm and sulfur fraction in reacting mixture of 8% at 140 °C for 90 min, and 86% of lead sulfidation extent was achieved.
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Zhang, Fan, Andrew J. Allen, Aaron C. Johnston-Peck, Jingyu Liu, and John M. Pettibone. "Transformation of engineered nanomaterials through the prism of silver sulfidation." Nanoscale Advances 1, no. 1 (2019): 241–53. http://dx.doi.org/10.1039/c8na00103k.

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Silver sulfidation under environmentally relevant conditions follows a first-order reaction kinetics without aggregation or dissolution. Rate and extent of sulfidation demonstrates strong dependence on the crystallographic orientation of the facets.
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Kim, Min Soo, Malenahalli Halappa Naveen, Rizwan Khan, and Jin Ho Bang. "Iterative oxidation and sulfidation reactions: revival of bulk cobalt sulfide into an active electrocatalyst for the oxygen evolution reaction." Journal of Materials Chemistry A 8, no. 16 (2020): 7647–52. http://dx.doi.org/10.1039/d0ta01578d.

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A thermal route based on iterative oxidation and sulfidation reactions opens a new way to revive a bulk sulfide into an active electrocatalyst that would have otherwise performed poorly for the oxygen evolution reaction.
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Hong, Sungwook, Aravind Krishnamoorthy, Chunyang Sheng, Rajiv K. Kalia, Aiichiro Nakano, and Priya Vashishta. "A Reactive Molecular Dynamics Study of Atomistic Mechanisms During Synthesis of MoS2 Layers by Chemical Vapor Deposition." MRS Advances 3, no. 6-7 (2018): 307–11. http://dx.doi.org/10.1557/adv.2018.67.

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ABSTRACTTransition metal dichalcogenide (TMDC) monolayers like MoS2 are promising materials for future electronic applications. Large-area monolayer MoS2 samples for these applications are typically synthesized by chemical vapor deposition (CVD) using MoO3 reactants and gas-phase sulfur precursors. Recent experimental studies have greatly improved our understanding of reaction pathways in the CVD growth process. However, atomic mechanisms of sulfidation process remain to be fully elucidated. In this work, we present quantum-mechanically informed and validated reactive molecular dynamics (RMD) simulations for CVD synthesis of MoS2 layers using S2 precursors. Our RMD simulations clarify atomic-level reaction pathways for the sulfidation of MoO3 surfaces by S2, which is a critical reaction step for CVD synthesis of MoS2 layers. These results provide a better understanding of the sulfidation process for the scalable synthesis of defect-free MoS2 and other TMDC materials.
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Perrin, Kévin, David Chiche, Javier Perez-Pellitero, Olivier Politano, and Sébastien Chevalier. "Investigation of Solid State Diffusion Processes Involved in the Zinc Oxide Sulfidation Reaction." Diffusion Foundations 9 (October 2016): 100–110. http://dx.doi.org/10.4028/www.scientific.net/df.9.100.

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Sulfidation of undoped and aluminum doped zinc oxide materials has been performed by TGA under a H2S atmosphere in order to evaluate the impact of the doping element on sulfidation reaction kinetics and mechanism. The presence of aluminum seems to slow-down the reaction kinetics. This phenomenon might be explained by a modification of the solid state diffusion processes involved in ZnO sulfidation reaction and the related ZnS outward growth, assuming the presence of aluminum atoms inside ZnO and ZnS phases. In order to determine solid state diffusion mechanisms controlling the reaction kinetics, molecular dynamics simulations were performed using a Coulomb-Buckingham potential. Firstly, the diffusion of the different elements (Zn, O, S) was simulated for both the oxide and sulfide phases considering a vacancy mechanism. Secondly, simulations of the oxide phase doped by a trivalent cation were also performed. The results obtained in this preliminary work are presented and compared to the literature.
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Gogos, Alexander, Basilius Thalmann, Andreas Voegelin, and Ralf Kaegi. "Sulfidation kinetics of copper oxide nanoparticles." Environmental Science: Nano 4, no. 8 (2017): 1733–41. http://dx.doi.org/10.1039/c7en00309a.

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LIU, DONGJING, WEIGUO ZHOU, and JIANG WU. "TEXTURE AND STRUCTURE VARIATION OF PEROVSKITE LaFeO3/ZSM-5 DURING HIGH-TEMPERATURE DESULFURIZATION." Surface Review and Letters 27, no. 05 (August 28, 2019): 1950151. http://dx.doi.org/10.1142/s0218625x19501518.

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Perovskite LaFeO3/ZSM-5 is synthesized via citrate route for H2S removal at high temperatures. It shows good thermal stability after heat treatment at 500–700∘C with respect to slight changes in crystallographic phase and textural property. It presents the optimal desulfurization performance at 600∘C with sulfur capacity of 1017[Formula: see text][Formula: see text]mol[Formula: see text]S/g and products of S, LaS2, and Fe7S8. Sulfidation at 500∘C yields the same products as sulfidation at 600∘C but displays the lowest sulfur capacity of 408[Formula: see text][Formula: see text]mol[Formula: see text]S/g. Sulfidation at 700∘C produces La2O2S, Fe3S4, and unreacted LaFeO3. The activation energy of the sulfidation reaction over LaFeO3/ZSM-5 is 109.6[Formula: see text]kJ/mol.
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Xu, Shujun, Siwei Fan, Wenqing Ma, Jiabao Fan, and Guangda Li. "Electrochemical reaction behavior of MnS in aqueous zinc ion battery." Inorganic Chemistry Frontiers 9, no. 7 (2022): 1481–89. http://dx.doi.org/10.1039/d1qi01659h.

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MnS/C nanosheets were prepared via the sulfidation of the Mn-based organometallic precursor. When served as the zinc ion battery cathode material, MnS/C shows high ion diffusion kinetics and cyclability.
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Yang, Tianzu, Bin Hu, Weifeng Liu, Duchao Zhang, and Lin Chen. "Selective separation of copper from copper-smelting waste acid by potential control." Metallurgical Research & Technology 116, no. 4 (2019): 409. http://dx.doi.org/10.1051/metal/2018134.

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An oxidation-sulfidation process by potential control was proposed for the separation of the Cu from copper-smelting waste acid (CSWA). This process consists of two steps: the oxidation of As (III) and the sulfidation of Cu by potential control. For the oxidation step, the oxidation efficiency of As (III) reached 99.4% under the following optimal conditions: a potential of 820 mV, temperature of 25 °C, and reaction time of 10 min. Subsequently, Na2S solution was pumped to the oxidized-CSWA and 99.4% of the Cu and 1.8% of the As were precipitated under the following optimal conditions: a potential of 508 mV, temperature of 25 °C, initial pH of 1.0, and reaction time of 30 min. It is confirmed that, the oxidation of As is the pre-requisite step for the selective separation of the Cu from CSWA via the sulfidation process. Therefore, the novel process realized a selective separation of the Cu, as well as provided an alternative option for the treatment of non-ferrous smelting waste acid.
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Li, Lei, Kwan San Hui, Kwun Nam Hui, and Young-Rae Cho. "Ultrathin petal-like NiAl layered double oxide/sulfide composites as an advanced electrode for high-performance asymmetric supercapacitors." Journal of Materials Chemistry A 5, no. 37 (2017): 19687–96. http://dx.doi.org/10.1039/c7ta06119f.

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We develop a facile approach to synthesize ultrathin petal-like NiAl layered double oxide/sulfide (LDO/LDS) composites with high electrochemical activity using hydrothermal reaction followed by sulfidation process.
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Dissertations / Theses on the topic "Sulfidation reaction"

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PILLIS, MARINA F. "Estudo do comportamento de sulfetacao de ligas Fe20Cr." reponame:Repositório Institucional do IPEN, 2001. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10925.

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Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
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GERIBOLA, GUILHERME A. "Influência de um revestimento de nióbio sobre a resistência à simulação das ligas FeCr e FeCrY." reponame:Repositório Institucional do IPEN, 2014. http://repositorio.ipen.br:8080/xmlui/handle/123456789/23496.

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Dissertação (Mestrado em Tecnologia Nuclear)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP
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Behrani, Vikas. "Surface Modifications of Steels to Improve Corrosion Resistance in Sulfidizing-Oxidizing Environments." Diss., Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/19708.

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Industrial and power generation processes employ units like boilers and gasifiers to burn sulfur containing fuels to produce steam and syn gas (H2 and CO), which can generate electricity using turbines and fuel cells. These units often operate under environments containing gases such as H2S, SO2, O2 etc, which can attack the metallic structure and impose serious problems of corrosion. Corrosion control in high temperature sulfur bearing environments is a challenging problem requiring information on local gaseous species at the surface of alloy and mechanisms of degradation in these environments. Coatings have proved to be a better alternative for improving corrosion resistance without compromising the bulk mechanical properties. Changes in process conditions may result in thermal and/or environment cycling between oxidizing and sulfidizing environments at the alloy surface, which can damage the protective scale formed on the alloy surface, leading to increase in corrosion rates. Objective of this study was to understand the effect of fluctuating environments on corrosion kinetics of carbon steels and develop diffusion based coatings to mitigate the high temperatures corrosion under these conditions. More specifically, the focus was : (1) to characterize the local gaseous environments at the surface of alloys in boilers; (2) optimizing diffusion coatings parameters for carbon steel; (3)understand the underlying failure mechanisms in cyclic environments; (4) to improve aluminide coating behavior by co-deposition of reactive elements such as Yttrium and Hafnium; (5) to formulate a plausible mechanism of coating growth and effects of alloying elements on corrosion; and (6) to understand the spallation behavior of scale by measuring stresses in the scales. The understanding of coating mechanism and effects of fluctuating gaseous environments provides information for designing materials with more reliable performance. The study also investigates the mechanism behind the effect of REs on scale adhesion and sulfidation behavior. Thus, the present work will have a broad impact on the field of materials and coatings selection for high temperature industrial environments such as boilers and gasifiers, and provides information on RE-modified aluminized coatings on carbon steel as an alternative for the use of bulk superalloys under high temperature sulfur bearing environments.
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Li, Kan. "Scavenging of uranium in experimental and natural samples." Thesis, 2016. http://hdl.handle.net/2440/106292.

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The hypothesis that interface coupled dissolution-reprecipitation reactions (ICDR) can play a key role in scavenging minor elements has been investigated via exploring the fate of U during the experimental sulfidation of hematite to chalcopyrite and the exsolution of chalcopyrite from bornite digenite solid solution (bdss) under hydrothermal conditions. The results of experiments with two kinds of Uranium (U) sources; either as solid UO₂₊ₓ(s) or as a soluble uranyl complex, differed from the U-free experiments. In the reactions from hematite to chalcopyrite under 220-300°C hydrothermal conditions, pyrite precipitated initially, before the onset of chalcopyrite precipitation. In addition, when UO₂₊ₓ(s) was included in the experiments, enhanced hematite dissolution led to increased porosity and precipitation of pyrite+magnetite within the hematite core. However, in uranyl nitrate bearing experiments, abundant pyrite formed initially, before being replaced by chalcopyrite. Uranium scavenging was mainly associated with the pyrite precipitation, as a result that a thin U-rich layer along the original hematite grain surface precipitated out. In the reactions of chalcopyrite exsolution from bdss during annealing under hydrothermal conditions in a solutions nominally containing Cu(I) and hydrosulfide in a pH₂₅°C [°C subscript] ~6 acetate buffer, a similar U-rich rim was observed along the original grain when uranyl nitrate as U-source was included in the reactions. The precipitation of uranium was related to the presences of HS- in buffer. Chemical mapping and X-ray absorption near edge structure (XANES) spectroscopy showed the UO₂₊ₓ(s) was the mainly restricted to the U-rich layer. The two sets of experiments demonstrate that the presence of minor components can affect the pathway of ICDR reactions. Reactions between U- and Cu-bearing fluids and hematite or chalcopyrite can explain the Cu-U association prominent in some iron oxide-copper-gold (IOCG) deposits. In this study, synchrotron-based X-ray fluorescence (SXRF) mapping was used to trace the distribution of uranium in natural samples from different geological contexts (sandstone-hosted U-deposit; IOCG) for investigating the deportment of uranium and its paragenesis in the context of thin-section scale textural complexity. It has been confirmed that the enrichment of U occurs via late dissolution-reprecipitation reactions in the bornite ores of the Moonta and Wallaroo IOCG deposits (South Australia), and that the U distribution in the ores of sandstone-hosted U-deposit is complex. Image analysis also revealed a number of new results for other minor elements, e.g. (i) the distribution of μm-sized Pt-rich grains and evidence for Ti-mobility during the formation of schistosity at the Fifield Pt prospect (New South Wales, Australia); (ii) the presence of Ge contained in organic matter and of Hg minerals associated within quartzite clasts in the Lake Frome U ores (South Australia); and (iii) confirmation of the two-stage Ge-enrichment in the Barrigão deposit, with demonstration of the presence of Ge in solid solution in the early chalcopyrite (Portuguese Iberian Pyrite Belt).
Thesis (Ph.D.) (Research by Publication) -- University of Adelaide,School of Chemical Engineering, 2016.
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Bromfield, Tracy Carolyn. "The effect of low level sulfide addition and the performance of precipitated- iron Fischer-Tropsch catalysts." Thesis, 2016. http://hdl.handle.net/10539/20979.

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A thesis submitted to the Faculty of Science, University of the Witwatersrand; Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. July 1991
Precipitated-iron Fischer- Tropsch catalysts were sulfided in the range 500 - 20000 ppm S/Fe with an aqueous sulfide source (Na2S, (NB4)zS, (NB4)zS5) during the precipitation process. Sulfidation was performed at pH 10.75, 8.5 and 6.9. Sodium ions were removed by centrifugation, and atomic absorption analysis confirmed low sodium levels (0-51 ppm). Based on solution speciation models, ferrous sulfide (FeS) which formed from aqueous HS' species, was found to influence the iron-oxyhydroxide crystallite morphology. It is proposed that, when sulfide was added at pH 10.75, FeS molecules functioned as nuclei for crystallite growth, while a pH 6.9 they assisted 'with the aggregation of particles. The processes of nucleation and aggregation appeared to be in competition following sulfidation at pH 8.5, resulting in a composite morphology that produced an inactive catalyst. The bulk structure of the catalysts was elucidated using XRD, SEM and nitrogen porosimetry, All sulfided catalysts exhibited enhanced BET surface areas and total pore volumes with a maximum at 2000 ppm S (surface area = 166 m2/g,total pore volume = 0.254 cm3/g) compared to an unsulfided catalyst (surface area = 58 m2/g, total pore volume = 0.184 cm3/g), Furthermore, for any series of catalysts at the same level of sulfidation, the BET surface areas were observed to decrease as the pH of sulfide addition decreased. Increasing levels of sulfidation (to 20000 ppm) brought about an increase in crystallite size and therefore, improved crystallinity as determined by XRD measurements. Materials with larger crystallites possess smaller surface areas, and thus the crystallinity was found to increase as the pH of sulfidation decreased. Surface characterisation by XPS after calcination at 400°C and reduction (400°C), revealed sulfate species (169.4 eV) on catalysts sulfided with 500-2000 ppm, while sulfide species (162.O eV) emerged at higher sulfide content. No sulfates were observed on reduced catalysts following calcination at 200 C. [Abbreviated Abstract. Open document to view full version]
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Book chapters on the topic "Sulfidation reaction"

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Flytzani-Stephanopoulos, M., and Z. Li. "Kinetics of Sulfidation Reactions Between H2S and Bulk Oxide Sorbents." In Desulfurization of Hot Coal Gas, 179–211. Berlin, Heidelberg: Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-58977-5_10.

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SMELTZER, W. W. "Modelling of Oxidation and Sulfidation Reactions." In Advances in Phase Transitions, 131–44. Elsevier, 1988. http://dx.doi.org/10.1016/b978-0-08-036234-2.50014-3.

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Simmons, Stuart F., Benjamin M. Tutolo, Shaun L. L. Barker, Richard J. Goldfarb, and François Robert. "Chapter 38: Hydrothermal Gold Deposition in Epithermal, Carlin, and Orogenic Deposits." In Geology of the World’s Major Gold Deposits and Provinces, 823–45. Society of Economic Geologists, 2020. http://dx.doi.org/10.5382/sp.23.38.

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Abstract Epithermal, Carlin, and orogenic Au deposits form in diverse geologic settings and over a wide range of depths, where Au precipitates from hydrothermal fluids in response to various physical and chemical processes. The compositions of Au-bearing sulfidic hydrothermal solutions across all three deposit types, however, are broadly similar. In most cases, they comprise low-salinity waters, which are reduced, have a near-neutral pH, and CO2 concentrations that range from <4 to >10 wt %. Experimental studies show that the main factor controlling the concentration of Au in hydrothermal solutions is the concentration of reduced S, and in the absence of Fe-bearing minerals, Au solubility is insensitive to temperature. In a solution containing ~300 ppm H2S, the maximum concentration of Au is ~1 ppm, representing a reasonable upper limit for many ore-forming solutions. Where Fe-bearing minerals are being converted to pyrite, Au solubility decreases as temperature cools due to the decreasing concentration of reduced S. High Au concentrations (~500 ppb) can also be achieved in strongly oxidizing and strongly acidic chloride solutions, reflecting chemical conditions that only develop during intense hydrolytic leaching in magmatic-hydrothermal high-sulfidation epithermal environments. Gold is also soluble at low to moderate levels (10–100 ppb) over a relatively wide range of pH values and redox states. The chemical mechanisms which induce Au deposition are divided into two broad groups. One involves achieving states of Au supersaturation through perturbations in solution equilibria caused by physical and chemical processes, involving phase separation (boiling), fluid mixing, and pyrite deposition via sulfidation of Fe-bearing minerals. The second involves the sorption of ionic Au on to the surfaces of growing sulfide crystals, mainly arsenian pyrite. Both groups of mechanisms have capability to produce ore, with distinct mineralogical and geochemical characteristics. Gold transport and deposition processes in the Taupo Volcanic Zone, New Zealand, show how ore-grade concentrations of Au can accumulate by two different mechanisms of precipitation, phase separation and sorption, in three separate hydrothermal environments. Phase separation caused by flashing, induced by depressurization and associated with energetic fluid flow in geothermal wells, produces sulfide precipitates containing up to 6 wt.% Au from a hydrothermal solution containing a few ppb Au. Sorption on to As-Sb-S colloids produces precipitates containing tens to hundreds of ppm Au in the Champagne Pool hot spring. Sorption on to As-rich pyrite also leads to anomalous endowments of Au of up to 1 ppm in hydrothermally altered volcanic rocks occurring in the subsurface. In all of these environments, Au-undersaturated solutions produce anomalous concentrations of Au that match and surpass typical ore-grade concentrations, indicating that near-saturated concentrations of dissolved metal are not a prerequisite for generating economic deposits of Au. The causes of Au deposition in epithermal deposits are related to sharp temperature-pressure gradients that induce phase separation (boiling) and mixing. In Carlin deposits, Au deposition is controlled by surface chemistry and sorption processes on to rims of As-rich pyrite. In orogenic deposits, at least two Au-depositing mechanisms appear to produce ore; one involves phase separation and the other involves sulfidation reactions during water-rock interaction that produces pyrite; a third mechanism involving codeposition of Au-As in sulfides might also be important. Differences in the regimes of hydrothermal fluid flow combined with mechanisms of Au precipitation play an important role in shaping the dimensions and geometries of ore zones. There is also a strong link between Au-depositing mechanisms and metallurgical characteristics of ores.
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Conference papers on the topic "Sulfidation reaction"

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Song, Zhanlong, and Mingyao Zhang. "Sulfidation Experiments in a Pressurized Thermogravimetric Analyzer With Chinese Calcined Limestones." In 18th International Conference on Fluidized Bed Combustion. ASMEDC, 2005. http://dx.doi.org/10.1115/fbc2005-78018.

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The sulfidation experiments with two kinds of Chinese calcined limestones were performed in a pressurized thermogravimetric analyzer (PTGA). The effects of reaction temperature (700–950°C), total pressure (0–1MPa), particle size (0.055–2mm), and H2S concentration (0.1–4%) on the sorbent conversions were analyzed. Morphological studies with scanning electron microscope and energy dispersive spectroscopy (SEM-EDS) equipment were made to obtain the pictures of solid surface and of the cross-sectioned samples. Nitrogen adsorption measurements were applied to determine the pore structure properties of the particles. Experimental results show that the sulfidation rate increases with total pressure when the volume fraction of H2S is constant. However, the rate of sulfidation decreases with the increase of total pressure when the H2S partial pressure is constant. Reaction temperature affects the sulfidation greatly, and the reaction rate increases with temperature. The sulfidation is the first order with respect to H2S partial pressure. Moreover, larger particles result in lower conversions and reaction rates. The unreacted shrinking core model was applied to describe the sulfidation to determine the kinetic parameters.
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Ola, Oluwafunmilola, and Yanqiu Zhu. "Two-Dimensional WS2/g-C3N4 Layered Heterostructures With Enhanced Pseudocapacitive and Electrocatalytic Properties." In ASME 2020 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/imece2020-23137.

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Abstract In this work, tungsten-based hybrid nanocomposites were grown on interconnected, macroscopic graphitic carbon nitride scaffold after solvothermal treatment followed by sulfidation to attain multifunctional composite electrocatalysts. The physicochemical properties of the obtained samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The tungsten-based composites were tested as electrodes for pseudocapacitors and as electrocatalysts for hydrogen evolution reaction, to take advantage of their porous graphitic carbon nitride features which would be beneficial for optimal ion transport to tungsten-based nanoparticles. These unique physicochemical features endow these composites with excellent electrochemical performances to reach a current density of 10 mA/cm2 for the hydrogen evolution reaction. In addition to demonstrating excellent specific capacitance, these hybrid nanocomposites also possess good stability after 8 hours of testing.
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Porter, Michael A., Dennis H. Martens, Thomas Duffy, and Sean McGuffie. "Computational Fluid Dynamics Investigation of a High Temperature Waste Heat Exchanger Tube Sheet Assembly." In ASME 2005 Pressure Vessels and Piping Conference. ASMEDC, 2005. http://dx.doi.org/10.1115/pvp2005-71143.

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Many modern Sulfur Recovery Unit (SRU) process waste heat recovery exchangers operate in high temperature environments. These exchangers are associated with the thermal reactor system where the tubesheet/tube/ferrule assemblies are exposed to gasses at temperatures approaching 3000°F. Because sulfur compounds are present in the process gas, the carbon steel tubesheet and tubes in the assembly will be deteriorated by sulfidation as the operating metal temperature rises above 600°F. Ferrule systems are used to protect the carbon steel from exposure to excessive temperatures. The temperature distribution in the steel tubesheet/tube/ferrule system is affected by process gas flow and heat transfer through the assembly. Rather than depend upon “assumed” heat transfer coefficients and fluid flow distribution, a Computational Fluid Dynamics (CFD) investigation was conducted to study the flow fields and heat transfer in the tubesheet assembly. It was found that the configuration of the ferrule installation has a large influence on the temperature distribution in the steel materials and, therefore, the possible sulfidation of the carbon steel parts.
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Reports on the topic "Sulfidation reaction"

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Silaban, A., and D. P. Harrison. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 2, Single particle kinetic studies of sulfidation and regeneration reactions of candidate zinc ferrite sorbents. Office of Scientific and Technical Information (OSTI), May 1989. http://dx.doi.org/10.2172/10163720.

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