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Journal articles on the topic 'Solid electrodes][Intercalation battery'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Wen, Shi-Jie, Xiao-Tian Yin, and L. Nazar. "The New Approach of Intercalation Material for The Application of Rechargeable Lithium Batteries." Active and Passive Electronic Components 17, no. 1 (1994): 1–8. http://dx.doi.org/10.1155/1994/95740.

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A new approach of lithium electrochemical (de)intercalation material has been put forward. This approach requires a two-compound (physically or chemically) composite in which one is a chemically and electrochemically stable and porous (tunnel, cage, layer, etc.) compound such as clay or zeolite, and the other is a chemically and electrochemically stable and metallic compound such as graphite, metal powder or black carbon. Neither does the redox couple in this composite absolutely exist nor does the redox reaction, which is associated with electrochemical charge and discharge processes when this composite is used as an cathodic electrode in a lithium battery cell. In this paper, we show the results of the lithium electrochemical intercalation process in both black carbon-mixed zeolite and clay electrodes. In these solid electrodes, black carbon serves to delocalize (transport) electrons for balancing the charges while zeolite and clay offer the neutrally reversible sites for lithium ions. This approach can hopefully become a guide for the designing of new intercalation material and so will be very important in the application of the lithium rechargeable battery.

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2

Chothe, Ujjwala, Chitra Ugale, Milind Kulkarni, and Bharat Kale. "Solid-State Synthesis of Layered MoS2 Nanosheets with Graphene for Sodium-Ion Batteries." Crystals 11, no. 6 (June 10, 2021): 660. http://dx.doi.org/10.3390/cryst11060660.

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Sodium-ion batteries have potential as energy-storage devices owing to an abundant source with low cost. However, most electrode materials still suffer from poor conductivity, sluggish kinetics, and huge volume variation. It is still challenging to explore apt electrode materials for sodium-ion battery applications to avoid the pulverization of electrodes induced by reversible intercalation of large sodium ions. Herein, we report a single-step facile, scalable, low-cost, and high-yield approach to prepare a hybrid material; i.e., MoS2 with graphene (MoS2-G). Due to the space-confined effect, thin-layered MoS2 nanosheets with a loose stacking feature are anchored with the graphene sheets. The semienclosed hybrid architecture of the electrode enhances the integrity and stability during the intercalation of Na+ ions. Particularly, during galvanostatic study the assembled Na-ion cell delivered a specific capacity of 420 mAhg−1 at 50 mAg−1, and 172 mAhg−1 at current density 200 mAg−1 after 200 cycles. The MoS2-G hybrid excels in performance due to residual oxygen groups in graphene, which improves the electronic conductivity and decreases the Na+ diffusion barrier during electrochemical reaction, in comparison with a pristine one.

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3

Alemu, Tibebu, and Fu-Ming Wang. "In situelectrochemical synchrotron radiation for Li-ion batteries." Journal of Synchrotron Radiation 25, no. 1 (January 1, 2018): 151–65. http://dx.doi.org/10.1107/s1600577517015533.

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Observing the electronic structure, compositional change and morphological evolution of the surface and interface of a battery during operation provides essential information for developing new electrode materials for Li-ion batteries (LIBs); this is because such observations demonstrate the fundamental reactions occurring inside the electrode materials. Moreover, obtaining detailed data on chemical phase changes and distributions by analyzing an operating LIB is the most effective method for exploring the intercalation/de-intercalation process, kinetics and the relationship between phase change or phase distribution and battery performance, as well as for further optimizing the material synthesis routes for advanced battery materials. However, most conventionalin situelectrochemical techniques (other than by using synchrotron radiation) cannot clearly or precisely demonstrate structural change, electron valence change and chemical mapping information.In situelectrochemical-synchrotron radiation techniques such as X-ray absorption spectroscopy, X-ray diffraction spectroscopy and transmission X-ray microscopy can deliver accurate information regarding LIBs. This paper reviews studies regarding various applications ofin situelectrochemical-synchrotron radiation such as crystallographic transformation, oxidation-state changes, characterization of the solid electrolyte interphase and Li-dendrite growth mechanism during the intercalation/de-intercalation process. The paper also presents the findings of previous review articles and the future direction of these methods.

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4

Man, Yu Hong, Yong Ping Zhang, and Pei Tao Guo. "Freestanding Ultralong Aligned Carbon Nanotube Films as Electrode Materials for a Lithium-Ion Battery." Advanced Materials Research 798-799 (September 2013): 143–46. http://dx.doi.org/10.4028/www.scientific.net/amr.798-799.143.

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Freestanding ultralong (900 μm) aligned carbon nanotube (ACNT) films were studied as both an electrode material and a dry adhesive binder with the current collector in lithium ion batteries. Results revealed the formation of a solid electrolyte interface (SEI). The amazingly large initial discharge capacity (1836 mAh g-1) indicated that the ACNT electrode we utilized had great potential for the intercalation of Li ions resulted from extremely large surface area of ACNT films. And electrochemical performances also exhibited excellent cycling stability for this ACNT electrode because of the presence of SEI and the unique structure of the electrode itself.

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5

Johnsen, Rune E., and Poul Norby. "Capillary-based micro-battery cell forin situX-ray powder diffraction studies of working batteries: a study of the initial intercalation and deintercalation of lithium into graphite." Journal of Applied Crystallography 46, no. 6 (October 11, 2013): 1537–43. http://dx.doi.org/10.1107/s0021889813022796.

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A novel capillary-based micro-battery cell forin situX-ray powder diffraction (XRPD) has been developed and used to study the initial intercalation and deintercalation of lithium into graphite in a working battery. The electrochemical cell works in transmission mode and makes it possible to obtain diffraction from a single electrode at a time, which facilitates detailed structural and microstructural studies of the electrode materials. The micro-battery cell is potentially also applicable forin situX-ray absorption spectroscopy and small-angle X-ray scattering experiments. Thein situXRPD study of the initial intercalation and deintercalation process revealed marked changes in the diffraction pattern of the graphitic electrode material. After the formation of the solid electrolyte interphase layer, thedspacing of the diffraction peak corresponding to the 002 diffraction peak of graphite 2H changes nearly linearly in two regions with slightly different slopes, while the apparent half-width of the diffraction peak displays a few minima and maxima during charging/discharging.DIFFaX+refinements based on the initial XRPD pattern and the one after the initial discharging–charging cycle show that the structure of the graphite changes from an intergrown structure of graphite 2H and graphite 3R to a nearly ideal graphite 2H structure.DIFFaX+was also used to refine a model of the stacking disorder in an apparent stage III compound withAαAB- andAαAC-type slabs.

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6

Vanimisetti, Sampath K., and Narayanrao Ramakrishnan. "Effect of the electrode particle shape in Li-ion battery on the mechanical degradation during charge–discharge cycling." Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science 226, no. 9 (December 16, 2011): 2192–213. http://dx.doi.org/10.1177/0954406211432668.

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The investigation addresses the effect of shape and aspect ratio, of typical electrode particles of Li-ion cell material, on the extent of fracture surface created due to intercalation-induced strain energy. Nodular, fibrous, and flaky-shaped particles were studied approximating them to sphere, cylinder, and disc geometries, respectively. Analytical expressions for stress distribution in slab and cylindrical-shaped particles were derived using thermal stress analogy. Such results are already available for spherical particles. Finite element study was carried out using COMSOL® Multiphysics package to complement the analytical work as well as for verification. The spatial and temporal variations of stresses and strain energy in the electrode particles of different shapes were established. Reportedly, solid electrolyte interphase formed on the fracture surface as well as the fracture-induced isolation of electrode material are the main causes of performance degradation and in this context, the intercalation-induced strain energy density becomes important. The sphericity of a particle, that is, the ratio of the surface area of a sphere to that of the particle of equal volume, was found to fittingly describe the effect of shape. The average strain energy density stored in a particle increases with the increasing sphericity. Therefore, fibrous and flaky-shaped particles are expected to have lower tendency for mechanical degradation than the nodular ones. The analysis is restricted only to the mechanics of mechanical degradation and not to the process or the chemistry point of view.

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7

MOLENDA, J. "MATERIAL PROBLEMS AND PROSPECTS OF Li-ION BATTERIES FOR VEHICLES APPLICATIONS." Functional Materials Letters 04, no. 02 (June 2011): 107–12. http://dx.doi.org/10.1142/s1793604711001816.

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This paper reviews material issues of development of Li -ion batteries for vehicles application. The most important of them is safety, which is related to application of nonflammable electrolyte with large electrochemical window and possibility of forming protective SEI (solid/electrolyte interface) to prevent plating of lithium on carbon anode during fast charge of the batteries. The amount of electrical energy, which a battery is able to deliver, depend on the electromotive power of the cell as well as on its capacity — both these factors are related to the chemistry of electrode materials. Nanotechnology applied to electrode materials may be a breakthrough for Li -batteries performance due to extreme reactivity of nanoparticles in relation to lithium. The electrode-electrolyte interface phenomena are decisive for a cell lifetime. Review of physicochemical properties of intercalated transition metal compounds with layered, spinel or olivine-type structure is provided in order to correlate their microscopic electronic properties, i.e. the nature of electronic states, with the efficiency of lithium intercalation process, which is controlled by the chemical diffusion coefficient of lithium. Data concerning cell voltage and character of discharge curves for various materials are correlated with the nature of chemical bonding and electronic structure. Proposed electronic model of the intercalation process allow for prediction and design of operational properties of intercalated electrode materials. Proposed method of measuring the Li x M a X b potential on the basis of the measurement of the electromotive force of the Li / Li +/ Li x M a X b electrochemical cell is a powerful tool of solid state physics allowing for direct observation of the Fermi level changes in such systems as a function of lithium content.

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8

Unocic, Raymond R., Xiao-Guang Sun, Robert L. Sacci, Leslie A. Adamczyk, Daan Hein Alsem, Sheng Dai, Nancy J. Dudney, and Karren L. More. "Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy." Microscopy and Microanalysis 20, no. 4 (July 4, 2014): 1029–37. http://dx.doi.org/10.1017/s1431927614012744.

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AbstractComplex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

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9

Zhang, Changhuan, Liran Zhang, Nianwu Li, and Xiuqin Zhang. "Studies of FeSe2 Cathode Materials for Mg–Li Hybrid Batteries." Energies 13, no. 17 (August 25, 2020): 4375. http://dx.doi.org/10.3390/en13174375.

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Rechargeable magnesium (Mg)-based energy storage has attracted extensive attention in electrochemical storage systems with high theoretical energy densities. The Mg metal is earth-abundant and dendrite-free for the anode. However, there is a strong Coulombic interaction between Mg2+ and host materials that often inhibits solid-state diffusion, resulting in a large polarization and poor electrochemical performances. Herein, we develop a Mg–Li hybrid battery using a Mg-metal anode, an FeSe2 powder with uniform size and a morphology utilizing a simple solution-phase method as the counter electrode and all-phenyl-complex/tetrahydrofuran (APC)-LiCl dual-ion electrolyte. In the Li+-containing electrolyte, at a current density of 15 mA g−1, the Mg–Li hybrid battery (MLIB) delivered a satisfying initial discharge capacity of 525 mAh g−1. Moreover, the capacity was absent in the FeSe2|APC|Mg cell. The working mechanism proposed is the “Li+-only intercalation” at the FeSe2 and the “Mg2+ dissolved or deposited” at the Mg foil in the FeSe2|Mg2+/Li+|Mg cell. Furthermore, ex situ XRD was used to investigate the structural evolution in different charging and discharging states.

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10

Fu, Kun (Kelvin), Yunhui Gong, Jiaqi Dai, Amy Gong, Xiaogang Han, Yonggang Yao, Chengwei Wang, et al. "Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries." Proceedings of the National Academy of Sciences 113, no. 26 (June 15, 2016): 7094–99. http://dx.doi.org/10.1073/pnas.1600422113.

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Beyond state-of-the-art lithium-ion battery (LIB) technology with metallic lithium anodes to replace conventional ion intercalation anode materials is highly desirable because of lithium’s highest specific capacity (3,860 mA/g) and lowest negative electrochemical potential (∼3.040 V vs. the standard hydrogen electrode). In this work, we report for the first time, to our knowledge, a 3D lithium-ion–conducting ceramic network based on garnet-type Li6.4La3Zr2Al0.2O12 (LLZO) lithium-ion conductor to provide continuous Li+ transfer channels in a polyethylene oxide (PEO)-based composite. This composite structure further provides structural reinforcement to enhance the mechanical properties of the polymer matrix. The flexible solid-state electrolyte composite membrane exhibited an ionic conductivity of 2.5 × 10−4 S/cm at room temperature. The membrane can effectively block dendrites in a symmetric Li | electrolyte | Li cell during repeated lithium stripping/plating at room temperature, with a current density of 0.2 mA/cm2 for around 500 h and a current density of 0.5 mA/cm2 for over 300 h. These results provide an all solid ion-conducting membrane that can be applied to flexible LIBs and other electrochemical energy storage systems, such as lithium–sulfur batteries.

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11

Kondo, Yasuyuki, Tomokazu Fukutsuka, Yuko Yokoyama, Yuto Miyahara, Kohei Miyazaki, and Takeshi Abe. "Kinetic properties of sodium-ion transfer at the interface between graphitic materials and organic electrolyte solutions." Journal of Applied Electrochemistry 51, no. 4 (February 7, 2021): 629–38. http://dx.doi.org/10.1007/s10800-020-01523-z.

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AbstractGraphitic materials cannot be applied for the negative electrode of sodium-ion battery because the reversible capacities of graphite are anomalously small. To promote electrochemical sodium-ion intercalation into graphitic materials, the interfacial sodium-ion transfer reaction at the interface between graphitized carbon nanosphere (GCNS) electrode and organic electrolyte solutions was investigated. The interfacial lithium-ion transfer reaction was also evaluated for the comparison to the sodium-ion transfer. From the cyclic voltammograms, both lithium-ion and sodium-ion can reversibly intercalate into/from GCNS in all of the electrolytes used here. In the Nyquist plots, the semi-circles at the high frequency region derived from the Solid Electrolyte Interphase (SEI) resistance and the semi-circles at the middle frequency region owing to the charge-transfer resistance appeared. The activation energies of both lithium-ion and sodium-ion transfer resistances were measured. The values of activation energies of the interfacial lithium-ion transfer suggested that the interfacial lithium-ion transfer was influenced by the interaction between lithium-ion and solvents, anions or SEI. The activation energies of the interfacial sodium-ion transfer were larger than the expected values of interfacial sodium-ion transfer based on the week Lewis acidity of sodium-ion. In addition, the activation energies of interfacial sodium-ion transfer in dilute FEC-based electrolytes were smaller than those in concentrated electrolytes. The activation energies of the interfacial lithium/sodium-ion transfer of CNS-1100 in FEC-based electrolyte solutions were almost the same as those of CNS-2900, indicating that the mechanism of interfacial charge-transfer reaction seemed to be the same for highly graphitized materials and low-graphitized materials each other. Graphic abstract

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12

Lai, Wei, and Francesco Ciucci. "Small-Signal Apparent Diffusion Impedance of Intercalation Battery Electrodes." Journal of The Electrochemical Society 158, no. 2 (2011): A115. http://dx.doi.org/10.1149/1.3515896.

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13

Flandrois, S., and J. Herran. "Battery electrodes based on metal chloride-graphite intercalation compounds." Synthetic Metals 14, no. 1-2 (March 1986): 103–11. http://dx.doi.org/10.1016/0379-6779(86)90132-3.

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14

Whittingham, M. "The intercalation and hydrothermal chemistry of solid electrodes." Solid State Ionics 94, no. 1-4 (February 1, 1997): 227–38. http://dx.doi.org/10.1016/s0167-2738(96)00509-7.

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15

Hall, Florian, Sabine Wußler, Hilmi Buqa, and Wolfgang G. Bessler. "Asymmetry of Discharge/Charge Curves of Lithium-Ion Battery Intercalation Electrodes." Journal of Physical Chemistry C 120, no. 41 (October 6, 2016): 23407–14. http://dx.doi.org/10.1021/acs.jpcc.6b07949.

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16

Garrick, Taylor R., Kenneth Higa, Shao-Ling Wu, Yiling Dai, Xinyu Huang, Venkat Srinivasan, and John W. Weidner. "Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes." Journal of The Electrochemical Society 164, no. 11 (2017): E3592—E3597. http://dx.doi.org/10.1149/2.0621711jes.

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17

Garrick, T. R., Y. Dai, K. Higa, V. Srinivasan, and J. W. Weidner. "Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes." ECS Transactions 72, no. 11 (September 21, 2016): 11–31. http://dx.doi.org/10.1149/07211.0011ecst.

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18

Lai, Wei, and Francesco Ciucci. "Thermodynamics and kinetics of phase transformation in intercalation battery electrodes – phenomenological modeling." Electrochimica Acta 56, no. 1 (December 2010): 531–42. http://dx.doi.org/10.1016/j.electacta.2010.09.015.

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19

Besenhard, J. O. "Ambient Temperature Solid State Reactions in Battery Electrodes." Materials Science Forum 152-153 (March 1994): 13–34. http://dx.doi.org/10.4028/www.scientific.net/msf.152-153.13.

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20

Santhanam, R., and M. Noel. "Electrochemical intercalation of ionic species of tetrabutylammonium perchlorate on graphite electrodes. A potential dual-intercalation battery system." Journal of Power Sources 56, no. 1 (July 1995): 101–5. http://dx.doi.org/10.1016/0378-7753(95)80016-a.

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21

Byles, Bryan W., Mallory Clites, David A. Cullen, Karren L. More, and Ekaterina Pomerantseva. "Improved electrochemical cycling stability of intercalation battery electrodes via control of material morphology." Ionics 25, no. 2 (September 12, 2018): 493–502. http://dx.doi.org/10.1007/s11581-018-2715-z.

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22

Jang, Yunjai, Chia-Hung Hou, Sanghyuk Park, Kyungjung Kwon, and Eunhyea Chung. "Direct electrochemical lithium recovery from acidic lithium-ion battery leachate using intercalation electrodes." Resources, Conservation and Recycling 175 (December 2021): 105837. http://dx.doi.org/10.1016/j.resconrec.2021.105837.

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23

Ishige, Yu, Stefan Klink, and Wolfgang Schuhmann. "Intercalation Compounds as Inner Reference Electrodes for Reproducible and Robust Solid-Contact Ion-Selective Electrodes." Angewandte Chemie International Edition 55, no. 15 (March 11, 2016): 4831–35. http://dx.doi.org/10.1002/anie.201600111.

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24

Balaish, Moran, and Yair Ein-Eli. "Enhancing oxygen adsorption capabilities in Li–O2battery cathodes through solid perfluorocarbons." Journal of Materials Chemistry A 5, no. 27 (2017): 14152–64. http://dx.doi.org/10.1039/c7ta03376a.

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Perfluorocarbons, solid at room temperature, were added at different weight ratios to carbon black-based air electrodes for Li–O₂battery. PFCs-modified air-electrodes showed improved battery performance and were characterized by HRSEM images, nitrogen adsorption (BET), liquid adsorption, a comprehensive wettability study and electrochemical investigation.

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25

McNulty, David, Hugh Geaney, Eileen Armstrong, and Colm O'Dwyer. "High performance inverse opal Li-ion battery with paired intercalation and conversion mode electrodes." Journal of Materials Chemistry A 4, no. 12 (2016): 4448–56. http://dx.doi.org/10.1039/c6ta00338a.

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26

Li, Yiyang, Farid El Gabaly, Todd R. Ferguson, Raymond B. Smith, Norman C. Bartelt, Joshua D. Sugar, Kyle R. Fenton, et al. "Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes." Nature Materials 13, no. 12 (September 14, 2014): 1149–56. http://dx.doi.org/10.1038/nmat4084.

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27

Proffit, Danielle L., Albert L. Lipson, Baofei Pan, Sang-Don Han, Timothy T. Fister, Zhenxing Feng, Brian J. Ingram, Anthony K. Burrell, and John T. Vaughey. "Reducing Side Reactions Using PF6-based Electrolytes in Multivalent Hybrid Cells." MRS Proceedings 1773 (2015): 27–32. http://dx.doi.org/10.1557/opl.2015.590.

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ABSTRACTThe need for higher energy density batteries has spawned recent renewed interest in alternatives to lithium ion batteries, including multivalent chemistries that theoretically can provide twice the volumetric capacity if two electrons can be transferred per intercalating ion. Initial investigations of these chemistries have been limited to date by the lack of understanding of the compatibility between intercalation electrode materials, electrolytes, and current collectors. This work describes the utilization of hybrid cells to evaluate multivalent cathodes, consisting of high surface area carbon anodes and multivalent nonaqueous electrolytes that are compatible with oxide intercalation electrodes. In particular, electrolyte and current collector compatibility was investigated, and it was found that the carbon and active material play an important role in determining the compatibility of PF6-based multivalent electrolytes with carbon-based current collectors. Through the exploration of electrolytes that are compatible with the cathode, new cell chemistries and configurations can be developed, including a magnesium-ion battery with two intercalation host electrodes, which may expand the known Mg-based systems beyond the present state of the art sulfide-based cathodes with organohalide-magnesium based electrolytes.

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28

Sangrós Giménez, Clara, Laura Helmers, Carsten Schilde, Alexander Diener, and Arno Kwade. "Modeling the Electrical Conductive Paths within All‐Solid‐State Battery Electrodes." Chemical Engineering & Technology 43, no. 5 (March 25, 2020): 819–29. http://dx.doi.org/10.1002/ceat.201900501.

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29

Bernardi, Dawn M., Rajeswari Chandrasekaran, and Joo Young Go. "Solid-State Transport of Lithium in Lithium-Ion-Battery Positive Electrodes." Journal of The Electrochemical Society 160, no. 9 (2013): A1430—A1441. http://dx.doi.org/10.1149/2.042309jes.

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30

Barannikova, Evgenia, and Mark Allen. "Solid-Binding Peptides as a Biotemplate for Li-Ion Battery Electrodes." Biophysical Journal 108, no. 2 (January 2015): 634a. http://dx.doi.org/10.1016/j.bpj.2014.11.3447.

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31

Song, Weixin, Elena Stein Scholtis, Peter C. Sherrell, Deana K. H. Tsang, Jonathan Ngiam, Johannes Lischner, Sarah Fearn, et al. "Electronic structure influences on the formation of the solid electrolyte interphase." Energy & Environmental Science 13, no. 12 (2020): 4977–89. http://dx.doi.org/10.1039/d0ee01825b.

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32

Christensen, Christian K., Espen D. Bøjesen, Daniel R. Sørensen, Jonas H. Kristensen, Jette K. Mathiesen, Bo B. Iversen, and Dorthe B. Ravnsbæk. "Structural Evolution during Lithium- and Magnesium-Ion Intercalation in Vanadium Oxide Nanotube Electrodes for Battery Applications." ACS Applied Nano Materials 1, no. 9 (August 31, 2018): 5071–82. http://dx.doi.org/10.1021/acsanm.8b01183.

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33

Huang, R. W. J. M., Foen Chung, and E. M. Kelder. "Impedance Simulation of a Li-Ion Battery with Porous Electrodes and Spherical Li[sup +] Intercalation Particles." Journal of The Electrochemical Society 153, no. 8 (2006): A1459. http://dx.doi.org/10.1149/1.2203947.

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34

Clites, Mallory, and Ekaterina Pomerantseva. "Bilayered vanadium oxides by chemical pre-intercalation of alkali and alkali-earth ions as battery electrodes." Energy Storage Materials 11 (March 2018): 30–37. http://dx.doi.org/10.1016/j.ensm.2017.09.005.

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35

Wang, Kuaibing, Saier Wang, Jiadi Liu, Yuxuan Guo, Feifei Mao, Hua Wu, and Qichun Zhang. "Fe-Based Coordination Polymers as Battery-Type Electrodes in Semi-Solid-State Battery–Supercapacitor Hybrid Devices." ACS Applied Materials & Interfaces 13, no. 13 (March 24, 2021): 15315–23. http://dx.doi.org/10.1021/acsami.1c01339.

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36

Yoshino, K., K. Suzuki, Y. Yamada, T. Satoh, M. Finsterbusch, K. Fujita, T. Kamiya, et al. "Lithium distribution analysis in all-solid-state lithium battery using microbeam particle-induced X-ray emission and particle-induced gamma-ray emission techniques." International Journal of PIXE 27, no. 01n02 (January 2017): 11–20. http://dx.doi.org/10.1142/s012908351850002x.

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For confirming the feasibility of micrometer scale analysis of lithium distribution in the all-solid-state lithium battery using a sulfide-based solid electrolyte, the cross-section of pellet type battery was analyzed by microbeam particle-induced X-ray emission (PIXE) and particle-induced gamma-ray emission (PIGE) measurements. A three-layered pellet-type battery (cathode: LiNbO3-coated [Formula: see text]/solid electrolyte: [Formula: see text]/anode: [Formula: see text]) was prepared for the measurements. Via elemental mapping of the cross-section of the prepared battery, the difference in the yields of gamma rays from the [Formula: see text] inelastic scattering (i.e., the lithium concentrations) between the composite electrodes and the solid electrolyte layer was clarified. The difference in the number of lithium ions at the composite anode/solid electrolyte interface of ([Formula: see text] mol) in the battery can be clearly detected by the microbeam PIGE technique. Therefore, lithium distribution analysis with a micrometer-scale spatial resolution is demonstrated. Further analysis of the cathode/anode composite electrodes with the different states of charge could provide important information to design a composite for high-performance all-solid-state lithium batteries.

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37

Chen, Chien-Fan, and Partha P. Mukherjee. "Probing the morphological influence on solid electrolyte interphase and impedance response in intercalation electrodes." Physical Chemistry Chemical Physics 17, no. 15 (2015): 9812–27. http://dx.doi.org/10.1039/c4cp05758a.

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38

Chen, Guangwei, Zhitao Liu, and Hongye Su. "An Optimal Fast-Charging Strategy for Lithium-Ion Batteries via an Electrochemical–Thermal Model with Intercalation-Induced Stresses and Film Growth." Energies 13, no. 9 (May 11, 2020): 2388. http://dx.doi.org/10.3390/en13092388.

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Optimal fast charging is an important factor in battery management systems (BMS). Traditional charging strategies for lithium-ion batteries, such as the constant current–constant voltage (CC–CV) pattern, do not take capacity aging mechanisms into account, which are not only disadvantageous in the life-time usage of the batteries, but also unsafe. In this paper, we employ the dynamic optimization (DP) method to achieve the optimal charging current curve for a lithium-ion battery by introducing limits on the intercalation-induced stresses and the solid–liquid interface film growth based on an electrochemical–thermal model. Furthermore, the backstepping technique is utilized to control the temperature to avoid overheating. This paper concentrates on solving the issue of minimizing charging time in a given target State of Charge (SoC), while limiting the capacity loss caused by intercalation-induced stresses and film formation. The results indicate that the proposed optimal charging method in this paper offers a good compromise between the charging time and battery aging.

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Shen, Hao, Eongyu Yi, Marco Amores, Lei Cheng, Nobumichi Tamura, Dilworth Y. Parkinson, Guoying Chen, Kai Chen, and Marca Doeff. "Oriented porous LLZO 3D structures obtained by freeze casting for battery applications." Journal of Materials Chemistry A 7, no. 36 (2019): 20861–70. http://dx.doi.org/10.1039/c9ta06520b.

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A novel freeze casting technique was employed to obtain 3D porous LLZO solid-electrolyte scaffolds that were infiltrated with NMC-622 cathode material to form thick composite electrodes for all-solid-state batteries.

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Suzuki, Shinya, Naoko Sakai, and Masaru Miyayama. "Fabrication of Titanate Thin Film by Electrophoretic Deposition of Tetratitanate Nanosheets for Electrodes of Li-Ion Battery." Key Engineering Materials 388 (September 2008): 37–40. http://dx.doi.org/10.4028/www.scientific.net/kem.388.37.

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Thin films of titanate were prepared by electrophoretic deposition (EPD) of a colloidal suspension of nanosheets, and their lithium intercalation properties were examined. Thickness of the obtained film increased approximately in proportion to the increase in deposition time and concentration of the colloidal suspension used for EPD bath. EPD method was revealed to be a convenient method for layer lamination of nanosheets. The reversible capacity for the obtained film was approximately 170 mA h g-1, and it was in common with anatase-type TiO2 or conventional titanate. Lithium diffusion coefficient along the thickness direction was estimated to be 6 × 10-14 cm2 sec-1.

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Zhou, Xin, Hao Jiang, Hao Zheng, Yi Sun, Xin Liang, and Hongfa Xiang. "Nonflammable hybrid solid electrolyte membrane for a solid-state lithium battery compatible with conventional porous electrodes." Journal of Membrane Science 603 (May 2020): 117820. http://dx.doi.org/10.1016/j.memsci.2020.117820.

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Eliseeva, Svetlana N., Mikhail A. Kamenskii, Elena G. Tolstopyatova, and Veniamin V. Kondratiev. "Effect of Combined Conductive Polymer Binder on the Electrochemical Performance of Electrode Materials for Lithium-Ion Batteries." Energies 13, no. 9 (May 1, 2020): 2163. http://dx.doi.org/10.3390/en13092163.

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The electrodes of lithium-ion batteries (LIBs) are multicomponent systems and their electrochemical properties are influenced by each component, therefore the composition of electrodes should be properly balanced. At the beginning of lithium-ion battery research, most attention was paid to the nature, size, and morphology peculiarities of inorganic active components as the main components which determine the functional properties of electrode materials. Over the past decade, considerable attention has been paid to development of new binders, as the binders have shown great effect on the electrochemical performance of electrodes in LIBs. The study of new conductive binders, in particular water-based binders with enhanced electronic and ionic conductivity, has become a trend in the development of new electrode materials, especially the conversion/alloying-type anodes. This mini-review provides a summary on the progress of current research of the effects of binders on the electrochemical properties of intercalation electrodes, with particular attention to the mechanisms of binder effects. The comparative analysis of effects of three different binders (PEDOT:PSS/CMC, CMC, and PVDF) for a number of oxide-based and phosphate-based positive and negative electrodes for lithium-ion batteries was performed based on literature and our own published research data. It reveals that the combined PEDOT:PSS/CMC binder can be considered as a versatile component of lithium-ion battery electrode materials (for both positive and negative electrodes), effective in the wide range of electrode potentials.

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Chung, S. K., A. A. Andriiko, A. P. Mon'ko, and S. H. Lee. "On charge conditions for Li-ion and other secondary lithium batteries with solid intercalation electrodes." Journal of Power Sources 79, no. 2 (June 1999): 205–11. http://dx.doi.org/10.1016/s0378-7753(99)00058-0.

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Kim, Sung-Woo, Seung-Bok Lee, and Su-Il Pyun. "ChemInform Abstract: The Fundamentals and Advances of Solid-State Electrochemistry: Intercalation (Insertion) and Deintercalation (Extraction) in Solid-State Electrodes." ChemInform 42, no. 1 (December 9, 2010): no. http://dx.doi.org/10.1002/chin.201101213.

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Zhu, Yun Guang, Thaneer Malai Narayanan, Michal Tulodziecki, Hernan Sanchez-Casalongue, Quinn C. Horn, Laura Meda, Yang Yu, et al. "High-energy and high-power Zn–Ni flow batteries with semi-solid electrodes." Sustainable Energy & Fuels 4, no. 8 (2020): 4076–85. http://dx.doi.org/10.1039/d0se00675k.

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Careful rheological design and electrochemical optimization of conductive ZnO and Ni(OH)₂ active semi-solid flowable electrodes is essential to achieve a high-energy and high-power Zn–Ni flow battery.

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Ashby, David S., Christopher S. Choi, Martin A. Edwards, A. Alec Talin, Henry S. White, and Bruce S. Dunn. "High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes." ACS Applied Energy Materials 3, no. 9 (July 21, 2020): 8402–9. http://dx.doi.org/10.1021/acsaem.0c01029.

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Anjass, Montaha H., Max Deisböck, Simon Greiner, Maximilian Fichtner, and Carsten Streb. "Differentiating Molecular and Solid-State Vanadium Oxides as Active Materials in Battery Electrodes." ChemElectroChem 6, no. 2 (November 20, 2018): 398–403. http://dx.doi.org/10.1002/celc.201801406.

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Ashby, David, Christopher S. Choi, Martin A. Edwards, A. Alec Talin, Henry S. White, and Bruce S. Dunn. "High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes." ECS Meeting Abstracts MA2020-02, no. 5 (November 23, 2020): 1026. http://dx.doi.org/10.1149/ma2020-0251026mtgabs.

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Castaing, Rémi, Philippe Moreau, Yvan Reynier, Donald Schleich, Séverine Jouanneau Si Larbi, Dominique Guyomard, and Nicolas Dupré. "NMR quantitative analysis of solid electrolyte interphase on aged Li-ion battery electrodes." Electrochimica Acta 155 (February 2015): 391–95. http://dx.doi.org/10.1016/j.electacta.2014.12.049.

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Davis, Andrew L., Vishwas Goel, Daniel W. Liao, Mark N. Main, Eric Kazyak, John Lee, Katsuyo Thornton, and Neil P. Dasgupta. "Rate Limitations in Composite Solid-State Battery Electrodes: Revealing Heterogeneity with Operando Microscopy." ACS Energy Letters 6, no. 8 (August 4, 2021): 2993–3003. http://dx.doi.org/10.1021/acsenergylett.1c01063.

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