Academic literature on the topic 'Solid State Electrolyte (SSE)'

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Journal articles on the topic "Solid State Electrolyte (SSE)"

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Ping, Weiwei, Chengwei Wang, Ruiliu Wang, Qi Dong, Zhiwei Lin, Alexandra H. Brozena, Jiaqi Dai, Jian Luo, and Liangbing Hu. "Printable, high-performance solid-state electrolyte films." Science Advances 6, no. 47 (November 2020): eabc8641. http://dx.doi.org/10.1126/sciadv.abc8641.

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Current ceramic solid-state electrolyte (SSE) films have low ionic conductivities (10−8 to 10−5 S/cm ), attributed to the amorphous structure or volatile Li loss. Herein, we report a solution-based printing process followed by rapid (~3 s) high-temperature (~1500°C) reactive sintering for the fabrication of high-performance ceramic SSE films. The SSEs exhibit a dense, uniform structure and a superior ionic conductivity of up to 1 mS/cm. Furthermore, the fabrication time from precursor to final product is typically ~5 min, 10 to 100 times faster than conventional SSE syntheses. This printing and rapid sintering process also allows the layer-by-layer fabrication of multilayer structures without cross-contamination. As a proof of concept, we demonstrate a printed solid-state battery with conformal interfaces and excellent cycling stability. Our technique can be readily extended to other thin-film SSEs, which open previously unexplores opportunities in developing safe, high-performance solid-state batteries and other thin-film devices.
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Isarraras, Gustavo, Tung Dang, Dirar Mashaleh, Michael Oye, Dahyun Oh, and Santosh KC. "Tuning Ionic Conductivity and Stability of Li10GeP2S12 Solid-State Electrolyte." ECS Meeting Abstracts MA2022-01, no. 2 (July 7, 2022): 212. http://dx.doi.org/10.1149/ma2022-012212mtgabs.

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All-solid-state Li-ion batteries gained a huge attention because they exhibit higher power density, wider electrochemical stability windows, and overall safety of solid-state electrolytes (SSE) compared to conventional liquid electrolyte-based batteries. Unfortunately, most of the SSE materials have not matched the ionic conductivity of their liquid counterpart. But, recent research and the synthesis of new materials have shown SSE can conduct ions at an equivalent or even higher rate. However, the electrochemical stability needs to be improved. There is a growing research effort in identifying a solid electrolyte that is both electrochemically stable and has a very high ionic conductivity. The Li10GeP2S12 (LGPS) is one of the superionic conductors, is known for its high ionic conductivity that can be deployed as a solid electrolyte in batteries. However, LGPS is not stable as exposed to air and moisture, posing challenges during its manufacturing, and designing process. Thus, in an attempt to optimize the stability and ionic conductivity, the effect of antimony (Sb), tin (Sn), and oxygen (O) substitution on conductivity and stability of LGPS is investigated using Density Functional Theory (DFT). The systematic study of compositional variation, phase stability, defects chemistry, and the impact on electronic properties and ionic conductivity is performed. Thus, this study will provide significant insights on ion conduction mechanisms and strategies that can tune the ionic conductivity and stability of LGPS based electrolytes. This project was supported in part by COE SJSU, DOE NERSC, and XSEDE.
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Hu, Shengyi, and Chun Huang. "Machine-Learning Approaches for the Discovery of Electrolyte Materials for Solid-State Lithium Batteries." Batteries 9, no. 4 (April 17, 2023): 228. http://dx.doi.org/10.3390/batteries9040228.

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Solid-state lithium batteries have attracted considerable research attention for their potential advantages over conventional liquid electrolyte lithium batteries. The discovery of lithium solid-state electrolytes (SSEs) is still undergoing to solve the remaining challenges, and machine learning (ML) approaches could potentially accelerate the process significantly. This review introduces common ML techniques employed in materials discovery and an overview of ML applications in lithium SSE discovery, with perspectives on the key issues and future outlooks.
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Liu, Junlong, Tao Wang, Jinjian Yu, Shuyang Li, Hong Ma, and Xiaolong Liu. "Review of the Developments and Difficulties in Inorganic Solid-State Electrolytes." Materials 16, no. 6 (March 21, 2023): 2510. http://dx.doi.org/10.3390/ma16062510.

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All-solid-state lithium-ion batteries (ASSLIBs), with their exceptional attributes, have captured the attention of researchers. They offer a viable solution to the inherent flaws of traditional lithium-ion batteries. The crux of an ASSLB lies in its solid-state electrolyte (SSE) which shows higher stability and safety compared to liquid electrolyte. Additionally, it holds the promise of being compatible with Li metal anode, thereby realizing higher capacity. Inorganic SSEs have undergone tremendous developments in the last few decades; however, their practical applications still face difficulties such as the electrode–electrolyte interface, air stability, and so on. The structural composition of inorganic electrolytes is inherently linked to the advantages and difficulties they present. This article provides a comprehensive explanation of the development, structure, and Li-ion transport mechanism of representative inorganic SSEs. Moreover, corresponding difficulties such as interface issues and air stability as well as possible solutions are also discussed.
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Bistri, Donald, and Claudio V. Di Leo. "A Thermodynamically Consistent, Phase-Field Electro-Chemo-Mechanical Theory with Account for Damage in Solids: Application to Metal Filament Growth in Solid-State Batteries." ECS Meeting Abstracts MA2022-02, no. 4 (October 9, 2022): 523. http://dx.doi.org/10.1149/ma2022-024523mtgabs.

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Solid-state batteries (SSBs) present a promising technology and have attracted significant research attention owing to their superior properties including increased energy density (3860 mAh), wider electrochemical window (0-5V) and safer electrolyte design. From a safety standpoint, SSBs are particularly appealing in that replacement of flammable conventional organic electrolytes with highly conductive, mechanically stiff inorganic solid-state electrolytes (SSEs) can alleviate failure due to short circuit or ignition. However, operation of SSBs is hampered by numerous chemo-mechanical challenges [1 - 4], the most critical one associated with metal filament growth across the SSE. Filament protrusions can initiate at perturbations of the interface or microstructural heterogeneities and subsequently grow through the SSE, causing the battery to short-circuit. It is critical to understand from both an experimental and modeling perspective the interplay of various mechanisms including morphology of the SSE microstructure, elastic-viscoplastic behavior of Li-metal, critical current density and stack pressure on the morphology of filamentary protrusions across the SSE. While much has been done to understand the interplay of aforementioned mechanisms from an experimental standpoint [5,6], theoretical frameworks on modeling of filaments growth in SSBs are still at their infancy and typically simplify dendrites as pressurized cracks under a linear-elastic fracture mechanics (LEFM) approach [7-8]. In this work, we propose a thermodynamically consistent phase-field reaction-diffusion-damage theory to investigate the morphology of filament growth across the SSE under varying chemo-mechanical operational conditions. The theory is fully coupled with electrodeposition at the Li metal-SSE interface impacting mechanical deformation, stress generation and subsequent fracture of the SSE. Conversely, electrodeposition kinetics are affected by mechanical stresses through a thermodynamically consistent, physically motivated driving force that distinguishes the role of various chemical, electrical and mechanical contributions. Concurrently, the theory captures the interplay between crack propagation and electrodeposition phenomena by tracking the damage and reaction field using separate phase-field variables such that metal growth is preceded by and confined to damaged regions within the SSE accessible by Li-metal. This is a critical feature of the theory and confirms experimental observations that the crack front propagates ahead of Li. We specialize the theory and study the role of variations of chemo-mechanical properties (i.e. applied electric potential, SSE fracture energy) on the morphology of metal filament growth and map operational conditions to distinguish between domains of i) stable vs. unstable growth ii) intergranular vs. transgranular growth mode. In doing so, the proposed framework provides a quantitative understanding on mechanisms dictating metal filament growth in SSEs and identifies mitigation strategies to employ in future SSB designs for successful operation. References: [1] Zhang, Fangzhou, et al. "A review of mechanics-related material damages in all-solid-state batteries: Mechanisms, performance impacts and mitigation strategies." Nano Energy 70 (2020): 104545. [2] Bistri, Donald, Arman Afshar, and Claudio V. Di Leo. "Modeling the chemo-mechanical behavior of all-solid-state batteries: a review." Meccanica 56.6 (2021): 1523-1554. [3] Wang, Peng, et al. "Electro–chemo–mechanical issues at the interfaces in solid‐state lithium metal batteries." Advanced Functional Materials 29.27 (2019): 1900950 [4] Bistri, Donald, and Claudio V. Di Leo. "Modeling of Chemo-Mechanical Multi-Particle Interactions in Composite Electrodes for Liquid and Solid-State Li-Ion Batteries." Journal of The Electrochemical Society 168.3 (2021): 030515. [5] Ren, Yaoyu, et al. "Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte." Electrochemistry Communications 57 (2015): 27-30. [6] Cheng, Eric Jianfeng, Asma Sharafi, and Jeff Sakamoto. "Intergranular Li metal propagation through polycrystalline Li6. 25Al0. 25La3Zr2O12 ceramic electrolyte." Electrochimica Acta 223 (2017): 85-91. [7] Klinsmann, Markus, et al. "Dendritic cracking in solid electrolytes driven by lithium insertion." Journal of Power Sources 442 (2019): 227226. [8] Bucci, Giovanna, and Jake Christensen. "Modeling of lithium electrodeposition at the lithium/ceramic electrolyte interface: the role of interfacial resistance and surface defects." Journal of Power Sources 441 (2019): 227186.
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Kalutara Koralalage, Milinda, Varun Shreyas, William Richard Arnold, Sharmin Akter, Arjun Thapa, Jacek Bogdan Jasinski, Gamini Sumanasekera, Hui Wang, and Badri Narayanan. "Quasi-Solid-State Lithium-Sulfur Batteries Consist of Super P – Sulfur Composite Cathode." ECS Meeting Abstracts MA2022-02, no. 4 (October 9, 2022): 541. http://dx.doi.org/10.1149/ma2022-024541mtgabs.

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Lithium-Sulfur (Li-S) batteries stand out to be one of the most promising candidates to meet the current energy storage requirement, with its natural abundance of materials, high theoretical capacity of 1672 mAhg-1, high energy density of 2600 Whkg-1, and low cost and lower environmental impact. Sulfur itself (S8), Li2S2 and Li2S formed during the discharge process, are electrical insulators and hence reduce the active material utilization and the electronic conductivity of the cathode affecting the battery performance. Combining of Carbon Super P (SP) with sulfur in cathode formulation is used to overcome these issues. In Liquid electrolyte batteries, polysulfides formed while charging and discharging, easily dissolve in liquid electrolyte and the resulting polysulfide shuttling leads to poor coulombic efficiency and cyclability. Liquid electrolytes used in the conventional Li-S batteries are easy to flow and become flammable. Further, Lithium dendrites piercing through separator causing short circuit paths leads to safety concerns. Replacement of the liquid electrolyte by a solid-state electrolyte (SSE) proves to be a strategy to overcome above mentioned issues. Sulfide based solid electrolytes have received greater attention due to their higher ionic conductivity, compatible interface with sulfur-based cathodes, and lower grain boundary resistance. Novel Li6PS5F0.5Cl0.5 due to its remarkable ionic conductivity of 3.5 x 10-4 S cm-1 makes it an excellent candidate for use in a Li-S solid state battery. However, the interface between SSEs and cathodes has become a challenge to be addressed in all solid-state Li-S batteries due to the rigidity of the participating surfaces. A hybrid electrolyte containing of SSE coupled with a small amount of ionic liquid at the interface, has been employed to improve the interface contact of the SSE with the electrodes. Cathode formulation consisting of sulfur as the active material, Super P as the conductive carbon black, acetylene carbon black as conductive carbon additive, with water based carboxymethyl cellulose (CMC) solution and Styrene butadiene rubber (SBR) as the binder was successfully developed. Thermo gravimetric analysis (TGA) studies of the cathode were carried out by the thermo gravimetric analyzer TA 2050 under N2 gas flow of 100 ml/min. Cathode surface morphology was characterized using the Field emission gun scanning electron microscope (FEI), TESCAN scanning electron microscope with energy dispersive X-ray spectroscopy (EDAX). Using a solvent-based process, Li6PS5F0.5Cl0.5 and Li6PS5F0.5Cl2 SSE were synthesized via the introduction of LiF into the argyrodite crystal structure, which enhances both the ionic conductivity and interface-stabilizing properties of the SSE. Relevant Ionic Liquids (IL) were prepared using Lithium bis(trifluoromethyl sulfonyl)imide (LiTFSI) as salt, with premixed pyrrolidinium bis(trifluoromethyl sulfonyl)imide (PYR) as solvent and 1,3-dioxolane (DOL) as diluent. SP-S cathode with 0.70 mgcm-2 sulfur loading was punched into disks of 2.0 cm2. SSE was pressed into 150 mg pellets using a stainless-steel tank. During the assembly, SSE was wetted with total of 40 μl of IL (LiTFSI dissolved in PYR and DOL solution) from both ends using a micropipette. 2032 type coin cells of Quasi-solid-state Li-S batteries (QSSLSB) consisting of SP-S based composite cathodes, Li anodes and novel Li6PS5F0.5Cl0.5 SSE were tested with an ionic liquid wetting both electrode-SSE interfaces. All the QSSLSB were cycled at 30 °C between 1.0 V and 2.8 V using an 8 channel Arbin battery testing system. Effect of IL dilution, co-solvent amount, LiTFSI concentration and C rate at which the batteries are tested, were systematically studied and optimized to develop a QSSLSB with higher capacity retention and cyclability. Optimum batteries had initial discharge capacity >1100 mAh/g and discharge capacity >400 mAh/g after 100 cycles at the C rate of C/10 with a significant coulombic efficiency. 40 μl of LiTFSI (2M) dissolved in PYR:DOL(1:1) IL was found to be optimum for high performance QSSEBs with low sulfur loading of 0.7 mg/cm2. From the C rate performance study QSSEBs have shown improved stability with the higher current rates. Next, cathodes with higher sulfur loading were studied and for sulfur loading > 4 mgcm-2, initial discharge capacity >950 mAh/g and 400 mAh/g after 60 cycles at C/20 rate were achieved with 40 μl of IL consisting of LiTFSI (3M) dissolved in PYR:DOL(1:3) for the SSE Li6PS5F0.5Cl2. Further testing is underway to improve the performance at high C rate for higher loading by incorporating SSE in the cathode to realize QSSLSB with higher capacity with improved cycle retention.
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Fu, Yao, Dangling Liu, Yongjiang Sun, Genfu Zhao, and Hong Guo. "Epoxy Resin-Reinforced F-Assisted Na3Zr2Si2PO12 Solid Electrolyte for Solid-State Sodium Metal Batteries." Batteries 9, no. 6 (June 19, 2023): 331. http://dx.doi.org/10.3390/batteries9060331.

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Solid sodium ion batteries (SIBs) show a significant amount of potential for development as energy storage systems; therefore, there is an urgent need to explore an efficient solid electrolyte for SIBs. Na3Zr2Si2PO12 (NZSP) is regarded as one of the most potential solid-state electrolytes (SSE) for SIBs, with good thermal stability and mechanical properties. However, NZSP has low room temperature ionic conductivity and large interfacial impedance. F−doped NZSP has a larger grain size and density, which is beneficial for acquiring higher ionic conductivity, and the composite system prepared with epoxy can further improve density and inhibit Na dendrite growth. The composite system exhibits an outstanding Na+ conductivity of 0.67 mS cm−1 at room temperature and an ionic mobility number of 0.79. It also has a wider electrochemical stability window and cycling stability.
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Bock, Robert, Morten Onsrud, Håvard Karoliussen, Bruno Pollet, Frode Seland, and Odne Burheim. "Thermal Gradients with Sintered Solid State Electrolytes in Lithium-Ion Batteries." Energies 13, no. 1 (January 3, 2020): 253. http://dx.doi.org/10.3390/en13010253.

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The electrolyte is one of the three essential constituents of a Lithium-Ion battery (LiB) in addition to the anode and cathode. During increasingly high power and high current charging and discharging, the requirement for the electrolyte becomes more strict. Solid State Electrolyte (SSE) sees its niche for high power applications due to its ability to suppress concentration polarization and otherwise stable properties also related to safety. During high power and high current cycling, heat management becomes more important and thermal conductivity measurements are needed. In this work, thermal conductivity was measured for three types of solid state electrolytes: Li 7 La 3 Zr 2 O 12 (LLZO), Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP), and Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) at different compaction pressures. LAGP and LATP were measured after sintering, and LLZO was measured before and after sintering the sample material. Thermal conductivity for the sintered electrolytes was measured to 0.470 ± 0.009 WK − 1 m − 1 , 0.5 ± 0.2 WK − 1 m − 1 and 0.49 ± 0.02 WK − 1 m − 1 for LLZO, LAGP, and LATP respectively. Before sintering, LLZO showed a thermal conductivity of 0.22 ± 0.02 WK − 1 m − 1 . An analytical temperature distribution model for a battery stack of 24 cells shows temperature differences between battery center and edge of 1–2 K for standard liquid electrolytes and 7–9 K for solid state electrolytes, both at the same C-rate of four.
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Yang, Guang, Yuxuan Zhang, Ethan Self, Teerth Brahmbhatt, Jean-Christophe Bilheux, Hassina Bilheux, and Jagjit Nanda. "(Invited) Initial Capacity Loss Mechanism of All-Solid-State Lithium Sulfide Battery Unraveled By in Situ Neutron Tomography." ECS Meeting Abstracts MA2022-01, no. 2 (July 7, 2022): 205. http://dx.doi.org/10.1149/ma2022-012205mtgabs.

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All-solid-state lithium metal batteries promise a specific energy >500 Wh/kg. A solid-state electrolyte (SSE) plays an irreplaceable role in reaching such an energy density goal. Among different SSE types, the sulfide and thiophosphate-based SSE has emerged as a prominent class of soft ionic conductors. Compared to their ceramic and oxide SSE counterparts, sulfide SSEs provide several favorable advantages, including a) high room temperature ionic conductivity up to 10 mS/cm that is comparable to liquid-based electrolytes; b) ductile and mechanically soft SSE that enables better processible and intimate contact with electrodes; and c) scalability with solution-based low-temperature synthesis route. However, when paring with a high voltage cathode, such as lithium nickel manganese cobalt oxide (NMC), the (electro)chemical instability of the sulfide SSE at the electrode/SSE interfaces becomes a major challenge to tackle with. The interfacial instability can result in up to 50% initial capacity loss in a Li/sulfide SSE/NMC battery, thereby keeping the sulfide SSEs from commercialization. Herein, by using neutron computed tomography, we trace in situ lithium displacement in an all-solid-state battery composed of a 7Li anode, natLi3PS4(LPS) electrolyte, and a natLiNi0.8Mn0.1Co0.1O2 (NMC811) cathode. We show that after the first galvanostatic charge/discharge cycle, lithium accumulates at the LPS/NMC811 interface and preferably fills in the pre-formed cracks in the cold-pressed LPS SSE pellet. Such irreversible lithium displacement contributes to the initial capacity loss of the Li/LPS/NMC battery. Our findings suggest that to achieve high-capacity retention of an all-solid-state sulfide-based battery using an NMC cathode, the cathode/sulfide interface should be better engineered and the defects of the LPS pellet should be suppressed. Acknowledgment This research was conducted at Oak Ridge National Laboratory, managed by UT Battelle, LLC, for the U.S. Department of Energy (DOE) and is supported by Asst. Secretary, Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (VTO) through the Advanced Battery Materials Research (BMR) Program. This research used resources at High Flux Isotope Reactor, a DOE Office of Science User Facilities operated by the Oak Ridge National Laboratory.
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Ryu, Kun, Kyungbin Lee, Hyun Ju, Jinho Park, Ilan Stern, and Seung Woo Lee. "Ceramic/Polymer Hybrid Electrolyte with Enhanced Interfacial Contact for All-Solid-State Lithium Batteries." ECS Meeting Abstracts MA2022-02, no. 7 (October 9, 2022): 2621. http://dx.doi.org/10.1149/ma2022-0272621mtgabs.

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All solid-state lithium batteries (ASSLBs) with a high energy density are challenging, yet desired by the rising energy demands. Its intrinsic safety of solid-state electrolytes (SSEs) compared to flammable liquid electrolytes makes ASSLBs a modern-day necessity. NASICON-type Li1.5Al0.5Ge1.5P3O12 (LAGP) has high ionic conductivity, high stability against air and water, and a wide electrochemical window. However, the application of LAGP is significantly hindered by its slow interfacial kinetics and brittle nature. In addition, the ionic conductivity of LAGP is relatively low at room temperature compared to that obtained at elevated temperatures. In our study, LAGP was incorporated into a polymer matrix to accelerate charge transport at the electrode-electrolyte interface to form LAGP-poly-DOL (LAGP-pDOL) hybrid electrolyte. The in-situ cationic ring-opening polymerization of DOL decreases the interfacial contact impedance and improves the mechanical properties of the SSE. LAGP-pDOL electrolyte exhibits prolonged cycle stability in symmetric cells (> 200 h) and in Li|LiFePO4 full cells (99% retention after 50 cycles) at room temperature. This study demonstrates the effective utilization of conductive polymer matrix into LAGP to enhance mechanical strength, interfacial contact, and room temperature electrochemical performance.
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Dissertations / Theses on the topic "Solid State Electrolyte (SSE)"

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Hernandez, Alvarez Erick Ivan. "Electrolyte selection for cobalt-free solid-state batteries." Thesis, Massachusetts Institute of Technology, 2018. http://hdl.handle.net/1721.1/119602.

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Thesis: S.B., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2018.
Cataloged from PDF version of thesis.
Includes bibliographical references (page 30).
Lithium-ion batteries are widespread in use due to their thermal stability and high energy density. The most common design uses an organic electrolyte and lithium-cobalt electrode. While safe under typical operating conditions, the use of an organic electrolyte subjects the battery user to certain risks; in particular, Li-ion liquid batteries are explosive when exposed to air and subject to thermal runoff, making them highly sensitive to any physical damage. The use of cobalt also poses a moral concern, as the mining and sourcing of cobalt is geographically restricted and most commonly sourced from countries that have a history of foreign exploitation and child labor. An all solid state battery is suggested as a possible alternative battery that reduces operation risks and maintains similar performance characteristics. Lithium-lanthanum-zirconium oxide is presented as a suitable electrolyte replacement. Coupled with cobalt-free electrodes, this battery design would provide a safer, more responsible battery.
by Erick Ivan Hernandez Alvarez.
S.B.
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Yada, Chihiro. "Studies on electrode/solid electrolyte interface of all-solid-state rechargeable lithium batteries." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/144024.

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Kyoto University (京都大学)
0048
新制・課程博士
博士(工学)
甲第12338号
工博第2667号
新制||工||1377(附属図書館)
24174
UT51-2006-J330
京都大学大学院工学研究科物質エネルギー化学専攻
(主査)教授 小久見 善八, 教授 江口 浩一, 教授 田中 功
学位規則第4条第1項該当
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Howell, Ian. "The structure of some simple aqueous electrolyte solutions." Thesis, University of Bristol, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386083.

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Shao, Yunfan. "Highly electrochemical stable quaternary solid polymer electrolyte for all-solid-state lithium metal batteries." University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron1522332577785545.

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Li, Si. "HIGHLY CONDUCTIVE SOLID POLYMER ELECTROLYTE CONTAINING LiBOB AT ROOM TEMPERATURE FOR ALL SOLID STATE BATTERY." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1490481514905008.

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Chen, Kezheng. "Origin of Polarization Behavior in All-Solid-State Lithium-Ion Battery Using Sulfide Solid Electrolyte." Kyoto University, 2018. http://hdl.handle.net/2433/235998.

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Yin, Yijing. "An Experimental Study on PEO Polymer Electrolyte Based All-Solid-State Supercapacitor." Scholarly Repository, 2010. http://scholarlyrepository.miami.edu/oa_dissertations/440.

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Supercapacitors are one of the most important electrochemical energy storage and conversion devices, however low ionic conductivity of solid state polymer electrolytes and the poor accessibility of the ions to the active sites in the porous electrode will cause low performance for all-solid-state supercapacitors and will limit their application. The objective of the dissertation is to improve the performance of all-solid-state supercapactor by improving electrolyte conductivity and solving accessibility problem of the ions to the active sites. The low ionic conductivity (10-8 S/cm) of poly(ethylene oxide) (PEO) limits its application as an electrolyte. Since PEO is a semicrystal polymer and the ion conduction take place mainly in the amorphous regions of the PEO/Lithium salt complex, improvements in the percentage of amorphous phase in PEO or increasing the charge carrier concentration and mobility could increase the ionic conductivity of PEO electrolyte. Hot pressing along with the additions of different lithium salts, inorganic fillers and plasticizers were applied to improve the ionic conductivity of PEO polymer electrolytes. Four electrode methods were used to evaluate the conductivity of PEO based polymer electrolytes. Results show that adding certain lithium salts, inorganic fillers, and plasticizers could improve the ionic conductivity of PEO electrolytes up 10-4 S/cm. Further hot pressing treatment could improve the ionic conductivity of PEO electrolytes up to 10-3 S/cm. The conductivity improvement after hot pressing treatment is elucidated as that the spherulite crystal phase is convert into the fringed micelle crystal phase or the amorphous phase of PEO electrolytes. PEO electrolytes were added into active carbon as a binder and an ion conductor, so as to provide electrodes with not only ion conduction, but also the accessibility of ion to the active sites of electrodes. The NaI/I2 mediator was added to improve the conductivity of PEO electrolyte and provide pseudocapacitance for all-solid-state supercapacitors. Impedance, cyclic voltammetry, and gavalnostatic charge/discharge measurements were conducted to evaluate the electrochemical performance of PEO polymer electrolytes based all-solid-state supercapacitors. Results demonstrate that the conductivity of PEO electrolyte could be improved to 0.1 S/cm with a mediator concentration of 50wt%. A high conductivity in the PEO electrolyte with mediator is an indication of a high electron exchange rate between the mediator and mediator. The high electron exchange rates at mediator carbon interface and between mediator and mediator are essential in order to obtain a high response rate and high power. This automatically solves the accessibility problem. With the addition of NaI/I2 mediator, the specific capacitance increased more than 30 folds, specific power increased almost 20 folds, and specific energy increased around 10 folds. Further addition of filler to the electrodes along with the mediator could double the specific capacitor and specific power of the all-solid-state supercapacitor. The stability of the corresponded supercapacitor is good within 2000 cycles.
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Zhao, Fangtong. "A SOLID-STATE COMPOSITE ELECTROLYTE FOR LITHIUM-ION BATTERIES WITH 3D-PRINTING FABRICATION." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619814091802231.

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Sun, Bing. "Functional Polymer Electrolytes for Multidimensional All-Solid-State Lithium Batteries." Doctoral thesis, Uppsala universitet, Strukturkemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-248084.

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Pressing demands for high power and high energy densities in novel electrical energy storage units have caused reconsiderations regarding both the choice of battery chemistry and design. Practical concerns originating in the conventional use of flammable liquid electrolytes have renewed the interests of using solvent-free polymer electrolytes (SPEs) as solid ionic conductors for safer batteries. In this thesis work, SPEs developed from two polymer host structures, polyethers and polycarbonates, have been investigated for all-solid-state Li- and Li-ion battery applications. In the first part, functional polyether-based polymer electrolytes, such as poly(propylene glycol) triamine based oligomer and poly(propylene oxide)-based acrylates, were investigated for 3D-microbattery applications. The amine end-groups were favorable for forming conformal electrolyte coatings onto 3D electrodes via self-assembly. In-situ polymerization methods such as UV-initiated and electro-initiated polymerization techniques also showed potential to deposit uniform and conformal polymer coatings with thicknesses down to nano-dimensions. Moreover, poly(trimethylene carbonate) (PTMC), an alternative to the commonly investigated polyether host materials, was synthesized for SPE applications and showed promising functionality as battery electrolyte. High-molecular-weight PTMC was first applied in LiFePO4-based batteries. By incorporating an oligomeric PTMC as an interfacial mediator, enhanced surface contacts at the electrode/SPE interfaces and obvious improvements in initial capacities were realized. In addition, room-temperature functionality of PTMC-based SPEs was explored through copolymerization of ε-caprolactone (CL) with TMC. Stable cycling performance at ambient temperatures was confirmed in P(TMC/CL)-based LiFePO4 half cells (e.g., around 80 and 150 mAh g-1 at 22 °C and 40 °C under C/20 rate, respectively). Through functionalization, hydroxyl-capped PTMC demonstrated good surface adhesion to metal oxides and was applied on non-planar electrodes. Ionic transport behavior in polycarbonate-SPEs was examined by both experimental and computational approaches. A coupling of Li ion transport with the polymer chain motions was demonstrated. The final part of this work has been focused on exploring the key characteristics of the electrode/SPE interfacial chemistry using PEO and PTMC host materials, respectively. X-ray photoelectron spectroscopy (XPS) was used to get insights on the compositions of the interphase layers in both graphite and LiFePO4 half cells.
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Yang, Run. "A Superionic Conductive Solid Polymer Electrolyte Based Solid Sodium Metal Batteries with Stable Cycling Performance at Room Temperature." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619741453185762.

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Books on the topic "Solid State Electrolyte (SSE)"

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State II: Application Aspects. Springer London, Limited, 2013.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State II: Application Aspects. Springer, 2013.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State II: Application Aspects. Springer, 2013.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State II: Application Aspects. Springer, 2016.

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Mller, Martin. Polyelectrolyte Complexes in the Dispersed and Solid State I: Principles and Theory. Springer Berlin / Heidelberg, 2013.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State I: Principles and Theory. Springer London, Limited, 2014.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State I: Principles and Theory. Springer, 2016.

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ller, Martin Mu. Polyelectrolyte Complexes in the Dispersed and Solid State I: Principles and Theory. Springer, 2013.

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Crowell, Kevin James. Solid state nuclear magnetic resonance studies of select electrolyte interactions with phospholipid bilayer membranes in various model membrane systems. 2002, 2002.

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Book chapters on the topic "Solid State Electrolyte (SSE)"

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Abraham, K. M. "Lithium Organic Liquid Electrolyte Batteries." In Solid State Batteries, 337–49. Dordrecht: Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-5167-9_22.

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Li, Yuyu, and Ming Xie. "Sodium-Ion Solid-State Electrolyte." In ACS Symposium Series, 275–94. Washington, DC: American Chemical Society, 2022. http://dx.doi.org/10.1021/bk-2022-1413.ch011.

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Goodenough, John B. "Designing a Solid Electrolyte II. Strategies and Illustrations." In Solid State Microbatteries, 177–93. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2263-2_9.

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Radhakrishnan, K. "Thin Films of Solid Electrolyte and Their Applications." In Solid State Materials, 110–21. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09935-3_6.

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Goodenough, John B. "Designing a Solid Electrolyte III. Proton Conduction and Composites." In Solid State Microbatteries, 195–212. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2263-2_10.

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Goodenough, John B. "Designing a Solid Electrolyte I. Quality Criteria and Applications." In Solid State Microbatteries, 157–75. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2263-2_8.

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Goodenough, John B. "Designing a Solid Electrolyte IV. Designing a Reversible Solid Electrode." In Solid State Microbatteries, 213–32. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2263-2_11.

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Jin, Bong Soo, Bok Ki Min, and Chil Hoon Doh. "Characteristics of Lithium Polysilicate Electrolyte Synthesized by Sol-Gel Processing." In Solid State Phenomena, 1031–34. Stafa: Trans Tech Publications Ltd., 2007. http://dx.doi.org/10.4028/3-908451-31-0.1031.

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Kim, Seok, J. Y. Kang, Sung Goo Lee, Jae Rock Lee, and Soo Jin Park. "Influence of Clay Addition on Ion Conductivity of Polymeric Electrolyte Composites." In Solid State Phenomena, 155–58. Stafa: Trans Tech Publications Ltd., 2006. http://dx.doi.org/10.4028/3-908451-18-3.155.

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Choi, Jae Won, Gouri Cheruvally, Yong Jo Shin, Hyo Jun Ahn, Ki Won Kim, and Jou Hyeon Ahn. "Effect of Various Lithium Salts in TEGDME Based Electrolyte for Li/Pyrite Battery." In Solid State Phenomena, 971–74. Stafa: Trans Tech Publications Ltd., 2007. http://dx.doi.org/10.4028/3-908451-31-0.971.

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Conference papers on the topic "Solid State Electrolyte (SSE)"

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Liu, Wei, Ryan Milcarek, Kang Wang, and Jeongmin Ahn. "Novel Structured Electrolyte for All-Solid-State Lithium Ion Batteries." In ASME 2015 13th International Conference on Fuel Cell Science, Engineering and Technology collocated with the ASME 2015 Power Conference, the ASME 2015 9th International Conference on Energy Sustainability, and the ASME 2015 Nuclear Forum. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/fuelcell2015-49384.

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In this study, a multi-layer structure solid electrolyte (SE) for all-solid-state electrolyte lithium ion batteries (ASSLIBs) was fabricated and characterized. The SE was fabricated by laminating ceramic electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) with polymer (PEO)10-Li(N(CF3SO2)2 electrolyte and gel-polymer electrolyte of PVdF-HFP/ Li(N(CF3SO2)2. It is shown that the interfacial resistance is generated by poor contact at the interface of the solid electrolytes. The lamination protocol, material selection and fabrication method play a key role in the fabrication process of practical multi-layer SEs.
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Wendler, F., P. Buschel, O. Kanoun, J. Schadewald, C. C. Bof Bufon, and O. G. Schmidt. "Impedance spectroscopy in solid state electrolyte characterization." In 2012 IEEE 9th International Multi-Conference on Systems, Signals and Devices (SSD). IEEE, 2012. http://dx.doi.org/10.1109/ssd.2012.6198113.

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Zhang, Qifeng, and Yi Ding. "A New Solid Electrolyte with A High Lithium Ionic Conductivity for Solid-State Lithium-Ion Batteries." In WCX SAE World Congress Experience. 400 Commonwealth Drive, Warrendale, PA, United States: SAE International, 2023. http://dx.doi.org/10.4271/2023-01-0519.

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<div class="section abstract"><div class="htmlview paragraph">Solid-state lithium-ion batteries that use a solid electrolyte may potentially operate at wide temperatures and provide satisfactory safety. Moreover, the use of a solid electrolyte, which blocks the formation of lithium dendrites, allows batteries to use metallic lithium for the anode, enabling the batteries gain an energy density significantly higher than that of traditional lithium-ion batteries. Solid electrolytes play a role of conducting lithium ions and are the core of solid-state lithium-ion batteries. However, the development of solid lithium electrolytes towards a high lithium ionic conductivity, good chemical and electrochemical stability and scalable manufacturing method has been challenging. We report a new material composed of nitrogen-doped lithium metaphosphate, denoted as NLiPO<sub>3</sub>. The material delivers a lithium ionic conductivity on the order of 10<sup>-4</sup> S/cm at room temperature, which is about two orders of magnitude higher than that of conventional LiPON – the electrolyte currently used in solid-state thin-film lithium-ion batteries, and is comparable or generally higher than that of most of the existing solid electrolytes. The high lithium ionic conductivity was attributed to the formation of <span class="formula inline"><math display="inline" id="M1"><mi mathvariant="normal">P</mi><mo>−</mo><mi mathvariant="normal">N</mi><mo>&lt;</mo><mtable displaystyle="true"><mtr><mtd><mi mathvariant="normal">P</mi></mtd></mtr><mtr><mtd><mi mathvariant="normal">P</mi></mtd></mtr></mtable></math></span> bonds in amorphous LiPO<sub>3</sub>. The material is stable in ambient environment over a wide range of temperature and can be handled and processed easily. These merits make the material a promising electrolyte for solid-state lithium-ion battery applications.</div></div>
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Sakamoto, Toshitsugu, Hiroshi Sunamura, Hisao Kawaura, Tsuyoshi Hasegawa, Tomonobu Nakayama, and Masakazu Aono. "Solid-electrolyte nanometer switch." In 2003 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2003. http://dx.doi.org/10.7567/ssdm.2003.e-7-1.

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Ramesh, S., K. C. James Raju, and C. Vishnuvardhan Reddy. "Characterization of SDC-Al2O3 solid electrolyte." In SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. AIP, 2012. http://dx.doi.org/10.1063/1.4710323.

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Maohua, Chen, Rayavarapu Prasada Rao, and Stefan Adams. "All-Solid-State Lithium Batteries Using Li6PS5Br Solid Electrolyte." In 14th Asian Conference on Solid State Ionics (ACSSI 2014). Singapore: Research Publishing Services, 2014. http://dx.doi.org/10.3850/978-981-09-1137-9_154.

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Banno, N., T. Sakamoto, S. Fujieda, and M. Aono. "On-state reliability of solid-electrolyte switch." In 2008 IEEE International Reliability Physics Symposium (IRPS). IEEE, 2008. http://dx.doi.org/10.1109/relphy.2008.4558999.

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Finsterbusch, Martin. "Oxide-Electrolyte Based All-Solid-State Batteries." In Materials for Sustainable Development Conference (MAT-SUS). València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2022. http://dx.doi.org/10.29363/nanoge.nfm.2022.088.

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Kumar, P. Naveen, U. Sasikala, P. Chandra Sekhar, V. B. S. Achari, V. V. R. N. Rao, A. K. Sharma, Alka B. Garg, R. Mittal, and R. Mukhopadhyay. "Discharge Characteristics of Low Molecular Weight Solid Polymer Electrolyte." In SOLID STATE PHYSICS, PROCEEDINGS OF THE 55TH DAE SOLID STATE PHYSICS SYMPOSIUM 2010. AIP, 2011. http://dx.doi.org/10.1063/1.3606028.

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Mishra, Kuldeep, S. S. Pundir, and D. K. Rai. "All-solid-state proton battery using gel polymer electrolyte." In SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4872700.

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Reports on the topic "Solid State Electrolyte (SSE)"

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Zhang, Pu. All Solid State Batteries Enabled by Multifunctional Electrolyte Materials. Office of Scientific and Technical Information (OSTI), December 2022. http://dx.doi.org/10.2172/1906484.

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Turner, Allen. Power and Thermal Technologies for Air and Space. Delivery Order 0001: Single Ionic Conducting Solid-State Electrolyte. Fort Belvoir, VA: Defense Technical Information Center, November 2005. http://dx.doi.org/10.21236/ada460518.

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Takeuchi, Esther, Amy Marschilok, and Kenneth Takeuchi. Final Technical Report - DE-EE0007785 - Dual Function Solid State Battery with Self-Forming Self-Healing Electrolyte and Separator. Office of Scientific and Technical Information (OSTI), June 2021. http://dx.doi.org/10.2172/1787465.

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