Academic literature on the topic 'Spin crossover complexes'

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Journal articles on the topic "Spin crossover complexes"

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Takahashi, Kazuyuki. "Spin-Crossover Complexes." Inorganics 6, no. 1 (March 1, 2018): 32. http://dx.doi.org/10.3390/inorganics6010032.

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Murray, Keith S., Hiroki Oshio, and José Antonio Real. "Spin-Crossover Complexes." European Journal of Inorganic Chemistry 2013, no. 5-6 (February 18, 2013): 577–80. http://dx.doi.org/10.1002/ejic.201300062.

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NIHEI, M., T. SHIGA, Y. MAEDA, and H. OSHIO. "Spin crossover iron(III) complexes." Coordination Chemistry Reviews 251, no. 21-24 (November 2007): 2606–21. http://dx.doi.org/10.1016/j.ccr.2007.08.007.

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Wang, Jun-Li, Qiang Liu, Xiao-Jin Lv, Rui-Lin Wang, Chun-Ying Duan, and Tao Liu. "Magnetic fluorescent bifunctional spin-crossover complexes." Dalton Transactions 45, no. 46 (2016): 18552–58. http://dx.doi.org/10.1039/c6dt03714c.

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Ekanayaka, Thilini K., Krishna Prasad Maity, Bernard Doudin, and Peter A. Dowben. "Dynamics of Spin Crossover Molecular Complexes." Nanomaterials 12, no. 10 (May 19, 2022): 1742. http://dx.doi.org/10.3390/nano12101742.

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We review the current understanding of the time scale and mechanisms associated with the change in spin state in transition metal-based spin crossover (SCO) molecular complexes. Most time resolved experiments, performed by optical techniques, rely on the intrinsic light-induced switching properties of this class of materials. The optically driven spin state transition can be mediated by a rich interplay of complexities including intermediate states in the spin state transition process, as well as intermolecular interactions, temperature, and strain. We emphasize here that the size reduction down to the nanoscale is essential for designing SCO systems that switch quickly as well as possibly retaining the memory of the light-driven state. We argue that SCO nano-sized systems are the key to device applications where the “write” speed is an important criterion.
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Dankhoff, Katja, and Birgit Weber. "Isostructural iron(iii) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties." Dalton Transactions 48, no. 41 (2019): 15376–80. http://dx.doi.org/10.1039/c9dt00846b.

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Quintero, Carlos M., Gautier Félix, Iurii Suleimanov, José Sánchez Costa, Gábor Molnár, Lionel Salmon, William Nicolazzi, and Azzedine Bousseksou. "Hybrid spin-crossover nanostructures." Beilstein Journal of Nanotechnology 5 (November 25, 2014): 2230–39. http://dx.doi.org/10.3762/bjnano.5.232.

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This review reports on the recent progress in the synthesis, modelling and application of hybrid spin-crossover materials, including core–shell nanoparticles and multilayer thin films or nanopatterns. These systems combine, often in synergy, different physical properties (optical, magnetic, mechanical and electrical) of their constituents with the switching properties of spin-crossover complexes, providing access to materials with unprecedented capabilities.
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Schulte, Kelsey A., Stephanie R. Fiedler, and Matthew P. Shores. "Solvent Dependent Spin-State Behaviour via Hydrogen Bonding in Neutral FeII Diimine Complexes." Australian Journal of Chemistry 67, no. 11 (2014): 1595. http://dx.doi.org/10.1071/ch14145.

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We report the syntheses, structures, and magnetic properties of cis-[Fe(pizR)2(NCS)2] complexes based on the pyridyl imidazoline ligands 2-(2′-pyridinyl)-4,5-dihydroimidazole (pizH, 1) and 2-(2′-pyridinyl)-4,5-dihydro-1-methylimidazole (pizMe, 2). The ligands, complexes, and magnetic measurements are chosen to separate hydrogen-bonding and intrinsic ligand field properties, so as to improve our understanding of the effect of hydrogen-bonding interactions on spin-state switching. In the solid state, both complexes are high spin between 5 and 300 K. In deuterated methanol and acetonitrile solutions, both complexes show gradual thermal spin crossover. Complex 1, capable of hydrogen bonding, shows solvent-sensitive spin crossover, whereas spin crossover in the methylated analogue 2 is insensitive to solvent identity.
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Halepoto, Dost M., David G. L. Holt, Leslie F. Larkworthy, David C. Povey, Gallienus W. Smith, and G. Jeffrey Leigh. "Spin crossover in chromium(II) complexes." Polyhedron 8, no. 13-14 (January 1989): 1821–22. http://dx.doi.org/10.1016/s0277-5387(00)80658-0.

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Harding, David J., Phimphaka Harding, and Wasinee Phonsri. "Spin crossover in iron(III) complexes." Coordination Chemistry Reviews 313 (April 2016): 38–61. http://dx.doi.org/10.1016/j.ccr.2016.01.006.

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Dissertations / Theses on the topic "Spin crossover complexes"

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Bergen, Elvira [Verfasser]. "Multifunctional Spin Crossover Complexes / Elvira Bergen." Mainz : Universitätsbibliothek der Johannes Gutenberg-Universität Mainz, 2021. http://d-nb.info/1225796032/34.

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Tovee, Clare Anne. "Metal complexes exhibiting spin crossover and fluorescence." Thesis, University of Leeds, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.509875.

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Schlamp, Stephan [Verfasser], and Birgit [Akademischer Betreuer] Weber. "Amphiphilic Spin Crossover Complexes / Stephan Schlamp. Betreuer: Birgit Weber." Bayreuth : Universität Bayreuth, 2014. http://d-nb.info/106001002X/34.

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Sung, Raymond Chi Wai. "ESR studies of some iron(II) spin crossover complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape10/PQDD_0013/NQ52415.pdf.

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Schlamp, Stephan Verfasser], and Birgit [Akademischer Betreuer] [Weber. "Amphiphilic Spin Crossover Complexes / Stephan Schlamp. Betreuer: Birgit Weber." Bayreuth : Universität Bayreuth, 2014. http://nbn-resolving.de/urn:nbn:de:bvb:703-epub-1718-4.

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Mohammed, Rufeida. "Iron complexes of new dipyrazolylpyridine derivatives for spin-crossover applications." Thesis, University of Leeds, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.590300.

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This thesis concerns the synthesis and characterisation of new di(pyrazolyl)pyridine and di(pyrazolyl)pyrazine derivatives, and their iron(II) complexes which exhibit spin crossover behaviour. The examination of their magnetic behaviour using NMR spectroscopy, X-ray crystallography and magnetic measurements is described. Chapter One introduces the background behind the spin crossover phenomenon, especially in the case of iron(H) compounds. The methods of identification and the applications of spin crossover are discussed. Finally the aims of the research are also detailed. Chapters Two and Three discuss the synthesis and characterisation of previously unreported 2,6-di(4-R-pyrazol-I-yl)pyrazine compounds (R ~ CI, Br, I, Me, NO" NH" CCPh). The synthesis of their iron(ll) complexes as BF, and CIO, salts is also detailed, and their magnetic behaviour is discussed and compared to previous 2,6- bis(pyrazol-l-yl)pyridine complexes. The crystal structures of the complexes are presented. Chapter Four is a study of novel di(pyrazol-l-yl)pyridine derivatives substituted at the pyrazolyl or pyridyl 4-positions, and their iron(Il) complexes as before. Magnetochemical data for three complexes are presented, together with crystallographic data and a discussion relating structure to magnetic behaviour. Chapter Five focuses on the study of di(pyrazolyl)pyridine derivatives substituted at the pyridyl 4-positions by azo, ethynyl or styryl groups, and their iron(ll) complexes. Examination of their magnetic behaviour and crystal structures demonstrates the difficulty of predicting the spin state of an iron(lI) complex.
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Elhaik, Jérôme Ange. "Iron (II) spin crossover complexes of dipyrazolylpyridine and related ligands." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.414161.

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Ould, Moussa Nawel. "Photomagnetic properties of spin crossover complexes with multi-metastable states." Toulouse 3, 2007. http://www.theses.fr/2007TOU30036.

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Ce travail de thèse a pour objectif principal l'étude des propriétés de photo-commutation dans le visible et l'infrarouge de composés moléculaires à transition de spin. Les systèmes étudiés ont la particularité de présenter plusieurs états métastables à basse température : "Composés à transition de spin multi-métastables". L'enjeu actuel de tels systèmes ainsi que les processus de photo-commutation est de taille dans le domaine de l'adressage optique de l'information. Afin d'effectuer cette étude, nous avons choisi cinq composés chimiquement distincts : un mononucléaire, [Fe(ptz)6](BF4)2 (ptz = 1-propyltetrazole), pour lequel on a mis en évidence le découplage entre la transition cristallographique et la transition de spin photo-induite et quatre binucléaires de la famille {[Fe(L)(NCX)2]2bpym} (X = S ou Se; L = bpym (2,2'-bipyrimidine) ou bt (2,2'-bithiazoline)), où nous avons pu montrer entre autre qu'il est possible de convertir l'état fondamental bas spin de façon sélective en deux états macroscopiques distincts en fonction de la longueur d'onde de l'éclairement utilisé (visible ou infrarouge)
The aim of the present work was to develop a detailed picture of the photo-excitation process in some special spin crossover complexes, which exhibit more than one long-lived metastable states. We are interested in the effects of visible and infrared light irradiation on these systems. Such “multi-metastable spin crossover complexes” display actually an interesting and largely unexplored photophysics and hold also some promises as future candidates for storing and transferring information in molecular devices. In order to explore this topic, we have chosen five different systems: the mononuclear [Fe(ptz)6](BF4)2 complex (ptz = 1-propyleterazole) for which we demonstrate a clear decoupling between the crystallographic phase transition and the light-induced spin conversion and four binuclear complexes of the family {[Fe(L)(NCX)2]2bpym} (X = S or Se; L = bpym (2,2'-bipyrimidine) or bt (2,2'-bithiazoline)). This last study led to a number of original results, revealing for example wavelength-selective photomagnetic phenomena in these systems
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Huxel, Timo [Verfasser], and Julia [Akademischer Betreuer] Klingele. "Low-melting cationic transition metal complexes : : developing spin crossover ionic liquids = Niedrigschmelzende kationische Übergangsmetallkomplexe : die Entwicklung von Spin Crossover Ionic Liquids." Freiburg : Universität, 2014. http://d-nb.info/1123481598/34.

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Marts, Amy Renae. "Magnetic Resonance Studies of Iron Spin Crossover Complexes and their Cobalt Analogs." Miami University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=miami1385033230.

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Books on the topic "Spin crossover complexes"

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Spin-Crossover Complexes. MDPI, 2018. http://dx.doi.org/10.3390/books978-3-03842-826-8.

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Book chapters on the topic "Spin crossover complexes"

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Weber, Birgit. "Novel Mononuclear Spin-Crossover Complexes." In Spin-Crossover Materials, 55–76. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch2.

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Olguín, Juan, and Sally Brooker. "Spin-Crossover in Discrete Polynuclear Complexes." In Spin-Crossover Materials, 77–120. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch3.

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Ovcharenko, Victor, and Elena Bagryanskaya. "Breathing Crystals from Copper Nitroxyl Complexes." In Spin-Crossover Materials, 239–80. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch9.

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Hayami, Shinya. "Amphiphilic and Liquid Crystalline Spin-Crossover Complexes." In Spin-Crossover Materials, 321–45. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch12.

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Boskovic, Colette. "Valence Tautomeric Transitions in Cobalt-dioxolene Complexes." In Spin-Crossover Materials, 203–24. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch7.

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Chergui, Majed. "Ultrafast Studies of the Light-Induced Spin Change in Fe(II)-Polypyridine Complexes." In Spin-Crossover Materials, 405–24. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118519301.ch15.

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Vogel, Carola S. "PhB(MesIm) 3 ? : Spin Crossover in a Four-Coordinate Iron(II) Complex." In High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, 119–32. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-27254-7_6.

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Gaspar, Ana B., Vadim Ksenofontov, Hartmut Spiering, Sergey Reiman, José A. Real, and Philipp Gütlich. "Interplay of Antiferromagnetic Coupling and Spin Crossover in Dinuclear Iron(II) Complexes." In Mössbauer Spectroscopy, 297–306. Dordrecht: Springer Netherlands, 2003. http://dx.doi.org/10.1007/978-94-010-0045-1_30.

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Klokishner, S. I., and O. S. Reu. "Spin Crossover in Trinuclear and Protonated Tetranuclear Iron(II) Complexes: DFT Modelling." In IFMBE Proceedings, 277–83. Cham: Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-92328-0_37.

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Shakirova, Olga G. "Thermally Induced Spin Crossover in Iron (II, III) Complexes with Tripodal Ligands." In Current Problems and Ways of Industry Development: Equipment and Technologies, 319–30. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-69421-0_34.

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Conference papers on the topic "Spin crossover complexes"

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Molnár, Gábor, Il'ya A. Gural'skyi, Lionel Salmon, William Nicolazzi, Carlos Quintero, Amal Akou, Khaldoun Abdul-kader, et al. "Bistable photonic nanostructures based on molecular spin crossover complexes." In SPIE Photonics Europe, edited by Hernán R. Míguez, Sergei G. Romanov, Lucio C. Andreani, and Christian Seassal. SPIE, 2012. http://dx.doi.org/10.1117/12.921849.

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TAYAGAKI, TAKESHI, KOICHIRO TANAKA, NAOKI YONEMURA, MASANOBU SHIRAI, and KEN-ICHI KAN'NO. "SYMMETRY LOWERING IN THE PHOTOINDUCED PHASE IN SPIN-CROSSOVER COMPLEXES." In Proceedings of 2000 International Conference. WORLD SCIENTIFIC, 2001. http://dx.doi.org/10.1142/9789812811387_0032.

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Jiang, Yifeng, Stuart Hayes, Simon Bittmann, Antoine Sarracini, Lai Chung Liu, Henrike M. Müller-Werkmeister, Jordan S. Wentzell, et al. "Capturing ultrafast synergistic spin transition in a multifunctional hybrid spin crossover system by ultrafast optical spectroscopy and electron diffraction." In International Conference on Ultrafast Phenomena. Washington, D.C.: Optica Publishing Group, 2022. http://dx.doi.org/10.1364/up.2022.f2a.3.

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Multifunctional spin crossover (SCO) complexes provide control over electronic properties of anions. Here, we study a prototypical complex to understand ultrafast reaction pathways and transitional structures and open a way for fast responsive multi-level photoswitches.
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Huse, N., H. N. Cho, T. K. Kim, L. Jamula, J. K. McCusker, and R. W. Schoenlein. "Ultrafast Soft X-ray Spectroscopy of Spin-crossover Dynamics in Solvated Transition-metal Complexes." In Laser Science. Washington, D.C.: OSA, 2009. http://dx.doi.org/10.1364/ls.2009.lstuc4.

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Gudyma, Iurii V., and Artur I. Maksymov. "Theoretical analysis of photoinduced first order phase transition in spin-crossover complexes under noise action." In Correlation Optics 2011, edited by Oleg V. Angelsky. SPIE, 2011. http://dx.doi.org/10.1117/12.917711.

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Ash, Ryan, Josh Vura-Weis, and Kaili Zhang. "TRACKING THE REACTION COORDINATE OF ULTRAFAST SPIN-CROSSOVER IN Fe(II) COMPLEXES WITH FEMTOSECOND M-EDGE XANES." In 2020 International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2020. http://dx.doi.org/10.15278/isms.2020.rh04.

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Nguyen, Thuy-Ai D., David E. Chavez, Alexander H. Mueller, Bryce C. Tappan, and Jacqueline M. Veauthier. "Investigation of explosive spin crossover complexes for on-demand initiation sensitivity and energetic polymers for additive manufacturing." In SHOCK COMPRESSION OF CONDENSED MATTER - 2019: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter. AIP Publishing, 2020. http://dx.doi.org/10.1063/12.0000867.

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Ash, Ryan, Josh Vura-Weis, and Kaili Zhang. "TRACKING THE REACTION COORDINATE OF ULTRAFAST SPIN-CROSSOVER IN Fe(II) COMPLEXES WITH FEMTOSECOND M-EDGE XANES." In 2021 International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2021. http://dx.doi.org/10.15278/isms.2021.rj02.

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KURODA, TAKAYOSHI. "SPIN CROSSOVER PROPERTIES OF IRON(II) COMPLEXES WITH A N4O2 DONOR SET BY EXTENDED Π-CONJUGATED SCHIFF-BASE LIGANDS." In Symposium on Quantum Information and Quantum Computing. WORLD SCIENTIFIC, 2012. http://dx.doi.org/10.1142/9789814425223_0011.

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Kimura, Akifumi, and Takayuki Ishida. "Substituent effect in spin-crossover behavior of iron(II)-Ar-pybox complexes (Ar-pybox = 4-aryl-2,6-bis(oxazolin-2-yl)pyridine)." In THE IRAGO CONFERENCE 2017: A 360-degree Outlook on Critical Scientific and Technological Challenges for a Sustainable Society. Author(s), 2018. http://dx.doi.org/10.1063/1.5021938.

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Reports on the topic "Spin crossover complexes"

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Wampler, James, Ping Wang, Michael Shatruk, Minseong Lee, and Vivien Zapf. Spin crossover transition in a Cobalt tautomeric complex. Office of Scientific and Technical Information (OSTI), January 2022. http://dx.doi.org/10.2172/1840869.

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