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Relevant bibliographies by topics / Rhodium iii complexes

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Academic literature on the topic 'Rhodium iii complexes'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Rhodium iii complexes"

1

Hill, Angela M., William Levason, and Michael Webster. "Rhodium(III) ditertiary stibine complexes." Inorganica Chimica Acta 271, no. 1-2 (April 1998): 203–6. http://dx.doi.org/10.1016/s0020-1693(97)05908-2.

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Belyaev, A. V., S. V. Tkachev, and S. N. Vorob’eva. "Photoactivation of Rhodium(III) Complexes." Journal of Structural Chemistry 61, no. 2 (February 2020): 238–46. http://dx.doi.org/10.1134/s0022476620020080.

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Albert Cotton, F., Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello, Kang Seong-Joo, Andrew C. Price, and Mark G. Verbruggen. "Bis(diphenylphosphino)methane complexes of rhodium(III) halides as synthons for dinuclear rhodium(III) complexes." Inorganica Chimica Acta 184, no. 1 (June 1991): 35–42. http://dx.doi.org/10.1016/s0020-1693(00)83042-x.

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Bakac, Andreja. "Aqueous rhodium(iii) hydrides and mononuclear rhodium(ii) complexes." Dalton Transactions, no. 13 (2006): 1589. http://dx.doi.org/10.1039/b518230a.

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Pošta, Martin, Jan Čermák, Pavel Vojtíšek, Jan Sýkora, and Ivana Císařová. "Diphosphinoazine rhodium(III) and iridium(III) octahedral complexes." Inorganica Chimica Acta 362, no. 1 (January 2009): 208–16. http://dx.doi.org/10.1016/j.ica.2008.03.080.

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Skibsted, L. H. "Photoisomerization of rhodium(III) amine complexes." Coordination Chemistry Reviews 64 (May 1985): 343–59. http://dx.doi.org/10.1016/0010-8545(85)80059-x.

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Máliková, Klaudia, Lukáš Masaryk, and Pavel Štarha. "Anticancer Half-Sandwich Rhodium(III) Complexes." Inorganics 9, no. 4 (April 8, 2021): 26. http://dx.doi.org/10.3390/inorganics9040026.

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Platinum-based anticancer drugs are most likely the most successful group of bioinorganic compounds. Their apparent disadvantages have led to the development of anticancer compounds of other noble metals, resulting in several ruthenium-based drugs which have entered clinical trials on oncological patients. Besides ruthenium, numerous rhodium complexes have been recently reported as highly potent antiproliferative agents against various human cancer cells, making them potential alternatives to Pt- and Ru-based metallodrugs. In this review, half-sandwich Rh(III) complexes are overviewed. Many representatives show higher in vitro potency than and different mechanisms of action (MoA) from the conventional anticancer metallodrugs (cisplatin in most cases) or clinically studied Ru drug candidates. Furthermore, some of the reviewed Rh(III) arenyl complexes are also anticancer in vivo. Pioneer anticancer organorhodium compounds as well as the recent advances in the field are discussed properly, and adequate attention is paid to their anticancer activity, solution behaviour and various processes connected with their MoA. In summary, this work summarizes the types of compounds and the most important biological results obtained in the field of anticancer half-sandwich Rh complexes.

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Fu, Li-Jie, Bo-Hsun An, Chih-Hsuan Chou, Chi-Min Chen, and Ching Tat To. "Base-promoted perfluoroalkylation of rhodium(iii) porphyrin complexes." Dalton Transactions 50, no. 28 (2021): 9949–57. http://dx.doi.org/10.1039/d1dt01118a.

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Yusenko, Kirill V., Aleksandr S. Sukhikh, Werner Kraus, and Sergey A. Gromilov. "Synthesis and Crystal Chemistry of Octahedral Rhodium(III) Chloroamines." Molecules 25, no. 4 (February 11, 2020): 768. http://dx.doi.org/10.3390/molecules25040768.

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Rhodium(III) octahedral complexes with amine and chloride ligands are the most common starting compounds for preparing catalytically active rhodium(I) and rhodium(III) species. Despite intensive study during the last 100 years, synthesis and crystal structures of rhodium(III) complexes were described only briefly. Some [RhClx(NH3)6-x] compounds are still unknown. In this study, available information about synthetic protocols and the crystal structures of possible [RhClx(NH3)6−x] octahedral species are summarized and critically analyzed. Unknown crystal structures of (NH4)2[Rh(NH3)Cl5], trans–[Rh(NH3)4Cl2]Cl⋅H2O, and cis–[Rh(NH3)4Cl2]Cl are reported based on high quality single crystal X-ray diffraction data. The crystal structure of [Rh(NH3)5Cl]Cl2 was redetermined. All available crystal structures with octahedral complexes [RhClx(NH3)6-x] were analyzed in terms of their packings and pseudo-translational sublattices. Pseudo-translation lattices suggest face-centered cubic and hexagonal closed-packed sub-cells, where Rh atoms occupy nearly ideal lattices.

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Geldmacher, Yvonne, Melanie Oleszak, and William S. Sheldrick. "Rhodium(III) and iridium(III) complexes as anticancer agents." Inorganica Chimica Acta 393 (December 2012): 84–102. http://dx.doi.org/10.1016/j.ica.2012.06.046.

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Dissertations / Theses on the topic "Rhodium iii complexes"

1

Pater, Boke Chan de. "Terpyridine complexes of rhodium (I, III)." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/70850.

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2

Goswami, Niranjan. "105Rh(III) complexes with acyclic tetrathioether ligands : potential radiotherapeutic agents /." free to MU campus, to others for purchase, 1996. http://wwwlib.umi.com/cr/mo/fullcit?p9812951.

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Karpin, George W. "Synthesis and Antimicrobial Activity of Half-Sandwich Ir(III), Rh(III), and Co(III) Complexes." Diss., Virginia Tech, 2017. http://hdl.handle.net/10919/79414.

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This dissertation describes the synthesis and antimicrobial use of a series of half-sandwich Ir(III), Rh(III), Co(III) amino acid and ethylenediamine complexes. This investigation focuses on the formulation (ηn-arene)M(L)X, (L = ethylenediamine or α-amino carboxylate), (M= Ir, Rh, Ru, Co). Arene, Ligand and metal center variations were designed to tailor antimicrobial activity specific for each organism studied (Staphylococcus aureus or Mycobacteria). Each of the D/L-amino acids formed a diasteromeric complex with chiral centers on both the metal center and amino acid ligand. The unique chirality of each center elicits different antimicrobial activity against the Mycobacteria studied. The metal center (M), arene ligand (ηn-arene), and amino acid (aa), were changed independently and studied for the antimicrobial activity. In a similar fashion, each of the complexes modified with ethylenediamine and diamine derivatives were studied for their antimicrobial activity against S.aureus. All complexes were synthesized,characterized by nuclear magnetic resonance (NMR), high-resolution mass spectroscopy (HRMS), single-crystal X-ray diffraction, and elemental analysis. During the course of this work it was found that the amino acid complexes with all metal centers were specific for antimicrobial activity against all types of Mycobacteria, while the diamine derivatives were active against different strains of S.aureus. Acitvity was measured to be as low as 2 ug/mL respectively depending on the complex used. A structure activity relationship was developed to determine what combinations of ligand, metal and arene were necessary to achieve the highest antimicrobial activity. The optimal arene R-chain length for CpR was determined to be R=hexyl for all complexes studied. The most active amino acidcomplex was determined to be that of L-phenylglycine for Mycobacteria, the cis-1,2-diaminocyclohexane complex is the most active ligand against S.aureus. Each metal center had similar activity levels. Toxicological studies were performed to test their viablity to be used in mammalian systems. The complexes with the highest activity were studied against several mammailan cell lines and revealed that mammailan cells were undergoing normal cellular processes at up to 40 times the minimal inhibitory concentration (MIC). A study of the MOA or mechanism of action revealed the ability of the amino acid complexes to affect the peptidyl transferase region on the 23s ribosomal subunit of M.smegmatis. This was accomplished by isolating resistant strains of M.smegmatis towards the most effective complex (Cp*hexyl)Ir(L-phenylglycine)-Cl. Cross drug resistance of these mutants was shown with clarithromycin. The DNA of the 23s ribosomal subunit was sequenced revealing a deletion/insertion mutation within domain V (bases 2057-2058).
Ph. D.

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4

Anderson, Margaret. "An electrochemical and kinetic investigation of some rhodium (III) complexes." Thesis, University of the West of Scotland, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294070.

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Matharu, Daljit. "Synthesis and applications of rhodium (III) complexes for asymmetric catalysis." Thesis, University of Warwick, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.445516.

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Bonnington, Kevin John. "Reactive rhodium (III) methyl complexes : kinetics, mechanisms and polymerisation catalysis." Thesis, University of Sheffield, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419638.

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Vitorino, Susana Ricardo. "Rhodium(III) supramolecular complexes : synthesis, DNA binding and biological studies." Thesis, University of Birmingham, 2011. http://etheses.bham.ac.uk//id/eprint/2814/.

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The work described in this thesis concerns the synthesis, DNA binding and cytotoxicity studies of new Rh(III) supramolecular complexes. Chapter 1 reviews DNA molecular recognition by synthetic agents; exploring the different DNA binding modes and their importance in the anticancer properties of several metallodrugs. Special attention is given to the exciting cylinder agents, which underpin the work in this thesis and to the work with rhodium complexes and their studies with DNA and as anticancer drugs. Chapter 2 describes the synthesis, purification and characterization of Rh(III) mononuclear, dinuclear single, double and triple stranded complexes. NMR, MS, UV‐Vis, elemental analyses and in some cases X‐ray crystallography are discussed in detail. In Chapter 3, DNA binding properties of the Rh(III) complexes are explored by CD and LD spectroscopy. Gel Electrophoresis experiments are also carried out using plasmid DNA (pBR322). The dinuclear complexes are found to bind to ct‐DNA and to have more dramatic effects than the mononuclear analogues. In addition they were found to cleave plasmid DNA. Chapter 4 presents cytotoxicity studies for some of the complexes synthesized against breast and ovarian cancer cell lines. A PCR study with the Rh(III) double stranded isomers is also carried out demonstrating that these complexes are able to inhibit and block DNA transactions as represented by PCR DNA replication.

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8

Ballard, Beau Jurisson Silvia S. "Synthesis and evaluation of ¹⁰⁵Rhodium (III) complexes of phosphine chelate systems." Diss., Columbia, Mo. : University of Missouri--Columbia, 2008. http://hdl.handle.net/10355/6693.

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Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 25, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Silvia Jurisson. Vita. Includes bibliographical references.

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9

Akgun, Zeynep. "Synthesis and evaluation of 105Rhodium(III) complexes derived from diaminodithioether (DADTE) ligands." Diss., Columbia, Mo. : University of Missouri-Columbia, 2006. http://hdl.handle.net/10355/4340.

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Thesis (Ph. D.) University of Missouri-Columbia, 2006.
The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on July 30, 2006). Includes bibliographical references.

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10

Nallas, Girlie Naomi A. "Heteronuclear trimetallic polyazine complexes of iridium (III) or rhodium (III) as electrocatalysts for the reduction of CO2." Diss., Virginia Tech, 1996. http://hdl.handle.net/10919/40465.

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Book chapters on the topic "Rhodium iii complexes"

1

Lay, Peter A., Alan M. Sargeson, Liangshiu Lee, and John D. Petersen. "Cis - and Trans -Bis(1,2-Ethanediamine)-Rhodium(III) Complexes." In Inorganic Syntheses, 283–87. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132555.ch76.

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2

Ficner, S., D. A. Palmer, T. P. Dasgupta, G. M. Harris, F. A. Cotton, and R. Philent. "Cobalt(III), Rhodium(III), and Iridium(III) Carbonato Complexes of the Pentaammine Type." In Inorganic Syntheses, 152–55. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132487.ch40.

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3

Lawrance, Geoffrey A., Alan M. Sargeson, George R. Brubaker, David W. Johnson, and Richard A. Peterson. "Pentakis(Methnamine)-(Trifluoromethanesulfonato-O ) Complexes of Chromium(III), Cobalt(III), and Rhodium(III)." In Inorganic Syntheses, 279–82. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132555.ch75.

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4

Hancock, Martin, Bente Nielsen, Johan Springborg, Alan Friedman, P. C. Ford, and Michael J. Saliby. "Cis -Tetraammine and Cis -Bis (1,2-Ethanediamine) Complexes of Rhodium(III)." In Inorganic Syntheses, 220–33. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132555.ch64.

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5

Pettinari, Claudio, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti. "Half-Sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-Based Ligands." In Advances in Organometallic Chemistry and Catalysis, 269–84. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch21.

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6

Rillema, D. P., and H. B. Ross. "Photophysical and Photochemical Properties of Ruthenium(II) Mixed-Ligand Complexes: Precursors to Homonuclear and Heteronuclear Multimetal Complexes Containing Ruthenium(II), Platinum(II), Rhenium(I) and Rhodium(III)." In Photochemistry and Photophysics of Coordination Compounds, 151–58. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_26.

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7

Pardasani, R. T., and P. Pardasani. "Magnetic properties of binuclear complex of rhodium(III) with N-hydroxylethyl-N,N′N′-tribenzimidazolylmethylenediamine." In Magnetic Properties of Paramagnetic Compounds, 15–16. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54234-7_3.

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Zhou, Chunhui, Mei-Hui Huang, and Kuo-Wei Huang. "Rhodium Pincer Complexes: Coordination, Reactivity and Catalysis." In Comprehensive Coordination Chemistry III, 43–107. Elsevier, 2021. http://dx.doi.org/10.1016/b978-0-08-102688-5.00102-1.

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Springborg, Johan. "Hydroxo-Bridged Complexes of Chromium (III), Cobalt (III), Rhodium (III), and Iridium (III)." In Advances in Inorganic Chemistry, 55–169. Elsevier, 1988. http://dx.doi.org/10.1016/s0898-8838(08)60231-7.

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van Leeuwen, P. W. N. M., and Z. Freixa. "Application of Rhodium Complexes in Homogeneous Catalysis with Carbon Monoxide." In Comprehensive Organometallic Chemistry III, 237–65. Elsevier, 2007. http://dx.doi.org/10.1016/b0-08-045047-4/00196-5.

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