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1
Pagel, Peter. "SOA? SOA!" Wirtschaftsinformatik und Management 1, no. 2 (May 2009): 3. http://dx.doi.org/10.1007/bf03248180.
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Baghdadi, Youcef. "SOA Maturity Models: Guidance to Realize SOA." International Journal of Computer and Communication Engineering 3, no. 5 (2014): 372–78. http://dx.doi.org/10.7763/ijcce.2014.v3.352.
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Liu, Shijie, Long Jia, Yongfu Xu, Narcisse T. Tsona, Shuangshuang Ge, and Lin Du. "Photooxidation of cyclohexene in the presence of SO<sub>2</sub>: SOA yield and chemical composition." Atmospheric Chemistry and Physics 17, no. 21 (November 9, 2017): 13329–43. http://dx.doi.org/10.5194/acp-17-13329-2017.
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Abstract. Secondary organic aerosol (SOA) formation from a cyclohexene ∕ NOx system with various SO2 concentrations under UV light was investigated to study the effects of cyclic alkenes on the atmospheric environment in polluted urban areas. A clear decrease at first and then an increase in the SOA yield was found with increasing SO2 concentrations. The lowest SOA yield was obtained when the initial SO2 concentration was in the range of 30–40 ppb, while higher SOA yield compared to that without SO2 could not be obtained until the initial SO2 concentration was higher than 85 ppb. The decreasing SOA yield might be due to the fact that the promoting effect of acid-catalysed reactions on SOA formation was less important than the inhibiting effect of decreasing OH concentration at low initial SO2 concentrations, caused by the competition reactions of OH with SO2 and cyclohexene. The competitive reaction was an important factor for SOA yield and it should not be neglected in photooxidation reactions. The composition of organic compounds in SOA was measured using several complementary techniques including Fourier transform infrared (FTIR) spectroscopy, ion chromatography (IC), and Exactive Plus Orbitrap mass spectrometer equipped with electrospray interface (ESI). We present new evidence that organosulfates were produced from the photooxidation of cyclohexene in the presence of SO2.
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Liu, Changgeng, Tianzeng Chen, Yongchun Liu, Jun Liu, Hong He, and Peng Zhang. "Enhancement of secondary organic aerosol formation and its oxidation state by SO<sub>2</sub> during photooxidation of 2-methoxyphenol." Atmospheric Chemistry and Physics 19, no. 4 (March 1, 2019): 2687–700. http://dx.doi.org/10.5194/acp-19-2687-2019.
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Abstract. 2-Methoxyphenol (guaiacol) is derived from the lignin pyrolysis and taken as a potential tracer for wood smoke emissions. In this work, the effect of SO2 at atmospheric levels (0–56 ppbv) on secondary organic aerosol (SOA) formation and its oxidation state during guaiacol photooxidation was investigated in the presence of various inorganic seed particles (i.e., NaCl and (NH4)2SO4). Without SO2 and seed particles, SOA yields ranged from (9.46±1.71) % to (26.37±2.83) % and could be well expressed by a one-product model. According to the ratio of the average gas-particle partitioning timescale (τ‾g-p) over the course of the experiment to the vapor wall deposition timescale (τg−w), the determined SOA yields were underestimated by a factor of ∼2. The presence of SO2 resulted in enhancing SOA yield by 14.04 %–23.65 %. With (NH4)2SO4 and NaCl seed particles, SOA yield was enhanced by 23.07 % and 29.57 %, respectively, which further increased significantly to 29.78 %–53.43 % in the presence of SO2, suggesting that SO2 and seed particles have a synergetic contribution to SOA formation. The decreasing trend of the τ‾g-p/τg-w ratio in the presence of seed particles and SO2 suggested that more SOA-forming vapors partitioned into the particle phase, consequently increasing SOA yields. It should be noted that SO2 was found to be in favor of increasing the carbon oxidation state (OSC) of SOA, indicating that the functionalization or the partitioning of highly oxidized products into particles should be more dominant than the oligomerization. In addition, the average N∕C ratio of SOA was 0.037, which revealed that NOx participated in the photooxidation process, consequently leading to the formation of organic N-containing compounds. The experimental results demonstrate the importance of SO2 on the formation processes of SOA and organic S-containing compounds and are also helpful to further understand SOA formation from the atmospheric photooxidation of guaiacol and its subsequent impacts on air quality and climate.
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Zhang, Wenyu, Weigang Wang, Junling Li, Chao Peng, Kun Li, Li Zhou, Bo Shi, Yan Chen, Mingyuan Liu, and Maofa Ge. "Effects of SO<sub>2</sub> on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions." Atmospheric Chemistry and Physics 20, no. 7 (April 17, 2020): 4477–92. http://dx.doi.org/10.5194/acp-20-4477-2020.
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Abstract. Secondary organic aerosol (SOA) has great impacts on air quality, climate change and human health. The composition and physicochemical properties of SOA differ greatly because they form under different atmospheric conditions and from various precursors as well as differing oxidation. In this work, photooxidation experiments of toluene were performed under four conditions (dry, dry with SO2, wet and wet with SO2) to investigate the effect of SO2 under different relative humidities on the composition and optical properties of SOA at wavelengths of 375 and 532 nm. According to our results, the increase in humidity enhances not only light absorption but also the scattering property of the SOA. Oligomers formed through multiphase reactions might be the reason for this phenomenon. Adding SO2 slightly lowers the real part of the complex refractive index, RI(n), of toluene-derived SOA (RI(n)dry,SO2<RI(n)dry, RI(n)wet,SO2<RI(n)wet), which might be a result of the partitioning of low-oxidation-state products. The imaginary part of the complex refractive index, RI(k), is enhanced under dry conditions with SO2 compared to that of only dry conditions, which might be due to acid-catalyzed aldol condensation reactions. Wet conditions with SO2 shows the combined effect of SO2 and humidity. The extinction properties of toluene-derived SOA under wet conditions with SO2 increased by approximately 30 % compared to that of toluene-derived SOA formed under dry conditions. Our results suggest that various atmospheric conditions will affect the composition and optical proprieties of SOA, which has significant implications for evaluating the impacts of SOA on the rapid formation of regional haze, global radiative balance and climate change.
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Matitaputty, Jenny Koce. "Totem: Soa and Its Role in the Indigenous Peoples Lives of Negeri Hutumuri - Maluku." Society 9, no. 2 (December 31, 2021): 429–46. http://dx.doi.org/10.33019/society.v9i2.358.
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Soa is a combination of several genealogically territorial eyes of the house. Each Soa usually has a symbol in the form of Totem, which is the identity of each Soa. Soa is still maintained until now. Even every symbol or Totem is still present in implementing traditional ceremonies. This study aimed to discover Soa and its role based on Totem in Negeri Hutumuri, South Leitimur Sub-district, Ambon City. This research is qualitative. The data source was obtained by purposive sampling. The Soa heads and traditional elders were used as informants. Data collection techniques through interviews, participatory observation, and documentation. The results of the study show: 1) Soa in the life of the people of Negeri Hutumuri consists of 5 Soa, namely Soa Pattihutung, Soa Mokihutung, Soa Tutupasar, Soa Lapaut, and Soa Puasel. 2) The role of each Soa is based on the Totem: 1. Soa Pattihutung, with the symbol of the Soa pigeon is role as an honest leader in leadership (King); 2. Soa Mokihutung symbolizes the Soa Mangole bird in charge of maintaining maritime security (Kewang sea/marine police). 3. Soa Tutupasar with the symbol of Soa, namely Soa-Soa, in charge of maintaining forest security (Kewang land/forest police). 4. Soa Lapaut, with the symbol of the Soa snake, is in charge of maintaining security and order (police/soldiers). 5. Soa Puasel, with the symbol of the Soa frog maintaining the cleanliness of water and art in the Negeri Hutumuri.
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Zhao, Defeng, Sebastian H. Schmitt, Mingjin Wang, Ismail-Hakki Acir, Ralf Tillmann, Zhaofeng Tan, Anna Novelli, et al. "Effects of NO<sub><i>x</i></sub> and SO<sub>2</sub> on the secondary organic aerosol formation from photooxidation of <i>α</i>-pinene and limonene." Atmospheric Chemistry and Physics 18, no. 3 (February 5, 2018): 1611–28. http://dx.doi.org/10.5194/acp-18-1611-2018.
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Abstract. Anthropogenic emissions such as NOx and SO2 influence the biogenic secondary organic aerosol (SOA) formation, but detailed mechanisms and effects are still elusive. We studied the effects of NOx and SO2 on the SOA formation from the photooxidation of α-pinene and limonene at ambient relevant NOx and SO2 concentrations (NOx: < 1to 20 ppb, SO2: < 0.05 to 15 ppb). In these experiments, monoterpene oxidation was dominated by OH oxidation. We found that SO2 induced nucleation and enhanced SOA mass formation. NOx strongly suppressed not only new particle formation but also SOA mass yield. However, in the presence of SO2 which induced a high number concentration of particles after oxidation to H2SO4, the suppression of the mass yield of SOA by NOx was completely or partly compensated for. This indicates that the suppression of SOA yield by NOx was largely due to the suppressed new particle formation, leading to a lack of particle surface for the organics to condense on and thus a significant influence of vapor wall loss on SOA mass yield. By compensating for the suppressing effect on nucleation of NOx, SO2 also compensated for the suppressing effect on SOA yield. Aerosol mass spectrometer data show that increasing NOx enhanced nitrate formation. The majority of the nitrate was organic nitrate (57–77 %), even in low-NOx conditions (< ∼ 1 ppb). Organic nitrate contributed 7–26 % of total organics assuming a molecular weight of 200 g mol−1. SOA from α-pinene photooxidation at high NOx had a generally lower hydrogen to carbon ratio (H ∕ C), compared to low NOx. The NOx dependence of the chemical composition can be attributed to the NOx dependence of the branching ratio of the RO2 loss reactions, leading to a lower fraction of organic hydroperoxides and higher fractions of organic nitrates at high NOx. While NOx suppressed new particle formation and SOA mass formation, SO2 can compensate for such effects, and the combining effect of SO2 and NOx may have an important influence on SOA formation affected by interactions of biogenic volatile organic compounds (VOCs) with anthropogenic emissions.
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Marais, E. A., D. J. Jacob, J. L. Jimenez, P. Campuzano-Jost, D. A. Day, W. Hu, J. Krechmer, et al. "Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the Southeast United States and co-benefit of SO<sub>2</sub> emission controls." Atmospheric Chemistry and Physics Discussions 15, no. 21 (November 13, 2015): 32005–47. http://dx.doi.org/10.5194/acpd-15-32005-2015.
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Abstract. Isoprene emitted by vegetation is an important precursor of secondary organic aerosol (SOA), but the mechanism and yields are uncertain. Aerosol is prevailingly aqueous under the humid conditions typical of isoprene-emitting regions. Here we develop an aqueous-phase mechanism for isoprene SOA formation coupled to a detailed gas-phase isoprene oxidation scheme. The mechanism is based on aerosol reactive uptake probabilities (γ) for water-soluble isoprene oxidation products, including sensitivity to aerosol acidity and nucleophile concentrations. We apply this mechanism to simulation of aircraft (SEAC4RS) and ground-based (SOAS) observations over the Southeast US in summer 2013 using the GEOS-Chem chemical transport model. Emissions of nitrogen oxides (NOx ≡ NO + NO2) over the Southeast US are such that the peroxy radicals produced from isoprene oxidation (ISOPO2) react significantly with both NO (high-NOx pathway) and HO2 (low-NOx pathway), leading to different suites of isoprene SOA precursors. We find a mean SOA mass yield of 3.3 % from isoprene oxidation, consistent with the observed relationship of OA and formaldehyde (a product of isoprene oxidation). The yield is mainly contributed by two immediate gas-phase precursors, isoprene epoxydiols (IEPOX, 58 % of isoprene SOA) from the low-NOx pathway and glyoxal (28 %) from both low- and high-NOx pathways. This speciation is consistent with observations of IEPOX SOA from SOAS and SEAC4RS. Observations show a strong relationship between IEPOX SOA and sulfate aerosol that we explain as due to the indirect effect of sulfate on aerosol acidity and volume, rather than a direct mechanistic role for sulfate. Isoprene SOA concentrations increase as NOx emissions decrease (favoring the low-NOx pathway for isoprene oxidation), but decrease as SO2 emissions decrease (due to the effect of sulfate on aerosol acidity and volume). The US EPA projects 2013–2025 decreases in anthropogenic emissions of 34 % for NOx (leading to 7 % increase in isoprene SOA) and 48 % for SO2 (35 % decrease in isoprene SOA). The combined projected decreases in NOx and SO2 emissions reduce isoprene SOA yields from 3.3 to 2.3 %. Reducing SO2 emissions decreases sulfate and isoprene SOA by a similar magnitude, representing a factor of 2 co-benefit for PM2.5 from SO2 emission controls.
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Marais, E. A., D. J. Jacob, J. L. Jimenez, P. Campuzano-Jost, D. A. Day, W. Hu, J. Krechmer, et al. "Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO<sub>2</sub> emission controls." Atmospheric Chemistry and Physics 16, no. 3 (February 11, 2016): 1603–18. http://dx.doi.org/10.5194/acp-16-1603-2016.
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Abstract. Isoprene emitted by vegetation is an important precursor of secondary organic aerosol (SOA), but the mechanism and yields are uncertain. Aerosol is prevailingly aqueous under the humid conditions typical of isoprene-emitting regions. Here we develop an aqueous-phase mechanism for isoprene SOA formation coupled to a detailed gas-phase isoprene oxidation scheme. The mechanism is based on aerosol reactive uptake coefficients (γ) for water-soluble isoprene oxidation products, including sensitivity to aerosol acidity and nucleophile concentrations. We apply this mechanism to simulation of aircraft (SEAC4RS) and ground-based (SOAS) observations over the southeast US in summer 2013 using the GEOS-Chem chemical transport model. Emissions of nitrogen oxides (NOx ≡ NO + NO2) over the southeast US are such that the peroxy radicals produced from isoprene oxidation (ISOPO2) react significantly with both NO (high-NOx pathway) and HO2 (low-NOx pathway), leading to different suites of isoprene SOA precursors. We find a mean SOA mass yield of 3.3 % from isoprene oxidation, consistent with the observed relationship of total fine organic aerosol (OA) and formaldehyde (a product of isoprene oxidation). Isoprene SOA production is mainly contributed by two immediate gas-phase precursors, isoprene epoxydiols (IEPOX, 58 % of isoprene SOA) from the low-NOx pathway and glyoxal (28 %) from both low- and high-NOx pathways. This speciation is consistent with observations of IEPOX SOA from SOAS and SEAC4RS. Observations show a strong relationship between IEPOX SOA and sulfate aerosol that we explain as due to the effect of sulfate on aerosol acidity and volume. Isoprene SOA concentrations increase as NOx emissions decrease (favoring the low-NOx pathway for isoprene oxidation), but decrease more strongly as SO2 emissions decrease (due to the effect of sulfate on aerosol acidity and volume). The US Environmental Protection Agency (EPA) projects 2013–2025 decreases in anthropogenic emissions of 34 % for NOx (leading to a 7 % increase in isoprene SOA) and 48 % for SO2 (35 % decrease in isoprene SOA). Reducing SO2 emissions decreases sulfate and isoprene SOA by a similar magnitude, representing a factor of 2 co-benefit for PM2.5 from SO2 emission controls.
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Lin, Y. H., E. M. Knipping, E. S. Edgerton, S. L. Shaw, and J. D. Surratt. "Investigating the influences of SO<sub>2</sub> and NH<sub>3</sub> levels on isoprene-derived secondary organic aerosol formation using conditional sampling approaches." Atmospheric Chemistry and Physics Discussions 13, no. 2 (February 1, 2013): 3095–134. http://dx.doi.org/10.5194/acpd-13-3095-2013.
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Abstract. Filter-based PM2.5 samples were chemically analyzed to investigate secondary organic aerosol (SOA) formation from isoprene in a rural atmosphere of the southeastern US influenced by both anthropogenic sulfur dioxide (SO2) and ammonia (NH3) emissions. Daytime PM2.5 samples were collected during summer 2010 using conditional sampling approaches based on pre-defined high and low SO2 or NH3 thresholds. Known molecular-level tracers for isoprene SOA formation, including 2-methylglyceric acid, 3-methyltetrahydrofuran-3,4-diols, 2-methyltetrols, C5-alkene triols, dimers, and organosulfate derivatives, were identified and quantified by gas chromatography coupled to electron ionization mass spectrometry (GC/EI-MS) and ultra performance liquid chromatography coupled to electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-Q-TOFMS). Mass concentrations of six isoprene low-NOx SOA tracers contributed to 12–19% of total organic matter (OM) in PM2.5 samples collected during the sampling period, indicating the importance of the hydroxyl radical (OH)-initiated oxidation (so-called photooxidation) of isoprene under low-NOx conditions that leads to SOA formation through reactive uptake of gaseous isoprene epoxydiols (IEPOX) in this region. IEPOX-derived SOA tracers were enhanced under high-SO2 sampling scenarios, suggesting that SO2 oxidation increases aerosol acidity of sulfate aerosols needed for enhancing heterogeneous oxirane ring-opening reactions of IEPOX. No clear associations between isoprene SOA formation and high and low NH3 conditional samples were found. Furthermore, weak correlations between aerosol acidity and mass of IEPOX SOA tracers suggests that IEPOX-derived SOA formation might be modulated by other factors as well in addition to aerosol acidity. Positive correlations between sulfate aerosol loadings and IEPOX-derived SOA tracers for samples collected under all conditions indicates that sulfate aerosol could be a surrogate for surface area in the uptake of IEPOX onto preexisting aerosols.
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Lin, Y. H., E. M. Knipping, E. S. Edgerton, S. L. Shaw, and J. D. Surratt. "Investigating the influences of SO<sub>2</sub> and NH<sub>3</sub> levels on isoprene-derived secondary organic aerosol formation using conditional sampling approaches." Atmospheric Chemistry and Physics 13, no. 16 (August 27, 2013): 8457–70. http://dx.doi.org/10.5194/acp-13-8457-2013.
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Abstract. Filter-based PM2.5 samples were chemically analyzed to investigate secondary organic aerosol (SOA) formation from isoprene in a rural atmosphere of the southeastern US influenced by both anthropogenic sulfur dioxide (SO2) and ammonia (NH3) emissions. Daytime PM2.5 samples were collected during summer 2010 using conditional sampling approaches based on pre-defined high and low SO2 or NH3 thresholds. Known molecular-level tracers for isoprene SOA formation, including 2-methylglyceric acid, 3-methyltetrahydrofuran-3,4-diols, 2-methyltetrols, C5-alkene triols, dimers, and organosulfate derivatives, were identified and quantified by gas chromatography coupled to electron ionization mass spectrometry (GC/EI-MS) and ultra performance liquid chromatography coupled to electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-Q-TOFMS). Mass concentrations of six isoprene low-NOx SOA tracers contributed to 12–19% of total organic matter (OM) in PM2.5 samples collected during the sampling period, indicating the importance of the hydroxyl radical (OH)-initiated oxidation (so-called photooxidation) of isoprene under low-NOx conditions that lead to SOA formation through reactive uptake of gaseous isoprene epoxydiols (IEPOX) in this region. The contribution of the IEPOX-derived SOA tracers to total organic matter was enhanced by 1.4% (p = 0.012) under high-SO2 sampling scenarios, although only weak associations between aerosol acidity and mass of IEPOX SOA tracers were observed. This suggests that IEPOX-derived SOA formation might be modulated by other factors simultaneously, rather than only aerosol acidity. No clear associations between isoprene SOA formation and high or low NH3 conditional samples were found. Positive correlations between sulfate aerosol loadings and IEPOX-derived SOA tracers for samples collected under all conditions indicates that sulfate aerosol could be a surrogate for surface accommodation in the uptake of IEPOX onto preexisting aerosols.
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Sheremetov, Leonid, and Christian Sanchez-Sanchez. "Semantic SOA 4 SOA Supply Networks." IFAC Proceedings Volumes 42, no. 4 (2009): 1304–9. http://dx.doi.org/10.3182/20090603-3-ru-2001.0445.
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Zhang, Peng, Tianzeng Chen, Jun Liu, Guangyan Xu, Qingxin Ma, Biwu Chu, Wanqi Sun, and Hong He. "Increased primary and secondary H<sub>2</sub>SO<sub>4</sub> showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis." Atmospheric Chemistry and Physics 21, no. 9 (May 10, 2021): 7099–112. http://dx.doi.org/10.5194/acp-21-7099-2021.
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Abstract. Stressed plants and polymer production can emit many unsaturated volatile organic esters (UVOEs). However, secondary organic aerosol (SOA) formation of UVOEs remains unclear, especially under complex ambient conditions. In this study, we mainly investigated ethyl methacrylate (EM) ozonolysis. Results showed that a substantial increase in secondary H2SO4 particles promoted SOA formation with increasing SO2. An important reason was that the homogeneous nucleation of more H2SO4 at high SO2 level provided greater surface area and volume for SOA condensation. However, increased primary H2SO4 with seed acidity enhanced EM uptake but reduced SOA formation. This was ascribed to the fact that the ozonolysis of more adsorbed EM was hampered with the formation of surface H2SO4 at higher particle acidity. Moreover, the increase in secondary H2SO4 particle via homogeneous nucleation favored to the oligomerization of oxidation products, whereas the increasing of primary H2SO4 with acidity in the presence of seed tended to promote the functionalization conversion products. This study indicated that the role of increased H2SO4 to EM-derived SOA may not be the same under different ambient conditions, which helps to advance our understanding of the complicated roles of H2SO4 in the formation of EM-derived SOA.
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Lambe, A. T., A. T. Ahern, L. R. Williams, J. G. Slowik, J. P. S. Wong, J. P. D. Abbatt, W. H. Brune, et al. "Characterization of aerosol photooxidation flow reactors: heterogeneous oxidation, secondary organic aerosol formation and cloud condensation nuclei activity measurements." Atmospheric Measurement Techniques Discussions 3, no. 6 (November 18, 2010): 5211–51. http://dx.doi.org/10.5194/amtd-3-5211-2010.
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Abstract. Motivated by the need to develop instrumental techniques for characterizing organic aerosol aging, we report on the performance of the Toronto Photo-Oxidation Tube (TPOT) and Potential Aerosol Mass (PAM) flow tube reactors under a variety of experimental conditions. The principal difference between the flow tubes was that the PAM system was designed to minimize wall effects, whereas the TPOT reactor was designed to study heterogeneous aerosol chemistry. The following studies were performed: (1) transmission efficiency measurements for CO2, SO2, and bis(2-ethylhexyl) sebacate (BES) particles, (2) H2SO4 yield measurements from the oxidation of SO2, (3) residence time distribution (RTD) measurements for CO2, SO2, and BES particles, (4) chemical composition and cloud condensation nuclei (CCN) activity measurements of BES particles exposed to OH radicals, and (5) chemical composition, CCN activity, and yield measurements of secondary organic aerosol (SOA) generated from gas-phase OH oxidation of m-xylene and α-pinene. OH exposures ranged from (2.0 ± 1.0) × 1010 to (1.8 ± 0.3) × 1012 molec cm−3 s. Where applicable, data from the flow tube reactors are compared with published results from the Caltech smog chamber. The TPOT yielded narrower RTDs. However, its transmission efficiency for SO2 was lower than that for the PAM. Transmission efficiency for BES and H2SO4 particles was size-dependent and was similar for the two flow tube designs. Oxidized BES particles had similar chemical composition and CCN activity at OH exposures greater than 1011 molec cm−3 s, but different CCN activity at lower OH exposures. The composition and yield of m-xylene and α-pinene SOA was strongly affected by reactor design and operating conditions, with wall interactions seemingly having the strongest influence on SOA yield. At comparable OH exposures, flow tube SOA was more oxidized than smog chamber SOA because of faster gas-phase oxidation relative to particle nucleation. SOA yields were lower in the TPOT than in the PAM, but CCN activity of flow-tube-generated SOA particles was similar. For comparable OH exposures, α-pinene SOA yields were similar in the PAM and Caltech chambers, but m-xylene SOA yields were much lower in the PAM compared to the Caltech chamber.
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Mehta, Kejal, Krishnapriya Priya Vadlapatla, Zamurrud Patel, and Bharat Shah. "Simple Objective Assessment to Determine Nutritional Status of Hemodialysis Patients." Journal of Renal Nutrition and Metabolism 8, no. 1 (2023): 60–63. http://dx.doi.org/10.4103/jrnm.jrnm_13_23.
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Objective: The objective is to determine nutritional status of hemodialysis (HD) patients using simple objective assessment (SOA) method. Methods: A total of 54 stable patients were evaluated at our dialysis center. All patients were undergoing maintenance HD for at least 6 months. Nutritional status was assessed by subjective global assessment (SGA) and SOA which included two parameters, i.e., change over past 6 months in weight and albumin. Results: The SGA scoring showed that 39 (72.22%) patients were well nourished, 14 (25.92%) mild to moderately malnourished, and 1 (1.85%) severely malnourished. Using the SOA scoring, 40 (74.07%) patients were well nourished, 13 (24.07%) mild to moderately malnourished, and 1 (1.85%) severely malnourished. There was good correlation between the two scoring methods with a correlation coefficient (R) of 0.85. Conclusion: Our study shows that SOA using delta weight and delta albumin over 6 months provides as good information as SGA (R = 0.85) and is easy to implement in routine clinical practice.
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Lambe, A. T., A. T. Ahern, L. R. Williams, J. G. Slowik, J. P. S. Wong, J. P. D. Abbatt, W. H. Brune, et al. "Characterization of aerosol photooxidation flow reactors: heterogeneous oxidation, secondary organic aerosol formation and cloud condensation nuclei activity measurements." Atmospheric Measurement Techniques 4, no. 3 (March 4, 2011): 445–61. http://dx.doi.org/10.5194/amt-4-445-2011.
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Abstract. Motivated by the need to develop instrumental techniques for characterizing organic aerosol aging, we report on the performance of the Toronto Photo-Oxidation Tube (TPOT) and Potential Aerosol Mass (PAM) flow tube reactors under a variety of experimental conditions. The PAM system was designed with lower surface-area-to-volume (SA/V) ratio to minimize wall effects; the TPOT reactor was designed to study heterogeneous aerosol chemistry where wall loss can be independently measured. The following studies were performed: (1) transmission efficiency measurements for CO2, SO2, and bis(2-ethylhexyl) sebacate (BES) particles, (2) H2SO4 yield measurements from the oxidation of SO2, (3) residence time distribution (RTD) measurements for CO2, SO2, and BES particles, (4) aerosol mass spectra, O/C and H/C ratios, and cloud condensation nuclei (CCN) activity measurements of BES particles exposed to OH radicals, and (5) aerosol mass spectra, O/C and H/C ratios, CCN activity, and yield measurements of secondary organic aerosol (SOA) generated from gas-phase OH oxidation of m-xylene and α-pinene. OH exposures ranged from (2.0 ± 1.0) × 1010 to (1.8 ± 0.3) × 1012 molec cm−3 s. Where applicable, data from the flow tube reactors are compared with published results from the Caltech smog chamber. The TPOT yielded narrower RTDs. However, its transmission efficiency for SO2 was lower than that for the PAM. Transmission efficiency for BES and H2SO4 particles was size-dependent and was similar for the two flow tube designs. Oxidized BES particles had similar O/C and H/C ratios and CCN activity at OH exposures greater than 1011 molec cm−3 s, but different CCN activity at lower OH exposures. The O/C ratio, H/C ratio, and yield of m-xylene and α-pinene SOA was strongly affected by reactor design and operating conditions, with wall interactions seemingly having the strongest influence on SOA yield. At comparable OH exposures, flow tube SOA was more oxidized than smog chamber SOA, possibly because of faster gas-phase oxidation relative to particle nucleation. SOA yields were lower in the TPOT than in the PAM, but CCN activity of flow-tube-generated SOA particles was similar. For comparable OH exposures, α-pinene SOA yields were similar in the PAM and Caltech chambers, but m-xylene SOA yields were much lower in the PAM compared to the Caltech chamber.
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Liu, T., X. Wang, Q. Hu, W. Deng, Y. Zhang, X. Ding, X. Fu, et al. "Formation of secondary aerosols from gasoline vehicle exhausts when mixing with SO<sub>2</sub>." Atmospheric Chemistry and Physics Discussions 15, no. 17 (September 2, 2015): 23613–49. http://dx.doi.org/10.5194/acpd-15-23613-2015.
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Abstract. Sulfur dioxide (SO2) can enhance the formation of secondary aerosols from biogenic volatile organic compounds (VOCs), but its influence on secondary aerosol formation from anthropogenic VOCs, particularly complex mixtures like vehicle exhausts, is still poorly understood. Here we directly co-introduced gasoline vehicles exhausts (GVE) and SO2, a typical pollutant from coal burning, into a smog chamber to investigate the formation of secondary organic aerosols (SOA) and sulfate aerosols through photooxidation. In the presence of high concentration of SO2, new particle formation was enhanced while substantial sulfate was formed through the oxidation of SO2. The homogenous oxidation by OH radicals contributed a negligible fraction to the conversion of SO2 to sulfate, and instead the oxidation by stabilized Criegee intermediates (sCIs), formed from alkenes in the exhaust reacting with ozone, dominated the conversion of SO2. After 5 h of photochemical aging, GVE's SOA production factor revealed an increase by 60–200 % in the presence of high concentration of SO2. This increase could largely be attributed to acid-catalyzed SOA formation, which was evidenced by the strong positive linear correlation (R2 = 0.97) between the SOA production factor and in-situ particle acidity calculated by AIM-II model. A high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS) resolved OA's relatively lower oxygen-to-carbon (O : C) and higher hydrogen-to-carbon (H : C) molar ratios for the GVE/SO2 mixture, with a much lower estimated average carbon oxidation state (OSc) of −0.51 ± 0.06 than that of −0.19 ± 0.08 for GVE alone. The relative higher mass loading of OA in the experiments with SO2 might be the major reason for the lower oxidation degree of SOA.
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Liu, T., X. Wang, Q. Hu, W. Deng, Y. Zhang, X. Ding, X. Fu, et al. "Formation of secondary aerosols from gasoline vehicle exhaust when mixing with SO<sub>2</sub>." Atmospheric Chemistry and Physics 16, no. 2 (January 21, 2016): 675–89. http://dx.doi.org/10.5194/acp-16-675-2016.
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Abstract. Sulfur dioxide (SO2) can enhance the formation of secondary aerosols from biogenic volatile organic compounds (VOCs), but its influence on secondary aerosol formation from anthropogenic VOCs, particularly complex mixtures like vehicle exhaust, remains uncertain. Gasoline vehicle exhaust (GVE) and SO2, a typical pollutant from coal burning, are directly co-introduced into a smog chamber, in this study, to investigate the formation of secondary organic aerosols (SOA) and sulfate aerosols through photooxidation. New particle formation was enhanced, while substantial sulfate was formed through the oxidation of SO2 in the presence of high concentration of SO2. Homogenous oxidation by OH radicals contributed a negligible fraction to the conversion of SO2 to sulfate, and instead the oxidation by stabilized Criegee intermediates (sCIs), formed from alkenes in the exhaust reacting with ozone, dominated the conversion of SO2. After 5 h of photochemical aging, GVE's SOA production factor revealed an increase by 60–200 % in the presence of high concentration of SO2. The increase could principally be attributed to acid-catalyzed SOA formation as evidenced by the strong positive linear correlation (R2 = 0.97) between the SOA production factor and in situ particle acidity calculated by the AIM-II model. A high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS) resolved OA's relatively lower oxygen-to-carbon (O : C) (0.44 ± 0.02) and higher hydrogen-to-carbon (H : C) (1.40 ± 0.03) molar ratios for the GVE / SO2 mixture, with a significantly lower estimated average carbon oxidation state (OSc) of −0.51 ± 0.06 than −0.19 ± 0.08 for GVE alone. The relative higher mass loading of OA in the experiments with SO2 might be a significant explanation for the lower SOA oxidation degree.
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Liu, Xinyu, Guangquan Li, and Peng Shao. "A Multi-Mechanism Seagull Optimization Algorithm Incorporating Generalized Opposition-Based Nonlinear Boundary Processing." Mathematics 10, no. 18 (September 11, 2022): 3295. http://dx.doi.org/10.3390/math10183295.
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The seagull optimization algorithm (SOA), a well-known illustration of intelligent algorithms, has recently drawn a lot of academic interest. However, it has a variety of issues including slower convergence, poorer search accuracy, the single path for pursuing optimization, and the simple propensity to slip into local optimality. This paper suggests a multi-mechanism seagull optimization algorithm (GEN−SOA) that incorporates the generalized opposition-based, adaptive nonlinear weights, and evolutionary boundary constraints to address these demerits further. These methods are balanced and promoted the population variety and the capability to conduct global and local search. Compared with SOA, PSO, SCA, SSA, and BOA on 12 well-known test functions, the experimental results demonstrate that GEN-SOA has a higher accuracy and faster convergence than the other five algorithms, and it can find the global optimal solution beyond the local optimum. Furthermore, to verify the capability of GEN−SOA to solve practical problems, this paper applied GEN−SOA to solve two standard engineering optimization design problems including a welding optimization and a pressure vessel optimization, and the experimental results showed that it has significant advantages over SOA.
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Li, Jialin, Meigen Zhang, Guiqian Tang, Yele Sun, Fangkun Wu, and Yongfu Xu. "Assessment of dicarbonyl contributions to secondary organic aerosols over China using RAMS-CMAQ." Atmospheric Chemistry and Physics 19, no. 9 (May 16, 2019): 6481–95. http://dx.doi.org/10.5194/acp-19-6481-2019.
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Abstract. The concentration of secondary organic aerosol (SOA) is underestimated in current model studies. Recent research suggests that the reactive uptake of dicarbonyls contributes to the production of SOA, although few models have included this pathway. Glyoxal, an important representative component of dicarbonyls in models, is significantly underestimated. We therefore incorporated the reactive uptake of dicarbonyls into the regional air quality modeling system RAMS-CMAQ (the Regional Atmospheric Modeling System-Community Multiscale Air Quality) to evaluate the contribution of dicarbonyls to SOA, and we then assess the impact of the underestimation of glyoxal on the production of SOA in China during two time periods: 3 June to 11 July 2014 (episode 1) and 14 October to 14 November 2014 (episode 2). When the reactive uptake process was added, the modeled mean concentration of SOA in episode 1 increased by 3.65 µg m−3, which explained 34.8 % of the unaccounted-for source of SOA. Meanwhile the increase in the concentration of SOA in episode 2 was 1.82 µg m−3 as a result of the lower liquid water content and the lower amount of dicarbonyls produced from biogenic precursors in the fall. On this basis, when the glyoxal simulation was improved, the modeled mean dicarbonyl-derived SOA (AAQ) increased by more than a factor of 2 in both episodes relative to case 1. AAQ in episode 1 contributed, on average, 60.6 % of the total concentration of SOA and the increase in this contribution represented 69.1 % of the unaccounted-for concentration of SOA, whereas the mean AAQ in episode 2 accounted for 64.5 % of total concentration of SOA. Based on the results, the mean AAQ over China was generally higher in the east than in the west during the two episodes. The highest value (10–15 µg m−3) of episode 1 appeared in the areas around the lower reaches of the Yellow River, whereas the highest value of 5–10 µg m−3 in episode 2 was concentrated over regions from south of the lower reaches of the Yellow River to the south of Guangzhou Province as well as the Sichuan Basin. The contribution of AAQ to the concentration of SOA in episode 1 varied from 10 % to 90 % throughout China, with the highest contributions (70 %–90 %) in the coastal regions and offshore along the East China Sea to the South China Sea and in the southwestern regions. The fraction of AAQ to SOA in episode 2 was in the range of 10 %–80 % over China, with the fraction up to 80 % in a small portion of northeastern China.
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Xu, Lu, Hongyu Guo, Christopher M. Boyd, Mitchel Klein, Aikaterini Bougiatioti, Kate M. Cerully, James R. Hite, et al. "Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States." Proceedings of the National Academy of Sciences 112, no. 1 (December 22, 2014): 37–42. http://dx.doi.org/10.1073/pnas.1417609112.
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Secondary organic aerosol (SOA) constitutes a substantial fraction of fine particulate matter and has important impacts on climate and human health. The extent to which human activities alter SOA formation from biogenic emissions in the atmosphere is largely undetermined. Here, we present direct observational evidence on the magnitude of anthropogenic influence on biogenic SOA formation based on comprehensive ambient measurements in the southeastern United States (US). Multiple high-time-resolution mass spectrometry organic aerosol measurements were made during different seasons at various locations, including urban and rural sites in the greater Atlanta area and Centreville in rural Alabama. Our results provide a quantitative understanding of the roles of anthropogenic SO2 and NOx in ambient SOA formation. We show that isoprene-derived SOA is directly mediated by the abundance of sulfate, instead of the particle water content and/or particle acidity as suggested by prior laboratory studies. Anthropogenic NOx is shown to enhance nighttime SOA formation via nitrate radical oxidation of monoterpenes, resulting in the formation of condensable organic nitrates. Together, anthropogenic sulfate and NOx can mediate 43–70% of total measured organic aerosol (29–49% of submicron particulate matter, PM1) in the southeastern US during summer. These measurements imply that future reduction in SO2 and NOx emissions can considerably reduce the SOA burden in the southeastern US. Updating current modeling frameworks with these observational constraints will also lead to more accurate treatment of aerosol formation for regions with substantial anthropogenic−biogenic interactions and consequently improve air quality and climate simulations.
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Cheng, Yubo, Yiqiu Ma, and Di Hu. "Tracer-based source apportioning of atmospheric organic carbon and the influence of anthropogenic emissions on secondary organic aerosol formation in Hong Kong." Atmospheric Chemistry and Physics 21, no. 13 (July 14, 2021): 10589–608. http://dx.doi.org/10.5194/acp-21-10589-2021.
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Abstract. Here we conducted comprehensive chemical characterization and source apportionment of 49 PM2.5 samples collected in Hong Kong. Besides the major aerosol constituents, 39 polar organic species, including 14 secondary organic aerosol (SOA) tracers of isoprene, monoterpenes, β-caryophyllene, and naphthalene, were quantified using gas chromatography–mass spectrometry (GC–MS). Six factors, i.e., SOA, secondary sulfate (SS), biomass burning (BB)/SOA, sea salt, marine vessels, and vehicle emissions, were apportioned by positive matrix factorization (PMF) as the major sources of ambient organic carbon (OC) in Hong Kong. The secondary formation, including OC from SOA, SS, and aging of BB plume, was the leading contributor to OC (51.4 %, 2.15 ± 1.37 µg C m−3) throughout the year. We then applied a tracer-based method (TBM) to estimate the SOA formation from the photo-oxidation of four selected precursors, and monoterpene SOA was the most abundant. A Kintecus kinetic model was used to examine the formation channels of isoprene SOA, and the aerosol-phase ring-opening reaction of isoprene epoxydiols (IEPOXs) was found to be the dominant formation pathway. Consistently, IEPOX tracers contributed 94 % to total GC–MS-quantified isoprene SOA tracers. The TBM-estimated secondary organic carbon (SOCTBM) and PMF-apportioned SOC (SOCPMF) showed similar temporal trends; however, SOCTBM only accounted for 26.5 % of SOCPMF, indicating a large fraction of ambient SOA was from other reaction pathways or precursors. Results of Pearson's R and multivariate linear regression analysis showed that NOx processing played a key role in both daytime and nighttime SOA production in the region. Moreover, sulfate had a significant positive linear relationship with SOCPMF and SS-related SOC, and particle acidity was significantly correlated with SOC from the aging of BB.
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Carey, M. J. "SOA What?" Computer 41, no. 3 (March 2008): 92–94. http://dx.doi.org/10.1109/mc.2008.97.
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Raepple, Martin. "SOA glossar." Datenschutz und Datensicherheit - DuD 31, no. 9 (September 2007): 689–90. http://dx.doi.org/10.1007/s11623-007-0225-7.
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Schelp, Joachim, and Matthias Stutz. "SOA-Governance." HMD Praxis der Wirtschaftsinformatik 44, no. 1 (February 2007): 66–73. http://dx.doi.org/10.1007/bf03340249.
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Shah, Deven, Vaibhav Vyas, Vishal Vyas, and Dhiren Patel. "Global SOA Architectural Style – SOA for End Users." Journal of Algorithms & Computational Technology 4, no. 4 (December 2010): 555–74. http://dx.doi.org/10.1260/1748-3018.4.4.555.
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Rattanavaraha, Weruka, Kevin Chu, Sri Hapsari Budisulistiorini, Matthieu Riva, Ying-Hsuan Lin, Eric S. Edgerton, Karsten Baumann, et al. "Assessing the impact of anthropogenic pollution on isoprene-derived secondary organic aerosol formation in PM<sub>2.5</sub> collected from the Birmingham, Alabama, ground site during the 2013 Southern Oxidant and Aerosol Study." Atmospheric Chemistry and Physics 16, no. 8 (April 21, 2016): 4897–914. http://dx.doi.org/10.5194/acp-16-4897-2016.
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Abstract. In the southeastern US, substantial emissions of isoprene from deciduous trees undergo atmospheric oxidation to form secondary organic aerosol (SOA) that contributes to fine particulate matter (PM2.5). Laboratory studies have revealed that anthropogenic pollutants, such as sulfur dioxide (SO2), oxides of nitrogen (NOx), and aerosol acidity, can enhance SOA formation from the hydroxyl radical (OH)-initiated oxidation of isoprene; however, the mechanisms by which specific pollutants enhance isoprene SOA in ambient PM2.5 remain unclear. As one aspect of an investigation to examine how anthropogenic pollutants influence isoprene-derived SOA formation, high-volume PM2.5 filter samples were collected at the Birmingham, Alabama (BHM), ground site during the 2013 Southern Oxidant and Aerosol Study (SOAS). Sample extracts were analyzed by gas chromatography–electron ionization-mass spectrometry (GC/EI-MS) with prior trimethylsilylation and ultra performance liquid chromatography coupled to electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-QTOFMS) to identify known isoprene SOA tracers. Tracers quantified using both surrogate and authentic standards were compared with collocated gas- and particle-phase data as well as meteorological data provided by the Southeastern Aerosol Research and Characterization (SEARCH) network to assess the impact of anthropogenic pollution on isoprene-derived SOA formation. Results of this study reveal that isoprene-derived SOA tracers contribute a substantial mass fraction of organic matter (OM) ( ∼ 7 to ∼ 20 %). Isoprene-derived SOA tracers correlated with sulfate (SO42−) (r2 = 0.34, n = 117) but not with NOx. Moderate correlations between methacrylic acid epoxide and hydroxymethyl-methyl-α-lactone (together abbreviated MAE/HMML)-derived SOA tracers with nitrate radical production (P[NO3]) (r2 = 0.57, n = 40) were observed during nighttime, suggesting a potential role of the NO3 radical in forming this SOA type. However, the nighttime correlation of these tracers with nitrogen dioxide (NO2) (r2 = 0.26, n = 40) was weaker. Ozone (O3) correlated strongly with MAE/HMML-derived tracers (r2 = 0.72, n = 30) and moderately with 2-methyltetrols (r2 = 0.34, n = 15) during daytime only, suggesting that a fraction of SOA formation could occur from isoprene ozonolysis in urban areas. No correlation was observed between aerosol pH and isoprene-derived SOA. Lack of correlation between aerosol acidity and isoprene-derived SOA is consistent with the observation that acidity is not a limiting factor for isoprene SOA formation at the BHM site as aerosols were acidic enough to promote multiphase chemistry of isoprene-derived epoxides throughout the duration of the study. All in all, these results confirm previous studies suggesting that anthropogenic pollutants enhance isoprene-derived SOA formation.
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Kang, Mingjie, Pingqing Fu, Kimitaka Kawamura, Fan Yang, Hongliang Zhang, Zhengchen Zang, Hong Ren, et al. "Characterization of biogenic primary and secondary organic aerosols in the marine atmosphere over the East China Sea." Atmospheric Chemistry and Physics 18, no. 19 (October 2, 2018): 13947–67. http://dx.doi.org/10.5194/acp-18-13947-2018.
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Abstract. Molecular composition and abundance of sugars and secondary organic aerosols (SOA) from biogenic sources over the East China Sea were investigated based on gas chromatography–mass spectrometry. Biogenic SOA tracers and sugars exhibit higher levels in the samples affected by continental air masses, demonstrating the terrestrial outflows of organic matter to the East China Sea. Glucose was the dominant sugar species (0.31–209, 18.8 ng m−3), followed by mannitol – a fungal spore tracer. All sugar compounds show generally higher average concentrations in the nighttime than in the daytime. 3-Methyl-1,2,3-butanetricarboxylic acid, one higher generation photooxidation tracer of monoterpene SOA, was found to be the most abundant species among measured biogenic SOA markers, suggesting the input of aged organic aerosols through long-range transport. Fungal-spore-derived organic carbon (OC) was the biggest contributor to total OC (0.03 %–19.8 %, 3.1 %), followed by sesquiterpene-derived secondary OC (SOC), biomass-burning-derived OC, and monoterpene- and isoprene-derived SOC. Larger carbon percentages of biogenic primary OCs and SOCs in total OC presented in the terrestrially influenced aerosols indicate significant contributions of continental aerosols through long-range transport. Positive matrix factorization results illustrate that the secondary nitrate and biogenic SOA, biomass burning, and fungal spores were the main sources of OC in marine aerosols over the East China Sea, again highlighting the importance of the Asian continent as a natural emitter of biogenic organic aerosols together with anthropogenic aerosols over the coastal marine atmosphere.
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Shashwat, Anurag, Deepak Kumar, and Lovneesh Chanana. "A Framework with Enhanced Security for Service Oriented Architecture." International Journal of Sensors, Wireless Communications and Control 10, no. 3 (November 2, 2020): 325–33. http://dx.doi.org/10.2174/2210327909666190710122505.
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Background: Service Oriented Architecture is one of the acceptable frameworks for application development which provides better functionality such as composability, reliability, reusability, distributed deployment and interoperability which meet enterprises dynamics. So, SOA framework is a point of attraction for consumers. Objective: However, SOA framework fails to provide security at a granular level. Along with SOA functionality, the consumer also needs a secure environment so that each application can be reliable. Methods: SOA functionality like modularity and reusability are helpful in cross-organization context but these quality requirements reduce the security of the applications. In the past years, many security techniques have been provided by different researchers, still, security is a concern of SOA framework. Results: Most of the research focus security enhancement at higher layers of SOA reference architecture only so that SOA functionality remains unaffected. In this paper, the author(s) provided a framework which enhances the security at both the higher layer and lower layer. Conclusion: Also, this framework focuses on security enhancement at the granular level so that application-level security can be enhanced. The author(s) also included a technique to keep SLA similar to the exiting application after the implementation of security at each layer. This framework will be helpful in enhancing the end to end security and reliability of an application.
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Liu, Changgeng, Yongchun Liu, Tianzeng Chen, Jun Liu, and Hong He. "Rate constant and secondary organic aerosol formation from the gas-phase reaction of eugenol with hydroxyl radicals." Atmospheric Chemistry and Physics 19, no. 3 (February 14, 2019): 2001–13. http://dx.doi.org/10.5194/acp-19-2001-2019.
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Abstract. Methoxyphenols are an important organic component of wood-burning emissions and considered to be potential precursors of secondary organic aerosol (SOA). In this work, the rate constant and SOA formation potential for the OH-initiated reaction of 4-allyl-2-methoxyphenol (eugenol) were investigated for the first time in an oxidation flow reactor (OFR). The rate constant was 8.01±0.40×10-11 cm3 molecule−1 s−1, determined by the relative rate method. The SOA yield first increased and then decreased as a function of OH exposure and was also dependent on eugenol concentration. The maximum SOA yields (0.11–0.31) obtained at different eugenol concentrations could be expressed well by a one-product model. The carbon oxidation state (OSC) increased linearly and significantly as OH exposure rose, indicating that a high oxidation degree was achieved for SOA. In addition, the presence of SO2 (0–198 ppbv) and NO2 (0–109 ppbv) was conducive to increasing SOA yield, for which the maximum enhancement values were 38.6 % and 19.2 %, respectively. The N∕C ratio (0.032–0.043) indicated that NO2 participated in the OH-initiated reaction, subsequently forming organic nitrates. The results could be helpful for further understanding the SOA formation potential from the atmospheric oxidation of methoxyphenols and the atmospheric aging process of smoke plumes from biomass burning emissions.
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Jo, Duseong S., Alma Hodzic, Louisa K. Emmons, Eloise A. Marais, Zhe Peng, Benjamin A. Nault, Weiwei Hu, Pedro Campuzano-Jost, and Jose L. Jimenez. "A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc." Geoscientific Model Development 12, no. 7 (July 15, 2019): 2983–3000. http://dx.doi.org/10.5194/gmd-12-2983-2019.
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Abstract. Secondary organic aerosol derived from isoprene epoxydiols (IEPOX-SOA) is thought to contribute the dominant fraction of total isoprene SOA, but the current volatility-based lumped SOA parameterizations are not appropriate to represent the reactive uptake of IEPOX onto acidified aerosols. A full explicit modeling of this chemistry is however computationally expensive owing to the many species and reactions tracked, which makes it difficult to include it in chemistry–climate models for long-term studies. Here we present three simplified parameterizations (version 1.0) for IEPOX-SOA simulation, based on an approximate analytical/fitting solution of the IEPOX-SOA yield and formation timescale. The yield and timescale can then be directly calculated using the global model fields of oxidants, NO, aerosol pH and other key properties, and dry deposition rates. The advantage of the proposed parameterizations is that they do not require the simulation of the intermediates while retaining the key physicochemical dependencies. We have implemented the new parameterizations into the GEOS-Chem v11-02-rc chemical transport model, which has two empirical treatments for isoprene SOA (the volatility-basis-set, VBS, approach and a fixed 3 % yield parameterization), and compared all of them to the case with detailed fully explicit chemistry. The best parameterization (PAR3) captures the global tropospheric burden of IEPOX-SOA and its spatiotemporal distribution (R2=0.94) vs. those simulated by the full chemistry, while being more computationally efficient (∼5 times faster), and accurately captures the response to changes in NOx and SO2 emissions. On the other hand, the constant 3 % yield that is now the default in GEOS-Chem deviates strongly (R2=0.66), as does the VBS (R2=0.47, 49 % underestimation), with neither parameterization capturing the response to emission changes. With the advent of new mass spectrometry instrumentation, many detailed SOA mechanisms are being developed, which will challenge global and especially climate models with their computational cost. The methods developed in this study can be applied to other SOA pathways, which can allow including accurate SOA simulations in climate and global modeling studies in the future.
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Wu, Li, Xue Li, HyeKyeong Kim, Hong Geng, Ricardo H. M. Godoi, Cybelli G. G. Barbosa, Ana F. L. Godoi, et al. "Single-particle characterization of aerosols collected at a remote site in the Amazonian rainforest and an urban site in Manaus, Brazil." Atmospheric Chemistry and Physics 19, no. 2 (January 31, 2019): 1221–40. http://dx.doi.org/10.5194/acp-19-1221-2019.
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Abstract. In this study, aerosol samples collected at a remote site in the Amazonian rainforest and an urban site in Manaus, Brazil, were investigated on a single-particle basis using a quantitative energy-dispersive electron probe X-ray microanalysis (ED-EPMA). A total of 23 aerosol samples were collected in four size ranges (0.25–0.5, 0.5–1.0, 1.0–2.0, and 2.0–4.0 µm) during the wet season in 2012 at two Amazon basin sites: 10 samples in Manaus, an urban area; and 13 samples at an 80 m high tower, located at the Amazon Tall Tower Observatory (ATTO) site in the middle of the rainforest, 150 km northeast of Manaus. The aerosol particles were classified into nine particle types based on the morphology on the secondary electron images (SEIs) together with the elemental concentrations of 3162 individual particles: (i) secondary organic aerosols (SOA); (ii) ammonium sulfate (AS); (iii) SOA and AS mixtures; (iv) aged mineral dust; (v) reacted sea salts; (vi) primary biological aerosol (PBA); (vii) carbon-rich or elemental carbon (EC) particles, such as soot, tarball, and char; (viii) fly ash; and (ix) heavy metal (HM, such as Fe, Zn, Ni, and Ti)-containing particles. In submicron aerosols collected at the ATTO site, SOA and AS mixture particles were predominant (50 %–94 % in relative abundance) with SOA and ammonium sulfate comprising 73 %–100 %. In supermicron aerosols at the ATTO site, aged mineral dust and sea salts (37 %–70 %) as well as SOA and ammonium sulfate (28 %–58 %) were abundant. PBAs were observed abundantly in the PM2−4 fraction (46 %), and EC and fly ash particles were absent in all size fractions. The analysis of a bulk PM0.25−0.5 aerosol sample from the ATTO site using Raman microspectrometry and attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) showed that ammonium sulfate, organics, and minerals are the major chemical species, which is consistent with the ED-EPMA results. In the submicron aerosols collected in Manaus, either SOA and ammonium sulfate (17 %–80 %) or EC particles (6 %–78 %) were dominant depending on the samples. In contrast, aged mineral dust, reacted sea salt, PBA, SOA, ammonium sulfate, and EC particles comprised most of the supermicron aerosols collected in Manaus. The SOA, ammonium sulfate, and PBAs were mostly of a biogenic origin from the rainforest, whereas the EC and HM-containing particles were of an anthropogenic origin. Based on the different contents of SOA, ammonium sulfate, and EC particles among the samples collected in Manaus, a considerable influence of the rainforest over the city was observed. Aged mineral dust and reacted sea-salt particles, including mineral dust mixed with sea salts probably during long-range transatlantic transport, were abundant in the supermicron fractions at both sites. Among the aged mineral dust and reacted sea-salt particles, sulfate-containing ones outnumbered those containing nitrates and sulfate + nitrate in the ATTO samples. In contrast, particles containing sulfate + nitrate were comparable in number to particles containing sulfate only in the Manaus samples, indicating the different sources and formation mechanisms of secondary aerosols, i.e., the predominant presence of sulfate at the ATTO site from mostly biogenic emissions and the elevated influences of nitrates from anthropogenic activities at the Manaus site.
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Huang, Yuanzhou, Fabian Mahrt, Shaun Xu, Manabu Shiraiwa, Andreas Zuend, and Allan K. Bertram. "Coexistence of three liquid phases in individual atmospheric aerosol particles." Proceedings of the National Academy of Sciences 118, no. 16 (April 15, 2021): e2102512118. http://dx.doi.org/10.1073/pnas.2102512118.
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Individual atmospheric particles can contain mixtures of primary organic aerosol (POA), secondary organic aerosol (SOA), and secondary inorganic aerosol (SIA). To predict the role of such complex multicomponent particles in air quality and climate, information on the number and types of phases present in the particles is needed. However, the phase behavior of such particles has not been studied in the laboratory, and as a result, remains poorly constrained. Here, we show that POA+SOA+SIA particles can contain three distinct liquid phases: a low-polarity organic-rich phase, a higher-polarity organic-rich phase, and an aqueous inorganic-rich phase. Based on our results, when the elemental oxygen-to-carbon (O:C) ratio of the SOA is less than 0.8, three liquid phases can coexist within the same particle over a wide relative humidity range. In contrast, when the O:C ratio of the SOA is greater than 0.8, three phases will not form. We also demonstrate, using thermodynamic and kinetic modeling, that the presence of three liquid phases in such particles impacts their equilibration timescale with the surrounding gas phase. Three phases will likely also impact their ability to act as nuclei for liquid cloud droplets, the reactivity of these particles, and the mechanism of SOA formation and growth in the atmosphere. These observations provide fundamental information necessary for improved predictions of air quality and aerosol indirect effects on climate.
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Zheng, Yiqi, Larry W. Horowitz, Raymond Menzel, David J. Paynter, Vaishali Naik, Jingyi Li, and Jingqiu Mao. "Anthropogenic amplification of biogenic secondary organic aerosol production." Atmospheric Chemistry and Physics 23, no. 15 (August 11, 2023): 8993–9007. http://dx.doi.org/10.5194/acp-23-8993-2023.
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Abstract. Biogenic secondary organic aerosols (SOAs) contribute to a large fraction of fine aerosols globally, impacting air quality and climate. The formation of biogenic SOA depends on not only emissions of biogenic volatile organic compounds (BVOCs) but also anthropogenic pollutants including primary organic aerosol, sulfur dioxide (SO2), and nitrogen oxides (NOx). However, the anthropogenic impact on biogenic SOA production (AIBS) remains unclear. Here we use the decadal trend and variability in observed organic aerosol (OA) in the southeast US, combined with a global chemistry–climate model, to better constrain AIBS. We show that the reduction in SO2 emissions can only explain 40 % of the decreasing decadal trend of OA in this region, constrained by the low summertime month-to-month variability in surface OA. We hypothesize that the rest of the OA decreasing trend is largely due to a reduction in NOx emissions. By implementing a scheme for monoterpene SOA with enhanced sensitivity to NOx, our model can reproduce the decadal trend and variability in OA in this region. Extending to a centennial scale, our model shows that global SOA production increases by 36 % despite BVOC reductions from the preindustrial period to the present day, largely amplified by AIBS. Our work suggests a strong coupling between anthropogenic and biogenic emissions in biogenic SOA production that is missing from current climate models.
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Nault, Benjamin A., Pedro Campuzano-Jost, Douglas A. Day, Jason C. Schroder, Bruce Anderson, Andreas J. Beyersdorf, Donald R. Blake, et al. "Secondary organic aerosol production from local emissions dominates the organic aerosol budget over Seoul, South Korea, during KORUS-AQ." Atmospheric Chemistry and Physics 18, no. 24 (December 14, 2018): 17769–800. http://dx.doi.org/10.5194/acp-18-17769-2018.
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Abstract. Organic aerosol (OA) is an important fraction of submicron aerosols. However, it is challenging to predict and attribute the specific organic compounds and sources that lead to observed OA loadings, largely due to contributions from secondary production. This is especially true for megacities surrounded by numerous regional sources that create an OA background. Here, we utilize in situ gas and aerosol observations collected on board the NASA DC-8 during the NASA–NIER KORUS-AQ (Korea–United States Air Quality) campaign to investigate the sources and hydrocarbon precursors that led to the secondary OA (SOA) production observed over Seoul. First, we investigate the contribution of transported OA to total loadings observed over Seoul by using observations over the Yellow Sea coupled to FLEXPART Lagrangian simulations. During KORUS-AQ, the average OA loading advected into Seoul was ∼1–3 µg sm−3. Second, taking this background into account, the dilution-corrected SOA concentration observed over Seoul was ∼140 µgsm-3ppmv-1 at 0.5 equivalent photochemical days. This value is at the high end of what has been observed in other megacities around the world (20–70 µgsm-3ppmv-1 at 0.5 equivalent days). For the average OA concentration observed over Seoul (13 µg sm−3), it is clear that production of SOA from locally emitted precursors is the major source in the region. The importance of local SOA production was supported by the following observations. (1) FLEXPART source contribution calculations indicate any hydrocarbons with a lifetime of less than 1 day, which are shown to dominate the observed SOA production, mainly originate from South Korea. (2) SOA correlated strongly with other secondary photochemical species, including short-lived species (formaldehyde, peroxy acetyl nitrate, sum of acyl peroxy nitrates, dihydroxytoluene, and nitrate aerosol). (3) Results from an airborne oxidation flow reactor (OFR), flown for the first time, show a factor of 4.5 increase in potential SOA concentrations over Seoul versus over the Yellow Sea, a region where background air masses that are advected into Seoul can be measured. (4) Box model simulations reproduce SOA observed over Seoul within 11 % on average and suggest that short-lived hydrocarbons (i.e., xylenes, trimethylbenzenes, and semi-volatile and intermediate-volatility compounds) were the main SOA precursors over Seoul. Toluene alone contributes 9 % of the modeled SOA over Seoul. Finally, along with these results, we use the metric ΔOA/ΔCO2 to examine the amount of OA produced per fuel consumed in a megacity, which shows less variability across the world than ΔOA∕ΔCO.
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Zhao, Jian, Wei Du, Yingjie Zhang, Qingqing Wang, Chen Chen, Weiqi Xu, Tingting Han, et al. "Insights into aerosol chemistry during the 2015 China Victory Day parade: results from simultaneous measurements at ground level and 260 m in Beijing." Atmospheric Chemistry and Physics 17, no. 4 (March 3, 2017): 3215–32. http://dx.doi.org/10.5194/acp-17-3215-2017.
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Abstract. Strict emission controls were implemented in Beijing and adjacent provinces to ensure good air quality during the 2015 China Victory Day parade. Here, we conducted synchronous measurements of submicron aerosols (PM1) at ground level and 260 m on a meteorological tower by using a high-resolution aerosol mass spectrometer and an aerosol chemical speciation monitor, respectively, in Beijing from 22 August to 30 September. Our results showed that the average PM1 concentrations are 19.3 and 14.8 µg m−3 at ground level and 260 m, respectively, during the control period (20 August–3 September), which are 57 and 50 % lower than those after the control period (4–30 September). Organic aerosols (OAs) dominated PM1 during the control period at both ground level and 260 m (55 and 53 %, respectively), while their contribution showed substantial decreases (∼ 40 %) associated with an increase in secondary inorganic aerosols (SIAs) after the parade, indicating a larger impact of emission controls on SIA than OA. Positive matrix factorization of OA further illustrated that primary OA (POA) showed similar decreases as secondary OA (SOA) at both ground level (40 % vs. 42 %) and 260 m (35 % vs. 36 %). However, we also observed significant changes in SOA composition at ground level. While the more oxidized SOA showed a large decrease by 75 %, the less oxidized SOA was comparable during (5.6 µg m−3) and after the control periods (6.5 µg m−3). Our results demonstrated that the changes in meteorological conditions and PM loadings have affected SOA formation mechanisms, and the photochemical production of fresh SOA was more important during the control period. By isolating the influences of meteorological conditions and footprint regions in polluted episodes, we found that regional emission controls on average reduced PM levels by 44–45 %, and the reductions were close among SIA, SOA and POA at 260 m, whereas primary species showed relatively more reductions (55–67 %) than secondary aerosol species (33–44 %) at ground level.
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Kelly, Jamie M., Ruth M. Doherty, Fiona M. O'Connor, and Graham W. Mann. "The impact of biogenic, anthropogenic, and biomass burning volatile organic compound emissions on regional and seasonal variations in secondary organic aerosol." Atmospheric Chemistry and Physics 18, no. 10 (May 28, 2018): 7393–422. http://dx.doi.org/10.5194/acp-18-7393-2018.
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Abstract. The global secondary organic aerosol (SOA) budget is highly uncertain, with global annual SOA production rates, estimated from global models, ranging over an order of magnitude and simulated SOA concentrations underestimated compared to observations. In this study, we use a global composition-climate model (UKCA) with interactive chemistry and aerosol microphysics to provide an in-depth analysis of the impact of each VOC source on the global SOA budget and its seasonality. We further quantify the role of each source on SOA spatial distributions, and evaluate simulated seasonal SOA concentrations against a comprehensive set of observations. The annual global SOA production rates from monoterpene, isoprene, biomass burning, and anthropogenic precursor sources is 19.9, 19.6, 9.5, and 24.6 Tg (SOA) a−1, respectively. When all sources are included, the SOA production rate from all sources is 73.6 Tg (SOA) a−1, which lies within the range of estimates from previous modelling studies. SOA production rates and SOA burdens from biogenic and biomass burning SOA sources peak during Northern Hemisphere (NH) summer. In contrast, the anthropogenic SOA production rate is fairly constant all year round. However, the global anthropogenic SOA burden does have a seasonal cycle which is lowest during NH summer, which is probably due to enhanced wet removal. Inclusion of the new SOA sources also accelerates the ageing by condensation of primary organic aerosol (POA), making it more hydrophilic, leading to a reduction in the POA lifetime. With monoterpene as the only source of SOA, simulated SOA and total organic aerosol (OA) concentrations are underestimated by the model when compared to surface and aircraft measurements. Model agreement with observations improves with all new sources added, primarily due to the inclusion of the anthropogenic source of SOA, although a negative bias remains. A further sensitivity simulation was performed with an increased anthropogenic SOA reaction yield, corresponding to an annual global SOA production rate of 70.0 Tg (SOA) a−1. Whilst simulated SOA concentrations improved relative to observations, they were still underestimated in urban environments and overestimated further downwind and in remote environments. In contrast, the inclusion of SOA from isoprene and biomass burning did not improve model–observations biases substantially except at one out of two tropical locations. However, these findings may reflect the very limited availability of observations to evaluate the model, which are primarily located in the NH mid-latitudes where anthropogenic emissions are high. Our results highlight that, within the current uncertainty limits in SOA sources and reaction yields, over the NH mid-latitudes, a large anthropogenic SOA source results in good agreement with observations. However, more observations are needed to establish the importance of biomass burning and biogenic sources of SOA in model agreement with observations.
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Li, Xinyi, Zhuoyue Ren, Xiangyu Zhang, Xiaodie Pang, Wei Song, Yanli Zhang, and Xinming Wang. "Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results." Atmosphere 15, no. 2 (February 6, 2024): 204. http://dx.doi.org/10.3390/atmos15020204.
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α-Pinene is a biogenic volatile organic compound (BVOC) that significantly contributes to secondary organic aerosols (SOA) in the atmosphere due to its high emission rate, reactivity, and SOA yield. However, the SOA yield measured in chamber studies from α-pinene photooxidation is limited in a purified air matrix. Assessing SOA formation from α-pinene photooxidation in real urban ambient air based on studies conducted in purified air matrices may be subject to uncertainties. In this study, α-pinene photooxidation and SOA yield were investigated in a smog chamber in the presence of NO and SO2 under purified air and ambient air matrices. With the accumulation of ozone (O3) during the photooxidation, an increasing part of α-pinene was consumed by O3 and finally nearly half of the α-pinene was oxidized by O3, facilitating the production of highly oxidized organic molecules and thereby SOA formation. Although the ambient air we introduced as matrix air was largely clean, with initial organic aerosol mass concentrations of ~1.5 μg m−3, the α-pinene SOA yield in the ambient air matrix was 42.3 ± 5.3%, still higher than that of 32.4 ± 0.4% in the purified air matrix. The chemical characterization of SOA by the high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) revealed that CxHy accounted for 53.7 ± 1.1% of the total signal in the ambient air matrix experiments, higher than 48.1 ± 0.3% in the purified air, while CxHyO and CxHyO>1 together constituted 45.0 ± 0.9% in the ambient air matrix, lower than 50.1 ± 1.0% in the purified air. The O:C ratio in the ambient air matrix experiments was 0.41 ± 0.01, lower than 0.46 ± 0.01 in the purified air. The higher SOA yield of α-pinene in the ambient air matrix compared to that in the purified air matrix was partly due to the presence of initial aerosols in the ambient air, which facilitated the low volatile organic compounds produced from photochemical oxidation to enter the aerosol phase through gas-particle partitioning. The in-situ aerosol acidity calculated by the ISORROPIA-II model in the ambient air matrix experiments was approximately six times higher than that in purified air, and the higher SOA yield in the ambient air matrix experiments might also be attributed to acid-catalyzed SOA formation.
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Stern, Yonatan, Danny Koren, Renana Moebus, Gabriella Panishev, and Roy Salomon. "Assessing the Relationship between Sense of Agency, the Bodily-Self and Stress: Four Virtual-Reality Experiments in Healthy Individuals." Journal of Clinical Medicine 9, no. 9 (September 11, 2020): 2931. http://dx.doi.org/10.3390/jcm9092931.
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The bodily-self, our experience of being a body, arises from the interaction of several processes. For example, embodied Sense of Agency (SoA), the feeling of controlling our body’s actions, is a fundamental facet of the bodily-self. SoA is disturbed in psychosis, with stress promoting its inception. However, there is little knowledge regarding the relationship between SoA, stress, and other facets of the bodily-self. In four experiments manipulating embodied SoA using a virtual hand (VH), we examined (1) How is embodied SoA related to other facets of the bodily-self?; and (2) How is SoA impacted by stress? We found that increased alteration of the VH significantly decreased subjective ratings of SoA and body ownership (Exp. 1), supporting the close relation between SoA and body ownership. Interoceptive accuracy and SoA were positively correlated (Exp. 3), connecting awareness to one’s actions and cardiac signals. Contrary to our expectations, SoA was not related to trait anxiety (Exp. 3), nor did induced stress impair SoA (Exp. 4). Finally, we found a negative correlation between self-reported prodromal symptoms and SoA. These results strongly support the connection between SoA and the bodily-self. Whereas, SoA was not impaired by stress, and weakly related to psychotic symptoms.
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Spracklen, D. V., J. L. Jimenez, K. S. Carslaw, D. R. Worsnop, M. J. Evans, G. W. Mann, Q. Zhang, et al. "Aerosol mass spectrometer constraint on the global secondary organic aerosol budget." Atmospheric Chemistry and Physics 11, no. 23 (December 7, 2011): 12109–36. http://dx.doi.org/10.5194/acp-11-12109-2011.
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Abstract. The budget of atmospheric secondary organic aerosol (SOA) is very uncertain, with recent estimates suggesting a global source of between 12 and 1820 Tg (SOA) a−1. We used a dataset of aerosol mass spectrometer (AMS) observations from 34 different surface locations to evaluate the GLOMAP global chemical transport model. The standard model simulation (which included SOA from monoterpenes only) underpredicted organic aerosol (OA) observed by the AMS and had little skill reproducing the variability in the dataset. We simulated SOA formation from biogenic (monoterpenes and isoprene), lumped anthropogenic and lumped biomass burning volatile organic compounds (VOCs) and varied the SOA yield from each precursor source to produce the best overall match between model and observations. We assumed that SOA is essentially non-volatile and condenses irreversibly onto existing aerosol. Our best estimate of the SOA source is 140 Tg (SOA) a−1 but with a large uncertainty range which we estimate to be 50–380 Tg (SOA) a−1. We found the minimum in normalised mean error (NME) between model and the AMS dataset when we assumed a large SOA source (100 Tg (SOA) a−1) from sources that spatially matched anthropogenic pollution (which we term antropogenically controlled SOA). We used organic carbon observations compiled by Bahadur et al. (2009) to evaluate our estimated SOA sources. We found that the model with a large anthropogenic SOA source was the most consistent with these observations, however improvement over the model with a large biogenic SOA source (250 Tg (SOA) a−1) was small. We used a dataset of 14C observations from rural locations to evaluate our estimated SOA sources. We estimated a maximum of 10 Tg (SOA) a−1 (10 %) of the anthropogenically controlled SOA source could be from fossil (urban/industrial) sources. We suggest that an additional anthropogenic source is most likely due to an anthropogenic pollution enhancement of SOA formation from biogenic VOCs. Such an anthropogenically controlled SOA source would result in substantial climate forcing. We estimated a global mean aerosol direct effect of −0.26 ± 0.15 Wm−2 and indirect (cloud albedo) effect of −0.6+0.24−0.14 Wm−2 from anthropogenically controlled SOA. The biogenic and biomass SOA sources are not well constrained with this analysis due to the limited number of OA observations in regions and periods strongly impacted by these sources. To further improve the constraints by this method, additional OA observations are needed in the tropics and the Southern Hemisphere.
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Spracklen, D. V., J. L. Jimenez, K. S. Carslaw, D. R. Worsnop, M. J. Evans, G. W. Mann, Q. Zhang, et al. "Aerosol mass spectrometer constraint on the global secondary organic aerosol budget." Atmospheric Chemistry and Physics Discussions 11, no. 2 (February 16, 2011): 5699–755. http://dx.doi.org/10.5194/acpd-11-5699-2011.
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Abstract. The budget of atmospheric secondary organic aerosol (SOA) is very uncertain, with recent estimates suggesting a global source of between 12 and 1820 Tg (SOA) a−1. We used a dataset of aerosol mass spectrometer (AMS) observations and a global chemical transport model including aerosol microphysics to produce top-down constraints on the SOA budget. We treated SOA formation from biogenic (monoterpenes and isoprene), lumped anthropogenic and lumped biomass burning volatile organic compounds (VOCs) and varied the SOA yield from each precursor source to produce the best overall match between model and observations. Organic aerosol observations from the IMPROVE network were used as an independent check of our optimised sources. The optimised model has a global SOA source of 140 ± 90 Tg (SOA) a−1 comprised of 13 ± 8 Tg (SOA) a−1 from biogenic, 100 ± 60 Tg (SOA) a−1 from anthropogenically controlled SOA, 23 ± 15 Tg (SOA) a−1 from conversion of primary organic aerosol (mostly from biomass burning) to SOA and an additional 3 ± 3 Tg (SOA) a−1 from biomass burning VOCs. Compared with previous estimates, our optimized model has a substantially larger SOA source in the Northern Hemisphere mid-latitudes. We used a dataset of 14C observations from rural locations to estimate that 10 Tg (SOA) a−1 (10%) of our anthropogenically controlled SOA is of urban/industrial origin, with 90 Tg (SOA) a−1 (90%) most likely due to an anthropogenic pollution enhancement of SOA from biogenic VOCs, almost an order-of-magnitude beyond what can be explained by current understanding. The urban/industrial SOA source is consistent with the 13 Tg a−1 estimated by de Gouw and Jimenez (2009), which was much larger than estimates from previous studies. The anthropogenically controlled SOA source results in a global mean aerosol direct effect of −0.26 ± 0.15 Wm−2 and global mean indirect (cloud albedo) effect of −0.6+0.24−0.14 Wm−2. The biogenic and biomass SOA sources are not well constrained due to the limited number of OA observations in regions and periods strongly impacted by these sources. To further improve the constraints by this method, additional observations are needed in the tropics and the Southern Hemisphere.
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Karl, M., K. Tsigaridis, E. Vignati, and F. Dentener. "Formation of secondary organic aerosol from isoprene oxidation over Europe." Atmospheric Chemistry and Physics 9, no. 18 (September 22, 2009): 7003–30. http://dx.doi.org/10.5194/acp-9-7003-2009.
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Abstract. The role of isoprene as a precursor to secondary organic aerosol (SOA) over Europe is studied with the two-way nested global chemistry transport model TM5. The inclusion of the formation of SOA from isoprene oxidation in our model almost doubles the atmospheric burden of SOA over Europe compared to SOA formation from terpenes and aromatics. The reference simulation, which considers SOA formation from isoprene, terpenes and aromatics, predicts a yearly European production rate of 1.0 Tg SOA yr−1 and an annual averaged atmospheric burden of about 50 Gg SOA over Europe. A fraction of 35% of the SOA produced in the boundary layer over Europe is transported to higher altitudes or to other world regions. Summertime measurements of organic matter (OM) during the extensive EMEP OC/EC campaign 2002/2003 are better reproduced when SOA formation from isoprene is taken into account, reflecting also the strong seasonality of isoprene and other biogenic volatile organic compounds (BVOC) emissions from vegetation. However, during winter, our model strongly underestimates OM, likely caused by missing wood burning in the emission inventories. Uncertainties in the parameterisation of isoprene SOA formation have been investigated. Maximum SOA production is found for irreversible sticking (non-equilibrium partitioning) of condensable vapours on particles, with tropospheric SOA production over Europe increased by a factor of 4 in summer compared to the reference case. Completely neglecting SOA formation from isoprene results in the lowest estimate (0.51 Tg SOA yr−1). The amount and the nature of the absorbing matter are shown to be another key uncertainty when predicting SOA levels. Consequently, smog chamber experiments on SOA formation should be performed with different types of seed aerosols and without seed aerosols in order to derive an improved treatment of the absorption of SOA in the models. Consideration of a number of recent insights in isoprene SOA formation mechanisms reduces the tropospheric production of isoprene derived SOA over Europe from 0.4 Tg yr−1 in our reference simulation to 0.1 Tg yr−1.
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Nakao, S., Y. Liu, P. Tang, C. L. Chen, J. Zhang, and D. Cocker III. "Role of glyoxal in SOA formation from aromatic hydrocarbons: gas-phase reaction trumps reactive uptake." Atmospheric Chemistry and Physics Discussions 11, no. 11 (November 15, 2011): 30599–625. http://dx.doi.org/10.5194/acpd-11-30599-2011.
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Abstract. This study evaluates the significance of glyoxal acting as an intermediate species leading to SOA formation from aromatic hydrocarbon photooxidation under humid conditions. Rapid SOA formation from glyoxal uptake onto aqueous (NH4)2SO4 seed particles is observed; however, glyoxal did not partition to SOA or SOA coated aqueous seed during all aromatic hydrocarbon experiments (RH up to 80%). Glyoxal is found to only influence SOA formation by raising hydroxyl (OH) radical concentrations. Four experimental approaches supporting this conclusion are presented in this paper: (1) increased SOA formation and decreased SOA volatility in the toluene + NOx photooxidation system with additional glyoxal was reproduced by matching OH radical concentrations through H2O2 addition; (2) glyoxal addition to SOA seed formed from toluene + NOx photooxidation did not increase observed SOA volume; (3) SOA formation from toluene + NOx photooxidation with and without deliquesced (NH4)2SO4 seed resulted in similar SOA growth, consistent with a coating of SOA preventing glyoxal uptake onto deliquesced (NH4)2SO4 seed; and (4) the fraction of a C4H9+ fragment (observed by Aerodyne High Resolution Time-of-Flight Aerosol Mass Spectrometer, HR-ToF-AMS) from SOA formed by 2-tert-butylphenol (BP) oxidation was unchanged in the presence of additional glyoxal despite enhanced SOA formation. This study suggests that glyoxal uptake onto aerosol is minor when the surface (and near-surface) of aerosols are primarily composed of secondary organic compounds.
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Mitra, Kalyan, Harsh Raj Mishra, Xiangyu Pei, and Ravi Kant Pathak. "Secondary Organic Aerosol (SOA) from Photo-Oxidation of Toluene: 1 Influence of Reactive Nitrogen, Acidity and Water Vapours on Optical Properties." Atmosphere 13, no. 7 (July 13, 2022): 1099. http://dx.doi.org/10.3390/atmos13071099.
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Many climate models treat the light-absorbing SOA component called “brown carbon” (BrC) as non-light absorbing because its formation and transformations are poorly understood. We therefore investigated the influence of reactive nitrogen (NOx, NH3)-, acidity (H2SO4)-, and water-mediated chemistry on SOA formed by the photo-oxidation of toluene, the subsequent formation and transformation of BrC, and its optical properties. We discovered that nitrogen-poor (NP) SOA is formed when the molar ratio of NOx to reacted toluene (henceforth, [NOx/ΔHC]) is 0.15 or less, whereas nitrogen-rich (NR) SOA is formed when [NOx/ΔHC] > 0.15. NR and NP SOA have markedly different characteristics. The light absorption coefficient (Babs) and mass absorption cross-section (MAC) of the SOA increased with [NOx/ΔHC] under both the NP and NR regimes. For NP SOA, the MAC increased with [NOx/ΔHC] independently of the relative humidity (RH). However, the MAC of NR SOA was RH-dependent. Under both NP and NR regimes, acidity promoted SOA browning while NH3 increased Babs and MAC at 80% RH. The highest MAC was observed at the lowest RH (20%) for acidic NR SOA, and it was postulated that the MAC of SOA depends mainly on the pH and the [H+]free/[SOA mass] ratio of the aqueous SOA phase.
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Djamal, Syuryani. "PERUBAHAN TATA RUANG KOTA KERAJAAN TIDORE." Jurnal Penelitian dan Karya Ilmiah Arsitektur Usakti 14, no. 2 (December 1, 2014): 12. http://dx.doi.org/10.25105/agora.v14i2.2034.
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<p>Tata ruang kota kerajaan Tidore terbentuk (dibentuk) berdasarkan sembilan Soa yaitu Soa kolano,<br />Soa sibumabelo, Soa mafu, Soa Jawa, Soa Yaba, Soa Kalaodi, Soa Failuku, Soa Rora, dan Soa<br />Cina. Soa dalam etimologi Tidore disebut kampung/desa/kabila/marga dan Sembilan disebut Sio,<br />karena kota kerajaan terbentuk berdasarkan sembilan Soa maka kawasan kota kerajaan Tidore<br />(K3T) kemudian disebut dengan sebutan Soasio yang berarti sembilan<br />kampung/desa/kabila/marga. Seiring perkembangannya, elemen kota sebagai identitas kota<br />kerajaan Tidore seperti pola permukiman masyarakat yang dibentuk berdasarkan kelompok kabila<br />(Soa) dan pola tata masa yang memiliki pagar pembatas, gerbang di depan rumah sebagai penanda<br />keberadaan komunitas masyarakat menjadi hilang dan tak dapat dipertahankan. Oleh karena itu,<br />penelitian ini dilakukan untuk menemukan, memahami, dan mengetahui faktor-faktor apa saja<br />yang mempengaruhi perubahan tata ruang kota kerajaan Tidore, bagaimana proses terjadinya<br />perubahan tata ruang kota kerajaan Tidore, dan elemen-elemen kota apa saja yang tetap dan yang<br />berubah pada tata ruang kota kerajaan Tidore.<br />Kata kunci: Tata Ruang, Kota, Kerajaan, Tidore</p>
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Im, Y., M. Jang, and R. L. Beardsley. "Simulation of aromatic SOA formation using the lumping model integrated with explicit gas-phase kinetic mechanisms and aerosol-phase reactions." Atmospheric Chemistry and Physics 14, no. 8 (April 23, 2014): 4013–27. http://dx.doi.org/10.5194/acp-14-4013-2014.
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Abstract. The Unified Partitioning-Aerosol phase Reaction (UNIPAR) model has been developed to predict the secondary organic aerosol (SOA) formation through multiphase reactions. The model was evaluated with aromatic SOA data produced from the photooxidation of toluene and 1,3,5-trimethylbenzene (135-TMB) under various concentrations of NOx and SO2 using an outdoor reactor (University of Florida Atmospheric PHotochemical Outdoor Reactor (UF-APHOR) chamber). When inorganic species (sulfate, ammonium and water) are present in aerosol, the prediction of both toluene SOA and 135-TMB SOA, in which the oxygen-to-carbon (O : C) ratio is lower than 0.62, are approached under the assumption of a complete organic/electrolyte-phase separation below a certain relative humidity. An explicit gas-kinetic model was employed to express gas-phase oxidation of aromatic hydrocarbons. Gas-phase products are grouped based on their volatility (6 levels) and reactivity (5 levels) and exploited to construct the stoichiometric coefficient (αi,j) matrix, the set of parameters used to describe the concentrations of organic compounds in multiphase. Weighting of the αi,j matrix as a function of NOx improved the evaluation of NOx effects on aromatic SOA. The total amount of organic matter (OMT) is predicted by two modules in the UNIPAR model: OMP by a partitioning process and OMAR by aerosol-phase reactions. The OMAR module predicts multiphase reactions of organic compounds, such as oligomerization, acid-catalyzed reactions, and organosulfate (OS) formation. The model reasonably simulates SOA formation under various aerosol acidities, NOx concentrations, humidities and temperatures. Furthermore, the OS fractions in the SOA predicted by the model were in good agreement with the experimentally measured OS fractions.
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Karl, M., K. Tsigaridis, E. Vignati, and F. Dentener. "Formation of secondary organic aerosol from isoprene oxidation over Europe." Atmospheric Chemistry and Physics Discussions 9, no. 1 (January 29, 2009): 2855–915. http://dx.doi.org/10.5194/acpd-9-2855-2009.
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Abstract. The role of isoprene as a precursor to secondary organic aerosol (SOA) over Europe is studied with the two-way nested global chemistry transport model TM5. The inclusion of the formation of SOA from isoprene oxidation in our model almost doubles the atmospheric burden of SOA over Europe compared to SOA formation from terpenes and aromatics. The reference simulation, which considers SOA formation from isoprene, terpenes and aromatics, predicts a yearly European production rate of 1.0 Tg SOA yr−1 and an annual averaged atmospheric burden of about 50 Gg SOA over Europe. A fraction of 35% of the SOA produced in the boundary layer over Europe is transported to higher altitudes or to other world regions. Summertime measurements of particulate organic matter (POM) during the extensive EMEP OC/EC campaign 2002/2003 are better reproduced when SOA formation from isoprene is taken into account, reflecting also the strong seasonality of isoprene and other biogenic volatile organic compounds (BVOC) emissions from vegetation. However, during winter, our model strongly underestimates POM, likely caused by missing wood burning in the emission inventories. Uncertainties in the parameterisation of isoprene SOA formation have been investigated. Maximum SOA production is found for irreversible sticking (non-equilibrium partitioning) of condensable vapours on particles, with tropospheric SOA production over Europe increased by a factor of 4 in summer compared to the reference case. Completely neglecting SOA formation from isoprene results in the lowest estimate (0.51 Tg SOA yr−1). The amount and the nature of the absorbing matter are shown to be another key uncertainty when predicting SOA levels. Tropospheric isoprene SOA production over Europe in summer more than doubles when, in addition to pre-existing carbonaceous aerosols, condensation of semi volatile vapours on ammonium and sulphate aerosols is considered. Consequently, smog chamber experiments on SOA formation should be performed with different types of seed aerosols and without seed aerosols in order to derive an improved treatment of the absorption of SOA in the models. Consideration of a number of recent insights in isoprene SOA formation mechanisms reduces the tropospheric production of isoprene derived SOA over Europe from 0.4 Tg yr−1 in our reference simulation to 0.1 Tg yr−1.
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INOUE, MASASHI, XIA LI, STUART A. McCAUGHEY, GARY K. BEAUCHAMP, and ALEXANDER A. BACHMANOV. "Soa genotype selectively affects mouse gustatory neural responses to sucrose octaacetate." Physiological Genomics 5, no. 4 (April 27, 2001): 181–86. http://dx.doi.org/10.1152/physiolgenomics.2001.5.4.181.
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In mice, behavioral acceptance of the bitter compound sucrose octaacetate (SOA) depends on allelic variation of a single gene, Soa. The SW.B6- Soabcongenic mouse strain has the genetic background of an “SOA taster” SWR/J strain and an Soa-containing donor chromosome fragment from an “SOA nontaster” C57BL/6J strain. Using microsatellite markers polymorphic between the two parental strains, we determined that the donor fragment spans 5–10 cM of distal chromosome 6. The SWR/J mice avoided SOA in two-bottle tests with water and had strong responses to SOA in two gustatory nerves, the chorda tympani (CT) and glossopharyngeal (GL). In contrast, the SW.B6- Soab mice were indifferent to SOA in two-bottle tests and had very weak responses to SOA in both of these nerves. The SWR/J and SW.B6- Soab mice did not differ in responses of either nerve to sucrose, NaCl, HCl, or the bitter-tasting stimuli quinine, denatonium, strychnine, 6- n-propylthiouracil, phenylthiocarbamide, and MgSO4. Thus the effect of the Soa genotype on SOA avoidance is mediated by peripheral taste responsiveness to SOA, involving taste receptor cells innervated by both the CT and GL nerves.
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Yuningsih, Lulu, Delfy Lensari, and Alam Piande. "EFFEKTIFITAS ZAT PERANGSANG TUMBUH TERHADAP PERTUMBUHAN STEK BATANG BALIK ANGIN (Mollotus paniculatus)." Sylva: Jurnal Ilmu-ilmu Kehutanan 8, no. 2 (August 12, 2020): 66. http://dx.doi.org/10.32502/sylva.v8i2.2698.
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Potensi sumber energi kita yang ada di negara Indonesia semakin hari semakin menipis yang disebabkan diambil secara terus menerus. Sumber energi yang berasal dari fosil ini jika kita ambil secara terus-menerus akan habis dan tidak bisa terbaharukan. Oleh karena itu perlu adanya altarnatif sumber energi yang bisa diperbaharui, salah satunya energi yang bisa diperbaharui untuk menggantikan energi fosil, adalah biomasa kayu. Salah satu Kayu yang bisa di jadikan sumber energi yang bisa diperbaharui adalah kayu Balik Angin (Mollotus paniculatus). Balik Angin (Mollotus paniculatus) merupakan jenis pohon teduhan yang dapat tumbuh di hutan gugur dan hijau sepanjang tahun. Permasalahan yang ada pada perbanyakan tanaman secara generatif untuk tanaman Balik Angin adalah benih hanya bisa didapat pada musim-musim tertentu saja, sehingga perlu adanya dilakukan penelitian perbanyakan tanaman secara vegetatif salah satunya stek batang. Penelitian ini bertujuan untuk mengetahui tingkat efektifitas keberhasilan pertumbuhan stek batang Balik Angin (Mollotus paniculatus) dengan menggunakan berbagai konsentrasi zat pengatur tumbuh (Rootone F). Metode penelitian yang digunakan adalah kuantitatif dengan melakukan berbagai eksperimen perlakuan terhadap stek batang Balik Angin yaitu tidak diberi perlakuan S0K Tanpa perlakuan (0 ppm) S1K Perlakuan mengunakan hormon Rootone-f dengan konsentrasi (100 ppm), S2K Perlakuan mengunakan hormon Rootone-f dengan konsentrasi (200 ppm). Untuk tingkat pertumbuhan rata-rata pertumbuhan. Jumlah tunas perlakuan SOA (tanpa perlakuan) 1 tunas, S1A (100 ppm) 1 tunas S2A (200 ppm) 1 tunas. Panjang tunas perlakuan S0A (tanpa perlakuan) 2,83 cm, S1A (100 ppm) 1,72 cm, S2A(200 ppm) 0,23 cm. Jumlah jumlah perlakuan S0A (tanpa perlakuan) 2 helai,S1A (100 ppm) 1 helai, S2A (200 ppm) 1 helai. Presentase hidup perlakuan S0A ( tanpa perlakuan) 11,1 %, S1A (100 ppm) 25,5 % S2A (200 ppm) 4,44 %, panjang akar perlakuan S0A (tanpa perlakuan )0,421 cm, S1A (100ppm) 1,07 cm, S2A (200 ppm) 0,18 cm.
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Beardsley, Ross, Myoseon Jang, Baber Ori, Yunseok Im, Carrie A. Delcomyn, and Ned Witherspoon. "Role of sea salt aerosols in the formation of aromatic secondary organic aerosol: yields and hygroscopic properties." Environmental Chemistry 10, no. 3 (2013): 167. http://dx.doi.org/10.1071/en13016.
Full textAbstract:
Environmental context In the coastal and ocean environment, oil spills and ship movement can produce hazardous, organic aerosols. In this study, the role of sea salt in the formation processes of crude-oil-derived organic aerosols derived was explored, and it was found that sea salt can greatly increase the formation and growth of these toxic aerosols. Understanding of this process is crucial for evaluating the effect of oil spills and ship movements on air quality and human health. Abstract Dual, large (52m3), outdoor chambers were used to investigate the effect of aerosol aqueous phase chemistry on the secondary organic aerosol (SOA) yields of the photooxidation products of aromatic hydrocarbons in the coastal environment. Toluene and 1,3,5-trimethylbenzene were photochemically oxidised in the presence and absence of inorganic seeds (sea salt aerosol (SSA) or NaCl) at low NOx conditions. Overall, the presence of SSA, which was shown to contain water even at low relative humidities (RHs), led to higher SOA yields than the presence of NaCl seeds and the seedless condition. The results suggest that SOA yields in the coastal environment will be higher than those produced in terrestrial environment. To study the effect of SOA formation on the chemical composition of SSA, inorganic species were measured using a particle-into-liquid-sampler coupled to an ion chromatograph. The hygroscopic properties of the SSA internally mixed with SOA were analysed using a Fourier-transform infrared spectrometer. The fresh SSA shows a weak phase transition whereas no clear phase transition appeared in the aged SSA. The depletion of Cl– due to the accommodation of nitric acid and carboxylic acids on the surface of SSA coincides with changes in aerosol hygroscopic properties.