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Journal articles on the topic 'RUDDLESDEN-POPPER STRUCTURE'

Author: Grafiati

Published: 26 June 2021

Last updated: 10 March 2023

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1

Tian, Jiyu, Eli Zysman-Colman, and Finlay D. Morrison. "Azetidinium Lead Halide Ruddlesden–Popper Phases." Molecules 26, no. 21 (October 27, 2021): 6474. http://dx.doi.org/10.3390/molecules26216474.

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A family of Ruddlesden–Popper (n = 1) layered perovskite-related phases, Az2PbClxBr4−x with composition 0 ≤ x ≤ 4 were obtained using mechanosynthesis. These compounds are isostructural with K2NiF4 and therefore adopt the idealised n = 1 Ruddlesden–Popper structure. A linear variation in unit cell volume as a function of anion average radius is observed. A tunable bandgap is achieved, ranging from 2.81 to 3.43 eV, and the bandgap varies in a second-order polynomial relationship with the halide composition.

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2

Urushihara, Daisuke, Kenta Nakajima, Ariki Nakamura, Koichiro Fukuda, Hodaka Sugai, Shinya Konishi, Katsuhisa Tanaka, and Toru Asaka. "Unique octahedral rotation pattern in the oxygen-deficient Ruddlesden–Popper compound Gd3Ba2Fe4O12." Acta Crystallographica Section C Structural Chemistry 77, no. 6 (May 26, 2021): 286–90. http://dx.doi.org/10.1107/s2053229621005258.

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A novel Ruddlesden–Popper-related compound, Gd3Ba2Fe4O12, was discovered and its crystal structure was determined via single-crystal X-ray diffraction. The structure has an ordered structure of octahedra and pyramids along the c axis. Gd3Ba2Fe4O12 belongs to the tetragonal system P42/ncm, with a = 5.59040 (10) Å and c = 35.1899 (10) Å. The A-site ions in the Ruddlesden–Popper structure, i.e. Gd3+ and Ba2+, exhibit an ordering along the c axis. The perfect oxygen deficiency is accommodated at the GdO layers in the proper Ruddlesden–Popper structure. Using the bond-valence-sum method, the Fe ions in the FeO6 octahedra and FeO5 pyramids represent valence states of +3 and +2.5, respectively, demonstrating a two-dimensional charge disproportionation. The corner-sharing FeO6 octahedra and FeO5 pyramids are tilted in opposite directions, with the neighbours around one axis of the simple perovskite configuration, which, using Glazer's notation, can be represented as a − b 0 c 0/b 0 a − c 0. In the perovskite blocks, the facing FeO5 pyramids across the Gd layer rotate in the same sense, which is a unique rotation feature related to oxygen deficiency.

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3

Song, Jia, De Ning, Bernard Boukamp, Jean-Marc Bassat, and Henny J. M. Bouwmeester. "Structure, electrical conductivity and oxygen transport properties of Ruddlesden–Popper phases Lnn+1NinO3n+1 (Ln = La, Pr and Nd; n = 1, 2 and 3)." Journal of Materials Chemistry A 8, no. 42 (2020): 22206–21. http://dx.doi.org/10.1039/d0ta06731h.

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4

Gareeva, Zukhra, Anatoly Zvezdin, Konstantin Zvezdin, and Xiangming Chen. "Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics." Materials 15, no. 2 (January 13, 2022): 574. http://dx.doi.org/10.3390/ma15020574.

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In this article, we performed symmetry analysis of perovskite-based multiferroics: bismuth ferrite (BiFeO3)-like, orthochromites (RCrO3), and Ruddlesden–Popper perovskites (Ca3Mn2O7-like), being the typical representatives of multiferroics of the trigonal, orthorhombic, and tetragonal crystal families, and we explored the effect of crystallographic distortions on magnetoelectric properties. We determined the principal order parameters for each of the considered structures and obtained their invariant combinations consistent with the particular symmetry. This approach allowed us to analyze the features of the magnetoelectric effect observed during structural phase transitions in BixR1−xFeO3 compounds and to show that the rare-earth sublattice has an impact on the linear magnetoelectric effect allowed by the symmetry of the new structure. It was shown that the magnetoelectric properties of orthochromites are attributed to the couplings between the magnetic and electric dipole moments arising near Cr3+ ions due to distortions linked with rotations and deformations of the CrO6 octahedra. For the first time, such a symmetry consideration was implemented in the analysis of the Ruddlesden–Popper structures, which demonstrates the possibility of realizing the magnetoelectric effect in the Ruddlesden–Popper phases containing magnetically active cations, and allows the estimation of the conditions required for its optimization.

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5

Tomkiewicz, Alex C., Mazin Tamimi, Ashfia Huq, and Steven McIntosh. "Oxygen transport pathways in Ruddlesden–Popper structured oxides revealed via in situ neutron diffraction." Journal of Materials Chemistry A 3, no. 43 (2015): 21864–74. http://dx.doi.org/10.1039/c5ta04193g.

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In situ neutron diffraction techniques were utilized to provide detailed information about the crystal structure of n = 1, n = 2, and n = 3 Ruddlesden–Popper structures focusing on the oxygen transport pathways created by localization of oxygen vacancies.

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6

HAUCK, J., and K. MIKA. "STRUCTURAL RELATION BETWEEN SUPERCONDUCTING OXIDES, AURIVILLIUS PHASES ANDRUDDLESDEN-POPPER PHASES." International Journal of Modern Physics B 07, no. 19 (August 30, 1993): 3423–33. http://dx.doi.org/10.1142/s0217979293003309.

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The Ruddlesden-Popper phases can be described as a stacking of v or v′ CaTiO 3 and w or w′ MO structural units with bcc M lattice and O at octahedral interstices. 50% of all octahedral interstices in the bcc M lattice are occupied in CaTiO 3, 33% in MO. The Aurivillius phases can be derived as complementary structures with an occupation of the 67% vacant sites of MO leading to MO 2 units similar to the CaF 2 structure. 14 different structures are obtained as combinations of up to 8 v and w units. The structures can also be described by the sequence of coordination numbers of metal atoms with respect to oxygen. The superconducting phases known so far are with different donor elements: e + for Ruddlesden-Popper phases and e – for Aurivillius phases.

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7

Yang, Chao, Yi Wang, Daniel Putzky, Wilfried Sigle, Hongguang Wang, Roberto A. Ortiz, Gennady Logvenov, Eva Benckiser, Bernhard Keimer, and Peter A. van Aken. "Ruddlesden–Popper Faults in NdNiO3 Thin Films." Symmetry 14, no. 3 (February 25, 2022): 464. http://dx.doi.org/10.3390/sym14030464.

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The NdNiO3 (NNO) system has attracted a considerable amount of attention owing to the discovery of superconductivity in Nd0.8Sr0.2NiO2. In rare-earth nickelates, Ruddlesden–Popper (RP) faults play a significant role in functional properties, motivating our exploration of its microstructural characteristics and the electronic structure. Here, we employed aberration-corrected scanning transmission electron microscopy and spectroscopy to study a NdNiO3 film grown by layer-by-layer molecular beam epitaxy (MBE). We found RP faults with multiple configurations in high-angle annular dark-field images. Elemental intermixing occurs at the SrTiO3–NdNiO3 interface and in the RP fault regions. Quantitative analysis of the variation in lattice constants indicates that large strains exist around the substrate–film interface. We demonstrate that the Ni valence change around RP faults is related to a strain and structure variation. This work provides insights into the microstructure and electronic-structure modifications around RP faults in nickelates.

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8

Barone, Matthew R., Myoungho Jeong, Nicholas Parker, Jiaxin Sun, Dmitri A. Tenne, Kiyoung Lee, and Darrell G. Schlom. "Synthesis of metastable Ruddlesden–Popper titanates, (ATiO₃)_nAO, with n ≥ 20 by molecular-beam epitaxy." APL Materials 10, no. 9 (September 1, 2022): 091106. http://dx.doi.org/10.1063/5.0101202.

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We outline a method to synthesize ( ATiO3) n AO Ruddlesden–Popper phases with high- n, where the A-site is a mixture of barium and strontium, by molecular-beam epitaxy. The precision and consistency of the method described is demonstrated by the growth of an unprecedented (SrTiO3)50SrO epitaxial film. We proceed to investigate barium incorporation into the Ruddlesden–Popper structure, which is limited to a few percent in bulk, and we find that the amount of barium that can be incorporated depends on both the substrate temperature and the strain state of the film. At the optimal growth temperature, we demonstrate that as much as 33% barium can homogeneously populate the A-site when films are grown on SrTiO3 (001) substrates, whereas up to 60% barium can be accommodated in films grown on TbScO3 (110) substrates, which we attribute to the difference in strain. This detailed synthetic study of high n, metastable Ruddlesden–Popper phases is pertinent to a variety of fields from quantum materials to tunable dielectrics.

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9

Putri, Yulia Eka, Hamsal Yusri, Hamsal Yusri, Zulhadjri, and Zulhadjri. "STUDI HANTARAN LISTRIK SENYAWA SRN+1TINO3N+1 (N = 1 DAN 2) FASA RUDDLESDEN-POPPER YANG DISINTESIS DENGAN METODE LELEHAN GARAM." Jurnal Riset Kimia 8, no. 2 (March 19, 2015): 176. http://dx.doi.org/10.25077/jrk.v8i2.237.

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Srn+1TinO3n+1 (n = 1, 2,...n)Ruddlesden-Popper phase is a metal oxide compound with a layered structure consisting of SrTiO3 perovskite layers and strontium oxide (SrO) layers, thus this material has a potential as termoeletrik compounds that could be developed as an alternative material for renewable energy. In this study, we examine one of the 3 parameters of termoelectric properties, namely the electrical conductivity. Srn+1TinO3n+1 (n = 1 and 2)Ruddlesden-Popper phases were synthesized using molten salt method. The synthesis was carried out at 950 °C for 10 hours with a ratio of precursor and salt were 1: 0.5. Structural analysis by X-Ray Diffractometer (XRD) confirmed that all synthesized compounds formed Srn+1TinO3n+1 (n = 1, and 2) Ruddlesden-Popper phase with the characteristic peaks at 2q = 31o, 32o, and 46o. The morphology analysis by Scanning Electron Microscope (SEM) showed that the particles have plate-shaped with crystallites size were 20 nm. The electrical properties were measured using LCR meter with the highest electrical conductivity of 2.25x10-7 S / cm which showed the semiconductors behaviour.

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10

Arabpour Roghabadi, Farzaneh, Maryam Alidaei, Seyede Maryam Mousavi, Tahereh Ashjari, Ali Shokrolahzadeh Tehrani, Vahid Ahmadi, and Seyed Mojtaba Sadrameli. "Stability progress of perovskite solar cells dependent on the crystalline structure: From 3D ABX3 to 2D Ruddlesden–Popper perovskite absorbers." Journal of Materials Chemistry A 7, no. 11 (2019): 5898–933. http://dx.doi.org/10.1039/c8ta10444a.

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This review presents the progress of the change of the PSK structure from 3 dimensional CH₃NH₃PbX₃ to mixed cations or halides based PSKs and finally to Ruddlesden–Popper PSK two dimensional (2D) homologous structures regarding the lifetime improvement.

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11

Liang, Jianghu, Zhanfei Zhang, Qi Xue, Yiting Zheng, Xueyun Wu, Ying Huang, Xin Wang, Chaochao Qin, Zhenhua Chen, and Chun-Chao Chen. "A finely regulated quantum well structure in quasi-2D Ruddlesden–Popper perovskite solar cells with efficiency exceeding 20%." Energy & Environmental Science 15, no. 1 (2022): 296–310. http://dx.doi.org/10.1039/d1ee01695d.

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A record power conversion efficiency of 20.1% is achieved for quasi-2D Ruddlesden–Popper perovskite solar cells. The quantum wells are reversely graded in the film, and the quantum confinement effect inside the film is significantly weakened.

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12

Cortecchia, D., S. Neutzner, J. Yin, T. Salim, A. R. Srimath Kandada, A. Bruno, Y. M. Lam, J. Martí-Rujas, A. Petrozza, and C. Soci. "Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites." APL Materials 6, no. 11 (November 2018): 114207. http://dx.doi.org/10.1063/1.5045782.

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13

Greenblatt, M. "Ruddlesden-Popper Lnn+1NinO3n+1 nickelates: structure and properties." Current Opinion in Solid State and Materials Science 2, no. 2 (April 1997): 174–83. http://dx.doi.org/10.1016/s1359-0286(97)80062-9.

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14

Pan, Yiyi, Haoliang Wang, Xiaoguo Li, Xin Zhang, Fengcai Liu, Meng Peng, Zejiao Shi, et al. "Detection range extended 2D Ruddlesden–Popper perovskite photodetectors." Journal of Materials Chemistry C 8, no. 10 (2020): 3359–66. http://dx.doi.org/10.1039/c9tc06109f.

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Two-dimensional (2D) perovskite materials are a promising platform to construct high performance photodetectors due to their novel structure, high stability, resistance to ion migration and decent light harvesting ability.

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15

Chen, Wei-Tin, Chris Ablitt, Nicholas C. Bristowe, Arash A. Mostofi, Takashi Saito, Yuichi Shimakawa, and Mark S. Senn. "Negative thermal expansion in high pressure layered perovskite Ca2GeO4." Chemical Communications 55, no. 20 (2019): 2984–87. http://dx.doi.org/10.1039/c8cc09614g.

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We report the high pressure synthesis of a layered perovskite Ca₂GeO₄ which is found to have the Ruddlesden–Popper structure with I4₁/acd symmetry, and to display pronounced uniaxial negative thermal expansion.

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16

Yao, Yunpeng, Bo Kou, Yu Peng, Zhenyue Wu, Lina Li, Sasa Wang, Xinyuan Zhang, Xitao Liu, and Junhua Luo. "(C3H9NI)4AgBiI8: a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption." Chemical Communications 56, no. 21 (2020): 3206–9. http://dx.doi.org/10.1039/c9cc07796k.

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A new iodide layered double perovskite (C₃H₉NI)₄AgBiI₈ (IPAB) has been developed based on a short-chain spacer cation, which is the first homologous compound in iodide double perovskites that adopt the Ruddlesden–Popper structure type.

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17

Zhang, Wenrui, Alessandro R. Mazza, Elizabeth Skoropata, Debangshu Mukherjee, Brianna Musico, Jie Zhang, Veerle M. Keppens, et al. "Applying Configurational Complexity to the 2D Ruddlesden–Popper Crystal Structure." ACS Nano 14, no. 10 (September 15, 2020): 13030–37. http://dx.doi.org/10.1021/acsnano.0c04487.

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18

Abdulaeva, Liliya, Oleg Silyukov, Irina Zvereva, and Yu Petrov. "Soft Chemistry Synthesis of Complex Oxides Using Protonic Form of Titanates HLnTiO₄ (Ln=La, Nd)." Solid State Phenomena 194 (November 2012): 213–16. http://dx.doi.org/10.4028/www.scientific.net/ssp.194.213.

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In the present work protonic forms of layered n=1 Ruddlesden-Popper oxides HLnTiO4 (Ln=La, Nd) were used as starting point for synthesis of three series of the perovskite-like compounds. Characterization by SEM, powder XRD and TGA has been performed for the determination of the structure and composition of synthesized oxides.

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19

Гареева, З. В., А. К. Звездин, Н. В. Шульга, Т. Т. Гареев, and С. М. Чен. "Механизмы магнитоэлектрических эффектов в оксидных мультиферроиках с прафазой перовскита." Физика твердого тела 64, no. 9 (2022): 1338. http://dx.doi.org/10.21883/ftt.2022.09.52830.43hh.

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Magnetoelectric effects are discussed in multiferroics with the perovskite structure: bismuth ferrite, rare-earth orthochromites, and Ruddlesden - Popper structures belonging to the trigonal, orthorhombic, and tetragonal syngonies. The influence of structural distortions on magnetic and ferroelectric properties is studied, possible magnetoelectric effects (linear, quadratic, inhomogeneous) in these materials are determined, and expressions for the linear magnetoelectric effect tensor are given. Macroscopic manifestations of the inhomogeneous magnetoelectric effect in multiferroic nanoelements are considered.

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20

Gareeva Z. V., Zvezdin A. K., Shulga N. V., Gareev T. T., and Chen X. M. "Mechanisms of magnetoelectric effects in oxide multiferroics with a perovskite praphase." Physics of the Solid State 64, no. 9 (2022): 1324. http://dx.doi.org/10.21883/pss.2022.09.54175.43hh.

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Magnetoelectric effects are discussed in multiferroics with the perovskite structure: bismuth ferrite, rare-earth orthochromites, and Ruddlesden--Popper structures belonging to the trigonal, orthorhombic, and tetragonal syngonies. The influence of structural distortions on magnetic and ferroelectric properties is studied, possible magnetoelectric effects (linear, quadratic, inhomogeneous) in these materials are determined, and expressions for the linear magnetoelectric effect tensor are given. Macroscopic manifestations of the inhomogeneous magnetoelectric effect in multiferroic nanoelements are considered. Keywords: multiferroics, magnetoelectric effect, perovskites, symmetry.

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21

Markovski, Mishel R., Dmitri O. Charkin, Oleg I. Siidra, and Diana O. Nekrasova. "Copper hydroselenite nitrates (A+NO3)n [Cu(HSeO3)2] (A=Rb+, Cs+ and Tl+, n=1, 2) related to Ruddlesden – Popper phases." Zeitschrift für Kristallographie - Crystalline Materials 234, no. 11-12 (December 18, 2019): 749–56. http://dx.doi.org/10.1515/zkri-2019-0036.

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AbstractThree new layered copper hydrogen selenite nitrates, (ANO3)[Cu(HSeO3)2] (A = Cs, and Tl), and (RbNO3)2[Cu(HSeO3)2] have been prepared via isothermal evaporation of concentrated nitric acid solutions. The Tl and Cs compounds adopt a motif related to previously known (NH4Cl)[Cu(HSeO3)2]; the structure of the Rb compound represents a new structure type. The structures of (ANO3)[Cu(HSeO3)2] (A = Cs, Tl), (RbNO3)2[Cu(HSeO3)2], and (NH4NO3)3[Cu(HSeO3)2] form a unique homological series distantly related to Ruddlesden – Popper series of layered perovskites.

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22

Tobías, G., J. Oró-Solé, D. Beltrán-Porter, and A. Fuertes. "Synthesis and crystal structure of novel Ruddlesden–Popper strontium niobium oxynitrides." Crystal Engineering 5, no. 3-4 (September 2002): 479–85. http://dx.doi.org/10.1016/s1463-0184(02)00059-x.

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23

Tarasova, N., and I. Animitsa. "Protonic transport in oxyfluorides Ba2InO3F and Ba3In2O5F2 with Ruddlesden–Popper structure." Solid State Ionics 275 (July 2015): 53–57. http://dx.doi.org/10.1016/j.ssi.2015.03.025.

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24

Tobías, Gerard, Daniel Beltrán-Porter, Oleg I. Lebedev, Gustaaf Van Tendeloo, Juan Rodríguez-Carvajal, and Amparo Fuertes. "Anion Ordering and Defect Structure in Ruddlesden−Popper Strontium Niobium Oxynitrides." Inorganic Chemistry 43, no. 25 (December 2004): 8010–17. http://dx.doi.org/10.1021/ic049236k.

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25

Battle, Peter D., and Matthew J. Rosseinsky*. "Synthesis, structure, and magnetic properties of n=2 Ruddlesden–Popper manganates." Current Opinion in Solid State and Materials Science 4, no. 2 (April 1999): 163–70. http://dx.doi.org/10.1016/s1359-0286(99)00012-1.

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26

GREENBLATT, M. "ChemInform Abstract: Ruddlesden-Popper Lnn+1NinO3n+1 Nickelates: Structure and Properties." ChemInform 28, no. 36 (August 3, 2010): no. http://dx.doi.org/10.1002/chin.199736287.

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27

Teranishi, Takashi, Sachi Takezawa, Kenji Toda, Hironori Ishikawa, Kenji Sato, Kazuyoshi Uematsu, and Mineo Sato. "Superconductivity of Layered Perovskite Synthesized by Soft Chemistry." Key Engineering Materials 350 (October 2007): 163–66. http://dx.doi.org/10.4028/www.scientific.net/kem.350.163.

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Reduced niobates, MLixCa2Nb3O10 (M = Rb, K and Na) and KNaxCa2Nb3O10 were synthesized by intercalation reaction with n-butyllithium or sodium azide. Ruddlesden-Popper type structure of sodium intercalation compound, KNaCa2Nb3O10, differ from that of the parent compound and lithium intercalation compound, KLiCa2Nb3O10. The magnetic susceptibility measurements showed that the sodium intercalation compound became superconductor with transition temperatures below 3.5 K. New lithium intercalation compound Na0.1Li0.8Ca2.45Nb3O10, for an ion exchange compound, Na0.1Ca2.45Nb3O10, with KCa2Nb3O10 type structure show the diamagnetic signals below 5 K.

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Titova, Yuriy A., Nadegda N. Belyavina, Mikola S. Slobodyanik, Olesya I. Nakonechna, and Nataliia Y. Strutynska. "Effect of size factor on the Ruddlesden-Popper single-slab compounds structure features." French-Ukrainian Journal of Chemistry 7, no. 1 (2019): 10–15. http://dx.doi.org/10.17721/fujcv7i1p10-15.

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Character of influence of the strontium atoms replacement by smaller atoms of calcium on structure features of the Ruddlesden-Popper (Sr,Ca)LaScO4 (A2BO4) single-slab compoundis established. Structure of phase with a maximum degree of replacementhas determined by the Rietveld method. It is shown that such type of substitution increases a degree of AO9 interblock polyhedra deformation, mutual inclination of the BO6 octahedra and a decrease of A - О interblock bond. Presence of structure changes is the precondition for regulation of structural-dependent features of the materials on the base of scandates alkaline-earth and rare earth metals.

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Tarasova, Nataliia, Anzhelika Galisheva, Irina Animitsa, Daniil Korona, Hala Kreimesh, and Irina Fedorova. "Protonic Transport in Layered Perovskites BaLanInnO3n+1 (n = 1, 2) with Ruddlesden-Popper Structure." Applied Sciences 12, no. 8 (April 18, 2022): 4082. http://dx.doi.org/10.3390/app12084082.

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The work focused on the layered perovskite-related materials as the potential electrolytic components of such devices as proton conducting solid oxide fuel cells for the area of clean energy. The two-layered perovskite BaLa2In2O7 with the Ruddlesden–Popper structure was investigated as a protonic conductor for the first time. The role of increasing the amount of perovskite blocks in the layered structure on the ionic transport was investigated. It was shown that layered perovskites BaLanInnO3n+1 (n = 1, 2) demonstrate nearly pure protonic conductivity below 350 °C.

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30

Liebendorfer, Adam. "New links found between structure of Ruddlesden-Popper perovskites and optoelectronic properties." Scilight 2018, no. 48 (November 26, 2018): 480001. http://dx.doi.org/10.1063/1.5081127.

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31

Huang, Liang-Feng, Nathan Z. Koocher, Mingqiang Gu, and James M. Rondinelli. "Structure Dependent Phase Stability and Thermal Expansion of Ruddlesden–Popper Strontium Titanates." Chemistry of Materials 30, no. 20 (September 26, 2018): 7100–7110. http://dx.doi.org/10.1021/acs.chemmater.8b02944.

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32

Sarjeant, Gregory M., Kevin B. Greenwood, Kenneth R. Poeppelmeier, Hong Zhang, Paul A. Salvador, Thomas O. Mason, and Laurence D. Marks. "Synthesis and Structure of LaSr2CuTiO6.5: A New Oxygen-Deficient Ruddlesden−Popper Phase." Chemistry of Materials 8, no. 12 (January 1996): 2792–98. http://dx.doi.org/10.1021/cm960279b.

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33

Xiang, Guangbiao, Yanwen Wu, Yushuang Li, Chen Cheng, Jiancai Leng, and Hong Ma. "Structural and Optoelectronic Properties of Two-Dimensional Ruddlesden–Popper Hybrid Perovskite CsSnBr3." Nanomaterials 11, no. 8 (August 20, 2021): 2119. http://dx.doi.org/10.3390/nano11082119.

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Ultrathin inorganic halogenated perovskites have attracted attention owing to their excellent photoelectric properties. In this work, we designed two types of Ruddlesden–Popper hybrid perovskites, Csn+1SnnBr3n+1 and CsnSnn+1Br3n+2, and studied their band structures and band gaps as a function of the number of layers (n = 1–5). The calculation results show that Csn+1SnnBr3n+1 has a direct bandgap while the bandgap of CsnSnn+1Br3n+2 can be altered from indirect to direct, induced by the 5p-Sn state. As the layers increased from 1 to 5, the bandgap energies of Csn+1SnnBr3n+1 and CsnSnn+1Br3n+2 decreased from 1.209 to 0.797 eV and 1.310 to 1.013 eV, respectively. In addition, the optical absorption of Csn+1SnnBr3n+1 and CsnSnn+1Br3n+2 was blue-shifted as the structure changed from bulk to nanolayer. Compared with that of Csn+1SnnBr3n+1, the optical absorption of CsnSnn+1Br3n+2 was sensitive to the layers along the z direction, which exhibited anisotropy induced by the SnBr2-terminated surface.

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34

Tarasova, Nataliia, Irina Animitsa, and Anzhelika Galisheva. "Novel Proton-Conducting Oxygen-Deficient Complex Oxides: Synthesis, Hydration Processes, Transport Properties." Materials Science Forum 998 (June 2020): 209–14. http://dx.doi.org/10.4028/www.scientific.net/msf.998.209.

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The complex oxide BaLaIn0.9Nb0.1O4.1 with Ruddlesden-Popper structure was obtained for the first time. It was found that the introduction of niobium into indium sublattice leads to the increase in the cell volume. Hydration processes and electrical properties have been investigated. For BaLaIn0.9Nb0.1O4.1 it was proved the capability for water uptake and the appearance of proton current carriers. It was established that niobium doping leads to the increase of conductivity compared to undoped composition BaLaInO4 at ~1 order of magnitude in whole temperature range.

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Battle, Peter D., Stephen J. Blundell, Amalia I. Coldea, Edmund J. Cussen, Matthew J. Rosseinsky, John Singleton, Lauren E. Spring, and Jaap F. Vente. "Crystal structure and electronic properties of Ca4Mn2TiO9.93, an n = 3 Ruddlesden-Popper compound." Journal of Materials Chemistry 11, no. 1 (2001): 160–67. http://dx.doi.org/10.1039/b003189p.

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Khvostova, L. V., N. E. Volkova, L. Ya Gavrilova, and V. A. Cherepanov. "Crystal structure, oxygen nonstoichiometry and properties of novel Ruddlesden-Popper phase Sm1.8Sr1.2Fe2O7-δ." Materials Letters 213 (February 2018): 158–61. http://dx.doi.org/10.1016/j.matlet.2017.11.041.

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Poltavets, Viktor V., Konstantin A. Lokshin, Takeshi Egami, and Martha Greenblatt. "The oxygen deficient Ruddlesden–Popper La3Ni2O7−δ (δ=0.65) phase: Structure and properties." Materials Research Bulletin 41, no. 5 (May 2006): 955–60. http://dx.doi.org/10.1016/j.materresbull.2006.01.028.

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Sirikanda, Nuansaeng, Hiroshige Matsumoto, and Tatsumi Ishihara. "Effect of Co doping on oxygen permeation in Sr3Ti2O7 with Ruddlesden-Popper structure." Solid State Ionics 192, no. 1 (June 2011): 599–601. http://dx.doi.org/10.1016/j.ssi.2010.04.018.

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Fawcett, Ian D., Sunstrom, Martha Greenblatt, Mark Croft, and K. V. Ramanujachary. "Structure, Magnetism, and Properties of Ruddlesden−Popper Calcium Manganates Prepared from Citrate Gels." Chemistry of Materials 10, no. 11 (November 1998): 3643–51. http://dx.doi.org/10.1021/cm980380b.

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McClure, Eric T., Abigail P. McCormick, and Patrick M. Woodward. "Four Lead-free Layered Double Perovskites with the n = 1 Ruddlesden–Popper Structure." Inorganic Chemistry 59, no. 9 (April 23, 2020): 6010–17. http://dx.doi.org/10.1021/acs.inorgchem.0c00009.

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Nishimoto, Shunsuke, Motohide Matsuda, Stefanus Harjo, Akinori Hoshikawa, Takashi Kamiyama, Toru Ishigaki, and Michihiro Miyake. "Structure determination of n=1 Ruddlesden–Popper compound HLaTiO4 by powder neutron diffraction." Journal of the European Ceramic Society 26, no. 4-5 (January 2006): 725–29. http://dx.doi.org/10.1016/j.jeurceramsoc.2005.07.001.

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Yan, J., M. Greenblatt, A. Sahiner, D. Sills, and M. Croft. "Ruddlesden-Popper zirconium sulfides—a novel preparation method and characterization of electronic structure." Journal of Alloys and Compounds 229, no. 1 (October 1995): 216–22. http://dx.doi.org/10.1016/0925-8388(95)01678-3.

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Zhang, Fei, So Yeon Park, Canglang Yao, Haipeng Lu, Sean P. Dunfield, Chuanxiao Xiao, Soňa Uličná, et al. "Metastable Dion-Jacobson 2D structure enables efficient and stable perovskite solar cells." Science 375, no. 6576 (January 7, 2022): 71–76. http://dx.doi.org/10.1126/science.abj2637.

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Abstract:

Directing efficient hole transport Surface defects in three-dimensional perovskites can decrease performance but can be healed with coatings based on two-dimensional (2D) perovskite such as Ruddlesden-Popper phases. However, the bulky organic groups of these 2D phases can lead to low and anisotropic charge transport. F. Zhang et al . show that a metastable polymorph of a Dion-Jacobson 2D structure based on asymmetric organic molecules reduced the energy barrier for hole transport and their transport through the layer. When used as a top layer for a triple-cation mixed-halide perovskite, a solar cell retained 90% of its initial power conversion efficiency of 24.7% after 1000 hours of operation at approximately 40°C in nitrogen. —PDS

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Sher, Falak, A. J. Williams, A. Venimadhev, Mark G. Blamire, and J. Paul Attfield. "Synthesis, Structure, and Properties of Two New Ruddlesden−Popper Phase Analogues of SFMO (Sr2FeMoO6)." Chemistry of Materials 17, no. 7 (April 2005): 1792–96. http://dx.doi.org/10.1021/cm0479178.

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Matvejeff, M., M. Lehtimäki, A. Hirasa, Y. H. Huang, H. Yamauchi, and M. Karppinen. "New Water-Containing Phase Derived from the Sr3Fe2O7-δPhase of the Ruddlesden−Popper Structure." Chemistry of Materials 17, no. 10 (May 2005): 2775–79. http://dx.doi.org/10.1021/cm050106z.

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Zibouche, Nourdine, and M. Saiful Islam. "Structure–Electronic Property Relationships of 2D Ruddlesden–Popper Tin- and Lead-based Iodide Perovskites." ACS Applied Materials & Interfaces 12, no. 13 (March 11, 2020): 15328–37. http://dx.doi.org/10.1021/acsami.0c03061.

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Tarasova, N., I. Animitsa, A. Galisheva, and V. Pryakhina. "Protonic transport in the new phases BaLaIn0.9M0.1O4.05 (M=Ti, Zr) with Ruddlesden-Popper structure." Solid State Sciences 101 (March 2020): 106121. http://dx.doi.org/10.1016/j.solidstatesciences.2020.106121.

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Bhuvanesh, N. S. P., M. P. Crosnier-Lopez, O. Bohnke, J. Emery, and J. L. Fourquet. "Synthesis, Crystal Structure, and Ionic Conductivity of Novel Ruddlesden−Popper Related Phases, Li4Sr3Nb5.77Fe0.23O19.77and Li4Sr3Nb6O20." Chemistry of Materials 11, no. 3 (March 1999): 634–41. http://dx.doi.org/10.1021/cm980736j.

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Nirala, Gurudeo, Dharmendra Yadav, and Shail Upadhyay. "Ruddlesden-Popper phase A2BO4 oxides: Recent studies on structure, electrical, dielectric, and optical properties." Journal of Advanced Ceramics 9, no. 2 (March 26, 2020): 129–48. http://dx.doi.org/10.1007/s40145-020-0365-x.

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Tarasova, N., I. Animitsa, and A. Galisheva. "Electrical properties of new protonic conductors Ba1 + хLa1–хInO4–0.5х with Ruddlesden-Popper structure." Journal of Solid State Electrochemistry 24, no. 7 (May 21, 2020): 1497–508. http://dx.doi.org/10.1007/s10008-020-04630-1.

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