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Relevant bibliographies by topics / Ruthenium Metal Complexes

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Academic literature on the topic 'Ruthenium Metal Complexes'

Author: Grafiati

Published: 6 September 2023

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Journal articles on the topic "Ruthenium Metal Complexes"

1

Sava, Gianni, Sabrina Pacor, Francesca Bregant, Valentina Ceschia, and Giovanni Mestroni. "Metal complexes of ruthenium." Anti-Cancer Drugs 1, no. 2 (December 1990): 99–108. http://dx.doi.org/10.1097/00001813-199012000-00001.

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Phillips, Ian G., and Peter J. Steel. "Mono- and Bi-nuclear Complexes of the Doubly Bidentate, Bridging Ligand 4,6-Di(2-pyridyl)pyrimidine." Australian Journal of Chemistry 51, no. 5 (1998): 371. http://dx.doi.org/10.1071/c97127.

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Thirteen mononuclear, homobinuclear and heterobinuclear transition metal complexes of 4,6-di(2- pyridyl)pyrimidine have been prepared. Assignments of the 1H n.m.r. spectra of the molybdenum(0) and ruthenium(II) complexes were achieved by a combination of one- and two-dimensional n.m.r. techniques, especially 1D-TOCSY. For the ruthenium complexes, electronic absorption spectroscopy and cyclic voltammetry were used to probe the nature of the metal{ligand and, for the binuclear complexes, metal-metal interactions. The complexes have low HOMO−LUMO energy gaps. Meta-metal interactions are shown to be of similar magnitude to those in complexes of the better-studied ligands 2,2′-bipyrimidine and 2,3-di(2-pyridyl)pyrazine.

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3

Gałczyńska, Katarzyna, Zuzanna Drulis-Kawa, and Michał Arabski. "Antitumor Activity of Pt(II), Ru(III) and Cu(II) Complexes." Molecules 25, no. 15 (July 31, 2020): 3492. http://dx.doi.org/10.3390/molecules25153492.

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Metal complexes are currently potential therapeutic compounds. The acquisition of resistance by cancer cells or the effective elimination of cancer-affected cells necessitates a constant search for chemical compounds with specific biological activities. One alternative option is the transition metal complexes having potential as antitumor agents. Here, we present the current knowledge about the application of transition metal complexes bearing nickel(II), cobalt(II), copper(II), ruthenium(III), and ruthenium(IV). The cytotoxic properties of the above complexes causing apoptosis, autophagy, DNA damage, and cell cycle inhibition are described in this review.

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Houbrechts, Stephan, Carlo Boutton, Koen Clays, André Persoons, Ian R. Whittall, Raina H. Naulty, Marie P. Cifuentes, and Mark G. Humphrey. "Novel Organometallic Compounds for Nonlinear Optics." Journal of Nonlinear Optical Physics & Materials 07, no. 01 (March 1998): 113–20. http://dx.doi.org/10.1142/s0218863598000090.

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Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel metal (ruthenium, nickel and gold) σ-arylacetylide complexes. The influence of the organometallic donor group and conjugating bridge on the quadratic hyperpolarizability is studied. For all organic ligands, the addition of the metal (donor) group is shown to increase the static hyperpolarizability by a factor of 2, 4 and 7 for gold, nickel and ruthenium complexes, respectively. Moreover, replacement of phenyl with a heterocyclic ring is demonstrated to enlarge the hyperpolarizability in the case of gold and ruthenium compounds.

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Voutyritsa, Errika, Ierasia Triandafillidi, Nikolaos V. Tzouras, Nikolaos F. Nikitas, Eleftherios K. Pefkianakis, Georgios C. Vougioukalakis, and Christoforos G. Kokotos. "Photocatalytic Atom Transfer Radical Addition to Olefins Utilizing Novel Photocatalysts." Molecules 24, no. 9 (April 26, 2019): 1644. http://dx.doi.org/10.3390/molecules24091644.

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Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common. Herein, we present the synthesis of two photoactive, ruthenium-based complexes bearing pyridine-quinoline or terpyridine ligands with extended aromatic conjugation. Our complexes were utilized in the atom transfer radical addition (ATRA) of haloalkanes to olefins, using bromoacetonitrile or bromotrichloromethane as the source of the alkyl group. The tailor-made ruthenium-based catalyst bearing the pyridine-quinoline bidentate ligand proved to be the best-performing photocatalyst, among a range of metal complexes and organocatalysts, efficiently catalyzing both reactions. These photocatalytic atom transfer protocols can be expanded into a broad scope of olefins. In both protocols, the photocatalytic reactions led to products in good to excellent isolated yields.

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Vatansever, Hafize Seda, Hilal Kabadayı, Mehmet Korkmaz, Feyzan Özdal-Kurt, Serdar Batıkan Kavukcu, and Hayati Türkmen. "Apoptotic Properties of Rutheinum Complexes on Different Type of Cancer Cell Lines." Proceedings 2, no. 25 (December 11, 2018): 1593. http://dx.doi.org/10.3390/proceedings2251593.

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Among chemotherapeutic agents, cisplatin and the other platinum-based drugs have occupied for 35 years an enviable position. The limitations of platinum-based drugs, dose dependent side effects and development of drug resistance mechanisms, have boosted the research for finding other metal-based drugs. Among metals, ruthenium is probably the one showing the greatest promises. Ruthenium (Ru) appears to be less toxic than platinum and several biological studies have indicated that ruthenium complexes possess diverse modes of action. The redox chemistry of ruthenium is rich and compatible with biological media, and the overall toxicity of ruthenium is lower than platinum, thus allowing higher doses of treatment. In this study we aimed that, analyses of different type of ruthenium complexes in cancer cell lines. Six Ru complexes were determined by elemental analysis, FTIR, NMR, UV-visible spectroscopy, electron density on the metal was measured by cyclic voltammetry. After that, the cellular properties of this complexes were analyses on PC-3, HT-29, Du-145 and Vero cell lines. DNA damage was analyzed H2AX staining, apoptotic cell analyses were performed flow cytometry and western blotting. After 48 h incubation of Ru complexes three of them more effective for cell lines. Especially Ru3 was more effective in cancer cell lines. Apoptotic pathway was triggered after Ru complexes incubation in PC-3, Du-145 and Ht-29 cancer cell lines. Our study suggest that Ru complexes may be used for cancer cell cytotoxicity as a drugs in patients.

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Vadivel, T., M. Dhamodaran, S. Kulathooran, M. Kavitha, and K. Amirthaganesan. "In Vitro Evaluation of Antifungal Activities by Permeation of Ru(III) Complexes Derived from Chitosan-Schiff Base Ligand." Current Applied Polymer Science 3, no. 3 (December 15, 2020): 212–20. http://dx.doi.org/10.2174/2452271603666191016130012.

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Background: The transition metal complexes are derived from a natural biopolymer which is a very potent material in various research areas of study. Objective: This study aims to show the preparation of ruthenium(III) complexes from chitosan Schiff base ligand for effective application in antifungal studies. Methods: Chemical modification was carried out through a condensation reaction of chitosan with some aromatic aldehydes, which resulted in the formation of a bidentate Schiff base ligand. The Ru(III) complexes were prepared by complexation of ruthenium metal ion with bidentate ligands. The series of Ru(III) complexes were characterized by Scanning Electron Microscope with Electron dispersive X-ray (SEM-EDX) analysis, Powder XRD. The biopolymer-based transition metal complexes have potential uses for their biological activities. The synthesized metal complexes were directed for antifungal study by the disc diffusion method. Results: The antifungal study results showed that the transition metal complexes have significant antifungal activities against some vital fungal pathogens such as Aspergillus flavus, Aspergillus niger, Fusarium oxysporum, Penicillim chryogenum and Trigoderma veride. Conclusion: A chitosan biopolymer offers some peculiar features such as biodegradability, biocompatibility etc., which are favorable for green synthesis of transition metal complexes through complexation with bidentate ligands. These metal complexes possess good antifungal property due to their chelation effect on micro-organisms.

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Enow, Charles A., Charlene Marais, and Barend C. B. Bezuidenhoudt. "Catalytic epoxidation of stilbenes with non-peripherally alkyl substituted carbonyl ruthenium phthalocyanine complexes." Journal of Porphyrins and Phthalocyanines 16, no. 04 (April 2012): 403–12. http://dx.doi.org/10.1142/s1088424612500459.

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A number of novel carbonyl(1,4,8,11,15,18,22,25-octaalkylphthalocyaninato)-ruthenium(II) complexes were prepared by metal insertion with Ru3(CO)12. The new compounds have been characterized by1H NMR,13C NMR, IR, UV-vis and mass spectroscopy. This study demonstrated that this type of complexes and specifically carbonyl(1,4,8,11,15,18,22,25-octahexylphthalo-cyaninato)ruthenium(II) and carbonyl[1,4,8,11,15,18,22,25-octa(2-cyclohexylethyl)phthalocyaninato]-ruthenium(II), exhibit high catalytic activity and stability in the epoxidation of stilbenes with 2,6-dichloropyridine N-oxide as oxidant.

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Motswainyana, William M., and Peter A. Ajibade. "Anticancer Activities of Mononuclear Ruthenium(II) Coordination Complexes." Advances in Chemistry 2015 (February 19, 2015): 1–21. http://dx.doi.org/10.1155/2015/859730.

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Ruthenium compounds are highly regarded as potential drug candidates. The compounds offer the potential of reduced toxicity and can be tolerated in vivo. The various oxidation states, different mechanism of action, and the ligand substitution kinetics of ruthenium compounds give them advantages over platinum-based complexes, thereby making them suitable for use in biological applications. Several studies have focused attention on the interaction between active ruthenium complexes and their possible biological targets. In this paper, we review several ruthenium compounds which reportedly possess promising cytotoxic profiles: from the discovery of highly active compounds imidazolium [trans-tetrachloro(dmso)(imidazole)ruthenate(III)] (NAMI-A), indazolium [trans-tetrachlorobis(1H-indazole)ruthenate(III)](KP1019), and sodium trans-[tetrachloridobis(1H-indazole)ruthenate(III)] (NKP-1339) to the recent work based on both inorganic and organometallic ruthenium(II) compounds. Half-sandwich organometallic ruthenium complexes offer the opportunity of derivatization at the arene moiety, while the three remaining coordination sites on the metal centre can be functionalised with various coordination groups of various monoligands. It is clear from the review that these mononuclear ruthenium(II) compounds represent a strongly emerging field of research that will soon culminate into several ruthenium based antitumor agents.

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Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

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The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's iron-sulfur-nitrosyl cluster anionsFe2S2(NO)42−andFe4S3(NO)7−and several ruthenium salen and porphyrin nitrosyls. These include studies using metal-nitrosyl photochemistry as a vehicle for delivering NO to hypoxic cell cultures in order to sensitizeγ-radiation damage. Also studied were the rates and mechanisms of NO “on” reactions with model water soluble heme compounds, the ferriheme protein met-myoglobin and various ruthenium complexes using ns laser flash photolysis techniques. An overview of these studies is presented.

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Dissertations / Theses on the topic "Ruthenium Metal Complexes"

1

Barthram, Anita Marie. "Metal-metal interactions in polynuclear complexes of ruthenium and osmium." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326683.

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Greguric, Ivan. "Molecular recognition of DNA by metal co-ordination complexes /." [Campbelltown, N.S.W.] : University of Western Sydney, Macarthur, Faculty of Informatics, Science and Technology, 1999. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030624.114833/index.html.

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Morewood, Catherine Alexandra. "π-complexes of osmium and ruthenium organometallic clusters." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/272792.

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Luther, Thomas Alan. "Dicationic dihydrogen complexes of osmium and ruthenium /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/11540.

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Wong, Chun-yuen. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Click to view the E-thesis via HKUTO, 2004. http://sunzi.lib.hku.hk/hkuto/record/B31040858.

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Stuart, Clare Anne. "Reactions of ruthenium(II) diphosphine complexes with silver(I) salts." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366948.

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7

Humphrey, Paul Andrew. "A study of transition metal complexes /." Title page, contents and summary only, 1990. http://web4.library.adelaide.edu.au/theses/09PH/09phh9262.pdf.

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Wong, Chun-yuen, and 黃駿弦. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31040858.

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9

Vanover, Eric. "Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes." TopSCHOLAR®, 2012. http://digitalcommons.wku.edu/theses/1201.

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In nature, transition metal containing enzymes display many biologically important, attractive and efficient catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely, the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions, such as the hydroxylation of alkanes. The present work focuses on photocatalytic studies of aerobic oxidation reactions with well characterized ruthenium porphyrin complexes. The photocatalytic studies of aerobic oxidation reactions of hydrocarbons The photocatalytic studies of aerobic oxidation reactions of hydrocarbons catalyzed by a bis-porphyrin-ruthenium(IV) μ-oxo dimer using atmospheric oxygen as the oxygen source in the absence of co-reductants were investigated. The ruthenium(IV) μ-oxo bisporphyrin (3a-d) was found to catalyze aerobic oxidation of a variety of organic substrates efficiently. By comparison, 3d was found to be a more efficient photocatalyst than the well-known 3a under identical conditions. A KIE at 298K was found to be larger than those observed in autoxidation processes, suggesting a nonradical mechanism that involved the intermediacy of ruthenium(V)-oxo species as postulated. The reactivity order in the series of ruthenium(IV) μ-oxo bisporphyrin complexes follows TPFPP>4- CF3TPP>TPP, and is consistent with expectations based on the electrophilic nature of the ruthenium(IV) μ-oxo bisporphyrin species. The trans-dioxoruthenium(VI) porphyrins have been among the best characterized metal-oxo intermediates and their involvement as the active oxidant in the hydrocarbon oxidation have been extensively studied. In addition to the well-known chemical methods, we developed a novel approach for generation of trans-dioxoruthenium( VI) porphyrins with visible light by extension of the known photoinduced ligand cleavage reactions. A series of trans-dioxoruthenium(VI) porphyrin complexes (6a-d) were photochemically synthesized and spectroscopically characterized by UV-vis, and 1H-NMR.

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Guest, Ruth Winifred. "Synthesis and reactions of iron and rutheniuim dinitrogen complexes." Connect to full text, 2008. http://ses.library.usyd.edu.au/handle/2123/3533.

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Thesis (Ph. D.)--University of Sydney, 2008.
Includes tables. Includes list of publications: leaves i-ii. Title from title screen (viewed October 30, 2008). Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy to the School of Chemistry, Faculty of Science. Includes bibliographical references. Also available in print form.

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Books on the topic "Ruthenium Metal Complexes"

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Baulieu, Etienne, Donald T. Forman, Magnus Ingelman-Sundberg, Lothar Jaenicke, John A. Kellen, Yoshitaka Nagai, Georg F. Springer, Lothar Träger, Liane Will-Shahab, and James L. Wittliff, eds. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1.

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E, Alessio, Clarke M. J, Società chimica italiana, Università degli studi di Trieste., and Symposium on Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy., eds. Ruthenium and other non-platinum metal complexes in cancer chemotherapy. Berlin: Spriger Verlag, 1989.

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Kellen, John A., Etienne Baulieu, Lothar Jaenicke, Donald T. Forman, Magnus Ingelman-Sundberg, Yashitaka Nagai, Georg F. Springer, Lothar Träger, Liane Will-Shahab, and James L. Wittliff. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer, 2011.

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4

Hinman, Justin Grant. Acidity of neutral transition metal polyhydride complexes and the study of anionic rhenium and ruthenium polyhydride dimers. 2001.

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Progress in Clinical Biochemistry and Medicine: Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy (Progress in Clinical Bioche). Springer, 1989.

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6

Trace, Rhonda. A new synthetic methodology applied to the preparation of some novel, alkyl substituted, cyclic carbene complexes of ruthenium, tungsten, and rhenium. 1991.

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Cundari, Thomas R. Molecular orbital investigations of metal-oxo catalyzed oxidations. 1990.

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Goldstein, Alan S. Catalytic oxidations of organic substrates by transition metal salts. 1991.

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Book chapters on the topic "Ruthenium Metal Complexes"

1

Bullock, Jimmie L., and Alvin A. Holder. "Photodynamic Therapy in Medicine with Mixed-Metal/Supramolecular Complexes." In Ruthenium Complexes, 139–60. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527695225.ch7.

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2

Mlodnicka, Teresa, and Brian R. James. "Oxidations Catalyzed by Ruthenium Porphyrins." In Catalysis by Metal Complexes, 121–48. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_4.

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3

Roper, W. R. "Carbyne Complexes of Ruthenium and Osmium." In Transition Metal Carbyne Complexes, 155–68. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_20.

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Griffith, William P. "The Chemistry of Ruthenium Oxidation Complexes." In Catalysis by Metal Complexes, 1–134. Dordrecht: Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-1-4020-9378-4_1.

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Farrell, Nicholas. "Metal Complexes as Radiosensitizers." In Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy, 89–109. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1_5.

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Süss-Fink, Georg. "Multicenter Ligand Transformations of Tetramethyl-Thiourea on Ruthenium Clusters." In Transition Metal Carbyne Complexes, 151–53. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_19.

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Chan, P. K. L., K. A. Skov, B. R. James, and N. P. Farrell. "Studies on Ruthenium Nitroimidazoles Complexes as Radiosensitizers." In Platinum and Other Metal Coordination Compounds in Cancer Chemotherapy, 638–42. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4613-1717-3_70.

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Braunstein, Pierre, Jacky Rose, and David C. Busby. "Stepwise Syntheses of Ruthenium Mixed-Metal Cluster Complexes." In Inorganic Syntheses, 356–60. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch64.

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Lentzen, Olivier, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker. "44Ru Perspectives of Ruthenium Complexes in Cancer Therapy." In Metallotherapeutic Drugs and Metal-Based Diagnostic Agents, 359–78. Chichester, UK: John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470864052.ch19.

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Ezhova, Maria B., and Brian R. James. "Catalytic oxidations using ruthenium porphyrins." In Advances in Catalytic Activation of Dioxygen by Metal Complexes, 1–77. Boston, MA: Springer US, 2003. http://dx.doi.org/10.1007/0-306-47816-1_1.

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Conference papers on the topic "Ruthenium Metal Complexes"

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Rebane, Aleksander K., Charles Stark, Juri Pahapill, Alexander Mikhaylov, and Matt Rammo. "Probing metal-to-ligand charge transfer transitions in ruthenium complexes by quantitative two-photon absorption spectroscopy." In Organic Photonic Materials and Devices XX, edited by Christopher E. Tabor, François Kajzar, Toshikuni Kaino, and Yasuhiro Koike. SPIE, 2018. http://dx.doi.org/10.1117/12.2290363.

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Záliš, S., R. S. Winter, M. Linseis, A. Kaim, B. Sarkar, I. Kratochvílová, George Maroulis, and Theodore E. Simos. "DFT modeling of Spectral and Redox Properties of Di-and Tetranuclear Ruthenium Transition Metal Complexes with Bridging Ligands." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Advances in Computational Science: Lectures presented at the International Conference on Computational Methods in Sciences and Engineering 2008 (ICCMSE 2008). AIP, 2009. http://dx.doi.org/10.1063/1.3225297.

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Murtaza, Zakir, and Joseph R. Lakowicz. "Lifetime-based sensing of glucose using luminescent ruthenium (II) metal complex." In BiOS '99 International Biomedical Optics Symposium, edited by Joseph R. Lakowicz, Steven A. Soper, and Richard B. Thompson. SPIE, 1999. http://dx.doi.org/10.1117/12.347552.

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Cantrel, Laurent, Thierry Albiol, Loïc Bosland, Juliette Colombani, Frédéric Cousin, Anne-Cécile Grégoire, Olivia Leroy, et al. "IRSN R&D Actions on FP Behaviour for RCS, Containment and FCVS in Severe Accident Conditions." In 2016 24th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icone24-61104.

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This paper deals with near past, ongoing and planned R&D works on fission products (FPs) behaviour in Reactor Cooling System (RCS), containment building and in Filtered Containment Venting Systems (FCVS) for severe accident (SA) conditions. For the last topic, in link with the Fukushima post-accident management and possible improvement of mitigation actions for such SA, the FCVS topic is again on the agenda (see Status Report on Filtered Containment Venting, OECD/NEA/CSNI, Report NEA/CSNI/R(2014)7, 2014.) with a large interest at the international scale. All the researches are collaborative works; the overall objective is to develop confident models to be implemented in ASTEC SA simulation software. After being initiated in the International Source Term Program (ISTP), researches devoted to the understanding of iodine transport through the RCS are still ongoing in the frame of a bilateral agreement between IRSN and EDF with promising results. In 2017, a synthesis report of the last 10 years of researches, which have combined experimental and fundamental works based on the use of theoretical chemistry tools, will be issued. For containment, the last advances are linked to the Source Term Evaluation and Mitigation (STEM) OECD/NEA project operated by IRSN. The objective of the STEM project was to improve the evaluation of Source Term (ST) for a SA on a nuclear power plant and to reduce uncertainties on specific phenomena dealing with the chemistry of two major fission products: iodine and ruthenium. More precisely, the STEM project provided additional knowledge and improvements for calculation tools in order to allow a more robust diagnosis and prognosis of radioactive releases in a SA. STEM data will be completed by a follow-up, called STEM2, to further the knowledge concerning some remaining issues and be closer to reactor conditions. Two additional programmes deal with FCVS issues: the MItigation of outside Releases in the Environment (MIRE) (2013–2019) French National Research Agency (NRA) programme and the Passive and Active Systems on Severe Accident source term Mitigation (PASSAM) (2013–2016) European project. For FCVS works, the efficiencies for trapping iodine with various FCVS, covering scrubbers and dry filters, are examined to get a clear view of their abilities in SA conditions. Another part, performed in collaboration with French universities (Lorraine and Lille 1), is focused on the enhancement of the performance of these filters with specific porous materials able to trap volatile iodine. For that, influence of zeolites materials parameters (nature of the counter-ions, structure, Si/Al ratio …) will be tested. New kind of porous materials constituted by Metal organic Frameworks (MOF) will also be looked at because they can constitute a promising way of trapping.

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