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Dissertations / Theses on the topic 'Sugars'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Hunter, Stuart James. "Synthesis and Exploitation of Branched Sugars and Sugar Amino Acids." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.491619.

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This thesis describes the synthesis of 2-C-branched carbohydrate derivatives from ketohexoses and some useful synthetic applications thereof. Chapter 1 encompasses a general introduction to branched-chain sugars, with the emphasis upon 2C- hydroxymethyl and -methyl branched sugars. Strategies for their synthesis are discussed, both from nucleophilic and electrophilic carbohydrate derivatives. Some synthetic applications of carbohydrates and consequently branched carbohydrates are highlighted, with a view to the derivatisation of a proposed chiron from the Kiliani ascension of L-sorbose, 2-C-hy

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2

Thomas, Albert. "Synthetic routes to amino sugars from 2,3-unsaturated sugars /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487262513409407.

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3

Hsia, Kenneth Y. "Carbocycles from sugars." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260126.

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4

Szarek, Mark Anthony. "Chemistry and biology of novel amino sugars and amino-sugar analogs." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ31955.pdf.

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5

PITTIA, PAOLA. "Physical state of sugar matrices and aroma-sugars interactions at nanoscale." Doctoral thesis, Università degli Studi di Trieste, 2016. http://hdl.handle.net/11368/2908096.

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6

Hemmings, Philippa Rachel. "Nitrogen heterocycles from sugars." Thesis, University of Oxford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314823.

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7

Beacham, Annabel R. "Studies on higher sugars." Thesis, University of Oxford, 1994. http://ora.ox.ac.uk/objects/uuid:a392cc72-9ff2-43cf-a9c4-38f16df261ff.

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This thesis describes the synthesis of three novel seven carbon bicyclic mimics of α-L-fucose, and of two new pyrrolidine amino sugars. 2,7-Anhydro- l-deoxy-β-L-gulo-heptulopyranose and l,2,7-trideoxy-2,7-imino-β- L-gulo-heptulopyranose were both synthesised from L-gulono-l,4-lactone. The addition of one equivalent of methyllithium to the diacetonide of L-gulono-1,4- lactone gave a keto-sugar, l-deoxy-3,4;6,7-di-0-isopropylidene-β-L-gulo- heptulofuranose. The anomeric configuration of this compound was determined by equilibrium nOe measurements. Hydrolysis in aqueous trifluoroacetic acid cause

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8

Pornpakakul, Surachai. "Synthesis of carba-sugars." Thesis, University of Manchester, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.683737.

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9

Fujii, Sachie. "Studies on drying of sugar solutions and stabilization of dried foods by sugars." Kyoto University, 2014. http://hdl.handle.net/2433/189644.

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10

Elliott, Russell Phillip. "Sugars as homochiral starting agents." Thesis, University of Oxford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316887.

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11

Hindle, Neil. "Amino sugars and their glycosides." Thesis, University of Oxford, 1995. http://ora.ox.ac.uk/objects/uuid:78ab400f-4a4c-47bb-9d18-1b3bef205044.

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This thesis describes approaches to the transformation of simple carbohydrates into a polyhydroxylated pyrrolidine and the formation of its glucosides. Chapter one describes the synthesis of the naturally occurring pyrrolidine 2,5-dideoxy-2,5-imino-D-mannitol. Synthesised from di-O-isopropylidene-D-glucose, the key steps are the introduction of nitrogen at C-5 with retention of configuration. Then cyclisation of the nitrogen onto the C-2 position with inversion to form the pyrrolidine ring. Reduction of the aldehyde furnished the polyhydroxylated heterocycle in 3.4% yield over 16 steps. The sy

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12

Dransfield, Paul John. "New routes to imino sugars." Thesis, University of Exeter, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.247066.

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13

Goughenour, Kristie. "Histoplasma capsulatum: Drugs and Sugars." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1584377509624302.

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14

Flynn, Claire June. "The synthesis of amino- and diamino-sugars and the evaluation of sugar-dye conjugates." Thesis, University of Nottingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.480978.

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15

Vargas-Ramirez, Juan Manuel. "Evaluation of Storage Techniques to Preserve Fermentable Sugars from Sugar Beets for Ethanol Production." Thesis, North Dakota State University, 2012. https://hdl.handle.net/10365/26618.

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New sugar beet varieties may qualify as an advanced biofuel feedstock in the U.S., but new alternatives to conventional pile storage are necessary to preserve fermentable sugars and allow yearlong beet ethanol production. Fermentable sugar preservation was assessed in sugar beets stored under aerobic and anaerobic atmospheres and in raw thick juice stored at acidic (2≤ pH≤ 5) and alkaline (8≤ pH≤11) conditions. Aerobic storage of sugar beets at 4°C for 14 wk resulted in higher fermentable sugar retention (99± 4%) than at 25°C or anaerobic storage at 4° C and 25&d

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16

Nazeri, Gelareh. "Formation of Sugars and Organic Acids from Hydrothermal Conversion of Biomass and Biomass-Derived Sugars." Thesis, Curtin University, 2022. http://hdl.handle.net/20.500.11937/89694.

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This study provides new insights into the formation mechanisms of various organic acids from hydrothermal decomposition of biomass under non-catalytic conditions. Firstly, the primary products from hydrothermal decomposition of mallee biomass and its main components are studied. Then, systematic research is undertaken to investigate the formation of various organic acids from hydrothermal decomposition of key intermediates including cellobiose, glucose, fructose and mannose. The reaction pathways of key organic acids from various sugar compounds are revealed.

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17

Odunlami, Benjamin Oladipo. "The role of sugars and sugar metabolism genes (sucrose synthase) in Arabidopsis thaliana seed development." Thesis, Northumbria University, 2009. http://nrl.northumbria.ac.uk/1687/.

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Seed development in Arabidopsis thaliana, has been studied at several levels. However, little has been done to study the role of sugar metabolism genes in seed pod development in this species. As the fertilized egg progresses to a mature seed, the sugars composition during different stages of the developing changes. These changes are related to metabolic processes in the developing seeds, but also to the activity of sucrose- converting and transporting genes, active at the interphase between the maternal tissue and the endosperm. Sucrose synthase (SUS) is one of these genes; it catalyses the r

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18

Naini, Venkatesh. "Physical and Chemical Stability of Spray Dried Sugars and Protein-Sugar MolecuIar Mixtures for Inhalation." VCU Scholars Compass, 1996. http://scholarscompass.vcu.edu/etd/4982.

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The feasibility of producing inhalable microparticles of sugars and protein-sugar molecular mixtures using spray drying was investigated as an alternative to conventional micronization techniques. Four sugars; lactose (L), trehalose (T), sucrose (S) and mannitol (M) were spray dried using a commercial bench-top spray dryer and their physicochemical stability, with respect to particle size, moisture uptake and crystallinity changes, investigated after storage at 23%, 52%, 75% and 93% relative humidity (RH) and 25 °C for 30 days. Two crystalline size fractions (“coarse” = 125-212 μm and “ﬁne” =

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19

Ellenberger, Suzanne Ray. "Total synthesis of selected deoxyamino sugars /." Full text open access at:, 1986. http://content.ohsu.edu/u?/etd,110.

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20

Mete, A. "Novel nucleoside analogues containing modified sugars." Thesis, City University London, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355583.

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21

Li, Bin. "Innovative Methods for Biomass Sugars Utilization." University of Toledo / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1353092448.

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22

Ehiwe, Tammy Iyobosa. "Investigating the bioprotective properties of sugars." Thesis, University of Greenwich, 2011. http://gala.gre.ac.uk/8076/.

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The purpose of this study was to investigate the stabilizing properties of osmolytes, specifically sugars on biomolecule such as protein. The strategy used in this study involved the utilisation of surfactant-rich micelles; where by the impact sugars have on the free energy of exposure of hydrocarbon groups present within the surfactant micelles was examined. The observation made for sugar-surfactant study was then applied to explain the stabilisation of the native structure and thus the physiologically active form of the protein by sugars. The sugars that have been studied include sucrose, tr

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23

WANG, YI. "Sugar Control of Artemisinin Production." Digital WPI, 2006. https://digitalcommons.wpi.edu/etd-theses/460.

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The role of sugars as regulatory signals has mainly focused on their effects on plant growth, development, gene expression, and metabolism. Little, however, is known about their role in controlling secondary metabolism. Previous work in our lab showed that sugars affect the production of the sesquiterpene antimalarial drug, artemisinin, in hairy roots of Artemisia annua. In this study, sugars alone or in combination with their analogues were used to investigate if sugars control artemisinin production in Artemisia annua seedlings. Compared to sucrose, a 200% increase in artemisinin by glucose

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24

Fitzpatrick, L. M. "Transport of sugars across the chloroplast envelope." Thesis, University of Cambridge, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.599063.

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The aim of the work described in this thesis was to investigate the role and importance of the glucose transporter in the chloroplast envelope. I believed that further characterisation would contribute to our knowledge of transitory starch degradation at night, and to the control of carbon partitioning. I have supplied tracer quantities of [U-<SUP>14</SUP>C]glucose and [U-<SUP>14</SUP>C]glycerol in the dark to leaves selected from a diverse range of species, and demonstrated that the net flux in the cytosol, during starch degradation in the dark, is glycolytic, so that a gluconegoenic flux fro

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25

Tran, Chuong Hao. "Synthesis of pseudo-sugars and related compounds." Thesis, University of Warwick, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308507.

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26

Wu, Luis Eduardo. "Synthesis of unnatural sugars from unsaturated ketones." Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368669.

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27

Young, Anne A. "Nitrile oxide/isoxazoline approach to higher sugars." Thesis, University of Edinburgh, 1990. http://hdl.handle.net/1842/11655.

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The application of nitrile oxide/isoxazoline chemistry towards the synthesis of higher sugars (monosaccharides containing seven or more contiguous carbon atoms) has been investigated. This convergent approach, involving the cycloaddition of sugar derived alkene and nitrile oxide fragments and subsequent manipulation of the resulting isoxazoline, has much of the product stereochemistry preselected. Three ω-unsaturated monosaccharides were chosen for study: the D-glucose-derived six carbon unit (<i>94</i>), its C-3 epimer (<i>102</i>) and a seven carbon alkene, (<i>97</i>), prepared from D-galac

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28

Parry, Loren L. "The synthesis of branched sugars and iminosugars." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:2a511d58-f626-4f7e-aebc-f595b147827a.

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Iminosugars, carbohydrate analogues in which nitrogen replaces the endocyclic oxygen, have attracted much interest due to their biological activity. Iminosugars inhibit carbohydrate-processing enzymes, thereby affecting many biological processes. Several iminosugars are licensed drugs, with many more compounds undergoing clinical trials. The main subject of this thesis is the synthesis and evaluation of novel iminosugars, particularly the effects of structural modifications on the biological activity of these compounds. Chapter 1 describes the role of carbohydrate-processing enzymes in the bod

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29

Uneyama, Emi. "Synthesis of bicyclic difluorinated analogues of sugars." Thesis, University of Leicester, 2007. http://hdl.handle.net/2381/29998.

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This thesis describes the synthesis of gem-difluorinated cyclooctenone analogues using building block approaches based on the RCM with Grubbs' catalysts.;Des- and gem-dialkyl-substituted difluorodienes were synthesised from commercially available trifluoroethanol by dehydrofluorination/metalation, trapping, allylation and [2,3]-Wittig rearrangement successfully.;The gem-difluorinated dienes produced the corresponding difluorinated cyclooctenones smoothly and in good yields. However, a dithioketal-containing diene did not afford any cyclic product. Thorpe-lngold effect was also observed from th

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30

Barker, Kathrine. "Novel di-branched monosaccharides and imino sugars." Thesis, University of Oxford, 2009. http://ora.ox.ac.uk/objects/uuid:5e9ef70b-9213-4c0c-b500-61200a049c1b.

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Branched chain sugars display a varied and valuable range of biological activities. This thesis concerns the synthesis of 3,5-di-C-methyl-D-glucose, a potential inhibitor of glycogen phosphorylase (GP), and therefore a proposed therapeutic agent for type 2 diabetes. Chapter 1 looks at the occurrence of branched sugars in the natural world and current therapies for type 2 diabetes. Inhibition of GP is explored, and the molecular modelling studies which led to the design of the project target. Chapter 1 also looks into the development of new foodstuffs, the chemistry and biochemistry of imino su

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31

Gogar, Ravikumar Leelamchand. "Economic Production of Furans from Lignocellulosic Sugars." University of Toledo / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1595977336480846.

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32

Kishore, P. V. "Studies on fermentation of sugars to glycerol." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Poona, 1985. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/3219.

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33

SCELFO, SIMONE. "Metal oxides catalysts for the synthesis of value-added chemicals from 2nd generation sugars and sugar derivatives." Doctoral thesis, Politecnico di Torino, 2017. http://hdl.handle.net/11583/2675152.

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The present Ph.D. thesis provides some examples of innovative 2nd generation catalytic processes for the conversion of renewable raw materials into green value-added chemicals. In particular, D-glucose and some its derivatives, all ideally representing waste materials of dedicated biomasses, agricultural residues, or solid organic urban waste exploitation in the biorefinery plant, were converted into useful chemical building-blocks. After a brief introduction to the topic and the description of the experimental method, each chapter of the work is based on one or more scientific articles eithe

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34

Alonzi, Dominic S. "Cellular Mechanism of Glycosylation Inhibition by Imino Sugars." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487138.

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Glycosylation is the most common posttranslational modification of proteins. It is a complex process involving many functional proteins and resulting'in a great diversity of structures. The retention of glucose residues on N-linked oligosaccharides following ER a-glucosidase inhibition by imino sugars such as N-butyl deoxynojirimycin, increases the protein misfolding and the amount of glycoprotein destined for degradation via the endoplasmic reticulum associated degradation (ERAD) pathway. Intracellular peptide N-glycosidases (PNGases) act generating free oligosaccharides (FOS) and the protein

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35

Kérourédan, Erwan. "Concise syntheses of diflouroanalogues of cyclitols and sugars." Thesis, University of Leicester, 2006. http://hdl.handle.net/2381/29980.

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The synthesis of (1 fl*,2f*,3S*,4S',)-5,5-dif luorocyclohexane-1,2,3,4-tetrol was accomplished with an overall yield of 20 % from trifluoroethanol over 8 steps featuring a key dehydrofluorination/metallation followed by trapping of aldehyde (scheme). The route based on a fluorinated building block approach delivered rapidly a small library of difluoroanalogues of carbasugars using readily available and inexpensive starting materials where the use of protecting group chemistry was reduced to its minimum as well as purification. This chemistry is unique as a method for the rapid syntheses of dif

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36

McGowan, Sheila Anne. "Modulation of the immune response by imino sugars." Thesis, University of Strathclyde, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.501808.

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Imino sugars are carbohydrate-like alkaloids largely characterised over the last ten years that function as glycosidase inhibitors as they mimic the sugar moiety of the natural substrate. They have been reported to have immunomodulatory activity and the purpose of this study was to identify and characterise such activity. The ability of over sixty imino sugars to modify macrophage/dendritic cell cytokine production was analysed. The immunomodulatory activity of two imino sugars MNLP 462a and MNLP 24 with pro-inflammatory activity was studied in depth. They were found to upregulate in vitro mac

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37

Kedward, Claire. "Crystallization of sugars in the chocolate crumb process." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324012.

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38

KeÌroureÌdan, Erwan. "Concise syntheses of difluoroanalogues of cyclitols and sugars." Thesis, University of Leicester, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.436598.

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39

Holt, Karen Elizabeth. "Asymmetric synthesis of aza-sugars using aldolase enzymes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272658.

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40

Denman, Carmen Cecile. "From osmolytes to diabetes : the impact of sugars and sugar alcohols on the cystic fibrosis pathogen, Burkholderia multivorans." Thesis, University of Exeter, 2013. http://hdl.handle.net/10871/9787.

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The incidence of CF related diabetes is on the rise as patient life expectancy continues to improve. Sugars elevated in diabetics include glucose, fructose, and mannose. These sugars, in addition to mannitol (recently approved as an inhaled osmolyte) are the basis for this study, aimed at assessing the impact these clinically relevant sugars have on virulence in Burkholderia multivorans. B. multivorans is a member of the Burkholderia cepacia complex (Bcc), and is the most frequent cause of Bcc infection in CF patients. Using an exopolysaccharide-deficient knockout in macrophage and Galleria me

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41

Chance, Deborah L. "Sulfated sugars in cystic fibrosis mucins and the effects of sugar sulfation on the growth of Pseudomonas aeruginosa /." free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9841269.

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42

Homan, Christopher David. "Phosphorus derivatives of carbohydrates." Thesis, University of Newcastle Upon Tyne, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239564.

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43

Park, Sung-Hae. "The biosynthesis of the deoxyhexose moieties in oleandomycin /." Thesis, Connect to this title online; UW restricted, 1999. http://hdl.handle.net/1773/8152.

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44

Yuhas, Maryam. "Improving Rural Health Disparities: Understanding and Addressing Intake of Added Sugars and Sugar-Sweetened Beverages among Adults and Adolescents." Diss., Virginia Tech, 2019. http://hdl.handle.net/10919/100730.

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Around 46.2 million Americans living in rural areas are disproportionately burdened by health disparities. Likewise, obesity and obesity-associated diseases (e.g., diabetes, cardiovascular disease) are much higher for rural residents when compared to their urban counterparts. There is a high need to understand and address the nutritional determinants of these health inequities among adults and adolescents. One area of concern in rural dietary habits pertains to added sugars and more specifically, sugar-sweetened beverages (SSB). Excessive added sugars and SSB intake have been strongly linked t

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45

Bierenstiel, Matthias. "Transition Metal Catalyzed Selective Oxidation of Sugars and Polyols." Diss., lmu, 2005. http://nbn-resolving.de/urn:nbn:de:bvb:19-37863.

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46

Schneider, L. (Laura). "Mechanocatalytic pretreatment of lignocellulosic barley straw to reducing sugars." Doctoral thesis, Oulun yliopisto, 2017. http://urn.fi/urn:isbn:9789526216478.

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Abstract Biomass conversion methods represent bioeconomic solutions for the sustainable production of value added commodities (chemicals and materials) as well as for energy purposes, either in solid (pellets), liquid (transport fuels) or gaseous (combustion gases e.g. biomethane) form. Lignocellulosic biomass as a renewable source available in immense quantity, is considered to be one of the most promising natural sources, with high potential in the replacement of conventional transportation fuels and reduction of greenhouse gas emissions. This thesis provides new insights into mechanocatalys

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47

Mellor, Howard R. "The biological properties of novel N-alkylated imino sugars." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398134.

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48

Geary, Peter Michael. "The co-crystallisation of sugars by the supersaturation process." Thesis, University of Hull, 2008. http://hydra.hull.ac.uk/resources/hull:2576.

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Co-crystallising sugars by the supersaturation process was investigated using sucrose and lactose as the matrix sugars. The components to be cocrystallised with either sucrose or lactose were a variety of mono- and disaccharides along with sweeteners such as saccharin. Analysis of the materials yielded from the supersaturation process was done primarily by differential scanning Calorimetry (DSC) and powder x-ray diffraction (PXRD). DSC analysis allowed information to be obtained on the thermal behaviour of the various co-crystalline materials, whilst PXRD permitted information on the structura

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49

Liu, Wei-Chun. "Studies of enzymes that process and use charged sugars." Thesis, University of Oxford, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.547468.

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50

Neuss, Judi. "Fragmentation-cyclisation approaches to the synthesis of aza-sugars." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338541.

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